2012 Air Monitoring Network Review Prepared by the Air Monitoring Division 2145 S. 11th Ave Suite 170 Phoenix, AZ 85007 ACKNOWLEDGEMENTS In 2012, the Maricopa County Air Quality Department’s Air Monitoring Division maintained 24 ambient air monitoring sites throughout Maricopa County. The Air Monitoring Division now operates with a full staff with some technicians pulling double duty in both ambient monitoring and mobile monitoring. The department would especially like to thank all of its air monitoring staff for the excellent job they do in maintaining Maricopa County’s air monitoring network. They are Ben Davis, Gary Ensminger, Robert Dyer, Ronald Pope, Casey Bryan, John Neff, Michael Perkins, Tom Shorb, Chris Hernandez, Hugh Tom, David Farganus, Daniel Daniels, Reynaldo Santillano, Larry Seals, Alex Herrera, Tom Dubishar and David Dubiel. In addition, the assistance of other agencies which provided data and helpful comments to this review is gratefully acknowledged. These include Arizona Department of Environmental Quality (ADEQ), Pinal County Air Quality Control District (PCAQCD) and the Maricopa Association of Governments (MAG). 2012 Maricopa County Air Quality Department Air Monitoring Division staff 2012 Air Monitoring Network Review 1 Maricopa County Air Quality Department Table of Contents ACKNOWLEDGEMENTS ................................................................................................................................................... 1 ABSTRACT ............................................................................................................................................................................ 5 DEFINITION OF TERMS .................................................................................................................................................... 6 CRITERIA POLLUTANT INFORMATION...................................................................................................................... 9 ABSTRACT OF POLLUTANTS .................................................................................................................................................. 9 CAUSES AND CHARACTERISTICS OF POLLUTANTS................................................................................................................. 9 Carbon Monoxide: ............................................................................................................................................................ 9 Lead: ................................................................................................................................................................................. 9 Nitrogen Dioxide: ........................................................................................................................................................... 10 Ozone: ............................................................................................................................................................................ 10 Particulate Matter: .......................................................................................................................................................... 10 Sulfur Dioxide: ............................................................................................................................................................... 11 NATIONAL AMBIENT AIR QUALITY STANDARDS ................................................................................................................ 11 ABSTRACT OF MARICOPA COUNTY AIR QUALITY DEPARTMENT POLLUTION MONITORING STRATEGIES ............ 12 NETWORK DESIGN .......................................................................................................................................................... 13 MONITORING OBJECTIVES .................................................................................................................................................. 13 MONITORING SITE TYPES.................................................................................................................................................... 13 MONITORING SPATIAL SCALES ........................................................................................................................................... 13 LOCATING MONITORS ......................................................................................................................................................... 14 OVERVIEW OF THE MARICOPA COUNTY AIR QUALITY DEPARTMENT’S AIR MONITORING NETWORK ............................... 15 2012 SUMMARY OF NETWORK RESULTS AND REQUIRED INFORMATION ................................................... 18 DATA COMPLETENESS ........................................................................................................................................................ 18 CRITERIA POLLUTANT SUMMARY ....................................................................................................................................... 19 Carbon Monoxide (CO).................................................................................................................................................. 19 Lead (Pb) ........................................................................................................................................................................ 21 Nitrogen Dioxide (NO2) ................................................................................................................................................ 23 Ozone (O3)...................................................................................................................................................................... 24 Particulate Matter <=10 Microns (PM10)........................................................................................................................ 27 Particulate Matter <=2.5 Microns (PM2 5) ...................................................................................................................... 30 Sulfur Dioxide (SO2) ...................................................................................................................................................... 34 2012 NAAQS EXCEEDANCE AND VIOLATION SUMMARY ................................................................................................... 36 2012 OZONE EXCEEDANCE AND VIOLATION DETAILS ........................................................................................................ 36 2012 VIOLATIONS OF THE 24-HOUR PM10 STANDARD ........................................................................................................ 41 EXCEPTIONAL EVENTS ........................................................................................................................................................ 41 2012 EXCEEDANCES OF THE 24-HOUR PM2 5 STANDARD .................................................................................................... 42 POLLUTION TRENDS ............................................................................................................................................................ 43 Carbon Monoxide ........................................................................................................................................................... 43 Nitrogen Dioxide ............................................................................................................................................................ 43 Ozone ............................................................................................................................................................................. 44 Particulates ..................................................................................................................................................................... 44 Sulfur Dioxide ................................................................................................................................................................ 46 SPECIAL PROJECTS AND NETWORK CHANGES .................................................................................................... 47 SEASONAL MONITORS......................................................................................................................................................... 47 THE CONSIDERATION OF ADDITIONAL SITES/MONITORS .................................................................................................... 47 LEAD MONITORING ............................................................................................................................................................. 47 OTHER NETWORK CHANGES/SPECIAL PROJECTS/COMMENTS............................................................................................. 48  AIR QUALITY FORECASTING ...................................................................................................................................... 48  AIR MONITORING WEBSITE ....................................................................................................................................... 48 MOBILE MONITORING PROGRAM ........................................................................................................................................ 48 NEAR-ROAD NO2 MONITORING .......................................................................................................................................... 48 RAPID RESPONSE NOTIFICATION SYSTEM ........................................................................................................................... 51 EMERGENCY RESPONSE NOTIFICATION SYSTEM ................................................................................................................. 51 2012 Air Monitoring Network Review 2 Maricopa County Air Quality Department ADDITIONAL COMMENTS ............................................................................................................................................. 53 ARIZONA DEPARTMENT OF ENVIRONMENTAL QUALITY NETWORK .................................................................................... 53 EPA OZONE MAPPING ........................................................................................................................................................ 53 REFERENCES ..................................................................................................................................................................... 55 APPENDIX I - MONITORING SITE DETAILS (PHOTOS AND SPECIFIC INFORMATION) .............................. 56 BUCKEYE (BE) (04-013-4011) ............................................................................................................................................ 57 CAVE CREEK (CC) (04-013-4008) ...................................................................................................................................... 58 CENTRAL PHOENIX (CP) (04-013-3002) ............................................................................................................................. 59 DEER VALLEY (DV) (04-013-4018) .................................................................................................................................... 60 DURANGO COMPLEX (DC) (04-013-9812) .......................................................................................................................... 61 DYSART (DY) (04-013-4010) ............................................................................................................................................. 62 FALCON FIELD (FF) (04-013-1010)..................................................................................................................................... 63 FOUNTAIN HILLS (FH) (04-013-9704) ................................................................................................................................ 64 GLENDALE (GL) (04-013-2001).......................................................................................................................................... 65 GREENWOOD (GR) (04-013-3010) ...................................................................................................................................... 66 HIGLEY (HI) (04-013-4006) ................................................................................................................................................ 67 HUMBOLDT MOUNTAIN (HM) (04-013-9508)..................................................................................................................... 68 MESA (ME) (04-013-1003) ................................................................................................................................................. 69 NORTH PHOENIX (NP) (04-013-1004)................................................................................................................................. 70 PINNACLE PEAK (PP) (04-013-2005) .................................................................................................................................. 71 RIO VERDE (RV) (04-013-9706) ......................................................................................................................................... 72 SOUTH PHOENIX (SP) (04-013-4003) .................................................................................................................................. 73 SOUTH SCOTTSDALE (SS) (04-013-3003) ........................................................................................................................... 74 TEMPE (TE) (04-013-4005)................................................................................................................................................. 75 WEST 43RD AVENUE (WF) (04-013-4009) ........................................................................................................................... 77 WEST PHOENIX (WP) (04-013-0019) .................................................................................................................................. 78 ZUNI HILLS (ZH) (04-013-4016)......................................................................................................................................... 79 APPENDIX II - EPA REQUIRED DATA ......................................................................................................................... 80 REQUIRED GENERAL STATEMENT REGARDING CHANGES TO THE PM2 5 NETWORK............................................................ 81 NOTES REGARDING APPENDIX DATA ................................................................................................................................... 81 APPENDIX III - PUBLIC NOTICE AND COMMENT INFORMATION .................................................................. 106 PUBLIC NOTICE PERIOD .................................................................................................................................................... 106 NEWS RELEASE ................................................................................................................................................................. 106 List of Tables Table 1 National Ambient Air Quality Standards .................................................................................................................. 11 Table 2 Site Monitoring Objectives ....................................................................................... Error! Bookmark not defined. Table 3 Spatial Measurement Scales ....................................................................................... Error! Bookmark not defined. Table 4 Maricopa County Ambient Air Monitoring Sites for 2012 ...................................................................................... 16 Table 5 Criteria Pollutants Monitored, by Site and Network ................................................................................................. 16 Table 6 Site Location ............................................................................................................................................................. 17 Table 7 Site Instrument Setup ................................................................................................................................................ 18 Table 8 2012 Criteria Pollutant Data Completeness............................................................................................................... 18 Table 9 2012 8-hour Average Carbon Monoxide Summary .................................................................................................. 20 Table 10 CO Data Required by EPA .................................................................................................................................. 20 Table 11 2012 Lead Summary ............................................................................................................................................... 21 Table 12 Lead Data Required by EPA ............................................................................................................................... 22 Table 13 2012 Nitrogen Dioxide Summary ........................................................................................................................... 23 Table 14 NO2 Data Required by EPA ................................................................................................................................. 24 Table 15 2012 8-hour Average Ozone Summary ................................................................................................................... 25 Table 16 3 Year Average of 8-Hour Ozone ........................................................................................................................... 26 Table 17 Ozone Data Required by EPA ............................................................................................................................. 26 Table 18 2012 PM10 Summary ............................................................................................................................................... 28 Table 19 PM10 Data Required by EPA ............................................................................................................................... 29 2012 Air Monitoring Network Review 3 Maricopa County Air Quality Department Table 20 2012 PM2 5 Summary (FRM Filter-based Monitors) ............................................................................................... 31 Table 21 2012 PM2 5 Data Summary (FEM Continuous Monitors) ....................................................................................... 31 Table 22 2012 PM2 5 3-Year Averages of 98th Percentile (FRM Monitors) .......................................................................... 31 Table 23 2012 PM2 5 3-Year Averages of 98th Percentile (FEM Monitors) .......................................................................... 32 Table 24 PM2.5 SLAMS Data Required by EPA ................................................................................................................ 32 Table 25 2012 Sulfur Dioxide Summary................................................................................................................................ 34 Table 26 SO2 Data Required by EPA ................................................................................................................................. 35 Table 27 2012 NAAQS Exceedances and Violation Summary ............................................................................................. 36 Table 28 2012 Ozone 8-hour Average Exceedance Details ................................................................................................... 36 Table 29 2012 Ozone Violations ............................................................................................................................................ 39 Table 30 2012 PM10 24-hour Average Exceedance Details ................................................................................................... 39 Table 31 Violations of the 24-hour PM10 Standard ................................................................................................................ 41 Table 32 2012 PM2.5 Exceedances........................................................................................................................................ 42 Table 33 Seasonal Monitors ................................................................................................................................................... 47 Table 34 Air Quality Index .................................................................................................................................................... 54 List of Figures Figure 1 Maricopa County Air Monitoring Sites for 2012 ..................................................................................................... 15 Figure 2 2012 Carbon Monoxide Monitoring Sites ................................................................................................................ 19 Figure 3 2012 Lead Monitoring Sites ..................................................................................................................................... 21 Figure 4 2012 Nitrogen Dioxide Monitoring Sites ............................................................................................................. 23 Figure 5 2012 Ozone Monitoring Sites .................................................................................................................................. 24 Figure 6 2012 PM10 Monitoring Sites (includes continuous and non-continuous sites)......................................................... 27 Figure 7 2012 PM2 5 Monitoring Sites (continuous and non-continuous) .............................................................................. 30 Figure 8 2011 Sulfur Dioxide Monitoring Sites ..................................................................................................................... 34 Figure 9. Aerial photograph and street view of proposed monitoring Site #1. .............................................................. 50 Figure 10 EPA AIRNow Website .......................................................................................................................................... 53 List of Charts Chart 1 2010-2012 8-hr Avg. Carbon Monoxide Maximum Values ...................................................................................... 43 Chart 2 2010-2012 Nitrogen Dioxide Annual Average Readings .......................................................................................... 43 Chart 3 2010-2012 Ozone 4th High 8-hr Average ................................................................................................................. 44 Chart 4 2010-2012 PM10 24-hr Average Maximum Values ................................................................................................... 44 Chart 5 2010-2012 PM10 Annual Average ............................................................................................................................. 45 Chart 6 2010-2012 PM2 5 Annual Average ............................................................................................................................. 45 Chart 7 2010-2012 PM2 5 98th Percentile ................................................................................................................................ 46 Chart 8 2010-2012 Sulfur Dioxide Annual Average .............................................................................................................. 46 2012 Air Monitoring Network Review 4 Maricopa County Air Quality Department ABSTRACT This 2012 Annual Air Monitoring Network Review is respectfully submitted by the Maricopa County Air Quality Department (MCAQD) to the United States Environmental Protection Agency (US EPA) Region 9. The Air Monitoring Network Review evaluates the adequacy of the ambient air monitoring network with respect to the monitoring objectives and spatial scales. This annual assessment is required by 40 CFR Part 58, Subpart B. Network changes, special projects, and 3-year data summaries are included in the review. This network review is also preliminary to our annual data certification with the US EPA and helps us assess the quality of our data before submitting for data certification. This network review has the secondary purpose of informing the public of air pollutants that can affect their health, how MCAQD monitors these pollutants, and what the actual readings are, so that our citizens can make informed decisions regarding their lifestyles. 2012 Air Monitoring Network Review 5 Maricopa County Air Quality Department DEFINITION OF TERMS ADEQ: Arizona Department of Environmental Quality. AQI: Air Quality Index. An index that is applicable to all pollutants which show the concentration of pollutant relative to its respective standard. When the AQI reaches 101 the concentration has exceeded the NAAQS. AQS: Environmental Protection Agency’s Air Quality System Attainment: This refers to the NAAQS used to comply with the federal Clean Air Act. After several years of no violations of the NAAQS, the EPA can classify the area as in attainment for that pollutant. AWT: Average Weekday Traffic count. BAM: Beta Attenuation Monitor. A continuous particulate measuring instrument used by MCAQD to measure PM10. CFR: Code of Federal Regulations. Class I: Federally designated park or wilderness area with mandated visibility protection. CO: Carbon monoxide. Continuous monitoring: A method of monitoring air pollutants that is continually measuring the quantity of the pollutant, either gaseous or particulate. Continuous monitors can be used to obtain real-time or short-term averages of pollutants. Criteria Pollutants: Six pollutants (CO, Lead, NO2, O3, Particulates, and SO2) that have NAAQS established by the US EPA. Delta T: Difference between two levels of temperature measurements. Delta T is measured in the MCAQD network at heights of 2 and 10 meters. A higher temperature at the upper level indicates a temperature inversion. Design Value: A design value is a statistic that describes the air quality status of a given area relative to the level of the NAAQS. For a concentration-based standard, the air quality design value is simply the standard-related test statistic. The design value of a pollutant monitoring network is the highest sample value in the network used to compare to the NAAQS; e.g. the 24-hour PM2 5 design value for the network is the monitor with the highest 3-year average of the 98th percentile. EPA: U. S. Environmental Protection Agency. Exceptional Events: An uncontrollable event caused by natural sources of pollution or an event that is not expected to recur at a given location. The ADEQ makes the determination of which events to classify as exceptional; they then petition the EPA for acceptance of the classification. If the EPA accepts the petition, the measured pollution event will not be used in determination of compliance with the NAAQS. FDMS-TEOM: Filter Dynamics Measurement System-Tapered Element Oscillating Microbalance. A continuous particulate measuring instrument used by MCAQD to measure PM2 5. 2012 Air Monitoring Network Review 6 Maricopa County Air Quality Department FEM: Federal Equivalency Method. An official method, i.e. equipment and procedure, of monitoring air pollution that has been determined to produce results similar to the Federal Reference Method (FRM). Filter-based Monitor A method of monitoring particulate pollution that involves exposing a preweighed filter to a specific flow volume of air to capture the particulates in the air. The filters are then post-weighed to determine the weight of particulates per volume, e.g. µg/m3. Filter-based monitors used by MCAQD are all FRM monitors. FRM: Federal Reference Method. An official method, i.e. equipment and procedure, of monitoring air pollution that has been tested and determined to produce results that accurately measure air pollution with acceptable precision. These methods are the baseline that all other methods, e.g. Federal Equivalency Methods (FEM), refer to. HAPs Hazardous air pollutants. An air-born chemical that has been listed in the federal Clean Air Act and has an associated standard or process requirement determined for it. MAG: Maricopa Association of Governments MCAQD: Maricopa County Air Quality Department. µg/m3: Microgram per cubic meter. MSA: Metropolitan Statistical Area. A geographical area designated by the federal government based on the concept of a core area with a large population nucleus, plus adjacent communities having a high degree of economic and social integration with that core. The MCAQD operates within the Phoenix-Mesa MSA which includes portions of Maricopa and Pinal County. NAAQS: National Ambient Air Quality Standards. A health and welfare-based standard that is set by the US EPA to qualify allowable levels of criteria pollutants. NCORE: National Core Multi-Pollutant Site. A national network of multi-pollutant monitoring sites used to represent the nation as a whole. There are currently ~75 NCORE sites (1-3 per state plus Washington DC, Virgin Islands, and Puerto Rico) located in both urban and rural areas. NO2: Nitrogen dioxide. NOX: Nitrogen oxides. Sum of nitric oxide (NO), NO2, and other nitrogen-containing compounds. O3: Ozone. Pb: Lead. PM: Particulate matter. Material suspended in the air in the form of minute solid particles or liquid droplets. PM2.5: Particulate matter of 2.5 Microns in diameter or smaller PM10: Particulate matter of 10 Microns in diameter or smaller. 2012 Air Monitoring Network Review 7 Maricopa County Air Quality Department PPB: Parts per billion. PPM: Parts per million. Primary Standard: One portion of the NAAQS. These standards are designed to protect the public health. Secondary Standard: One portion of the NAAQS. environment. SIP: State Implementation Plan. SIPs are a collection of state and local regulations and plans to achieve healthy air quality under the Clean Air Act. SLAMS: State and Local Air Monitoring Station. The SLAMS consist of a network of approximately 5,000 monitoring stations nationwide whose size and distribution is largely determined by the needs of State and local air pollution control agencies to meet their respective State implementation plan (SIP) requirements. Other types of monitoring stations include NCORE (national core) and SPM (special purpose) monitors. Maricopa County does not currently operate any NCORE sites and only operates one SPM site. SO2: Sulfur dioxide. SPM: Special purpose monitor. Special Purpose Monitoring Stations provide for special studies needed by the State and local agencies to support State implementation plans and other air program activities. The SPMs are not permanently established and can be adjusted easily to accommodate changing needs and priorities. SSI: Size Selective Inlet. SSI High Volume Samplers are filter-based instruments used by MCAQD to measure PM10. TEOM Tapered Element Oscillating Microbalance. A continuous particulate measuring instrument used by MCAQD to measure PM10. VOC: Volatile organic compounds. VOCs are chemical compounds that can easily vaporize and enter the atmosphere. There are many natural and artificial sources of VOCs; solvents and gasoline make up some of the largest artificial sources. VOCs will react with NOx in the presence of sunlight to create ground-level ozone pollution. 2012 Air Monitoring Network Review 8 These standards are designed to protect the Maricopa County Air Quality Department CRITERIA POLLUTANT INFORMATION Abstract of Pollutants Certain air pollutants, called “criteria air pollutants,” are common throughout the United States. These pollutants can cause health problems, harm the environment, and cause property damage. These criteria pollutants are so named since the US EPA has regulations, called the National Ambient Air Quality Standards (NAAQS), on allowable levels of these substances using health-based criteria. One set of limits, called “primary standards,” protect health, while another set of “secondary standards”, are designed to protect property and the environment. The US EPA names the following pollutants as criteria pollutants: carbon monoxide (CO), lead (Pb), nitrogen dioxide (NO2), ozone (O3), particulates (PM10 & PM2.5), and sulfur dioxide (SO2). MCAQD operates monitors for all of the criteria pollutants. Causes and Characteristics of Pollutants Carbon Monoxide: CO is the most widely distributed and most commonly occurring air pollutant. Total emissions of CO to the atmosphere exceed all other pollutants combined, on a weight basis. Fortunately, CO does not persist in the atmosphere, but is quickly converted to carbon dioxide (CO2). CO can reach dangerous levels in localized areas or hotspots such as heavily traveled intersections or city streets. In addition, CO has been implicated in ozone formation. Most people are familiar with CO and are aware that automobiles produce this deadly odorless and colorless gas. In Maricopa County, more than 70% of all anthropogenic CO comes from motor vehicle emissions. In fact, this gas is produced almost anytime something is burned. All substances that are living (plants, animals) or that were once living (wood, coal, oil, gasoline) are composed of carbon compounds. If these substances are burned in the presence of sufficient oxygen, the carbon is converted to CO2 gas. If, as is often the case, not enough oxygen is present, carbon monoxide gas is produced. Carbon monoxide’s danger lies in the extremely strong affinity that hemoglobin has for it. Hemoglobin, the special oxygen-transporting material in the red blood cell, has approximately 200 times stronger affinity for CO than for oxygen. Therefore, if both CO and O2 are present the bonding between the CO and hemoglobin will prevent the O2 from exchanging within a person’s body. This puts a heavy burden on people with heart disease and can aggravate angina, but even healthy people can suffer from harmful side effects from CO. In 2012 Maricopa County achieved its 16th consecutive year of compliance with the eight-hour CO standard. Lead: Lead is a metal found naturally in the environment as well as in manufactured products. The major sources of lead emissions have historically been motor vehicles (such as cars and trucks) and industrial sources. Due to the phase out of leaded gasoline, metals processing is the major source of lead emissions to the air today. The highest levels of lead in air are generally found near lead smelters. General aviation airports are also a significant source of lead, as general aviation fuel still contains lead additives. Other stationary sources are waste incinerators, utilities, and lead-acid battery manufacturers. In the early 1970s, EPA set national regulations to gradually reduce the lead content in gasoline. In 1975, unleaded gasoline was introduced for motor vehicles equipped with catalytic converters. EPA banned the use of leaded gasoline in highway vehicles in December 1995. Primarily as a result of EPA's regulatory efforts to remove lead from gasoline, levels of lead in the air have decreased by 94 percent between 1980 and 1999. Following the removal of lead from automotive fuel, levels of airborne lead in Maricopa County were drastically reduced. Because concentrations were consistently below national levels, Maricopa County was allowed to discontinue ambient air monitoring for lead in 1997. However, recent changes in the lead monitoring 2012 Air Monitoring Network Review 9 Maricopa County Air Quality Department regulations have brought the need to resume monitoring activities in Maricopa County. In July 2010, MCAQD opened a new lead monitoring site at Deer Valley airport. Deer Valley airport is the busiest general aviation airport in the county, and thus the largest expected source of lead emissions. Results from the last twelve months of monitoring have shown that ambient levels of lead are still well below the air quality standard, even with the much more stringent regulations. Nitrogen Dioxide: NO2 belongs to a family of highly reactive gases called nitrogen oxides. These gases are formed when fuel is burned at high temperatures, and are emitted primarily from automobile exhaust and power plants. Exposure to nitrogen dioxide can irritate the lungs and lower resistance to respiratory infections, particularly in people with existing respiratory illness such as asthma. Maricopa County is currently in attainment status for NO2. Maricopa County will be engaging in near-road monitoring to ensure compliance with the new 1-hour NO2 standard. Ozone: O3 is a naturally occurring compound in which three oxygen atoms combine together. This is an unstable combination, and ozone is continually going through a natural cycle of being formed and then converting back to the more stable “normal” double oxygen compound (O2). The cycle occurs fairly rapidly. In the stratosphere (six miles and more above the earth), naturally occurring ozone has a beneficial effect of screening out harmful ultraviolet light from the sun. However, ground-level ozone is a pollutant and is a component of the regional smog that affects the valley. Ozone is not directly emitted into the air, but rather forms in a complex reaction that involves heat, sunlight, and a “soup” of toxic pollutants, especially volatile organic compounds (VOCs). Some of the most common sources of VOCs are gasoline vapors, chemical solvents, and combustion products of fuels and consumer products. Ozone is created by sunlight acting on nitrates (NOX) and VOCs from motor vehicles and stationary sources, and can be carried hundreds of miles from their origins. Ozone affects the respiratory system in people and animals, and also affects the growth of plants. Maricopa County is currently in non-attainment for Ozone pollution, although the number of violations of the standard had been decreasing in recent years. However, in February 2008, the EPA lowered the NAAQS for ozone from 0.08 ppm to 0.075 ppm. Many of the ozone monitoring sites were in borderline compliance with the older standard and now are exceeding the new standard. Strategies will have to be developed to lower ambient ozone levels into compliance with the new standard, improving air quality for all. Particulate Matter: Particulate matter is the term for solid or liquid particles found in the air. Particle pollution is made up of a number of components, including acids (such as nitrates and sulfates), organic chemicals, metals, and soil or dust particles. While some particles are large or dark enough to be seen as soot or smoke, others can only be seen through an electron microscope. In 1987 the EPA replaced the Total Suspended Particulates (TSP) air quality standard with a standard for PM10 (particles measuring ten microns or less). Health research studies have found that PM10 has the ability to reach the lower regions of the respiratory tract, and thus can affect the respiratory system in both humans and animals. The size of particles is directly linked to their potential for causing health problems. EPA is concerned about particles that are 10 micrometers in diameter or smaller because those are the particles that generally pass through the throat and nose and enter the lungs. Once inhaled, these particles can affect the heart and lungs and cause serious health effects. EPA groups particle pollution into two categories: • "Coarse particles," such as those found near roadways and dusty industries, range in size from 2.5 to 10 microns in diameter. 2012 Air Monitoring Network Review 10 Maricopa County Air Quality Department • "Fine pait icles," such as tl1ose fotmd in smoke and haze, have diameters smaller than 2.5 microns. These particles can be directly emitted from sources such as forest fires, or they can form when gases emitted from power plants, industries and automobiles react in the air. Maricopa C01mty is cmTently in non-attainment. for PM 10, but. is in attainment. for PM2 5 Sulfur Dioxide: S02 is emitted (in gaseous form) largely from burning high-sulfur coal, oil, and diesel fuel. Because this gas is usually folllld in association with paiticulate pollution, as S02 is the precursor for fine sulfate paiticles, separating the health effects of these two pollutants is difficult. Together S02 ai1d PM2 5 make up a major portion of the pollutant load in many cities, acting sepai·ately and in concert to threaten public health. S02 contributes to respiratory illness, particularly in children and the elderly, and aggravates existing heait and Imig diseases. S02 contributes to tl1e formation of acid rain, and it contributes to the formation of atmospheric particles that cause visibility impairment, most noticeably in national pai·ks. S02 and the pollutants fonned from S02, such as sulfate part icles, can be transported over long distances and deposited far from the point of origin. This means that problems with S02 ar·e not confined to areas where it is emitted. Maricopa County is in attainment for Sulfur Dioxide. National Ambient Air Quality Standards The EPA Office of Air Quality Planning ai1d Standards (OAQPS) manages programs to improve air quality in areas where the cmTent quality is m1acceptable and to prevent deterioration in areas where the air is relatively free of contamination. To accomplish this task, OAQPS establishes the National Ambient Air Quality Standard (NAAQS) for each of the criteria pollutants (see Table 1). There are two types of standar·ds. Primary standards protect against adverse health effects; secondary standards protect against. welfare effects, such as damage to farm crops and vegetation and/or damage to buildings. Because different pollutants have different effects, the NAAQS are also different. Some pollutants have standards for both long-term and short-term averaging times. The short-term standat·ds ar·e designed to protect against acute, or short-term, health effects, while the long-term star1dar·ds are established to protect against chronic health effects. Table 1 lists the NAAQS for the six criteria pollutants. Table 1 National Ambient Air Quality Standards Pollutant Primary/ Secondary I Carbon Monoxide primary Lead primary I secondary Rolling 3 month average primary Nitrogen Dioxide Ozone Particle Pollution PM2.s PM10 Averaging Time primary I secondary primary and secondary primary secondary Primary I secondary primary I 2012 Air Monitoring Network Review Level Form 8-hour 9 ppm 1-hour 35 ppm Not to exceed one per year on avg. over 3 years 0.15 µg/m3 Not to exceed one per year on avg. over 3 years 1-hour 100 ppb 98th percentiles, avg. over 3 years Annual 53 ppb 8-hour 0.075 ppm Annual Annual 12 µg/m 3 15 µg/m 3 35 µg/m 3 ~nnual Mean 3 year avg. of the fourth high 8-hr avg. daily max. 3 year avg. of the annual means 3 year avg. of the annual means 3 yea r avg. of the 98th percentiles 3 150 µg/m Not to be exceeded more than once 24-hour 24-hour 11 Maricopa County Air Quality Dep artment secondary Sulfur Dioxide primary 1-hour 75 ppb secondary 3-hour 0.5 ppm per year on average over 3 years 99th percentile of 1-hour daily max., averaged over 3 years Not to exceed one per year Abstract of MARICOPA COUNTY AIR QUALITY DEPARTMENT Pollution Monitoring Strategies MCAQD monitors for these criteria pollutants by maintaining twenty-four ambient air-monitoring sites throughout Maricopa County. The dates that the sites were established range from 1961 (Central Phoenix) to July 2011 (Deer Valley). Land use patterns around these sites vary from heavy populated urban areas to sparsely populated rural settings. Site elevations range from 845 feet above sea level (Buckeye) to 5190 feet above sea level at the top of Humboldt Mountain. Not all pollutants are measured at all sites; some sites measure most of the pollutants, while others only measure one or two pollutants. No agreements have been made to share network design responsibilities for any MSAs in our jurisdiction. The following section will detail how the department designs its air monitoring network to obtain representative samples of these air pollutants. Following this will be details of the results obtained from our 2012 sampling season. 2012 Air Monitoring Network Review 12 Maricopa County Air Quality Department NETWORK DESIGN Monitoring Objectives The ambient air monitoring networks must be designed to meet three basic monitoring objectives. These basic objectives are listed below. The appearance of any one objective in the order of this list is not based upon a prioritized scheme. Each objective is important and must be considered individually. • Provide air pollution data to the general public in a timely manner. Data can be presented to the public in a number of attractive ways including through air quality maps, newspapers, Internet sites, and as part of weather forecasts and public advisories. • Support compliance with ambient air quality standards and emissions strategy development. Data from FRM, FEM, and ARM monitors for NAAQS pollutants will be used for comparing an area's air pollution levels against the NAAQS. Data from monitors of various types can be used in the development of attainment and maintenance plans. SLAMS and N-Core station data will be used to evaluate the regional air quality models used in developing emission strategies, and to track trends in air pollution abatement control measures' impact on improving air quality. • Support for air pollution research studies. Air pollution data from the N-Core network can be used to supplement data collected by researchers working on health effects assessments and atmospheric processes, or for monitoring methods development work. Monitoring Site Types In order to support the air quality management work indicated in the three basic air monitoring objectives, a network must be designed with a variety of types of monitoring sites. Monitoring sites must be capable of informing managers and the general public about many things including the peak air pollution levels, typical levels in populated areas, air pollution transported into and outside of a city or region, and air pollution levels near specific sources (Table 2). Table 2 Site Monitoring Types Highest concentrations expected to occur in the area covered by the network. Measure typical concentrations in areas of high population density. Determine the impact of significant sources or source categories on air quality. Determine general background concentration levels. Determine the extent of regional pollutant transport among populated areas and in support of secondary standards. Sites located to measure air pollution impacts on visibility, vegetation damage, or other welfare-based impacts. Monitoring Spatial Scales The concept of spatial scale of representativeness was created to help link monitoring objectives and site types with the physical location of a monitor. Spatial scale of representativeness is defined in terms of the physical dimensions of the air parcel around a monitoring site throughout which pollutant 2012 Air Monitoring Network Review 13 Maricopa County Air Quality Department concentrations are reasonably similar. There are six scales of representativeness of most interest for the monitoring site types (Table 3). Table 3 Spatial Scales of Representativeness Name Micro Scale Middle Scale Neighborhood Scale Urban Scale Regional scale National and global Scales Distance 0 to 100 meters 100 to 500 meters 0.5 to 4 kilometers 4 to 50 kilometers 10 to 100’s of kilometers Characterizing the nation and the globe as a whole. Locating Monitors Since it is physically and fiscally impossible to monitor air quality in every location, the goal in locating monitors is to correctly integrate the monitoring objective and monitoring site type with the spatial scale most appropriate for the air pollutant to be measured. For example, consider the case where the objective is to determine NAAQS compliance by understanding the maximum ozone concentrations for an area. Such areas would most likely be located downwind of a metropolitan area, quite likely in a suburban residential area where children and other susceptible individuals are likely to be outdoors. Sites located in these areas are most likely to represent an urban scale of measurement. In this example, physical location was determined by considering ozone precursor emission patterns, public activity, and meteorological characteristics affecting ozone formation and dispersion. Thus, spatial scale of representativeness was not used in the selection process but was a result of site location. Using these principles, the total number of monitoring sites that will serve the variety of data needs will be substantially higher than federal minimum requirements. The optimum size of a particular network involves trade-offs among data needs and available resources. This does not mean that the number of monitoring sites is fixed. To the contrary, each network must be dynamic enough to maintain a current representative sample of the air quality. The EPA, State, and local agencies will periodically collaborate on network design issues through the network assessment process outlined in § 58.10. 2012 Air Monitoring Network Review 14 Maricopa County Air Quality Department Overview of the Maricopa County Air Quality Department’s Air Monitoring Network Maricopa County has a population of over 3.9 million people (2012 US Census estimate). The EPA has mandated a minimum number of monitors required to properly represent this population. MCAQD has designed its network, using the concepts of scale and objective mentioned previously, to meet and in most cases exceed these EPA requirements (see “Required General Information on Monitoring Network” in Appendix II). Altogether, the department operated a network of 24 monitoring sites in 2012. The following image details the location of these sites and gives the abbreviation symbols used by Maricopa County. Table 4 and Table 5, which follows, gives the AQS code assigned to each site and details which criteria pollutant is monitored at which site along with the monitor designation, respectively. Table 6 and Table 7 give more specific information about the location of the sites and the types and numbers of monitors at each site, respectively. Figure 1 Maricopa County Air Monitoring Sites for 2012 2012 Air Monitoring Network Review 15 Maricopa County Air Quality Department Table 2 Maricopa County Ambient Air Monitoring Sites for 2012 Site Name Blue Point Buckeye Cave Creek Central Phoenix Deer Valley Durango Complex Dysart Falcon Field Fountain Hills Glendale Greenwood Higley Humboldt Mountain Site Abbr. BP BE CC CP DV DC DY FF FH GL GR HI HM AQS Code 04-013-9702 04-013-4011 04-013-4008 04-013-3002 04-013-4018 04-013-9812 04-013-4010 04-013-1010 04-013-9704 04-013-2001 04-013-3010 04-013-4006 04-013-9508 Site Name Mesa North Phoenix Pinnacle Peak Rio Verde South Phoenix South Scottsdale Tempe West Chandler West 43rd Ave. West Phoenix Zuni Hills Site Abbr. ME NP PP RV SP SS TE WC WF WP ZH AQS Code 04-013-1003 04-013-1004 04-013-2005 04-013-9706 04-013-4003 04-013-3003 04-013-4005 04-013-4004 04-013-4009 04-013-0019 04-013-4016 Table 3 Criteria Pollutants Monitored, by Site and Network Site Blue Point Buckeye Cave Creek Central Phoenix Deer Valley Durango Complex Dysart Falcon Field Fountain Hills Glendale Greenwood Higley Humboldt Mountain Mesa North Phoenix Pinnacle Peak Rio Verde South Phoenix South Scottsdale Tempe West Chandler West 43rd Ave. West Phoenix Zuni Hills CO Pb SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS O3 SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS PM2.5 PM10 NO2 SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SLAMS SPM SLAMS SLAMS SO2 SLAMS SLAMS SLAMS SLAMS SLAMS=State and Local Monitoring Station; SPM=Special Purpose Monitoring Station 2012 Air Monitoring Network Review 16 Maricopa County Air Quality Department Table 4 Site Location Site Latitude Longitude Site Location BP BE CC CP DV DC DY FF FH GL GR HI HM ME NP PP RV SP SS TE WC WF WP ZH 33.54549 -111.60925 33.37005 -112.62070 33.82169 -112.01739 33.45793 -112.04601 33.684627 -112.08635 33.42650 -112.11814 33.63713 -112.34184 33.45223 -111.73331 33.61103 -111.72529 33.56936 -112.19153 33.46093 -112.11748 33.31074 -111.72255 33.98280 -111.79870 33.41045 -111.86507 33.56033 -112.06626 33.71231 -111.85272 33.71881 -111.67183 33.40316 -112.07533 33.47968 -111.91721 33.4124 -111.93473 33.29898 -111.88431 33.40642 -112.14434 33.48385 -112.14257 33.686738 -112.294171 Usery Pass & Bush Highway MC85 & HWY 85 32nd St. & Carefree Highway 19th St & Roosevelt 10th Ave. & Deer Valley Rd. 27th Ave. & Durango St. Bell Rd. & Dysart Rd. McKellips & Greenfield Palisades & Fountain Hills Blvd. 59th Ave & W. Olive 27th Ave. & Interstate 10 Higley Rd. & Chandler Blvd Top of Humboldt Mountain Broadway Rd. & Alma School Rd. 7th Street & Dunlap Avenue Pima Rd & Pinnacle Peak Forest Rd & Del Ray Ave. Central Ave. & Broadway Scottsdale Rd. & Miller Rd. College Ave. & Apache Blvd. Ellis St. & Frye Rd. 43rd Ave. & Broadway Rd. 39th Ave. & Earll Dr. 109th Ave & Deer Valley Rd. 2012 Air Monitoring Network Review 17 AQS Code 04-013-9702 04-013-4001 04-013-4008 04-013-3002 04-013-4018 04-013-9812 04-013-4010 04-013-1010 04-013-9704 04-013-2001 04-013-3010 04-013-4006 04-013-9508 04-013-1003 04-013-1004 04-013-2005 04-013-9706 04-013-4003 04-013-3003 04-013-4005 04-013-4004 04-013-4009 04-013-0019 04-013-4016 Maricopa County Air Quality Department Table 5 Site Instrument Setup AIR MONITORING NETWORK OPERATIONS Sites BP BE CC CP DC DY DV FF FH GL GR HI HM ME MM # NP PP RV SP SS TE WC WF WP ZH Active Instr WS/ WD 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 23 O3 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 19 * = seasonal monitor CO 1 NO2 * 1 1 1 1 * 1 1 * 1 1 1 * 1 * 1 1 1 1 SO2 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 13 1 1 1 1 1 4 2 PM10 1 1 1 1 1 * * * * 1 Press Delta Temp 17 1 1 1 1 1 5 1 1 1 1 1 1 PM2.5 Pb 1 2 1 1 1 1 1 1 1 1 1 1 1 1 17 8 1 1 2 Temp 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Rel Hum 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 23 13 1 Room Tmp 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 25 Rain Multi -Gas 1 1 1 1 1 1 1 1 1 2 2 2 2 1 AQS Code 04-013-9702 04-013-4011 04-013-4008 04-013-3002 04-013-9812 04-013-4010 04-013-4017 04-013-1010 04-013-9704 04-013-2001 04-013-3010 04-013-4006 04-013-9508 04-013-1003 Mobile Truck 04-013-1004 04-013-2005 04-013-9706 04-013-4003 04-013-3003 04-013-4005 04-013-4004 04-013-4009 04-013-0019 04-013-4016 18 Maricopa County Air Quality Department Active Inst 4 10 6 10 8 8 6 4 6 9 8 6 4 9 13 10 3 2 9 9 9 8 6 12 4 6 Total # of Pollutant Monitors Total # of Active Instruments Number of Active Sites # = Mobile Monitoring Truck 2012 Air Monitoring Network Review Solar PM 2.5 Filter 67 183 24 Last Audit 12/6/12 12/6/12 4/22/10 4/22/10 4/22/10 4/22/10 6/8/10 12/10/12 4/22/10 4/22/10 12/22/12 4/22/10 12/10/12 12/10/12 1/22/13 12/10/12 4/22/10 4/22/10 12/7/12 12/7/12 12/1/12 4/22/10 12/10/12 4/22/10 12/10/12 2012 SUMMARY OF NETWORK RESULTS AND REQUIRED INFORMATION Data Completeness Before any data set can be considered valid it must first pass a data recovery test that consists of determining the ratio of actual samples to scheduled samples by quarter. This ratio must be greater than 75% for a data set to pass the first validity test. After all validation tests have been passed, the data can be used to determine compliance with the NAAQS. The following is a summary of the annual data completeness for all criteria pollutants (Table 8). Note that CO, O3, NO2, and SO2 samples are all from continuous monitors and are therefore hourlyaveraged samples. PM monitors are either continuous, and therefore hourly-averaged, or filter-based and daily-averaged. Filters are sampled for 24 hours every 3rd day (PM2.5) or every 6th day (PM10). Table 6 2012 Criteria Pollutant Data Completeness Carbon Monoxide Lead Nitrogen Dioxide Ozone PM2 5 (1 in 3 day) PM2 5 (continuous) PM10 (1 in 6 day) PM10 (continuous) Sulfur Dioxide Total Number of Actual Samples 68674 Number of Scheduled Samples 69456 Data Completeness (Actual/Schedule) 98.9 71 91 78.0 34313 35136 97.7 110311 112128 98.4 213 221 96.4 48323 52680 97.3 378 389 97.2 124321 125928 98.8 17187 17568 97.8 403791 413597 97.6 2012 Air Monitoring Network Review 18 Maricopa County Air Quality Department Criteria Pollutant Summary Carbon Monoxide (CO) Figure 2 2012 Carbon Monoxide Monitoring Sites During 2012, twelve CO monitors were reported as operational to the US EPA Air Quality System (AQS) (Figure 2). All CO monitors are classified as SLAMS (Table 5). There are two primary standards for CO, the 8-hour average and the 1-hour average. The 8-hour primary standard is 9 ppm and the 1-hour primary standard is 35 ppm. A violation of the standard is any two exceedances in a calendar year. For calendar year 2012, no exceedances of the CO 1-hour or 8-hour standards were recorded at any MCAQD monitoring sites (see Table 9). 2012 Air Monitoring Network Review 19 Maricopa County Air Quality Department Table 7 2012 8-hour Average Carbon Monoxide Summary CO 8-hour Average Max. (PPM); Date: Hour 0.5; 01/01:06 CO 8-hour Average 2nd High (PPM); Date: Hour 0.5; 01/16:07 Number of Exceedances of 8-Hour average 0 C. Phoenix 2.7; 01/01:05 2.0; 01/06:01 0 Dysart 0.6; 11/18:01 0.6; 12/17:10 0 Glendale 1.3; 11/18:01 1.3; 12/23:00 0 Greenwood 3.2; 01/01:05 2.1; 01/13:08 0 Mesa 1.4; 12/06:01 1.3; 01/07:01 0 N. Phoenix 1.5; 12/30:02 1.1; 12/30:07 0 S. Phoenix 2.3; 01/01:07 1.6; 01/07:01 0 South Scottsdale 1.3; 01/06:01 1.3; 11/15:00 0 Tempe 1.6; 12/06:01 1.6; 12/08:02 0 West Chandler 1.4; 12/02:02 1.3; 11/01:01 0 W. Phoenix 3.9; 01/01:05 2.5; 01/06:02 0 Site Buckeye Note: this table is read as the bold number representing the data followed by the date and time, e.g. 0.7; 01/10:18 is read as: 0.7 PPM on January 10 in the 6 o’clock PM (18:00) hour. Additional information required by EPA is shown in Table 10. Table 8 CO Data Required by EPA CBSA 38060 Population & Census Year 3,942,169 (2012) 2012 Air Monitoring Network Review No. of Required Near-Road Monitors No. of Active NearRoad Monitors No. of Additional Monitors Needed 0 0 0 20 Maricopa County Air Quality Department Lead (Pb) Figure 3 2012 Lead Monitoring Sites Following the introduction of unleaded gasoline in the early 1990’s, ambient air concentrations of lead fell to such a low level that Maricopa County was given permission to discontinue monitoring for this pollutant. However, the lead NAAQS was drastically lowered by a new regulation in 2008, and this caused concern to begin monitoring for this pollutant again to ensure that the new standard is being met. In July of 2010 a new lead monitoring site was opened near the Deer Valley airport in north Phoenix. Deer Valley Airport, as one of the busiest general aviation airports in the region, is assumed to be the largest point source of lead within Maricopa County. The new lead NAAQS has identical primary and secondary standards, a rolling three-month average. The rolling three month average is violated by an exceedance of 0.15 µg/m3. Table 9 2012 Lead Summary Site 24-hour Max. (µg/m3); Date: Hour 24-hour 2nd High (µg/m3); Date: Hour Max. Quarterly Average (µg/m3) Number of Samples Deer Valley 0.057; 12/05:00 0.053; 01/10:00 .0398; 4th Qtr 49 Note: this table is read as the bold number representing the data followed by the date and time, e.g. 0.024; 06/30:05 is read as: 0.024 PPM on June 30 in the 5 o’clock AM (05:00) hour. 2012 Air Monitoring Network Review 21 Maricopa County Air Quality Department Additional information required by EPA is shown in Table 12. Table 10 Lead Data Required by EPA Source Name Address Pb Emissions (tons/yr) Deer Valley Airport Phoenix, AZ 1.1 2012 Air Monitoring Network Review Emission Inventory Source & Data Year General Aviation Airport 2008 22 Max 3-month Design Value (µg/m3) Design Value Date (third month, year) No. of Required Monitors No. of Active Monitors No. of Additional Monitors Needed 0.0398 Dec 2012 1 1 0 Maricopa County Air Quality Department Nitrogen Dioxide (NO2) Figure 4 2012 Nitrogen Dioxide Monitoring Sites All parts of Maricopa County are in attainment for nitrogen dioxide. During 2012, four NO2 monitors were operational and were reported in AQS (Figure 4). All NO2 monitors are designated as SLAMS (see Table 5). Compliance with the NO2 standard is achieved when the annual arithmetic mean concentration in a calendar year is less than or equal to 53 ppb. A new hourly standard for NO2 began in 2010; this regulation states that the 3-year average of the 98th percentile cannot exceed 100 ppb. For calendar year 2012, no exceedances of the NO2 annual or 1-hour standard were recorded at Maricopa County monitoring sites. Table 11 2012 Nitrogen Dioxide Summary Buckeye NO2 Avg. 1-hour Max. (PPB); 47.0 NO2. 1-hour 98th Percentile (PPB) 39.0 Central Phoenix Greenwood West Phoenix 75.0 87.0 77.0 63.0 65.0 58.0 Site 3-Year Avg. of 98th Percentile (PPB) 37.3 60.7 66.0 56.0 # of 1-hour Samples 8643 Annual Average (PPB) 9.4 8493 8538 8639 21.2 26.0 19.4 Additional information required by EPA is shown in Table 14. 2012 Air Monitoring Network Review 23 Maricopa County Air Quality Department Table 12 NO2 Data Required by EPA CBSA 38060 Population Max & Census AADT Year Counts (year) 3,942,169 (2012) 320,137 No. Required Near Road Monitors No. of Active NearRoad Monitors No of Additional NearRoad Monitors Needed No. of Required AreaWide Monitors No. of Active AreaWide Monitors No of Additional AreaWide Monitors Needed 2 0 0 0 4 0 Ozone (O3) Figure 5 2012 Ozone Monitoring Sites During 2012, seventeen ozone monitors were reported as operational in AQS (Figure 5). All of the ozone monitors are classified as SLAMS (Table 5). The 1-hour average ozone standard was revoked by the EPA on June 15, 2005, and has been replaced by the 8-hour average standard for compliance purposes. On March 12, 2008, the EPA lowered the eight-hour ozone NAAQS from 0.080 to 0.075 ppm. Compliance with the standard is determined by averaging the 4th highest eight-hour average over a three-year period. This three-year average must be less than or equal to 0.075 ppm. There were 90 exceedances of the eight hour primary standard for ozone in 2012. Table 15 presents the 2012 data summary for eight-hour ozone at department monitoring sites. Also in 2012, there were 2012 Air Monitoring Network Review 24 Maricopa County Air Quality Department eight violations of the eight-hour primary standard (the 8-hour average NAAQS for ozone is violated when the three-year average of the fourth high is greater than 0.075 ppm (see Table 16). Table 13 2012 8-hour Average Ozone Summary 8-hour max. (PPM); Date: Hour 2nd High (PPM); Date: Hour 3rd High (PPM); Date: Hour 4th High (PPM); Date: Hour Blue Point .079; 05/29:11 .079; 08/08:12 .078; 05/31:11 .077; 05/10:11 Buckeye .078; 05/14:11 .070; 05/12:11 .069; 05/20:10 .068; 05/09:11 1 Cave Creek .081; 08/09:12 .080; 05/14:16 .078; 05/20:11 .078; 05/21:10 10 Central Phoenix .084; 05/14:12 .082; 08/09:11 .081; 07/12:12 .077; 05/20:11 6 Dysart .079; 05/14:11 .078; 08/09:11 .074; 08/13:10 .073; 08/10:11 2 Falcon Field .075; 08/09:12 .071; 08/07:11 .069; 05/20:10 .069; 05/21:09 0 Fountain Hills .083; 05/14:13 .081; 05/31:12 .079; 05/21:09 .077; 05/20:11 5 Glendale .088; 05/14:12 .084; 07/12:11 .079; 07/10:10 .078; 08/06:10 4 Humboldt Mt. .082; 05/14:18 .082; 05/28:16 .080; 08/10:18 .079; 05/20:15 11 North Phoenix .091; 05/14:12 .089; 08/09:11 .087; 07/12:11 .083; 07/10:10 17 Pinnacle Peak .082; 07/12:12 .082; 08/09:12 .080; 08/10:11 .079; 08/08:10 6 Rio Verde .076; 08/08:12 .076; 08/09:13 .075; 05/29:11 .072; 05/10:12 2 South Phoenix .087; 05/14:12 .081; 07/12:11 .078; 05/20:10 .078; 08/09:10 5 South Scottsdale .086; 07/12:12 .083; 08/09:11 .081; 05/14:12 .080; 05/20:11 7 Tempe .078; 07/12:12 .075; 05/20:10 .073; 05/14:10 .073; 08/09:10 1 West Chandler .082; 07/12:11 .079; 05/14:11 .075; 08/09:09 .074; 05/12:11 2 West Phoenix .087; 05/14:11 .087; 07/12:11 .084; 08/09:11 .083; 08/06:10 9 Site Number of Days > 0.075 11 Note: This table is read as the bold number representing the data followed by the date and time, e.g. 0.073; 4/30:12 is read as: 0.073 PPM on April 30 in the 12 o’clock PM (12:00) hour. 2012 Air Monitoring Network Review 25 Maricopa County Air Quality Department Table 14 3 Year Average of 8-Hour Ozone Site 2010 4th High (PPM) 2011 4th High (PPM) 2012 4th High (PPM) .081 .077 .068 Blue Point Buckeye 3 Yr. Avg. of 4th High (PPM)* 0.075 .064 .067 .068 0.066 Cave Creek .074 .081 .078 0.077 Central Phoenix .072 .073 .077 0.074 Dysart .071 .070 .073 0.071 Falcon Field .070 .069 .069 0.069 Fountain Hills .074 .077 .077 0.076 Glendale .074 .076 .078 0.076 Humboldt Mt. .070 .077 .079 0.075 North Phoenix .079 .081 .083 0.081 Pinnacle Peak .077 .077 .079 0.077 Rio Verde .071 .081 .072 0.074 South Phoenix .074 .076 .078 0.076 South Scottsdale .076 .075 .080 0.077 Tempe .068 .070 .073 0.070 West Chandler .074 .074 .074 0.074 West Phoenix .075 .078 .083 0.078  Indicates violation of the standard. Additional information required by EPA is shown in Table 17. Table 15 Ozone Data Required by EPA CBSA County 38060 Maricopa Population & Census Year 3,942,169 (2012) 2012 Air Monitoring Network Review 8-Hr Design Value (ppm) Design Value Site North Phoenix 0.081 26 No. Required Monitors No. Active Monitors No. of Additional Monitors Needed 2 17 0 Maricopa County Air Quality Department Particulate Matter <=10 Microns (PM10) Figure 6 2012 PM10 Monitoring Sites (includes continuous and non-continuous sites) During 2012, sixteen PM10 monitors were reported as operational in AQS (Figure 6). All PM10 monitors are classified as SLAMS; except for Zuni Hills which is classified as a Special Purpose (SP) monitor (Table 5). Note that fourteen of these PM10 sites operate continuous monitors which collect hourly-averaged data; the other two are non-continuous filter-based monitors which collect 24-hour averaged data on a 1-in-6 day schedule. The 24-hour Primary standard for PM10 is 150 µg/m3 (155 µg/m3 with mathematical rounding). This standard is violated when the expected number of exceedances for the calendar year is more than one. A formula, as detailed in 40 CFR 50, is used to determine the expected number of exceedances. The formula takes into account the number of days sampling occurred and the number of valid samples collected. A 3-year average of these estimated days is then used to determine compliance. On December 18, 2006 new monitoring rules from the EPA revoked the PM10 annual primary standard, although the annual average is still displayed below for informational purposes (See Table 18). 2012 Air Monitoring Network Review 27 Maricopa County Air Quality Department Table 16 2012 PM10 Summary Site Name Buckeye 24-hr 24-hr Number of Average Average Annual 24-hour Max 2nd High NAAQS Expected Average #Exceptional (µg/m3) (µg/m3) Exceedances Exceedances (µg/m3) Events Number of Samples 205* 202* 2 2.022 47.4 4 8692 Central Phoenix 340* 137 1 1 37.9 1 8649 Durango Complex 221* 217* 4 4 49.1 4 8677 Dysart (continuous) Glendale (continuous) Greenwood 167* 337* 127 136 1 1 1 1 30.0 34.1 1 1 8694 8715 323* 212* 2 2 45.3 2 8664 Higley (continuous) Mesa North Phoenix 224* 64 194* 57 4 0 4 0 38.0 22.8 4 0 8713 55 178* 140 1 1 32.4 1 8624 South Phoenix 342* 285* 3 3.095 47.9 2 8564 South Scottsdale Tempe (continuous) West Chandler 102 169* 91 145 0 1 0 1 31.6 34.7 0 2 159 7285 402* 221* 5 5.067 36.1 5 8668 West 43 Ave 254* 220* 6 6.055 50.5 7 8681 West Phoenix 189* 148* 1 1.011 46.9 1 8696 Zuni Hills 285* 147 1 1 49.1 1 8700 (continuous) (continuous) (continuous) (continuous) (continuous) (continuous) (continuous) rd (continuous) (continuous) (continuous) *Indicates an exceedance of the standard. Note that some data have the potential for being classified as exceptional events (see Definition of Terms for explanation of exceptional events). In accordance with the EPA’s exceptional events policy, once approved these data are not used in determining compliance with the NAAQS. Values in Table 18 are from official AQS reports as of the date of publishing this review; exceptional events that have not yet been approved by the EPA will not affect these values until they are approved. The process of approving exceptional events can take over a year after the exceedance day, so some values in Table 18 could change upon EPA approval of an exceptional event petition. On July 2, 2002 (67 FR 44369), EPA found the state implementation plan (SIP) for the Metropolitan Phoenix (Maricopa County), Arizona serious PM10 non-attainment area to be inadequate to attain the 24-hour particulate (PM10) air quality standard at the Salt River monitoring site. Under authority from the Clean Air Act, EPA has required a SIP revision to be submitted by the State of Arizona to correct the inadequacy. In 2004 the Arizona Department of Environmental Quality submitted a SIP addressing the inadequacies in the Salt River Area to the EPA. As of December 31, 2012, Maricopa County has not come into compliance with the NAAQS for PM10. As a result of this, the EPA is requiring a 5% plan which began in 2008. This required Maricopa County to submit an approved plan to reduce the annual PM10 emissions of Maricopa County by 5% until the standard is met. Failure to 2012 Air Monitoring Network Review 28 Maricopa County Air Quality Department comply with this plan or to meet the NAAQS for PM10 will result in further 5% reductions annually, and could result in sanctions from the EPA. Additional information required by EPA is shown in Table 19. Table 17 PM10 Data Required by EPA CBSA County 38060 Maricopa Population & Census Year 3,942,169 (2012) 2012 Air Monitoring Network Review Max Conc. Max Conc. Site West Chandler 669 29 No. Required Monitors No. Active Monitors No. of Additional Monitors Needed 6-10 16 0 Maricopa County Air Quality Department Particulate Matter <=2.5 Microns (PM2.5) Figure 7 2012 PM2.5 Monitoring Sites (continuous and non-continuous) Currently MCAQD operates collocated filter-based compliance PM2.5 monitors at the West Phoenix site and single filter-based monitors at the Mesa and South Phoenix site (Figure 7). These compliance PM2.5 monitors all use sample filters and are non-continuous in nature. On July 1, 2007, the department took over weighing the sample filters, a process that was previously done by the ADEQ. All filters are processed and weighed in our internal laboratory. In addition to the filter-based monitors, the department operates seven continuous PM2.5 monitors at the Durango, Glendale, Mesa, North Phoenix, South Phoenix, Tempe and West Phoenix sites. These continuous monitors have recently been reclassified as Federal Equivalency Methods (FEM), so their data are applicable to comparison with the national standards. All monitors are identified as SLAMS (Table 5). Note that the PM2 5 network is much smaller than the PM10 network. The reason for this is that historically more concern and resources have been given to PM10, since Maricopa County is not in attainment for this pollutant (Maricopa County is currently in attainment for PM2 5). According to federal regulations, Maricopa County does operate more than the required minimum number of PM2 5 monitors for the MSA (see Table 24 and Appendix II). The Air Monitoring Division continually assesses if the existing network adequately represents the air quality (PM2 5) in Maricopa County. One result from these ongoing assessments has been the addition of the continuous PM2 5 monitors. On December 18, 2006, the EPA implemented new primary standards for PM2.5. These new rules changed the 24-hour average standard from 65 µg/m3 to 35 µg/m3. The annual average standard of 15 µg/m3 remains unchanged. Compliance with the 24-hour standard is determined by taking the 3-year average of the 98th percentile at each monitoring site. Compliance with the Annual standard is 2012 Air Monitoring Network Review 30 Maricopa County Air Quality Department determined by taking the 3-year average of the spatially averaged annual means. There were no violations of the 24-hour standard or the annual standard. Data is summarized in Table 20 and Table 21. Averages used for determining compliance with the NAAQS are shown in Table 22 and Table 23. Table 18 2012 PM2.5 Summary (FRM Filter-based Monitors) 24-hr Avg. 24-hr Avg. Max 2nd High 3 (µg/m ) (µg/m3) 23.3 11.5 Site Name Mesa 98th Percentile Value 23.3 Annual Avg. Number of (µg/m3) Samples 8.51# 9# South Phoenix 70.0* 24.4 24.4 11.5# 58# West Phoenix 112.6* 35.5* 29.0 12.0 120 *Indicates an exceedance of the standard. #Does not meet data completeness standards for year. Table 19 2012 PM2.5 Data Summary (FEM Continuous Monitors) 24-hr Avg. 24-hr Avg. Max 2nd High (µg/m3) (µg/m3) Site Name North Phoenix 98th Percentile Annual Avg. Number of Value (µg/m3) Samples 30.1 29.9 21.2 9.26 8616 Glendale 66.1* 42.7* 18.6 8.74 8688 Durango Complex 74.4* 36.7* 24.9 11.6 8688 South Phoenix 70.8* 46.8* 20.9 9.24 8472 West Phoenix 89.1* 37.0* 23.6 10.4# 5808 Tempe 23.1 22.4 19.5 9.27 7128 Mesa 16.0 10.4 10.4 5.84# 1464 (continuous) (continuous) (continuous) (continuous) (continuous) (continuous) (continuous) *Indicates an exceedance of the standard. #The continuous FEM PM2.5 monitors represents a part year monitor and do not constitute a 75% data completeness rate for 2012 annual averages. Table 20 2012 PM2.5 3-Year Averages of 98th Percentile (FRM Monitors) Site Name Mesa South Phoenix West Phoenix 2010 98th Percentile Value 11.8 24.0 21.6 2011 98th Percentile Value 20.4 31.5 28.9 #Does not meet data completeness standards for year. 2012 Air Monitoring Network Review 31 2012 98th Percentile Value 23.3# 24.4# 29.0 98th Percentile 3-Year Average 18.5 26.6 26.5 Maricopa County Air Quality Department Table 21 2012 PM2.5 3-Year Averages of 98th Percentile (FEM Monitors) Site Name North Phoenix Glendale Durango Complex South Phoenix West Phoenix Tempe Mesa 2010 98th Percentile Value N.A. N.A. 24.3 24.4 22.0 N.A. N.A. 2011 98th Percentile Value 23.0 27.8 31.2 27.2 31.5 N.A. N.A. 2012 98th Percentile Value 21.2 18.6 24.9 20.9 23.6 19.5 10.4 98th Percentile 3-Year Average 22.1 23.2 26.8 24.2 25.7 19.5 10.4 Additional information required by EPA is shown in Table 24. Table 22 PM2.5 SLAMS Data Required by EPA CBSA County 38060 Maricopa Population & Census Year 3,942,169 (2012) Annual Design Value (µg/m3) 10.7 2012 Air Monitoring Network Review Annual Design Value Site West Phoenix Daily Design Value (µg/m3) 26.6 32 Daily Design Value Site South Phoenix No. of Required Monitors No. of Active Monitors No. of Additional Monitors Needed 3 7 0 Maricopa County Air Quality Department Sulfur Dioxide (SO2) Figure 8 2012 Sulfur Dioxide Monitoring Sites Maricopa County is in attainment for SO2. During 2012, two SO2 monitors were operational and were reported in AQS (Figure 8). Both of these monitors were designated SLAMS (see Table 5). Sulfur Dioxide has a 1-hour primary standard and a 3-hour average secondary standard. The 24-hour and annual average standards were revoked in a June 2010 rulemaking. A violation of the primary standard occurs when the 3-year average of the 99th percentile of the daily maximum 1-hour average exceeds 75 ppb. A violation of the 3-hour average secondary standard occurs when a 3-hour average of 500 ppb is exceeded more than once per year. For calendar year 2012, no exceedances of the SO2 1-hour or 3-hour standard were recorded at Maricopa County monitoring sites (see Table 25 for 1-hour values – note that EPA no longer reports 3-hour values). Table 23 2012 Sulfur Dioxide Summary 1-hour Max. (PPB) Site 1-hour 2nd High (PPB) 99th Percentile (PPB) Number of Samples Central Phoenix 9.0 9.0 8.0 8573 Durango Complex 18.0 11.0 9.0 8614 2012 Air Monitoring Network Review 34 Maricopa County Air Quality Department Additional information required by EPA is shown in Table 26. Table 24 SO2 Data Required by EPA CBSA County 38060 Maricopa Population & Census Year 3,942,169 (2012) 2012 Air Monitoring Network Review Total SO2 (tons/year) Population Weighted Emission Index (million persons-tons per year) No. of Required Monitors No. of Active Monitors No. of Additional Monitors Needed 977 3851 0 2 0 35 Maricopa County Air Quality Department 2012 NAAQS Exceedance and Violation Summary The following is a summary of the number, types and dates of exceedances and violations of the NAAQS for 2012 (Table 27). Table 25 2012 NAAQS Exceedances and Violation Summary Carbon Monoxide No exceedances or violations of the 1-hr or 8-hr NAAQS standard were logged. Nitrogen Dioxide No exceedances or violations of NAAQS were logged. Ozone There were 28 unique days when at least one monitor exceeded the standard. There were 90 individual exceedances of the 8-hour standard which occurred at 16 different sites. There were eight violation of the 8-hour standard. PM10 There were 13 unique days when at least one monitor exceeded the standard and 13 sites violated the 24-hour standard. PM2.5 There were 4 unique days when at least 1 FRM or FEM monitor exceeded the standard.. There were no violations of the 24-hour or annual standards. Sulfur Dioxide No exceedances or violations of NAAQS were logged. 2012 Ozone Exceedance and Violation Details Table 28 details the dates and values for exceedances of the 8-hour ozone standard. The standard is 0.075 ppm for an eight hour average. Table 29 details violations of the 8-hour ozone standard. Violations are calculated with a three-year average of the fourth-highest annual 8-hour value, if this three-year average is greater than 0.075 ppm the site violates the standard. Table 26 2012 Ozone 8-hour Average Exceedance Details Site Buckeye Blue Point Date 5/14/12 2/29/12 8/08/12 5.31/12 5/10/12 5/22/12 7/12/12 8/09/12 5/13/12 5/14/12 5/20/12 Cave Creek 2012 Air Monitoring Network Review 8/09/12 36 Value (ppm) 0.078 0.079 0.079 0.078 0.077 0.077 0.077 0.077 0.076 0.076 0.076 0.081 Maricopa County Air Quality Department 5/14/12 5/20/12 5/21/12 5/28/12 5/13/12 5/31/12 6/02/12 7/12/12 8/10/12 5/14/12 8/09/12 7/12/12 5/20/12 8/04/12 7/11/12 5/14/12 8/09/12 5/14/12 5/31/12 5/21/12 5/20/12 5/29/12 5/14/12 7/12/12 7/10/12 8/06/12 5/14/12 5/28/12 8/10/12 5/20/12 4/17/12 5/22/12 6/01/12 6/02/12 8/09/12 5/21/12 5/14/12 8/09/12 7/12/12 7/10/12 5/20/12 8/06/12 8/14/12 8/04/12 8/10/12 5/13/12 Central Phoenix Dysart Fountain Hills Glendale Humbolt Mountain North Phoenix 2012 Air Monitoring Network Review 37 0.080 0.078 0.078 0.077 0.076 0.076 0.076 0.076 0.076 0.084 0.082 0.081 0.077 0.077 0.076 0.079 0.078 0.083 0.081 0.079 0.077 0.076 0.088 0.084 0.079 0.078 0.082 0.082 0.080 0.079 0.078 0.078 0.078 0.078 0.077 0.076 0.091 0.089 0.087 0.083 0.082 0.081 0.081 0.080 0.080 0.077 Maricopa County Air Quality Department Table 28 2012 Ozone 8-hour Average Exceedance Details (Cont’d) Site Pinnacle Peak Date 7/12/12 8/09/12 8/10/12 8/08/12 8/07/12 8/20/12 8/08/12 8/09/12 5/14/12 7/12/12 5/20/12 8/09/12 7/11/12 7/12/12 8/09/12 5/14/12 5/20/12 8/04/12 8/06/12 8/10/12 7/12/12 7/12/12 5/14/12 5/14/12 7/12/12 8/09/12 8/06/12 7/11/12 7/10/12 8/10/12 5/20/12 8/27/12 Rio Verde South Phoenix South Scottsdale Tempe West Chandler West Phoenix 2012 Air Monitoring Network Review 38 Value (ppm) 0.082 0.082 0.080 0.079 0.077 0.076 0.076 0.076 0.087 0.081 0.078 0.078 0.076 0.086 0.083 0.081 0.080 0.078 0.078 0.077 0.078 0.082 0.079 0.087 0.087 0.084 0.083 0.080 0.078 0.078 0.076 0.076 Maricopa County Air Quality Department Table 27 2012 Ozone Violations Site Cave Creek Fountain Hills Glendale North Phoenix Pinnacle Peak South Phoenix South Scottsdale West Phoenix Value (ppm) 0.077 0.076 0.076 0.081 0.077 0.076 0.077 0.078 2012 Exceedances of the 24-Hour PM10 Standard Table 30 details the site and date of exceedances of the 24-hour PM10 standard. Note that this table includes all exceedances, even those that will be or are in the process of being classified as exceptional events. Exceptional events are not used in calculating compliance with the NAAQS. Table 28 2012 PM10 24-hour Average Exceedance Details Site Buckeye Date 8/6/12 6/16/12 24-hr avg. PM-10 Concentration in µg/m3 205* 202* Central Phoenix 6/27/12 340* Durango 6/27/12 7/11/12 6/16/12 8/14/12 221* 217* 186* 179* Dysart 6/16/12 167* Glendale 6/27/12 337* Greenwood 6/27/12 7/11/12 323* 212* Higley 6/27/12 6/16/12 1/22/12 8/11/12 224* 194* 162* 159* North Phoenix 6/27/12 178* *MCAQD has applied for exceptional events status. 2012 Air Monitoring Network Review 39 Maricopa County Air Quality Department Table 30 2012 PM10 24-hour Average Exceedance Details (Cont’d) Site South Phoenix Date 6/27/12 7/11/12 6/16/12 24-hr avg. PM-10 Concentration in µg/m3 342* 285* 165* Tempe West Chandler 6/16/12 4/3/13 6/27/12 8/11/12 4/4/12 9/6/12 169* 402* 221* 219* 196* 164* West 43rd 8/14/12 6/27/12 6/16/12 1/21/12 6/18/12 7/11/12 254* 220* 211* 209* 174* 172* West Phoenix Zuni Hills 6/16/12 6/27/12 189* 285* *MCAQD has applied for exceptional events status. 2012 Air Monitoring Network Review 40 Maricopa County Air Quality Department 2012 Violations of the 24-H ou r PM1 o Standard The 24-hr NAAQS for paiiiculates is violated when the rate of expected occuITence of exceedances (samples greater than or equal to 155 µg/m 3) is greater than one over three consecutive years (Table 31) (40 CFR Pait 50.6 (a)). Table 29 Violations of the 24-hour PM 10 Standard 2010 2011 24-hr Max. Site Buckeye Expected /m3 Exceedances 113 0 24-hr Max. 2012 385+ Expected Exceedances 9 /m 3 24-hr Max. /m3 205+ Rate of Expected Expected Exceedances Exceedances 2.022 106 0 308+ 8.022 340; 1 111 0 436; 8 221+ 4 81 0 273; 5 167; 1 92 0 242; 5.095 337; 1 158 1.045 388; 7 323; 2 Higley 83 0 362; 8 224+ 4 Mesa 86 0 127 0 64# 0 No1t h Phoenix 44 0 186+ 3.629 178+ 1 South Phoenix 120 0 420; 9.023 342; 3.095 37 0 119 0 102 0 N.A. N.A. N.A. 169 1 76 0 669; 11 402; 5.067 112 0 369; 7.066 254; 6.055 86 0 279; 7.457 189; 1.011 70 0 411; 4 285; 1 Central Phoenix Dmango Com lex Dysa1t Glendale Greenwood South Scottsdale Tempe West Chandler West 43rd Avenue West Phoenix Zuni Hills N.A. • Indicates violation of the standard. #Indicates <75% data available. t Indicates Exceptional Events occtlffed at this site. The listed value is the highest official AQS reading at time of publication. Excep tion al Events Table 31 lists the official records in AQS (at time of publication) for exceedances and violations. Some of these 2010-201 2 exceedance days were petitioned to be classified as exceptional events and a request made to the EPA to remove them from official consideration as compliance data. EPA approval of these requests can talce over a year. 2012 Air Monitoring Network Review 41 Maricopa County Air Quality Department 2012 Exceedances of the 24-Hour PM2.5 Standard The 24-hour NAAQS for PM2.5 is 35 µg/m3; if the 24-hour block average (midnight-to-midnight) surpasses this value than it is counted as an exceedance. The 24-hour standard is violated when the three year average of the 98th percentile exceeds 35 µg/m3. There were no violations in 2012. Table 30 2012 PM2.5 Exceedances Site Durango Glendale South Phoenix West Phoenix Date 01/01 12/05 01/01 06/27 01/01 12/24 01/01 06/27 2012 Air Monitoring Network Review Value (ppm) 74.4 36.7 66.1 42.7 70.8 46.8 89.1 37.0 42 Method Continuous FEM Continuous FEM Continuous FEM Continuous FEM Continuous FEM Continuous FEM Continuous FEM Continuous FEM Maricopa County Air Quality Department Pollution Trends The following cha11s depict the most recent three-year trends (2009-2011) for each criteria pollutant. See Table 4 for explanations of site abbreviations. Carbon Monoxide 10 -.------------------~ 9 +-:~~-*"""--;----~It-"""*-----,.---~~~ 8 -+--- - - - - - - - - - - - - - - - -----! 7 -+--- - - - - - - - - - - - - - - - -----! 6 -+--- - - - - - - - - - - - - - - - -----! 5 -+--- - - - - - - - - - - - - - - - -----! 4 -+--- - - - - - - - - - - - - - - - - - ! 3 2 +-- - I 1 - - -- - -r1t---=-----r - - - - ; 1 - - ---+-- - BECP i=J 2011 i=J 2012 --*"""" Standard < 9.0 DY GL GR ME NP SP SS TE WC WP Chart 12010-20128-hr Avg. Carbon Monoxide Maximum Values Nitrogen Dioxide 60 0 50 0 40 0 al c.. c.. 30 0 = 201 0 - 2011 c:::::::::J 2012 - - Standard 53 ppb 20 0 10 0 0.0 BE CP GR WP Chart 2 2010-2012 Nitr ogen Dioxide Annual Average Readings 2012 Air Monitoring Networ k Review 43 Maricopa County Air Quality Dep artment Ozone 0.09 0.08 PPM 0.07 0.06 2010 0.05 2011 0.04 2012 0.03 Standard <0.075 0.02 0.01 0 BP BE CC CP DY FF FH GL HM NP PP RV SP SS TE WC WP Chart 3 2010-2012 Ozone 4th High 8-hr Average Particulates 800 700 600 2010 ug/m3 500 2011 400 2012 300 Standard <155 200 100 0 BE CP DC DY GL GR HI ME NP SP SS TE WC WF WP ZH Chart 4 2010-2012 PM10 24-hr Average Maximum Values 2012 Air Monitoring Network Review 44 Maricopa County Air Quality Department 60.0 50.0 ug/m3 40.0 2010 2011 30.0 2012 20.0 10.0 0.0 BE CP DC DY GL GR HI ME NP SP SS TE WC WF WP ZH Chart 5 2010-2012 PM10 Annual Average 16 14 12 2010 ug/m3 10 2011 8 2012 6 Standard <15 4 2 0 DC GL ME NP SP TE WP Chart 6 2010-2012 PM2.5 Annual Average 2012 Air Monitoring Network Review 45 Maricopa County Air Quality Department 40 35 - 30 - ,__ 25 - M E c;, 20 - - - - 2010 c::::::J 2011 c::::::J 20 12 :s 15 ~ Standard <35 ppm 10 5 0 DC Gl ME NP SP -- TE WP Chart 7 2010-2012 PM2 .5 98th Percentile Sulfur Dioxide 35 30 --- ' c:::::::::J 2010 25 20 c:::::::::J 2012 al 3: 15 10 - Previous Standard 30 PPB 5 0 1.7 1.2 1.2 1.5 1.1 I I DC CP Chart 8 2010-2012 Sulfur Dioxide Annual Average 2012 Air Monitoring Network R eview 46 Maricopa C ounty Air Quality Dep ar tment SPECIAL PROJECTS AND NETWORK CHANGES Air quality issues such as the SIP, natural events policy, and permits for new sources are diverse and controversial subjects for the citizens of Maricopa County. Since no policies can be made without high-quality monitoring data, MCAQD’s Air Monitoring Division strives to provide the most reliable and relevant air monitoring data to the public. The following is a list of projects and changes that have occurred during the year 2012. Seasonal Monitors The department continues to run some of its carbon monoxide (CO) monitors on a seasonal basis (see Table 33). Having part of the network operating seasonally allows the county to upgrade instruments, perform preventive maintenance, extend the life expectancy of the instruments, reduce replacement costs, and better utilize its QA and QC resources on the remaining instruments. During the off-season the number of CO monitors operating still exceeds the minimum EPA requirements. Table 31 Seasonal Monitors Seasonal Carbon Monoxide Monitors (Operational Sept. 1 – Apr. 1) Buckeye Dysart Glendale Mesa North Phoenix South Phoenix South Scottsdale Tempe West Chandler The Consideration of Additional Sites/Monitors The department continues to evaluate the PM10 network for possible additional sites for determining the impact on ambient pollution levels of significant sources or source categories. The significant sources would include industry and agriculture. The allocation of both financial and personnel resources continue to remain significant obstacles to the establishment of new monitoring sites. Lead Monitoring In conjunction with the recent strengthening of the lead NAAQS, EPA is improving the existing national lead monitoring network by requiring monitors to be placed in areas with sources such as industrial facilities that emit one ton or more per year (tpy) of lead and in urban areas with more than 500,000 people. In 1997, the EPA allowed MCAQD to stop monitoring for airborne lead because the data showed values were far below the standard. With the new more stringent standard, the department once again began monitoring for airborne lead. MCAQD located a new lead monitoring site at the Deer Valley airport in North Phoenix, which was chosen because federal emissions inventories have indicated that the Deer Valley Airport emits more than one tpy of lead. This is due to the lead contained in the general aviation fuel (Deer Valley is a general aviation airport). The site 2012 Air Monitoring Network Review 47 Maricopa County Air Quality Department began operation in July 2010 and has two co-located filter-based lead monitors which operate on a 1in-6 day schedule. Other Network Changes/Special Projects/Comments Air Quality Forecasting ADEQ, in conjunction with the MCAQD, has developed a year-round air quality forecasting capability for the Phoenix metropolitan area. ADEQ takes the lead on air quality forecasting and issuing of High Pollution Advisories, while the MCAQD provides monitoring data and designates No-Burn Days. Air Monitoring Website The department is continuing its distribution of air monitoring data to the public by posting one-hour and 5-minute continuous data on the Internet (see “Maricopa County Interactive Pollution Map” section below). Maricopa County Air Quality Dept: http://alert.fcd.maricopa.gov/alert/Google/v3/air.html Mobile Monitoring Program The department received approval in late 2006 from the Maricopa County Board of Supervisors to start a Mobile Monitoring program. This program enables the department to do more source-specific air monitoring (as opposed to the ambient monitoring that we have historically performed); the ability to track down sources of air pollutants; the ability to collect and analyze hazardous air-pollutant (HAP) samples; and the ability to respond to emergencies. The program is useful for collecting and analyzing scientific data for various projects, including assisting our compliance division in the enforcement of air pollution control regulations. The equipment for this program includes a vehicle outfitted with air monitoring and analytical equipment. Monitoring and sampling equipment consists of various meteorological, criteria pollutant, and HAP monitors. Analytical equipment includes a portable Gas-Chromatograph/Mass Spectrometer (GCMS) and geographical positioning systems. Air monitoring equipment has also been placed in a mobile trailer that can be quickly moved to areas to operate independently. We also have the ability to use geographical information systems to build geo-referenced models of sampled pollutants. In 2012, MCAQD’s Air Monitoring Division is equipped to respond to air quality emergencies throughout Maricopa County such as heavy smoke from fires or toxic releases that threaten air quality. All MCAQD Monitoring personnel are required to meet OSHA medical monitoring and U.S. EPA’s 40 CFR 1910.120 training. Members remain current through regular recertification. Near-Road NO2 Monitoring In February of 2010, EPA promulgated new minimum monitoring requirements for the nitrogen dioxide (NO2) monitoring network in support of a newly revised 1-hour NO2 NAAQS. In the new monitoring requirements, state and local air monitoring agencies are required to install near-road NO2 monitoring stations in larger urban areas where hourly NO2 concentrations in the near-road environment are believed to be the highest in that urban area. 2012 Air Monitoring Network Review 48 Maricopa County Air Quality Department The regulations require Core Based Statistical Areas (CBSAs) with 2,500,000 or more persons, or those CBSAs with one or more roadway segments carrying traffic volumes of 250,000 or more vehicles (as measured by annual average daily traffic [AADT] counts), shall have two near-road NO2 monitors within that CBSA. Based on the regulation, Maricopa County is required to have two nearroad NO2 monitors. MCAQD has applied for and received EPA grant money to install the first of two near-road monitors. Important parameters for traffic activity that can be readily obtained for near-road monitoring assessments include the number of vehicles, the fleet mix, vehicle speeds (traffic congestion), local terrain and topography, and meteorology. Each of these parameters has an effect on the concentration and characteristics of the near-road pollutants. State and local ambient air monitoring agencies are required (per 40 CFR Part 58 Appendix D, Section 4.3.2.a) to use the latest available census figures (e.g., census counts and/or estimates) and available traffic data in assessing what monitoring may be required. We have completed the process of determining specific locations following procedures found in the EPA Technical Assistance Document. The two selected sites have been submitted to EPA for approval. Site #1 Following an analytical review, our first choice for a new site was chosen in Tempe. Not only was this site first in fleet equivalency rank, but it passed all of our tests. Specifically, the reasons for choosing this location are: • #1 in fleet-equivalency rank (a comparative rating including both light and heavy-duty vehicles), #1 in average weekday traffic rank (AWT), and #3 in heavy duty vehicle traffic. Traffic congestion is extreme. • This candidate had desirable supporting features such as freeway orientation and surrounding grade. Though most of the adjacent area is commercial property, there are considerable residential parcels nearby. • There are locations alongside this road segment with access, safety, security, and power available. The Arizona Department of Transportation (ADOT), which owns these frontage spaces, is willing to work with us in establishing a monitoring site. • Though major road construction is planned on this freeway in 2019 (freeway widening), we’ve discussed the issue with ADOT and believe that we’ll be able to move the monitoring site back far enough to accommodate it (during and after construction). In the event that such a move is not possible, we would have to prepare another assessment to relocate the monitoring site; there are other possibilities on the I-10 freeway, though the entire freeway is undergoing major road construction from the US60/I-10 split to the I-17/I10 split beginning in 2019. The specific location that we are considering is located on the west side of the I-10 freeway just south of the Fairmont/Diablo way intersection (Figure 9). The coordinates are 33.396250, -111.967967. There is a concrete barrier between the freeway and the frontage, offering safety. We will erect a secure shelter for housing the monitoring instruments, and power can be brought in. 2012 Air Monitoring Network Review 49 Maricopa County Air Quality Department Figure 9. Aerial photograph and street view of proposed monitoring Site #1. Site #2 For the second near-road site, it was decided to find a location farther away from the Site #1 so as to represent a different area. We also wanted to locate the monitor near a high-density population source. The next most desirable location is located in western Phoenix. This location was chosen for Site #2 for the following reasons: • #13 in fleet-equivalency rank, #17 in AWT traffic, and #12 in heavy-duty vehicle traffic. • Extreme traffic congestion.. • Many residential parcels nearby. • Features around the site, such as access and background NO2 sources, are favorable. • The frontage space is owned by ADOT, who will work with us to establish a site. The site does have drawbacks: it located in an east-west orientation, which is parallel to the average wind direction; the freeway is also approximately 20’ below grade; there is an overpass at 35th Avenue; and there are sound walls located along the freeway. However, we propose that the positive aspects outweigh the negative, and features alongside this road segment will allow us access while avoiding the sound walls. The location that we are considering is at 34th Avenue on the south side of the I-10 freeway, in a sound wall gap following the 35th Avenue on-ramp. The coordinates are 33.462103, -112.130393. It is proposed to place a secure monitoring shelter at the top of the grade; safety features consist of the setback from the on-ramp and the grade of the slope (note that concrete barricades could be put in place around the shelter). Availability of power has not yet been verified at this location, though it appears feasible. 2012 Air Monitoring Network Review 50 Maricopa County Air Quality Department If power is unavailable at this location, alternative sites are being considered on the south side of I-10 near 33rd Avenue or on the south side of I-10 near 28th Avenue. Figure 10. Aerial photograph and street view of proposed monitoring Site #2. Rapid Response Notification System Maricopa County enjoys many days with clean air. However, there are several days during the year when air pollution levels approach or exceed federal health standards. It is those days when action needs to be taken to avoid adding pollution to the air. In spite of the robust ambient air monitoring network maintained by MCAQD, a lot of pollution can build up in 60 minutes of time. If a pollution causing event were to go unaddressed, the air quality levels could greatly exceed a federal health standard causing immediate health impacts to county residents and threaten our attainment status with the U.S. EPA. The Rapid Response Notification System was developed to provide a three part value: real-time air monitoring data, a notification system to alert residents and stakeholders of a pollution problem, and onsite response from department inspectors and stakeholders to identify and discourage pollution activity to reduce the risk of pollution impacts. The Rapid Response Notification System serves as a tool for residents, intergovernmental stakeholders and staff of MCAQD. When a Rapid Response notification is broadcast, the department will require dust control permit holders to inspect their site as soon as possible and employ Best Available Control Measures to stabilize all disturbed soils to reduce blowing dust. Permittees with multiple sites should contact each site supervisor to ensure compliance with ambient air quality standards. Emergency Response Notification System MCAQD assists in monitoring the public exposure to air pollutants including information about the characteristics, ambient concentration and meteorological data to support decisions on pollutant dispersion, direction and protection of populated areas. 2012 Air Monitoring Network Review 51 Maricopa County Air Quality Department MCAQD’s Air Monitoring Division is equipped to respond to air quality emergencies throughout Maricopa County such as heavy smoke from fires or toxic releases that threaten air quality. All MCAQD Monitoring personnel are trained for hazardous materials and emergency response based on U.S. EPA and OSHA approved health and safety guidelines. Team members are required to meet OSHA medical monitoring and U.S. EPA’s 40 CFR 1910.120 training. Members remain current through regular recertification. In responding to emergencies, MCAQD has a wide variety of specialized equipment to assess air quality and meteorological conditions. These include a large self powered van equipped with a gas chromatograph/mass spectrometer (GS/MS), carbon monoxide, ozone, sulfur dioxide, nitrogen dioxide, hydrosulfide and particulate monitors. There is an onboard meteorological station with video cameras and a centralized data acquisition system (DAS) to collect, store, and distribute the data. It also has the ability to collect air samples (canisters) to bring back to the GC/MS for analysis. 2012 Air Monitoring Network Review 52 Maricopa County Air Quality Department ADDITIONAL COMMENTS Arizona Department of Environmental Quality Network The ADEQ operates its own monitoring network within the State of Arizona, including some sites within Maricopa County. In addition to these state-run sites, ADEQ also utilizes several MCAQD sites to operate their own monitoring equipment. The ADEQ does a variety of ambient pollution, air toxics, visibility, and meteorological monitoring. One of the main sites in Maricopa County that is operated by ADEQ is the JLG Supersite in central Phoenix. The Supersite is a National Core multipollutant monitoring station (NCore) and is part of the national monitoring network (MCAQD’s monitors, on the other hand, are part of the State and Local Air Monitoring network (SLAMS)). For more information about the state’s network or the NCore JLG Supersite consult the ADEQ’s Annual Network Plan on their website at: http://www.azdeq.gov/function/forms/reports.html. EPA Ozone Mapping The AIRNow website (http://wwww.airnow.gov/) provides real-time air pollution (ozone and PM2.5) maps for major metropolitan areas around the United States, including the Phoenix Metropolitan Area. MCAQD has participated in the program since 2001. MCAQD, in cooperation with ADEQ and the Pinal County Air Pollution Control District, has expanded the area that the maps cover. This area now includes sites as far east as Queen Creek, as far south as Casa Grande, and as far west as Palo Verde. This website can be used as a tool for which the public can plan their daily activities and limit their exposure to air pollution. Eight-hour average peak ozone concentration maps and real-time eighthour ozone animation maps are provided. Colors on the map indicate different concentrations of ozone pollution. The one-hour average values are given in parts per billion. The eight-hour averages are converted into Air Quality Index (AQI) numbers. The AQI is based on the NAAQS. The index was developed to convert pollution measurements into a common index that the general public can more easily understand. 2012 Air Monitoring Network Review Figure 10 EPA AIRNow Website 53 Maricopa County Air Quality Department Different colors on the map correspond to different categories of air quality and health impacts ((Table 34) Table 32 Air Quality Index 0 – 50 51 – 100 Color Air Quality Designation Green Good Yellow Moderate 101 – 150 Orange 151 – 200 Red Unhealthy for Sensitive Groups Unhealthy 201 – 300 301 – 500 Purple Maroon Very Unhealthy Hazardous Index Health Impact No harmful effects expected. Unusually sensitive people should consider limiting prolonged outdoor exertion. Active children & adults, people with respiratory disease (i.e., asthma) should limit prolonged outdoor exertion. Everyone should observe caution. Avoid prolonged outdoor exertion. Avoid all outdoor exertion. Use extreme caution outdoors Everyone should avoid all outdoor exertion. The animated map is updated every hour from 8am to 8pm seven days a week. Updates to the site will be made during the ozone season (April through October). 2012 Air Monitoring Network Review 54 Maricopa County Air Quality Department REFERENCES 1. Code of Federal Regulations, Chapter 40, Part 50 and 58, 1997 2. EPA’s AirData (AQS) information: http://www.epa.gov/air/data/index.html 3. EPA’s NAAQS Info: http://www.epa.gov/air/criteria.html 4. SIP Information: http://www.azdeq.gov/environ/air/plan/index.html 5. EPA’s Air Program Information: http://www.epa.gov/rgytgrnj/programs/artd/air/quality/quality.htm 6. Maricopa County Air Quality Department Air Monitoring Map: http://aqwww.maricopa.gov/AirMonitoring/SitePollutionMap.aspx 7. AIRNow: http://airnow.gov/ 8. Criteria Pollutant Information: http://www.epa.gov/air/urbanair/6poll.html 9. Maricopa County Air Quality Department Prior Network Reviews: http://www.maricopa.gov/aq/divisions/monitoring/network.aspx. 2012 Air Monitoring Network Review 55 Maricopa County Air Quality Department APPENDIX I - MONITORING SITE DETAILS (PHOTOS AND SPECIFIC INFORMATION) Blue Point (BP) (04-013-9702) Location: Bush Highway and Usery Pass Rd., Maricopa County Spatial Scale: Urban Monitoring Objective: Maximum Ozone Concentration Site Description: The Blue Point site became operational in July 1995 and is located in a Maricopa County Sheriff’s Sub-Station in Tonto National Forest. This site represents the maximum ozone concentration, and urban-scale downwind transport conditions. This site is located approximately 40 miles east of the Phoenix metropolitan area. Ozone is the only criteria pollutant monitored at this SLAMS station. Wind speed and direction are also monitored at the site. Ozone 2010 0.076* 1 0.070 Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm O3 Three year average of 4th High *Indicates an exceedance of the standard. 2012 Air Monitoring Network Review 56 2011 0.092* 9 0.073 2012 0.079* 10 0.075 Maricopa County Air Quality Department Buckeye (BE) (04-013-4011) Location: US 85 & MC 85, Buckeye Spatial Scale: Neighborhood and Urban (NO2) Monitoring Type: Population Exposure and Source Oriented (NO2) Site Description: The Buckeye site was established on August 1, 2004. This site is a SLAMS location for carbon monoxide, ozone, PM10, and NO2 criteria pollutants. The site is located in the Maricopa County Department of Transportation Southwest Facility. The immediate area is agriculture and encroaching residential development. The NO2 monitors at this site are classified with the Source Oriented objective; the sources are complexes of power plants that are located approximately 15 miles to the west. The PM10 monitor at this site was changed from a 1-in-6 day to hourly schedule as of October 1, 2004. Carbon Monoxide Ozone PM10 Nitrogen Dioxide Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm O3 Three year avg. of 4th High Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) Annual NO2 Avg. (PPB) NO2 1-hour Average 98th Percentile 2010 0.6 0 0.066 0 0.065 113 0 34.1 7.65 35.0 *Indicates an exceedance of the standard. ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 57 2011 0.9 0 0.072 0 0.064 385* 9 43.7 8.8 36.0 2012 0.5 0 0.078 1 0.066 205*‡ 2 47.4 9.4 39.0 Maricopa County Air Quality Department Cave Creek (CC) (04-013-4008) Location: 32nd St. & Carefree Highway, Cave Creek Spatial Scale: Urban Monitoring Type: Maximum Ozone Concentration Site Description: The Cave Creek site became operational in August 2001 and is located in the Maricopa County Cave Creek Recreation Area (Park Office). This site was chosen through discussions on modifying the ozone network for the 2005 8-hr ozone standard. Ozone is the only criteria pollutant monitored at this SLAMS station. Wind speed and direction are also monitored at the site. Ozone Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm O3 Three year average of 4th High *Indicates an exceedance of the standard. #Indicates a violation of the standard. 2012 Air Monitoring Network Review 58 2010 0.078* 1 0.074 2011 0.088* 6 0.075 2012 0.081* 10 0.077# Maricopa County Air Quality Department Central Phoenix (CP) (04-013-3002) Location: 19th St. and Roosevelt Spatial Scale: Neighborhood Monitoring Type: High Population Exposure and Highest Concentration (NO2 and SO2) Site Description: The Central Phoenix site has been in existence for over four decades and has provided a long-term historical database with a high rate of data recovery. The site is representative of high population exposure (greater than 5000 people per square mile) in the central Phoenix area. This site is a SLAMS location for carbon monoxide, ozone, PM10, SO2 and NO2 criteria pollutants. Carbon Monoxide Ozone PM10 Nitrogen Dioxide Sulfur Dioxide Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm O3 Three year avg. of 4th High Max. 24-hr PM10 Avg. Continuous (µg/m3) Number exceedances Continuous 24-hr PM10 Annual PM10 Avg. Continuous (µg/m3) Annual NO2 Avg. (PPB) NO2 1-hour Average 98th Percentile (PPB) Max. 24-hr SO2 Avg. (PPB) Number of Exceedances SO2 Annual SO2 Avg. (PPB) 2010 2.4 0 0.078* 2 0.071 106 0 27.4 18.82 59.0 5 0 1.7 2011 2.1 0 0.081* 2 0.071 308* 8 39.5 19.8 60.0 4.1 0 1.2 *Indicates an exceedance of the standard. ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 59 2012 2.7 0 0.084* 6 0.074 340*‡ 1 37.9 21.2 63.0 3.4 0 1.2 Maricopa County Air Quality Department Deer Valley (DV) (04-013-4018) Location: 7th Avenue & Deer Valley Rd. Spatial Scale: Middle Monitoring Type: Source Oriented Site Description: The Deer Valley site is located on the grounds of the Deer Valley Airport in north Phoenix. This site was started in July 2010 because changes in the lead NAAQS necessitates that MCAQD begin lead monitoring again (lead monitoring was discontinued in 1997 because ambient concentrations were consistently much lower than the standard at that time). Deer Valley Airport is one of the busiest general aviation airports in Maricopa County; since general aviation fuel still contains lead additives, this is thought to be the largest single source of lead in the county. Lead 3 Max. 24-hr Pb Avg. (µg/m ) Pb #Daily Exceedances >0.15 µg/m3 Pb Maximum Quarterly Average *Incomplete data, only two quarters of data are available for calendar year 2010. 2012 Air Monitoring Network Review 60 2010 0.066 0 0.0274* 2011 0.07 0 0.0329 2012 0.057 0 0.0398 Maricopa County Air Quality Department Durango Complex (DC) (04-013-9812) Location: 27th Ave and Durango St. Spatial Scale: Middle Monitoring Type: Highest Concentration Site Description: This site is located in the Maricopa County Flood Control District storage yard one mile northwest from the former Salt River site, which was closed in 2002. Sampling began on January 6, 1999 with the intent to replace the Salt River site. However, in 2000 the EPA determined that the site is not equivalent to the Salt River site, which prompted the opening of the West 43rd Avenue site. Continuous particulate monitors (SLAMS PM10 and PM2.5) are located at this site, and a SO2 monitor was started here in 2011. Note that the PM2.5 monitor is a continuous FDMS-TEOM monitor, which was not a FEM monitor before 2010, so data from before then was not used for NAAQS compliance purposes. There are also meteorological monitors (wind speed/direction and atmospheric pressure) located at the site. Sulfur Dioxide PM10 PM2 5 Max. 24-hr SO2 Avg. (PPB) Number of Exceedances SO2 Annual SO2 Avg. (PPB) Max. 24-hr PM10 Avg. Continuous (µg/m3) Number exceedances Continuous 24-hr PM10 Annual PM10 Avg. Continuous (µg/m3) Max. 24-hr PM2 5 Avg. (µg/m3) No. of daily exceedances Annual PM2 5 Avg. (µg/m3) 98th Percentile Value (µg/m3) 2010 N/A N/A N/A 111 0 36.2 64.1* 1 10.16# 24.3 *Indicates an exceedance of the standard. ‡Indicates exceptional events at this site. Listed value is the highest official current AQS reading. #Indicates <75% data completeness. 2012 Air Monitoring Network Review 61 2011 4.1 0 1.1 436* 8 48.0 52.6* 4 12.4 31.2 2012 4.5 0 1.5 221*‡ 4 49.1 74.4* 2 11.6 24.9 Maricopa County Air Quality Department Dysart (DY) (04-013-4010) Location: Bell Rd. & Dysart Rd., Surprise Spatial Scale: Neighborhood Monitoring Type: Population Exposure Site Description: The Dysart site was established in July 2003. It is located at the Maricopa County Facility Maintenance Yard at the corner of Bell Rd. and Dysart Rd. The site is in a growing population area in the northwest valley. The land use around the site consists of subdivisions of single family homes, commercial, and industrial. The site is approx. one mile west of the Agua Fria riverbed. Seasonal carbon monoxide, ozone, and PM10 (all SLAMS) are the criteria pollutants monitored at this station. In September 2009 the PM10 monitor was upgraded from a 1-in-6 day scheduled monitor to a continuous-monitoring TEOM. This upgrade took place in accordance with regulations due to a PM10 exceedance which occurred at the site. Carbon Monoxide Ozone PM10 Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year avg. of 4th High Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) 2010 0.9 0 0.082* 1 0.069 81 0 21.5 *Indicates an exceedance of the standard. ‡Indicates exceptional events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 62 2011 0.5 0 0.075 0 0.070 273* 5 29.2 2012 0.6 0 0.079* 2 0.071 167* 1 30.0 Maricopa County Air Quality Department Falcon Field (FF) (04-013-1010) Location: Greenfield and McKellips Spatial Scale: Neighborhood Monitoring Type: Population Exposure Site Description: Ozone is the only SLAMS criteria pollutant monitored at this station. Monitoring began in June of 1989. The site is located near an airfield in a fire station within a growing residential area. Ozone Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year avg. of 4th High *Indicates an exceedance of the standard. 2012 Air Monitoring Network Review 63 2010 0.074 0 0.070 2011 0.074 0 0.068 2012 0.075 0 0.069 Maricopa County Air Quality Department Fountain Hills (FH) (04-013-9704) Location: Fountain Hills Blvd. and Palisades Blvd. Spatial Scale: Neighborhood Monitoring Type: Maximum Ozone Concentrations Site Description: The site, located at a Fountain Hills fire station, became operational in April of 1996 and monitors ozone (SLAMS) and wind speed and direction. The site is located approximately 15 miles downwind from the Phoenix metropolitan area and represents the high downwind concentrations on the fringes of the central basin district along the predominant summer/fall daytime wind direction. Ozone 2010 0.081* 3 0.074 Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year avg. of 4th High *Indicates an exceedance of the standard. #Indicates a violation of the standard. 2012 Air Monitoring Network Review 64 2011 0.089* 9 0.073 2012 0.083 5 0.076# Maricopa County Air Quality Department Glendale (GL) (04-013-2001) Location: 59th Ave. and Olive Ave. Spatial Scale: Neighborhood Monitoring Type: Population Exposure Site Description: The Glendale site was established over three decades ago and is located on the grounds of Glendale Community College in a populous residential area. Homes, various strip malls, food establishments, and parks surround the site. Seasonal carbon monoxide, Ozone, PM2.5 and PM10 (all SLAMS) are the criteria pollutants monitored at this station. In September 2009 the PM10 monitor was upgraded from a 1-in-6 day filter-based monitor to a continuous-monitoring TEOM. This upgrade took place in accordance with regulations due to a PM10 exceedance which occurred at the site. The continuous PM2.5 monitor was added in 2011. Carbon Monoxide Ozone PM10 PM2 5 Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year avg. of 4th High Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) Max. 24-hr PM2 5 Avg. (µg/m3) No. of daily exceedances Annual PM2 5 Avg. (µg/m3) 98th Percentile Value (µg/m3) 2010 3.0 0 0.083* 3 0.072 92 0 22.9 N/A N/A N/A N/A *Indicates an exceedance of the standard. + Represents less than a calendar year of observations (4926 observations) ‡Indicates exceptional events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 65 2011 1.3 0 0.083* 4 0.073 242* 5 32.3 42.7*+ 2+ 9.1+ 27.8+ 2012 1.3 0 0.088 4 0.076# 337*‡ 1 34.1 66.1* 2 8.7 18.6 Maricopa County Air Quality Department Greenwood (GR) (04-013-3010) Location: 27th Ave. and I-10, Phoenix Spatial Scale: Middle Monitoring Type: Population Exposure Site Description: Monitoring began at this site in December 1993. The station is bordered on the north by Interstate 10, on the west and south by neighborhood homes, and to the east by Greenwood Cemetery. Interstate 17 is approximately one mile to the east of the site. Carbon monoxide, NO2, and PM10 are the criteria pollutants monitored at this SLAMS facility. This site was converted to continuous PM10 monitoring in the beginning of 2006. Carbon Monoxide PM10 Nitrogen Dioxide Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) Annual NO2 Avg. (PPB) NO2 1-hour Average 98th Percentile (PPB) 2010 3.0 0 158* 1 34.9 24.52 68.0 *Indicates an exceedance of the standard. ‡Indicates exceptional events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 66 2011 2.5 0 388* 7 42.2 25.4 65.0 2012 3.2 0 323*‡ 2 45.3 26.0 65.0 Maricopa County Air Quality Department Higley (HI) (04-013-4006) Location: Higley Rd. and Williams Field Rd., Gilbert Spatial Scale: Neighborhood Monitoring Type: Population Exposure Site Description: Originally, in 1994, ADEQ set up this site to monitor for background particulate concentrations near the urban limits of Maricopa County. Since then, urban expansion has enveloped the site, so it no longer serves its original intended purpose. The Department installed a (1-in-6 day) PM10 (SLAMS) in the second quarter of 2000. The data from this site was compared to the Chandler site and was found to be comparable. Since the City of Chandler requested that the department remove the Chandler site on 12/31/05, this site has taken over the role of that site. As of October 2004 the 1-in-6 day PM10 monitor was replaced with an hourly continuous PM10 monitor in accordance with 40 CFR 50, Appendix K. This continuous monitor samples on the neighborhood scale with a monitoring objective of high population exposure. PM10 Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) 2010 83 0 30.1 2011 362* 8 39.0 *Indicates an exceedance of the standard. ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 67 2012 224*‡ 4 38.3 Maricopa County Air Quality Department Humboldt Mountain (HM) (04-013-9508) Location: Humboldt Mountain Summit Spatial Scale: Regional Monitoring Type: Maximum Ozone Concentrations Site Description: This site became operational in August 1995. The Humboldt Mountain site is located on Federal Aviation Agency property, in a National Forest Service building in the Tonto National Forest. This site is located approximately 40 miles north-northeast of the Phoenix metropolitan area at an elevation of 5190 feet. Ozone is the only criteria pollutant that is monitored at this SLAMS site. Ozone 2010 0.074 0 0.071 Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year avg. of 4th High *Indicates an exceedance of the standard. #Indicates a violation of the standard. 2012 Air Monitoring Network Review 68 2011 0.088 6 0.071 2012 0.082 10 0.075 Maricopa County Air Quality Department Mesa (ME) (04-013-1003) Location: Broadway Rd. and Brooks Ave. Spatial Scale: Neighborhood Monitoring Type: Population Exposure Site Description: This site is located at the City of Mesa Brooks Reservoir at the western edge of the city near the Tempe border. It is centered in an area that contains residential, industrial, and a small amount of agricultural activity. An open field borders the site on the west with commercial development to the north, and light industry east and south of the site. Carbon monoxide, ozone, PM2 5, and PM10 are the criteria pollutants monitored at this SLAMS site. The department started operation of the PM2 5 Federal Reference Method monitor in May 2005. In December 2012, following an operational hiatus during a ten-month site construction by the City of Mesa, the site began operation again with new continuous PM10 and PM2 5 monitors replacing the filter-based monitors. A new ozone monitor was also started at the site. Carbon Monoxide PM10 PM2 5 Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) Max. 24-hr PM2 5 Avg. (µg/m3) Number of Daily Exceedances Annual PM2 5 Avg. (µg/m3) 98th Percentile Value (µg/m3) * Indicates an exceedance of the standard #Indicates <75% data completeness 2012 Air Monitoring Network Review 69 2010 1.4 0 86 0 17.4 14.0 0 6.25 11.8 2011 1.5 0 127 0 26.7 102.3* 1 8.9 20.4 2012 1.4 0 64 0# 22.8 23.3 0# 8.5 23.3 Maricopa County Air Quality Department North Phoenix (NP) (04-013-1004) Location: 7th St. and Butler Ave. Spatial Scale: Neighborhood Monitoring Type: Population Exposure Site Description: This site is located in the Sunnyslope area of North Phoenix. Sunnyslope is an older established neighborhood, primarily residential. High-density population surrounds the site. CO, ozone, PM2.5 and PM10 (all SLAMS) are monitored at this site, along with delta temperature (temperature inversion). Carbon Monoxide Ozone PM10 PM2 5 2010 1.7 0 0.085* 6 0.077# 44 0 19.3 N/A N/A N/A N/A Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year Avg. of 4th High Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) Max. 24-hr PM2 5 Avg. (µg/m3) Number of Daily Exceedances Annual PM2 5 Avg. (µg/m3) 98th Percentile Value (µg/m3) 2011 1.6 0 0.090* 8 0.078# 186* 2 26.5 46.9*+ 1+ 9.3+ 23.0+ *Indicates an exceedance of the standard. #Indicates a violation of the standard +Represents less than a year of observations (2895 observations) ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 70 2012 1.5 0 0.091 10 0.081# 178*‡ 1 32.4 30.1 0 9.3 21.2 Maricopa County Air Quality Department Pinnacle Peak (PP) (04-013-2005) Location: Pima Rd & Pinnacle Peak Spatial Scale: Urban Monitoring Type: Maximum Ozone Concentrations Site Description: This SLAMS site for ozone was formerly located on the roof of a golf course country club surrounded by residential homes, though from November 2011 through July 2012 it was shut down and moved ½ mile south to a maintenance yard following a request by the property owner. It is located in a geographic area of low-density population (less than 2500 people per square mile). In the current and previous years, ozone exceedances have been recorded due to transport of ozone and precursors from more urbanized areas of metropolitan Phoenix. Ozone 2010 0.080* 4 0.073 Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year Avg. of 4th High *Indicates an exceedance of the standard #Indicates a violation of the standard 2012 Air Monitoring Network Review 71 2011 0.088* 4 0.075 2012 0.082* 6 0.077# Maricopa County Air Quality Department Rio Verde (RV) (04-013-9706) Location: Forest Rd. and Del Ray Ave. Spatial Scale: Urban Monitoring Type: Maximum Ozone Concentrations Site description: This ozone site became operational in spring of 1997. The monitor is located at the fire station / County Sheriff’s office sub-station located in a residential area surrounded by the desert of Tonto National Forest. The site is eight miles north of the Fountain Hills SLAMS station, on the edge of a Class I Wilderness Area. Ozone 2010 0.078* 1 0.073 Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year Avg. of 4th High *Indicates an exceedance of the standard #Indicates a violation of the standard. 2012 Air Monitoring Network Review 72 2011 0.088* 6 0.073 2012 0.076* 2 0.074 Maricopa County Air Quality Department South Phoenix (SP) (04-013-4003) Location: Central Ave. and Broadway Rd. Spatial Scale: Neighborhood Monitoring Type: Population Exposure Site Description: The site was opened at its current location in October 1999. The site is at the edge of a high population area, but also borders on a mixture of residential and commercial (retail stores, food establishments, and office parks) land use. The station has two high population areas (>5000 people per square miles) north and west of the site. Carbon monoxide, ozone, and PM10 (all SLAMS) are the criteria pollutants monitored at this station. The department started operation of a PM2 5 FRM filter-based monitor in May 2005. A continuous Thermo Scientific 1405 PM2 5 monitor started operation at this site in December 2008. This monitor is classified as a Federal Equivalent Method (FEM), and therefore the data can be used for compliance purposes within AQS. The filter-based PM2 5 FRM was shut down in July 2012. Carbon Monoxide Ozone PM10 PM2 5 2010 3.1 0 0.076* 1 0.072 120 0 35.0 63.4* (82.6*) # 1 (2)# 9.23 (7.98)# 24.0 Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year Avg. of 4th High Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) Max. 24-hr PM2 5 Avg. (µg/m3) Number of Daily Exceedances Annual PM2 5 Avg. (µg/m3) 98th Percentile value (µg/m3) 2011 2.6 0 0.081* 4 0.072 420* 9 47.7 62.0* (60.8*)# 2012 2.3 0 0.087* 5 0.076 342*‡ 3 47.9 70.0* (70.8)# 2 (4)# 11.4 (9.33)# 27.2 0 (2)# 11.5 (9.2)# 24.4 *Indicates an exceedance of the standard. ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. #First number is filter-based monitor; second number (in parenthesis) is continuous monitor. 2012 Air Monitoring Network Review 73 Maricopa County Air Quality Department South Scottsdale (SS) (04-013-3003) Location: Thomas Rd. and Miller Rd. Spatial Scale: Neighborhood, Urban (NO2) Monitoring Type: Population Exposure Site Description: The South Scottsdale site is located at a City of Scottsdale Fire Station. The area surrounding the site is residential with a density of 2500 to 5000 persons per square mile. This site is located 12 miles east of metropolitan Central Phoenix. Carbon monoxide, ozone, and PM10 (all SLAMS) are the criteria pollutants monitored at this station. SO2 monitoring was discontinued in 2010 due to extremely low values being recorded. The SO2 monitor was moved the Durango Complex site, which is closer to SO2 point sources. NO2 monitoring was discontinued in 2011. Continuous PM monitors replaced filter based monitors on September 1, 2012. Carbon Monoxide Ozone PM10 Nitrogen Dioxide Sulfur Dioxide Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year Avg. of 4th High Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) Annual NO2 Avg. (PPB) NO2 1-hour Average 98th Percentile (PPB) Max. 24-hr SO2 Avg. (PPB) Number of Exceedances SO2 Annual SO2 Avg. (PPB) 2010 1.6 0 0.084* 4 0.075 37 0 17.4 13.92 53.0 3 0 1.3 2011 1.4 0 0.083* 3 0.074 119 0 25.8 15.5 54.0 2012 1.3 0 0.086* 7 0.077# 102 0 31.6 *Indicates an exceedance of the standard. #Indicates a violation of the standard. ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 74 Maricopa County Air Quality Department Tempe (TE) (04-013-4005) Location: Apache Blvd. & College Ave. Spatial Scale: Neighborhood Monitoring Type: Population Exposure Site Description: The site was established in 2000 to fill in a spatial gap between the metropolitan Phoenix area and the city of Mesa. Ozone and carbon monoxide (both SLAMS) are monitored at the site, and continuous PM10 and PM2.5 monitors (SLAMS) were added in 2012. Wind speed and direction and delta temperature (temperature inversion) meteorological parameters are also monitored at this site. Carbon Monoxide Ozone PM10 PM2 5 2010 1.9 0 0.075 0 0.071 N/A N/A N/A N/A N/A N/A N/A Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year Avg. of 4th High Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) Max. 24-hr PM2 5 Avg. (µg/m3) Number of Daily Exceedances Annual PM2 5 Avg. (µg/m3) 98th Percentile Value (µg/m3) *Indicates an exceedance of standard. #Indicates a violation of the standard. 2012 Air Monitoring Network Review 75 2011 3.2 0 0.076* 1 0.068 N/A N/A N/A N/A N/A N/A N/A 2012 1.6 0 0.078 1 0.070 169* 1 31.6 23.1 0 9.27 19.5 Maricopa County Air Quality Department West Chandler (WC) (04-013-4004) Location: Frye Rd. and Ellis St. Spatial Scale: Neighborhood, Middle (PM10) Monitoring Type: Population Exposure Site Description: This site was first established in January 1995. The site was moved one half mile to the southeast in May 2000 when the Chandler fire station that hosts it relocated. A wide range of land uses surround the site including residential, agriculture, and heavy industry (semiconductor manufacturing plants and liquid air storage). Carbon monoxide, ozone, and PM10 are the criteria pollutants monitored at this SLAMS site. In September 2009 the PM10 monitor was upgraded from a 1-in-6 day scheduled monitor to a continuous-monitoring TEOM. This upgrade took place in accordance with regulations due to a PM10 exceedance which occurred at the site. Carbon Monoxide Ozone PM10 Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #Daily Exceedances >0.075 ppm Three year Avg. of 4th High Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) 2010 1.9 0 0.083* 2 0.074 76 0 23.3 *Indicates an exceedance of the standard. ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. #Indicates a violation of the standard. 2012 Air Monitoring Network Review 76 2011 1.4 0 0.079* 3 0.073 669* 7 47.9 2012 1.4 0 0.082* 2 0.074 402*‡ 5 36.1 Maricopa County Air Quality Department West 43rd Avenue (WF) (04-013-4009) Location: 43rd Ave. & Broadway Rd. Spatial Scale: Middle Monitoring Type: Highest Concentrations Site Description: Monitoring began at the site in the 2nd quarter of 2002. This site is located at a Maricopa County Department of Transportation storage lot and is surrounded by a combination of heavy industry and residential homes. The site has one continuous TEOM PM10 monitor and a temperature inversion monitor, as well as other meteorological instruments. The main purpose of the site is to measure maximum concentration PM10 and to determine the impact on ambient pollution levels of significant sources or source categories. The sources around the site include sand and gravel operations, auto and metal recycling facilities, landfills, paved and unpaved haul roads, and cement casting. PM10 2010 112 0 39.4 Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) 2011 369*‡ 7 47.9 *Indicates an exceedance of the standard. ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 77 2012 254*‡ 6 50.5 Maricopa County Air Quality Department West Phoenix (WP) (04-013-0019) Location: 39th Ave. and Earll Dr. Spatial Scale: Neighborhood Monitoring Type: Population Exposure, Highest Concentration (PM2.5) Site Description: This site became operational in 1984. The spatial scale for the West Phoenix site is neighborhood. It is located in an area of stable, high-density residential population. CO, PM10, PM2.5, O3, and NO2 (All SLAMS) are the criteria pollutants monitored at this site. The department operates collocated PM2.5 FRM filter-based monitors and a continuous PM2.5 FEM monitor (SLAMS) at this site. Carbon Monoxide Ozone PM10 PM2 5 Max. 8-hr CO Avg. (PPM) Number exceedances 8-hr CO Max. 8-hr O3 Avg. (PPM) O3 #of Daily Exceedances >0.075 ppm Three year Avg. of 4th High Max. 24-hr PM10 Avg. (µg/m3) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) Max. 24-hr PM2 5 Avg. (µg/m3) Number of Daily Exceedances Annual PM2 5 Avg. (µg/m3) Nitrogen Dioxide 98th Percentile Value Annual NO2 Avg. (PPB) NO2 1-hour Average 98th Percentile (PPB) 2010 4.3 0 0.082* 2 0.074 86 0 29.8 53.3* (55.3*)# 1 (2)# 8.36 (7.60)# 21.6 17.72 55.0 2011 3.0 0 0.086* 5 0.074 279 8 48.0 30.6 (99.1*)# 0 (4)# 10.2 (11.6)# 31.5 18.0 55.0 *Indicates an exceedance of the standard. #Indicates a violation of the standard. #First number is filter-based monitor; second number (in parenthesis) is continuous monitor. ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 78 2012 3.9 0 0.087* 9 0.078# 189*‡ 1 46.9 112.6* (89.1*)# 2 (2)# 12.0 (10.4) 29.0 19.4 58.0 Maricopa County Air Quality Department Zuni Hills (ZH) (04-013-4016) Location: 109th Ave. and Deer Valley Road. Spatial Scale: Neighborhood Monitoring Type: Population Exposure Site Description: This site was opened in December 2009 and is located on the campus of the Zuni Hills elementary school, which is approximately 1.7 miles to the northeast from the now closed Coyote Lakes monitor. Coyote Lakes was a source-oriented, middle scale PM10 site that was situated in the Agua Fria River bottom adjacent to sand and gravel mines; Zuni Hills replaces this with a populationoriented neighborhood scale site that is situated on the higher-elevation river bank. This site will theoretically be able to represent the air quality for a larger area and a greater number of people. PM10 3 Max. 24-hr PM10 Avg. (µg/m ) Number exceedances 24-hr PM10 Annual PM10 Avg. (µg/m3) 2010 70 0 20.7 *Indicates an exceedance of the standard. ‡Indicates Exceptional Events at this site. Listed value is the highest official current AQS reading. 2012 Air Monitoring Network Review 79 2011 411*‡ 4 28.4 2012 285*‡ 1 49.1 Maricopa County Air Quality Department APPENDIX II - EPA REQUIRED DATA Details compliance with requirements of 40CFR58 §58.10 and Appendices A, C, D, and E 2012 Air Monitoring Network Review 80 Maricopa County Air Quality Department Required General Statement Regarding Changes to the PM2.5 Network In the event the department needed to move or change a violating PM2 5 monitor the following procedure would be followed: The department would hold a public hearing regarding the requested change. Details and documentation of the requested change, as well as all public comments, would then be forwarded to the EPA for approval. Any action on the department’s part will be dependent on EPA approval. Please note that the previous statement is general in nature and is required to be placed in the annual network review by 40CFR58. The department does not currently have any violating PM2.5 monitors, nor does it have any proposals to move any PM2.5 monitors. Notes regarding appendix data Analysis Method (filters only) refers to the method used to process filter-based particulate samples. Distance from Supporting Structure refers to those sample probes that are attached to a supporting structure, such as the side of a building. In most cases the sample probe is located above the supporting structure, in which case the entry will say N/A. Distance from Obstructions refers to those obstructions, both on the roof and off the roof, which are located higher than the probe. In the case of a nearby obstruction being higher than the probe, details of its location will be listed in the entry. If there are no obstructions higher than the probe, then the entry will be N/A. Last Annual Performance Evaluation Date refers to the performance evaluations detailed in 40CFR58, Appendix A, §3.2.2. These performance evaluations are performed by an agency outside of MCAQD. At least 25% of the network should be evaluated once per calendar quarter. Last Two Semi-Annual Flow Rate Audit Dates refers to the performance evaluations detailed in 40CFR58, Appendix A, §3.2.4. These performance evaluations are performed by an agency outside of MCAQD at least once every six months. Probe Sample Line Material refers to the material makeup of the intake sample lines. Pollutant Sample Residence Time refers to the amount of time that it takes a sample of air to travel between the probe inlet and the monitor. This residence time is calculated by a formula that is based on the sample line diameter and length and the flow rate of the air intake. It is important to keep this residence time low so as to prevent gases in the air sample from reacting with the sample line material or with other gases in the sample; e.g. ozone could react with nitrogen oxide in the air sample if the residence time exceeds 20 seconds. This measurement only applies to NO2, SO2, and O3 monitors. 2012 Air Monitoring Network Review 81 Maricopa County Air Quality Department BLUE POINT County ID: BP AQS ID: 04-013-9702 Address: Bush Highway & Usery Pass Road, Maricopa County Coordinates: 33.54549N – 111.60925W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 82 Ozone Continuous N/A No N/A 26 3 Yes Submitted July 2013 Bi-Weekly N/A API M400 (087) 01/01/1993 SLAMS FEM Max Ozone Concentration Urban Jan-Dec Yes N/A 5.3 meters 360º Teflon 7.6 sec N/A N/A N/A N/A Bush Highway 160 meters, South 1,000 Paved Maricopa County Air Quality Department BUCKEYE County ID: BE AQS ID: 04-013-4011 Address: 26449 W 100th DR, Buckeye Coordinates: 33.37005N – 111.62070W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Distance from Supporting Structure Probe Sample Line Material Pollutant Sample Residence Time Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review Ozone Continuous N/A No N/A CO Continuous N/A No N/A NO2 Continuous N/A No N/A PM10 Continuous N/A No N/A 26 4 Yes 15 2 Yes 26 4 Yes 23 2 Yes Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 N/A Bi-Weekly API M400 (087) 08/01/2004 SLAMS FEM API M300 (093) 08/01/2004 SLAMS FRM API M200 (099) 08/01/2004 SLAMS FRM Thermo TEOM 1400AB (079) 08/01/2004 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Sep-Mar Yes Source Oriented Urban Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes N/A 4 meters 360º N/A Teflon 4.0 sec N/A N/A 14 meters, N US Hwy 85 31 meters, N 3,000 Paved N/A 4 meters 360º N/A Teflon N/A N/A N/A 14 meters, N US Hwy 85 31 meters, N 3,000 Paved N/A 4 meters 360º N/A Teflon 4.0 sec N/A N/A 14 meters, N US Hwy 85 31 meters, N 3,000 Paved N/A 4.5 meters 360º N/A N/A N/A N/A N/A 14 meters, N US Hwy 85 31 meters, N 3,000 Paved 83 Maricopa County Air Quality Department CAVE CREEK County ID: CC AQS ID: 04-013-4008 Address: 37019 N Lava Lane, Phoenix Coordinates: 33.82169N – 112.01739W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 84 Ozone Continuous N/A No N/A 26 4 Yes Submitted July 2013 Bi-Weekly N/A API M400 (087) 07/20/2001 SLAMS FEM Max Ozone Concentration Urban Jan-Dec Yes N/A 4.8 meters 360º Teflon 10.2 sec N/A N/A N/A 20 meters, E 32nd Street 240 meters, NE 1,000 Paved Maricopa County Air Quality Department CENTRAL PHOENIX County ID: CP AQS ID: 04-013-3002 Address: 1645 E Roosevelt, Phoenix Coordinates: 33.45793N - 112.04601W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2.5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway A Distance and Direction to Road Traffic Count (ADT) Nearest Major Roadway B Distance and Direction to Road Traffic Count (ADT) Groundcover Ozone Continuous N/A No CO Continuous N/A No NO2 Continuous N/A No SO2 Continuous N/A No PM10 Continuous N/A No N/A N/A N/A N/A N/A 27 26 25 25 23 5 4 5 2 2 Yes Yes Yes Yes Yes Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 N/A Bi-Weekly API M400 (087) API M300 (093) API M200 (099) API M100 (100) Thermo TEOM 1400AB (079) 06/01/1967 SLAMS FEM 10/01/1966 SLAMS FRM 01/01/1967 SLAMS FRM 01/01/1965 SLAMS FEM 04/01/1985 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes Highest Concentration Neighborhood Jan-Dec Yes Highest Concentration Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes N/A N/A N/A N/A N/A 11.3 meters 360 Teflon 9.0 sec N/A N/A N/A N/A 16th Street 88 meters, W 24,000 Roosevelt St. 75 meters, N Unknown Paved 11.3 meters 360 Teflon N/A N/A N/A N/A N/A 16th Street 88 meters, W 24,000 Roosevelt St. 75 meters, N Unknown Paved 11.3 meters 360 Teflon 9.0 sec N/A N/A N/A N/A 16th Street 88 meters, W 24,000 Roosevelt St. 75 meters, N Unknown Paved 11.3 meters 360 Teflon 10.0 sec N/A N/A N/A N/A 16th Street 88 meters, W 24,000 Roosevelt St. 75 meters, N Unknown Paved 11.3 meters 360 N/A N/A N/A N/A N/A N/A 16th Street 91 meters, W 24,000 Roosevelt St. 75 meters, N Unknown Paved 2012 Air Monitoring Network Review 85 Maricopa County Air Quality Department DEER VALLEY County ID: DV AQS ID: 04-013-4018 Address: 1030 West Deer Valley Road, Phoenix Coordinates: 33.684627N -112.08635W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 86 Lead 1 in 6 day Filters sent out to independent laboratory for weighing No N/A 25 (collocated) 1 Yes Submitted July 2013 N/A Semi-Annual Hi-Q TSP Sampler (109) 07/01/2010 SLAMS FRM Source Oriented Middle Scale Jan-Dec Yes 2.7 meters 4.1 meters 360º N/A N/A N/A N/A N/A N/A Deer Valley 300 meters, S 6,452 Paved Maricopa County Air Quality Department DURANGO COMPLEX County ID: DC AQS ID: 04-013-9812 Address: 2702 RC Esterbrooks Blvd, Phoenix Coordinates: 33.42650N -112.11814W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule PM10 Continuous PM2.5 Continuous SO2 Continuous Analysis Method (filters only) N/A N/A N/A Any Proposal to Remove or Move Monitor? No No No Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? N/A Yes N/A # Precision Checks Performed Annually # Accuracy Checks Performed Annually 24 3 25 3 26 3 All Precision/Accuracy Reports Submitted to AQS? Yes Yes Yes Annual Data Certification Submitted? Submitted July 2013 Submitted July 2013 Submitted July 2013 Frequency of One-Point QC Check N/A N/A Bi-Weekly Frequency of Flow Rate Verification Bi-Weekly Bi-Weekly N/A Sampler Make & Model Thermo TEOM 1400AB (079) API M100 (100) Date Established 07/01/1999 Thermo FDMSTEOM 1400AB (181) 07/01/2005 Classification SLAMS SLAMS SLAMS Method (FRM, FEM, ARM) FEM FEM FRM Highest Concentration Highest Concentration Highest Concentration Monitoring Scale Middle Middle Middle Sampling Season Jan-Dec Jan-Dec Jan-Dec Network Meets Minimum Number of Monitors Required? Yes Yes Yes -Appendix E Requirements Distance between collocated samplers N/A N/A N/A Probe Inlet Height 3.9 meters 4.8 meters 3.9 meters Airflow Arc 360º 360º 360º Probe Sample Line Material N/A N/A Teflon Pollutant Sample Residence Time N/A N/A 10.0 sec Distance from Supporting Structure Distance from Obstructions N/A N/A N/A N/A N/A N/A Distance to Furnace Flue N/A N/A N/A Spacing from Trees 14 meters, S 14 meters, S 14 meters, S -Appendix A Requirements -Appendix C Requirements -Appendix D Requirements Monitoring Type th Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 87 th 01/01/2011 27 Ave 27 Ave 27th Ave 78 meters, E 76 meters, E 76 meters, E 16,000 Paved 16,000 Paved 16,000 Paved Maricopa County Air Quality Department DYSART County ID: DY AQS ID: 04-013-4010 Address: 16825 N Dysart Rd, Surprise Coordinates: 33.63713N – 112.34184W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Ozone Continuous N/A No N/A CO Continuous N/A No N/A PM10 Continuous N/A No N/A 26 5 Yes 15 2 Yes 24 2 Yes Submitted July 2013 Submitted July 2013 Submitted July 2013 Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Bi-Weekly N/A Bi-Weekly N/A N/A Monthly API M400 (087) API M300 (093) Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type 7/21/2003 SLAMS FEM 09/01/2003 SLAMS FRM Thermo TEOM 1400AB (079) 07/14/2003 SLAMS FRM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Sep-Mar Yes Population Exposure Neighborhood Jan-Dec Yes N/A 3.3 meters 360º Teflon 4.8 sec N/A N/A N/A N/A Dysart 17 meters, W 12,000 Bell Rd 495 meters, N 43,000 Paved/Gravel N/A 3.3 meters 360º Teflon N/A N/A N/A N/A N/A Dysart 17 meters, W 12,000 Bell Rd 495 meters, N 43,000 Paved/Gravel N/A 2.6 meters 360º N/A N/A N/A N/A N/A N/A Dysart 12 meters, W 12,000 Bell Rd 460 meters, N 43,000 Paved/Gravel Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway A Distance and Direction to Road Traffic Count (ADT) Nearest Major Roadway B Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 88 Maricopa County Air Quality Department FALCON FIELD County ID: FF AQS ID: 04-013-1010 Address: 4530 E McKellips Rd, Mesa Coordinates: 33.45223N – 111.73331W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 89 Ozone Continuous N/A No N/A 26 4 Yes Submitted July 2013 Bi-Weekly N/A API M400 (087) 06/01/1989 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes N/A 9.3 meters 360º Teflon 16.4 sec N/A N/A N/A N/A McKellips 58 meters, S 29,000 Paved Maricopa County Air Quality Department FOUNTAIN HILLS County ID: FH AQS ID: 04-013-9704 Address: 16426 E Palisades Blvd, Fountain Hills Coordinates: 33.61103N – 111.72529W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 90 Ozone Continuous N/A No N/A 27 5 Yes Submitted July 2013 Bi-Weekly N/A API M400 (087) 04/01/1996 SLAMS FEM Max Ozone Concentration Neighborhood Jan-Dec Yes N/A 4.3 meters 360º Teflon 4.8 sec N/A Canopy 1 meter higher than probe, located 9 meters to the south N/A 15 meters, W Palisades Blvd 70 meters, SW 8,000 Paved Maricopa County Air Quality Department GLENDALE County ID: GL AQS ID: 04-013-2001 Address: 6001 W Olive, Glendale Coordinates: 33.56936N – 112.19153W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway A Distance and Direction to Road Traffic Count (ADT) Nearest Major Roadway B Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review Ozone Continuous N/A No N/A CO Continuous N/A No N/A PM10 Continuous N/A No N/A PM2.5 Continuous N/A No Yes 26 4 Yes Submitted July 2013 Bi-Weekly N/A 16 2 Yes Submitted July 2013 Bi-Weekly N/A 24 2 Yes Submitted July 2013 N/A Bi-Monthly 24 2 Yes Submitted July 2013 N/A Bi-Monthly API M400 (087) API M300 (093) Thermo TEOM 1400AB (079) Thermo FDMSTEOM 1400AB (181) 01/01/1974 SLAMS FEM 01/01/1974 SLAMS FRM 07/01/1987 SLAMS FEM 6/1/2011 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Sep-Mar Yes Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes N/A 3.7 meters 360º Teflon 4.5 sec N/A N/A N/A N/A Olive Ave 225 meters, S 25,000 59th Ave 475 meters, E 30,500 Paved N/A 3.7 meters 360º Teflon N/A N/A N/A N/A N/A Olive Ave 225 meters, S 25,000 59th Ave 475 meters, E 30,500 Paved N/A 3.4 meters 360º N/A N/A N/A N/A N/A N/A Olive Ave 227 meters, S 25,000 59th Ave 430 meters, E 30,500 Paved N/A 4.0 meters 360º N/A N/A N/A N/A N/A N/A Olive Ave 227 meters, S 25,000 59th Ave 430 meters, E 30,500 Paved 91 Maricopa County Air Quality Department GREENWOOD County ID: GR AQS ID: 04-013-3010 Address: 1128 N 27th Ave., Phoenix Coordinates: 33.46093N – 112.11748W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway A Distance and Direction to Road Traffic Count (ADT) Nearest Major Roadway B Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review CO Continuous N/A No N/A NO2 Continuous N/A No N/A PM10 Continuous N/A No N/A 26 2 Yes Submitted July 2013 Bi-Weekly N/A 27 4 Yes Submitted July 2013 Bi-Weekly N/A 24 2 Yes Submitted July 2013 N/A Bi-Weekly API M300 (093) API M200 (099) 11/01/1993 SLAMS FRM 11/01/1993 SLAMS FRM Thermo TEOM 1400AB (079) 11/01/1993 SLAMS FEM Population Exposure Middle Jan-Dec Yes Population Exposure Middle Jan-Dec Yes Population Exposure Middle Jan-Dec Yes N/A 4.2 meters 360º Teflon N/A N/A N/A N/A 20 meters, NW 27th Ave 10 meters, E 18,500 I-10 85 meters, N 229,000 Paved N/A 4.2 meters 360º Teflon 4.3 sec N/A N/A N/A 20 meters, NW 27th Ave 10 meters, E 18,500 I-10 85 meters, N 229,000 Paved N/A 4.4 meters 360º N/A N/A N/A N/A N/A 20 meters, NW 27th Ave 10 meters, E 18,500 I-10 85 meters, N 229,000 Paved 92 Maricopa County Air Quality Department HIGLEY County ID: HI AQS ID: 04-013-4006 Address: 15400 South Higley Road, Gilbert Coordinates: 33.31074N – 111.72255W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway A Distance and Direction to Road Traffic Count (ADT) Nearest Major Roadway B Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 93 PM10 Continuous N/A No N/A 26 2 Yes Submitted July 2013 N/A Bi-Weekly Thermo TEOM 1400AB (079) 07/01/2000 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes N/A 2.9 meters 360º N/A N/A N/A N/A N/A N/A Higley Rd 117 meters, E 11,500 Williams Field Rd 410 meters, S 11,500 Paved Maricopa County Air Quality Department HUMBOLDT MOUNTAIN County ID: HM AQS ID: 04-013-9508 Address: Seven Springs Rd-FAA Radar Station, Tonto National Forest Coordinates: 33.98280N – 111.79870W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 94 Ozone Continuous N/A No N/A 26 4 Yes Submitted July 2013 Bi-Weekly N/A API M400 (087) 01/01/1993 SLAMS FEM Max Ozone Concentration Regional Jan-Dec Yes N/A 4.5 meters 360º Teflon 6.2 sec N/A N/A N/A N/A N/A (Remote mountaintop site, only reachable by small access road) N/A N/A Dirt/Vegetated Maricopa County Air Quality Department MESA County ID: ME AQS ID: 04-013-1003 Address: 310 S Brooks, Mesa Coordinates: 33.41045N – 111.86507W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review Ozone Continuous N/A No N/A CO Continuous N/A No N/A PM2.5 Continuous N/A No Yes PM10 Continuous N/A No N/A 4 1 Yes Submitted July 2013 Bi-Weekly N/A 6 4 Yes Submitted July 2013 Bi-Weekly N/A 4 1 Yes Submitted July 2013 N/A Bi-Weekly 4 1 Yes Submitted July 2013 N/A Bi-Weekly API M400 (087) API M300 (093) Thermo FDMSTEOM 1405-DF (182) Thermo TEOM 1400AB (079) 11/1/2012 SLAMS FEM 01/01/1978 SLAMS FEM 11/1/2012 SLAMS FEM 11/1/2012 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Sep-Mar Yes Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes N/A 7 meters 360º Teflon N/A N/A N/A N/A N/A Broadway Rd. 305 meters, S 33,000 Paved/Gravel N/A 7 meters 360º Teflon N/A N/A N/A N/A N/A Broadway Rd. 305 meters, S 33,000 Paved/Gravel N/A 6.9 meters 360º N/A N/A N/A N/A N/A N/A Broadway Rd. 305 meters, S 33,000 Paved/Gravel N/A 6.2 meters 360º N/A N/A N/A N/A N/A N/A Broadway Rd. 305 meters, S 33,000 Paved/Gravel 95 Maricopa County Air Quality Department NORTH PHOENIX County ID: NP AQS ID: 04-013-1004 Address: 601 E Butler Dr., Phoenix Coordinates: 33.56033N – 112.06626W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review Ozone Continuous N/A No N/A CO Continuous N/A No N/A PM10 Continuous N/A No Yes PM2.5 Continuous N/A No N/A 26 5 Yes 15 2 Yes 25 2 Yes 25 2 Yes Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 N/A Bi-Weekly Submitted July 2013 N/A Bi-Weekly API M400 (087) 01/01/1975 SLAMS FEM API M300 (093) 01/01/1974 SLAMS FRM BAM 1020 (122) 9/1/2011 SLAMS FEM BAM 1020 (122) 9/1/2011 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Sep-Mar Yes Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes N/A 4.6 meters 360º Teflon 5.0 sec N/A N/A N/A N/A 7th Street 75 meters, E 32,000 Gravel N/A 4.6 meters 360º Teflon N/A N/A N/A N/A N/A 7th Street 75 meters, E 32,000 Gravel N/A 4.5 meters 360º N/A N/A N/A N/A N/A N/A 7th Street 75 meters, E 32,000 Gravel N/A 4.5 meters 360º N/A N/A N/A N/A N/A N/A 7th Street 75 meters, E 32,000 Gravel 96 Maricopa County Air Quality Department PINNACLE PEAK County ID: PP AQS ID: 04-013-2005 Address: 25000 N Windy Walk, Scottsdale Coordinates: 33.71231N – 111.85272W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 97 Ozone Continuous N/A No N/A 14 2 Yes Submitted July 2013 Bi-Weekly N/A API M400 (087) 02/01/1988 SLAMS FEM Max Ozone Concentration Urban Jan-Dec Yes N/A 5.9 meters 360º Teflon 6.2 sec N/A N/A N/A N/A Happy Valley Rd. 61 meters, S 16,000 Paved/Grass Maricopa County Air Quality Department RIO VERDE County ID: RV AQS ID: 04-013-9706 Address: 25608 N Forest Rd., Rio Verde Coordinates: 33.71881N – 111.67183W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 98 Ozone Continuous N/A No N/A 27 4 Yes Submitted July 2013 Bi-Weekly N/A API M400 (087) 01/01/1997 SLAMS FEM Max Ozone Concentration Urban Jan-Dec Yes N/A 6.2 meters 360º Teflon 9.7 sec N/A N/A N/A 16 meters, S Forest Rd 43 meters, E Unknown Paved Maricopa County Air Quality Department SOUTH PHOENIX County ID: SP AQS ID: 04-013-4003 Address: 33 W Tamarisk, Phoenix Coordinates: 33.40316N – 112.07533W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2.5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway A Distance and Direction to Road Traffic Count (ADT) Nearest Major Roadway B Distance and Direction to Road Traffic Count (ADT) Groundcover Ozone Continuous N/A CO Continuous N/A PM2.5 1 in 3 day Filters Weighed In-House PM2.5 Continuous N/A PM10 Continuous N/A No No No No No N/A N/A Yes Yes N/A 27 4 Yes 15 2 Yes N/A 3 Yes 24 3 Yes 24 2 Yes Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 N/A Every 6 Weeks Submitted July 2013 N/A Submitted July 2013 N/A Bi-Monthly API M400 (087) API M300 (093) Thermo 2025 Thermo TEOM 1400AB (079) 10/01/1999 SLAMS FEM 10/01/1999 SLAMS FRM 01/01/2005 SLAMS FRM Thermo FDMSTEOM 1405-DF (182) 05/01/2010 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Sep-Mar Yes Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes N/A 4.9 meters 360 Teflon 6.9 sec N/A N/A N/A N/A Central Ave 168 meters, E 24,000 Broadway Rd 385 meters, N 18,000 Paved N/A 4.9 meters 360 Teflon N/A N/A N/A N/A N/A Central Ave 168 meters, E 24,000 Broadway Rd 385 meters, N 18,000 Paved N/A 5.5 meters 360 N/A N/A N/A N/A N/A N/A Central Ave 168 meters, E 24,000 Broadway Rd 385 meters, N 18,000 Paved N/A 5.5 meters 360 N/A N/A N/A N/A N/A N/A Central Ave 168 meters, E 24,000 Broadway Rd 385 meters, N 18,000 Paved N/A 5.4 meters 360 N/A N/A N/A N/A N/A N/A Central Ave 165 meters, E 24,000 Broadway Rd 385 meters, N 13,000 Paved 2012 Air Monitoring Network Review 99 7/1/2007 SLAMS FEM Maricopa County Air Quality Department SOUTH SCOTTSDALE County ID: SS AQS ID: 04-013-3003 Address: 2857 N Miller Rd., Scottsdale Coordinates: 33.47968N – 111.91721W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2.5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway A Distance and Direction to Road Traffic Count (ADT) Nearest Major Roadway B Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review Ozone Continuous N/A No N/A CO Continuous N/A No N/A NO2 Continuous N/A No N/A SO2 Continuous N/A No N/A PM10 Continuous N/A No N/A 26 5 Yes 15 2 Yes 13 2 Yes 26 5 Yes 24 2 Yes Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 N/A Bi-Monthly API M400 (087) 01/01/1974 SLAMS FEM API M300 (093) 01/01/1974 SLAMS FRM API M200 (099) 10/01/1975 SLAMS FRM API M100 (100) 01/01/1984 SLAMS FEM TEOM 1405 (079) 09/01/2012 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Sep-Mar Yes Population Exposure Urban Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes N/A 5.8 meters 360 Teflon 7.3 sec N/A N/A N/A 14 meters, S Thomas 66 meters, N 33,000 Miller 32 meters, W 13,000 Paved N/A 5.8 meters 360 Teflon N/A N/A N/A N/A 14 meters, S Thomas 66 meters, N 33,000 Miller 32 meters, W 13,000 Paved N/A 5.8 meters 360 Teflon 7.3 sec N/A N/A N/A 14 meters, S Thomas 66 meters, N 33,000 Miller 32 meters, W 13,000 Paved N/A 5.8 meters 360 Teflon 12.1 sec N/A N/A N/A 14 meters, S Thomas 66 meters, N 33,000 Miller 32 meters, W 13,000 Paved 6.5 meters 6.1 meters 360 N/A N/A N/A N/A N/A 14 meters, S Thomas 62 meters, N 33,000 Miller 35 meters, W 13,000 Paved 100 Maricopa County Air Quality Department TEMPE County ID: TE AQS ID: 04-013-4005 Address: 1525 S College, Tempe Coordinates: 33.4124N – 111.93473W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2.5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Ozone Continuous N/A No N/A CO Continuous N/A No N/A PM10 Continuous N/A No N/A PM2.5 Continuous N/A No Yes 26 4 Yes Submitted July 2013 15 2 Yes Submitted July 2013 Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Bi-Weekly N/A Bi-Weekly N/A 22 4 Yes Submitted July 2013 N/A Bi-Weekly 16 4 Yes Submitted July 2013 N/A Bi-Weekly API M400 (087) API M300 (093) Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type 07/01/2000 SLAMS FEM 07/01/2000 SLAMS FRM Thermo TEOM 1400 AB (079) 3/1/2012 SLAMS FEM Thermo 1405 DF (182) 3/1/2012 SLAMS FEM Population Exposure Population Exposure Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway A Distance and Direction to Road Traffic Count (ADT) Neighborhood Jan-Dec Yes Neighborhood Sep-Mar Yes Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes N/A 4.4 meters 360 Teflon 4.5 sec N/A N/A N/A N/A College Ave 11 meters, W Unknown (secondary street) Apache 370 meters, N 25000 Gravel N/A 4.4 meters 360 Teflon N/A N/A N/A N/A N/A College Ave 11 meters, W Unknown (secondary street) Apache 370 meters, N 25000 Gravel N/A 2.7 meters 360 N/A N/A N/A N/A N/A N/A College Ave 11 meters, W Unknown (secondary street) Apache 370 meters, N 25000 Gravel N/A 3.7 meters 360 N/A N/A N/A N/A N/A N/A College Ave 11 meters, W Unknown (secondary street) Apache 370 meters, N 25000 Gravel Nearest Major Roadway B Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 101 Maricopa County Air Quality Department WEST CHANDLER County ID: WC AQS ID: 04-013-4004 Address: 275 S Ellis, Chandler Coordinates: 33.29898N – 111.88431W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements Ozone Continuous N/A No N/A CO Continuous N/A No N/A PM10 Continuous N/A No N/A # Precision Checks Performed Annually 26 15 24 # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? 4 Yes Submitted July 2013 Bi-Weekly N/A 2 Yes Submitted July 2013 Bi-Weekly N/A 2 Yes Submitted July 2013 N/A Monthly API M400 (087) API M300 (093) Thermo TEOM 1400 AB (079) 07/01/2000 SLAMS FEM 07/01/2000 SLAMS FRM 07/01/2000 SLAMS FRM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Sep-Mar Yes Population Exposure Middle Jan-Dec Yes N/A 4.4 meters 360º Teflon 4.6 sec N/A N/A N/A 14 meters, E Frye Rd 23 meters, S Unknown (secondary street) Ellis St 73 meters, W Unknown (secondary street) Paved/Gravel N/A 4.4 meters 360º Teflon N/A N/A N/A N/A 14 meters, E Frye Rd 23 meters, S Unknown (secondary street) Ellis St 73 meters, W Unknown (secondary street) Paved/Gravel N/A 4.4 meters 360º N/A N/A N/A N/A N/A 14 meters, E Frye Rd 25 meters, S Unknown (secondary street) Ellis St 71 meters, W Unknown (secondary street) Paved/Gravel Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway A Distance and Direction to Road Traffic Count (ADT) Nearest Major Roadway B Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 102 Maricopa County Air Quality Department WEST 43RD AVENUE County ID: WF AQS ID: 04-013-4009 Address: 3940 W Broadway, Phoenix Coordinates: 33.40642N – 112.14434W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 103 PM10 Continuous N/A No N/A 24 1 Yes Submitted July 2013 N/A Bi-Weekly Thermo TEOM 1400AB (079) 04/01/2002 SLAMS FEM Highest Concentrations Middle Jan-Dec Yes N/A 5 meters 360º N/A N/A N/A N/A N/A N/A Broadway Road 37 meters, SE Unknown Gravel Maricopa County Air Quality Department WEST PHOENIX County ID: WP AQS ID: 04-013-0019 Address: 3847 W Earll, Phoenix Coordinates: 33.48385N – 112.14257W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) PM2.5 Continuous N/A PM10 Continuous N/A No PM2.5 1 in 3 days Filters Weighed InHouse No No No N/A N/A Yes Yes N/A 26 26 25 23 24 4 3 4 26 (Collocated) 2 4 2 Yes Yes Yes Yes Yes Yes Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 Bi-Weekly N/A Submitted July 2013 N/A Every 6 weeks Submitted July 2013 N/A Bi-Weekly Submitted July 2013 N/A Bi-Weekly API M400 (087) API M300 (093) API M200 (099) Thermo 2025 BAM 1020 (170) BAM 1020 (122) 01/01/84 SLAMS FEM 01/01/84 SLAMS FRM 05/24/90 SLAMS FRM 06/13/00 SLAMS FRM 09/01/05 SLAMS FEM 02/01/88 SLAMS FEM Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes Highest Concentration Neighborhood Jan-Dec Yes Highest Concentration Neighborhood Jan-Dec Yes Population Exposure Neighborhood Jan-Dec Yes N/A N/A N/A 2.3 meters N/A N/A 4.3 meters 360 4.3 meters 360 4.3 meters 360 Probe Sample Line Material Pollutant Sample Residence Time Teflon Teflon Teflon 2.8 meter 360 N/A 3.6 meter 360 N/A 2.7 meters 360 N/A 4.4 sec N/A 4.4 sec N/A N/A N/A Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover N/A N/A N/A N/A Thomas 360 meters, S 29,000 Gravel N/A N/A N/A N/A Thomas 360 meters, S 29,000 Gravel N/A N/A N/A N/A Thomas 360 meters, S 29,000 Gravel N/A N/A N/A N/A Thomas 360 meters, S 29,000 Gravel N/A N/A N/A N/A Thomas 360 meters, S 29,000 Gravel N/A N/A N/A N/A Thomas 360 meters, S 29,000 Gravel Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Ozone Continuous N/A CO Continuous N/A NO2 Continuous N/A No No N/A 2012 Air Monitoring Network Review 104 Maricopa County Air Quality Department ZUNI HILLS County ID: ZH AQS ID: 04-013-4016 Address: 10851 West Williams Rd., Sun City, AZ Coordinates: 33.68674N, -112.29417W Metropolitan Sampling Area (MSA): 6200 Phoenix-Mesa -General Information Pollutant Sampling Schedule Analysis Method (filters only) Any Proposal to Remove or Move Monitor? Is site suitable for comparison to PM2 5 NAAQS per Part 58.30? -Appendix A Requirements # Precision Checks Performed Annually # Accuracy Checks Performed Annually All Precision/Accuracy Reports Submitted to AQS? Annual Data Certification Submitted? Frequency of One-Point QC Check Frequency of Flow Rate Verification -Appendix C Requirements Sampler Make & Model Date Established Classification Method (FRM, FEM, ARM) -Appendix D Requirements Monitoring Type Monitoring Scale Sampling Season Network Meets Minimum Number of Monitors Required? -Appendix E Requirements Distance between collocated samplers Probe Inlet Height Airflow Arc Probe Sample Line Material Pollutant Sample Residence Time Distance from Supporting Structure Distance from Obstructions Distance to Furnace Flue Spacing from Trees Nearest Major Roadway Distance and Direction to Road Traffic Count (ADT) Groundcover 2012 Air Monitoring Network Review 105 PM10 Continuous N/A No N/A 24 2 Yes Submitted July 2013 N/A Bi-Weekly Thermo TEOM 1400AB (079) 12/01/09 SPM FEM Population Exposure Neighborhood Scale Jan-Dec Yes N/A 2.3 meters 360º N/A N/A N/A N/A N/A N/A Williams Rd 200 meters, N Unknown (residential street) Lawn/Dirt Maricopa County Air Quality Department APPENDIX III - PUBLIC NOTICE AND COMMENT INFORMATION Public Notice Period To fulfill the requirements of 40CFR58 §58.10, the Maricopa County Air Quality Department posted a draft copy of this Network Review on its website on August 30, 2012. In an effort to notify the public of its network review, the department published information on a Network Review Public Workshop through the following outlets: • News item on department website. • Electronic feed to subscribers. • Public Notice posted in the Arizona Republic, a newspaper of general circulation in Maricopa County. News Release The following is a copy of the news release that was advertised in the Arizona Republic: Public Notice The Maricopa County Air Quality Department will hold a public meeting to discuss its 2012 Air Monitoring Network Review on October 23, 2013 at 1:00 p.m. The meeting will be held at the Air Monitoring Division’s offices at 2145 S. 11th Ave. suite 170, Phoenix, AZ 85007. A copy of the draft network review is currently available on the department’s website at the following website address: http://www.maricopa.gov/aq/divisions/monitoring/network.aspx Hard copies of the document may be requested from the department’s Records Management Coordinator at (602) 506-6201 or at the department's address: 1001 North Central Avenue, Phoenix, Arizona 85004. Arrangements may be made to view the information every Monday through Friday (excluding major holidays) between 8:00 a.m. and 4:30 p.m. There is a small fee for copying available documents. The 2012 Air Monitoring Network Review covers ambient air monitoring activity captured by the department’s 24 air monitoring sites throughout 2012. The Air Monitoring Network Review also provides a summary of the pollutants measured by Maricopa County, a look at the air monitoring network design and monitoring site details and statistics from the past year among other information. Additional information on the draft Air Monitoring Network Review may be obtained by contacting Ben Davis at 2145 S 11th Avenue #170, Phoenix, AZ 85007 or (602) 258-5155 x221. The purpose of the October 23, 2013 public meeting is to receive comments from the public on the draft Network Review. Members of the public may comment in person or through written statements to the department. 2012 Air Monitoring Network Review 106 Maricopa County Air Quality Department Written comments shall state the name and mailing address of the person making comment and be signed by that person or authorized agent or attorney. Written comments on the draft document are due to the department by October 23, 2013 at 5:00 p.m. A sign language and/or Spanish interpreter will be made available upon request with 72 hour notice. Additional reasonable accommodations will be made available to the extent possible within the time frame of the request. 2012 Air Monitoring Network Review 107 Maricopa County Air Quality Department Public Meeting Announcement: NEWS for immediate release MARICOPA CO UNTY Air Quality 1001 North Central Avenue Phoenix, p.z. 85004 Ph 602-506-6713 www ma.-icopa.gov 2012 Air Monitoring Network Review The Maricopa County Air Quality Department will hold a public meeting to discuss its 2012 Air Monitoring Network Review on October 23, 2013 at 1:00 p.m. The meeting will be held at the Air Monitoring Division's offices at 2145 S. 11th Ave., Suite 170, Phoenix, AZ 85007. A copy of the draft netv.•ork review is cwTently available on the department's website at the following website address: http://www.maricopa.gov/aq/ divisions /monitoring/network.aspx. Hard copies of the document may be requested from the department's Records Management Coordinator at (602) 506-6201 or at the department's address: 1001 North Central Avenue, Phoenix, Arizona 85004. Alrnngements may be made to view the infonnation every Monday through Friday (excluding major holidays) between 8:00 am. and 4:30 p.m. There is a small fee for copying available documents. The 2012 Air Monitoring Network Review covers ambient air monitoring activity captmed by the depa1tment's 24 air monitoring sites throughout 2012. The Air Monitoring Network Review also provides a summary of the pollutants measmed by Maricopa County, a look at the air monitoring netv.•ork design and monitoring site details and statistics from the past year among other infonnation. The purpose of the October 23, 2013 public meeting is to receive comments from the public on the draft Netv.•ork Review. Members of the public may comment in person or through written statements to the department. Written comments shall state the name and mailing address of the person making comment and be signed by that person or authorized agent or attomey. Written comments on the draft document are due to the deprutment by October 23, 2013 at 5:00 p.m. A sign language and/or Spanish interpreter will be made available dming the public meeting upon request. The department asks for 72 homs' notice in order to make necessa1y a1rnngements. Additional reasonable accommodations will be made available to the extent possible within the time frame of the request. Additional information on the Air Monitoring Network Review may be obtained by contacting Ben Davis at 2145 S 11th Ave., Suite 170, Phoenix, AZ 85007 or (602) 258-5155 x221. About M aricopa County Ail' Quality Department The Maricopa County Air Quality Deprutment is a regulat01y agency whose goal is to ensme federal clean air standards are achieved and maintained for the residents and visitors of Maricopa County. The deprutment is govemed by the Maricopa County Board of Supervisors and follows air quality standards set fo1th by the federal Clean Air Act. The department offers air quality infonnation and resomces on its Clean Air Make More website. Visit www.CleanAirMakeMore.com to lerun more. Follow us on Twitter: http://twitter.com/cleanainnakemor Friend us on Facebook: www.facebook.com/CleanAirMakeMore 2012 Air Monitoring Network Review 108 Maricopa County Air Quality Department Attendees List: 2012 Air Monitoring Network Review 109 Maricopa County Air Quality Department