2011 Periodic Emissions Inventory for Ozone Precursors for the Maricopa County, Arizona, Eight-Hour Ozone Nonattainment Area February 2014 Foreword Maricopa County Air Quality Department released a draft version of this document, its 2011 emission inventory of ozone precursors, for a 30-day public review period on January 22, 2014. (The department’s news release to announce the availability of the draft report, which outlines the schedule for public review and comment, is contained in Appendix D, along with a copy of the department’s calendar item providing details on the workshop). The department held a public workshop on February 14, 2014 to discuss the draft inventory. No formal comments were received during the 30-day public review period. Maricopa County Air Quality Department Emissions Inventory Unit 1001 N. Central Avenue, Suite 595 Phoenix, AZ 85004 e-mail: EmisInv@mail.maricopa.gov 2011 Periodic Emissions Inventory for Ozone Precursors for the Maricopa County, Arizona Eight-Hour Ozone Nonattainment Area February 2014 Table of Contents 1. Introduction .....................................................................................................................................1 1.1 1.2 1.3 1.4 1.5 1.6 Overview .......................................................................................................................................1 Agencies responsible for the emissions inventory........................................................................1 Temporal scope .............................................................................................................................2 Geographic scope ..........................................................................................................................2 Overview of local demographic and land use data .......................................................................3 1.5.1 Demographic profile ..........................................................................................................3 1.5.2 Land use data .....................................................................................................................3 Emissions overview by source category .......................................................................................4 1.6.1 Point sources ......................................................................................................................4 1.6.2 Area sources .......................................................................................................................4 1.6.3 Nonroad mobile sources ....................................................................................................5 1.6.4 Onroad mobile sources ......................................................................................................6 1.6.5 Biogenic sources ................................................................................................................6 1.6.6 Summary of all source categories ......................................................................................7 2. Point Sources .................................................................................................................................11 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 Introduction and scope ................................................................................................................11 Identification of point sources ....................................................................................................11 Procedures for estimating emissions from point sources............................................................12 2.3.1 Application of rule effectiveness .....................................................................................13 Detailed overview of point source emissions .............................................................................13 Emission reduction credits ..........................................................................................................13 Summary of point source emissions ...........................................................................................14 Quality assurance/quality control procedures .............................................................................14 2.7.1 Emission survey preparation and data collection .............................................................14 2.7.2 Submission processing .....................................................................................................15 2.7.3 Analysis of annual point source emissions data for this inventory ..................................16 References ...................................................................................................................................16 3. Area Sources ..................................................................................................................................17 3.1 3.2 Scope and methodology ..............................................................................................................17 Fuel combustion..........................................................................................................................19 3.2.1 Industrial distillate oil ......................................................................................................19 3.2.2 Industrial natural gas ........................................................................................................20 3.2.3 Commercial/institutional distillate oil..............................................................................21 3.2.4 Commercial/institutional natural gas ...............................................................................21 2011 Ozone Precursor Emissions Inventory i February 2014 3.3 3.4 3.5 3.6 3.7 3.2.5 Residential distillate oil....................................................................................................22 3.2.6 Residential natural gas .....................................................................................................23 3.2.7 Residential liquefied petroleum gas (LPG)......................................................................23 3.2.8 Residential kerosene ........................................................................................................24 3.2.9 Residential wood combustion ..........................................................................................24 Industrial processes .....................................................................................................................25 3.3.1 Chemical manufacturing ..................................................................................................25 3.3.2 Food and kindred products...............................................................................................26 3.3.2.1 Commercial cooking..........................................................................................26 3.3.2.2 Bakeries .............................................................................................................27 3.3.3 Secondary metal production ............................................................................................28 3.3.4 Rubber/plastics product manufacturing ...........................................................................28 3.3.5 Electrical equipment manufacturing ................................................................................29 3.3.6 Industrial processes not elsewhere classified (NEC) .......................................................30 Solvent use ..................................................................................................................................30 3.4.1 Surface coating.................................................................................................................30 3.4.1.1 Architectural coatings ........................................................................................30 3.4.1.2 Auto refinishing .................................................................................................31 3.4.1.3 Traffic markings ................................................................................................31 3.4.1.4 Factory-finished wood .......................................................................................32 3.4.1.5 Wood furniture ..................................................................................................33 3.4.1.6 Aircraft surface coating .....................................................................................34 3.4.1.7 Miscellaneous surface coating ...........................................................................34 3.4.2 Degreasing .......................................................................................................................35 3.4.3 Dry cleaning .....................................................................................................................36 3.4.4 Graphic arts ......................................................................................................................36 3.4.5 Miscellaneous industrial solvent use................................................................................37 3.4.6 Consumer and commercial products ................................................................................38 3.4.7 Asphalt application ..........................................................................................................38 3.4.8 Agricultural pesticides .....................................................................................................40 Storage and transport ..................................................................................................................40 3.5.1 Portable fuel containers ....................................................................................................40 3.5.2 Bulk plants .......................................................................................................................41 3.5.3 Gasoline stations (Stage I) ...............................................................................................42 3.5.4 Gasoline stations (Stage II) ..............................................................................................42 3.5.5 Gasoline stations underground tanks, breathing/emptying ..............................................43 3.5.6 Airports: Aviation gasoline ..............................................................................................43 3.5.7 Gasoline tank trucks in transit..........................................................................................44 3.5.8 Pipeline gasoline ..............................................................................................................44 3.5.9 Volatile organic liquid (VOL) storage and transport .......................................................45 Waste treatment and disposal .....................................................................................................45 3.6.1 On-site incineration ..........................................................................................................45 3.6.2 Open burning: Land clearing debris ................................................................................46 3.6.3 Landfills ...........................................................................................................................47 3.6.4 Publicly owned treatment works ......................................................................................47 3.6.5 Leaking underground storage tanks .................................................................................48 3.6.6 Other waste ......................................................................................................................48 Miscellaneous area sources .........................................................................................................49 3.7.1 Agricultural field burning ................................................................................................49 2011 Ozone Precursor Emissions Inventory ii February 2014 3.7.2 Structure fires ...................................................................................................................50 3.7.3 Aircraft engine testing......................................................................................................51 3.7.4 Vehicle fires .....................................................................................................................51 3.7.5 Crematories ......................................................................................................................52 3.7.6 Accidental releases ...........................................................................................................52 3.7.7 Hospitals ..........................................................................................................................53 3.7.8 Wildfires ..........................................................................................................................53 3.7.9 Prescribed fires .................................................................................................................55 3.8 Summary of all area sources .......................................................................................................57 3.9 Quality assurance / quality control procedures ...........................................................................60 3.10 References ...................................................................................................................................62 4. Nonroad Mobile Sources ..............................................................................................................65 4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 4.9 4.10 4.11 4.12 4.13 4.14 4.15 Introduction.................................................................................................................................65 Agricultural equipment ...............................................................................................................66 Airport ground support equipment .............................................................................................67 Commercial equipment ...............................................................................................................68 Construction and mining equipment ...........................................................................................68 Industrial equipment ...................................................................................................................69 Lawn and garden equipment .......................................................................................................69 Pleasure craft...............................................................................................................................70 Railway maintenance equipment ................................................................................................70 Recreational equipment ..............................................................................................................71 Aircraft ........................................................................................................................................71 Locomotives................................................................................................................................77 Summary of all nonroad mobile source emissions .....................................................................78 Quality assurance procedures .....................................................................................................79 References ...................................................................................................................................79 5. Onroad Mobile Sources ................................................................................................................81 5.1 5.2 Introduction.................................................................................................................................81 Onroad emissions ........................................................................................................................81 5.2.1 MOVES2010b model.......................................................................................................82 5.2.2 MOVES2010b local input data ........................................................................................82 5.2.2.1 Fuel data ............................................................................................................82 5.2.2.2 I/M programs .....................................................................................................82 5.2.2.3 Meteorological data ...........................................................................................83 5.2.2.4 Vehicle population .............................................................................................83 5.2.2.5 Source type age distribution ..............................................................................83 5.2.2.6 Annual VMT......................................................................................................83 5.2.2.7 Road type distribution .......................................................................................84 5.2.2.8 VMT fraction .....................................................................................................84 5.2.2.9 Average speed distribution ................................................................................85 5.2.2.10 Ramp fraction ....................................................................................................85 5.2.2.11 AVFT strategy ...................................................................................................85 5.2.2.12 Stage II refueling control programs ...................................................................85 5.2.3 MOVES2010b outputs .....................................................................................................86 5.2.4 MOVES2010b emission estimates ..................................................................................86 2011 Ozone Precursor Emissions Inventory iii February 2014 5.3 5.4 5.5 Summary of ozone precursor emissions from onroad mobile sources .......................................95 Quality assurance process ...........................................................................................................97 5.4.1 VMT estimates .................................................................................................................97 5.4.2 Emission estimates ...........................................................................................................97 5.4.3 Draft emissions inventory for ozone precursors ..............................................................97 References ...................................................................................................................................97 6. Biogenic Sources ............................................................................................................................99 6.1 6.2 6.3 6.4 6.5 6.6 Introduction.................................................................................................................................99 Modeling domain ........................................................................................................................99 Input data ....................................................................................................................................99 6.3.1 Land cover data ..............................................................................................................100 6.3.2 Weather data ..................................................................................................................100 Emission estimation ..................................................................................................................101 Summary of biogenic source emissions....................................................................................105 References .................................................................................................................................106 List of Tables Table 1.2–1. Table 1.5–1. Table 1.5–2. Table 1.6–1. Table 1.6–2. Table 1.6–3. Table 1.6–4. Table 1.6–5. Table 1.6–6. Table 1.6–7. Table 1.6–8. Table 1.6–9. Table 2.2–1. Table 2.4–1. Table 2.5–1. Table 2.6–1. Table 3.1–1. Table 3.2–1. Table 3.2–2. Table 3.2–3. Chapter authors and QA/QC contacts for this report. ....................................................1 Demographic profile of Maricopa County and the eight-hour ozone NAA. ..................3 Land use categories used to apportion emissions. ..........................................................4 Annual and season-day emissions from point sources. ..................................................4 Annual and season-day emissions from area sources in Maricopa County. ..................5 Annual and season-day emissions from area sources in the eight-hour ozone NAA.....5 Annual and season-day emissions from nonroad mobile sources in Maricopa County. ...........................................................................................................................5 Annual and season-day emissions from nonroad mobile sources in the eight-hour ozone NAA. ....................................................................................................................6 Annual and season-day emissions from onroad mobile sources in Maricopa County and the eight-hour ozone NAA. .........................................................................6 Annual and season-day emissions from biogenic sources in Maricopa County and the eight-hour ozone NAA. ............................................................................................6 Annual and season-day emissions from all sources in Maricopa County. .....................7 Annual and season-day emissions from all sources in the eight-hour ozone nonattainment area. ........................................................................................................9 Name and location of all point sources in Maricopa County. ......................................12 Annual and season-day point source emissions, by facility. ........................................13 Emission reduction credits as of December 31, 2011. .................................................14 Annual and season-day point source emissions (including emission reduction credits). .........................................................................................................................14 List of area source categories included in this ozone precursor inventory...................17 Maricopa County natural gas sales by end-user category and supplier. ......................19 Annual and season-day emissions from area-source industrial distillate oil combustion for boilers. .................................................................................................20 Annual and season-day emissions from area-source industrial distillate oil combustion for engines. ...............................................................................................20 2011 Ozone Precursor Emissions Inventory iv February 2014 Table 3.2–4. Natural gas usage, emission factors, and annual emissions from area-source industrial natural gas consumption, by combustion type. ............................................20 Table 3.2–5. Annual and season-day emissions from area-source industrial natural gas combustion. ..................................................................................................................21 Table 3.2–6. Annual and season-day emissions from area-source commercial/institutional distillate oil combustion for boilers. .............................................................................21 Table 3.2–7. Annual and season-day emissions from area-source commercial/institutional distillate oil combustion for engines. ...........................................................................21 Table 3.2–8. Emission factors and annual emissions from area-source commercial/institutional natural gas combustion, by combustion type. ..............................................................22 Table 3.2–9. Annual and season-day emissions from area-source commercial/institutional natural gas combustion. ................................................................................................22 Table 3.2–10. Annual and season-day emissions from residential distillate oil combustion. .............23 Table 3.2–11. Residential natural gas combustion emission factors. ..................................................23 Table 3.2–12. Annual and season-day emissions from residential natural gas combustion. ..............23 Table 3.2–13. Annual and season-day emissions from residential liquefied petroleum gas (LPG) combustion. ..................................................................................................................24 Table 3.2–14. Annual and season-day emissions from residential kerosene combustion...................24 Table 3.2–15. Annual emissions by appliance type for Maricopa County from EPA’s residential wood combustion estimation tool.................................................................................25 Table 3.2–16. Annual and season-day emissions from residential wood combustion. .......................25 Table 3.3–1. County-level employment estimates for chemical manufacturing, by NAICS code. ..26 Table 3.3–2. Annual and season-day emissions from area-source chemical manufacturing. ...........26 Table 3.3–3. Emission factors for commercial cooking equipment, by device type. ........................26 Table 3.3–4. Annual and daily emissions from commercial cooking equipment in Maricopa County. .........................................................................................................................27 Table 3.3–5. Annual and daily emissions from commercial cooking equipment in the eight-hour ozone NAA. ..................................................................................................................27 Table 3.3–6. Annual and season-day emissions from area-source bakeries. ....................................28 Table 3.3–7. Annual and season-day emissions from area-source secondary metal production. .....28 Table 3.3–8. County-level employment estimates for rubber and plastic product manufacturing, by NAICS code. ...........................................................................................................29 Table 3.3–9. Annual and season-day emissions from area-source rubber/plastic product manufacturing. ..............................................................................................................29 Table 3.3–10. Annual and season-day emissions from area-source electric equipment manufacturing. ..............................................................................................................30 Table 3.3–11. Annual and season-day emissions from industrial processes not elsewhere classified. ......................................................................................................................30 Table 3.4–1. Annual and season-day emissions from architectural coating. ....................................31 Table 3.4–2. County-level employment estimates for auto refinishing, by NAICS code. ................31 Table 3.4–3. Annual and season-day emissions from auto refinishing. ............................................31 Table 3.4–4. Annual and season-day emissions from traffic markings. ...........................................32 Table 3.4–5. County-level employment estimates for factory-finished wood coating, by NAICS code. .............................................................................................................................32 Table 3.4–6. Annual and season-day emissions from area-source factory-finished wood surface coating. .........................................................................................................................33 Table 3.4–7. County-level employment estimates for wood furniture surface coating, by NAICS code. ................................................................................................................33 2011 Ozone Precursor Emissions Inventory v February 2014 Table 3.4–8. Annual and season-day emissions from area-source wood furniture surface coating. .........................................................................................................................34 Table 3.4–9. Annual and season-day VOC emissions from area-source aircraft surface coating. ...34 Table 3.4–10. Annual and season-day emissions from miscellaneous surface coating. .....................35 Table 3.4–11. Annual and season-day VOC emissions from area-source degreasing. .......................35 Table 3.4–12. Annual and season-day emissions from dry cleaning. .................................................36 Table 3.4–13. County-level employment estimates for graphic arts, by NAICS code. ......................36 Table 3.4–14. Annual and season-day VOC emissions from area-source graphic arts sources. ........37 Table 3.4–15. Annual and season-day emissions from area-source miscellaneous industrial solvent use. ...................................................................................................................38 Table 3.4–16. Annual and season-day emissions from consumer and commercial products. ............38 Table 3.4–17. 2008 and 2011 population and VMT, by geographic area. ..........................................39 Table 3.4–18. Emissions from asphalt use, by type, in Maricopa County. .........................................39 Table 3.4–19. Emissions from asphalt use, by type, in the eight-hour ozone NAA. .........................39 Table 3.4–20. Annual and season-day emissions from agricultural pesticide application. .................40 Table 3.5–1. Annual and season-day emissions from portable fuel containers (PFCs). ...................41 Table 3.5–2. Annual and season-day emissions from bulk plants. ...................................................42 Table 3.5–3. Emission factors for gasoline service stations (Stage I). ..............................................42 Table 3.5–4. Annual and season-day emissions from gasoline service stations (Stage I). ...............42 Table 3.5–5. Annual and season-day emissions from gasoline service stations underground tank, breathing and emptying. ......................................................................................43 Table 3.5–6. Annual emissions from aviation gasoline for Maricopa County. .................................43 Table 3.5–7. Annual and season-day emissions from aviation gasoline. ..........................................44 Table 3.5–8. Annual and season-day emissions from gasoline trucks in transit. ..............................44 Table 3.5–9. Annual and season-day emissions from pipeline gasoline. ..........................................45 Table 3.5–10. Annual and season-day emissions from area-source volatile organic liquid storage/transport. ..........................................................................................................45 Table 3.6–1. Annual and season-day emissions from on-site incineration. ......................................46 Table 3.6–2. Maricopa County burn permit activity. ........................................................................46 Table 3.6–3. Emission and fuel loading factors for open burning. ...................................................46 Table 3.6–4. Annual and season-day emissions from land clearance and fire hazard open burning..........................................................................................................................47 Table 3.6–5. Annual and season-day emissions from landfills. ........................................................47 Table 3.6–6. VOC emissions from publicly owned treatment works. ..............................................48 Table 3.6–7. Annual and season-day emissions from remediation of leaking underground storage tanks. ................................................................................................................48 Table 3.6–8. Annual and season-day emissions from other waste. ...................................................49 Table 3.7–1. Emission factors for open burning. ..............................................................................49 Table 3.7–2. Annual and season-day emissions from ditchbank and fence row burning. ................50 Table 3.7–3. Maricopa County population growth, 2008 to 2011. ...................................................50 Table 3.7–4. 2008 and 2011 annual emissions from structure fires in Maricopa County. ................50 Table 3.7–5. Annual and season-day emissions from structure fires. ...............................................51 Table 3.7–6. Annual and season-day emissions from aircraft engine testing. ..................................51 Table 3.7–7. 2008 and 2011 annual emissions from vehicle fires in Maricopa County. ..................51 Table 3.7–8. Annual and season-day emissions from vehicle fires. .................................................51 Table 3.7–9. County-level employment estimates for crematories, by NAICS code. ......................52 Table 3.7–10. Annual and season-day emissions from crematories. ..................................................52 Table 3.7–11. Annual and season-day emissions from accidental releases. .......................................53 Table 3.7–12. Annual and season-day emissions from hospitals. .......................................................53 2011 Ozone Precursor Emissions Inventory vi February 2014 Table 3.7–13. Table 3.7–14. Table 3.7–15. Table 3.7–16. Table 3.7–17. Table 3.7–18. Table 3.7–19. Table 3.7–20. Table 3.7–21. Table 3.8–1. Table 3.8–2. Table 4.1–1. Table 4.1–2. Table 4.2–1. Table 4.3–1. Table 4.3–2. Table 4.4–1. Table 4.5–1. Table 4.6–1. Table 4.7–1. Table 4.8–1. Table 4.9–1. Table 4.10–1. Table 4.11–1. Table 4.11–2. Table 4.11–3. Table 4.11–4. Table 4.12–1. Table 4.12–2. Table 4.12–3. Table 4.12–4. Table 4.13–1. Table 4.13–2. Table 5.2–1. Table 5.2–2. Table 5.2–3. Table 5.3–1. Table 5.3–2. 2011 wildfire activity in Maricopa County. .................................................................54 Data used to estimate 2011 wildfire emissions. ...........................................................54 Summary of 2011 wildfires, acres burned, and estimate of material burned. ..............54 Emission factors for wildfires and prescribed broadcast burning. ...............................55 Annual emissions from wildfires. ................................................................................55 Season-day emissions from wildfires. ..........................................................................55 2011 prescribed fire activity in Maricopa County........................................................56 Emission factors for prescribed fire (piled fuels). ........................................................56 Annual and season-day emissions from prescribed fires. ............................................56 Annual and season-day emissions from all area sources in Maricopa County. ...........57 Annual and season-day emissions from all area sources in the eight-hour ozone NAA. ............................................................................................................................59 NONROAD2008 model county temperature and fuel-related inputs. .........................65 Default weekday and weekend day activity allocation fractions. ................................66 Annual and season-day emissions from agricultural equipment. .................................67 Annual emissions (tons/yr) from airport ground support equipment (GSE) and auxiliary power units (APUs). ......................................................................................68 Season-day emissions (lbs/day) from airport GSE and APU. ......................................68 Annual and season-day emissions from commercial equipment. ................................68 Annual and season-day emissions from construction and mining equipment. ............69 Annual and season-day emissions from industrial equipment. ....................................69 Annual and season-day emissions from lawn and garden equipment. .........................70 Annual and season-day emissions from pleasure craft equipment...............................70 Annual and season-day emissions from railway maintenance equipment. ..................70 Annual and season-day emissions from recreational equipment. ................................71 Annual airport operations (by aircraft category) and related data sources...................73 Growing aircraft-specific activity for EDMS modeling input. ....................................75 Annual and season-day emissions, by aircraft type, for airports in the eight-hour ozone NAA. ..................................................................................................................76 Annual and season-day emissions, by aircraft type, for airports outside the eighthour ozone NAA. .........................................................................................................77 Emission factors for locomotives. ................................................................................77 Fuel use and annual emissions from locomotives in Maricopa County. ......................77 Annual emissions from locomotives in the eight-hour ozone NAA. ...........................77 Season-day emissions from locomotives in Maricopa County and the eight-hour ozone NAA. ..................................................................................................................78 Annual and season-day emissions from nonroad mobile sources in Maricopa County. .........................................................................................................................78 Annual and season-day emissions from nonroad mobile sources in the eight-hour ozone NAA. ..................................................................................................................78 2011 daily VMT by facility type (annual average daily traffic). .................................84 Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in the eight-hour ozone NAA. .................................................................87 Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in Maricopa County. ...............................................................................91 Annual and ozone season-day onroad mobile source emissions by facility type in the eight-hour ozone NAA. ..........................................................................................95 Annual and ozone season-day onroad mobile source emissions by facility type in Maricopa County. .........................................................................................................95 2011 Ozone Precursor Emissions Inventory vii February 2014 Table 5.3–3. Annual and ozone season-day onroad mobile source emissions by vehicle class in the eight-hour ozone NAA. ..........................................................................................96 Table 5.3–4. Annual and ozone season-day onroad mobile source emissions by vehicle class in Maricopa County. .........................................................................................................96 Table 5.3–5. Annual and ozone season-day emissions from all onroad mobile sources in the eight-hour ozone NAA and Maricopa County. ............................................................96 Table 6.2–1. Two modeling domains defined in the LCP coordinate system. ..................................99 Table 6.4–1. Daily mean biogenic emissions for each month in the eight-hour ozone NAA. ........102 Table 6.4–2. Daily mean biogenic emissions for each month in Maricopa County. ......................103 Table 6.4–3. Monthly biogenic emissions in the eight-hour ozone NAA. ......................................105 Table 6.4–4. Monthly biogenic emissions in Maricopa County. ....................................................105 Table 6.5–1. Season-day biogenic emissions. .................................................................................106 Table 6.5–2. Annual biogenic emissions. ........................................................................................106 List of Figures Map of Maricopa County and the eight-hour ozone nonattainment area. ......................2 Data flow for annual point source emissions inventory reporting. ..............................15 The masked grid cells in the 4-km modeling domain. ...............................................100 Monthly averaged temperature (left panel) and annual mean diurnal cycle of temperature (right panel) in 2011. ..............................................................................101 Figure 6.3–3. Monthly averaged radiation (left panel) and annual mean diurnal cycle of radiation (right panel) in 2011. ...................................................................................101 Figure 6.4–1. Estimated emission rates of ISOP (left panel) and NOx (right panel) at 17:00 MST, August 2011 by MEGAN model. ...............................................................................102 Figure 6.4–2. Monthly emissions of VOC (top), NOx (middle) and CO (bottom) in Maricopa County (pink solid line, abbreviated as “County”) and the eight-hour ozone NAA (blue solid line, abbreviated as “O3 NAA”)...............................................................104 Figure 1.4–1. Figure 2.7–1. Figure 6.3–1. Figure 6.3–2. 2011 Ozone Precursor Emissions Inventory viii February 2014 Appendices Appendix A Instructions for Reporting 2011 Annual Air Pollution Emissions Appendix B Rule Effectiveness Studies B.1 Introduction B.2 Calculating Rule Effectiveness Rates for Title V Facilities and Non-Title V Facilities B.3 References Appendix C MOVES2010b Local Input Data and RunSpecs MOVES2010b RunSpec Summary (Maricopa County, December 2011) MOVES2010b RunSpec (Maricopa County, December 2011) MOVES2010b Local Input Data (Maricopa County, December 2011) Appendix D Public Comment Period Documentation 2011 Ozone Precursor Emissions Inventory ix February 2014 1. Introduction 1.1 Overview This 2011 periodic ozone emissions inventory was developed to meet requirements set forth in Title I of the Clean Air Act Amendments of 1990 (CAAA). The CAAA require development of a baseline emissions inventory and periodic revisions for areas that fail to meet the National Ambient Air Quality Standards (NAAQS). A portion of Maricopa County is classified as nonattainment for the eight-hour ozone standard. This inventory includes emission estimates for three ozone precursors: volatile organic compounds (VOCs), carbon monoxide (CO) and nitrogen oxides (NOx). VOC is defined by Maricopa County’s Rule 100 as “any organic compound, which participates in atmospheric photochemical reactions, except the non-precursor organic compounds”. The inventory provides emission estimates from point, area, nonroad mobile, onroad mobile, and biogenic sources. Note that totals shown in tables may not equal the sum of individual values due to independent rounding. 1.2 Agencies responsible for the emissions inventory Maricopa County Air Quality Department (MCAQD) has primary responsibility for preparing and submitting the 2011 Periodic Emissions Inventory for Ozone Precursors for Maricopa County. Point, area, and some nonroad mobile source emission estimates were prepared by MCAQD. The Maricopa Association of Governments (MAG) prepared the emission estimates for onroad mobile, biogenic, and the majority of nonroad mobile sources. Table 1.2–1 lists those responsible for inventory preparation and quality assurance/quality control activities, which are described in the respective chapters. Table 1.2–1. Chapter authors and QA/QC contacts for this report. Chapter Author(s) QA/QC contact persons 2. Point sources Bob Downing, MCAQD (602) 506-6790 Eric Raisanen, MCAQD (602) 506-6790 3. Area sources 4. Nonroad mobile sources 5. Onroad mobile sources 6. Biogenic sources Eric Raisanen, Tom Ekren and Dena Konopka, MCAQD (602) 506-6790 Matt Poppen, MAG (602) 254-6300 Dena Konopka, MCAQD (602) 506-6790 Ieesuck Jung, MAG (602) 254-6300 Feng Liu, MAG (602) 254-6300 2011 Ozone Precursor Emissions Inventory 1 Matt Poppen, MAG (602) 254-6300 Bob Downing, MCAQD (602) 506-6790 Matt Poppen, MAG (602) 254-6300 Cathy Arthur, MAG (602) 254-6300 Bob Downing, MCAQD (602) 506-6790 Cathy Arthur, MAG (602) 254-6300 Matt Poppen, MAG (602) 254-6300 Cathy Arthur, MAG (602) 254-6300 Matt Poppen, MAG (602) 254-6300 Cathy Arthur, MAG (602) 254-6300 February 2014 1.3 Temporal scope Annual and ozone season-day emissions were estimated for the year 2011, for Maricopa County and the Maricopa County eight-hour ozone nonattainment area (NAA). The three-month peak ozone season for the Maricopa County nonattainment area has been defined as July 1 through September 30, based on the 1981–1991 pattern of ozone exceedances. 1.4 Geographic scope This inventory includes emission estimates for Maricopa County and for the Maricopa County eight-hour ozone nonattainment area. Maricopa County encompasses approximately 9,223 square miles of land area, while the Maricopa County eight-hour ozone nonattainment area is approximately 5,018 square miles or about 54 percent of the Maricopa County land area.1 A portion of the southeastern boundary of the eight-hour ozone nonattainment area includes areas of Pinal County totaling 48 square miles or 0.96% of the nonattainment area. A map of Maricopa County and the eight-hour ozone nonattainment area is provided in Figure 1.4–1. Figure 1.4–1. Map of Maricopa County and the eight-hour ozone nonattainment area. 1. In May 2012, EPA designated a new eight-hour ozone nonattainment area based on the 2008 eight-hour ozone NAAQS (77 FR 30088, May 12, 2012). The previous eight-hour ozone nonattainment area was based on the 1997 eight-hour ozone NAAQS. The 2012 nonattainment area boundary was used for this 2011 inventory, as it is expected to be used as a base-year inventory for a future state implementation plan. 2011 Ozone Precursor Emissions Inventory 2 February 2014 1.5 Overview of local demographic and land use data Many of the emissions estimates generated in this report were calculated using demographic and land use data provided by the Maricopa Association of Governments (MAG). These data were used to apportion and/or scale Maricopa County emissions estimates to the nonattainment area and vice versa. (For example, county-level emissions from residential natural gas usage in Maricopa County were apportioned to the nonattainment area using the ratio of total population in each area). Detailed explanations of how emission estimates were apportioned or scaled are presented in each of the following chapters, along with the data sources used. 1.5.1 Demographic profile The demographic data provided by MAG included population, employment data, and single family/multi-family splits for calendar year 2011, for both Maricopa County and the eight-hour ozone nonattainment area. Table 1.5–1 provides an overview of the key demographic data used in this report. As noted throughout the text, these data are frequently used to derive estimates of activity or emissions within the eight-hour ozone nonattainment area from county-level calculations. It is important to note, however, that the nonattainment area includes a portion of Pinal County, AZ as shown in Figure 1.4–1. Thus in some cases (e.g., those source categories calculated based on total population), the multiplier used to derive nonattainment area estimates from County-level values may be greater than 1, and thus the resulting NAA emission totals are larger than the County-level estimates from which they are derived. Table 1.5–1. Demographic profile of Maricopa County and the eight-hour ozone NAA. 8-hr ozone Percentage within Demographic variable Maricopa County NAA 8-hr ozone NAA Total resident population 3,843,370 3,873,528 100.78% Total non-resident population 286,276 303,342 105.96% Total population: 4,129,646 4,176,870 101.14% Retail employment Office employment Industrial employment Public employment Other employment Construction Work at home Total employment: Single-family/multi-family household split: Single-family Multi-family 1.5.2 414,477 320,536 374,338 240,952 261,769 24,026 100,016 1,736,114 415,672 320,189 372,731 241,429 258,963 24,791 100,617 1,734,392 77% 23% 100.29% 99.89% 99.57% 100.20% 98.93% 103.18% 100.60% 99.90% 77% 23% Land use data MAG provided draft 2010 land use data. The 2010 land use data was assumed to be representative of 2011. Table 1.5–2 presents a summary of the land use categories and acreage used to develop emission estimates for this inventory. 2011 Ozone Precursor Emissions Inventory 3 February 2014 Table 1.5–2. Land use categories used to apportion emissions. Acreage within Maricopa Land use category County General/active open space/golf course (e.g., parks) 210,159 Passive/restricted open space, washes 2,614,870 Lakes 12,525 Agriculture 276,016 Vacant (e.g., developable land) 2,045,587 1.6 Emissions overview by source category 1.6.1 Point sources Acreage within 8-hour ozone NAA 211,297 1,188,251 12,525 161,371 911,304 Percentage within 8-hour ozone NAA 100.54% 45.44% 100.00% 58.46% 44.55% The point source category includes those stationary sources that emit a significant amount of pollution into the air such as power plants, petroleum product storage and transfer facilities, and large industrial facilities. MCAQD utilizes the US EPA’s Annual Emissions Reporting Requirements (AERR) rule to define which stationary sources are listed as point sources. A detailed definition of a point source can be found in Section 2.1 of Chapter 2. Table 1.6–1 summarizes annual and season-day emissions from point sources (including emission reduction credits) in Maricopa County and the eight-hour ozone nonattainment area, respectively. A detailed breakdown of emissions calculations for all point sources is contained in Chapter 2. Table 1.6–1. Annual and season-day emissions from point sources. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 768.54 1,754.12 1,078.48 4,908.3 15,407.1 9,715.8 8-hour ozone NAA 768.54 1,754.12 1,078.48 4,908.3 15,407.1 9,715.8 1.6.2 Area sources Area sources are facilities or activities whose individual emissions do not qualify them as point sources. Area sources represent numerous facilities or activities that individually release small amounts of a given pollutant, but collectively they can release significant amounts of a pollutant. Emissions from stationary sources that were not identified as point sources in this report have been included in the area source inventory. Examples of area source categories include residential wood burning, commercial cooking, waste incineration and wildfires. Tables 1.6–2 and 1.6–3 summarize annual and season-day emissions of the chief area source categories, for Maricopa County and the eight-hour ozone nonattainment area, respectively. A detailed breakdown of emissions calculations for each area source category is contained in Chapter 3. 2011 Ozone Precursor Emissions Inventory 4 February 2014 Table 1.6–2. Annual and season-day emissions from area sources in Maricopa County. Annual emissions (tons/yr) Season-day emissions (lbs/day) Source category VOC NOx CO VOC NOx CO Fuel combustion 653.61 4,675.41 4,866.67 593.3 23,544.5 9,255.2 Industrial processes 2,284.00 263.41 585.79 17,516.5 1,489.5 3,396.2 Solvent use 28,153.45 167,043.9 Storage/transport 5,176.39 28,577.9 Waste treatment/disposal 115.61 56.21 193.56 842.6 320.7 1,227.1 Misc. area sources 271.58 166.54 4,765.93 13,982.3 6,680.5 281,693.1 All area sources: 36,654.65 5,161.56 10,411.95 228,556.4 32,035.2 295,571.5 Table 1.6–3. Annual and season-day emissions from area sources in the eight-hour ozone NAA. Annual emissions (tons/yr) Season-day emissions (lbs/day) Source category VOC NOx CO VOC NOx CO Fuel combustion 659.63 4,670.68 4,898.99 593.0 23,483.5 9,235.4 Industrial processes 2,276.48 263.41 590.27 17,452.4 1,489.5 3,420.8 Solvent use 28,139.77 166,557.4 Storage/transport 5,211.35 28,766.2 Waste treatment/disposal 116.10 56.04 190.06 837.8 315.6 1,119.6 Misc. area sources 261.09 161.70 4,664.71 13,650.0 6,531.8 278,544.9 All area sources: 36,664.42 5,151.83 10,344.03 227,856.8 31,820.5 292,320.7 1.6.3 Nonroad mobile sources Nonroad mobile sources include off-highway vehicles and engines that move or are moved within a 12-month period. Tables 1.6–4 and 1.6–5 summarize annual and season-day emissions from nonroad mobile sources, for Maricopa County and the eight-hour ozone nonattainment area, respectively. A detailed breakdown of emissions calculations for each source category is contained in Chapter 4. Table 1.6–4. Annual and season-day emissions from nonroad mobile sources in Maricopa County. Annual emissions (tons/yr) Season-day emissions (lbs/day) Source category VOC NOx CO VOC NOx CO Agricultural equipment 38.53 330.49 303.71 329.3 2,762.6 2,584.4 Airport GSE (+APU) 111.98 406.04 3,275.98 587.3 2,136.6 17,155.0 Commercial equipment 1,924.41 1,361.42 30,224.21 14,537.1 8,334.7 203,404.4 Construction & mining 1,881.88 12,937.30 14,396.92 13,116.9 87,972.9 99,942.8 Industrial equipment 341.25 1,839.35 7,140.99 2,212.6 11,763.4 46,138.5 Lawn & garden 4,913.96 866.64 54,798.41 51,990.4 6,998.4 523,235.5 Pleasure craft 530.39 96.56 1,249.66 11,527.0 1,996.8 26,738.3 Railway maintenance 1.94 8.55 16.48 14.2 59.0 117.8 Recreational equipment 1,518.97 66.10 6,373.46 17,804.4 679.3 74,424.8 Aircraft 1,719.33 2,588.82 11,781.38 8,451.0 12,548.2 65,325.4 Locomotives 77.60 1,406.08 245.74 425.2 7,704.5 1,346.5 All nonroad mobile sources: 13,060.24 21,907.35 129,806.94 120,995.4 142,956.4 1,060,413.4 2011 Ozone Precursor Emissions Inventory 5 February 2014 Table 1.6–5. Annual and season-day emissions from nonroad mobile sources in the eight-hour ozone NAA. Annual emissions (tons/yr) Season-day emissions (lbs/day) Source category VOC NOx CO VOC NOx CO Agricultural equipment 22.52 193.22 177.56 192.5 1,615.1 1,510.9 Airport GSE (+APU) 111.43 404.49 3,259.08 584.5 2,128.9 17,071.7 Commercial equipment 1,916.15 1,355.57 30,094.46 14,474.7 8,299.0 202,531.2 Construction & mining 1,941.80 13,349.23 14,855.32 13,534.5 90,774.0 103,125.0 Industrial equipment 339.78 1,831.45 7,110.33 2,203.1 11,712.9 45,940.4 Lawn & garden 4,970.15 876.55 55,425.05 52,584.9 7,078.4 529,218.9 Pleasure craft 530.39 96.56 1,249.66 11,527.0 1,996.8 26,738.3 Railway maintenance 1.96 8.64 16.67 14.4 59.7 119.1 Recreational equipment 684.30 29.78 2,871.27 8,020.9 306.0 33,528.7 Aircraft 1,705.43 2,585.98 11,719.36 8,385.8 12,535.3 64,993.6 Locomotives 50.15 901.12 153.29 274.8 4,937.7 839.9 All nonroad mobile sources: 12,274.06 21,632.59 126,932.05 111,797.1 141,443.8 1,025,617.7 1.6.4 Onroad mobile sources Emissions from onroad mobile sources were calculated for Maricopa County and the eight-hour ozone nonattainment area. A detailed description of emissions calculations is contained in Chapter 5. Table 1.6–6 summarizes annual and season-day emissions from onroad mobile sources in Maricopa County and the eight-hour ozone nonattainment area, respectively. Table 1.6–6. Annual and season-day emissions from onroad mobile sources in Maricopa County and the eight-hour ozone NAA. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 24,556.85 60,269.94 235,088.25 150,603.7 319,470.2 1,378,165.5 8-hour ozone NAA 24,110.04 56,861.82 226,581.20 148,186.2 301,823.7 1,321,680.2 1.6.5 Biogenic sources The biogenic source category includes emissions from all vegetation (e.g., crops, indigenous vegetation, landscaping, etc.) in Maricopa County and the eight-hour ozone nonattainment area. Emissions were estimated using the Model of Emissions of Gases and Aerosols from Nature (MEGAN). MEGAN is a state-of-the-art biogenic emissions model developed by the National Center for Atmospheric Research (NCAR). Some corrections and improvements were made in the latest version of MEGAN2.1. MEGAN2.1 was used to compute biogenic emissions in Maricopa County and the eight-hour ozone nonattainment area. Annual and season-day emissions from biogenic sources are shown in Table 1.6–7 for Maricopa County and the eighthour ozone nonattainment area. Table 1.6–7. Annual and season-day emissions from biogenic sources in Maricopa County and the eighthour ozone NAA. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 79,714.87 779.52 11,548.84 895,860.0 9,199.0 122,186.2 8-hour ozone NAA 55,311.84 527.18 5,934.55 624,395.0 6,231.7 62,584.2 2011 Ozone Precursor Emissions Inventory 6 February 2014 1.6.6 Summary of all source categories Tables 1.6–8 and 1.6–9 provide summary totals of annual and season-day emissions from all emission sources in Maricopa County and the eight-hour ozone nonattainment area, respectively. Table 1.6–8. Annual and season-day emissions from all sources in Maricopa County. Annual emissions (tons/year) Season-day emissions (lbs/day) Section VOC NOx CO VOC NOx CO POINT SOURCES: 768.54 1,754.12 1,078.48 4,908.3 15,407.1 9,715.8 AREA SOURCES: Fuel combustion: Industrial distillate oil: Boilers Industrial distillate oil: Engines Industrial natural gas Comm./inst. distillate oil: Boilers Comm./inst. distillate oil: Engines Comm./inst. natural gas Residential distillate oil Residential natural gas Residential LPG Residential wood combustion Residential kerosene All Fuel Combustion Industrial Processes: Chemical manufacturing Commercial cooking Bakeries Secondary metal production Rubber/plastic product mfg. Electrical equipment mfg. Industrial processes, NEC All Industrial Processes Solvent Use: Architectural coatings Auto refinishing Traffic markings Factory finished wood Wood furniture Aircraft surface coating Miscellaneous surface coating Degreasing Dry cleaning Graphics arts Miscellaneous industrial solvent use Consumer and commercial products Cutback asphalt Emulsified asphalt Roofing asphalt Agricultural pesticides All Solvent Use 2011 Ozone Precursor Emissions Inventory 0.61 60.87 0.00 1,838.26 36.99 730.94 0.00 0.12 0.00 3.72 54.48 1,080.73 0.01 0.35 49.81 851.32 2.00 51.35 509.7 57.72 0.00 0.03 653.61 4,675.41 77.42 149.33 78.18 41.01 1,766.75 122.80 48.51 2,284.00 15.22 395.65 455.30 0.03 0.80 662.84 0.10 362.26 14.56 2,959.91 0.01 4,866.67 392.60 15.02 98.36 23.47 224.92 263.41 2.98 91.84 585.79 4,976.22 1,333.26 179.60 137.72 416.56 65.84 316.38 217.55 23.15 290.98 721.85 17,406.46 835.84 866.06 3.04 362.93 28,153.45 3.9 0.0 217.8 0.0 0.0 252.0 0.0 119.6 0.0 0.0 0.0 593.3 599.0 820.5 547.8 306.4 14,171.0 746.2 325.6 17,516.5 390.2 11,783.7 4,303.8 0.8 23.8 4,998.0 0.0 2,044.2 0.0 0.0 0.0 23,544.5 97.5 2,536.2 2,680.8 0.2 5.1 3,065.4 0.0 869.9 0.0 0.0 0.0 9,255.2 2,157.1 107.9 697.4 135.8 1,245.8 1,489.5 16.4 525.2 3,396.2 30,622.9 10,255.9 1,823.6 1,396.7 3,434.7 473.1 2,450.5 1,451.4 178.1 2,225.7 5,126.6 95,377.9 4,567.4 4,732.6 23.4 2,903.4 167,043.9 7 February 2014 Table 1.6–8. Annual and season-day emissions from all sources in Maricopa County (continued). Annual emissions (tons/year) Season-day emissions (lbs/day) Section VOC NOx CO VOC NOx CO Storage/Transport: Residential portable gas cans 2,935.09 16,126.8 Commercial portable gas cans 564.43 3,101.2 Bulk plants 120.91 659.3 Gas stations Stage I: Submerged fill 85.08 528.7 Gas stations Stage I: Bal. submerged fill 229.60 1,426.8 Gas stations Stage II 0.00 0.0 Underground tanks: Breathing/emptying 777.00 4,138.6 Airports: aviation gasoline Stage I 347.57 1,904.5 Airports: aviation gasoline Stage II 18.04 98.8 Truck: gasoline (tank trucks in transit) 50.82 315.8 Pipeline gasoline 17.32 94.5 Volatile organic liquids storage/transport 30.54 182.7 All Storage/Transport 5,176.39 28,577.9 Waste Treatment/Disposal: On-site incineration Open burning: Land clearing debris Landfills Publicly owned treatment works Leaking underground storage tanks Other waste All Waste Treatment/Disposal 0.17 0.67 36.59 75.02 1.05 2.12 115.61 3.31 0.30 30.40 0.79 6.30 108.55 22.19 56.21 77.93 193.56 Miscellaneous Area Sources: Agricultural field burning Structure fires Aircraft engine testing Vehicle fires Crematories Accidental releases Hospitals Wildfires Prescribed fires All Misc. Area Sources 26.14 14.78 4.72 9.27 1.18 0.45 8.57 206.08 0.39 271.58 11.62 1.88 46.36 1.16 11.19 0.00 246.85 80.63 16.16 36.23 2.23 0.00 93.95 0.38 166.54 4,379.29 4.54 4,765.93 1.1 20.5 200.7 577.1 32.3 10.9 842.6 21.4 9.1 167.4 5.3 193.8 596.4 122.8 320.7 431.4 1,227.1 804.2 72.4 26.1 50.8 51.1 2.1 52.3 12,794.0 129.2 13,982.3 357.4 9.2 259.3 6.4 88.5 0.0 7,595.5 395.2 91.2 198.5 17.3 0.0 5,832.6 127.1 6,680.5 271,872.2 1,523.2 281,693.1 295,571.5 ALL AREA SOURCES 36,654.65 5,161.56 10,411.95 228,556.4 32,035.2 NONROAD MOBILE SOURCES: Agricultural equipment Airport GSE (+APU) Commercial equipment Construction & mining equipment Industrial equipment Lawn and garden equipment Pleasure craft Railway maintenance equipment Recreational equipment Aircraft Locomotives ALL NONROAD MOBILE 38.53 111.98 1,924.41 1,881.88 341.25 4,913.96 530.39 1.94 1,518.97 1,719.33 77.60 13,060.24 329.3 587.3 14,537.1 13,116.9 2,212.6 51,990.4 11,527.0 14.2 17,804.4 8,451.0 425.2 120,995.4 ONROAD MOBILE SOURCES 24,556.85 60,269.94 235,088.25 330.49 406.04 1,361.42 12,937.30 1,839.35 866.64 96.56 8.55 66.10 2,588.82 1,406.08 21,907.35 303.71 3,275.98 30,224.21 14,396.92 7,140.99 54,798.41 1,249.66 16.48 6,373.46 11,781.38 245.74 129,806.94 2,762.6 2,584.4 2,136.6 17,155.0 8,334.7 203,404.4 87,972.9 99,942.8 11,763.4 46,138.5 6,998.4 523,235.5 1,996.8 26,738.3 59.0 117.8 679.3 74,424.8 12,548.2 65,325.4 7,704.6 1,346.5 142,956.4 1,060,413.4 150,603.7 319,470.2 1,378,165.5 79,714.87 779.52 11,548.84 895,860.0 9,199.0 122,186.2 BIOGENIC SOURCES TOTAL, ALL SOURCE CATEGORIES 154,755.15 89,872.48 387,934.46 1,400,923.9 519,067.9 2,866,052.4 2011 Ozone Precursor Emissions Inventory 8 February 2014 Table 1.6–9. Annual and season-day emissions from all sources in the eight-hour ozone nonattainment area. Annual emissions (tons/year) Season-day emissions (lbs/day) Section VOC NOx CO VOC NOx CO POINT SOURCES: 768.54 1,754.12 1,078.48 4,908.3 15,407.1 9,715.8 AREA SOURCES: Fuel combustion: Industrial distillate oil: Boilers Industrial distillate oil: Engines Industrial natural gas Comm./inst. distillate oil: Boilers Comm./inst. distillate oil: Engines Comm./inst. natural gas Residential distillate oil Residential natural gas Residential LPG Residential wood combustion Residential kerosene All Fuel Combustion: Industrial processes: Chemical manufacturing Commercial cooking Bakeries Secondary metal production Rubber/plastic product manufacturing Electrical equipment manufacturing Industrial processes, NEC All Industrial Processes: Solvent use: Architectural coatings Auto refinishing Traffic markings Factory finished wood Wood furniture Aircraft surface coating Miscellaneous surface coating Degreasing Dry cleaning Graphics arts Miscellaneous industrial solvent use Consumer and commercial products Cutback asphalt Emulsified asphalt Roofing asphalt Agricultural pesticides All Solvent Use: 2011 Ozone Precursor Emissions Inventory 0.61 60.61 0.00 1,830.35 36.83 727.80 0.00 0.12 0.00 3.70 54.42 1,079.44 0.01 0.35 50.20 857.96 2.02 51.93 515.53 58.38 0.00 0.03 659.63 4,670.68 77.09 151.03 77.85 41.01 1,759.15 122.80 47.55 2,276.48 15.15 393.95 453.34 0.03 0.80 662.05 0.10 365.09 14.73 2,993.75 0.01 4,898.99 397.07 5,033.13 1,327.53 171.12 137.12 414.77 65.84 315.02 216.62 23.42 289.73 718.75 17,605.51 788.72 817.24 3.08 212.18 28,139.77 15.02 98.36 23.47 224.92 263.41 2.98 91.84 590.27 3.9 388.5 0.0 11,733.0 216.9 4,285.3 0.0 0.8 0.0 23.7 251.7 4,992.0 0.0 0.0 120.5 2,060.1 0.0 0.0 0.0 0.0 0.0 0.0 593.0 23,483.5 596.5 829.8 545.4 306.4 14,110.1 746.2 318.0 17,452.4 97.1 2,525.3 2,669.3 0.2 5.1 3,061.7 0.0 876.7 0.0 0.0 0.0 9,235.4 2,181.7 107.9 697.4 135.8 1,245.8 1,489.5 16.4 525.2 3,420.8 30,973.1 10,211.8 1,737.5 1,390.7 3,419.9 473.1 2,440.0 1,445.1 180.1 2,216.1 5,104.6 96,468.5 4,309.9 4,465.8 23.7 1,697.5 166,557.4 9 February 2014 Table 1.6–9. Annual and season-day emissions from all sources in the eight-hour ozone nonattainment area (continued). Annual emissions (tons/year) Season-day emissions (lbs/day) Section VOC NOx CO VOC NOx CO Storage/transport: Residential portable gas cans 2,968.67 16,311.39 Commercial portable gas cans 570.89 3,136.73 Bulk plants 120.91 659.3 Gas stations Stage I: Submerged fill 85.08 528.7 Gas stations Stage I: Bal. submerged fill 229.60 1,426.8 Gas stations Stage II 0.00 0.0 Underground tanks: Breathing/emptying 777.00 4,138.6 Airports: Aviation gasoline Stage I 344.41 1,887.2 Airports: Aviation gasoline Stage II 17.87 97.9 Truck: Gasoline (tank trucks in transit) 50.82 315.8 Pipeline gasoline 17.32 94.5 Volatile organic liquids storage/transport 28.80 169.3 All Storage/Transport: 5,211.35 28,766.2 Waste treatment/disposal: On-site incineration Open Burning: Land clearing debris Landfills Publicly owned treatment works Leaking underground storage tanks Other waste All Waste Treatment/Disposal: 0.17 0.30 36.59 75.88 1.05 2.12 116.10 3.31 0.13 30.40 0.79 2.81 108.55 22.19 56.04 77.93 190.06 Misc. area sources: Agricultural field burning Structure fires Aircraft engine testing Vehicle fires Crematories Accidental releases Hospitals Wildfires Prescribed fires All Misc. Area Sources 15.28 14.95 4.72 9.38 1.18 0.45 8.66 206.08 0.39 261.09 6.79 1.90 46.36 1.17 11.14 0.00 144.32 81.55 16.16 36.64 2.22 0.00 93.95 0.38 161.70 ALL AREA SOURCES: 36,664.42 5,151.83 NONROAD MOBILE SOURCES: Agricultural equipment Airport ground support equipment (+APU) Commercial equipment Construction & mining equipment Industrial equipment Lawn and garden equipment Pleasure craft Railway maintenance equipment Recreational equipment Aircraft Locomotives ALL NONROAD MOBILE SOURCES: ONROAD MOBILE SOURCES: 1.1 9.1 200.7 583.7 32.3 10.9 837.8 21.4 4.1 167.4 5.3 86.4 596.4 122.8 315.6 431.4 1,119.6 209.0 9.3 259.3 6.4 88.1 0.0 4,440.7 399.7 91.2 200.8 17.2 0.0 4,379.28 4.54 4,664.71 470.2 73.3 26.1 51.4 50.9 2.1 52.9 12,794.0 129.2 13,650.0 5,832.6 127.1 6,531.8 271,872.2 1,523.2 278,544.9 10,344.03 227,856.8 31,820.5 292,320.7 22.52 111.43 1,916.15 1,941.80 339.78 4,970.15 530.39 1.96 684.30 1,705.43 50.15 12,274.06 193.22 177.56 404.49 3,259.08 1,355.57 30,094.46 13,349.23 14,855.32 1,831.45 7,110.33 876.55 55,425.05 96.56 1,249.66 8.64 16.67 29.78 2,871.27 2,585.98 11,719.36 901.12 153.29 21,632.59 126,932.05 192.5 584.5 14,474.7 13,534.5 2,203.1 52,584.9 11,527.0 14.4 8,020.9 8,385.8 274.8 111,797.1 1,615.1 1,510.9 2,128.9 17,071.7 8,299.0 202,531.2 90,774.0 103,125.0 11,712.9 45,940.4 7,078.4 529,218.9 1,996.8 26,738.3 59.7 119.1 306.0 33,528.7 12,535.3 64,993.6 4,937.7 839.9 141,443.8 1,025,617.7 24,110.04 56,861.82 226,581.20 148,186.2 301,823.7 1,321,680.2 BIOGENIC SOURCES: 55,311.84 TOTAL, ALL SOURCE CATEGORIES: 129,128.91 527.18 5,934.55 624,395.0 85,927.54 370,870.31 1,117,143.4 6,231.7 62,584.2 496,726.7 2,711,918.6 2011 Ozone Precursor Emissions Inventory 10 February 2014 2. 2.1 Point Sources Introduction and scope This inventory of ozone precursors (VOC, NOx, and CO) is one of two 2011emissions inventory reports being prepared to meet US EPA reporting requirements. This inventory has been developed concurrently with a similar inventory for PM10 and related pollutants (PM2.5, NOx, SOx, and NH3) as part of Maricopa County's requirements under the respective SIPs. In addition to preparing a periodic emissions inventory for the eight-hour ozone nonattainment area (NAA) as a commitment under the current ozone State Implementation Plan (SIP), the federal Air Emission Reporting Requirements (AERR) rule requires that state and local agencies prepare emissions estimates on a county basis, and submit data electronically to the US EPA for inclusion in the National Emissions Inventory (NEI) for 2011. In order to provide consistency among all these inventories, it was decided to standardize the definition of a “point source” by adopting the designation of point sources as outlined in the AERR: We are basing the requirement for point source format reporting on whether the source is major under 40 CFR part 70 for the pollutants for which reporting is required, i.e., CO, VOC, NOx, SO2, PM2.5, PM10, lead and NH3 but without regard to emissions of HAPs… [T]his approach will result in a more stable universe of reporting point sources, which in turn will facilitate elimination of overlaps and gaps in estimating point source emissions, as compared to nonpoint source emissions. Under this requirement, states will know well in advance of the start of the inventory year which sources will need to be reported. (US EPA, 2008) This chapter contains several tables that provide information on point source emissions. Table 2.2–1 provides an alphabetical listing of all point sources and their location. Table 2.4–1 shows the annual and ozone season-day emissions of VOC, NOx, and CO for those point sources which reported emissions of one or more of these pollutants in 2011. Table 2.5–1 lists emission reduction credits for the area, while Table 2.6–1 summarizes point source emission totals for both Maricopa County and the eight-hour ozone nonattainment area. Note that the totals shown in tables may not equal the sum of individual values due to independent rounding. 2.2 Identification of point sources The Maricopa County Air Quality Department (MCAQD) identified point sources within Maricopa County through its electronic permit system database, EMS, and the 2011 annual emissions reports submitted to the department. A total of 18 stationary sources were identified as point sources using the definition described in Section 2.1. While the Arizona Department of Environmental Quality (ADEQ) retains permitting authority for a limited number of industrial source categories in Maricopa County, no ADEQ-permitted facilities are considered point sources, and are addressed instead as area sources. Table 2.2–1 contains an alphabetical listing of all point sources, including a unique business identification number, NAICS industry classification code, business name, and physical address. 2011 Ozone Precursor Emissions Inventory 11 February 2014 Table 2.2–1. Name and location of all point sources in Maricopa County. ID # NAICS Business name Address 3313 221112 APS West Phoenix Power Plant 4606 W Hadley St 43063 221112 Arlington Valley LLC 39027 W Elliot Rd 127771 331111 CMC Steel Fabricators Inc 11444 E Germann Rd 44439 221112 Gila River Power Station 1250 E Watermelon Rd 3300 92811 Luke AFB – 56th Fighter Wing 14002 W Marauder St 44186 221112 Mesquite Generating Station 37625 W Elliot Rd 43530 221112 New Harquahala Generating Co 2530 N 491st Ave 20706 32614 New Wincup Holdings Inc 7980 W Buckeye Rd 1879 562212 Northwest Regional Landfill 19401 W Deer Valley Rd 1331 337122 Oak Canyon Manufacturing Inc 3021 N 29th Dr 52382 221112 Ocotillo Power Plant 1500 E University Dr 42956 221112 Redhawk Generating Facility 11600 S 363rd Ave 303 332431 Rexam Beverage Can Company 211 N 51st Ave 3315 221112 Santan Generating Station 1005 S Val Vista Rd 4175 424710 SFPP LP Phoenix Terminal 49 N 53rd Ave 3316 221112 SRP Agua Fria Generating Station 7302 W Northern Ave 3317 221112 SRP Kyrene Generating Station 7005 S Kyrene Rd 1210 337122 Trendwood Inc 2402 S 15th Ave 2.3 City Phoenix Arlington Mesa Gila Bend Glendale Arlington Tonopah Phoenix Surprise Phoenix Tempe Arlington Phoenix Gilbert Phoenix Glendale Tempe Phoenix ZIP 85043 85322 85212 85337 85309 85322 85354 85043 85387 85017 85281 85322 85043 85296 85043 85303 85283 85007 Procedures for estimating emissions from point sources Annual and season-day emission estimates were determined from annual source emissions reports, MCAQD investigation reports, permit files and logs, or telephone contacts with sources. For most of the sources, material balance methods were used for determining emissions. Emissions were estimated using the emission factors from AP–42, source tests, engineering calculations, or manufacturers' specifications. MCAQD distributes annual emissions survey forms to nearly all facilities for which MCAQD has issued an operating permit. Facilities are required to report detailed information on stacks, control devices, operating schedules, and process-level information concerning their annual activities. (See Appendix A for a copy of the instructions to complete the emissions inventory.) These instructions include examples and explanations on how to complete the annual emissions reporting forms that facilities must submit to MCAQD. After a facility has submitted an annual emissions report to MCAQD, emissions inventory staff check all reports for missing and questionable data, and check the accuracy and reasonableness of all emissions calculations with AP–42, the Factor Information and REtrieval (webFIRE) software, and other EPA documentation. Control efficiencies are determined by source tests when available, or by AP–42 factors, engineering calculations, or manufacturers’ specifications. MCAQD has conducted annual emissions surveys for permitted facilities since 1988, and the department's database system, EMS, contains numerous automated quality assurance/quality control checks for data input and processing. 2011 Ozone Precursor Emissions Inventory 12 February 2014 2.3.1 Application of rule effectiveness Rule effectiveness reflects the actual ability of a regulatory program to achieve the emission reductions required by regulation. The concept of applying rule effectiveness in a SIP emissions inventory has evolved from the observation that regulatory programs may be less than 100 percent effective for some source categories. Rule effectiveness (“RE”) is applied to those sources affected by a regulation and for which emissions are determined by means of emission factors and control efficiency estimates. For processes that claimed emissions reductions through the use of a control device, RE calculations were performed separately for Title V and non-Title V sources. Overall RE values of 91.81% (for Title V processes) and 87.81% (for non-Title V processes) were calculated. Appendix B contains further details on the methods and data used in computing the above RE rates. 2.4 Detailed overview of point source emissions Table 2.4–1 provides a summary of annual and season-day emissions from all point sources. All point sources are located within the eight-hour ozone nonattainment area, therefore, county and nonattainment area emissions are equal. Sources for which rule effectiveness has been applied are noted. Values of “0.00” and “0.0” for annual and daily emissions denote a value below the level of significance (0.005 tons/yr and 0.05 lbs/day, respectively). Table 2.4–1. ID # 3313 43063 127771 44439 3300 44186 43530 20706 1879 1331 52382 42956 303 3315 4175 3316 3317 1210 Annual and season-day point source emissions, by facility. Annual emissions (tons/yr) Business name VOC NOx CO APS West Phoenix Power Plant * 28.43 596.56 80.92 Arlington Valley LLC 0.52 38.68 24.12 CMC Steel Fabricators Inc * 23.63 34.05 455.94 Gila River Power Station 10.40 194.22 53.43 Luke AFB – 56th Fighter Wing * 8.07 10.04 5.36 Mesquite Generating Station * 22.53 192.49 22.99 New Harquahala Generating Co * 15.50 23.24 35.24 New Wincup Holdings Inc 125.98 11.82 2.10 Northwest Regional Landfill 2.47 9.74 5.18 Oak Canyon Manufacturing Inc 62.86 Ocotillo Power Plant 4.79 82.96 15.54 Redhawk Generating Facility 5.61 150.82 168.87 Rexam Beverage Can Company 99.49 4.35 3.65 Santan Generating Station * 8.78 257.77 150.24 SFPP LP Phoenix Terminal 101.15 4.89 5.53 SRP Agua Fria Generating Station * 1.88 104.92 25.55 SRP Kyrene Generating Station 3.16 27.77 8.51 Trendwood Inc 128.59 TOTAL: 653.84 1,744.32 1,063.18 Ozone season day (lbs/day) VOC NOx CO 163.6 4,162.0 422.6 8.7 605.4 377.5 226.7 318.6 4,376.6 93.9 1,777.7 501.0 53.1 52.2 22.5 134.0 1,146.1 137.2 169.0 251.0 386.3 684.0 65.1 12.9 13.6 53.5 28.5 483.5 51.1 1,087.8 203.7 26.6 813.2 890.8 481.1 21.0 17.7 87.7 2,817.6 1,648.7 556.6 36.2 47.4 32.2 1,900.1 481.8 25.2 245.8 76.9 989.1 4,279.8 15,353.4 9,632.0 * = Facility for which rule effectiveness has been applied. 2.5 Emission reduction credits A major source or major modification planned in a nonattainment area must obtain emissions reductions as a condition for approval. These emissions reductions, generally obtained from 2011 Ozone Precursor Emissions Inventory 13 February 2014 existing sources located in the vicinity of a proposed source, must offset the emissions increase from the new source or modification. The obvious purpose of acquiring offsetting emissions decreases is to allow an area to move towards attainment of the national ambient air quality standards while still allowing some industrial growth. In order for these emission reductions to be available in the future for offsetting, they must be: 1) explicitly included and quantified as growth in projection-year inventories required in rate of progress plans or attainment demonstrations that were based on 1990 actual inventories, and 2) meet the requirements outlined in MCAQD Rule 240 (Permit Requirements for New Major Sources and Major Modification to Existing Major Sources). Table 2.5–1 provides a list of emission reduction credits for VOC, NOx, and CO. Table 2.5–1. ID 1151 2.6 Emission reduction credits as of December 31, 2011. Facility/ Owner Freescale Semiconductor, Inc. Grey K Envl Fund, NYC Woodstuff Mfg TOTAL: Reduction Date 3/1/2004 12/11/2006 11/30/2007 Emission reduction credits (tons/yr) VOC NOx CO 17.1 9.8 15.3 80.0 17.6 114.7 9.8 15.3 Summary of point source emissions Table 2.6–1 provides a summary of point source emissions for Maricopa County and the eighthour ozone nonattainment area, including emission reduction credits. Table 2.6–1. Annual and season-day point source emissions (including emission reduction credits). Annual (tons/yr) Season-day emissions (lbs/day) Geographic Area VOC NOx CO VOC NOx CO Maricopa County 768.54 1,754.12 1,078.48 4,908.3 15,407.1 9,715.8 8-hr ozone NAA 768.54 1,754.12 1,078.48 4,908.3 15,407.1 9,715.8 2.7 Quality assurance/quality control procedures 2.7.1 Emission survey preparation and data collection The MCAQD's Emissions Inventory (EI) Unit annually collects point source criteria pollutant emission data from sources in the county. MCAQD annually reviews EPA guidance, documents from the Emissions inventory Improvement Program (EIIP), and other source materials to ensure that the most current emission factors and emission calculation methods are used for each year’s survey. Each January, the EI Unit prepares a pre-populated hard copy of the preceding year’s submissions and mails reporting forms to permitted sources, along with detailed instructions for completing the forms. (A copy of these instructions is included as Appendix A). The EI Unit asks sources to verify and update the data. The EI Unit also holds numerous workshops each spring to assist businesses in completing EI forms. The general data flow for data collection and inventory preparation is shown in Figure 2.7–1. 2011 Ozone Precursor Emissions Inventory 14 February 2014 Figure 2.7–1. Data flow for annual point source emissions inventory reporting. EI Reporting Forms • • Hard Copy Forms/ Instructions Instruction on Web EI Reporting Forms Log In EI reports/ Issue Receipts Issue NOVs for late submitters • • • Data Entry EMS Code/field check Range checks Referential value checks Create Inventory files Automated QA checks Technical QA/ QC Using completed survey data Finalized Inventory Data Reconciliation 2.7.2 Submission processing Submitted EI reports are logged in as they are received, and receipts are issued for emissions fees paid. The data are input “as received” into the department's data base. During data entry, a variety of automated quality control (QC) checks are performed, including: • • • • • pull-down menus to minimize data entry errors (e.g., city, pollutant, emission factor unit, etc.) mandatory data field requirement checks (e.g., a warning screen appears if a user tries to save an emission record with a missing emission factor). range checks (e.g., were valid SCC, Tier, SIC, and NAICS codes entered?) referential value checks (e.g., emission factor units, annual throughput units) automatic formatting of date, time, telephone number fields, etc. Automated quality assurance (QA) checks on the report that has been entered include the following: • • Comparing reported emission factors to SCC reference lists Comparing reported emission factors to material name reference list 2011 Ozone Precursor Emissions Inventory 15 February 2014 • • Checking the report for calculation errors. This includes annual throughput, emission factors, unit conversion factors (e.g., BTU to therms), capture efficiency, primary / secondary control device efficiency, and any offsite recycling credits claimed. Checking the report for completeness of required data. When data entry is complete, an electronic version of the original data is preserved separately to document changes made during the technical review and QA/QC process. When errors are flagged, the businesses are contacted and correct information is obtained and input to the EMS. Outstanding reporting issues are documented. Confidential business information (CBI) is identified by a checkbox on the form, and these data elements are flagged during data entry and are not transmitted to the EPA. To prepare the inventory for submittal to the National Emissions Inventory (NEI), the EI Unit has developed a series of MS-Access queries to extract data from EMS; and to append or convert codes, units of measure, etc., in order to create staging tables that adhere to the EPA’s Consolidated Emissions Reporting Schema (CERS). These tables are then converted to XML files using EPA’s Bridge conversion tool for submittal to the EPA’s Emissions inventory System (EIS). 2.7.3 Analysis of annual point source emissions data for this inventory Two air quality planners checked inventory accuracy and reasonableness, and assured that all point sources had been identified and that the methodology applied to calculate emissions was appropriate and that the calculations were correct. Other reasonableness checks were conducted by recalculating emissions using methods other than those used to make the initial emissions calculations and then comparing results. QA was conducted by checking all emissions reports submitted to MCAQD for the year 2011 for missing and questionable data and by checking the accuracy and reasonableness of all emissions calculations made for such reports. Notes concerning follow-up calls and corrections to calculations were documented on each 2011 annual emissions report. The QA point source coordinator reviewed and checked calculations, identified errors, and performed completeness, reasonableness and accuracy checks. 2.8 References US EPA, 2008. Air Emissions Reporting Requirements: Final Rule. 73 Fed. Reg. 76539. Available at: http://www.epa.gov/ttn/chief/aerr/final_published_aerr.pdf. 2011 Ozone Precursor Emissions Inventory 16 February 2014 3. 3.1 Area Sources Scope and methodology This chapter considers all stationary sources which are too small or too numerous to be treated as point sources. US EPA guidance documents, including “Introduction to Area Source Inventory Development” (US EPA, 2001a) as well as permit and emissions data in the MCAQD’s Environmental Management System (EMS) database, and previous SIP inventories, were evaluated to develop the list of area source categories for inclusion. Some source categories were deemed “insignificant” because there are no large production facilities and/or very few small sources, and therefore emissions were not quantified. MCAQD prepared the emission estimates for all area sources and provided quality assurance checks on all data. Table 3.1–1 contains a list of all area source categories, with Source Classification Codes (SCCs), addressed in this chapter. Table 3.1–1. SCC code List of area source categories included in this ozone precursor inventory. Area source description Section 2102004001 2102004002 2102006000 2103004001 2103004002 2103006000 2104004000 2104006000 2104007000 2104011000 2104008100 2104008210 2104008220 2104008230 2104008310 2104008320 2104008330 2104008400 2104008610 2104008700 2104009000 Fuel combustion: Industrial distillate oil: Boilers Industrial distillate oil: Engines Industrial natural gas Commercial/institutional distillate oil: Boilers Commercial/institutional distillate oil: Engines Commercial/institutional natural gas Residential distillate oil Residential natural gas Residential liquefied petroleum gas (LPG) Residential kerosene Residential Wood Combustion (RWC): Fireplace RWC: Woodstove: fireplace inserts: Non-EPA certified RWC: Woodstove: fireplace inserts: EPA certified; non-catalytic RWC: Woodstove: fireplace inserts: EPA certified; catalytic RWC: Woodstove: freestanding: Non-EPA certified RWC: Woodstove: freestanding: EPA certified, non-catalytic RWC: Woodstove: freestanding: EPA certified, catalytic RWC: Woodstove: Pellet-fired RWC: Hydronic heater: Outdoor RWC: Outdoor wood burning device, NEC RWC: Residential firelog 3.2 3.2.1 3.2.1 3.2.2 3.2.3 3.2.3 3.2.4 3.2.5 3.2.6 3.2.7 3.2.8 3.2.9 3.2.9 3.2.9 3.2.9 3.2.9 3.2.9 3.2.9 3.2.9 3.2.9 3.2.9 3.2.9 2301000000 2302002100 2302002200 2302003000 2302003100 2302003200 2302050000 2304000000 2308000000 2312000000 2399000000 Industrial processes: Chemical manufacturing Commercial cooking: Conveyorized charbroiling Commercial cooking: Under-fired charbroiling Commercial cooking: Deep fat frying Commercial cooking: Flat griddle frying Commercial cooking: Clamshell griddle frying Bakeries Secondary metal production Rubber/plastics product manufacturing Electrical equipment manufacturing Industrial processes not elsewhere classified (NEC) 3.3 3.3.1 3.3.2.1 3.3.2.1 3.3.2.1 3.3.2.1 3.3.2.1 3.3.2.2 3.3.3 3.3.4 3.3.5 3.3.6 2401001000 2401005000 2401008000 2401015000 Solvent use: Architectural coatings Auto refinishing Traffic markings Factory-finished wood 3.4 3.4.1.1 3.4.1.2 3.4.1.3 3.4.1.4 2011 Ozone Precursor Emissions Inventory 17 February 2014 Table 3.1–1. AMS code 2401020000 2401075000 2401090000 2415000000 2420000000 2425000000 2440000000 2460100000 2460200000 2460400000 2460500000 2460600000 2460800000 2460900000 2461021000 2461022000 2461023000 2461850000 List of area source categories included in this inventory (continued). Area source description Section Wood furniture 3.4.1.5 Aircraft surface coating 3.4.1.6 Miscellaneous surface coating 3.4.1.7 Degreasing 3.4.2 Dry cleaning 3.4.3 Graphic arts 3.4.4 Miscellaneous industrial solvent use 3.4.5 Consumer & commercial products (C&CP): Personal care products 3.4.6 C&CP: Household products 3.4.6 C&CP: Automotive aftermarket products 3.4.6 C&CP: Coatings and related products 3.4.6 C&CP: Adhesives and sealants 3.4.6 C&CP: FIFRA related products 3.4.6 C&CP: Miscellaneous products, NEC 3.4.6 Cutback asphalt 3.4.7 Emulsified Asphalt 3.4.7 Roofing Asphalt 3.4.7 Agricultural pesticides 3.4.8 2501011011 2501011012 2501011013 2501011014 2501011015 2501012011 2501012012 2501012013 2501012014 2501012015 2501055120 2501060051 2501060053 2501060201 2501080050 2501080100 2505030120 2505040120 2510000000 Storage and transport: Residential portable gas cans (RPG): Permeation RPG: Evaporation RPG: Spillage during transport RPG: Refilling at the pump - vapor displacement RPG: Refilling at the pump - spillage Commercial portable gas cans (CPG): Permeation CPG: Evaporation CPG: Spillage during transport CPG: Refilling at the pump - vapor displacement CPG: Refilling at the pump - spillage Bulk plants Gasoline service stations Stage I: Submerged filling Gasoline service stations Stage I: Balanced submerged filling Gasoline service stations: Underground tank, breathing/emptying Airports: Aviation gasoline Stage I: Total Airports: Aviation gasoline Stage II: Total Gasoline tank trucks in transit Pipeline gasoline Volatile organic liquid (VOL) storage and transport 3.5 3.5.1 3.5.1 3.5.1 3.5.1 3.5.1 3.5.1 3.5.1 3.5.1 3.5.1 3.5.1 3.5.2 3.5.3 3.5.3 3.5.5 3.5.6 3.5.6 3.5.7 3.5.8 3.5.9 2601000000 2610000500 2620000000 2630020000 2660000000 2650000000 Waste treatment and disposal: On-site incineration Open burning: Land clearing debris Landfills Publicly owned treatment works Leaking underground storage tanks Other waste 3.6 3.6.1 3.6.2 3.6.3 3.6.4 3.6.5 3.6.6 2801500000 2810030000 2810040000 2810050000 2810060100 2830001000 2850000000 n/a n/a Miscellaneous area sources: Agricultural field burning Structure fires Aircraft engine testing Vehicle fires Crematories Accidental releases Hospitals Wildfires Prescribed fires 3.7 3.7.1 3.7.2 3.7.3 3.7.4 3.7.5 3.7.6 3.7.7 3.7.8 3.7.9 2011 Ozone Precursor Emissions Inventory 18 February 2014 For nearly all categories, emissions were calculated in one of the following ways: • Emissions estimates for some categories were developed by conducting surveys on local usage (e.g., natural gas consumption) or derived from state-wide data (e.g., fuel oil use). • For some widespread or diverse categories (e.g., consumer solvent use), emissions were calculated using published per-capita or per-employee emission factors. • For source categories with some information available from annual emissions reports (e.g., bakeries), these data were combined with employment data to “scale up” reported emissions to reflect the entire source category. • For those source categories with detailed emissions data available from most or all of the significant sources in the category, emissions were calculated based on detailed process-level and operational data provided by these sources. The specific emissions estimation methodologies used for each source category (including the derivation and application of rule effectiveness) are described in greater detail in the respective sections. 3.2 Fuel combustion Area-source emission estimates are provided in this section for the following categories of fuel consumption: Industrial distillate oil, industrial natural gas, commercial/institutional distillate oil, commercial/institutional natural gas, residential distillate oil, residential natural gas, residential liquefied petroleum gas, residential kerosene, and residential wood. Data for natural gas combustion emission estimates came from a survey of the three natural gas suppliers in Maricopa County. Table 3.2–1 summarizes the natural gas sales data received from Maricopa County natural gas suppliers. Table 3.2–1. Maricopa County natural gas sales by end-user category and supplier. Sales by end-user category (in MMCF/yr) Natural gas Electric Commercial/ supplier Utilities Industrial Institutional Residential Transport* Southwest Gas n/a 592.74 13,303.23 17,083.04 9,288.47 City of Mesa n/a 91.17 1,631.61 1,030.07 175.13 El Paso 112,963.97 150.78 n/a n/a n/a Total: 112,963.97 834.68 14,934.84 18,113.11 9,463.60 Other* 406.92 n/a n/a 406.92 *For emissions calculations, sales from transport and other were grouped with industrial sales. 3.2.1 Industrial distillate oil Annual emissions from industrial distillate oil combustion were derived from EPA NEI (US EPA, 2012c) calculations. Emissions come from two different sources, boilers and engines burning distillate oil. Ozone season-day emissions for the county are calculated by first multiplying annual emissions by 25% to estimate ozone season totals. Ozone season emission totals are then divided by the number of days that activity occurs during the ozone season (6 days/week and 13 weeks), as recommended by EIIP guidance (US EPA, 2001a). Annual and season-day emissions in the eight-hour ozone nonattainment area were calculated by applying the ratio of industrial 2011 Ozone Precursor Emissions Inventory 19 February 2014 employment in the nonattainment area to county-level emission calculations (99.57%). (See Section 1.5.1 for a discussion of the employment data used). Results for boilers and engines are shown in Tables 3.2–2 and 3.2–3, respectively. Table 3.2–2. boilers. Annual and season-day emissions from area-source industrial distillate oil combustion for Geographic area Maricopa County 8-hr ozone NAA Table 3.2–3. engines. Season-day emissions (lbs/day) VOC NOx CO 3.9 390.2 97.5 3.9 388.5 97.1 Annual and season-day emissions from area-source industrial distillate oil combustion for Geographic area Maricopa County 8-hr ozone NAA 3.2.2 Annual emissions (tons/yr) VOC NOx CO 0.61 60.87 15.22 0.61 60.61 15.15 Annual emissions (tons/yr) VOC NOx CO 0.00 1,838.26 395.65 0.00 1,830.35 393.95 Season-day emissions (lbs/day) VOC NOx CO 0.0 11,783.7 2,536.2 0.0 11,733.0 2,525.3 Industrial natural gas All natural gas suppliers in Maricopa County were surveyed to gather information on the volume of natural gas distributed, by user category, within the county in 2011. Area-source industrial natural gas usage for the county is based on the reported total volume of natural gas sold to industrial sources (10,705.20 MMCF), minus natural gas used by industrial point sources (463.95 MMCF). Natural gas is used for both external combustions (boilers and heaters) and internal combustion (generators), each of which have different emission factors. Thus the area-source natural gas usage derived above must be divided between these two categories. This apportionment was based on the percentages of external and internal natural gas combustion reported by all industrial area sources in 2008. A 2008 apportionment was used because 2011 data were not available for all industrial area sources at the time that these emission estimates were developed. Annual emissions for the county were calculated by multiplying natural gas usage by the respective emission factors for external (SCC=102006* & 103006*) and internal (SCC=2020020*) combustion obtained from EPA’s WebFIRE database (US EPA, 2012a). Table 3.2–4. Natural gas usage, emission factors, and annual emissions from area-source industrial natural gas consumption, by combustion type. Combustion % of Natural gas usage Emission factors (lb/MMCF) Annual emissions (tons/yr) type total (MMCF) VOC NOx CO VOC NOx CO External 98.44 10,081.49 5.5 100 84 27.72 504.07 423.42 Internal 1.56 159.76 116 2,840 399 9.27 226.86 31.87 Total: 100.00 10,241.25 36.99 730.94 455.30 Ozone season-day emissions for the county are calculated by first multiplying annual emissions by the percentage of industrial natural gas sold used during the ozone season (22.96%). (Figures reported by natural gas suppliers for the June–August time period are assumed to be representative for the July–September ozone season.) Ozone season emission totals are then divided by the number of days that activity occurs during the ozone season (6 days/wk × 13 wks/season). 2011 Ozone Precursor Emissions Inventory 20 February 2014 Annual and season-day emissions within the eight-hour ozone nonattainment area were calculated by applying the ratio of industrial employment in the nonattainment area to county-level emission calculations (99.57%). (See Section 1.5.1 for a discussion of the employment data used). Table 3.2–5. Annual and season-day emissions from area-source industrial natural gas combustion. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 36.99 730.94 455.30 217.8 4,303.8 2,680.8 8-hr ozone NAA 36.83 727.80 453.34 216.9 4,285.3 2,669.3 3.2.3 Commercial/institutional distillate oil Annual emissions from commercial/institutional distillate oil combustion were derived from EPA NEI (US EPA, 2012c) calculations. Emissions come from two different sources, boilers and engines burning distillate oil. Ozone season-day emissions for the county are calculated by first multiplying annual emissions by 25% to estimate ozone season totals. Ozone season emission totals are then divided by the number of days that activity occurs during the ozone season (6 days/week and 13 weeks), as recommended by EIIP guidance (US EPA, 2001a). Annual and season-day emissions in the eight-hour ozone nonattainment area were calculated by applying the ratio of industrial employment in the nonattainment area to county-level emission calculations (99.57%). (See Section 1.5.1 for a discussion of the employment data used.) Emissions estimates for boilers and engines are shown in Tables 3.3–6 and 3.3–7, respectively. Table 3.2–6. Annual and season-day emissions from area-source commercial/institutional distillate oil combustion for boilers. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 0.00 0.12 0.03 0.0 0.8 0.2 8-hr ozone NAA 0.00 0.12 0.03 0.0 0.8 0.2 Table 3.2–7. Annual and season-day emissions from area-source commercial/institutional distillate oil combustion for engines. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 0.00 3.72 0.80 0.0 23.8 5.1 8-hr ozone NAA 0.00 3.70 0.80 0.0 23.7 5.1 3.2.4 Commercial/institutional natural gas All natural gas suppliers in Maricopa County were surveyed to gather information on the volume of natural gas distributed, by user category, within the county in 2011. Area-source commercial and institutional (C&I) natural gas usage for the county is based on the reported total volume of natural gas sold to C&I sources (14,934.84 MMCF), minus natural gas used by C&I point sources (77.80 MMCF). Natural gas is used for both external combustion (boilers, heaters) and internal combustion (generators), each of which have different emission factors. Thus the area-source natural gas usage derived above must be apportioned between these two categories. This apportionment was 2011 Ozone Precursor Emissions Inventory 21 February 2014 based on the percentages of external and internal natural gas combustion reported by all C&I area sources in 2008. A 2008 apportionment was used because 2011 data were not available for all C&I area sources at the time that these emission estimates were developed. Annual emissions for the county were calculated by multiplying natural gas usage by the respective emission factors for external (SCC=1020060*) and internal (SCC=2020020*) combustion obtained from EPA’s WebFIRE database (US EPA, 2012a). Table 3.2–8. Emission factors and annual emissions from area-source commercial/institutional natural gas combustion, by combustion type. Emission factors (lb/MMCF) Annual emissions (tons/yr) Combustion % of Natural gas type total usage (MMCF) VOC NOx CO VOC NOx CO External 98.34 14,610.42 5.5 100 84 40.18 730.52 613.64 Internal 1.66 246.63 116 2,840 399 14.30 350.21 49.20 Total: 100.00 14,857.04 54.48 1,080.73 662.84 Ozone season-day emissions for the county were calculated by first multiplying annual emissions by the percentage of C&I natural gas used during the ozone season (18.04%). (Figures reported by natural gas suppliers for the June–August time period are assumed to be representative of the July–September ozone season.) Ozone season emission totals are then divided by the number of days that activity occurs during the ozone season (6 days/wk × 13 wks/yr). Annual and season-day emissions within the eight-hour ozone nonattainment area were calculated by applying the combined ratio of retail, office, public and other employment in the nonattainment area to county-level emission calculations (99.88%). (See Section 1.5.1 for a discussion of the employment data used). Table 3.2–9. combustion. Annual and season-day emissions from area-source commercial/institutional natural gas Geographic area Maricopa County 8-hr ozone NAA 3.2.5 Annual emissions (tons/yr) VOC NOx CO 54.48 1,080.73 662.84 54.42 1,079.44 662.05 Season-day emissions (lbs/day) VOC NOx CO 252.0 4,998.0 3,065.4 251.7 4,992.0 3,061.7 Residential distillate oil Annual emissions from residential distillate oil were derived from EPA NEI (US EPA, 2012c) calculations. Ozone season-day emissions would normally be calculated by dividing ozone season emissions by heating degree days (i.e. the number of degrees per day that the daily average temperature is below 65°F). However, data obtained from Arizona Energy Statistics (GOEP, 2013) indicated that there were no heating degree days reported during the 2011 ozone season (July–September). Thus, ozone season-day emissions from residential distillate oil combustion are assumed to be zero. Annual and season-day emissions within the eight-hour ozone nonattainment area were calculated by multiplying county totals by the ratio of total population in the nonattainment area to the total population in the county (101.14%). See Section 1.5.1 for a further discussion of the population used. Table 3.2–10 summarizes annual and ozone season-day emissions from residential distillate oil combustion for both the county and the eight-hour ozone nonattainment area. 2011 Ozone Precursor Emissions Inventory 22 February 2014 Table 3.2–10. Annual and season-day emissions from residential distillate oil combustion. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 0.01 0.35 0.10 0.0 0.0 0.0 8-hr ozone NAA 0.01 0.35 0.10 0.0 0.0 0.0 3.2.6 Residential natural gas All natural gas suppliers in Maricopa County were surveyed to gather information on the volume of natural gas sold, by user category, within the county. Annual emissions from residential natural gas combustion emissions were calculated by multiplying 2011 residential natural gas sales (18,113.11 MMCF) by emission factors for residential natural gas combustion summarized in the table below (US EPA, 1998). Table 3.2–11. Residential natural gas combustion emission factors. Pollutant Emission Factor (lb/MMCF) VOC 5.5 NOx 94.0 CO 40.0 Ozone season-day emissions were calculated by first multiplying reported natural gas usage during the ozone season (1,978.95 MMCF) by the AP-42 emission factors for residential natural gas combustion to produce ozone season emissions. (Natural gas usage reported for the months of June–August is assumed to represent ozone season usage). Ozone season emissions were then divided by days during the ozone season that residential natural gas combustion occurs (7 days/wk × 13 wks/yr) (US EPA, 2001a). Annual and season-day residential natural gas emissions in the eight-hour ozone nonattainment area were calculated by multiplying county-level emissions by the percentage of total resident population in the eight-hour ozone nonattainment area (100.78%). Table 3.2–12. Annual and season-day emissions from residential natural gas combustion. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 49.81 851.32 362.26 119.6 2,044.2 869.9 8-hr ozone NAA 50.20 857.96 365.09 120.5 2,060.1 876.7 3.2.7 Residential liquefied petroleum gas (LPG) Annual emissions from residential liquefied petroleum gas (LPG) were derived from EPA NEI (US EPA, 2012c) calculations. Ozone season-day emissions would normally be calculated by dividing ozone season emissions by heating degree days (i.e. the number of degrees per day that the daily average temperature is below 65°F). However, data obtained from Arizona Energy Statistics (GOEP, 2013) indicated that there were no heating degree days reported during the 2011 ozone season (July–September). Thus, ozone season-day emissions from residential liquefied petroleum gas (LPG) combustion are assumed to be zero. 2011 Ozone Precursor Emissions Inventory 23 February 2014 Annual and season-day emissions within the eight-hour ozone nonattainment area were calculated by multiplying county totals by the ratio of total population in the nonattainment area to the total population in the county (101.14%). See Section 1.5.1 for a further discussion of the population used. Table 3.2–13 summarizes annual and ozone season-day emissions from residential liquefied petroleum gas (LPG) combustion for both the county and the eight-hour ozone nonattainment area. Table 3.2–13. Annual and season-day emissions from residential liquefied petroleum gas (LPG) combustion. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 2.00 51.35 14.56 0.0 0.0 0.0 8-hr ozone NAA 2.02 51.93 14.73 0.0 0.0 0.0 3.2.8 Residential kerosene Annual emissions from residential kerosene were derived from EPA NEI (US EPA, 2012c) calculations. Ozone season-day emissions would normally be calculated by dividing annual emissions by heating degree days (i.e. the number of degrees per day that the daily average temperature is below 65°F). However, data obtained from Arizona Energy Statistics (GOEP, 2013) indicated that there was no heating degree days reported during the 2011 ozone season (July–September). Thus, ozone season-day emissions from residential kerosene combustion are assumed to be zero. Annual and season-day emissions within the eight-hour ozone nonattainment area were calculated by multiplying county totals by the ratio of total population in the nonattainment area to the total population in the county (101.14%). See Section 1.5.1 for a further discussion of the population used. Table 3.2–14 summarizes annual and season-day emissions from residential kerosene combustion for both the county and the eight-hour ozone nonattainment area. Table 3.2–14. Annual and season-day emissions from residential kerosene combustion. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 0.00 0.03 0.01 0.0 0.0 0.0 8-hr ozone NAA 0.00 0.03 0.01 0.0 0.0 0.0 3.2.9 Residential wood combustion Annual emissions from residential wood combustion for Maricopa County were obtained from the US Environmental Protection Agency’s Residential Wood Combustion Estimation Tool (US EPA, 2012b). County-level annual emissions by appliance type are shown below in Table 3.2– 15. 2011 Ozone Precursor Emissions Inventory 24 February 2014 Table 3.2–15. Annual emissions by appliance type for Maricopa County from EPA’s residential wood combustion estimation tool. Annual emissions (tons/yr) SCC Appliance Type VOC NOx CO 2104008100 Fireplace 191.08 26.29 1,506.38 2104008210 Woodstove: fireplace inserts; non-EPA certified 147.35 7.78 641.66 2104008220 Woodstove: fireplace inserts; EPA certified; non-catalytic 10.70 2.03 125.54 2104008230 Woodstove: fireplace inserts; EPA certified; catalytic 4.46 0.59 31.02 2104008310 Woodstove: freestanding, non-EPA certified 71.45 3.77 311.15 2104008320 Woodstove: freestanding, EPA certified, non-catalytic 5.18 0.99 60.83 2104008330 Woodstove: freestanding, EPA certified, catalytic 2.16 0.29 15.04 2104008400 Woodstove: pellet-fired, general 0.01 1.19 4.97 2104008610 Hydronic heater: outdoor 0.00 0.00 0.00 2104008700 Outdoor wood burning device, NEC 3.99 0.55 31.49 2104009000 Residential firelog 73.32 14.24 231.82 Total 509.70 57.72 2,959.91 Ozone season-day emissions would normally be calculated by dividing ozone season emissions by heating degree days (i.e. the number of degrees per day that the daily average temperature is below 65°F). However, data obtained from Arizona Energy Statistics (GOEP, 2013) indicated that there was no heating degree days reported during the 2011 ozone season (July–September). Thus, ozone season-day emissions from residential wood combustion are assumed to be zero. Annual and season-day emissions within the eight-hour ozone nonattainment area were calculated by multiplying county totals by the ratio of total population in the nonattainment area to the total population in the county (101.14%). See Section 1.5.1 for a further discussion of the population used. Table 3.2–16 summarizes annual and season-day emissions from residential wood combustion for both the county and the eight-hour ozone nonattainment area. Table 3.2–16. Annual and season-day emissions from residential wood combustion. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 509.70 57.72 2,959.91 0.0 0.0 0.0 8-hr ozone NAA 515.53 58.38 2,993.75 0.0 0.0 0.0 3.3 Industrial processes 3.3.1 Chemical manufacturing Emissions from area-source chemical manufacturing were calculated by the “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from the US Census Bureau (2012) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP), representing 2010 employment, were used. Table 3.3–1 shows the NAICS codes and employment data used to calculate emissions from chemical manufacturing. 2011 Ozone Precursor Emissions Inventory 25 February 2014 Table 3.3–1. County-level employment estimates for chemical manufacturing, by NAICS code. NAICS Estimated code NAICS description (and employment range) employment 325 Chemical manufacturing 4,605 42469 Other chemical & allied products merchant wholesalers 1,484 424910 Farm supplies merchant wholesalers 904 33312 Construction machinery manufacturing (250–499) 375 Total: 7,368 Since there were no point sources in this category, an area-source employment estimate is used to “scale up” emissions reported from those facilities surveyed in 2011. Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the percentage industrial employment within the nonattainment area. See Section 1.5.1 for a discussion of the employment data used. Table 3.3–2 summarizes annual and season-day emissions from chemical manufacturing in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.3–2. Annual and season-day emissions from area-source chemical manufacturing. Geographic area Annual emissions (tons/yr) Season-day emissions (lbs/day) Maricopa County 77.42 599.0 8-hr ozone NAA 77.09 596.5 3.3.2 Food and kindred products 3.3.2.1 Commercial cooking Emissions from commercial cooking were estimated for five types of commercial cooking equipment using per capita emissions factors developed by EPA for the 2008 National Emissions Inventory (NEI) (Pechan, 2012a). The per capita emission factors for each equipment type are contained in Table 3.3–3. EPA created the emission factors listed in Table 3.3–3 by taking 2002 emissions in the NEI and dividing by the 2002 population to develop per capita emission factors. The equipment types include: chain-driven charbroilers, under-fired charbroilers, deep-fat fryers, flat griddles, and clamshell griddles. Table 3.3–3. Emission factors for commercial cooking equipment, by device type. Emission Factor (lb/person) Equipment type VOC CO Chain-driven charbroilers 0.012056010 0.042446624 Under-fired charbroilers 0.041480307 0.135002176 Deep-fat fryers 0.012608151 0.000000000 Flat griddle fryers 0.005943281 0.012687330 Clamshell griddles 0.000231564 0.000000000 Annual commercial cooking emissions for Maricopa County were estimated by multiplying the MAG-estimated county population (4,129,646) by the per capita emission factors for each type of cooking equipment. See Section 1.5.1 for a discussion of the population data used. 2011 Ozone Precursor Emissions Inventory 26 February 2014 Commercial cooking is assumed to occur uniformly throughout the year, therefore, it was assumed that 25% of annual activity occurs during the ozone season, and that activity occurs 7 days/week. Thus, season-day emissions were estimated by multiplying annual emissions by 25% then dividing the result by 91 (7 days/wk × 13 wks/ozone season). The results are shown in Table 3.3–4 below. Table 3.3–4. Annual and daily emissions from commercial cooking equipment in Maricopa County. Annual Emissions Season-day (tons/yr) emissions (lbs/day) Equipment type VOC CO VOC CO Chain-driven charbroilers 24.89 87.64 136.8 481.6 Under-fired charbroilers 85.65 278.76 470.6 1,531.6 — Deep-fat fryers 26.03 143.0 0.0 Flat griddles 12.27 26.20 67.4 143.9 — Clamshell griddles 0.48 2.6 0.0 Total: 149.33 392.60 820.5 2,157.1 Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the county totals by the ratio of total population in the nonattainment area to the total population in the county (101.14%). See Section 1.5.1 for a discussion of the population data used. Table 3.3–5 summarizes the annual and season-day emissions from commercial cooking for the eight-hour ozone nonattainment area. Table 3.3–5. Annual and daily emissions from commercial cooking equipment in the eight-hour ozone NAA. Annual emissions Season-day (tons/yr) emissions (lbs/day) Equipment type VOC CO VOC CO Chain-driven charbroilers 25.18 88.64 138.3 487.1 Under-fired charbroilers 86.63 281.93 476.0 1,549.1 Deep-fat fryers 26.33 0.00 144.7 0.0 Flat griddles 12.41 26.50 68.2 145.6 Clamshell griddles 0.48 0.00 2.7 0.0 Total: 151.03 397.07 829.8 2,181.7 3.3.2.2 Bakeries Emissions from area-source bakeries were calculated by the “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources and County-level employment data from the US Census Bureau (2012) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2010 employment were used. (Where employment estimates were provided as a range of values, the midpoint was used.) CBP estimates for Maricopa County employment in NAICS codes 311812 and 31183 (Commercial bakeries and Tortilla manufacturing) to total 2,491 persons. There were no point sources in this category, thus all emissions from this source category are reported as area sources. Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. 2011 Ozone Precursor Emissions Inventory 27 February 2014 Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the ratio of industrial employment in the nonattainment area to industrial employment in the county. Results are summarized in Table 3.3–6. See section 1.5.1 for a discussion of the employment data used. Table 3.3–6. Annual and season-day emissions from area-source bakeries. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 78.18 547.8 8-hr ozone NAA 77.85 545.4 3.3.3 Secondary metal production Annual emissions from secondary metal production facilities were derived from annual emissions reports from permitted sources. As this category consists primarily of foundries, it was assumed that there were no significant unpermitted sources within Maricopa County. Since all facilities considered in this section are located within the eight-hour ozone nonattainment area, total emission values for the county and the nonattainment area from secondary metal production are equal. Annual and season-day emissions are shown in Table 3.3–7. Table 3.3–7. Annual and season-day emissions from area-source secondary metal production. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 41.01 15.02 98.36 306.4 107.9 697.4 8-hr ozone NAA 41.01 15.02 98.36 306.4 107.9 697.4 3.3.4 Rubber/plastics product manufacturing Emissions from area-source rubber and plastic manufacturing facilities were calculated by the “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from the US Census Bureau (2012) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2010 employment were used. Where CBP employment estimates were presented as a range, the midpoint values were chosen for these calculations. Table 3.3–8 shows the NAICS codes and employment data used to calculate emissions from rubber and plastic manufacturing facilities. 2011 Ozone Precursor Emissions Inventory 28 February 2014 Table 3.3–8. County-level employment estimates for rubber and plastic product manufacturing, by NAICS code. NAICS Estimated code NAICS description (and employment range) employment 325211 Plastic material and resin manufacturing (0–19) 10 325991 Custom compounding of purchased resins (100–249) 175 326140 Polystyrene foam product manufacturing 164 326199 All other plastics product manufacturing 3,027 326212 Tire retreading 135 326299 All other rubber product manufacturing 92 332313 Plate work manufacturing 151 336413 Other aircraft parts and aux. equipment manufacturing 2,086 337920 Blind and shade manufacturing (250–499) 375 339115 Ophthalmic goods manufacturing 97 423830 Industrial machinery & equip. merchant wholesalers 2,634 423930 Recyclable material merchant wholesalers 1,268 441310 Automotive parts and accessories stores 3,392 441320 Tire dealers 2,095 Total: 15,701 Some facilities in this category are considered point sources, and have been addressed in Chapter 2. To avoid double-counting, employment at point sources is subtracted from total employment. Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the ratio of industrial employment in the nonattainment area to industrial employment in the county. See Section 1.5.1 for a discussion of the employment data used. Table 3.3–9 summarizes annual and season-day emissions from area source rubber and plastic products manufacturing in Maricopa County and the eight-hour ozone nonattainment area. Table 3.3–9. Annual and season-day emissions from area-source rubber/plastic product manufacturing. Geographic area Annual VOC Season-day VOC emissions (tons/yr) emissions (lbs/day) Maricopa County 1,766.75 14,171.0 8-hr ozone NAA 1,759.15 14,110.1 3.3.5 Electrical equipment manufacturing Annual and season-day emissions from electric equipment manufacturing were derived from annual emissions reports submitted by permitted sources. It was assumed that there were no significant unpermitted sources within Maricopa County and all electrical equipment manufacturing permitted sources are reported here as area-sources. As all facilities addressed in this source category are located within the eight-hour ozone nonattainment area, emission totals for both areas are equal. Annual and season-day emissions are shown in Table 3.3–10. 2011 Ozone Precursor Emissions Inventory 29 February 2014 Table 3.3–10. Annual and season-day emissions from area-source electric equipment manufacturing. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 122.80 23.47 2.98 746.2 135.8 16.4 8-hr ozone NAA 122.80 23.47 2.98 746.2 135.8 16.4 3.3.6 Industrial processes not elsewhere classified (NEC) Annual area-source emissions from other industrial processes not elsewhere classified (NEC) were derived primarily from annual emissions reports from permitted facilities. Other industrial processes include a wide array of industrial activities that are often specific to the permitted facility that reported the process. For this reason, it is assumed there are no significant emissions from other industrial processes, other than those reported by permitted facilities on their annual emissions reports. Ozone season-day emissions were calculated based on operating schedule information provided by individual facilities through MCAQD’s annual emissions reporting program. Emissions estimates for the eight-hour ozone nonattainment area were derived using data on the location of the facilities that report other industrial processes. In addition, emissions from ADEQ-permitted sources are included in this category due to a lack of specificity regarding the nature of the reported emissions. As a conservative estimate, all of these emissions were assumed to occur within the eight-hour ozone nonattainment area. Estimates of total emissions from this source category are presented in Table 3.3–11. Table 3.3–11. Annual and season-day emissions from industrial processes not elsewhere classified. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 48.51 224.92 91.84 325.6 1,245.8 525.2 8-hr ozone NAA 47.55 224.92 91.84 318.0 1,245.8 525.2 3.4 Solvent use 3.4.1 Surface coating 3.4.1.1 Architectural coatings VOC emissions from architectural coatings were calculated using a per-capita emission factor developed and used by EPA for the 2008 NEI (Pechan, 2012). Because Maricopa County Rule 335 contains an emission limit for coatings, the “controlled” VOC emission factor (2.41 lbs/person) was used. Annual VOC emissions for architectural coating for both Maricopa County and the eight-hour ozone nonattainment area were calculated by multiplying the per-capita emission factor by the county and nonattainment area populations (4,129,646 and 4,176,870, respectively). See Section 1.5.1 for a discussion of the population data used. Ozone season-day emissions were developed using default assumptions from EIIP (US EPA, 1995a). The seasonal factor for ozone season architectural coating activity was assumed to be 28 percent of annual activity. In addition, it was assumed that coating use may take place 7 days a week during the ozone season (13 wks/season). Thus, season-day emissions were calculated by multiplying annual VOC emissions by the seasonal factor and then dividing the results by 91 days per season. Table 3.4–1 presents the assumptions used as well as annual and season-day 2011 Ozone Precursor Emissions Inventory 30 February 2014 VOC emissions from architectural coatings for Maricopa County and the eight-hour ozone nonattainment area. Table 3.4–1. Annual and season-day emissions from architectural coating. Annual VOC % annual Activity emissions activity in level Geographic area Population (tons/yr) ozone season (days/wk) Maricopa County 4,129,646 4,976.22 28 % 7 8-hr ozone NAA 4,176,870 5,033.13 28 % 7 Season-day VOC emissions (lbs/day) 30,622.9 30,973.1 3.4.1.2 Auto refinishing VOC emissions from auto refinishing were calculated using the per employee emission factor (89.0 lbs of VOC/employee) developed and reviewed by the Eastern Regional Technical Advisory Committee (ERTAC) advisory panel for the 2008 NEI (Pechan, 2012). The most recent employment estimates (for the year 2010) from the US Census Bureau’s County Business Patterns (CBP) were used (US Census Bureau, 2012). Employment data is listed by the North American Industry Classification System (NAICS) code(s). Table 3.4–2 shows the NAICS codes and employment estimates used to calculate emissions from auto refinishing. Table 3.4–2. NAICS code 81112 4411 4412 Total: County-level employment estimates for auto refinishing, by NAICS code. Estimated NAICS description employment Auto body, paint, interior, & glass repair 4,236 Auto dealers 22,632 Other motor vehicle dealers 3,093 29,961 The seasonal activity factor for ozone season auto refinishing was assumed to be 25 percent of annual activity. In addition, it was assumed that auto refinishing occurs evenly throughout the year, 5 days/wk (US EPA, 2001a). Thus, ozone season-day emissions were calculated by multiplying annual VOC emissions by the seasonal factor and then dividing the results by 65 days per season (5 days/wk × 13 wks/season). Annual and season-day emissions for the eight-hour ozone nonattainment area were derived by multiplying Maricopa County annual and season-day emissions by the ratio of industrial employment in the nonattainment area to industrial employment in the county (99.57%). See Section 1.5.1 for a discussion of the employment data used. Table 3.4–3. Annual and season-day emissions from auto refinishing. Annual VOC % annual Activity Season-day emissions activity in level VOC emissions Geographic area (tons/yr) ozone season (days/wk) (lbs/day) Maricopa County 1,333.26 25 % 5 10,255.9 8-hr ozone NAA 1,327.53 25 % 5 10,211.8 3.4.1.3 Traffic markings VOC emissions from traffic markings were calculated using the emissions factor developed by EPA for the 2008 NEI (22.1 lbs of VOC/road mile) (Pechan, 2012). Annual VOC emissions for 2011 Ozone Precursor Emissions Inventory 31 February 2014 the county were calculated by multiplying the VOC emission factor by 2010 Maricopa County public road and street mileage obtained from the Arizona Department of Transportation Highway Performance Monitoring System (HPMS). ADOT reported 16,253 miles of public roads and streets in Maricopa County in 2010, which was assumed to be representative of 2011 (M. Catchpole, pers. commun., August 9, 2012). Annual VOC emissions for the eight-hour ozone nonattainment area were estimated by multiplying the 2010 Maricopa County public road and street mileage by the percentage of miles within the nonattainment area (95.28%) and then multiplying by the VOC emission factor. MAG estimated the percentage of miles within the eight-hour ozone nonattainment area as compared to Maricopa County based on 2012 GIS highways and streets data (M. Poppen, pers. commun., October 1, 2012). The 2012 mileage data was assumed to be representative of 2011. Ozone season-day emissions during the ozone season for Maricopa County and the eight-hour ozone nonattainment area were calculated assuming 33 percent of annual activity occurred during the ozone season (13 wks per year) and a typical activity level of 5 days per week (US EPA, 1997). Table 3.4–4. Annual and season-day emissions from traffic markings. Annual VOC % annual Activity Season-day emissions activity in level VOC emissions Geographic area (tons/yr) ozone season (days/wk) (lbs/day) Maricopa County 179.60 33 % 5 1,823.6 8-hr ozone NAA 171.12 33 % 5 1,737.5 3.4.1.4 Factory-finished wood Emissions from factory-finished wood coating were calculated by the “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from the US Census Bureau (2012) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2011 employment were used. Where CBP employment estimates were presented as a range, the midpoint value was chosen for these calculations. Table 3.4–5 shows the NAICS codes and employment data used to calculate emissions from factory-finished wood surface coating. Table 3.4–5. County-level employment estimates for factory-finished wood coating, by NAICS code. NAICS Estimated code NAICS description (and employment range) employment 321911 Wood window & door manufacturing 299 321918 Other millwork 163 337212 Custom architectural woodwork & millwork manufacturing 368 337215 Showcase, partition, shelving & locker manufacturing 163 337920 Blind & shade manufacturing (250–499) 375 Total: 1,368 Since there were no point sources in this category, an area-source employment estimate was used to “scale up” emissions reported from those facilities surveyed in 2011. 2011 Ozone Precursor Emissions Inventory 32 February 2014 Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the ratio of industrial employment in the nonattainment area to industrial employment in the county (99.57%). See Section 1.5.1 for a discussion of the employment data used. Table 3.4–6 summarizes annual and season-day VOC emissions from factory-finished wood surface coating in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.4–6. Annual and season-day emissions from area-source factory-finished wood surface coating. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 137.72 1,396.7 8-hr ozone NAA 137.12 1390.7 3.4.1.5 Wood furniture Emissions from wood furniture surface coating were calculated by the “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from the US Census Bureau (2012) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2010 employment were used. Where CBP employment estimates were presented as a range, the midpoint values was chosen for these calculations. Table 3.4–7 shows the NAICS codes and employment data used to calculate emissions from wood furniture surface coating. Table 3.4–7. County-level employment estimates for wood furniture surface coating, by NAICS code. NAICS Estimated code NAICS code description employment 337110 Wood kitchen cabinet & countertop manufacturing 693 337121 Upholstered household furniture manufacturing 72 337122 Non-upholstered wood household furniture manufacturing 1,303 337129 Wood television, radio & sewing machine cabinet mfg. (0–19) 10 337211 Wood office furniture manufacturing (0–19) 10 811420 Re-upholstery & furniture repair 132 Total: 2,220 Some facilities in this category are considered point sources and have been addressed in Chapter 2. To avoid double-counting, employment at point sources was subtracted from total employment. Annual emissions were calculated by “scaling up” area-source emissions reported from those facilities surveyed in 2011. Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the ratio of industrial employment in the nonattainment area to industrial 2011 Ozone Precursor Emissions Inventory 33 February 2014 employment in the county (99.57%). See Section 1.5.1 for a discussion of the employment data used. Table 3.4–8 summarizes annual and season-day VOC emissions from wood furniture surface coating in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.4–8. Annual and season-day emissions from area-source wood furniture surface coating. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 416.56 3,434.7 8-hr ozone NAA 414.77 3,419.9 3.4.1.6 Aircraft surface coating Annual emissions from aircraft surface coating facilities were derived from annual emissions reports from permitted sources. It is assumed that all aircraft surface coating facilities were surveyed in 2011 based on a comparison of county-level employment data (US Census Bureau, 2012) and annual emissions report employment data. Ozone season-day emissions were calculated based on operating schedule information provided in the facilities’ annual emissions reports. Since all facilities considered in this section are located within the eight-hour ozone nonattainment area, total emission values for the county and the nonattainment area are equal. Table 3.4–9. Annual and season-day VOC emissions from area-source aircraft surface coating. Annual emissions Season-day emissions Geographic area (tons/yr) (lbs/day) Maricopa County 65.84 473.1 8-hr ozone NAA 65.84 473.1 3.4.1.7 Miscellaneous surface coating Area-source VOC emissions from miscellaneous surface coating were estimated by a “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions and employment data from Maricopa County permitted facilities to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category The typical “scale-up” methodology was revised slightly for this source category for a number of reasons. First, miscellaneous surface coating activity occurs, at some level, across an exceptionally broad spectrum of industries, both industrial and commercial/institutional. Additionally, annual emissions reports may be inconsistent in how activities are reported, and it is uncertain if all relevant activities are categorized as “miscellaneous surface coating” vs. some other category (e.g., manufacturing). Estimating total emissions from miscellaneous surface coating based on county employment by NAICS code (for which employment data are often presented only as a broad range), or all industrial employment (including industries which have little or no miscellaneous surface coating activities) would therefore be misleading and lead to an over-estimate of area-source emissions from this source category. Instead, the list of SIC codes used by facilities that reported miscellaneous surface coating activities was conservatively assumed to represent the “universe” of businesses that could possibly have significant miscellaneous surface coating activity. To avoid double-counting, employment at point sources was subtracted from total employment within these SIC categories. 2011 Ozone Precursor Emissions Inventory 34 February 2014 Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the ratio of industrial employment in the nonattainment area to industrial employment in the county (99.57%). See Section 1.5.1 for a discussion of the employment data used. Table 3.4–10 summarizes annual and season-day VOC emissions from area-source miscellaneous surface coating in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.4–10. Annual and season-day emissions from miscellaneous surface coating. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 316.38 2,450.5 8-hr ozone NAA 315.02 2,440.0 3.4.2 Degreasing Area-source VOC emissions from degreasing were estimated by a “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions and employment data from Maricopa County permitted facilities to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The typical “scale-up” methodology was revised slightly for this source category for a number of reasons. First, degreasing activity occurs at some level across a wide spectrum of industries, both industrial and commercial/ institutional. Additionally, annual emissions reports may be inconsistent in how activities are reported and it is uncertain if all relevant activities are categorized as “degreasing” vs. some other category (e.g., manufacturing). Estimating total emissions from degreasing based on county employment by NAICS code (for which employment data are often presented only as a broad range), or all industrial employment (including industries which have little or no degreasing activities) would therefore be misleading and lead to an overestimate of area-source emissions from this source category. Instead, the list of SIC codes used by businesses that reported degreasing activities was conservatively assumed to represent the “universe” of businesses that could possibly have significant degreasing activity. To avoid double-counting, employment at point sources was subtracted from total employment within these SIC. Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the percentage of industrial employment within the nonattainment area. (See Section 1.5.1 for a discussion of the employment data used.) Table 3.4–11 summarizes annual and season-day emissions from area-source degreasing in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.4–11. Annual and season-day VOC emissions from area-source degreasing. 2011 Ozone Precursor Emissions Inventory 35 February 2014 Geographic area Maricopa County 8-hr ozone NAA 3.4.3 Annual emissions (tons/yr) 217.55 216.62 Season-day emissions (lbs/day) 1,451.1 1,445.1 Dry cleaning Dry cleaning facilities are identified as one of two types: those that use perchloroethylene and those that use a petroleum solvent (140 or Stoddard solvent) or other VOC-based solvent. Perchloroethylene is a synthetic solvent that is not considered photochemically reactive and therefore is not included in this inventory. Data from the 2008 periodic emissions inventory were grown to 2011 based on total population. Based on operating schedule information provided in the facilities’ historic annual emissions reports, it is assumed that operations occur evenly throughout the year, 5 days per week, thus season-day emissions were derived by dividing the annual total emissions by 260 (= 5 days/ wk × 52 weeks/yr). Annual and season-day emissions estimates for the eight-hour ozone nonattainment area were calculated by multiplying county-level emissions by the ratio of Maricopa County population to nonattainment area population. See Section 1.5.1 for a discussion of the population data used. Table 3.4–12 summarizes the annual and season-day VOC emissions from dry cleaning. Table 3.4–12. Annual and season-day emissions from dry cleaning. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 23.15 178.1 8-hr ozone NAA 23.42 180.1 3.4.4 Graphic arts Emissions from graphic arts were calculated by the “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from the US Census Bureau (2012) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2010 employment were used. Table 3.4–13 shows the NAICS codes and employment data used to calculate emissions from graphic arts. Table 3.4–13. NAICS code 323 5111 Total: County-level employment estimates for graphic arts, by NAICS code. Estimated NAICS description employment Printing & related support activities 3,892 Newspaper, periodical, book & database publishers 3,800 7,692 2011 Ozone Precursor Emissions Inventory 36 February 2014 There were no point sources in this category. An area-source employment estimate was used to “scale up” emissions reported from those facilities surveyed in 2011. Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the ratio of industrial employment in the nonattainment area to industrial employment in the county (99.57%). See Section 1.5.1 for a discussion of the employment data used. Table 3.4–14 summarizes annual and season-day emissions from graphic arts in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.4–14. Annual and season-day VOC emissions from area-source graphic arts sources. Annual emissions Season-day emissions Geographic area (tons/yr) (lbs/day) Maricopa County 290.98 2,225.7 8-hr ozone NAA 289.73 2,216.1 3.4.5 Miscellaneous industrial solvent use Area-source VOC emissions from miscellaneous industrial solvent use were estimated by a “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions and employment data from Maricopa County permitted facilities to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The typical “scale-up” methodology was revised slightly for this source category for a number of reasons. First, miscellaneous industrial solvent use occurs at some level across a wide spectrum of industries. Additionally, annual emissions reports may be inconsistent in how activities are reported, and it is uncertain if all relevant activities are categorized as “miscellaneous industrial solvent use” vs. some other category (e.g., manufacturing). Estimating total emissions from miscellaneous industrial solvent use based on county employment by NAICS code (for which employment data are often presented only as a broad range), or all industrial employment (including industries which have little or no solvent use activities) would therefore be misleading and lead to an overestimate of area-source emissions from this source category. Instead, the list of SIC codes used by businesses that reported miscellaneous industrial solvent use activities was conservatively assumed to represent the “universe” of businesses that could possibly have significant miscellaneous industrial solvent use activity. To avoid doublecounting, employment at point sources (addressed in Chapter 2) was subtracted from total employment within these SICs. Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the ratio of industrial employment in the nonattainment area to industrial employment in the county. See Section 1.5.1 for a discussion of the employment data used. 2011 Ozone Precursor Emissions Inventory 37 February 2014 Table 3.4–15 summarizes annual and season-day VOC emissions from area-source miscellaneous industrial solvent use in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.4–15. Annual and season-day emissions from area-source miscellaneous industrial solvent use. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 721.85 5,126.6 8-hr ozone NAA 718.75 5,104.6 3.4.6 Consumer and commercial products Consumer and commercial products emissions include emissions from the following seven product categories: personal care products, household products, automotive aftermarket products, adhesives and sealants, FIFRA-regulated products, coatings and related products, and miscellaneous products. Annual area-source VOC emissions from consumer and commercial products were calculated by multiplying per-capita emission factors recommended by the Eastern Regional Technical Advisory Committee (Pechan, 2012c) by the population estimates for Maricopa County and the eight-hour ozone nonattainment area (see Section 1.5.1 for a discussion of population data). Ozone season-day emissions for the county and the eight-hour ozone nonattainment area were calculated by dividing annual emissions by 365 days as activity is assumed to occur uniformly throughout the year according to EIIP guidance (US EPA, 2001a). Table 3.4–16. Annual and season-day emissions from consumer and commercial products. Maricopa County 8-hr ozone NAA Emission Annual VOC Season-day Annual VOC Season-day emissions VOC emissions emissions VOC emissions factor Product category (lbs/person) (tons/yr) (lbs/day) (tons/yr) (lbs/day) Personal care 1.9 3,923.16 21,496.8 3,968.03 21,742.6 Household 1.8 3,716.68 20,365.4 3,759.18 20,598.3 Automotive aftermarket 1.36 2,808.16 15,387.2 2,840.27 15,563.1 Coatings and related 0.95 1,961.58 10,748.4 1,984.01 10,871.3 Adhesives/sealants 0.57 1,176.95 6,449.0 1,190.41 6,522.8 FIFRA-regulated 1.78 3,675.38 20,139.1 3,717.41 20,369.4 Miscellaneous 0.07 144.54 792.0 146.19 801.0 Total: 8.43 17,406.46 95,377.9 17,605.51 96,468.5 3.4.7 Asphalt application Asphalt is applied to pave, seal, and repair surfaces such as roads, parking lots, drives, walkways, roofs, and airport runways. In the past, MCAQD estimated emissions from asphalt application by allocating state-level asphalt usage data obtained from the Asphalt Institute to Maricopa County by the use of two surrogates: vehicle miles traveled (VMT) and population. However, the Asphalt Institute no longer compiles asphalt usage data by state. Therefore, 2011 emissions from asphalt application were calculated by growing 2008 asphalt emissions to 2011 based on VMT and population. Asphalt emissions were grown for three categories of asphalt application: roofing, cutback and emulsified. A population-based growth factor was used to grow 2008 roofing asphalt emissions 2011 Ozone Precursor Emissions Inventory 38 February 2014 to 2011, while a VMT-based growth factor was used to grow 2008 cutback and emulsified asphalt emissions to 2011. Table 3.4–17 shows 2008 and 2011 VMT and population for Maricopa County and the eighthour ozone nonattainment area. Table 3.4–17. 2008 and 2011 population and VMT, by geographic area. Total population Maricopa County 8-hr ozone NAA 2008 4,279,760 4,322,710 2011 4,129,646 4,176,870 Change, 2008–2011 –3.51% –3.37% Vehicle miles traveled (mi/day) 2008 2011 Change, 2008–2011 91,257,000 88,885,000 –2.60% 88,713,000 83,874,000 –5.45% Table 3.4–18 details county VOC emissions from asphalt application by asphalt type and the growth factors used to estimate 2011 emissions. Table 3.4–18. Emissions from asphalt use, by type, in Maricopa County. 2008 2011 Annual VOC Season-day 2008:2011 Annual VOC Season-day emissions VOC emissions growth emissions VOC emissions Asphalt type (tons/yr) (lbs/day) factor (tons/yr) (lbs/day) Cutback 858.15 4,689.3 –2.60% 835.84 4,567.4 Emulsified 889.17 4,858.9 –2.60% 866.06 4,732.6 Roofing 3.15 24.3 –3.51% 3.04 23.4 Total: 1,750.47 9,572.5 1,704.94 9,323.5 Annual and season-day emissions for the eight-hour ozone nonattainment area were also grown from 2008 by multiplying the 2008 nonattainment area emission by a 2008:2011 growth factor for VMT within the nonattainment area (for cutback and emulsified asphalt) and population within the nonattainment area (for roofing asphalt). Table 3.4–19 details nonattainment area asphalt emissions by type and the factors used to grow 2008 nonattainment area emissions to 2011. Table 3.4–19. Asphalt type Cutback Emulsified Roofing Total: Emissions from asphalt use, by type, in the eight-hour ozone NAA. 2008 2011 Annual VOC Season-day 2008:2011 Annual VOC Season-day emissions VOC emissions growth emissions VOC emissions (tons/yr) (lbs/day) factor (tons/yr) (lbs/day) 834.22 4,558.6 –5.45% 788.72 4,309.9 864.39 4,723.4 –5.45% 817.24 4,465.8 3.19 24.5 –3.37% 3.08 23.7 1,701.80 9,306.5 1,609.04 8,799.4 2011 Ozone Precursor Emissions Inventory 39 February 2014 3.4.8 Agricultural pesticides Annual emissions from agricultural pesticide usage within Maricopa County were obtained from the US Environmental Protection Agency’s 2011 National Emissions Inventory data and documentation (US EPA, 2012c). US EPA estimated 362.93 tons of VOCs were emitted from agricultural pesticide usage in Maricopa County in 2011. Agricultural pesticide data for 2011 were obtained from the Arizona Department of Agriculture’s 1080 Investigative Search website (ADA, 2013). This data was used to determine ozone season emissions from agricultural pesticide applications. The data included quantities of pesticides applied and the date of pesticide application. Quantities reported in gallons were converted to pounds assuming 8.33 lbs per gallon. The data showed approximately 2,086,356 lbs of agricultural pesticides were applied in Maricopa County in 2011. Based on the date of pesticide application, approximately, 36.4% (759,349 lbs.) of agricultural pesticides were applied during the ozone season. Ozone season-day emissions for Maricopa County were calculated by multiplying annual emissions (362.93 tons) by 36.4% and then dividing the result by 91 days/season (7 days/wk × 13 wks/ozone season). Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying county totals by the ratio of agricultural land located in the nonattainment area to the agricultural land in the county (58.46%). See Section 1.5.1 for a further discussion of the land use data used. Table 3.4–20. Annual and season-day emissions from agricultural pesticide application. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 362.93 2,903.4 8-hr ozone NAA 212.18 1,697.5 3.5 Storage and transport 3.5.1 Portable fuel containers Annual Maricopa County emissions from area-source portable fuel containers (PFCs) were obtained from the US Environmental Protection Agency’s 2011 National Emissions Inventory (US EPA, 2012c). These calculations identify a total of seven mechanisms by which emissions can be generated from portable fuel containers: • • • Emissions associated with filling the gas can at the gas pump: – Displacement of the vapor within the can, and – Spillage of gasoline while filling the can Emissions associated with transporting the gas can: – Spillage of gasoline during transport Emissions (adjusted for changes in ambient temperature) associated with storage of the gasoline in the PFCs: – Emissions due to evaporation (i.e., diurnal emissions), and – Emissions due to permeation. 2011 Ozone Precursor Emissions Inventory 40 February 2014 Two additional sources of emissions associated with using PFCs to refuel pieces of nonroad equipment are considered by the NONROAD model (described in Chapter 4) and thus not addressed here: – Displacement of the vapor within nonroad equipment, and – Spillage of gasoline while filling nonroad equipment. Ozone season-day emissions for the county were calculated by dividing annual emissions by 365 days as activity is assumed to occur uniformly throughout the year. Annual and ozone season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the county totals by the ratio of total population in the nonattainment area to total population in the county (101.14%). See Section 1.5.1 for a discussion of the employment data used. Table 3.5–1 summarizes annual and season-day VOC emissions from portable fuel containers in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.5–1. Annual and season-day emissions from portable fuel containers (PFCs). Maricopa County Eight-hour ozone NAA Season-day Season-day Annual VOC VOC Annual VOC VOC emissions emissions emissions emissions Emissions source (tons/yr) (lbs/day) (tons/yr) (lbs/day) Permeation: Residential 887.25 4,875.0 897.40 4,930.8 Evaporation/diurnal: Residential 1,732.33 9,518.3 1,752.15 9,627.2 Spillage during transport: Residential 226.04 1,242.0 228.63 1,256.2 Vapor displacement in PFCs: Residential 82.87 455.3 83.82 460.5 Spillage at pump: Residential 6.60 36.2 6.67 36.7 Permeation: Commercial 28.34 155.7 28.66 157.5 Evaporation/diurnal: Commercial 55.33 304.0 55.96 307.5 Spillage during transport: Commercial 308.36 1,694.3 311.89 1,713.7 Vapor displacement in PFCs: Commercial 159.71 877.5 161.54 887.6 Spillage at pump: Commercial 12.69 69.7 12.84 70.5 Displacement during refueling of nonroad equipment* Spillage during refueling of nonroad equipment* Total: 3,499.52 19,228.2 3,539.56 19,448.1 *These activities are included in the NONROAD model emissions calculations, described in Chapter 4. 3.5.2 Bulk plants Emissions from this source category were calculated from annual emissions inventory reports from all bulk plants located within the county. It is assumed that there are no unpermitted bulk plants in Maricopa County. To avoid double-counting, emissions from bulk terminals are treated as point sources (totaling 105.94 tons/yr) and thus are reported in Chapter 2. Ozone season-day emissions were calculated based on operating schedule information provided in the facilities annual emissions reports. Since all facilities considered in this section are located within the eight-hour ozone nonattainment area, total emission values for the county and the eight-hour ozone nonattainment area are equal. 2011 Ozone Precursor Emissions Inventory 41 February 2014 Table 3.5–2. Annual and season-day emissions from bulk plants. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 120.91 659.3 8-hr ozone NAA 120.91 659.3 3.5.3 Gasoline stations (Stage I) Stage I gasoline distribution emissions occur when gasoline vapors are displaced from storage tanks during unloading of gasoline from tank trucks at service stations. Following EPA methodologies (US EPA, 2001b), annual VOC emissions from gasoline service station unloading were calculated by multiplying gasoline sales (1,553,993 Mgals) (B. Steen, pers. commun., September 13, 2012) by emission factors provided in AP-42 (US EPA, 1995b) for each filling technology. Based on annual emissions reports from 2002, 98.5% of gasoline is delivered using balanced submerged filling with the remaining 1.5% delivered by submerged filling. Table 3.5–3 below shows the emission factors used. Table 3.5–3. Emission factors for gasoline service stations (Stage I). VOC emission factors Emission source (lbs of VOC/Mgal throughput) Submerged filling 7.3 Balanced submerged filling 0.3 Ozone season-day emissions were calculated by multiplying ozone-season (July–September) gasoline sales (376,616 Mgal) by the emission factors listed above, then dividing by 78 days (13 weeks in the ozone season × 6 days/week). As a conservative assumption, annual and season-day emissions for the eight-hour ozone nonattainment area are assumed to be equal to Maricopa County emissions. Table 3.5–4. Annual and season-day emissions from gasoline service stations (Stage I). Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County and 8-hr ozone NAA: –Submerged filling 85.08 528.7 –Balanced submerged filling 229.60 1,426.8 Total: 314.68 1,955.5 3.5.4 Gasoline stations (Stage II) Stage II gasoline service station emissions are the refueling emissions that occur during the transfer of gasoline from storage tanks at service stations to vehicle fuel tanks (i.e. vehicle refueling and spillage emissions). The MOVES2010b model that was used to calculate onroad emissions captures stage II emissions. Therefore, these emissions are addressed in Chapter 5 as part of the onroad mobile sources emissions and are no longer reported as an area source. 2011 Ozone Precursor Emissions Inventory 42 February 2014 3.5.5 Gasoline stations underground tanks, breathing/emptying Breathing losses are the expulsion of vapor from a tank vapor space that has expanded or contracted because of daily changes in temperature and barometric pressure; these emissions occur in the absence of any liquid level change in the tank. Emptying losses occur when the air that is drawn into the tank during liquid removal saturates with hydrocarbon vapor and expands, thus exceeding the fixed capacity of the vapor space and overflowing through the pressure vacuum valve. Following EPA methodologies (US EPA, 2001b), annual VOC emissions from storage tank breathing and emptying were calculated by multiplying annual gasoline throughput (1,553,993 Mgal [B. Steen, ADOT, pers. commun., September 13, 2012]) by the emission factor for underground tank breathing and emptying (1.0 lb/Mgal) found in AP-42 Table 5.2–7 (US EPA, 1995b). Ozone season-day VOC emissions were calculated using the same formula as above, using only the gasoline distributed during the ozone season (July–September, 376,616 Mgal) and dividing by the 91 days (13 weeks in the ozone season × 7 days per week that gasoline storage occurs). As a conservative estimate, all activity was assumed to occur within the nonattainment area; thus annual and season-day emissions estimates for the nonattainment area are equal to county totals. Table 3.5–5. Annual and season-day emissions from gasoline service stations underground tank, breathing and emptying. Geographic area Annual VOC Season-day VOC emissions (tons/yr) emissions (lbs/day) Maricopa County 777.00 4,138.6 8-hr ozone NAA 777.00 4,138.6 3.5.6 Airports: Aviation gasoline Aviation gasoline is used by small reciprocating, piston-engine aircraft in civil aviation. Commercial and military aviation rarely use aviation gasoline. Aviation gasoline is shipped to airports and is filled into bulk terminals, and then into tanker trucks. The displacement vapors during the transfer of gasoline from tank trucks to storage tanks, and vice versa falls under the definition of stage I. Stage II involves the transfer of fuel from the tanker trucks into general aviation aircraft. Annual emissions from aviation gasoline Stage I and Stage II were obtained from the US Environmental Protection Agency’s 2011 National Emissions Inventory (US EPA, 2012c). Table 3.5–6 shows US EPA 2011 estimated VOC emissions from aviation gasoline for Maricopa County. Table 3.5–6. Annual emissions from aviation gasoline for Maricopa County. VOC Emissions (tons/yr) Aviation Gasoline Stage I 347.57 Aviation Gasoline Stage II 18.04 Due to lack of data, daily emissions were assumed to be equal throughout the year and were calculated by dividing annual emissions by 365 days/year. 2011 Ozone Precursor Emissions Inventory 43 February 2014 Annual and season-day emission in the eight-hour ozone nonattainment area were calculated by multiplying county totals by the percentage of general aviation operations that occurred within the nonattainment area in 2011 (99.1%) (See Table 4.11–1 for general aviation aircraft operational data used). Table 3.5–7. Annual and season-day emissions from aviation gasoline. Maricopa County 8-hr ozone NAA Annual VOC Season-day Annual VOC Season-day emissions VOC emissions emissions VOC emissions (tons/yr) (lbs/day) (tons/yr) (lbs/day Aviation Gasoline Stage I 347.57 1904.5 344.41 1,887.2 Aviation Gasoline Stage II 18.04 98.8 17.87 97.9 3.5.7 Gasoline tank trucks in transit Emissions from tank trucks in transit occur when gasoline vapor evaporates from (1) loaded tank trucks during transportation of gasoline from bulk terminals/plants to service stations, and (2) empty tank trucks returning from service stations to bulk terminals/plants. Annual VOC emissions from gasoline trucks in transit were calculated by multiplying county-level tank truck gasoline throughput by a 0.06 lb of VOC per 1,000 gallon emission factor (Pechan, 2012b). Gasoline consumption for Maricopa County was determined from gasoline tax sales reports obtained from the Arizona Department of Transportation for 2011 (ADOT, 2012). Gasoline throughput for tank trucks was computed by multiplying the Maricopa County gasoline sales (1,553,992,539 gallons) by a transportation adjustment factor of 1.09 to account for gasoline that is transported more than once in a given area (i.e., transported from bulk terminals to bulk plant and then from bulk plant to service station) (Pechan, 2012b). Ozone season gasoline throughput for tank trucks was estimated by multiplying the gallons of gasoline sold (376,615,906 gallons) during the ozone-season (July-September) in Maricopa County by the 1.09 transportation adjustment factor noted above to account for gasoline that is transported more than once. Ozone season-day VOC emissions were calculated by multiplying the estimated ozone season gasoline throughput for tank trucks by the 0.06 lb of VOC per 1,000 gallon emission factor noted above and then dividing by 78 days (13 weeks × 6 days/wk). As a conservative estimate, all activity was assumed to occur within the nonattainment area; thus annual and season-day emissions estimates for the nonattainment area are equal to county totals. Table 3.5–8. Annual and season-day emissions from gasoline trucks in transit. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 50.82 315.8 8-hr ozone NAA 50.82 315.8 3.5.8 Pipeline gasoline Pipeline emissions result from the valves and pumps found at pipeline pumping stations and from the valves, pumps, and storage tanks at pipeline breakout stations. 2011 Ozone Precursor Emissions Inventory 44 February 2014 Annual VOC emissions from gasoline pipelines were derived based on the ratio of pipeline emissions to total emissions for bulk terminals, bulk plants, and pipelines as reported in the US Environmental Protection Agency’s 2011 National Emissions Inventory (NEI) (US EPA, 2012c). The NEI reported that 2011 pipeline emissions for Maricopa County were 12.53% of total emissions from bulk terminals, bulk plants, and pipelines. Thus, annual pipeline emissions for the county were derived by multiplying annual emissions reported in bulk plant emissions reports by 12.53%. Ozone season-day emissions were calculated in the same manner, by multiplying season-day emissions (derived from operating schedule information provided in the facilities annual emissions reports) by 12.53%. Since all facilities considered in this section are located within the eight-hour ozone nonattainment area, emissions for the county and the eight-hour ozone nonattainment area are equal. Table 3.5–9. Annual and season-day emissions from pipeline gasoline. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 17.32 94.5 8-hr ozone NAA 17.32 94.5 3.5.9 Volatile organic liquid (VOL) storage and transport Emissions from this source category were calculated by summing reported VOC emissions from volatile organic liquid storage/transfer emissions inventory reports. It is assumed that there are no significant unpermitted volatile organic liquid storage/transfer facilities in Maricopa County. To avoid double-counting, emissions from those facilities treated as point sources (totaling 28.8 tons/yr) are addressed in Chapter 2. Ozone season-day emissions were calculated based on operating schedule information provided in the facilities annual emissions reports. Table 3.5–10. Annual and season-day emissions from area-source volatile organic liquid storage/transport. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 30.54 182.7 8-hr ozone NAA 28.80 169.3 3.6 Waste treatment and disposal 3.6.1 On-site incineration This section includes emissions from on-site industrial incinerators, primarily burn-off ovens used to reclaim electric wire or other materials. Emissions from human and animal crematories are addressed in Section 3.7.5. There were no incinerators at residential (e.g., apartment complexes) or commercial/institutional facilities (e.g., hospitals, service establishments) in operation during 2011. Emissions from on-site incineration were determined from annual emissions inventory reports. It is assumed that all incinerator emissions are accounted for, since all permitted incinerators 2011 Ozone Precursor Emissions Inventory 45 February 2014 received surveys in 2011. All surveyed facilities are located within the eight-hour ozone nonattainment area, thus total emissions for the county and nonattainment area are equal. Table 3.6–1. Annual and season-day emissions from on-site incineration. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 0.17 3.31 0.79 1.1 21.4 5.3 8-hr ozone NAA 0.17 3.31 0.79 1.1 21.4 5.3 3.6.2 Open burning: Land clearing debris Emissions from controlled open burning are regulated by Maricopa County Air Pollution Control Regulations Rule 314 (Open Outdoor Fires and Indoor Fireplaces at Commercial and Institutional Establishments), which requires a burn permit for open burning in Maricopa County. Burn permits are issued primarily for purposes of agricultural ditchbank and fence row burning, tumbleweed burning, land clearance, and firefighting training. Maricopa County’s burn permit data base was used to identify all burn permits issued in 2011. A total of 57 open burn permits were issued during the year. The quantity and reported activity for the open burn permits (except for firefighting burn permits) are shown in Table 3.6–2. Table 3.6–2. Maricopa County burn permit activity. Number of Category permits Unit of measure Annual ditchbank & fence row 41 Linear Feet Land clearance 4 Acres Fire hazard 1 Acres Total reported activity 1,967,795 14.14 2 Emissions from land clearance and fire hazard open burning are addressed in this section whereas ditchbank and fence row burning are addressed in Section 3.7.1. The activity data for land clearance and fire hazard were converted to tons of material burned using fuel loading factor for “weeds, unspecified” from AP-42 (US EPA, 1992). The emission and loading factors used are shown in Table 3.6–3. Table 3.6–3. Emission and fuel loading factors for open burning. Emission factors (lbs/ton burned) Fuel loading factors (tons/acre) Category VOC NOx CO Weeds, unspecified 9 4 85 3.2 Activity data were multiplied by the 3.2 tons/acre fuel loading factor to derive the total mass of material burned. Annual emissions were then calculated by multiplying the amount of material burned by the AP-42 emission factors for “weeds, unspecified” (shown in Table 3.6–3). Based on an analysis of complaints received in 2011 reporting suspected open or illegal outside burning, emissions estimates were multiplied by a factor of 2.87 to account for unpermitted illegal outdoor burning. It was assumed that land clearance and fire hazard open burning occur 5 days per week (most burn permits are issued for weekdays but permits may be issued on weekends depending on 2011 Ozone Precursor Emissions Inventory 46 February 2014 circumstances) and evenly during the ozone season months (July–September). Thus, season-day emissions for Maricopa County were derived by dividing annual emissions (lbs/year) by 65 (5 days/wk × 13 wks/yr). Annual and season-day emissions for the nonattainment area were calculated by multiplying the percentage of vacant land use located in the eight-hour ozone nonattainment area (44.55%) by the Maricopa County emissions estimates. See Section 1.5.2 for a discussion of the land use data used. Table 3.6–4 summarizes 2011 annual and season-day emissions for the Maricopa County and the eight-hour ozone nonattainment area from land clearance and fire hazard open burning activity. Table 3.6–4. Annual and season-day emissions from land clearance and fire hazard open burning. Annual emissions (tons/yr) Season-day emissions (lbs/day) NOx NOx Geographic area VOC CO VOC CO Maricopa County 0.67 0.30 6.30 20.5 9.1 193.8 8-hr ozone NAA 0.30 0.14 2.81 9.1 4.1 86.4 3.6.3 Landfills Emissions from municipal solid waste (MSW) landfills come from uncontrolled landfill gas emissions as well as from combustion from control measures, such as a flare. Total emissions were calculated from annual emissions inventory reports from all landfills located within the county. Northwest Regional Landfill was considered a point sources; all other MSW landfills are reportered here as area source landfills. Since there are no landfills located outside the eight-hour ozone nonattainment area, total emission values for the county and the eight-hour ozone nonattainment area are equal. Annual and season-day emissions are shown in Table 3.6–5. Table 3.6–5. Annual and season-day emissions from landfills. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 36.59 30.40 108.55 200.7 167.4 596.4 8-hr ozone NAA 36.59 30.40 108.55 200.7 167.4 596.4 3.6.4 Publicly owned treatment works Annual emissions from publicly owned treatment works (POTW) in Maricopa County were obtained from the US Environmental Protection Agency’s 2011 National Emissions Inventory (US EPA, 2012c). EPA estimated 75.02 tons of VOC were emitted from POTWs in Maricopa County in 2011. There were no point sources in this category that needed to be subtracted. Ozone season-day emissions were calculated by multiplying annual emissions by a 35% season adjustment factor and then dividing by 91 days per season (US EPA, 2001a). Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the percentage of total population in the nonattainment area to the total population in the county (101.14%). See Section 1.5.1 for a discussion of the population data used. 2011 Ozone Precursor Emissions Inventory 47 February 2014 Table 3.6–6. VOC emissions from publicly owned treatment works. Annual emissions Season-day emissions Geographic area (tons/yr) (lbs/day) Maricopa County 75.02 577.1 8-hr ozone NAA 75.88 583.7 3.6.5 Leaking underground storage tanks Leaking underground storage tanks (LUST) are typically not considered a quantifiable source of air emissions until excavation and remediation efforts begin. The majority of air emissions from LUST site remediation occur during initial site action, which is typically tank removal. Emissions from soil occur as the tank is being removed and when soil is deposited on the ground before treatment/disposal occurs (US EPA, 2001c). A default emission rate of 28 lbs/day per remediation event was used to estimate VOC emissions from LUST remediation (US EPA, 2001c). Data obtained from the Arizona Department of Environmental Quality Leaking Underground Storage Tank Section indicated that 15 LUST opened in Maricopa County in 2011 (N. Giuntoli, pers. commun., March 19, 2013). Data were not available on the number or date of remediation that occurred in 2011; therefore, it was conservatively assumed that all 15 LUST were remediated in 2011 during the ozone season. It was also assumed that an initial site action (tank and soil removal) for an average LUST remediation lasts five days. Ozone season-day emissions were calculated by dividing annual values by 65 (5 days/wk × 13 wks/ozone season). To be conservative, it was assumed that all gasoline retail outlets were located within the ozone nonattainment area and therefore, annual and season-day emissions for the eight-hour ozone nonattainment area were assumed to be equal to the Maricopa County totals. Table 3.6–7. Annual and season-day emissions from remediation of leaking underground storage tanks. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 1.05 32.3 8-hr ozone NAA 1.05 32.3 3.6.6 Other waste Annual area-source emissions from other industrial waste disposal were derived from annual emissions reports from permitted facilities. Other industrial waste disposal processes include a wide array of industrial activities that are often specific to the permitted facility that reported the process. For this reason, it is assumed there are no significant emissions from this category, other than those reported by permitted facilities on their annual emissions reports. Ozone season-day emissions were calculated based on operating schedule information provided by the facilities in their annual emissions report. All surveyed facilities for this area source category are located inside the eight-hour ozone nonattainment area; therefore emissions for Maricopa County and the eight-hour ozone nonattainment area are equal. Table 3.6–8 summarizes annual and season-day emissions for Maricopa County and the nonattainment area. 2011 Ozone Precursor Emissions Inventory 48 February 2014 Table 3.6–8. Annual and season-day emissions from other waste. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 2.12 22.19 77.93 10.9 122.8 431.4 8-hr ozone NAA 2.12 22.19 77.93 10.9 122.8 431.4 3.7 Miscellaneous area sources 3.7.1 Agricultural field burning Agricultural ditchbank and fence row burning are regulated by Maricopa County Air Pollution Control Regulations Rule 314 (Open Outdoor Fires and Indoor Fireplaces at Commercial and Institutional Establishments) which requires a burn permit for open burning activity in Maricopa County. A total of 41 permits were issued during the year for ditchbank and fence row burning. The permit data indicated that a total of 1,967,795 linear feet of ditchbank and fence rows were burned in 2011. To calculate the amount of material burned, MCAQD assumed that ditchbanks and fence rows in Maricopa County average 7 feet in width and are burned twice per year, based on a previous Maricopa County emissions inventory (MCESD, 1999). MCAQD estimated 632.44 acres burned [(1,967,795 linear ft. × 7 ft. × 2)/43,560 ft/acre]. Acres burned were converted to tons of material burned using a 3.2 tons/acre fuel loading factor for “weeds, unspecified” from AP-42 (US EPA, 1992). This resulted in an estimated 2,023.81 ton of material burned. Annual emissions were then calculated by multiplying the amount of material burned by AP-42 emission factors for “weeds, unspecified” as shown in Table 3.7–1. Table 3.7–1. Emission factors for open burning. Emission factors (lbs/ton burned) Category VOC NOx CO Weeds, unspecified 9 4 85 Based on an analysis of 2011 complaints received reporting suspected open or illegal outside burning, emissions estimates were multiplied by a factor of 2.87 to account for unpermitted illegal outdoor burning. It was assumed that ditchbank and fence row burning occurs 5 days per week. Thus, season-day emissions were calculated by dividing annual emissions (in lbs) by 65 (5 days/wk × 13 wks/ozone season). Annual and season-day emissions for the nonattainment area were calculated by multiplying the percentage of agricultural land use within the eight-hour ozone nonattainment area (58.46%) by the Maricopa County emissions estimates. See Section 1.5.2 for a discussion of the land use data used. 2011 Ozone Precursor Emissions Inventory 49 February 2014 Table 3.7–2 summarizes annual and season-day emissions from ditchbank and fence row burning for Maricopa County and the eight-hour ozone nonattainment area. Table 3.7–2. Annual and season-day emissions from ditchbank and fence row burning. Annual emissions (tons/yr) Season-day emissions (lbs/day) Category VOC NOx CO VOC NOx CO Maricopa County 26.14 11.62 246.85 804.2 357.4 7,595.5 8-hr ozone NAA 15.28 6.79 144.32 470.2 209.0 4,440.7 3.7.2 Structure fires Structure fire emissions for Maricopa County were grown from 2008 based on county population growth from 2008 to 2011. Population data was provided by MAG and is shown in Table 3.7−3. Table 3.7–3. Maricopa County population growth, 2008 to 2011. 2008 2011 Maricopa Co. Total Population 4,279,760 4,129,646 % change –3.51% The 2008 annual emissions from structure fires in Maricopa County and the subsequently grown 2011 annual emissions are shown in Table 3.7–4. Table 3.7–4. Year 2008 2011 2008 and 2011 annual emissions from structure fires in Maricopa County. Annual emissions (tons/yr) VOC NOx CO 15.32 1.95 83.56 14.78 1.88 80.63 Annual emissions for the eight-hour ozone nonattainment area were derived by multiplying annual county emissions by the percentage of total residential population within the nonattainment area (101.14%). See Section 1.5.1 for a discussion of the population data used. It was assumed that structure fires occur 7 days a week; however, structure fires vary seasonally and may increase during cold weather. Because local season-specific data were not readily available, seasonal occurrences of residential and non-residential structure fires reported by the Federal Emergency Management Agency (FEMA) were used to derive a seasonal adjustment factor for the ozone season (US EPA, 2001d). FEMA reported that 20.9% of residential structure fires and 23.7% of non-residential structural fires occurred during July, August, and September 1994. Thus, an average occurrence of 22.3% [(20.9% + 23.7%) ÷ 2] was used as a seasonal adjustment factor to estimate ozone season-day emissions. Ozone season-day emissions for Maricopa County and the nonattainment area were derived by multiplying the annual emissions (in lbs) by the seasonal adjustment factor (22.3%) and then dividing by 91 (7 days/wk × 13 wks/ozone season). 2011 Ozone Precursor Emissions Inventory 50 February 2014 Table 3.7–5. Annual and season-day emissions from structure fires. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 14.78 1.88 80.63 72.4 9.2 395.2 8-hr ozone NAA 14.95 1.90 81.55 73.3 9.3 399.7 3.7.3 Aircraft engine testing Annual emissions from engine testing facilities were derived from annual emissions reports from permitted sources that were not considered point sources in this inventory. It was assumed that there were no significant unpermitted sources within Maricopa County. Ozone season-day emissions were calculated based on operating schedule information provided in the facilities’ annual emissions reports. Since all facilities considered in this section are located within the eight-hour ozone nonattainment area, total emission values for the county and the nonattainment area are equal. Results are shown in Table 3.7–6. Table 3.7–6. Annual and season-day emissions from aircraft engine testing. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 4.72 46.36 16.16 26.1 259.3 91.2 8-hr ozone NAA 4.72 46.36 16.16 26.1 259.3 91.2 3.7.4 Vehicle fires Vehicle fire emissions for Maricopa County were grown from 2008 based on county population growth from 2008 to 2011. The population data used is shown in Table 3.7−3. The 2008 annual emissions from vehicle fires in Maricopa County and the subsequently grown 2011 annual emissions are shown in Table 3.7–7. Table 3.7–7. Year 2008 2011 2008 and 2011 annual emissions from vehicle fires in Maricopa County. Annual emissions (tons/yr) VOC NOx CO 9.61 1.20 37.55 9.27 1.16 36.23 Annual emissions for the eight-hour ozone nonattainment area were derived by multiplying annual county emissions by the percentage of total residential population within the nonattainment area (101.14%). See Section 1.5.1 for a discussion of the population data used. It was assumed that vehicle fires occur evenly throughout the year. Thus, ozone season-day emissions were derived by dividing the Maricopa County and nonattainment area annual emissions (in lbs.) by 365 days/year. The results are shown in Table 3.7−8 below. Table 3.7–8. Annual and season-day emissions from vehicle fires. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 9.27 1.16 36.23 50.8 6.4 198.5 8-hr ozone NAA 9.38 1.17 36.64 51.4 6.4 200.8 2011 Ozone Precursor Emissions Inventory 51 February 2014 3.7.5 Crematories Emissions from human and animal crematories were calculated by the “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from the US Census Bureau (2012) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2010 employment were used. Table 3.7–9 shows the NAICS code and employment data used to calculate emissions from crematories. Table 3.7–9. County-level employment estimates for crematories, by NAICS code. NAICS Estimated code NAICS description employment 81222 Cemeteries and crematories 251 There were no point sources in this category. Area-source employment estimate were used to “scale up” emissions reported from those facilities surveyed in 2011. Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the ratio of industrial employment in the nonattainment area to industrial employment in the county. See Section 1.5.1 for a discussion of the employment data used. Table 3.7–10 summarizes annual and season-day emissions from crematories in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.7–10. Annual and season-day emissions from crematories. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 1.18 11.19 2.23 51.1 88.5 17.3 8-hr ozone NAA 1.18 11.14 2.22 50.9 88.1 17.2 3.7.6 Accidental releases As part of its air quality permit compliance program, MCAQD keeps an “upset log” for each calendar year that records excess emissions and accidental releases at permitted facilities. Annual emissions inventory reports also provide for recording of accidental releases. Data from these two sources documented the release of 0.45 tons of VOC for the year 2012. Ozone season-day emissions were calculated based on the whether the reported release occurred during the ozone season. If emissions occurred during the ozone season, those emissions were summed and divided by the number of days in the ozone season to produce season-day emissions. Emissions within the eight-hour ozone nonattainment area are calculated based on locations of facilities that reported releases. Results are shown in Table 3.7–11. 2011 Ozone Precursor Emissions Inventory 52 February 2014 Table 3.7–11. Annual and season-day emissions from accidental releases. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 0.45 0.0 0.0 2.1 0.0 0.0 8-hr ozone NAA 0.45 0.0 0.0 2.1 0.0 0.0 3.7.7 Hospitals Emissions from hospitals were calculated by the “scaling up” method as described in EPA emissions inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources and county-level employment data from the US Census Bureau (2012) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2010 employment were used. CBP employment data for NAICS code 662110 (general medical and surgical hospitals) indicated 59,646 employees in this industry in Maricopa County. Ozone season-day emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and season-day emissions for the eight-hour ozone nonattainment area were calculated by multiplying the Maricopa County emission totals by the ratio of population in the nonattainment area to population in the county. See Section 1.5.1 for a discussion of the employment data used. Table 3.7–12 summarizes annual and season-day emissions from hospitals in both Maricopa County and the eight-hour ozone nonattainment area. Table 3.7–12. Annual and season-day emissions from hospitals. Annual VOC Season-day VOC Geographic area emissions (tons/yr) emissions (lbs/day) Maricopa County 8.57 52.3 8-hr ozone NAA 8.66 52.9 3.7.8 Wildfires 2011 Maricopa County wildfire data were obtained from the Arizona State Forestry Division (ASFD) (G. Buettner, pers. commun., December 17, 2012); the National Wildfire Coordinating Group (NWCG, 2012), and the US Fire Administration, National Fire Data Center (USFA, 2012). The Arizona State Forestry Division (ASFD) provides for the prevention and suppression of wildfires on state trust land and private lands located outside of incorporated communities. The wildfire data provided by ASFD includes wildfires that occur outside of local fire districts and municipalities on State, private, and U.S. Bureau of Land Management (BLM) land. In 2011, the (ASFD) reported 5 wildfires in Maricopa County, encompassing 15.2 acres. Wildfire data provided by ASFD were compared to 2011 Incident Status Summary reports (ICS209) to identify wildfires that may have occurred outside of ASFD jurisdiction. ICS-209 reports only include large wildfires, generally fires greater than 100 acres. ICS-209 reports showed two additional Maricopa County wildfires in 2011, totaling 2,006 acres (NWCG, 2012). 2011 Ozone Precursor Emissions Inventory 53 February 2014 Lastly, 2011 National Fire Incident Reporting System (NFIRS) data were obtained from the US Fire Administration (USFA, 2012). NFIRS is a voluntary national reporting system used by fire departments to report fires and other incidents to which they respond and to maintain records of these incidents in a uniform manner. However, not all fire departments report to NFIRS and they may not report all of their fire incidents. The 2011 NFIRS data was culled for wildland fires greater than 1 acre that contained either latitude and longitude or township and range information. Wildfire data for Arizona included 18 fires which met these criteria; however, only 2 of these fires were located within Maricopa County, encompassing 7 acres. The NFIRS data was compared to the ASFD data to identify duplicates by comparing the incident dates and locations. One NFIRS fire was excluded from the combined dataset because it may have been a duplicate already captured in the ASFD data. Table 3.7–13 summarizes fire data obtained from each data source. Table 3.7–13. 2011 wildfire activity in Maricopa County. Number of Acres Data source fires in 2011 burned Arizona State Forestry Division 5 15.2 2011 NFIRS data 1 1.5 ICS-209 2 2,006.0 Total: 8 2,022.7 Estimates for fuel loading rates were assigned using fuel model codes from the National Fire Danger Rating System (NFDRS) and a table of fuel loading values for NFDRS fuel model categories (WGA/WRAP, 2005). The department used the NFDRS Fuel Model map in ArcGIS to identify NFDRS fuel types for fires with latitude and longitude data. Table 3.7–14. Data used to estimate 2011 wildfire emissions. Number of Acres Fuel loading NFDRS model category fires in 2011 burned factor (tons/acre) Agriculture* 1 1.5 4.5 Barren* 1 0.1 0.75 Intermediate brush 4 2,019.5 15.0 Sagebrush grass 2 1.6 4.5 Total: 8 2,022.7 — * “Agriculture” and “barren” NFDRS model descriptions were not included in WGA/WRAP 2002 fuel loading values for NFDRS fuel model categories. Therefore, it was assumed that “Agriculture” is similar to "sagebrush grass" and “Barren” is similar to “western grasses (annual)” and fuel loadings were assigned accordingly. Estimates of the material burned were derived by multiplying the acres burned for each category by the applicable fuel loading factor. Latitude and longitude data were used to determine the number of acres burned inside of the nonattainment area. Only one wildfire (=0.1 acre) occurred outside of the eight-hour ozone nonattainment area. Table 3.7–15 shows the number of wildfires and acres burned for Maricopa County and the eight-hour ozone nonattainment area and an estimate of material burned. Table 3.7–15. Summary of 2011 wildfires, acres burned, and estimate of material burned. No. of Acres Material burned Material burned in 8-hr Geographic Area fires burned annually (tons/yr) ozone season (tons/season) Maricopa County 8 2,023 30,307 30,104 8-hr ozone NAA 7 2,023 30,306 30,104 2011 Ozone Precursor Emissions Inventory 54 February 2014 Annual emissions from wildfires for each geographic area were calculated by multiplying the material burned for each area by the emission factor shown in Table 3.7–16 below. Emission factors were obtained from the Western Regional Air Partnership's (WRAP) 2002 Fire Emissions Inventory (WGA/WRAP, 2005). Table 3.7–16. Emission factors for wildfires and prescribed broadcast burning. Emission factors (lb/ton) Activity VOC NOx CO Wildfires and prescribed broadcast burning 13.6 6.2 289 Annual emissions from wildfires for Maricopa County and the nonattainment area are shown in Table 3.7–17. Table 3.7–17. Annual emissions from wildfires. Annual emissions (tons/yr) Geographic Area VOC NOx CO Maricopa County 206.08 93.95 4,379.29 8-hr ozone NAA 206.08 93.95 4,379.28 Because all fires that occurred during ozone season were within the nonattainment area, seasonday emissions for the county and the nonattainment area were the same. Ozone season-day emissions were estimated by multiplying the material burned during ozone season by the appropriate emission factor and dividing the result by the number of ozone season burn days. In 2011, 32 burn days occurred during the ozone season in Maricopa County. Table 3.7–18 shows season-day emissions from wildfires in Maricopa County and the nonattainment area. Table 3.7–18. Season-day emissions from wildfires. Season-day emissions (lbs/day) Ozone-season Geographic Area burn days VOC NOx CO Maricopa County 12,794.0 5,832.6 271,872.2 32 8-hr ozone NAA 12,794.0 5,832.6 271,872.2 3.7.9 Prescribed fires Prescribed fire data were obtained from the Arizona Department of Environmental Quality (ADEQ) (B. Busby, pers. commun., November 8, 2012). The ADEQ reported that fourteen prescribed fires occurred in Maricopa County in 2011. Sixty-two acres of piled fuels were burned. All fourteen prescribed fires occurred inside the eight-hour ozone nonattainment area. Because all 2011 prescribed fires were piled fuels, material burned was derived by multiplying the number of acres burned by tons of piles per acre for each fire. Table 3.7–19 shows the data provided by the ADEQ, the amount of material burned for each fire, whether the fire occurred within the nonattainment area and during the ozone season. 2011 Ozone Precursor Emissions Inventory 55 February 2014 Table 3.7–19. 2011 prescribed fire activity in Maricopa County. Date 01/05/2011 04/06/2011 04/13/2011 04/14/2011 04/19/2011 07/23/2011 08/10/2011 08/11/2011 08/16/2011 10/20/2011 11/08/2011 11/15/2011 11/16/2011 12/20/2011 Total: Burn number TNF0301 TNF0301 TNF0106 TNF0106 TNF0301 TNF0611 TNF0301 TNF0301 TNF0301 TNF0301 TNF0301 TNF0106 TNF0106 TNF0301 Burn location T7N,R8E,S36 T2N,R7E,S18 T6N,R7E,S33 T7N,R5E,S7 T3N,R8E,S27 T3N,R11E,S2 T3N,R8E,S27 T3N,R8E,S27 T3N,R8E,S25 T2N,R9E,S31 T2N,R9E,S31 T6N,R7E,S15 T7N,R6E,S1 T2N,R9E,S11 Tons/ acre 1 1 1 1 1 5 0.25 0.25 1 1 3 1 1 0.25 Acres burned 5 1 1 1 10 15 6 6 4 5 5 1 1 1 62 Material burned (tons) 5 1 1 1 10 75 1.5 1.5 4 5 15 1 1 0.25 122.25 During ozone season? N N N N N Y Y Y Y N N N N N Within 8-hr NAA? Y Y Y Y Y Y Y Y Y Y Y Y Y Y Prescribed fire emission factors for “piled fuels” were obtained from the Western Regional Air Partnership’s (WRAP) 2002 Fire Emissions Inventory (WGA/WRAP, 2005). The emission factors are listed below in Table 3.7–20. Table 3.7–20. Emission factors for prescribed fire (piled fuels). Emission factors (lbs/ton burned) Type of fire VOC NOx CO Prescribed fire (piled fuels) 6.3 6.2 74.3 Annual emissions from prescribed fires in Maricopa County were derived by multiplying material burned by the emission factor then dividing by 2000 lbs/ton. Four prescribed fires occurred during the ozone season. The fires resulted in 82 tons of material burned. It was assumed the prescribed fires lasted one day. Ozone-season day emissions were derived by multiplying 82 tons of material burned by the emission factor (lbs/ton) and then dividing the resulting emissions by four burn days. Since the prescribed fire data provided by ADEQ included burn location, GIS was used to determine the fires that burned inside the nonattainment area. All the 2011 prescribed fires burned within the eight-hour nonattainment area; therefore, annual and season-day emissions estimates for the nonattainment area are equal to county totals . Table 3.7–21 shows the annual and season-day from prescribed fires for Maricopa County and the nonattainment area. Table 3.7–21. Annual and season-day emissions from prescribed fires. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic Area VOC NOx CO VOC NOx CO Maricopa County 0.39 0.38 4.54 129.2 127.1 1,523.2 8-hr ozone NAA 0.39 0.38 4.54 129.2 127.1 1,523.2 2011 Ozone Precursor Emissions Inventory 56 February 2014 3.8 Summary of all area sources Tables 3.8–1 and 3.8–2 summarize the total annual and average season-day emissions from all area sources addressed in this chapter, for both Maricopa County and the eight-hour ozone NAA, respectively. Table 3.8–1. Annual and season-day emissions from all area sources in Maricopa County. Annual emissions (tons/yr) Season-day emissions (lbs/day) Source Category VOC NOx CO VOC NOx CO Fuel combustion: Industrial distillate oil: Boilers 0.61 60.87 15.22 3.9 390.2 97.5 Industrial distillate oil: Engines 0.00 1,838.26 395.65 0.0 11,783.7 2,536.2 Industrial natural gas 36.99 730.94 455.30 217.8 4,303.8 2,680.8 Comm./inst. distillate oil: Boilers 0.00 0.12 0.03 0.0 0.8 0.2 Comm./inst. distillate oil: Engines 0.00 3.72 0.80 0.0 23.8 5.1 Comm./inst. natural gas 54.48 1,080.73 662.84 252.0 4,998.0 3,065.4 Residential distillate oil 0.01 0.35 0.10 0.0 0.0 0.0 Residential natural gas 49.81 851.32 362.26 119.6 2,044.2 869.9 Residential LPG 2.00 51.35 14.56 0.0 0.0 0.0 Residential wood combustion 509.7 57.72 2,959.91 0.0 0.0 0.0 Residential kerosene 0.00 0.03 0.01 0.0 0.0 0.0 All Fuel Combustion: 653.61 4,675.41 4,866.67 593.3 23,544.5 9,255.2 Industrial processes: Chemical manufacturing Commercial cooking Bakeries Secondary metal production Rubber/plastic product mfg. Electrical equipment mfg. Industrial processes, NEC All Industrial Processes: Solvent use: Architectural coatings Auto refinishing Traffic markings Factory finished wood Wood furniture Aircraft surface coating Miscellaneous surface coating Degreasing Dry cleaning Graphics arts Miscellaneous industrial solvent use Consumer and commercial products Cutback asphalt Emulsified asphalt Roofing asphalt Agricultural pesticides All Solvent Use 2011 Ozone Precursor Emissions Inventory 77.42 149.33 78.18 41.01 1,766.75 122.80 48.51 2,284.00 392.60 4,976.22 1,333.26 179.60 137.72 416.56 65.84 316.38 217.55 23.15 290.98 721.85 17,406.46 835.84 866.06 3.04 362.93 28,153.45 15.02 98.36 23.47 224.92 263.41 2.98 91.84 585.79 599.0 820.5 547.8 306.4 14,171.0 746.2 325.6 17,516.5 2,157.1 107.9 697.4 135.8 1,245.8 1,489.5 16.4 525.2 3,396.2 30,622.9 10,255.9 1,823.6 1,396.7 3,434.7 473.1 2,450.5 1,451.4 178.1 2,225.7 5,126.6 95,377.9 4,567.4 4,732.6 23.4 2,903.4 167,043.9 57 February 2014 Table 3.8–1. Annual and season-day emissions from all area sources in Maricopa County (continued). Annual emissions (tons/yr) Season-day emissions (lbs/day) Source Category VOC NOx CO VOC NOx CO Storage/transport: Residential portable gas cans 2,935.10 16,126.9 Commercial portable gas cans 564.43 3,101.3 Bulk plants 120.91 659.3 Gas stations Stage I: Submerged fill 85.08 528.7 Gas stations Stage I: Bal. submerged fill 229.60 1,426.8 Gas stations Stage II 0.00 0.0 Underground tanks: Breathing/emptying 777.00 4,138.6 Airports: aviation gasoline Stage I 347.57 1,904.5 Airports: aviation gasoline Stage II 18.04 98.8 Truck: gasoline (tank trucks in transit) 50.82 315.8 Pipeline gasoline 17.32 94.5 Volatile organic liquids storage/transport 30.54 182.7 All Storage/Transport 5,176.39 28,577.9 Waste treatment/disposal: On-site incineration Open burning: Land clearing debris Landfills Publicly owned treatment works Other waste Leaking underground storage tanks All Waste Treatment/Disposal 0.17 0.67 36.59 75.02 2.12 1.05 116.10 3.31 0.30 30.40 0.79 6.30 108.55 22.19 77.93 56.04 190.06 Misc. area sources: Agricultural field burning Structure fires Aircraft engine testing Vehicle fires Crematories Accidental releases Hospitals Wildfires Prescribed fires All Misc. Area Sources TOTAL, ALL AREA SOURCES 26.14 14.78 4.72 9.27 1.18 0.45 8.57 206.08 0.39 271.58 36,654.65 11.62 1.88 46.36 1.16 11.19 0.00 246.85 80.63 16.16 36.23 2.23 0.00 2011 Ozone Precursor Emissions Inventory 93.95 4,379.29 0.38 4.54 166.54 4,765.93 5,161.56 10,411.95 58 1.1 20.5 200.7 577.1 10.9 32.3 837.8 21.4 9.1 167.4 5.3 193.8 596.4 122.8 431.4 315.6 1,119.6 804.2 72.4 26.1 50.8 51.1 2.1 52.3 12,794.0 129.2 13,982.3 228,556.4 357.4 9.2 259.3 6.4 88.5 0.0 7,595.5 395.2 91.2 198.5 17.3 0.0 5,832.6 271,872.2 127.1 1,523.2 6,680.5 281,693.1 32,035.2 295,571.5 February 2014 Table 3.8–2. Annual and season-day emissions from all area sources in the eight-hour ozone NAA. Annual emissions (tons/yr) Season-day emissions (lbs/day) Source Category VOC NOx CO VOC NOx CO Fuel combustion: Industrial distillate oil: Boilers 0.61 60.61 15.15 3.9 388.5 97.1 Industrial distillate oil: Engines 0.00 1,830.35 393.95 0.0 11,733.0 2,525.3 Industrial natural gas 36.83 727.80 453.34 219.9 4,285.3 2,669.3 Comm./inst. distillate oil: Boilers 0.00 0.12 0.03 0.0 0.8 0.2 Comm./inst. distillate oil: Engines 0.00 3.70 0.80 0.0 23.7 5.1 Comm./inst. natural gas 54.42 1,079.44 662.05 251.7 4,992.0 3,061.7 Residential distillate oil 0.01 0.35 0.10 0.0 0.0 0.0 Residential natural gas 50.20 857.96 365.09 120.5 2,060.1 876.7 Residential LPG 2.02 51.93 14.73 0.0 0.0 0.0 Residential wood combustion 515.53 58.38 2,993.75 0.00 0.00 0.00 Residential kerosene 0.00 0.03 0.01 0.0 0.0 0.0 All Fuel Combustion 659.63 4,670.68 4,898.99 593.0 23,483.5 9,235.4 Industrial processes: Chemical manufacturing Commercial cooking Bakeries Secondary metal production Rubber/plastic product manufacturing Electrical equipment manufacturing Industrial processes, NEC All Industrial Processes Solvent use: Architectural coatings Auto refinishing Traffic markings Factory finished wood Wood furniture Aircraft surface coating Miscellaneous surface coating. Degreasing Dry cleaning Graphics arts Miscellaneous industrial solvent use Consumer and commercial products Cutback asphalt Emulsified asphalt Roofing asphalt Agricultural pesticides All Solvent Use 2011 Ozone Precursor Emissions Inventory 77.09 151.03 77.85 41.01 1,759.15 122.80 47.55 2,276.48 397.07 15.02 98.36 23.47 224.92 263.41 2.98 91.84 590.27 5,033.13 1,327.53 171.12 137.12 414.77 65.84 315.02 216.62 23.42 289.73 718.75 17,605.51 788.72 817.24 3.08 212.18 28,139.77 596.5 829.8 545.4 306.4 14,110.1 746.2 318.0 17,452.4 2,181.7 107.9 697.4 135.8 1,245.8 1,489.5 16.4 525.2 3,420.8 30,973.1 10,211.8 1,737.5 1,390.7 3,419.9 473.1 2,440.0 1,445.1 180.1 2,216.1 5,104.6 96,468.5 4,309.9 4,465.8 23.7 1,697.5 166,557.4 59 February 2014 Table 3.8–2. (continued). Annual and season-day emissions from all area sources in the eight-hour ozone NAA Source Category Storage/transport: Residential portable gas cans Commercial portable gas can: Bulk plants Gas stations Stage I: Submerged fill Gas stations Stage I: Bal. submerged fill Gas stations Stage II Underground tanks: Breathing/emptying Airports : Aviation gasoline Stage I Airports : Aviation gasoline Stage II Truck: Gasoline (tank trucks in transit) Pipeline gasoline Volatile organic liquids storage/transport All Storage/Transport: Waste treatment/disposal: On-site incineration Open burning: Land clearing debris Landfills Publicly owned treatment works Other waste Leaking underground storage tanks All Waste Treatment/Disposal Misc. area sources: Agricultural field burning Structure fires Aircraft engine testing Vehicle fires Crematories Accidental releases Hospitals Wildfires Prescribed fires All Misc. Area Sources ALL AREA SOURCES: 3.9 Annual emissions (tons/yr) VOC NOx CO 2,968.67 570.89 120.91 85.08 229.60 0.00 777.00 344.41 17.87 50.82 17.32 28.80 5,211.35 Season-day emissions (lbs/day) VOC NOx CO 16,311.4 3,136.7 659.3 528.7 1,426.8 0.0 4,138.6 1,887.2 97.9 315.8 94.5 169.3 28,766.2 0.17 0.30 36.59 75.88 2.12 1.05 116.10 3.31 0.13 30.40 0.79 2.81 108.55 22.19 77.93 56.04 190.06 15.28 14.95 4.72 9.38 1.18 0.45 8.66 206.08 0.39 261.09 36,664.42 6.79 1.90 46.36 1.17 11.14 0.00 144.32 81.55 16.16 36.64 2.22 0.00 93.95 0.38 161.70 5,151.83 4,379.28 4.54 4,664.71 10,344.03 1.1 9.1 200.7 583.7 10.9 32.3 837.8 21.4 4.1 167.4 5.3 86.4 596.4 122.8 431.4 315.6 1,119.6 470.2 73.3 26.1 51.4 50.9 2.1 52.9 12,794.0 129.2 13,650.0 227,856.8 209.0 9.3 259.3 6.4 88.1 0.0 4,440.7 399.7 91.2 200.8 17.2 0.0 5,832.6 127.1 6,531.8 31,820.5 271,872.2 1,523.2 278,544.9 292,320.7 Quality assurance / quality control procedures Quality assurance and quality control (QA/QC) activities for the area source emissions inventory were designed to create a comprehensive, accurate, representative and comparable inventory of area source emissions for Maricopa County and the nonattainment area. During each step of creating, building and reviewing the area source emissions inventory, quality checks and assurances were performed to establish confidence in the inventory structure and data. Area source categories were identified for inclusion in the inventory based on the latest Emissions Inventory Improvement Program (EIIP) guidance available. In addition, recent EPA activities to develop county-level emissions estimates for newly created source categories (such as portable fuel containers) or refined source classification codes were also reviewed, and incorporated where relevant. Prior-year inventories for the region were also examined to identify possible additional categories for inclusion in the present inventory. The list of area source 2011 Ozone Precursor Emissions Inventory 60 February 2014 categories developed based on these guidance documents was modified to fit the characteristics of Maricopa County, with some area source categories determined to be insignificant (e.g., emissions from industrial coal combustion, or oil and natural gas production, and snowmobile use). Data for area source emission calculations were gathered from a wide universe of resources. Whenever applicable, local surveyed data (such as annual emissions report) was used as this data best reflects activity in the county and the nonattainment area. When local data was not available, state data from state agencies (such as the Arizona Department of Transportation) and regional bodies (such as the Western Regional Air Partnership [WRAP]) were used. National level data (such as the US Census Bureau) was used when no local, state or regional data was available. In addition, the most recent EIIP guidance for area sources was consulted for direction in determining the most relevant data source for use in emissions calculations. Emissions calculations for area sources were performed by three air quality planners and one unit manager. All area source emission estimates were calculated in spreadsheets to ensure the calculations could be verified and reproduced. Whenever possible or available, the “preferred method” described in the most recent EIIP guidance documents for area sources was used to calculate emissions. Emissions were estimated using emission factors from EIIP guidance, AP42, and local source testing. Local seasonal and activity data were used when available, with EPA and EIIP guidance used when no local seasonal or activity data existed. All calculations were evaluated to ensure that emissions from point sources were not being double-counted and to determine if rule effectiveness applied. Once area source emission estimates had been produced, several quality control checks were performed to substantiate the calculations. Most area source calculations were peer-reviewed by two other planners, with all area sources being reviewed by at least one other planner. Peer review ensured that all emission calculations were reasonable and could be reproduced. Sensitivity analyses and computational method checks were performed on area sources when emissions seemed to be outside the expected ranges. When errors were found, the appropriate changes were made by the author of the calculations to ensure consistency of the emissions calculations. The peer-reviewed emissions estimates were combined into a draft area source chapter. This draft chapter was read through in its entirety by the unit manager and the three air quality planners for final review, with any identified errors corrected by the author of the section. The draft version of the area source chapter was sent to the Arizona Department of Environmental Quality, the Arizona Department of Transportation, and the Maricopa Association of Governments for a quality assurance review. These agencies provided comments which were addressed and incorporated into the final area source chapter. The QA/QC activities described here have produced high levels of confidence in the area source emissions estimates detailed in this chapter, and represent the best efforts of the inventory preparers. 2011 Ozone Precursor Emissions Inventory 61 February 2014 3.10 References ADA, 2013. Arizona Department of Agriculture, 1080 database. Internet address: http://www.azda.gov/Search1080/Search.aspx ADOT, 2012. Arizona Department of Transportation, Motor Vehicle Division, County Distribution Summary Report and Adjusted County MVF Distribution Report, for Jan. through December 2011. GOEP, 2013. Governor's Office of Energy Policy, Arizona Energy Statistics, Heating and Cooling Degree Days. Internet address: http://www.azenergy.gov/doclib/Degreedays.pdf. MCESD, 1999. 1999 Periodic Ozone Emissions Inventory for the Maricopa County, Arizona Nonattainment Area, Maricopa County Environmental Services Department, Rev. Aug. 2002. NWCG, 2012. National Wildfire Coordinating Group, Historical Incident ISC-209 reports. 2011 Significant Incident Summary Spreadsheet for southwest GACC Incidents. Internet address: http://fam.nwcg.gov/fam-web/hist_209/report_list_209. Pechan, 2012. Pechan Environmental Consulting. 2008 Nonpoint Emission Estimates. Solvent Usage – Surface Coatings. Solvent Utilization Documentation. Internet address: http://cert.pechan.com/epa/npee2008/index.html Pechan,2012a. Pechan Environmental Consulting. 2008 Nonpoint Emission Estimates. Internet address: http://cert.pechan.com/epa/npee2008/index.html#CommercialCooking Pechan, 2012b. 2008 Nonpoint Emission Estimates. Pechan Environmental Consulting. Gasoline Distribution: Stage I: Tank Trucks in Transit, Internet address: http://cert.pechan.com/epa/npee2008/index.html Pechan, 2012c. 2008 Nonpoint Emission Estimates. Pechan Environmental Consulting. Solvent Usage – Other. Solvent Utilization Documentation, Table 2. Internet address: http://cert.pechan.com/epa/npee2008/index.html US Census Bureau, 2012. 2010 County Business Patterns (NAICS). Internet address: http://censtats.census.gov/cgi-bin/cbpnaic/cbpsect.pl US EPA, 1992. Compilation of Air Pollution Emission Factors (AP-42). Volume I: Stationary Point and Area Sources. Fifth ed. Chapter 2: Solid Waste Disposal, 2.5 Open Burning, Table 2.5–5. US EPA, Office of Air Quality Planning and Standards, Research Triangle Park, NC. US EPA, 1995a. Architectural Surface Coating. Emissions Inventory Improvement Program (EIIP) Vol. III, Chap. 1. Nov. 1995. Prepared by Eastern Research Group, Inc. for the Area Source Committee, EIIP. Internet address: http://www.epa.gov/ttn/chief/eiip/techreport/ volume03/archsfc.pdf US EPA, 1995b. Compilation of Air Pollution Emission Factors (AP-42). Fifth Ed., Volume I, Chapter 5: Petroleum Industry, 5.2, Transportation and Marketing of Petroleum Liquids. Table 5.2-7. Jan. 1995. http://www.epa.gov/ttn/chief/ap42/ch05/final/c05s02.pdf US EPA, 1997. Traffic Markings. Emissions Inventory Improvement Program (EIIP) Vol. III, Chap. 14. May 1997. Prepared by Eastern Research Group, Inc. for the Area Source Committee, EIIP. Internet address: http://www.epa.gov/ttnchie1/eiip/techreport/volume03/ iii14.pdf US EPA, 1998. Compilation of Air Pollution Emission Factors (AP-42). Fifth Ed., Volume 1, Chapter 1: External Combustion Sources. Natural Gas Combustion. Internet address: http://www.epa.gov/ttn/chief/ap42/ch01/final/c01s04.pdf US EPA, 2001a. Introduction to Area Source Emission Inventory Development. Emission Inventory Improvement Program (EIIP) Vol. III, Chapter 1. Revised Final, January 2001. Prepared by Eastern Research Group, Inc. for the Area Source Committee, EIIP. Internet address: http://www.epa.gov/ttn/chief/eiip/techreport/volume03/iii01_apr2001.pdf 2011 Ozone Precursor Emissions Inventory 62 February 2014 US EPA, 2001b. Gasoline Marketing (Stage I and Stage II). Emissions Inventory Improvement Program (EIIP) Vol. III, Chap 11. Revised Final, January 2001. Prepared by Eastern Research Group, Inc. for the Area Source Committee, EIIP. Internet address: http://www.epa.gov/ttn/chief/eiip/techreport/volume03/iii11_apr2001.pdf US EPA, 2001c. Leaking Underground Storage Tanks. Emission Inventory Improvement Program Vol. III, Area Source Method Abstract. May 2001. Internet address: http://www.epa.gov/ttn/chief/eiip/techreport/volume03/ust2_dec2000.pdf US EPA, 2001d. Structure Fires. Emission Inventory Improvement Program (EIIP) Vol. III, Chap. 18. Revised Final, Jan. 2001. Prepared by Eastern Research Group, Inc. for the Area Sources Committee, EIIP. Internet address: http://www.epa.gov/ttn/chief/eiip/techreport/volume03/iii18_apr2001.pdf US EPA, 2012a. WebFIRE. EPA’s online emissions factor repository, retrieval, and development tool. Internet address: http://www.epa.gov/ttn/chief/webfire/index.html US EPA, 2012b. Residential Wood Combustion (RWC) Estimation Tool. Internet address: ftp://ftp.epa.gov/EmisInventory/2011nei/doc/ US EPA, 2012c. 2011 National Emissions Inventory Information, Data and documentation. Internet address: ftp://ftp.epa.gov/EmisInventory/2011nei/doc/ USFA, 2012. The United States Fire Administration, National Fire Data Center, National Fire Incident Reporting System (NFIRS), Data Archives: 2011 Public Data Release CD, December 11, 2012. WGA/WRAP, 2005. 2002 Fire Emission Inventory for the WRAP Region – Phase II. Project No. 178-6. Western Governors Association/Western Regional Air Partnership. July 22, 2005. Tables 5 and 6. Internet address: http://www.wrapair.org/forums/fejf/documents/ WRAP_2002_PhII_EI_Report_20050722.pdf. 2011 Ozone Precursor Emissions Inventory 63 February 2014 This page intentionally blank. . 2011 Ozone Precursor Emissions Inventory 64 February 2014 4. Nonroad Mobile Sources 4.1 Introduction Nonroad mobile sources are defined as those that move or are moved within a 12-month period and are not licensed or certified as highway vehicles. Nonroad mobile sources are vehicles and engines that fall under the following categories: • • • • • • • • • • • • • Agricultural equipment, such as tractors, combines and balers; Airport ground support equipment, such as baggage tugs and terminal tractors; Commercial equipment, such as generators and pumps; Industrial equipment, such as forklifts and sweepers; Construction and mining equipment, such as graders, back hoes and trenchers; Lawn and garden equipment, such as leaf blowers and lawn mowers; Logging equipment (not present in Maricopa County); Pleasure craft, such as power boats and personal watercraft; Railway maintenance equipment, such as rail straighteners; Recreational equipment, such as all-terrain vehicles and off-road motorcycles; Underground mining and oil field equipment (not present in Maricopa County); Aircraft, such as jet and piston engines; and Locomotives, such as switching and line haul trains. Emission calculations for most nonroad mobile source categories except aircraft, airport ground support equipment (GSE) and locomotives were derived using EPA’s NONROAD2008a model (Core version 2008a, July 2009). Aircraft and airport GSE emission estimates were made using the Federal Aviation Administration’s EDMS (Emissions Dispersion Modeling System) model, ver. 5.1.1. Locomotive emission calculations were derived from surveys of the three railroad companies that have operations in the county. County specific temperature and fuel-related inputs are required for the operation of the NONROAD2008a model. Monthly temperature and fuel data were provided by the Arizona Department of Weights and Measures. The following table lists the local county inputs used: Table 4.1–1. NONROAD2008 model county temperature and fuel-related inputs. Fuel Diesel Gasoline Temperatures (°F) RVP Sulfur Sulfur ETOH Month Max. Min. Average (psi) (ppm) (ppm) (vol %) January 64 45 54.9 9 9 15 9.92 February 69 48 58.5 9 9 16 10.29 March 79 54 66.8 8 9 11 9.52 April 87 61 74.2 8 9 14 7.90 May 91 66 78.7 7 9 13 9.41 June 107 80 93.4 7 10 18 9.38 July 106 84 95.2 7 9 21 9.70 August 104 82 93.2 7 6 18 9.58 September 101 79 90.1 7 6 18 9.73 October 91 65 78.1 8 9 15 9.49 November 81 56 68.7 8 6 14 10.17 December 65 46 56.0 8 16 12 9.02 Ethanol Blend Market Total Oxygen share (%) (wt %) 100 3.66 100 3.85 100 3.58 100 2.98 100 3.48 100 3.45 100 3.62 100 3.70 100 3.60 100 3.56 100 3.80 100 3.41 Note: All other required temperature and fuel-related inputs not listed assumed NONROAD2008 default values. The US EPA recommends adjusting default NONROAD2008a model values (such as equipment 2011 Ozone Precursor Emissions Inventory 65 February 2014 population, activity levels of equipment, growth factors, etc.) where local data is available, as the default values in the model are derived from national averages. The NONROAD2008a model defaults were adjusted in the following manner: • Equipment population numbers and activity levels for commercial lawn and garden equipment were adjusted based on 2003 survey results of the commercial lawn and garden industry performed by ENVIRON as part of an inventory developed to study the impact of visibility impairing pollutants (ENVIRON et al., 2003). Survey results show that for most categories of lawn and garden equipment, the equipment populations for Maricopa County are significantly lower than EPA default values, while the average annual hours of operation for most equipment types are slightly higher than EPA's values. Using these new local data results in a considerable decrease in emissions from this category, compared with earlier results using EPA default data. Spatial allocation factors were developed (based on EPA guidance documents) to apportion nonroad emissions to the eight-hour ozone nonattainment area. The approaches used are described in each section of this chapter. Temporal allocations (used to calculate ozone season-day emissions) for nonroad equipment categories modeled in the NONROAD2008a model are based on EPA recommendations on weekday and weekend day activity levels for each nonroad equipment category (US EPA, 1999). Table 4.1–2 below lists the weighted activity level allocation fractions for each equipment class for weekdays and weekend days. For this report, the most conservative (highest) allocation fraction in each nonroad equipment class was used to calculate season-day emissions. Table 4.1–2. Default weekday and weekend day activity allocation fractions. Equipment category Weekday Weekend day Agricultural 0.1666667 0.0833334 Airport ground support 0.1428571 0.1428571 Commercial 0.1666667 0.0833334 Construction and mining 0.1666667 0.0833334 Industrial 0.1666667 0.0833334 Lawn and garden (residential) 0.1111111 0.2222222 Lawn and garden (commercial) 0.1600000 0.1000000 Logging 0.1666667 0.0833334 Pleasure craft 0.0600000 0.3500000 Railway maintenance 0.1800000 0.0500000 Recreational 0.1111111 0.2222222 4.2 Agricultural equipment Annual emissions from agricultural equipment in Maricopa County were calculated using EPA’s NONROAD2008a model, as discussed above. Ozone nonattainment area annual emissions were calculated based on EIIP guidance (US EPA, 2002) which recommends using the ratio of agricultural land inside the nonattainment area (161,371 acres) to agricultural land inside the county (276,016 acres). See Section 1.5.2 for a discussion of land use data used. Ozone nonattainment area emissions = Total Maricopa County from agricultural equipment VOC emissions from agricultural equipment 2011 Ozone Precursor Emissions Inventory 66 × Agricultural land use allocation factor February 2014 = 38.53 tons × 58.46% = 22.52 tons VOC/yr County season-day emissions were calculated by multiplying ozone season emissions (generated by the NONROAD2008a model) by the most conservative weekday/weekend day activity allocation factor for agricultural equipment listed in Table 4.1–2, and dividing the product by the number of weeks (13) in the ozone season (US EPA, 1999), as follows: Maricopa County VOC = Ozone season × 2,000 season-day emissions VOC emissions (lb/ton) (lbs/day) (tons/season) = 12.84 × 2,000 × daily activity allocation factor for agricultural equipment expressed as (week/day) ÷ 13 (weeks/season) × 0.166667 ÷ 13 = 392.3 lbs/day Ozone nonattainment area season-day emissions were calculated by multiplying County seasonday emissions by the agricultural land use allocation factor: Ozone nonattainment area = Maricopa County VOC season-day emissions season-day emissions = 392.3 lbs/day × Agricultural land use allocation factor × 58.46% = 192.5 lbs/day Table 4.2–1. Annual and season-day emissions from agricultural equipment. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 38.53 330.49 303.71 329.3 2,762.6 2,584.4 8-hr ozone NAA 22.52 193.22 177.56 192.5 1,615.1 1,510.9 4.3 Airport ground support equipment Annual emissions from airport ground support equipment (GSE) and auxiliary power units (APUs) were calculated using the Emissions Dispersion Modeling System (EDMS, v. 5.1.3) from the U.S. Federal Aviation Administration (FAA). Activity data on 2011 aircraft operations and GSE use for eight major airports were obtained from FAA’s Air Traffic Activity Data System. In addition, activity data for 2011 for six small general aviation airports were assumed to be the same as those in 2008, which was included in MAG’s 2009 survey data. (Further details concerning the modeling input data and results are described in Section 4.11, Aircraft). Emissions from GSE and APUs at Luke Air Force Base (AFB) for the year 2011 are assumed to be the same as those used in the 2008 PM10 Periodic Emissions Inventory Report for the Maricopa County, Arizona, Nonattainment Area (MCAQD, 2011) based on input from Luke AFB. 2011 Ozone Precursor Emissions Inventory 67 February 2014 Table 4.3–1. Annual emissions (tons/yr) from airport ground support equipment (GSE) and auxiliary power units (APUs). Maricopa County 8-hr ozone NAA VOC NOx CO VOC NOx CO GSE 104.94 317.86 3,171.63 104.40 316.39 3,155.22 APU 7.04 88.18 104.36 7.03 88.10 103.86 Total: 111.98 406.04 3,275.99 111.43 404.49 3,259.08 Table 4.3–2. GSE APU Total: 4.4 Season-day emissions (lbs/day) from airport GSE and APU. Maricopa County 8-hr ozone NAA VOC NOx CO VOC NOx CO 549.4 1,663.2 16,597.8 546.7 1,656.0 16,516.8 37.8 473.4 557.3 37.8 473.0 554.8 587.3 2,136.6 17,155.0 584.5 2,128.9 17,071.7 Commercial equipment Annual emissions from commercial equipment in Maricopa County were calculated using EPA’s NONROAD2008a model, as described in Section 4.1. Annual emissions for the eight-hour ozone nonattainment area for this category were derived by applying the ratio of industrial employment in the nonattainment area to Maricopa County totals, as data on the number of wholesale establishments recommended by EIIP guidance (US EPA, 2002) was not available. See Section 1.5.1 for a discussion of the industrial employment data used. County season-day emissions were calculated by multiplying Maricopa County ozone season emissions (generated by the NONROAD2008a model) by the most conservative weekday/ weekend day activity allocation factor for commercial equipment (0.1666667) listed in Table 4.1–2, and dividing the product by the number of weeks (13) in the ozone season (US EPA, 1999). Ozone nonattainment area season-day emissions were calculated based on industrial employment ratios as described above. Table 4.4–1. Annual and season-day emissions from commercial equipment. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 1,924.41 1,361.42 30,224.21 14,537.1 8,334.7 203,404.4 8-hr ozone NAA 1,916.15 1,355.57 30,094.46 14,474.7 8,299.0 202,531.2 4.5 Construction and mining equipment Annual emissions from construction and mining equipment in Maricopa County were calculated using EPA’s NONROAD2008a model as described in Section 4.1. Annual emissions for the eight-hour ozone nonattainment area for this category were derived by applying the ratio of construction employment in the nonattainment area to Maricopa County totals as a conservative estimate, since the EIIP-recommended allocation factor of total dollar value of construction was unavailable (US EPA, 2002). See Section 1.5.1 for a discussion of the population data used. County season-day emissions were calculated by multiplying Maricopa County ozone season emissions (generated by the NONROAD2008a model) by the most conservative weekday/ weekend day activity allocation factor for construction/mining equipment (0.1666667) listed in Table 4.1–2, and dividing the product by the number of weeks (13) in the ozone season (US 2011 Ozone Precursor Emissions Inventory 68 February 2014 EPA, 1999). Ozone nonattainment area season-day emissions were calculated based on construction employment ratios as described above. Table 4.5–1. Annual and season-day emissions from construction and mining equipment. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 1,881.88 12,937.30 14,396.92 13,116.9 87,972.9 99,942.8 8-hr ozone NAA 1,941.80 13,349.23 14,855.32 13,534.5 90,774.0 103,125.0 4.6 Industrial equipment Annual emissions from industrial equipment in Maricopa County were calculated using EPA’s NONROAD2008a model, as described in Section 4.1. Annual emissions for the eight-hour ozone nonattainment area for this category were derived by applying the ratio of industrial employment in the nonattainment area to Maricopa County totals as a conservative estimate, since the number of employees in manufacturing, as recommended by EIIP guidance (US EPA, 2002), was not available. See Section 1.5.1 for a discussion of the industrial employment data used. County season-day emissions were calculated by multiplying Maricopa County ozone season emissions (generated by the NONROAD2008a model) by the most conservative weekday/ weekend day activity allocation factor for industrial equipment (0.1666667) listed in Table 4.1– 2, and dividing the product by the number of weeks (13) in the ozone season (US EPA, 1999). Ozone nonattainment area season-day emissions were calculated based on industrial employment ratios as described above. Table 4.6–1. Annual and season-day emissions from industrial equipment. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 341.25 1,839.35 7,140.99 2,212.6 11,763.4 46,138.5 8-hr ozone NAA 339.78 1,831.45 7,110.33 2,203.1 11,712.9 45,940.4 4.7 Lawn and garden equipment Annual emissions from lawn and garden equipment in Maricopa County were calculated using EPA’s NONROAD2008a model, as described in Section 4.1. These results reflect new equipment population and usage estimates from survey work done in early 2003 for the Arizona Department of Environmental Quality (discussed further in Section 4.1). Annual emissions for the eight-hour ozone nonattainment area for this category were derived by applying the ratio of population in the nonattainment area to Maricopa County totals, since the number of housing units, as recommended by EIIP guidance, was not available (US EPA, 2002). See Section 1.5.1 for a discussion of the population data used. County season-day emissions were calculated by multiplying Maricopa County ozone season emissions (generated by the NONROAD2008a model) by the most conservative weekday/ weekend day activity allocation factor for lawn and garden equipment (0.1600000 for the commercial segment, 0.2222222 for residential) listed in Table 4.1–2, and dividing the product by the number of weeks (13) in the ozone season (US EPA, 1999). Ozone nonattainment area season-day emissions were calculated based on population as described above. 2011 Ozone Precursor Emissions Inventory 69 February 2014 Table 4.7–1. Annual and season-day emissions from lawn and garden equipment. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 4,913.96 866.64 54,798.41 51,990.4 6,998.4 523,235.5 8-hr ozone NAA 4,970.15 876.55 55,425.05 52,584.9 7,078.4 529,218.9 4.8 Pleasure craft Annual emissions from pleasure craft equipment in Maricopa County were calculated using EPA’s NONROAD2008a model, as described in Section 4.1. Annual emissions for the eighthour ozone nonattainment area for this category were derived by applying the ratio of lake surface area in the nonattainment area to Maricopa County totals, as recommended by EIIP guidance (US EPA, 2002). See Section 1.5.2 for a discussion of the land use data used. County season-day emissions were calculated by multiplying Maricopa County ozone season emissions (generated by the NONROAD2008a model) by the most conservative weekday/ weekend day activity allocation factor for pleasure craft (0.350000) listed in Table 4.1–2, and dividing the product by the number of weeks (13) in the ozone season (US EPA, 1999). Ozone nonattainment area season-day emissions were calculated based on lake surface area as described above. Table 4.8–1. Annual and season-day emissions from pleasure craft equipment. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 530.39 96.56 1,249.66 11,527.0 1,996.8 26,738.3 8-hr ozone NAA 530.39 96.56 1,249.66 11,527.0 1,996.8 26,738.3 4.9 Railway maintenance equipment Annual emissions from railway maintenance equipment in Maricopa County were calculated using EPA’s NONROAD2008a model, as described in Section 4.1. Annual emissions for the eight-hour ozone nonattainment area for this category were derived by applying the ratio of population in the nonattainment area to Maricopa County totals, as recommended by EIIP guidance (US EPA, 2002). See Section 1.5.1 for a discussion of the population data used. County season-day emissions were calculated by multiplying Maricopa County ozone season emissions (generated by the NONROAD2008a model) by the most conservative weekday/ weekend day activity allocation factor for railway maintenance equipment (0.1800000) listed in Table 4.1–2, and dividing the product by the number of weeks (13) in the ozone season (US EPA, 1999). Ozone nonattainment area season-day emissions were calculated based on the population ratio as described above. Table 4.9–1. Annual and season-day emissions from railway maintenance equipment. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 1.94 8.55 16.48 14.2 59.0 117.8 8-hr ozone NAA 1.96 8.64 16.67 14.4 59.7 119.1 2011 Ozone Precursor Emissions Inventory 70 February 2014 4.10 Recreational equipment Annual emissions from recreational equipment in Maricopa County were calculated using EPA’s NONROAD2008a model, as described in Section 4.1. Annual emissions for the eight-hour ozone nonattainment area for this category were derived by applying the ratio of passive open space and vacant land use in the nonattainment area to Maricopa County totals, as recommended by EIIP guidance (US EPA, 2002). See Section 1.5.2 for a discussion of the land use data used. County season-day emissions were calculated by multiplying Maricopa County ozone season emissions (generated by the NONROAD2008a model) by the most conservative weekday/ weekend day activity allocation factor for recreational equipment (0.2222222) listed in Table 4.1–2, and dividing the product by the number of weeks (13) in the ozone season (US EPA, 1999). Ozone nonattainment area season-day emissions were calculated based on land use as described above. Table 4.10–1. Annual and season-day emissions from recreational equipment. Annual emissions (tons/yr) Season-day emissions (lbs/day) Geographic area VOC NOx CO VOC NOx CO Maricopa County 1,518.97 66.10 6,373.46 17,804.4 679.3 74,424.8 8-hr ozone NAA 684.30 29.78 2,871.27 8,020.9 306.0 33,528.7 4.11 Aircraft Emissions from aircraft at the largest airports in Maricopa County were estimated using the Federal Aviation Administration’s Emissions and Dispersion Model (EDMS, v. 5.1.3). The FAA EDMS model combines specified aircraft and activity levels with default emissions factors in order to estimate annual emissions inventories for a specific airport. The model calculates emissions of sulfur oxides (SOx), oxides of nitrogen (NOx), particulate matter (only for certain categories of airframes and engines), carbon monoxide (CO), and hydrocarbons (HC). The model can also estimate emissions from ground support equipment (GSE) and auxiliary power units (APUs), using either default profiles or user-specified activity of these components. The EDMS runs were executed by the Maricopa Association of Governments. The contact person for the EDMS emission estimates is Adam Xia (602-254-6300). Aircraft emissions were estimated for four aircraft categories: 1. Air carriers (abbreviated “AC”): Larger commercial aircraft with at least 60 seats or 18,000 lbs payload capacity, used for scheduled service to transport passengers and/or freight; 2. Air taxis (“AT”): Smaller commercial turbine- or piston-powered aircraft with less than 60 seats or 18,000 lbs payload capacity; 3. General aviation (“GA”): Aircraft used on an unscheduled basis for recreational flying, personal transportation, and other activities, including business travel; and 4. Military (“ML”): Aircraft used to support military operations. First, three databases from FAA’s website provide the year 2011 aircraft activity, fleet mix for the types of aircraft used, and hourly/weekly/monthly operational profiles for eight major airports (Chandler Municipal, Falcon Field, Glendale Municipal, Phoenix Deer Valley, Phoenix Goodyear, Phoenix-Mesa Gateway, Phoenix Sky Harbor, and Scottsdale airport). The three databases are (1) FAA’s Air Traffic Activity Data System (ATADS) (FAA, 2012a); (2) 2011 Ozone Precursor Emissions Inventory 71 February 2014 Enhanced Traffic Management System Counts (ETMSC) database; and (3) FAA Aviation Performance Metrics (APM) database (FAA, 2012b). To supplement the FAA’s database for the eight major airports, MAG conducted a survey of six additional small general aviation airports (Buckeye Municipal, Gila Bend Municipal, Pleasant Valley, Sky Ranch at Carefree, Stellar Airpark, and Wickenburg Municipal airport) in Maricopa County to gather the year 2008 data on aircraft activity (landings and take-offs or LTOs) and estimated average taxi/idle times in 2009. The year 2008 data for these small general aviation airports are assumed to be the same as those in year 2011, since no updated aircraft activity data were available for the year 2011. Table 4.11–1 summarizes the activity level for each aircraft category for each airport included in the modeling, and indicates the data sources for each airport’s activity (reported number of operations) and fleet mix. One required meteorological input for EDMS is an atmospheric mixing height, which is defined as the height (or depth) above ground where relatively vigorous vertical mixing occurs due to convection. To calculate the time-varying mixing height, the latest version of the EPA AERMOD Meteorological Preprocessor (AERMET version 11059) was employed. 2011 Ozone Precursor Emissions Inventory 72 February 2014 Table 4.11–1. Annual airport operations (by aircraft category) and related data sources. Airport Operations Data Fleet Mix Data Aircraft 2011 Airport Code Source1 Source2 Type3 Operations Buckeye Municipal BXK airnav.com Generic GA profile GA 53,070 Chandler Municipal CHD FAA/ATADS FAA/ETMSC AC 6 AT 2,168 GA 158,960 ML 456 Falcon Field FFZ FAA/ATADS FAA/ETMSC AC 4 AT 2,718 GA 214,486 ML 2,872 Gila Bend Municipal E63 airnav.com Generic GA profile GA 3,536 Glendale Municipal GEU FAA/ATADS FAA/ETMSC AT 1,070 GA 85,998 ML 56 Luke Air Force Base LUF [2011 F-16 aircraft emissions were grown based on the total number of F-16 operations in 2008 vs. 2011] Phoenix Deer Valley DVT FAA/ATADS, Survey response, AC 2 Survey response FAA/ETMSC AT 3,832 GA 313,362 * ML 248 Phoenix Goodyear GYR FAA/ATADS, Survey response, AC 146 Survey response FAA/ETMSC AT 312 GA 132,566 * ML 5,582 Phoenix-Mesa Gateway IWA FAA/ATADS FAA/ETMSC AC 7,782 (formerly Williams AT 9,176 Gateway) GA 147,596 ML 6,646 Phoenix Sky Harbor PHX FAA/ATADS FAA/ETMSC AC 375,104 AT 63,796 GA 20,582 ML 2,506 Pleasant Valley P48 airnav.com Generic GA profile GA 6,010 Scottsdale SDL FAA/ATADS FAA/ETMSC AC 6 AT 12,970 GA 127,924 ML 740 Sky Ranch at Carefree 18AZ Survey response Generic GA profile GA 3,030 Stellar Airpark P19 airnav.com Generic GA profile GA 39,056 Wickenburg Municipal E25 Survey responses Generic GA profile GA 12,000 1. FAA/ATADS: Federal Aviation Administration’s Air Traffic Activity Data System (database); http://aspm.faa.gov. 2. FAA/ETMSC: Federal Aviation Administration’s Enhanced Traffic Management System Counts (database); http://aspm.faa.gov. 3. AC: Air Commercial; AT: Air Taxi; GA: General Aviation; ML: Military * includes touch-and-go operations reported by airport. 2011 Ozone Precursor Emissions Inventory 73 February 2014 Both the 2011 hourly surface meteorological data and the 2011 one-minute Automated Surface Observing System (ASOS) wind data from the National Weather Service (NWS) station at the Phoenix Sky Harbor were used (NCDC, 2012). Full year upper air data in 2011 at the Tucson station (station number 23160) were obtained from the National Oceanic and Atmospheric Administration (NOAA) Earth System Research Laboratory (ESRL) Radiosonde Database (ESRL, 2012). Ultimately, a single mixing height dataset in 2011 is used for all airports, except Luke Air Force Base. F-16 aircraft emissions estimates for Luke AFB for the year 2011 were scaled using a ratio of the number of F-16s in 2011 to the number of F-16s in 2008. The emissions from “transient” aircraft and on-wing engine testing in 2011 were assumed to be the same as those in 2008 based on input from Luke AFB. Emissions from the military aircraft, “transient” aircraft, and on-wing engine testing were summed into a single “ML” category for Luke AFB. This summation method is consistent with that used in the 2008 PM10 Periodic Emissions Inventory Report for the Maricopa County, Arizona, Nonattainment Area (MCAQD, 2011). As with all other airports included in this inventory, emissions from ground support equipment (GSE) at Luke AFB are addressed in Section 4.3, Airport ground support equipment and auxiliary power units. The following section describes how activity and emissions were estimated for a representative airport, Falcon Field (FFZ). The FAA’s Air Traffic Activity System (ATADS, available at www.aspm.faa.gov) provided data on 2011 activity by aircraft type; these results are contained in Table 4.11–1. While ATADS reported a total of 214,486 general aviation operations at this airport in 2011, further information on the aircraft types comprising this activity was needed. The FAA’s Enhanced Traffic Management System Counts (ETMSC) database was used to “grow” available aircraft-specific operational data as described below. The ETMSC database on general aviation activity at Falcon Field airport (FFZ) in 2011 comprises 145 different aircraft types, totaling 3,731 operations (See Table 4.11–2). To simplify modeling input requirements, this aircraft-specific activity data were ranked in order of decreasing frequency. Activity data for the most frequently reported aircraft was then grown to represent all general aviation activity. How this approach was applied for general aviation activity at Falcon Field airport is shown in Table 4.11–2. This approach of ranking reported activity, and then growing this subset of data, typically resulted in a set of 10 to 30 aircraft types being modeled for each airport/aircraft class combination, representing 75 to 100% of all reported activity. Ozone season-day emissions were calculated by dividing ozone season total emissions by 92 (the number of days in the ozone season). Tables 4.11–3 and 4.11–4 list the total annual emissions and season-day emissions, by airport and aircraft type for airports within and outside the eighthour ozone nonattainment area, respectively. Tables 4.11–3 and 4.11–4 list the total annual and seasonal daily emissions by aircraft type, for airports located inside and outside the eight-hour ozone nonattainment area, respectively. 2011 Ozone Precursor Emissions Inventory 74 February 2014 Table 4.11–2. Growing aircraft-specific activity for EDMS modeling input. Rank 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26  145 Aircraft Type DA40 - Diamond Star DA40 BE9L - Beech King Air 90 P28R - Cherokee Arrow/Turbo DA42 - Diamond Twin Star BE20 - Beech 200 Super King C25B - Cessna Citation CJ3 PC12 - Pilatus PC-12 C680 - Cessna Citation Sovereign C441 - Cessna Conquest B350 - Beech Super King Air 350 BE36 - Beech Bonanza 36 C172 - Cessna Skyhawk 172/Cutlass CL60 - Bombardier Challenger 600/601/604 P46T - Piper Malibu Meridian SR22 - Cirrus SR 22 P28A - Piper Cherokee COL4 - Lancair LC-41 Columbia 400 TBM7 - Socata TBM-7 C182 - Cessna Skylane 182 C560 - Cessna Citation V/Ultra/Encore M20P - Mooney M-20C Ranger C210 - Cessna 210 Centurion PAY2 - Piper Cheyenne 2 C525 - Cessna CitationJet/CJ1 BE35 - Beech Bonanza 35 C414 - Cessna Chancellor 414  T34P - Beech T-34B Mentor Total: 2011 Ozone Precursor Emissions Inventory ETMSCReported Operations 536 350 250 163 130 118 110 103 99 86 84 83 70 68 67 62 52 50 48 47 46 44 40 38 37 37  1 3,731 75 % of Total Reported Operations 14.37% 9.38% 6.70% 4.37% 3.48% 3.16% 2.95% 2.76% 2.65% 2.31% 2.25% 2.22% 1.88% 1.82% 1.80% 1.66% 1.39% 1.34% 1.29% 1.26% 1.23% 1.18% 1.07% 1.02% 0.99% 0.99% Cumulative Percent 14.37% 23.75% 30.45% 34.82% 38.30% 41.46% 44.41% 47.17% 49.83% 52.13% 54.38% 56.61% 58.48% 60.31% 62.10% 63.76% 65.16% 66.50% 67.78% 69.04% 70.28% 71.46% 72.53% 73.55% 74.54% 75.53%  < 0.1%  100.00% “Grown” Operations for EDMS Modeling 40,796 26,640 19,028 12,406 9,894 8,982 8,372 7,840 7,536 6,546 6,394 6,318 5,328 5,176 5,100 4,718 3,958 3,806 3,654 3,578 3,502 3,348 3,044 2,892 2,816 2,814 (n/a) 214,486 February 2014 Table 4.11–3. Annual and season-day emissions, by aircraft type, for airports in the eight-hour ozone NAA. Annual emissions (tons/yr) Season-day emissions (lbs/day) Facility Category VOC NOx CO VOC NOx CO Buckeye Municipal GA 5.46 2.69 211.10 26.7 11.3 1,172.3 Chandler Municipal AC 0.02 0.00 0.04 0.4 0.0 0.8 AT 12.82 1.23 13.52 69.0 6.2 73.5 GA 127.56 14.18 1,329.77 629.0 62.4 7,236.4 ML 0.05 0.04 4.85 1.0 0.7 91.2 Total 140.45 15.45 1,348.17 699.3 69.2 7,401.9 Falcon Field AC 0.01 0.00 0.02 0.2 0.0 0.4 AT 7.15 2.27 11.43 36.5 10.5 58.9 GA 103.99 31.13 1,170.22 484.1 126.8 6,009.2 ML 3.73 2.67 9.86 17.4 10.8 47.2 Total 114.88 36.07 1,191.53 538.1 148.1 6,115.7 Gila Bend Municipal GA 0.36 0.18 14.29 1.8 0.9 71.0 Glendale Municipal AT 3.67 0.88 5.17 15.6 3.6 22.3 GA 88.19 17.14 519.57 449.8 78.3 2,899.0 ML 0.05 0.01 0.14 0.1 0.0 0.4 Total 91.91 18.02 524.88 465.5 81.9 2,921.7 Luke Air Force Base ML 154.13 347.83 601.72 844.5 1905.9 3,297.1 Phoenix Deer Valley AC 0.00 0.00 0.00 0.0 0.0 0.0 AT 13.65 3.00 17.69 60.0 11.9 78.4 GA 93.34 52.99 2,382.41 525.7 278.4 15,313.0 ML 0.20 0.11 0.70 1.2 0.5 3.9 Total 107.19 56.10 2,400.81 586.9 290.8 15,395.2 Phoenix Goodyear AC 0.12 0.40 0.92 0.5 1.6 4.4 AT 0.53 1.01 1.49 2.4 4.5 6.9 GA 43.39 13.80 1,224.97 234.8 62.9 7,380.0 ML 3.55 1.31 17.22 25.8 8.6 132.6 Total 47.60 16.52 1,244.61 263.6 77.6 7,523.9 Phoenix Sky Harbor AC 266.99 1,823.15 1,893.82 1,414.1 8,732.7 9,944.4 Intl AT 26.03 101.94 182.25 143.0 506.8 1,004.2 GA 42.59 7.41 140.93 198.2 31.1 702.2 ML 110.67 14.01 119.21 474.6 52.9 510.3 Total 446.28 1,946.50 2,336.21 2,230.0 9,323.5 12,161.0 Phoenix-Mesa AC 2.25 27.46 33.32 12.3 138.9 179.9 Gateway Airport AT 56.62 3.53 58.50 285.8 16.2 298.1 GA 146.94 9.81 713.40 666.4 39.8 3,512.1 ML 47.87 25.62 100.88 202.6 95.6 428.0 Total 253.68 66.42 906.11 1,167.2 290.5 4,418.1 Pleasant Valley GA 0.21 1.61 2.69 1.1 7.6 14.6 Scottsdale AC 0.02 0.00 0.04 0.0 0.0 0.0 AT 57.90 8.19 69.79 242.1 31.8 295.1 GA 274.72 67.08 650.51 1,271.3 283.6 3,082.5 ML 1.33 0.35 3.64 5.3 1.2 14.6 Total 333.96 75.63 723.98 1,518.7 316.5 3,392.1 Skyranch at Carefree GA 1.63 0.58 16.13 4.9 1.6 55.5 Stellar Airpark GA 7.69 2.38 197.13 37.5 9.9 1,053.5 8–hr ozone NAA total: 1,705.43 2,585.98 11,719.36 8,385.8 12,535.3 64,993.6 AC: Air Commercial; AT: Air Taxi; GA: General Aviation; ML: Military 2011 Ozone Precursor Emissions Inventory 76 February 2014 Table 4.11–4. Annual and season-day emissions, by aircraft type, for airports outside the eight-hour ozone NAA. Annual emissions Season-day emissions (tons/yr) (lbs/day) Facility Category VOC NOx CO VOC NOx CO Wickenburg Municipal GA 13.90 2.84 62.02 65.2 12.9 331.8 Maricopa County total: 1,719.33 2,588.82 11,781.38 8,451. 0 12,548.2 65,325.4 4.12 Locomotives Annual emissions from locomotives were calculated based on diesel fuel usage provided by Burlington Northern/Santa Fe Railway (BNSF), Union Pacific Railway (UP) and Amtrak. Railway operations from these companies fall into three categories: Class I haul lines, yard/switching operations, and passenger trains. Annual emissions were calculated by multiplying diesel fuel usage by the emission factors listed in Table 4.12–1 (US EPA, 2009). Table 4.12–1. Emission factors for locomotives. Emission factors (lbs/gal diesel) Activity type VOC NOx CO Class I haul line 0.018 0.328 0.059 Yard/switch operations 0.032 0.517 0.060 Passenger trains 0.019 0.367 0.059 Fuel use reported by railroads and emission totals are summarized in Table 4.12–2. Table 4.12–2. Fuel use and annual emissions from locomotives in Maricopa County. Annual emissions (tons/yr) Locomotive type Diesel fuel used (gals) VOC NOx CO Class I haul line 7,706,715 68.74 1,263.13 231.75 Yard/switch operations 520,076 8.43 134.44 12.63 Passenger trains 46,301 0.43 8.51 1.36 Total: 8,273,092 77.60 1,406.08 245.74 Eight-hour ozone nonattainment area emissions were calculated by multiplying Maricopa County emissions by the percentage of track miles inside the eight-hour ozone nonattainment area, determined by GIS mapping. Results are shown in Table 4.12–3. Table 4.12–3. Annual emissions from locomotives in the eight-hour ozone NAA. Annual emissions (tons/yr) Track in nonattainLocomotive type ment area (%) VOC NOx CO Class I haul line 60.65% 41.69 766.09 140.56 Yard/switch operations 100.00% 8.43 134.44 12.63 Passenger trains 6.98% 0.03 0.59 0.09 Total: 50.15 901.12 153.29 Ozone season-day emissions for both the county and the eight-hour ozone nonattainment area (shown in Table 4.12–4) were calculated by dividing annual totals by 365 days per year, as locomotive activity is assumed to be uniform throughout the year. 2011 Ozone Precursor Emissions Inventory 77 February 2014 Table 4.12–4. Season-day emissions from locomotives in Maricopa County and the eight-hour ozone NAA. Maricopa County 8-hr ozone NAA Season-day emissions (lbs/day) Locomotive type VOC NOx CO VOC NOx CO Class I haul line 376.6 6,921.3 1,269.9 228.4 4,197.7 770.2 Yard/switch operations 46.2 736.7 69.2 46.2 736.7 69.2 Passenger trains 2.4 46.6 7.4 0.2 3.3 0.5 Total: 425.2 7,704.5 1,346.5 274.8 4,937.7 839.9 4.13 Summary of all nonroad mobile source emissions Table 4.13–1 summarizes annual and season day emissions of VOC, NOx, and CO from nonroad mobile sources in Maricopa County, respectively. Table 4.13–2 shows annual and season-day emissions for these pollutants for the eight-hour ozone nonattainment area. Table 4.13–1. Annual and season-day emissions from nonroad mobile sources in Maricopa County. Annual emissions (tons/yr) Season-day emissions (lbs/day) Category VOC NOx CO VOC NOx CO Agricultural 38.53 330.49 303.71 329.3 2,762.6 2,584.4 Airport GSE & APUs 111.98 406.04 3,275.98 587.3 2,136.6 17,155.0 Commercial 1,924.41 1,361.42 30,224.21 14,537.1 8,334.7 203,404.4 Construction & mining 1,881.88 12,937.30 14,396.92 13,116.9 87,972.9 99,942.8 Industrial 341.25 1,839.35 7,140.99 2,212.6 11,763.4 46,138.5 Lawn & garden 4,913.96 866.64 54,798.41 51,990.4 6,998.4 523,235.5 Pleasure craft 530.39 96.56 1,249.66 11,527.0 1,996.8 26,738.3 Railway maintenance 1.94 8.55 16.48 14.2 59.0 117.8 Recreational 1,518.97 66.10 6,373.46 17,804.4 679.3 74,424.8 Aircraft 1,719.33 2,588.82 11,781.38 8,451. 0 12,548.2 65,325.4 Locomotives 77.60 1,406.08 245.74 425.2 7,704.5 1,346.5 Total: 13,060.24 21,907.35 129,806.94 120,995.4 142,956.4 1,060,413.4 Table 4.13–2. Annual and season-day emissions from nonroad mobile sources in the eight-hour ozone NAA. Annual emissions (tons/yr) Season-day emissions (lbs/day) Category VOC NOx CO VOC NOx CO Agricultural 22.52 193.22 177.56 192.5 1,615.1 1,510.9 Airport GSE & APUs 111.43 404.49 3,259.08 584.5 2,128.9 17,071.7 Commercial 1,916.15 1,355.57 30,094.46 14,474.7 8,299.0 202,531.2 Construction & mining 1,941.80 13,349.23 14,855.32 13,534.5 90,774.0 103,125.0 Industrial 339.78 1,831.45 7,110.33 2,203.1 11,712.9 45,940.4 Lawn & garden 4,970.15 876.55 55,425.05 52,584.9 7,078.4 529,218.9 Pleasure craft 530.39 96.56 1,249.66 11,527.0 1,996.8 26,738.3 Railway maintenance 1.96 8.64 16.67 14.4 59.7 119.1 Recreational 684.30 29.78 2,871.27 8,020.9 306.0 33,528.7 Aircraft 1,705.43 2,585.98 11,719.36 8,385.8 12,535.3 64,993.6 Locomotives 50.15 901.12 153.29 274.8 4,937.7 839.9 Total: 12,274.06 21,632.59 126,932.05 111,797.1 141,443.8 1,025,617.7 2011 Ozone Precursor Emissions Inventory 78 February 2014 4.14 Quality assurance procedures Established procedures were used to check, and correct when necessary, the nonroad mobile sources emissions estimates. All NONROAD model input and output files, and Excel spreadsheets used to calculate the emissions, were checked by personnel who were not involved in the development of the modeling inputs/outputs and spreadsheets. In addition, the emissions estimates were reviewed for reasonableness by external agency staff. 4.15 References ENVIRON et al., 2003. Maricopa County 2002 Comprehensive Emission Inventory for the Cap and Trade Oversight Committee, Final Report prepared for Arizona Department of Environmental Quality, Oct. 9, 2003. ESRL, 2012. NOAA/ESRL Radiosonde Database, (http://www.esrl.noaa.gov/raobs/). FAA, 2012a. Air Traffic Activity System (ATADS), (http://aspm.faa.gov/opsnet/sys/Airport.asp). FAA, 2012b. Aviation Performance Metrics (APM), (https://aspm.faa.gov/apm/sys/AnalysisAP.asp). MCAQD, 2011. 2008 PM10Periodic Emissions Inventory for the Maricopa County, Nonattainment Area. NCDC, 2012. The 2008 1-miniute Automated Surface Observing System (ASOS) Data, (ftp://ftp.ncdc.noaa.gov/pub/data/asos-onemin/) US EPA, 2009. Emission Factors for Locomotives. Office of Transportation and Air Quality. Rep. EPA420-F-09-025, April 2009. Internet address: http://www.epa.gov/otaq/regs/ nonroad/locomotv/420f09025.pdf. US EPA, 2002. Geographic Allocation of State Level Nonroad Engine Population Data to the County Level. EPA Office of Transportation and Air Quality, Rep. EPA420-P-02-009, July. Internet address: http://www.epa.gov/otaq/models/nonrdmdl/p02009.pdf US EPA, 1999. Weekday and Weekend Day Temporal Allocation of Activity in the NONROAD Model. EPA Office of Transportation and Air Quality, Rep. EPA420-P-99-033, March. Internet address: http://www.epa.gov/otaq/models/nonrdmdl/p99033.pdf 2011 Ozone Precursor Emissions Inventory 79 February 2014 This page intentionally blank. 2011 Ozone Precursor Emissions Inventory 80 February 2014 5. 5.1 Onroad Mobile Sources Introduction Onroad mobile source emissions for ozone precursors, such as volatile organic compounds (VOCs), nitrogen oxides (NOx), and carbon monoxide (CO), have been calculated for the eighthour ozone nonattainment area (NAA) and Maricopa County for the 2011 Periodic Emissions Inventory (PEI). Motor Vehicle Emission Simulator (MOVES2010b) is the latest model developed by the U.S. Environmental Protection Agency (EPA) for the purpose of estimating onroad and off-network motor vehicle emission factors. The MOVES2010b modeling accounted for the oxygenated fuel and the Arizona Vehicle Inspection/Maintenance (I/M) programs applied in Maricopa County in 2011. The fuel use assumptions, including oxygen content and Reid Vapor Pressure (RVP), were derived from the 2011 fuel inspection results provided by the Arizona Department of Weights and Measures. In order to develop the 2011 onroad mobile source emissions, the 2011 vehicle miles traveled (VMT) estimates by facility type and road type were derived from the 2011 Highway Performance Monitoring System (HPMS) data provided by the Arizona Department of Transportation (ADOT). The distribution of VMT by vehicle type is based on the July 2011 vehicle registration data for Maricopa County provided by ADOT. The VMT by vehicle type was provided as local input data for MOVES2010b to produce onroad emissions. The main references for preparing the onroad mobile source portion of the 2011 emissions inventory were: • Emission Inventory Requirements for Ozone State Implementation Plans (US EPA, 1991); • Procedures for Emission Inventory Preparation Volume IV: Mobile Sources (US EPA, 1992a); • Quality Review Guidelines for 1990 Base Year Emission Inventories (US EPA, 1992b); • User’s Guide for the SMOKE-MOVES Integration Tool (US EPA, 2010); • Motor Vehicle Emission Simulator (MOVES) - User Guide Version, MOVES2010b (US EPA, 2012a); • Policy Guidance on the Use of MOVES2010 and Subsequent Minor Revisions for State Implementation Plan Development, Transportation Conformity, and Other Purposes (US EPA, 2012b); and • Using MOVES to Prepare Emissions Inventories in State Implementation Plans and Transportation Conformity: Technical Guidance for MOVES2010, 2010a and 2010b (US EPA, 2012c). 5.2 Onroad emissions Vehicle exhaust and evaporative emission factors for VOC, NOx, and CO were calculated using MOVES2010b. The MOVES2010b runs were executed by MAG. The contact person for the MOVES2010b emission estimates is Ieesuck Jung (602-254-6300). 2011 Ozone Precursor Emissions Inventory 81 February 2014 5.2.1 MOVES2010b model The emissions were calculated using MOVES2010b. MOVES2010b is EPA’s state-of-the-art emissions modeling tool, which replaces EPA’s previous mobile source emissions model, MOBILE6.2. MOVES2010b is intended for official use to estimate national, state, and county level inventories of criteria air pollutants from highway vehicles. The user of MOVES2010b is allowed to specify vehicle types, time periods, geographical areas, pollutants, vehicle operating characteristics, and road types for a particular scenario to be modeled by creating a Run Specification (RunSpec). In order to calculate vehicle emissions for the calendar year 2011, MOVES2010b was executed using local input data for each month of the year and each geographical area (the eight-hour ozone nonattainment area and Maricopa County). Each scenario was created using the County Domain/Scale and the Inventory Calculation Type. The specific MOVES2010b model RunSpec and RunSpec summaries are described in Appendix C. 5.2.2 MOVES2010b local input data Compared with MOBILE6.2, MOVES2010b requires a more detailed level of local data, including fuel data, I/M program, meteorological data, vehicle population, source type age distribution, annual VMT, monthly/daily/hourly VMT fractions, road type distribution, average speed distribution, ramp fraction, and Alternative Vehicle and Fuel Technologies (AVFT) strategy. 5.2.2.1 Fuel data Regarding the fuel local input data, MOVES2010b provides two MOVES tables, which are [fuelsupply] and [fuelformulation]. The fuel data for each month were derived from the 2011 fuel inspection results in Maricopa County provided by the Arizona Department of Weights and Measures. The 2011 fuel inspection results reflected the committed control measure – California Phase 2 Reformulated Gasoline with (1) 3.5% Oxygen Content from November 1 through March 31 (MAG, 2003) and (2) 7 psi from May 1 through September 30 (MAG, 2009). The fuel data for Maricopa County were also applied to the eight-hour ozone nonattainment area. The specific MOVES tables for fuel data are presented in Appendix C. 5.2.2.2 I/M programs MOVES2010b has an [IMCoverage] table for I/M programs; this table was prepared using MOBILE6.2 input. This table reflects the actual proportions of vehicles subject to the specified levels of inspection. The term “I/M vehicles” denotes vehicles which are required to undergo an emission test and/or inspection under the Vehicle Inspection/Maintenance Program. It is important to note that participation in the I/M program is required for all vehicles registered in Area A, with the exception of certain model years and vehicle classes. However, it is assumed that 91.6 percent of the vehicles operating within the eight-hour ozone nonattainment area and Maricopa County participate in the I/M program and the remaining 8.4 percent do not participate in the program. These percentages reflect the control measures “Tougher Enforcement of Vehicle Registration and Emissions Test Compliance” and “Expansion of Area A Boundaries,” described in the MAG Eight-Hour Ozone Redesignation Request and Maintenance Plan for the 2011 Ozone Precursor Emissions Inventory 82 February 2014 Maricopa Nonattainment Area (MAG, 2009). This percentage is directly applied to the Compliance Factor in the [IMCoverage] table. The same I/M programs were applied for the eight-hour ozone nonattainment area and Maricopa County. The specific MOVES table for I/M programs is presented in Appendix C. 5.2.2.3 Meteorological data MOVES2010b requires hourly temperature and relative humidity data by specific month of the year. Meteorological data for the Phoenix Sky Harbor International Airport in 2011 were obtained from the National Climatic Data Center (http://www.ncdc.noaa.gov/). The same hourly average temperature and relative humidity data for each month were applied for the eight-hour ozone nonattainment area and Maricopa County. The specific MOVES table [ZoneMonthHour] for meteorological data is presented in Appendix C. 5.2.2.4 Vehicle population In order to capture start, evaporative, and extended idle emissions, MOVES2010b introduced a new mobile source emission category called off-network emissions. In MOVES2010b, these off-network emissions are directly determined by population of vehicles in an area. The vehicle population in Maricopa County was obtained from the July 2011 vehicle registration data provided by ADOT. The vehicle population data were allocated to the 28 MOBILE6.2 vehicle types based on MOBILE6.2 VMT fractions for 2011. Then, the vehicle population data allocated to the 28 MOBILE6.2 vehicle types were assigned to the 13 MOVES source types using the match-up table (Table A.1) in EPA’s technical guidance (EPA, 2012c). The vehicle population in the eight-hour ozone nonattainment area was estimated by applying the population ratio of the two geographical areas to the vehicle population in Maricopa County. The specific MOVES table [SourceTypeYear] for vehicle population is presented in Appendix C. 5.2.2.5 Source type age distribution MOVES2010b categorizes vehicles according to vehicle classes and model years. The source type age distribution was prepared using EPA’s data converter that takes the registration distribution input file created for MOBILE6.2 and converts it to the appropriate MOVES age distribution input table [SourceTypeAgeDistribution]. The same source type age distribution was applied for the eight-hour ozone nonattainment area and Maricopa County. The specific MOVES table for source type age distribution is presented in Appendix C. 5.2.2.6 Annual VMT The 2011 daily VMTs by facility type were used to estimate onroad exhaust and evaporative emissions. The 2011 VMT distributions by facility type for the eight-hour ozone nonattainment area and Maricopa County were obtained from the 2011 Maricopa County Estimates of Daily Vehicle Travel by Highway Functional Classification provided by ADOT. The 2011 VMT distributions were multiplied by the 2011 HPMS VMT for the eight-hour ozone nonattainment area and Maricopa County. The resultant VMT estimates by facility type for the eight-hour ozone nonattainment area and Maricopa County are shown in Table 5.2–1. Since MOVES2010b requires annual VMTs by HPMS vehicle type as a local input, the daily VMTs by HPMS vehicle type were derived from the 2011 traffic assignment data provided by 2011 Ozone Precursor Emissions Inventory 83 February 2014 the MAG transportation modeling group in May 2011 and the daily VMTs by facility type and the estimated percentages of daily vehicle travel by vehicle type and highway functional classification provided by ADOT. Then, the daily VMTs by HPMS vehicle type were multiplied by 365 days to obtain the annual VMTs by HPMS vehicle type. The specific MOVES table [HPMSvTypeYear] for annual VMT is presented in Appendix C. 2011 daily VMT by facility type (annual average daily traffic). 8-hr ozone NAA Facility Type (thousand miles/day) Interstate 1,833 Other Principal Arterial 897 Minor Arterial 166 Major Collector 734 Minor Collector 95 Local 149 Interstate 10,906 Other Freeway/Expressway 19,263 Other Principal Arterial 21,474 Minor Arterial 13,767 Collector 4,680 Local 9,910 Total: 83,874 Urban Rural Table 5.2–1. 5.2.2.7 Maricopa County (thousand miles/day) 3,247 1,589 293 1,301 168 264 11,182 19,750 22,017 14,115 4,799 10,160 88,885 Road type distribution MOVES2010b requires the distribution of VMTs by road type as a local input. The road type VMT distribution by HPMS vehicle type was derived from the 2011 traffic assignment data and the daily VMTs by HPMS vehicle type mentioned in the previous section. As suggested in EPA’s technical guidance (US EPA, 2010), the same road type distribution by HPMS vehicle type was used for all MOVES source types within an HPMS vehicle class. The specific MOVES table [RoadTypeDistribution] for road type distribution is presented in Appendix C. 5.2.2.8 VMT fraction Since VMT varies by month, day of week, and hour, MOVES2010b requires month/day/hour VMT fractions as a local input in order to derive hourly VMT for each weekday/weekend and month from the annual VMT. The month/day/hour VMT fractions were developed from data recorded by continuous traffic counters on freeways (ADOT Freeway Management System) and arterials (Phoenix Automatic Traffic Recorders) during the year 2007. The specific MOVES tables [MonthVMTFraction], [DayVMTFraction], and [HourVMTFraction] for VMT fractions are presented in Appendix C. 2011 Ozone Precursor Emissions Inventory 84 February 2014 5.2.2.9 Average speed distribution In MOVES2010b, vehicle power, speed, and acceleration have a significant effect on vehicle emissions for all pollutants. MOVES2010b estimates those emission effects by assigning activity to operating mode distributions, which are determined by the distribution of vehicle hours traveled (VHT) by average speed. As recommended in EPA’s technical guidance (US EPA, 2010), estimates of local average speeds were developed by post-processing the output from the 2011 traffic assignment data provided by the MAG transportation modeling group in May 2011. To develop the average speed distribution, VHTs in sixteen speed bins were accumulated separately for each hour of the day, source type, and road type in Maricopa County. Then, the average speed distribution was calculated by normalizing VHTs in sixteen speed bins for each hour of the day, source type, and road type. The same methodology was applied to develop the speed estimates for the eight-hour ozone nonattainment area. The specific MOVES table [AvgSpeedDistribution] for the average speed distribution is presented in Appendix C. 5.2.2.10 Ramp fraction MOVES2010b requires the ramp fraction, which represents the percent of VHT on ramps, on both rural restricted roads (road type 2) and urban restricted roads (road type 4). The fraction of VHT on ramps was derived by dividing the total VHTs on ramps by the total VHTs for each restricted road type. Those VHTs were obtained from the 2011 traffic assignment data provided by the MAG transportation modeling group in May 2011. The specific MOVES table [RoadType] for ramp fractions is presented in Appendix C. 5.2.2.11 AVFT strategy MOVES2010b allows users to modify the fuel engine fraction using different fuels and technologies in each model year in order to reflect the local situation. The fleet information for transit buses for model years 1997 through 2011 was provided by Valley Metro and used to prepare the AVFT input file. Since the fleet data are available only for specific model years, MOVES2010b default values were obtained from the [fuelEngFraction] table in the MOVES default database and used for the rest of the model years. The specific MOVES table [AVFT] for AVFT strategy is presented in Appendix C. 5.2.2.12 Stage II refueling control programs As an option, MOVES2010b allows to apply Stage refueling emission control programs. Since 1994, the Stage II refueling program has been implemented in Area A as one of committed control measures (MAG, 2009). The program efficiency of 46 percent for the refueling displacement vapor losses and the refueling spillage losses are assumed for LDGVs, LDGTs, and HDGVs (Yantorno, 2007). The same program efficiency was applied to the eight-hour ozone nonattainment area and Maricopa County. The specific MOVES table [CountyYear] for Stage II refueling control programs is presented in Appendix C. 2011 Ozone Precursor Emissions Inventory 85 February 2014 5.2.3 MOVES2010b outputs MOVES2010b was executed with the RunSpec files described in Appendix C to obtain exhaust and evaporative emissions for VOC, NOx, and CO. These values were obtained for the following categories by month: • • • Vehicle classes: light duty gasoline vehicles (LDGV), light duty gasoline trucks 1 and 2 (LDGT1), light duty gasoline trucks 3 and 4 (LDGT2), heavy duty gasoline vehicles 2B thru 8B and gasoline buses (HDGV), motorcycles (MC), light duty diesel vehicles (LDDV), light duty diesel trucks 1 thru 4 (LDDT), heavy duty diesel vehicles class 2B (2BHDDV), heavy duty diesel vehicles classes 3, 4, and 5 (LHDDV), heavy duty diesel vehicles classes 6 and 7 (MHDDV), heavy duty diesel vehicles classes 8A and 8B (HHDDV), and heavy duty diesel buses (BUSES) Facility types: rural interstate, rural principal arterial, rural minor arterial, rural major collector, rural minor collector, rural local, urban interstate, urban freeway/expressway, urban principal arterial, urban minor arterial, urban collector, urban local, and off-network, which was newly added in MOVES2010b Days: weekdays and weekend days 5.2.4 MOVES2010b emission estimates MOVES2010b was used to generate onroad emissions by vehicle class, facility type, weekdays/ weekend days, and month. By specifying the output time aggregate level as month, the model produces monthly emissions including weekday and weekend emissions for a given month. The annual emissions were calculated by aggregating monthly onroad emissions derived by MOVES2010b. The ozone season-day emissions were calculated by dividing the three-month peak ozone season emissions from July through September by 92 days. Tables 5.2–2 and 5.2–3 show the calculated annual and ozone season-day VOC, NOx, and CO emissions by facility type and vehicle class in the eight-hour ozone nonattainment area and Maricopa County, respectively. 2011 Ozone Precursor Emissions Inventory 86 February 2014 Table 5.2–2. Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in the eight-hour ozone NAA. Annual emissions (tons/year) Season-day emissions (lbs/day) Vehicle Facility Type Class SCC VOC NOx CO VOC NOx CO LDGV 2201001110 28.13 110.70 758.49 163.3 604.9 5,232.5 LDGT1 2201020110 51.89 243.02 1,356.15 303.6 1,314.9 9,185.7 LDGT2 2201040110 26.73 125.19 698.62 156.4 677.4 4,732.0 HDGV 2201070110 13.02 72.48 319.37 74.6 369.0 1,921.9 MC 2201080110 6.40 4.22 69.24 34.8 21.0 368.5 LDDV 2230001110 0.05 0.84 0.40 0.3 4.6 2.7 Rural Interstate LDDT 2230060110 1.62 13.96 8.85 9.2 77.5 60.3 2BHDDV 2230071110 0.71 6.18 3.89 4.0 34.4 26.5 LHDDV 2230072110 3.85 32.92 20.87 21.8 182.4 141.9 MHDDV 2230073110 10.86 164.12 45.16 57.2 807.2 237.2 HHDDV 2230074110 23.31 570.60 116.92 123.1 2,806.7 614.3 BUSES 2230075110 1.20 23.68 6.14 6.3 116.5 32.3 LDGV 2201001130 20.73 70.04 387.68 119.5 403.2 2,614.6 LDGT1 2201020130 18.86 76.50 363.07 109.6 434.4 2,408.3 LDGT2 2201040130 9.72 39.41 187.04 56.5 223.8 1,240.7 HDGV 2201070130 3.53 17.03 71.63 20.3 90.3 435.2 MC 2201080130 11.93 6.20 105.39 64.6 31.0 561.0 Rural LDDV 2230001130 0.04 0.63 0.26 0.2 3.7 1.7 Principal LDDT 2230060130 0.66 5.13 3.60 3.7 29.9 24.0 Arterial 2BHDDV 2230071130 0.29 2.28 1.58 1.6 13.3 10.6 LHDDV 2230072130 1.57 12.04 8.49 8.8 70.1 56.7 MHDDV 2230073130 2.27 27.40 8.99 11.9 135.0 47.2 HHDDV 2230074130 3.98 80.40 19.42 21.0 396.0 102.0 BUSES 2230075130 0.40 6.97 1.97 2.1 34.3 10.3 LDGV 2201001150 20.14 68.06 376.72 116.1 391.8 2,540.7 LDGT1 2201020150 18.33 74.33 352.81 106.5 422.1 2,340.3 LDGT2 2201040150 9.44 38.29 181.75 54.9 217.4 1,205.6 HDGV 2201070150 3.43 16.55 69.61 19.7 87.8 422.9 MC 2201080150 11.59 6.03 102.42 62.8 30.1 545.1 Rural LDDV 2230001150 0.04 0.61 0.26 0.2 3.6 1.7 Minor LDDT 2230060150 0.64 4.98 3.49 3.6 29.0 23.4 Arterial 2BHDDV 2230071150 0.28 2.21 1.54 1.6 12.9 10.3 LHDDV 2230072150 1.53 11.70 8.25 8.6 68.1 55.1 MHDDV 2230073150 2.20 26.63 8.73 11.6 131.1 45.9 HHDDV 2230074150 3.87 78.12 18.87 20.4 384.8 99.1 BUSES 2230075150 0.39 6.77 1.91 2.1 33.4 10.0 LDGV 2201001170 3.75 12.69 70.22 21.6 73.0 473.5 LDGT1 2201020170 3.42 13.86 65.76 19.9 78.7 436.2 LDGT2 2201040170 1.76 7.14 33.88 10.2 40.5 224.7 HDGV 2201070170 0.64 3.08 12.97 3.7 16.4 78.8 MC 2201080170 2.16 1.12 19.09 11.7 5.6 101.6 Rural LDDV 2230001170 0.01 0.11 0.05 0.0 0.7 0.3 Major LDDT 2230060170 0.12 0.93 0.65 0.7 5.4 4.4 Collector 2BHDDV 2230071170 0.05 0.41 0.29 0.3 2.4 1.9 LHDDV 2230072170 0.28 2.18 1.54 1.6 12.7 10.3 MHDDV 2230073170 0.41 4.96 1.63 2.2 24.4 8.5 HHDDV 2230074170 0.72 14.56 3.52 3.8 71.7 18.5 BUSES 2230075170 0.07 1.26 0.36 0.4 6.2 1.9 2011 Ozone Precursor Emissions Inventory 87 February 2014 Table 5.2–2. Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in the eight-hour ozone NAA (continued). Annual emissions (tons/year) Season-day emissions (lbs/day) Facility Vehicle Type Class SCC VOC NOx CO VOC NOx CO LDGV 2201001190 0.87 2.94 16.26 5.0 16.9 109.6 LDGT1 2201020190 0.79 3.21 15.22 4.6 18.2 101.0 LDGT2 2201040190 0.41 1.65 7.84 2.4 9.4 52.0 HDGV 2201070190 0.15 0.71 3.00 0.9 3.8 18.2 MC 2201080190 0.50 0.26 4.42 2.7 1.3 23.5 Rural LDDV 2230001190 0.00 0.03 0.01 0.0 0.2 0.1 Minor LDDT 2230060190 0.03 0.21 0.15 0.2 1.3 1.0 Collector 2BHDDV 2230071190 0.01 0.10 0.07 0.1 0.6 0.4 LHDDV 2230072190 0.07 0.50 0.36 0.4 2.9 2.4 MHDDV 2230073190 0.10 1.15 0.38 0.5 5.7 2.0 HHDDV 2230074190 0.17 3.37 0.81 0.9 16.6 4.3 BUSES 2230075190 0.02 0.29 0.08 0.1 1.4 0.4 LDGV 2201001210 9.08 30.68 169.82 52.3 176.6 1,145.3 LDGT1 2201020210 8.26 33.51 159.04 48.0 190.3 1,055.0 LDGT2 2201040210 4.26 17.26 81.93 24.7 98.0 543.5 HDGV 2201070210 1.55 7.46 31.38 8.9 39.6 190.6 MC 2201080210 5.22 2.72 46.17 28.3 13.6 245.7 Rural LDDV 2230001210 0.02 0.27 0.12 0.1 1.6 0.8 LDDT 2230060210 0.29 2.25 1.58 1.6 13.1 10.5 Local 2BHDDV 2230071210 0.13 1.00 0.69 0.7 5.8 4.6 LHDDV 2230072210 0.69 5.27 3.72 3.9 30.7 24.8 MHDDV 2230073210 0.99 12.00 3.94 5.2 59.1 20.7 HHDDV 2230074210 1.74 35.22 8.51 9.2 173.5 44.7 BUSES 2230075210 0.18 3.05 0.86 0.9 15.0 4.5 LDGV 2201001230 315.59 1,122.85 8,542.12 1,828.0 6,198.7 58,613.4 LDGT1 2201020230 389.33 1,602.91 9,784.95 2,271.6 8,744.6 65,893.5 LDGT2 2201040230 200.56 825.74 5,040.73 1,170.2 4,504.8 33,945.1 HDGV 2201070230 125.37 594.77 2,799.95 712.5 3,011.8 16,433.1 MC 2201080230 128.88 73.37 1,238.82 698.9 365.4 6,593.8 2230001230 0.54 8.81 4.59 3.0 49.4 30.9 Urban LDDV Interstate LDDT 2230060230 13.00 102.99 71.45 73.3 575.8 483.3 2BHDDV 2230071230 5.68 45.66 31.36 32.0 255.6 212.6 LHDDV 2230072230 31.01 242.58 169.13 174.7 1,354.0 1,141.6 MHDDV 2230073230 93.83 1,316.73 378.86 494.4 6,475.6 1,990.4 HHDDV 2230074230 173.92 3,747.08 854.68 918.0 18,429.4 4,490.3 BUSES 2230075230 14.35 272.67 73.30 75.6 1,341.1 385.1 LDGV 2201001250 331.11 1,178.07 8,962.22 1,917.9 6,503.5 61,496.0 LDGT1 2201020250 408.48 1,681.74 10,266.18 2,383.3 9,174.7 69,134.0 LDGT2 2201040250 210.43 866.35 5,288.63 1,227.8 4,726.3 35,614.5 HDGV 2201070250 131.53 624.02 2,937.66 747.5 3,160.0 17,241.3 Urban MC 2201080250 135.22 76.98 1,299.75 733.2 383.3 6,918.1 Freeway LDDV 2230001250 0.56 9.25 4.82 3.2 51.9 32.4 And LDDT 2230060250 13.64 108.06 74.96 76.9 604.1 507.1 Express2BHDDV 2230071250 5.96 47.91 32.90 33.6 268.2 223.0 way LHDDV 2230072250 32.53 254.51 177.45 183.3 1,420.6 1,197.8 MHDDV 2230073250 98.44 1,381.48 397.49 518.7 6,794.1 2,088.3 HHDDV 2230074250 182.48 3,931.36 896.71 963.2 19,335.8 4,711.2 BUSES 2230075250 15.05 286.08 76.90 79.3 1,407.1 404.0 2011 Ozone Precursor Emissions Inventory 88 February 2014 Table 5.2–2. Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in the eight-hour ozone NAA (continued). Annual emissions (tons/year) Season-day emissions (lbs/day) Facility Vehicle Type Class SCC VOC NOx CO VOC NOx CO LDGV 2201001270 867.65 2,461.71 14,822.61 4,980.2 14,626.5 98,722.0 LDGT1 2201020270 723.35 2,268.85 11,877.79 4,187.4 13,305.9 77,666.8 LDGT2 2201040270 372.63 1,168.80 6,118.85 2,157.1 6,854.6 40,010.1 HDGV 2201070270 159.42 526.27 2,610.59 907.1 2,833.3 15,528.2 MC 2201080270 364.35 120.97 2,387.52 1,968.4 603.7 12,707.9 Urban LDDV 2230001270 1.49 24.89 10.67 8.3 150.4 69.4 Principal LDDT 2230060270 25.26 203.10 142.81 141.2 1,229.5 939.0 Arterial 2BHDDV 2230071270 11.03 90.29 62.60 61.7 547.5 412.4 LHDDV 2230072270 60.30 478.09 338.58 336.9 2,889.2 2,221.8 MHDDV 2230073270 99.13 1,116.86 362.02 522.0 5,499.7 1,901.7 HHDDV 2230074270 167.56 2,988.26 778.64 883.9 14,715.7 4,090.3 BUSES 2230075270 14.31 229.46 66.76 75.4 1,130.0 350.7 LDGV 2201001290 441.02 1,251.27 7,534.27 2,531.4 7,434.6 50,180.0 LDGT1 2201020290 367.67 1,153.25 6,037.43 2,128.4 6,763.4 39,477.6 LDGT2 2201040290 189.41 594.10 3,110.19 1,096.5 3,484.2 20,337.0 HDGV 2201070290 81.03 267.50 1,326.95 461.1 1,440.2 7,892.9 MC 2201080290 185.20 61.49 1,213.57 1,000.5 306.8 6,459.4 Urban LDDV 2230001290 0.76 12.65 5.42 4.2 76.4 35.3 Minor LDDT 2230060290 12.84 103.24 72.59 71.8 625.0 477.3 Arterial 2BHDDV 2230071290 5.61 45.89 31.82 31.4 278.3 209.6 LHDDV 2230072290 30.65 243.01 172.10 171.2 1,468.6 1,129.3 MHDDV 2230073290 50.39 567.70 184.01 265.3 2,795.5 966.6 HHDDV 2230074290 85.17 1,518.92 395.78 449.3 7,479.9 2,079.1 BUSES 2230075290 7.27 116.63 33.93 38.3 574.4 178.3 LDGV 2201001310 86.13 244.37 1,471.39 494.4 1,451.9 9,799.8 LDGT1 2201020310 71.80 225.22 1,179.07 415.7 1,320.8 7,709.7 LDGT2 2201040310 36.99 116.02 607.40 214.1 680.4 3,971.7 HDGV 2201070310 15.82 52.24 259.14 90.0 281.3 1,541.4 MC 2201080310 36.17 12.01 237.00 195.4 59.9 1,261.5 2230001310 0.15 2.47 1.06 0.8 14.9 6.9 Urban LDDV Collector LDDT 2230060310 2.51 20.16 14.18 14.0 122.1 93.2 2BHDDV 2230071310 1.10 8.96 6.21 6.1 54.4 40.9 LHDDV 2230072310 5.99 47.46 33.61 33.4 286.8 220.5 MHDDV 2230073310 9.84 110.87 35.94 51.8 545.9 188.8 HHDDV 2230074310 16.63 296.63 77.29 87.7 1,460.8 406.0 BUSES 2230075310 1.42 22.78 6.63 7.5 112.2 34.8 LDGV 2201001330 415.75 1,179.56 7,102.48 2,386.3 7,008.5 47,304.1 LDGT1 2201020330 346.60 1,087.15 5,691.42 2,006.4 6,375.7 37,215.2 LDGT2 2201040330 178.55 560.05 2,931.94 1,033.6 3,284.5 19,171.4 HDGV 2201070330 76.39 252.17 1,250.90 434.7 1,357.6 7,440.6 MC 2201080330 174.58 57.96 1,144.02 943.2 289.2 6,089.2 Urban LDDV 2230001330 0.71 11.93 5.11 4.0 72.0 33.3 LDDT 2230060330 12.11 97.32 68.43 67.7 589.1 449.9 Local 2BHDDV 2230071330 5.29 43.26 30.00 29.6 262.4 197.6 LHDDV 2230072330 28.89 229.09 162.23 161.4 1,384.4 1,064.6 MHDDV 2230073330 47.50 535.16 173.46 250.1 2,635.3 911.2 HHDDV 2230074330 80.29 1,431.87 373.10 423.5 7,051.3 1,960.0 BUSES 2230075330 6.86 109.95 31.99 36.1 541.4 168.1 2011 Ozone Precursor Emissions Inventory 89 February 2014 Table 5.2–2. Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in the eight-hour ozone NAA (continued). Annual emissions (tons/year) Season-day emissions (lbs/day) Vehicle Facility Type Class SCC VOC NOx CO VOC NOx CO 220100100 LDGV 9,402.26 4,424.20 43,163.97 61,052.9 23,759.3 183,525.8 LDGT1 220102000 2,588.87 1,468.89 19,360.70 16,455.7 7,981.9 96,124.0 LDGT2 220104000 1,333.66 756.70 9,973.69 8,477.2 4,111.9 49,518.4 220107000 HDGV 372.55 217.03 4,052.96 2,338.4 1,182.2 20,958.3 220108000 MC 547.02 2.43 83.60 4,271.9 9.8 208.1 223000100 LDDV 6.48 27.63 25.05 22.4 120.8 131.4 OffNetwork LDDT 223006000 3.32 26.59 16.91 7.6 120.8 87.9 2BHDDV 223007100 1.42 11.66 7.35 3.2 52.9 38.2 LHDDV 223007200 7.79 62.35 39.03 17.8 283.1 202.6 MHDDV 223007300 24.50 144.11 189.20 112.6 621.4 1,016.4 223007400 HHDDV 418.93 2,672.32 1,119.58 2,179.6 12,161.2 5,908.3 BUSES 223007500 1.63 4.45 96.15 0.1 0.0 522.5 2011 Ozone Precursor Emissions Inventory 90 February 2014 Table 5.2–3. Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in Maricopa County. Annual emissions (tons/year) Season-day emissions (lbs/day) Facility Vehicle Type Class SCC VOC NOx CO VOC NOx CO LDGV 2201001110 41.81 166.74 1,147.40 242.9 911.2 7,919.6 LDGT1 2201020110 100.56 475.25 2,658.13 588.5 2,571.6 18,011.7 LDGT2 2201040110 51.80 244.83 1,369.34 303.2 1,324.8 9,278.8 HDGV 2201070110 21.52 118.92 538.20 123.8 610.0 3,301.0 MC 2201080110 11.22 7.49 122.76 61.0 37.3 653.4 LDDV 2230001110 0.07 1.25 0.60 0.4 6.9 4.1 Rural Interstate LDDT 2230060110 3.14 27.11 17.13 17.7 150.4 116.7 2BHDDV 2230071110 1.37 12.00 7.53 7.8 66.7 51.4 LHDDV 2230072110 7.47 63.90 40.44 42.2 354.2 275.0 MHDDV 2230073110 17.23 281.49 73.31 90.8 1,384.5 385.2 HHDDV 2230074110 45.10 1,129.87 228.30 238.2 5,557.7 1,199.4 BUSES 2230075110 1.71 34.23 8.79 9.0 168.4 46.2 LDGV 2201001130 33.65 113.61 629.45 193.9 654.0 4,244.8 LDGT1 2201020130 36.88 149.19 708.92 214.4 847.2 4,701.6 LDGT2 2201040130 19.00 76.86 365.20 110.4 436.4 2,422.1 HDGV 2201070130 6.69 31.89 135.07 38.5 169.7 824.3 MC 2201080130 21.15 10.98 186.63 114.5 54.8 993.4 Rural LDDV 2230001130 0.06 1.02 0.43 0.3 5.9 2.8 Principal LDDT 2230060130 1.30 10.05 7.05 7.3 58.6 47.1 Arterial 2BHDDV 2230071130 0.57 4.46 3.10 3.2 26.1 20.7 LHDDV 2230072130 3.08 23.59 16.65 17.3 137.3 111.1 MHDDV 2230073130 4.17 51.42 16.61 22.0 253.2 87.3 HHDDV 2230074130 7.84 159.49 38.37 41.4 785.5 201.6 BUSES 2230075130 0.72 12.48 3.53 3.8 61.5 18.5 LDGV 2201001150 32.70 110.40 611.65 188.5 635.5 4,124.9 LDGT1 2201020150 35.84 144.97 688.88 208.3 823.2 4,568.7 LDGT2 2201040150 18.46 74.68 354.88 107.3 424.1 2,353.6 HDGV 2201070150 6.50 30.98 131.25 37.4 164.9 801.0 MC 2201080150 20.55 10.67 181.35 111.3 53.2 965.3 Rural LDDV 2230001150 0.06 0.99 0.42 0.3 5.8 2.8 Minor LDDT 2230060150 1.26 9.76 6.85 7.1 56.9 45.8 Arterial 2BHDDV 2230071150 0.55 4.34 3.01 3.1 25.3 20.2 LHDDV 2230072150 2.99 22.92 16.18 16.8 133.4 107.9 MHDDV 2230073150 4.05 49.96 16.14 21.3 246.1 84.8 HHDDV 2230074150 7.62 154.98 37.28 40.2 763.3 195.9 BUSES 2230075150 0.70 12.13 3.43 3.7 59.8 18.0 LDGV 2201001170 6.09 20.58 114.00 35.1 118.4 768.8 LDGT1 2201020170 6.68 27.02 128.40 38.8 153.4 851.6 LDGT2 2201040170 3.44 13.92 66.14 20.0 79.0 438.7 HDGV 2201070170 1.21 5.78 24.46 7.0 30.7 149.3 MC 2201080170 3.83 1.99 33.80 20.7 9.9 179.9 Rural LDDV 2230001170 0.01 0.18 0.08 0.1 1.1 0.5 Major LDDT 2230060170 0.23 1.82 1.28 1.3 10.6 8.5 Collector 2BHDDV 2230071170 0.10 0.81 0.56 0.6 4.7 3.8 LHDDV 2230072170 0.56 4.27 3.01 3.1 24.9 20.1 MHDDV 2230073170 0.76 9.31 3.01 4.0 45.9 15.8 HHDDV 2230074170 1.42 28.89 6.95 7.5 142.3 36.5 BUSES 2230075170 0.13 2.26 0.64 0.7 11.1 3.4 2011 Ozone Precursor Emissions Inventory 91 February 2014 Table 5.2–3. Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in Maricopa County (continued). Annual emissions (tons/year) Season-day emissions (lbs/day) Facility Vehicle Type Class SCC VOC NOx CO VOC NOx CO LDGV 2201001190 1.41 4.76 26.39 8.1 27.4 178.0 LDGT1 2201020190 1.55 6.26 29.73 9.0 35.5 197.1 LDGT2 2201040190 0.80 3.22 15.31 4.6 18.3 101.6 HDGV 2201070190 0.28 1.34 5.66 1.6 7.1 34.6 MC 2201080190 0.89 0.46 7.83 4.8 2.3 41.7 Rural LDDV 2230001190 0.00 0.04 0.02 0.0 0.2 0.1 Minor LDDT 2230060190 0.05 0.42 0.30 0.3 2.5 2.0 Collector 2BHDDV 2230071190 0.02 0.19 0.13 0.1 1.1 0.9 LHDDV 2230072190 0.13 0.99 0.70 0.7 5.8 4.7 MHDDV 2230073190 0.17 2.16 0.70 0.9 10.6 3.7 HHDDV 2230074190 0.33 6.69 1.61 1.7 32.9 8.5 BUSES 2230075190 0.03 0.52 0.15 0.2 2.6 0.8 LDGV 2201001210 14.74 49.77 275.73 85.0 286.5 1,859.5 LDGT1 2201020210 16.15 65.35 310.54 93.9 371.1 2,059.6 LDGT2 2201040210 8.32 33.67 159.98 48.4 191.2 1,061.0 HDGV 2201070210 2.93 13.97 59.17 16.8 74.3 361.1 MC 2201080210 9.27 4.81 81.75 50.2 24.0 435.1 Rural LDDV 2230001210 0.03 0.45 0.19 0.1 2.6 1.2 LDDT 2230060210 0.57 4.40 3.09 3.2 25.7 20.6 Local 2BHDDV 2230071210 0.25 1.96 1.36 1.4 11.4 9.1 LHDDV 2230072210 1.35 10.33 7.29 7.6 60.1 48.7 MHDDV 2230073210 1.83 22.52 7.28 9.6 110.9 38.2 HHDDV 2230074210 3.43 69.87 16.81 18.1 344.1 88.3 BUSES 2230075210 0.31 5.47 1.55 1.7 26.9 8.1 LDGV 2201001230 321.75 1,147.02 8,736.08 1,863.8 6,328.9 59,952.7 LDGT1 2201020230 398.95 1,645.13 10,050.63 2,327.9 8,971.4 67,690.5 LDGT2 2201040230 205.52 847.49 5,177.59 1,199.2 4,621.6 34,870.8 HDGV 2201070230 129.18 613.34 2,887.04 734.1 3,105.0 16,939.0 MC 2201080230 131.85 75.30 1,270.33 715.0 375.0 6,761.5 2230001230 0.55 8.99 4.69 3.1 50.4 31.5 Urban LDDV Interstate LDDT 2230060230 13.33 105.63 73.26 75.1 590.3 495.6 2BHDDV 2230071230 5.82 46.83 32.15 32.9 262.1 218.0 LHDDV 2230072230 31.79 248.83 173.43 179.1 1,388.4 1,170.7 MHDDV 2230073230 96.93 1,361.53 391.49 510.7 6,696.0 2,056.8 HHDDV 2230074230 179.94 3,879.33 884.45 949.8 19,079.9 4,646.8 BUSES 2230075230 14.81 281.59 75.68 78.0 1,385.0 397.6 LDGV 2201001250 337.58 1,203.43 9,165.73 1,955.5 6,640.2 62,901.2 LDGT1 2201020250 418.57 1,726.04 10,544.93 2,442.3 9,412.6 71,019.7 LDGT2 2201040250 215.63 889.17 5,432.23 1,258.2 4,848.9 36,585.8 HDGV 2201070250 135.53 643.51 3,029.03 770.2 3,257.7 17,772.0 Urban MC 2201080250 138.33 79.00 1,332.81 750.1 393.4 7,094.0 Freeway LDDV 2230001250 0.58 9.43 4.92 3.2 52.9 33.1 and LDDT 2230060250 13.98 110.83 76.86 78.8 619.4 519.9 Express2BHDDV 2230071250 6.11 49.13 33.73 34.5 275.0 228.7 way LHDDV 2230072250 33.36 261.06 181.96 187.9 1,456.7 1,228.3 MHDDV 2230073250 101.70 1,428.49 410.75 535.8 7,025.3 2,158.0 HHDDV 2230074250 188.78 4,070.12 927.95 996.5 20,018.3 4,875.3 BUSES 2230075250 15.54 295.43 79.40 81.9 1,453.1 417.2 2011 Ozone Precursor Emissions Inventory 92 February 2014 Table 5.2–3. Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in Maricopa County (continued). Annual emissions (tons/year) Season-day emissions (lbs/day) Facility Vehicle Type Class SCC VOC NOx CO VOC NOx CO LDGV 2201001270 887.40 2,518.28 15,177.93 5,093.7 14,946.0 101,100.4 LDGT1 2201020270 740.73 2,323.35 12,173.14 4,288.1 13,611.0 79,607.5 LDGT2 2201040270 381.59 1,196.87 6,271.01 2,209.0 7,011.7 41,009.9 HDGV 2201070270 163.87 541.20 2,685.49 932.4 2,910.9 15,968.7 MC 2201080270 372.91 123.95 2,445.17 2,014.6 618.5 13,014.7 Urban LDDV 2230001270 1.53 25.46 10.92 8.5 153.6 71.0 Principal LDDT 2230060270 25.87 207.85 146.31 144.6 1,256.8 962.1 Arterial 2BHDDV 2230071270 11.30 92.40 64.13 63.2 559.6 422.5 LHDDV 2230072270 61.76 489.28 346.88 345.0 2,953.3 2,276.6 MHDDV 2230073270 102.21 1,151.68 373.34 538.2 5,671.2 1,961.2 HHDDV 2230074270 172.44 3,077.56 801.69 909.6 15,155.6 4,211.4 BUSES 2230075270 14.77 236.81 68.89 77.8 1,166.2 361.9 LDGV 2201001290 451.06 1,280.03 7,714.88 2,589.1 7,597.0 51,389.0 LDGT1 2201020290 376.51 1,180.95 6,187.56 2,179.6 6,918.4 40,464.2 LDGT2 2201040290 193.96 608.37 3,187.53 1,122.8 3,564.0 20,845.2 HDGV 2201070290 83.30 275.09 1,365.02 473.9 1,479.6 8,116.9 MC 2201080290 189.55 63.00 1,242.87 1,024.0 314.4 6,615.3 Urban LDDV 2230001290 0.78 12.94 5.55 4.3 78.1 36.1 Minor LDDT 2230060290 13.15 105.65 74.37 73.5 638.8 489.0 Arterial 2BHDDV 2230071290 5.74 46.97 32.60 32.1 284.5 214.8 LHDDV 2230072290 31.39 248.70 176.32 175.4 1,501.2 1,157.2 MHDDV 2230073290 51.95 585.39 189.77 273.6 2,882.6 996.9 HHDDV 2230074290 87.65 1,564.31 407.50 462.3 7,703.5 2,140.7 BUSES 2230075290 7.51 120.37 35.02 39.5 592.8 184.0 LDGV 2201001310 88.09 249.98 1,506.66 505.6 1,483.6 10,035.9 LDGT1 2201020310 73.53 230.63 1,208.39 425.7 1,351.1 7,902.4 LDGT2 2201040310 37.88 118.81 622.50 219.3 696.0 4,070.9 HDGV 2201070310 16.27 53.72 266.58 92.6 289.0 1,585.2 MC 2201080310 37.02 12.30 242.72 200.0 61.4 1,291.9 2230001310 0.15 2.53 1.08 0.8 15.2 7.1 Urban LDDV Collector LDDT 2230060310 2.57 20.63 14.52 14.4 124.8 95.5 2BHDDV 2230071310 1.12 9.17 6.37 6.3 55.6 41.9 LHDDV 2230072310 6.13 48.57 34.43 34.3 293.2 226.0 MHDDV 2230073310 10.15 114.32 37.06 53.4 563.0 194.7 HHDDV 2230074310 17.12 305.50 79.58 90.3 1,504.4 418.1 BUSES 2230075310 1.47 23.51 6.84 7.7 115.8 35.9 LDGV 2201001330 425.21 1,206.67 7,272.74 2,440.7 7,161.6 48,443.8 LDGT1 2201020330 354.93 1,113.27 5,832.94 2,054.7 6,521.9 38,145.1 LDGT2 2201040330 182.84 573.50 3,004.85 1,058.5 3,359.8 19,650.5 HDGV 2201070330 78.52 259.32 1,286.79 446.8 1,394.8 7,651.6 MC 2201080330 178.68 59.39 1,171.64 965.3 296.4 6,236.2 Urban LDDV 2230001330 0.73 12.20 5.23 4.1 73.6 34.0 Local LDDT 2230060330 12.40 99.59 70.11 69.3 602.2 461.0 2BHDDV 2230071330 5.41 44.27 30.73 30.3 268.2 202.5 LHDDV 2230072330 29.59 234.45 166.21 165.3 1,415.1 1,090.9 MHDDV 2230073330 48.97 551.84 178.89 257.9 2,717.4 939.8 HHDDV 2230074330 82.63 1,474.66 384.14 435.8 7,262.0 2,018.0 BUSES 2230075330 7.08 113.47 33.01 37.3 558.8 173.4 2011 Ozone Precursor Emissions Inventory 93 February 2014 Table 5.2–3. Annual and ozone season-day onroad mobile source emissions by facility type and vehicle class in Maricopa County (continued). Annual emissions (tons/year) Season-day emissions (lbs/day) Facility Vehicle Type Class SCC VOC NOx CO VOC NOx CO LDGV 2201001000 9,343.57 4,398.52 42,913.45 60,666.2 23,621.4 182,460.8 LDGT1 2201020000 2,565.00 1,457.16 19,206.53 16,298.8 7,918.2 95,359.0 LDGT2 2201040000 1,321.36 750.66 9,894.27 8,396.3 4,079.0 49,124.2 HDGV 2201070000 369.74 215.64 4,033.93 2,320.0 1,174.6 20,862.9 MC 2201080000 539.75 2.40 82.65 4,215.5 9.7 205.7 LDDV 2230001000 6.44 27.47 24.90 22.3 120.1 130.6 OffNetwork LDDT 2230060000 3.29 26.39 16.79 7.6 119.8 87.2 2BHDDV 2230071000 1.41 11.57 7.30 3.2 52.5 37.9 LHDDV 2230072000 7.74 61.88 38.74 17.6 281.0 201.1 MHDDV 2230073000 26.03 153.86 192.53 120.6 666.0 1,033.9 HHDDV 2230074000 448.68 2,863.21 1,186.93 2,336.0 13,033.7 6,262.1 BUSES 2230075000 1.62 4.42 95.35 0.1 0.0 518.1 2011 Ozone Precursor Emissions Inventory 94 February 2014 5.3 Summary of ozone precursor emissions from onroad mobile sources Tables 5.3–1 and 5.3–2 show the annual and ozone season-day onroad mobile source emissions by facility type in the eight-hour ozone nonattainment area and Maricopa County, respectively. Table 5.3–1. ozone NAA. Annual and ozone season-day onroad mobile source emissions by facility type in the eight-hour Urban Rural Facility Type Interstate Principal Arterial Minor Arterial Major Collector Minor Collector Local Interstate Freeway/Expressway Principal Arterial Minor Arterial Collector Local Off-network Total Table 5.3–2. County. Rural Season-day emissions (lbs/day) VOC NOx CO 954.6 7,016.5 22,555.8 419.8 1,865.0 7,512.3 408.1 1,812.1 7,300.1 76.1 337.7 1,360.6 17.8 78.3 314.9 183.8 816.9 3,290.7 8,452.2 51,306.2 190,213.1 8,867.9 53,829.6 199,567.7 16,229.6 64,386.0 254,620.3 8,249.4 32,727.3 129,422.4 1,610.9 6,391.4 25,275.2 7,776.6 30,851.4 122,005.2 94,939.4 50,405.3 358,241.9 148,186.2 301,823.7 1,321,680.2 Annual and ozone season-day onroad mobile source emissions by facility type in Maricopa Facility Type Interstate Principal Arterial Minor Arterial Major Collector Minor Collector Local Interstate Freeway/Expressway Principal Arterial Minor Arterial Collector Local Off-network Total Urban Annual emissions (tons/year) VOC NOx CO 167.77 1,367.91 3,404.10 73.98 344.03 1,159.12 71.88 334.28 1,126.36 13.39 62.30 209.96 3.12 14.42 48.60 32.41 150.69 507.76 1,492.06 9,956.16 28,989.94 1,565.43 10,445.81 30,415.67 2,866.48 11,677.55 39,579.44 1,457.02 5,935.65 20,118.06 284.55 1,159.19 3,928.92 1,373.52 5,595.47 18,965.08 14,708.43 9,818.36 78,128.19 24,110.04 56,861.82 226,581.20 Annual emissions (tons/year) VOC NOx CO 303.00 2,563.08 6,211.93 135.11 645.04 2,111.01 131.28 626.78 2,051.32 24.46 116.83 382.33 5.66 27.05 88.53 59.18 282.57 924.74 1,530.42 10,261.01 29,756.82 1,605.69 10,765.64 31,220.30 2,936.38 11,984.69 40,564.90 1,492.55 6,091.77 20,618.99 291.50 1,189.67 4,026.73 1,406.99 5,742.63 19,437.28 14,634.63 9,973.18 77,693.37 24,556.85 60,269.94 235,088.25 Season-day emissions (lbs/day) VOC NOx CO 1,725.5 13,143.7 41,242.5 767.0 3,490.2 13,675.3 745.3 3,391.5 13,288.9 138.9 632.0 2,476.9 32.0 146.3 573.7 336.0 1,528.8 5,990.5 8,668.7 52,854.0 195,231.5 9,094.9 55,453.5 204,833.2 16,624.7 66,014.4 260,967.9 8,450.1 33,554.9 132,649.3 1,650.4 6,553.1 25,905.5 7,966.0 31,631.8 125,046.8 94,404.2 51,076.0 356,283.5 150,603.7 319,470.2 1,378,165.5 Tables 5.3–3 and 5.3–4 present the same emissions by vehicle class in the eight-hour ozone nonattainment area and Maricopa County, respectively. 2011 Ozone Precursor Emissions Inventory 95 February 2014 Table 5.3–3. Annual and ozone season-day onroad mobile source emissions by vehicle class in the eighthour ozone NAA. Annual emissions (tons/year) Season-day emissions (lbs/day) Vehicle Class VOC NOx CO VOC NOx CO LDGV 11,942.21 12,157.14 93,378.25 75,668.9 68,649.4 521,757.3 LDGT1 4,997.65 9,932.44 66,509.59 30,440.7 56,125.6 408,747.3 LDGT2 2,574.55 5,116.70 34,262.49 15,681.6 28,913.2 210,566.7 HDGV 984.43 2,651.31 15,746.11 5,819.4 13,873.3 90,103.4 MC 1,609.22 425.76 7,951.01 10,016.4 2,120.7 42,083.4 LDDV 10.85 100.12 57.82 46.7 550.2 346.9 LDDT 86.04 688.92 479.65 471.5 4,022.6 3,161.3 2BHDDV 37.56 305.81 210.30 205.9 1,788.7 1,388.6 LHDDV 205.15 1,621.70 1,135.36 1,123.8 9,453.6 7,469.4 MHDDV 440.46 5,409.17 1,789.81 2,303.5 26,530.0 9,424.9 HHDDV 1,158.77 17,368.71 4,663.83 6,083.6 84,483.4 24,528.1 BUSES 63.15 1,084.04 396.98 324.2 5,313.0 2,102.9 Total 24,110.04 56,861.82 226,581.20 148,186.2 301,823.7 1,321,680.2 Table 5.3–4. County. Annual and ozone season-day onroad mobile source emissions by vehicle class in Maricopa Vehicle Class LDGV LDGT1 LDGT2 HDGV MC LDDV LDDT 2BHDDV LHDDV MHDDV HHDDV BUSES Total Annual emissions (tons/year) VOC NOx CO 11,985.06 12,469.79 95,292.09 5,125.88 10,544.57 69,728.72 2,640.60 5,432.05 35,920.83 1,015.54 2,804.70 16,447.69 1,655.00 451.74 8,402.31 10.99 102.95 59.03 91.14 730.13 507.92 39.77 324.10 222.70 217.34 1,718.77 1,202.24 466.15 5,763.97 1,890.88 1,242.98 18,784.48 5,001.56 66.40 1,142.69 412.28 24,556.85 60,269.94 235,088.25 Season-day emissions (lbs/day) VOC NOx CO 75,868.1 70,411.7 535,379.4 31,170.0 59,506.6 430,578.7 16,057.2 30,654.8 221,813.1 5,995.1 14,668.3 94,367.6 10,247.0 2,250.3 44,488.1 47.5 566.4 354.9 500.2 4,256.8 3,351.0 218.7 1,892.8 1,472.4 1,192.3 10,004.6 7,918.3 2,438.8 28,272.7 9,956.3 6,527.4 91,383.2 26,302.6 341.4 5,602.0 2,183.1 150,603.7 319,470.2 1,378,165.5 Table 5.3–5 summarizes annual and ozone season-day emissions for VOC, NOx, and CO from all onroad mobile sources in the eight-hour ozone nonattainment area and Maricopa County in 2011. Table 5.3–5. Annual and ozone season-day emissions from all onroad mobile sources in the eight-hour ozone NAA and Maricopa County. Annual emissions (tons/year) Season-day emissions (lbs/day) VOC NOx CO VOC NOx CO 8-hr ozone NAA 24,110.04 56,861.82 226,581.20 148,186.2 301,823.7 1,321,680.2 Maricopa County 24,556.85 60,269.94 235,088.25 150,603.7 319,470.2 1,378,165.5 2011 Ozone Precursor Emissions Inventory 96 February 2014 5.4 Quality assurance process 5.4.1 VMT estimates Normal quality assurance procedures, including automated and manual consistency checks, were conducted by MAG in developing the 2011 TransCAD traffic assignment network used to generate the VMT data. The VMT estimates using the MAG travel demand model have been validated by the MAG transportation modeling group. 5.4.2 Emission estimates The quality assurance process performed on the MOVES2010b analyses included accuracy, completeness, and reasonableness checks. For accuracy and completeness, all calculations were checked by an independent reviewer. Any errors found were corrected and the corrections were then rechecked by the reviewer. 5.4.3 Draft emissions inventory for ozone precursors The draft onroad mobile source portion of the 2011 periodic emissions inventory for ozone precursors was reviewed using published EPA quality review guidelines for base year emissions inventories (EPA, 1992b). The procedure review (Levels I, II, and III) included checks for completeness, consistency, and the correct use of appropriate procedures. 5.5 References MAG, 2003. Carbon Monoxide Redesignation Request and Maintenance Plan for the Maricopa County Nonattainment Area, May 2003. MAG, 2009. MAG Eight-Hour Ozone Redesignation Request and Maintenance Plan for the Maricopa Nonattainment Area, February 2009. US EPA, 1991. Emission Inventory Requirements for Ozone State Implementation Plans, EPA450/4-91-010, March 1991. US EPA, 1992a. Procedures for Emission Inventory Preparation Volume IV: Mobile Sources, EPA-450/4-81-026d (Revised), 1992. US EPA, 1992b. Quality Review Guidelines for 1990 Base Year Emission Inventories, EPA454/R-92-007, July 1992. US EPA, 2010. User’s Guide for the SMOKE-MOVES Integration Tool, EPA Contract EP-D07-102 (WA 3-03), July 2010. US EPA, 2012a. Motor Vehicle Emission Simulator (MOVES) - User Guide Version, MOVES2010b, EPA-420-B-12-001, March 2012. US EPA, 2012b. Policy Guidance on the Use of MOVES2010 and Subsequent Minor Revisions for State Implementation Plan Development, Transportation Conformity, and Other Purposes, EPA-420-B-12-010, April 2012. US EPA, 2012c. Using MOVES to Prepare Emission Inventories in State Implementation Plans and Transportation Conformity: Technical Guidance for MOVES2010, 2010a and 2010b, EPA-420-B-12-028, April 2012. Yantorno, D., 2007. E-mail correspondence with Mr. Duane Yantorno at the Arizona Department of Weights and Measures, February 16, 2007. 2011 Ozone Precursor Emissions Inventory 97 February 2014 This page intentionally blank. 2011 Ozone Precursor Emissions Inventory 98 February 2014 6. 6.1 Biogenic Sources Introduction Biogenic emissions have been estimated for the 2011 Periodic Emissions Inventory for ozone precursors in Maricopa County (9,223 square miles) and the eight-hour ozone nonattainment area (NAA) (5,025 square miles). The Model of Emissions of Gases and Aerosols from Nature (MEGAN) has been used to estimate the biogenic emissions. MEGAN is a state-of-the-art biogenic emissions model developed by the National Center for Atmospheric Research (NCAR). Some important corrections and improvements were made in the latest version of MEGAN2.1 (Guenther et al, 2012; Jiang et al, 2011) compared to previous versions (Guenther, 2006a, 2006b, and 2007; Guenther et al, 2006). The most important change is that higher temporal and spatial resolution of land use and land cover data for MEGAN input has become available. MEGAN, with the vegetation data released in 2011, was applied to compute biogenic emissions in Maricopa County and the eight-hour ozone nonattainment area. Estimated emissions for volatile organic compounds (VOC), carbon monoxide (CO), and nitrogen oxides (NOx) are included in this biogenic emissions inventory. The MEGAN runs were executed by the Maricopa Association of Governments. The contact person for the MEGAN emission estimates is Feng Liu (602-254-6300). 6.2 Modeling domain As a numerical model, the MEGAN inputs and outputs are given in user-defined twodimensional grid cells. To develop biogenic emissions for the 2011 Periodic Emissions Inventory for ozone precursors, the 4-km modeling domain that covers the entire area of Maricopa County were employed. The target area is the eight-hour ozone nonattainment area within the County. The definition of the domain in the Lambert Conformal Conic Projection (LCP) coordinate system is presented in Table 6.2–1. Since MEGAN estimates biogenic emissions for the entire modeling domain rather than specific areas, additional input files, masking areas covered by the eight-hour ozone nonattainment area and Maricopa County, were developed by applying Geographic Information Systems (GIS) to calculate emissions for those two target areas. In order to represent the target area, the masking file assigns 1.0 for the grid cells fully covered by the target area, a fractional value for grid cells partially covered by the target area, and 0.0 for grid cells outside the target area. As shown in Figure 6.3–1, biogenic emissions for the eight-hour ozone nonattainment area and Maricopa County were extracted from MEGAN runs for the masked grid cells in the 4-km modeling domain. Table 6.2–1. Two modeling domains defined in the LCP coordinate system. Grid Horizontal Grid Size LCP Range (km) Resolution (–131.4713, –129.4593) to 4-km 65 by 65 (127.9845, 131.1945) 6.3 Target Area Eight-hour ozone NAA and Maricopa County Input data To calculate biogenic emissions using MEGAN, the following gridded input files for land cover and meteorological data were prepared: 2011 Ozone Precursor Emissions Inventory 99 February 2014 EFMAP_LAI file: This file provides emission factors (EF) for 20 MEGAN species including NOx, CO and VOC, and 8-day average leaf index (LAI) for year 2011in each grid cell. 2. PFTF file: This input file gives percentage of four plant function types (PFT) including broadleaf trees (BT), needle leaf trees (NT), grass and crops (HB) and shrubs (SB) for each model domain grid location. 3. METCRO2D file: This file contains meteorological parameters including temperature, short wave radiation, wind speed, humidity and soil moisture for each grid. 1. Figure 6.3–1. The masked grid cells in the 4-km modeling domain. 6.3.1 Land cover data The land cover data, including the 8-day averaged LAI input files for North America for years 2003 to 2011 based on NASA MODIS data, monthly mean PFT, and EF, are provided by the EFMAP_LAI and PFTF files. These input data were derived from the MEGAN land cover database available at the resolution of 30 seconds latitude by 30 seconds longitude (1x1 km2) in netCDF format (http://acd.ucar.edu/~guenther/MEGAN/MEGAN.htm). 6.3.2 Weather data The weather data used by MEGAN are temperature, downward short wave radiation, wind speed, humidity and soil moisture. The Measurement and Instrumentation Data Center (MIDC) collects irradiance and meteorological data from nation-wide stations. One of those stations is located in northern Phoenix (33.83°N, 112.17°W, see red star in Figure 6.3–1) and is operated by the National Renewable Energy Laboratory (NREL). The archived hourly temperature, wind speed, humidity and radiation data from this site are available to the public. Monthly mean 2011 Ozone Precursor Emissions Inventory 100 February 2014 diurnal cycles of the weather parameters were calculated based on hourly data for the year 2011, and a netCDF file representing 24-hour data for each month was prepared for MEGAN inputs. Biogenic emissions of VOC, NOx, and CO are first governed by temperature and then highly dependent on downward short wave radiation. Figure 6.3–2 shows monthly mean (left panel) and annual mean diurnal cycle (right panel) of temperature. Figure 6.3–3 illustrates monthly averaged and annual mean diurnal cycle of short wave radiation. The maximum monthly temperature was recorded in August, while the highest radiation was observed in June. The maximum monthly temperature appeared two months later than the highest radiation. The peak hourly temperature was observed around 4:00 – 6:00 pm and lagged three hours behind the peak radiation. The delay is due to the fact that heating of the air occurs not from the sun’s rays, but from heating of the earth and infrared radiation leaving the ground in the form of heat. As a result, maximum seasonal emission rates appear in the summer. The highest hourly emission rates take place in the afternoon because the emission rates are positively related to both temperature and short wave radiation (Guenther et al., 2006, 2012). The maximum monthly VOC, NOx, and CO biogenic emission rates would be expected to occur in the same month as the maximum temperature. Figure 6.3–2. Monthly averaged temperature (left panel) and annual mean diurnal cycle of temperature (right panel) in 2011. Figure 6.3–3. Monthly averaged radiation (left panel) and annual mean diurnal cycle of radiation (right panel) in 2011. 6.4 Emission estimation MEGAN runs for the modeling domain provide hourly emission outputs for the year 2011. Figure 6.4–1 illustrates isoprene (ISOP), a major contributor to VOCs, and NOx emission rates simulated by MEGAN at 17:00 MST in August, 2011. The high ISOP emissions occur in northeastern portion. The high NOx emissions appear at the central part of Maricopa County and southeastern portion. Daily mean emissions for each month in 2011 are derived by using the hourly outputs for each month. In addition, monthly total emissions were obtained by multiplying the daily mean emissions for each month by the number of days in the month. The 2011 Ozone Precursor Emissions Inventory 101 February 2014 daily mean emissions for the 12 months in 2011 are shown in Tables 6.4–1 and 6.4–2 for the eight-hour ozone nonattainment area and Maricopa County, respectively. Figure 6.4–1. Estimated emission rates of ISOP (left panel) and NOx (right panel) at 17:00 MST, August 2011 by MEGAN model. Table 6.4–1. Month January February March April May June July August September October November December Daily mean biogenic emissions for each month in the eight-hour ozone NAA. VOC NOx CO kg/day lbs/day kg/day lbs/day kg/day 15,264.7 33,652.9 210.5 464.1 2,950.2 35,341.7 77,915.0 351.6 775.1 5,262.4 73,407.4 161,835.4 796.7 1,756.4 10,665.2 97,461.1 214,864.7 910.5 2,007.3 11,966.6 139,906.1 308,439.8 1,113.0 2,453.7 14,937.6 313,026.5 690,104.5 2,308.4 5,089.1 27,998.8 314,669.0 693,725.6 2,855.0 6,294.2 29,982.6 326,736.8 720,330.5 3,415.3 7,529.4 32,557.0 208,257.6 459,128.9 2,209.6 4,871.3 22,623.7 86,989.6 191,779.0 994.4 2,192.3 11,389.6 20,395.5 44,964.3 309.9 683.2 3,687.5 11,230.4 24,758.8 171.8 378.8 2,295.1 2011 Ozone Precursor Emissions Inventory 102 lbs/day 6,504.1 11,601.6 23,512.7 26,381.8 32,931.7 61,726.7 66,100.2 71,775.8 49,876.7 25,109.7 8,129.5 5,059.8 February 2014 Table 6.4–2. Month January February March April May June July August September October November December Daily mean biogenic emissions for each month in Maricopa County. VOC NOx kg/day lbs/day kg/day lbs/day 23,123.3 50,978.1 316.3 697.3 53,015.2 116,878.4 524.0 1,155.2 104,165.5 229,645.3 1,152.6 2,541.0 139,181.0 306,841.2 1,330.8 2,933.9 200,913.3 442,937.5 1,641.2 3,618.2 451,990.3 996,466.9 3,432.5 7,567.4 451,204.3 994,734.0 4,207.9 9,276.8 467,398.8 1,030,436.7 5,031.7 11,093.0 300,464.1 662,409.2 3,278.2 7,227.2 129,711.0 285,963.5 1,506.4 3,321.0 30,063.3 66,278.2 462.5 1,019.6 16,413.2 36,184.9 252.8 557.3 CO kg/day 5,654.4 9,971.5 19,383.1 22,591.4 28,869.2 55,292.2 58,566.5 63,445.8 44,256.1 23,713.3 7,101.2 4,255.2 lbs/day 12,465.8 21,983.4 42,732.4 49,805.5 63,645.6 121,898.3 129,116.9 139,873.9 97,567.9 52,278.8 15,655.4 9,381.1 Monthly mean emissions for Maricopa County and the eight-hour ozone nonattainment area are illustrated in Figure 6.4–2. Monthly emission values for the eight-hour ozone nonattainment area and Maricopa County are presented in Tables 6.4–3 and 6.4–4, respectively. It can be seen that the maximum monthly VOC, NOx, and CO emissions took place in August, because monthly mean temperatures reached the maximum levels in this month. 2011 Ozone Precursor Emissions Inventory 103 February 2014 Figure 6.4–2. Monthly emissions of VOC (top), NOx (middle) and CO (bottom) in Maricopa County (pink solid line, abbreviated as “County”) and the eight-hour ozone NAA (blue solid line, abbreviated as “O3 NAA”). 2011 Ozone Precursor Emissions Inventory 104 February 2014 Table 6.4–3. Month January February March April May June July August September October November December Table 6.4–4. Month January February March April May June July August September October November December 6.5 Monthly biogenic emissions in the eight-hour ozone NAA. VOC NOx Metric tons Short tons Metric tons Short tons 473.21 521.62 6.53 7.19 989.57 1,090.81 9.84 10.85 2,275.63 2,508.45 24.70 27.22 2,923.83 3,222.97 27.32 30.11 4,337.09 4,780.82 34.50 38.03 9,390.80 10,351.57 69.25 76.34 9,754.74 10,752.75 88.51 97.56 10,128.84 11,165.12 105.87 116.71 6,247.73 6,886.93 66.29 73.07 2,696.68 2,972.57 30.83 33.98 611.87 674.46 9.30 10.25 348.14 383.76 5.33 5.87 CO Metric tons 91.46 147.35 330.62 359.00 463.07 839.96 929.46 1,009.27 678.71 353.08 110.63 71.15 Short tons 100.81 162.42 364.45 395.73 510.44 925.90 1,024.55 1,112.53 748.15 389.20 121.94 78.43 Monthly biogenic emissions in Maricopa County. VOC NOx Metric tons Short tons Metric tons Short tons 716.82 790.16 9.81 10.81 1,484.43 1,636.30 14.67 16.17 3,229.13 3,559.50 35.73 39.39 4,175.43 4,602.62 39.92 44.01 6,228.31 6,865.53 50.88 56.08 13,559.71 14,947.00 102.98 113.51 13,987.33 15,418.38 130.44 143.79 14,489.36 15,971.77 155.98 171.94 9,013.92 9,936.14 98.35 108.41 4,021.04 4,432.43 46.70 51.48 901.90 994.17 13.88 15.29 508.81 560.87 7.84 8.64 CO Metric tons 175.29 279.20 600.88 677.74 894.95 1,658.77 1,815.56 1,966.82 1,327.68 735.11 213.04 131.91 Short tons 193.22 307.77 662.35 747.08 986.51 1,828.47 2,001.31 2,168.05 1,463.52 810.32 234.83 145.41 Summary of biogenic source emissions Ozone season daily emissions for Maricopa County and the eight-hour ozone nonattainment area in 2011 are shown in Table 6.5–1. Annual emissions for Maricopa County and the eight-hour ozone nonattainment area in 2011 are summarized in Table 6.5–2. Emissions of VOC, NOx, and CO all decreased in 2011 compared to MEGAN results for PEI 2008. Due to the incorporation of land cover data that are more characteristic of plants located in the desert southwest, as well as improvements to the MEGAN model, the 2011 data shown in Tables 6.5–1 and 6.5–2 represent a substantial improvement over previous biogenic emission estimates for Maricopa County and the eight-hour ozone NAA. 2011 Ozone Precursor Emissions Inventory 105 February 2014 Table 6.5–1. Season-day biogenic emissions. VOC Area kg/day lbs/day Maricopa County 406,355.7 895,860.0 8-hr ozone NAA 283,221.1 624,395.0 Annual biogenic emissions. VOC Area tonnes*/yr tons*/yr Maricopa County 72,316.20 79,714.87 8-hr ozone NAA 50,178.11 55,311.84 NOx kg/day 4,172.6 2,826.6 CO lbs/day 9,199.0 6,231.7 kg/day 55,422.8 28,387.8 tons/yr 779.52 527.18 tonnes/yr 10,476.94 5,383.74 lbs/day 122,186.2 62,584.2 Table 6.5–2. NOx tonnes/yr 707.17 478.25 CO tons/yr 11,548.84 5,934.55 * “Tonne” denotes metric ton, and “ton” denotes short (or English) ton 6.6 References Guenther, A., 2006a. User’s Guide to Processing Driving Variables for Model of Emissions of Gases and Aerosols from Nature (MEGAN). Guenther, A., 2006b. User’s Guide to the Model of Emissions of Gases and Aerosols from Nature (MEGAN) Version MEGAN-VBA-2.0. Guenther, A., 2007. Corrigendum to "Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature)" Atmos. Chem. Phys., 6, 3181–3210, 2006, Atmos. Chem. Phys., 7, 4327-4327. Guenther, A., T. Karl, P. Harley, C. Wiedinmyer, P. I. Palmer, and C. Geron, 2006. Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmos. Chem. Phys., 6, 1-30. Guenther, A., X. Jiang, C. L. Heald, T Sakulyanontvittaya, T. Duhl, L. K. Emmons, and X. Wang, 2012. The model of emissions of gases and aerosols from nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions, Geosci. Model Dev. Discuss., 5, 1503-1560. Jiang, X., A. Guenther, and T. Duhl, 2011. MEGAN version 2.10 User’s Guide. 2011 Ozone Precursor Emissions Inventory 106 February 2014 Appendix A. Instructions for Reporting 2011 Annual Air Pollution Emissions INSTRUCTIONS FOR REPORTING 2011 ANNUAL AIR POLLUTION EMISSIONS February 2012 Emissions Inventory Unit 1001 North Central Avenue, Suite 125 Phoenix, Arizona 85004 Phone: (602) 506-6790 Fax: (602) 506-6179 Email: EmisInv@mail.maricopa.gov Copies of this document, related forms, and other reference materials are available online at our web site: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx TABLE OF CONTENTS WHAT’S NEW FOR 2011? .............................................................................................................. 1 I. INTRODUCTION............................................................................................................................. 2 Steps to Complete Your 2011 Maricopa County Emissions Inventory II. REPORTING REQUIREMENTS................................................................................................... 3 - Pollutants to be Reported - Emission Calculation Method Hierarchy III. CONFIDENTIALITY OF DATA SUBMITTED............................................................................ 5 - Arizona State Statue and Maricopa County Rule IV. HELPFUL HINTS AND INFORMATION..................................................................................... 6 - What is a Process? - Processes and Materials That Do Not Have to be Reported - Grouping Materials and/or Equipment Under One Process ID - Assigning Identification Numbers (IDs) - Industry-Specific Instructions - Commonly Used Conversion Factors - Additional Resources and Assistance V. INSTRUCTIONS AND EXAMPLES FOR EMISSIONS REPORTING FORMS Business Form ..................................................................................................................................... 8 Stack Form ......................................................................................................................................... 9 Control Device Form ....................................................................................................................... 10 General Process Form ....................................................................................................................... 11 Evaporative Process Form ................................................................................................................ 15 Off-Site Recycling/Disposal Form.................................................................................................... 19 Documentation of Emission Factor Calculations.............................................................................. 20 Data Certification Form (for NON-Title V sources) ........................................................................ 21 How to Calculate an Emission Fee (for Title V sources ONLY)...................................................... 22 Data Certification/Fee Calculation Form (for Title V sources ONLY) ............................................ 23 Maricopa County Emissions Inventory Unit ii Instructions for Reporting 2011 Emissions WHAT'S NEW FOR 2011? Reporting forms: • Emission factors for PM-10 for several processes typically found at sand and gravel facilities and/or concrete batch plants, have been revised. The new values are lower than the previous EPA default emission factors, and reflect the more stringent moisture-content requirements required by Maricopa County Rule 316 (Nonmetallic Mineral Processing). • Some preprinted information on your report may be different from last year’s version. Please review the enclosed forms carefully, and verify all preprinted information. • Many of our reporting forms have changed in past years. If you develop your own forms, or a computerized reproduction of our forms, the forms used MUST conform to the current information requirements and FORMAT as supplied on our preprinted forms. “Homemade” reporting forms that vary significantly from the preprinted forms sent to you will not be accepted. • Please VERIFY THOROUGHLY that the information you provide on all reporting forms match the information presented on the preprinted forms from MCAQD. Miscellaneous: • Non-operational facilities: Any facility that has been issued an air quality permit, but that did NOT operate at any time during 2011, must still respond in writing to this request for annual emissions information, as a condition of its air quality permit. Please provide ALL information requested on both the “Business Form” and the “Data Certification Form”, and submit these forms, along with a letter certifying that there were no operations at the facility during calendar year 2011, by the due date shown on the Business Form. • Emissions fees for Title V facilities: In accordance with Maricopa County Air Pollution Control Rule 280 (Fees), the 2011 annual emission fee for Title V sources is $39.83/ton. NOTE: Only emissions from Title V sources (those whose air quality permit numbers have a “V” prefix) are subject to this annual emissions fee. Maricopa County Emissions Inventory Unit 1 Instructions for Reporting 2011 Emissions I. INTRODUCTION An annual emissions inventory is a document submitted by a business that: (1) lists all processes emitting reportable air pollutants and (2) provides details about each of those processes. Submitting the emissions inventory report is required as a condition of your Maricopa County Air Quality Permit. A separate emissions report is required for each business location with its own air quality permit. Follow these steps to complete your 2011 Maricopa County emissions inventory: STEP 1: Determine which forms are needed for your business. There are eight different forms available, but not all are required for every type of business. For most permitted sources, the packet you received from us contains the necessary preprinted forms based on your site’s most recent emissions inventory. 1. 2. 3. 4. 5. 6. 7. 8. Business Form: Contains general contact information about the permitted site. This form is required for all businesses. Stack Form: Only required if your business location annually emits over 10 tons of a single pollutant (CO, VOC, NO x , PM 10 , or SO x ). A “stack” is defined as a stack, pipe, vent or opening through which a significant percentage of emissions (from one or more processes) are released into the atmosphere. See the “Stack Form Instructions” on page 9 for specific requirements. Control Device Form: Required only if there is one or more emission control devices used at the business location. General Process Form and Either or both will be required for all businesses. Evaporative Process Form: Off-Site Recycling/Disposal Form: Required if you want to claim off-site recycling or disposal. Emission Factor Calculations: Required as attachment for each process for which you calculated your own emission factors. Data Certification Form or Data Certification/Fee Calculation Form: Only sources with a Title V (permit number would start with “V”) permit are required to pay a fee for their emissions and need to use the Data Certification/Fee Calculation Form. All other sources use the Data Certification Form. } STEP 2: Complete the applicable forms. Verify all preprinted information, and make corrections where necessary. When making corrections, strike out the preprinted data and write in corrections beside it. Please make all changes readily noticeable. Detailed information on how to complete the most common forms is included in this document. The packet you received also contains information about other resources (workshops, one-on-one assistance, etc.) available to help you in completing the necessary forms. STEP 3: Make a copy of your completed emissions inventory report. Make sure to KEEP COPIES of all forms submitted and copies of all records and calculations used in completing the forms. Air pollution control regulations require that you keep all documentation for at least FIVE YEARS at the location where pollution is being emitted. STEP 4: Make sure the Data Certification Form (or Data Certification/Fee Calculation Form for Title V sources) is signed by a company representative. Include your air quality permit number on all correspondence and applicable checks submitted with your report. Return the original, signed copy of your annual emission report, with payment for any applicable emission fees to: Maricopa County Air Quality Department Emissions Inventory Unit 1001 North Central Avenue, Suite 125 Phoenix, AZ 85004 Maricopa County Emissions Inventory Unit 2 Instructions for Reporting 2011 Emissions II. REPORTING REQUIREMENTS POLLUTANTS TO BE REPORTED: Your emissions inventory must include your business’s emissions of the following air pollutants: CO NO x PM 10 SO x VOC HAP&NON NH x Pb = = = = = = = = Carbon monoxide Nitrogen oxides Particulate matter less than 10 microns Sulfur oxides Volatile organic compounds * Hazardous Air Pollutant (HAP) that is also NOT a volatile organic compound (VOC)** Ammonia and ammonium compounds Lead * A volatile organic compound (VOC) is defined as any compound of carbon that participates in atmospheric photochemical reactions. This definition excludes: carbon monoxide, carbon dioxide, acetone, carbonic acid, metallic carbides or carbonates, and ammonium carbonate, as well as certain other organic compounds. (See Maricopa County Air Pollution Control Rule 100, Sections 200.69 and 200.110 for a full definition.) EPA has re-designated the chemical t-butyl acetate (CAS Number 540-88-5) as a VOC for record-keeping requirements and emissions reporting, but not for emission limitations or content requirements. County Rule 100, Section 200.69b states: “The following compound(s) are VOC for purposes of all recordkeeping, emissions reporting, photochemical dispersion modeling and inventory requirements which apply to VOC and shall be uniquely identified in emission reports, but are not VOC for purposes of VOC emissions limitations or VOC content requirements: t-butyl acetate (540-88-5).” Therefore, if your facility uses t-butyl acetate, it is necessary to report t-butyl acetate as a separate material on the evaporative process form, not as part of a grouped material (e.g., solvents, thinners, activators, etc.). T-butyl acetate will continue to be identified as a VOC on your emission report and count towards any applicable emission fees. ** HAP&NON: Usage of certain materials that are: (1) a Hazardous Air Pollutant (HAP) and (2) not also a VOC (that is, not also an ozone precursor) should also be reported if: (a) your site is subject to a Federal MACT (Maximum Achievable Control Technology) standard or (b) your air quality permit contains specific quantitative limits for HAP emissions. The most common materials categorized as “HAP&NON” include: • methylene chloride (dichloromethane) • perchloroethylene • 111-trichloroethane (111-TCA or methyl chloroform) • hydrochloric acid • hydrofluoric acid NOTE: HAPs that are also considered volatile organic compounds are reported as VOC. Maricopa County Emissions Inventory Unit 3 Instructions for Reporting 2011 Emissions EMISSION CALCULATION METHOD HIERARCHY: When preparing emission information for your report, the most accurate method for calculating actual emissions must be used. The hierarchy listed below outlines the preferred methods for calculating emission estimates (taken from County Rule 280, Section 305.1). (1) Whenever available, emissions estimates should be calculated from continuous emissions monitors certified under 40 CFR Part 75, Subpart C, or data quality assured pursuant to Appendix F of 40 CFR, Part 60. (2) When sufficient data obtained using the methods described in paragraph 1 is not available, emissions estimates should be calculated from source performance tests conducted pursuant to Rule 270 in Maricopa County’s Air Pollution Control Rules and Regulations. (3) When sufficient data obtained using the methods described in paragraphs 1 or 2 is not available, emissions estimates should be calculated from material balance using engineering knowledge of the process. (4) When sufficient data obtained using the methods described in paragraphs 1 through 3 is not available, emissions estimates shall be calculated using emissions factors from EPA Publication No. AP-42 "Compilation of Air Pollutant Emission Factors," Volume I: Stationary Point and Area Sources. (5) When sufficient data obtained using the methods described in paragraphs 1 through 4 is not available, emissions estimates should be calculated by equivalent methods supported by back-up documentation that will substantiate the chosen method. Maricopa County Emissions Inventory Unit 4 Instructions for Reporting 2011 Emissions III. CONFIDENTIALITY OF DATA SUBMITTED Information submitted in your annual emissions reports must be made available to the public unless it meets certain criteria of Arizona State Statutes and Maricopa County Rules. Applicable excerpts concerning confidentiality of data are reproduced below. ARS § 49-487 D. ...the following information shall be available to the public:… 2. The chemical constituents, concentrations and amounts of any emission of any air contaminant. ... MARICOPA COUNTY AIR POLLUTION CONTROL RULES AND REGULATIONS, Rule 100: § 200.107 TRADE SECRETS - Information to which all of the following apply: a. A person has taken reasonable measures to protect from disclosure and the person intends to continue to take such measures. b. The information is not, and has not been, reasonably obtainable without the person’s consent by other persons, other than governmental bodies, by use of legitimate means, other than discovery based on a showing of special need in a judicial or quasi-judicial proceeding. c. No statute, including ARS §49-487, specifically requires disclosure of the information to the public. d. The person has satisfactorily shown that disclosure of the information is likely to cause substantial harm to the business’s competitive position. § 402 402.2 a. b. CONFIDENTIALITY OF INFORMATION: Any records, reports or information obtained from any person under these rules shall be available to the public ... unless a person: Precisely identifies the information in the permit(s), records, or reports which is considered confidential. Provides sufficient supporting information to allow the Control Officer to evaluate whether such information satisfies the requirements related to trade secrets as defined in Section 200.107 of this rule. For emissions inventory information to be deemed confidential, the following steps must be followed: • Specific data which you request be held confidential must be identified by marking an “X” in the corresponding gray confidentiality box(es) on the relevant report forms. • Provide a written explanation which gives factual information satisfactorily describing why releasing this information could cause substantial harm to the business’s competitive position. • Use the gray-shaded boxes on the reporting forms to indicate which data are to be held confidential. Do NOT stamp “Confidential”, highlight data, or otherwise mark the page. No data can be held confidential without proper justification. Maricopa County Emissions Inventory Unit 5 Instructions for Reporting 2011 Emissions IV. HELPFUL HINTS AND INFORMATION Be sure to verify all preprinted information on forms. If any information is incorrect or blank, please provide correct information. Making a change on the Business Form will NOT transfer the permit ownership or location. You must contact the Department's Small Business Assistance Program at (602) 506-5102 or the Engineering & Permitting Division at (602) 506-6094 to accomplish this. WHAT IS A PROCESS? A process is a business activity at your location that emits one or more of the pollutants listed on page 3, and has only one material type as input and one operating schedule. For each applicable process at your business, you must assign a unique Process ID number to differentiate each process. PROCESSES AND MATERIALS THAT DO NOT HAVE TO BE REPORTED: • Welding. • Acetone usage. • Fuel use for forklifts or other vehicles. (NOTE: Fuel use in non-vehicle engines is reportable.) • Soil remediation activities. (Note: Other periodic reporting requirements may exist; consult your permit.) • Storage emissions from fuels or organic chemicals in any tank with a capacity of 250 gallons or less. • Storage emissions of diesel and Jet A fuel in underground tanks of any size. • Storage emissions of diesel and Jet A fuel in aboveground tanks, with throughput < 4,000,000 gal/yr. • Routine pesticide usage, housekeeping cleaners, and routine maintenance painting at your facility. Please group all similar equipment and materials together before applying the following limitations: • Internal combustion engines (e.g., emergency generators) or external combustion equipment (e.g., boilers and heaters) that operated less than 100 hrs. and burned less than 200 gals. diesel or gas, or less than 100,000 cubic feet of natural gas. • Materials with usage of less than 15 gallons or 100 pounds per year. GROUPING MATERIALS AND/OR EQUIPMENT UNDER ONE PROCESS ID: You can group together under one process ID: • All internal combustion engines less than 600 hp if they burn the same fuel and have similar operating schedules. • All external combustion equipment (boilers, heaters) with a capacity of less than 10,000,000 Btu per hour if they burn the same fuel and have similar operating schedules. • All similar evaporative materials with similar emission factors that have similar operating schedules and process descriptions. For example, group low-VOC red paint, green paint and white paint together as one material: “Paint: Low-VOC.” Do not group dissimilar materials together, such as thinners and paints. Attach documentation (see example, p. 20) showing how the grouped emission factor was determined. • All underground tanks with the same fuel and same type of vapor recovery system. ASSIGNING IDENTIFICATION NUMBERS (IDs): Unique IDs are required for the following report elements: Stacks, Control Devices and Processes. For processes, that means a process ID number may be used only once on each General Process form and for each material reported on the Evaporative Process Forms. These numbers are usually assigned by the person who prepares the original report. If you are adding a new item to a preprinted report, assign a number not already in use. Once an ID number is assigned, continue using the same number for that item each year. If that item is no longer reportable, mark it with ‘DELETE’ and return the preprinted form with a brief explanation. Do not use that ID number again. Maricopa County Emissions Inventory Unit 6 Instructions for Reporting 2011 Emissions INDUSTRY-SPECIFIC INSTRUCTIONS: Additional help sheets, detailed examples, and special instructions are available for a number of specific processes or industries listed below. To get copies of any of these documents, please call (602) 506-6790, or visit our web site at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx • • • • • Bakeries Concrete Batch Plants Fuel Storage and Handling Incinerators and Crematories Lg. Aboveground Storage Tanks • • • • • Natural Gas Boilers/Heaters Polyester Resin Printing Plants Roofing Asphalt Sand and Gravel Plants • • • • Using EPA's TANKS 4.09d Program Vehicle Refinishing Vehicle Travel on Unpaved Roads Woodworking COMMONLY USED CONVERSION FACTORS: 1 gram/liter = 0.00834 lbs/gal 1 foot = 0.0001894 mile 1 liter = 0.2642 gallon (US) 1 square foot = 0.000022957 acre 1 therm = 0.0000952 MMCF 1 pound = 0.0005 ton NOTE: MM = 1,000,000 Example: MMCF = 1,000,000 cubic feet M = 1,000 Example: MGAL = 1,000 gallons ADDITIONAL RESOURCES AND ASSISTANCE: The Maricopa County Emissions Inventory web site at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx contains additional reference materials, such as: • • • • blank copies of most emissions reporting forms. an updated list of emission factors for a large number of industrial processes, including SCC codes. a list of Tier Codes for industrial processes. detailed help sheets for a number of specific industries or processes. To receive any of the above materials by fax or mail, or for additional information or assistance in how to calculate and report your emissions, please call us at (602) 506-6790. Maricopa County Emissions Inventory Unit 7 Instructions for Reporting 2011 Emissions V. INSTRUCTIONS AND EXAMPLES FOR COMPLETING EMISSIONS REPORTING FORMS Business Form Instructions Verify all preprinted information, and make corrections where necessary. When making corrections, strike out the preprinted data and write in corrections beside it. Please make all changes readily noticeable. NOTE: Making a change on the Business Form will NOT transfer the permit ownership or location. You must contact the Department's Small Business Assistance Program at (602) 506-5102 or the Engineering & Permitting Division at (602) 506-6094 to accomplish this. Data fields: 6 Number of employees: This should be the annual average number of full-time equivalent (FTE) employee positions at this business location. 9 NAICS Code: This 5- or 6-digit North American Industrial Classification System (NAICS) code has been introduced to replace the 4-digit Standard Industrial Classification (SIC) codes. Please list the primary and secondary NAICS codes for your business, if known. (Consult our website, at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx, for a link to a full list of NAICS codes.) 10 Preparer of the Inventory (primary contact for technical questions concerning this report): This should be the person who knows the most about the data in the report. If this person has an e-mail address used for business purposes, please provide it. 11 Who should receive the Annual Emissions Inventory Form next year?: This should be a person who is directly employed with the business. This person should not be a consultant for the business. Maricopa County Emissions Inventory Unit 8 Instructions for Reporting 2011 Emissions Stack Form Instructions A “stack” is defined as a stationary stack, pipe, vent or opening through which a significant percentage of emissions (from one or more processes) are released into the atmosphere (with or without a control device). NOTE: Stack information is required only if your business location annually emits over 10 tons of any one individual pollutant. If so, you must complete a Stack Form for: • each stack connected to a control device. • any stack that discharges annually more than 5 tons of combined pollutant emissions (such as a paint booth exhaust). EXAMPLE Stack Form Information: 1 2 Stack ID Stack Type Code* 3 1 W 30 ft 2 V 14 ft 4 5a OR 5b 6a OR 6b & 6c 7 Stack Exit Gas Velocity Flow Rate Diameter Length / Width Height** Temperature feet/sec acfm inside inch inside inch * Stack Type Codes: 90 200 o o F F Stack Name/Description. Include lat/long coordinates of stack (in decimal degrees) 20,000 36 paint booth Lat: N33. 5277 19,186 40 thermal oxidizer, Bldg. 2 Long: W1 1 2. 2626 Lat: N33. 5259 Long: W1 1 2. 261 3 V = Vertical unobstructed D = Downward unobstructed W = Obstructed vertical (e.g. weather cap) H = Horizontal unobstructed G = Gooseneck ** Stack height is calculated relative to the surrounding terrain. For instance, the stack height of a 10-foot stack on top of a 20-foot tall building is 30 feet. Data fields: 1 Stack ID: (See “Assigning Identification Numbers” on page 6.) A number (up to three digits, numeric only) which identifies a specific stack. It is suggested you start with 1, then 2, etc. 4 Exit Gas Temperature: Should represent average operating conditions, in degrees Fahrenheit. DO NOT report “ambient”. 5a Exit Gas Velocity: OR 5b Gas Flow Rate: Provide EITHER the exit velocity (in feet per second) OR the flow rate of gas (in actual cubic feet per minute) exiting the stack during normal operations. Preprinted information provides both. 6a Inside Stack Diameter: For round stacks, provide Inside Stack Diameter in inches. OR 6b & 6c Inside Stack Length and Width: For square or rectangular stacks, provide inside Length and inside Width in inches. 7 Stack Name/Description and Lat/Long Coordinates: Provide a brief text description of the stack along with the latitude and longitude coordinates of the stack (in decimal degrees). Maricopa County Emissions Inventory Unit 9 Instructions for Reporting 2011 Emissions Control Device Form Instructions EXAMPLE Control Device Form Information 1 2 3 4 Control ID Installation/ Reconstruction* Date 5 Size or Rated Capacity** Control Type Code Control Device Name/Description 1 05/09/98 25,000.0 cfm 021 Thermal oxidizer 4 03/10/97 cfm 153 Watering with water trucks 6 Stack ID 2 Data fields: 1 Control ID: (See “Assigning Identification Numbers” on page 6.) A unique number (up to three digits) that you assign to identify a specific control device. 2 Installation/Reconstruction Date: The completion date (given in mm/dd/yy format) of installation or the most recent reconstruction of the identified control device. This is not a date on which routine repair or maintenance was done. “Reconstruction” means any component of the control device was replaced and the cost (fixed capital) of the new component(s) was more than half of what it would have cost to purchase or construct a new control device. 3 Size or Rated Capacity: Report the air or water flow rate in cubic feet per minute. Some devices (e.g., water trucks for dust control) will not include a value in this field. 4 Control Type Code: A 3-digit code designating the type of control device. A complete list of all EPA control device codes can be found on the Web at: http://www.maricopa.gov/aq/divisions/ planning_analysis/emissions inventory/Default.aspx or call (602) 506-6790 for assistance. 6 Stack ID: Not all businesses require a Stack ID. This is required if the Stack Form is used for your site (see page 9) and the control device is vented through that identified stack. This is the ID number shown in column 1 of the Stack Form. The Stack ID can be entered on this form after the Stack Form has been filled out. Maricopa County Emissions Inventory Unit 10 Instructions for Reporting 2011 Emissions General Process Form Instructions The General Process Form is used to record data on all emissions-producing processes except evaporative processes. A “general process” is normally characterized by the burning or handling of a material. One form reports all the pollutants for one process. For example, several pollutants are produced by burning fuel, and PM 10 is emitted by processing rock products, processing materials such as wood or cotton, and driving on unpaved areas. Data fields: (See sample forms on pages 13 and 14.) 1 Process ID: A number (up to three digits) that is preprinted or you assign. (See “Assigning Identification Numbers” on page 6.) This Process ID number can not be used for any other process at this location. 2 Process Type/Description: Brief details on the type of activity that is occurring. 3 Stack ID(s): The stack ID number(s) shown in column 1 of the Stack Form that identify the stack(s) which vent pollution created by this process. Not all businesses are required to report stacks. This is only required if the Stack Form is required for your site (see page 9) and the process has a stack. 4 5 Process Tier Code and SCC Code: 6 Seasonal Throughput Percent: Enter the percent of total annual operating time that occurred per season, rounded to the nearest percent. For example, “Dec-Feb 30% ” means 30% of total annual activity occurred in January, February and December 2011. The total for all four seasons must equal 100%. 7 8 Normal Operating Schedule and Typical Hours of Operation: 9 Emissions Based on: Provide the name of the material used, fuel used, product produced, or whatever was measured for the purpose of calculating emissions, such as “natural gas”, “hours of operation,” “vehicle miles traveled,” or “acres.” If these codes are not preprinted on your form, please consult the section “Other Resources” on our web site, or call (602) 506-6790. These reflect the normal daily, weekly, and annual operating parameters of this process during 2011. 10 Used, Produced or Existing: Indicate whether calculated emissions are based on a material type or fuel used (an input, such as “paint” or “natural gas”), or an output (such as “sawdust produced” or “finished product”). Use “Existing” if the parameter reported on line 9 is not directly used or produced in the process (such as “vehicle miles traveled” or “acres”). 11 Annual Amount: The annual amount (a number) of material that was used, fuel combusted, product produced, hours of operation, vehicle miles traveled, or acres. 12 Fuel Sulfur Content (in percent): For processes that involve the combustion of oil or diesel fuels, report the sulfur content of the fuel as a decimal value. Example: 0.05 % (= 500 ppm) 13 Unit of Measure: Units of the material used, fuel used or product produced shown on line 9. For example: gallons, pounds, tons, therms, acres, vehicle miles traveled, units produced. 14 Unit Conversion Factor: You must provide this if you use an emission factor with an emission factor unit (see item 17 below) that is not the same as the unit of measure (from line 13). This is the standard number you would multiply your amount (line 11) by to convert it to the units of the emission factor. See page 7 for a list of commonly used conversion factors. Maricopa County Emissions Inventory Unit 11 Instructions for Reporting 2011 Emissions General Process Form Instructions (continued) 15 Pollutant: See page 3 for a list of pollutants that need to be reported. 16 Emission Factor (EF): The number to be multiplied by the annual amount (line 11) to determine how much of the pollutant was emitted. If you calculate your own emission factor or change the preprinted emission factor, you must provide details of your calculations in an attachment. 17 Emission Factor (EF) Units: Enter the appropriate Emission Factor Units in pounds (lb) per unit; e.g., lb/ton, lb/MMCF, lb/gal. 18 Controlled Emission Factor (EF)? YES or NO: Indicate “YES” if: 1) you have your own emission factor from testing and included the control device efficiency within the factor, or 2) the emission factor used is clearly identified as a controlled emission factor. A “YES” response requires the use of Formula A (see #25 below). Indicate “NO” if: 1) there is no emission control device, or 2) the emission factor represents emission rates before controls. A “NO” response requires the use of Formula B (see #25 below). 19 Calculation Method: Enter the number code (listed at the bottom of the General Process Form) which best describes the method you used to obtain this emission factor. Code 5, “AP-42/FIRE Method or Emission Factor” means that the factor comes from EPA documents or software. NOTE: If you have continuous emissions monitors (CEM) data or conducted a source test that was required and approved by the County for a specific process or piece of equipment, you must use the emission data from the CEM or the test results. Report “1” in this column for CEM data or “4” for performance test data. 20 through 24: Leave blank if there is no control device. 20 Capture % Efficiency: The percent of the pollutant that is captured and sent to the primary control device in this process. Be sure to list capture efficiency separately for each pollutant affected. 21 Primary Control Device ID: If this pollutant is being controlled in this process, enter the Control Device ID number which represents the first control device affecting the pollutant. 22 Secondary Control Device ID: If this pollutant is being controlled sequentially by 2 devices, enter the Control Device ID number which represents the second control device; otherwise leave this field blank. 23 Control Device(s) % Efficiency: Enter the total control efficiency of the control device(s). Be sure to list control device efficiency separately for each pollutant affected. If you report control device efficiency, you must also show capture efficiency in column 20. 24 Efficiency Reference Code: Enter the code (1 through 6) that best describes how you determined the control device efficiency. A list of possible codes is included at the bottom of the form. 25 Estimated Actual Emissions (in pounds/year): You may round the calculated emissions values to the nearest pound. Calculate as follows: A. Emissions with no controls or controls are reflected in the emission factor: Column 25 = line 11 × line 14 × column 16 B. Emissions after control: Column 25 = line 11 × line 14 × column 16 × (1 – [column 20 × column 23]) Use the decimal equivalent for columns 20 and 23. Example: 96.123% = 0.96123 Maricopa County Emissions Inventory Unit 12 Instructions for Reporting 2011 Emissions General Process Form 2011 Permit number(s) EXAMPLE: Internal Combustion V99999 Place an X in any gray cell to mark data requested to be held confidential. See page 5 for requirements for information to be deemed confidential. 1- Process ID 80 2- Process Type/Description: 3 ENGINES FOR CRUSHING (EACH LESS THAN 600 HP) 3- Stack ID(s) (only if required on Stack Form) ________ 020599 4- Process TIER Code: 5- SCC Code _______ 20200102 IND:DIESEL-RECIPROCATING (8 digit number) 6- Seasonal Throughput Percent: 25 Dec-Feb 7- Normal Operating Schedule: Hours/Day 8- Typical Hours of Operation: (military time) ________ ________ ________ FUEL COMB. INDUSTRIAL: INTERNAL COMBUSTION % 8 Days/Week 0700 Start 25 Mar-May Jun-Aug 25 Hours/Year 2080 % 5  Used (input) 11- Annual Amount: or Produced (output) or Pollutant CO NOx PM-10 SOx VOC Emission Factor (EF) (number) 130 604 42.5 39.7 49.3 Emission Factor Unit (lb per) M M M M M 19 20 Controlled EF? Yes or No Calculation Method Code* Capture % Efficiency N N N N N 5 5 5 5 5 GALS GALS GALS GALS GALS * Calculation Method Codes: 1 = Continuous Emissions Monitoring Measurements 2 = Best Guess / Engineering Judgment 3 = Material Balance 4 = Source Test Measurements (Stack Test) 5 = AP-42 / FIRE Method or Emission Factor Maricopa County Emissions Inventory Unit 52 x __0.05_______% GALLONS 14- Unit Conversion Factor (if needed to convert Unit of Measure to correlate with emission factor units) Emission Factor (EF) Information 16 17 18 % DIESEL 12- Fuel Sulfur Content (in percent) 13- Unit of Measure: (for example: tons, gallons, million cu ft, acres, units produced, etc.) 15 Weeks/Year 25 Existing (e.g. VMT, acres) 16,250 (a number) Sep-Nov 1530 End 9- Emissions based on (name of material or other parameter, e.g. “rock”, “diesel”, “vehicle miles traveled”) 10- % 0.001 Control Device Information 21 22 23 Primary Control Device ID Secondary Control Device ID Control Device(s) % Efficiency 24 25 Efficiency Reference Code** Estimated Actual Emissions 2,113 9,815 691 645 801 6 = State or Local Agency Emission Factor 7 = Manufacturer Specifications 8 = Site-Specific Emission Factor 9 = Vendor Emission Factor 10 = Trade Group Emission Factor 13 lbs lbs lbs lbs lbs ** Control Efficiency Reference Codes: 1 = Tested efficiency / EPA reference method 2 = Tested efficiency / other source test method 3 = Design value from manufacturer 4 = Best guess / engineering estimate 5 = Calculated based on material balance 6 = Estimated, based on a published value Instructions for Reporting 2011 Emissions General Process Form 2011 Permit number(s) EXAMPLE: Unpaved Road Travel V99999 Place an X in any gray cell to mark data requested to be held confidential. See page 5 for requirements for information to be deemed confidential. 1- Process ID 28 2- Process Type/Description: UNPAVED ROAD TRAVEL: HEAVY-DUTY TRUCKS @ 15 MPH _______ 3- Stack ID(s) (only if required on Stack Form) 4- Process TIER Code: 5- SCC Code ________ 140799 30502504 ________ 6- Seasonal Throughput Percent: SAND/GRAVEL: HAULING 25 Dec-Feb % Jun-Aug 25 Hours/Year 2080 % 5 Days/Week 0700 Start 25 Mar-May 8 Hours/Day 8- Typical Hours of Operation: (military time) Used (input) 11- Annual Amount: or Produced (output) or Sep-Nov Weeks/Year 25 % 52 x VEHICLE MILES TRAVELED (VMT)  Existing (e.g. VMT, acres) 7,500 (a number) % 1530 End 9- Emissions based on (name of material or other parameter, e.g. “rock”, “diesel”, “vehicle miles traveled”) 10- ________ MISCELLANEOUS: FUGITIVE DUST (8 digit number) 7- Normal Operating Schedule: ________ 12- Fuel Sulfur Content (in percent) ______________% VMT 13- Unit of Measure: (for example: tons, gallons, million cu ft, acres, units produced, etc.) 14- Unit Conversion Factor (if needed to convert Unit of Measure to correlate with emission factor units) 15 Pollutant PM-10 Emission Factor (EF) Information 16 17 18 Emission Factor (EF) (number) 3.2 Emission Factor Unit (lb per) VMT Control Device Information 21 22 23 19 20 Controlled EF? Yes or No Calculation Method Code* Capture % Efficiency Primary Control Device ID N 6 100 4 Secondary Control Device ID 24 25 Control Device(s) % Efficiency Efficiency Reference Code** Estimated Actual Emissions 90 6 2400 lbs lbs lbs lbs lbs lbs NOTE: Emissions in col. 25 are calculated as follows: * Calculation Method Codes: 1 = Continuous Emissions Monitoring Measurements 2 = Best Guess / Engineering Judgment 3 = Material Balance 4 = Source Test Measurements (Stack Test) 5 = AP-42 / FIRE Method or Emission Factor Maricopa County Emissions Inventory Unit (line 11 × col. 16) × (1 – [col. 20 × col. 23]) 6 = State or Local Agency Emission Factor 7 = Manufacturer Specifications 8 = Site-Specific Emission Factor 9 = Vendor Emission Factor 10 = Trade Group Emission Factor 14 ** Control Efficiency Reference Codes 1 = Tested efficiency / EPA reference method 2 = Tested efficiency / other source test method 3 = Design value from manufacturer 4 = Best guess / engineering estimate 5 = Calculated based on material balance 6 = Estimated, based on a published value Instructions for Reporting 2011 Emissions Evaporative Process Form Instructions The Evaporative Process Form is used to report all emissions produced by evaporation. Examples include: cleaning with solvents, painting and other coatings, printing, using resin, evaporation of fuels from storage tanks, ammonia use, etc. All other processes should be shown on the General Process Form. One Evaporative Process Form may be used to report numerous materials, with each material given a separate process ID number, as long as the information on lines 1–5 apply to all items on that form. Use a separate form for each group of materials that has a different Process Type/Description (shown on line 1), different Tier Code (line 2) or different operating schedule (lines 3, 4, or 5). Data fields: (See sample forms on pages 17 and 18.) 1 Process Type/Description: Brief details of the activity in which the listed materials were used. 2 Process Tier Code: If this 6-digit code is not preprinted on your form, please refer to the Tier Code list at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx or call (602) 506-6790. 3 Seasonal Throughput Percent: Enter the percent of total annual operating time that occurred per season (rounded to the nearest percent). For example, “Dec-Feb 30% ” means 30% of the total annual activity occurred during January, February and December 2011. The total for all four seasons must equal 100%. 4 5 Normal Operating Schedule and Typical Hours of Operation: 6 Process ID: A number (up to three digits) that represents this specific material (process). Each process on one form must have the same tier code and operating schedule as that shown in the top portion of the form. This Process ID number can not be used for any other process at this business location. See page 6 of these instructions for more explanation of ID numbers and for exclusions and guidance on grouping materials. 7 Stack ID(s): The stack ID number(s) shown in column 1 of the Stack Form that identify the stack(s) which vent pollution created by this process. Not all businesses are required to report stacks. This is only required if the Stack Form is required for your site (see page 9) and the process has a stack. 8 Material Type: Provide the name of the material used in this process. Give the chemical name for pure chemicals or a name that reflects its use (paint, ink, etc.), rather than just a brand name or code number. Examples of materials include: paint, thinner, degreasing solvent (plus its common name), ink, fountain solution, ammonia, alcohol, ETO (ethylene oxide), gasoline (in a storage tank). 9 Annual Material Usage/Input: Amount of this material used during the year. In most cases, the amount purchased is suitable. Write in “lbs” or “gal” (pounds or gallons). These represent the usual number of hours, time of day and weeks per year when this process occurred during the calendar year. 10 Pollutant: The only pollutants reported on this form are VOC, HAP&NON and NH X (see definitions on page 3). When one process (or material) has more than one of these pollutants, list each pollutant on a separate line, using the same process ID number. Maricopa County Emissions Inventory Unit 15 Instructions for Reporting 2011 Emissions Evaporative Process Form (continued) 11 Emission Factor (EF): An emission factor is a number used to calculate the pounds of pollutant emitted based on the quantity of material used in a process. Emission factors can be obtained from your supplier (usually provided on a Material Safety Data Sheet or environmental data sheet), and must correspond with the material units reported in column 9. If the material unit is “gal,” then the emission factor must be in pounds of pollutant per gallon. If the material unit is “lb,” then the emission factor must be in pounds of pollutant per pound of material. Verify (and correct, where necessary) all preprinted emission factors, as the composition of materials used may have changed since your last report. A “lb/gal” emission factor is almost always less than 8 and never greater than 14. A “lb/lb” emission factor is never larger than 1.0. 12 Pounds of pollutant sent off-site: Required only if you wish to take credit for reduced emissions because waste of this material is sent off-site for recycling or disposal. Only waste generated during the report year may be claimed. The Off-Site Recycling/Disposal Form must be completed if you wish to claim a credit. The number of pounds reported in column 12 must equal the number of pounds reported on the Off-Site Recycling/Disposal Form(s) for the same Process ID number. 13 and 14: Leave these fields blank if there is no control device present. 13 Capture % Efficiency: The percent of the pollutant from this process that is captured and sent to the control device. 14 Control ID: If this pollutant is being controlled in this process, enter the Control Device ID number from column 1 of the Control Device Form. Control % Efficiency: Enter the percent of this pollutant that is controlled by this control device. Code: Select the Control Efficiency Reference Code from the list at the bottom of the form. 15 Estimated Emissions (lbs/yr): Estimated pounds of the pollutant emitted during the year, after off-site recycling/disposal and controls if applicable. Credit will not be given for off-site recycling/disposal unless it is shown on the Off-Site Recycling/Disposal Form. Round to the nearest pound. If the answer is 0, give a decimal answer to the first significant digit. Column 15 is calculated as follows: Emissions without off-site recycling/disposal or controls: Column 15 = column 9 × column 11 Emissions with off-site recycling/disposal: Column 15 = (column 9 × column 11) – column 12 Emissions with off-site recycling/disposal and controls: Column 15 = ([column 9 × column 11] – column 12) × (1 – [column 13 × column 14]) Use the decimal equivalent for columns 13 and 14. Example: 96.123% = 0.96123 Maricopa County Emissions Inventory Unit 16 Instructions for Reporting 2011 Emissions EXAMPLE: Coating and Painting Evaporative Process Form 2011 Permit number(s) V99999 Place an X in any gray cell to mark data requested to be held confidential. See page 5 for requirements for information to be deemed confidential. 1- Process Type/Description: Coating metal parts 2- Process TIER Code: 080415 3- Seasonal Throughput Percent: 4- Normal Operating Schedule: 5- Typical Hours of Operation SOLVENT USE: SURFACE COATING - MISC METAL PARTS Dec-Feb Hours/Day 25 % 8 Days/Week (military time) 6 7 8 Process ID Stack ID(s) Material Type 800 1 801 1 802 1 803 803 Mar-May Start 9 5 Hours/Year End 0800 Jun-Aug 25 2080 % Sep-Nov 25 % Weeks/Year 52__ 1700 10 11 Emission Factor EF Units (lbs per) 12 13 Pounds of pollutant* sent off site Capture Efficiency % 14 Control ID 15 lb or gal VOC, HAP&NON or NHx 95 gl VOC 4.7 gal % % 447 120 gl VOC 7.1 gal % % 852 940 gl VOC 4.2 gal % % 3,948 1 Paint red 4039-03 Toro-Red Paint 707 gl VOC 7.0 gal % % 4,949 1 Toro-Red Paint 707 gl HAP&NON 0.5 gal % % 354 Lacquer 6455-06 lacq thinner Annual Usage Input % 25 Control Efficiency % Control Efficiency Code** Estimated Emissions (lbs/yr) lb powder paint 20,200 VOC 0.001 lb 20 % % 8730-11 Note: Do NOT change preprinted Process ID numbers. See page 6 of these instructions for information on how to delete materials that are no longer used, or to assign Process ID numbers for new materials. 804 1 * If you have off-site recycling/disposal of any of the materials listed above, you must complete an Off-site Recycling/Disposal Form to receive credit for reduced emissions. NOTE: Emissions in col. 15 are calculated as follows: ** Control Efficiency Reference Codes 1 = Tested efficiency / EPA reference method 4 = Best guess / engineering estimate Maricopa County Emissions Inventory Unit ([col. 9 × col. 11] – col. 12) × (1 – [col. 13 × col. 14]) 2 = Tested efficiency / other source test method 5 = Calculated based on material balance 17 3 = Design value from manufacturer 6 = Estimated, based on a published value. Instructions for Reporting 2011 Emissions EXAMPLE: Cleaning solvent (with recycling) Evaporative Process Form 2011 Permit number(s) V99999 Place an X in any gray cell to mark data requested to be held confidential. See page 5 for requirements for information to be deemed confidential. 1- Process Type/Description: 2- Process TIER Code: CLEANING METAL PARTS 080103 3- Seasonal Throughput Percent: Dec-Feb 4- Normal Operating Schedule: 5- Typical Hours of Operation SOLVENT USE: DEGREASING - COLD CLEANING Hours/Day 25 % 8 Days/Week (military time) 6 7 8 Process ID Stack ID(s) Material Type 3 2 Mar-May Start 9 % 25 Hours/Year 5 End 1300 Jun-Aug 2080 25 % Sep-Nov 25 % Weeks/Year 52__ 1700 10 11 EF Units (lbs per) 12 13 Capture Efficiency % 14 VOC, HAP&NON or NHx SANITIZER 716 lb VOC 1.0 lb 6 GUN CLEANER 180 gl VOC 7.2 gl 569 % % 727 7 XYZ STRIPPER 1300 gl VOC 3.3 gl 1,884 % % 2,406 8 CLEANING SOLVENTS MEGASOLVE 358 gl VOC 6.4 gl 1,006 % % 1,285 2258 gl VOC 6.8 gl 6,741 % % 8,613 % % 95 % Control ID 15 lb or gal 9 Emission Factor Pounds of pollutant* sent off site Annual Usage Input 1 Control Efficiency % 80 % Control Efficiency Code** Estimated Emissions (lbs/yr) 3 172 Note: Do NOT change preprinted Process ID numbers. See page 6 of these instructions for information on how to delete materials that are no longer used, or to assign Process ID numbers for new materials. * If you have off-site recycling/disposal of any of the materials listed above, you must complete an Off-site Recycling/Disposal Form to receive credit for reduced emissions. NOTE: This example shows the case where 2,400 of the original 4,096 gallons of materials #6 through 9 were captured for off-site recycling, and the pollutant content of the waste material was estimated to be 75% of the original. The pounds of pollutant sent off-site shown in column 12 is calculated on the example Off-Site Recycling/Disposal Form on the next page. Maricopa County Emissions Inventory Unit 18 Instructions for Reporting 2011 Emissions EXAMPLE Off-Site Recycling/Disposal Form 2011 Permit number(s) V99999 NOTE: If you need blank copies of this form, call the Emissions Inventory Unit at (602) 506-6790 or consult our web page at http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx Provide one off-site recycling/disposal form for each waste stream at your business location. A waste stream is the waste from one or more processes mixed together to make one waste product before it is taken off site for recycling, disposal or combustion. 01 1) Assign a unique two-digit ID number to identify the waste stream that will be described below. (Start with ID# 01 for first waste stream. Make copies of a blank Off-Site Recycling/Disposal form and use 02 for second, etc.) Check one: 2,400 pounds gallons 2) What was the quantity of this waste stream in 2011? Indicate whether this quantity is reported in pounds or gallons. Keep waste disposal company manifests as proof that this amount of waste was taken off-site. 3) What was the average pollutant content of the waste stream? NOTE: Report in the same units (pounds or gallons) as used in line 2. VOC 4.25 lbs/unit HAP&NON lbs/ unit NHx lbs/ unit NOTE: Waste normally has less pollutant content than the new product. Some of the pollutant evaporates during the use of the product, and there is usually dirt, water or other contaminants in the waste stream. The estimated pollutant content of the waste is usually between 50% and 95% of the new product. This example estimates an average VOC content (on line 3) to be 75% of the original VOC content of 5.67 lbs/gal., to account for evaporation and contaminants. See page 20 to calculate a weighted average. 4) Calculate the total annual pollutant content of the waste in this waste stream. (volume of waste, from Line 2) × (pollutant content, from Line 3) = Total pollutants in waste stream, in lbs/yr. VOC 10,200 lbs/yr HAP&NON lbs/yr NHx lbs/yr 5) List the process ID numbers of the processes contributing to this waste stream. Also estimate the pounds of pollutant that each process contributed to this waste stream. NOTE: In this example, the amount each process material contributed to total pollutants in the waste stream (Line 4) is based on the percentage, by weight, of each material that contributed to the waste stream (e.g., Process ID #6 contributed 5.6%, therefore 5.6% × 10,200 lbs/yr = 569 lbs. See example on page 20). NOTE: Column totals in the table below must equal the total for each pollutant type reported on line 4. The quantities you report below for each pollutant and process must also be reported in column 12 on the Evaporative Process Form. Process ID 6 Contributed about 7 Contributed about 8 Contributed about 9 Contributed about Annual VOC (lbs) 569 1,884 1,006 6,741 Maricopa County Emissions Inventory Unit Annual HAP&NON (lbs) lbs lbs lbs lbs 19 Annual NHx (lbs) lbs lbs lbs lbs lbs lbs lbs lbs Instructions for Reporting 2011 Emissions EXAMPLE: Documentation of Emission Factor Calculations Identify the process ID number(s) and pollutant(s). Show calculations made to obtain the emission factors used for the process(es). Include references to data sources used, including the document name, date published, page numbers, etc. Emission Factor Calculation Process ID Permit number 201 V99999 Emission factors derived from source test performed 12/2/00 by XYZ Engineering Company (copy of summary tables also attached). Outlet (after controls): CO = 0.43 lb/hr × 1 hr/60 min × 1 min/77.9 cu. ft × 1,000,000 cu. ft/MMCF = 92.0 lb/MMCF = 0.09 lb/hr × 1 hr/60 min × 1 min/77.9 cu. ft × 1,000,000 cu. ft/MMCF = 19.3 lb/MMCF NOx Weighted average sample calculation NOTE: The example below shows how the weighted average of the materials going into the waste stream is calculated. A weighted-average emission factor has been calculated by listing usage amounts and emission factors for each material, summing each column, and then dividing the total emissions by the total gallons used. In this example: 23,231 lbs ÷ 4,096 gal = 5.67 lb/gal average VOC content. This emission factor is then used to calculate the average pollutant content in the Offsite Recycling/Disposal Form example. This process can also be used to find the weighted average emission factor for similar materials if you are reporting them together as a single line item on the Evaporative Process form. Refer to the explanation of “grouping” on page 6. Process ID # 6 7 8 9 Material Type gun cleaner xyz stripper cleaning solvent MEGASOLVE Totals: Average VOC content: Maricopa County Emissions Inventory Unit 2011 Usage Units 180 1,300 358 2,258 4,096 gal gal gal gal gal VOC (lbs/unit) 7.2 3.3 6.4 6.8 23,231 lbs. 4,096 gals 20 VOC Emissions (= Usage × VOC content) 1,296 lbs. 4,290 lbs. 2,291 lbs. 15,354 lbs. 23,231 lbs. = Percent contributed to waste stream 5.6 % 18.5 9.9 66.1 100.0 % % % % 5.67 lb/gal Instructions for Reporting 2011 Emissions EXAMPLE (for all sources except Title V sources) Data Certification Form 2011 Permit number 999999 For EACH pollutant listed, total up all emissions recorded on your General Process and Evaporative Process Forms. Enter these numbers in column 1, “Totals from Process Forms.” Report any emissions from accidental releases in column 2. Add the figures in each row across, and enter the result in column 3, “Total Emissions”. NOTE: “Accidental Releases” reported in column 2 should include all excess emissions reported to the Department under Rule 140, Section 500. (1) Totals from Process Forms Summary of 2011 Annual Emissions: (2) + Accidental Releases 2,113 0 0 354 24,220 9,815 645 3,091 CO NH x Lead HAP&NON VOC NO x SO x PM 10 0 0 0 0 0 0 0 0 (3) = TOTAL 2011 Emissions 2,113 0 0 354 24,220 9,815 645 3,091 NOTE: Review specific requirements for data confidentiality on page 5. We cannot hold any data confidential without the required documentation. TO COMPLETE YOUR EMISSIONS INVENTORY REPORT: - Complete the Confidentiality Statement below. Sign and date this form below where indicated. Send the original copy of your completed forms to: Maricopa County Air Quality Dept., Emissions Inventory Unit,1001 North Central Avenue, Suite 125, Phoenix, AZ 85004. Keep a copy of all forms for your records. CONFIDENTIALITY STATEMENT: This annual emissions report contains requests to keep some data confidential. YES NO If you check “YES”, you must submit documentation and meet certain requirements before your data can be deemed confidential. See enclosed instructions for further details. NOTE: The Data Certification form must be signed by a responsible company official. CERTIFICATION STATEMENT: I declare under penalty of perjury that the data (e.g. inputs, emission factors, controls, and annual emissions) presented herein represents the best available information and is true, accurate and complete to the best of my knowledge. ___________________________________________________________________________________________________________ Signature of owner/business officer Date of signature Telephone number ___________________________________________________________________________________________________________ Type or print full name of owner/business officer Type or print full title Maricopa County Emissions Inventory Unit 21 Instructions for Reporting 2011 Emissions How to calculate an emission fee (for Title V sources only): 1. For each pollutant listed on the “Data Certification/Fee Calculation” form, total up all emissions recorded on your General Process and Evaporative Process Forms. Enter these numbers in column 1, “Totals from Process Forms.” NOTE: While most processes that generate PM 10 should be reported on line 5 of the Data Certification/Fee Calculation form, “[f]ugitive emissions of PM 10 from activities other than crushing, belt transfers, screening, or stacking” (County Rule 280, § 305.2d) are NOT subject to annual emission fees. The most common occurrences of these PM 10 -producing activities that are NON-billable are listed below: SCC codes and description of PM 10 -producing processes that are NOT subject to emission fees SCC 30200814 30400737 30500120 30500121 30500134 30500135 30500141 30500143 30500203 30500212 30500213 30500290 30500303 30500608 30500708 30501710 30502007 30502011 30502504 30502507 30502760 30531090 30532007 30704002 31100199 31100299 50100401 50100402 50100403 50100404 50100405 Major Category Subcategory Facility / Process Type Process Description Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Waste Disposal Waste Disposal Waste Disposal Waste Disposal Waste Disposal Feed Manufacture Steel Foundries Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Concrete Asphalt Concrete Asphalt Concrete Asphalt Concrete Brick Manufacture Cement Manufacturing (Dry Process) Cement Manufacturing (Wet Process) Mineral Wool Stone Quarrying - Processing Stone Quarrying - Processing Construction Sand and Gravel Construction Sand and Gravel Industrial Sand and Gravel Coal Mining, Cleaning, Material Handling Stone Quarrying - Processing Bulk Handling and Storage - Wood/Bark Construction: Building Contractors Demolitions/Special Trade Contracts Landfill Dump Landfill Dump Landfill Dump Landfill Dump Landfill Dump Storage Raw Material Silo Storage Bins: Ferric Chloride Storage Bins: Mineral Stabilizer Blown Saturant Storage Blown Coating Storage Granules Storage Mineral Dust Storage Storage Piles Heated Asphalt Storage Tanks Storage Silo Haul Roads: General Storage of Raw Materials Raw Material Piles Raw Material Piles Storage of Oils and Binders Open Storage Hauling Hauling Storage Piles Sand Handling, Transfer, & Storage Haul Roads: General Open Storage Stockpiles Other Not Classified Other Construction/Demolition Unpaved Road Traffic Fugitive Emissions Area Method Trench Method Ramp Method Food and Agriculture Secondary Metal Production Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Pulp and Paper & Wood Pdts. Building Construction Building Construction Solid Waste Disposal Solid Waste Disposal Solid Waste Disposal Solid Waste Disposal Solid Waste Disposal 2. Report any accidental releases in column 2. Add columns 1 and 2 together for each pollutant, and enter the sum in column 3. Sum lines 1 through 5 together, and enter the total on line 6. 3. Divide your facility's total billable emissions (on line 6) by 2000 to convert pounds into tons. Round to the nearest ton. Enter this value on line 7. Multiply this number by $39.83, and enter the result on line 8. This is your 2011 emission fee. Maricopa County Emissions Inventory Unit 22 Instructions for Reporting 2011 Emissions EXAMPLE (for Title V sources only) Data Certification/Fee Calculation Form 2011 Permit number V99999 For EACH pollutant listed, total up all emissions recorded on your General Process and Evaporative Process Forms. Enter these numbers in column 1, “Totals from Process Forms.” Report any emissions from accidental releases in column 2. Add the figures in each row across, and enter the result in column 3, “Total Emissions”. Carefully follow the instructions on lines 6 through 8 to calculate any emission fee owed. NOTE: “Accidental Releases” reported in column 2 should include all excess emissions reported to the Department under Rule 140, Section 500. (1) Totals from Process Forms Summary of 2011 Annual Emissions: 2,113 0 0 2,400 CO NH x Lead PM 10 (non-billable; see page 22) (2) + Accidental Releases (3) = TOTAL 2011 Emissions 0 0 0 0 2,113 0 0 2,400 Emissions fees are based on your emissions of the following pollutants ONLY: 1 2 3 4 5 6 7 8 354 24,220 9,815 645 691 HAP&NON VOC NO x SO x PM 10 (billable; see page 22) 0 0 0 0 0 354 24,220 9,815 645 691 35,725 Add “TOTAL” column from lines 1 through 5 ONLY: Divide the total on line 6 by 2000 (pounds per ton) to get tons, and round the number to the nearest ton. (Drop any decimal of .499 or less. Increase to the next whole number any decimal of .500 or more.) Enter the resulting WHOLE NUMBER here. Multiply line 7 (a WHOLE number) by $ 39.83. This is your 2011 ANNUAL EMISSION FEE. 18 $ lbs. TONS 716.94 NOTE: Review specific requirements for data confidentiality on page 5. We cannot hold any data confidential without the required documentation. TO COMPLETE YOUR EMISSIONS INVENTORY REPORT: - Include a check (made payable to Maricopa County Air Quality Department) for the amount calculated on line 8 above. Complete the Confidentiality Statement below. Sign and date this form below where indicated. Send the Original copy of your completed forms along with any emission fee due to: Maricopa County Air Quality Department, Emissions Inventory Unit,1001 North Central Avenue, Suite 125, Phoenix, AZ 85004. Keep a copy of all forms for your records. CONFIDENTIALITY STATEMENT: This annual emissions report contains requests to keep some data confidential. YES NO If you check “YES”, you must submit documentation and meet certain requirements before your data can be deemed confidential. See enclosed instructions for further details. NOTE: The Data Certification form must be signed by a responsible company official. CERTIFICATION STATEMENT: I declare under penalty of perjury that the data (e.g. inputs, emission factors, controls, and annual emissions) presented herein represents the best available information and is true, accurate and complete to the best of my knowledge. ___________________________________________________________________________________________________________ Signature of owner/business officer Date of signature Telephone number ___________________________________________________________________________________________________________ Type or print full name of owner/business officer Type or print full title Maricopa County Emissions Inventory Unit 23 Instructions for Reporting 2011 Emissions Appendix B. Rule Effectiveness (RE) Studies 1. Introduction Rule effectiveness (RE) studies are designed to assess the success of regulatory rules at controlling their targeted emissions. It is acknowledged that facilities and source categories subject to control techniques and devices mandated by rules do not always achieve 100% compliance with those requirements. Given this reality, the US EPA recommends the use of rule effectiveness studies to improve the quality of emission estimates presented in emission inventories. Once an RE rate has been calculated, its value is applied to relevant sources at an individual process level, thus adjusting (i.e., increasing) emission estimates to reflect a lower degree of control efficiency. The formulas below illustrate how inclusion of rule effectiveness can significantly affect the resulting emission estimates: Emissions before the application of rule effectiveness: Uncontrolled Emissions × [1 – (Control Efficiency)] = Emissions with Control 100 tons × [ 1 – (0.90) ] = 10.0 tons Emissions including the application of rule effectiveness: Uncontrolled Emissions × [1 – (Control Efficiency × RE)] 100 tons × [ 1 – (0.90 × 0.83) ] = Emissions with Control = 25.3 tons In general, the RE rate is applied to all processes where a control device or control technique is in use. There are however some limitations to this blanket rule, as expressed in US EPA’s most recent guidance: …not all emission estimates involving use of a control device or technique need to be adjusted to account for RE…For example, a state or local agency may conclude that a control device that operates in conjunction with a continuous emissions monitor, or is equipped with an automatic shutdown device, may provide a sufficient level of assurance that intended emission reductions will be achieved, and therefore an adjustment for rule effectiveness is not necessary. Another example would be in instances where a direct determination of emissions, such as via a mass balance calculation, can be made. (US EPA, 2005) Another complication in any attempt to apply a blanket RE percentage rate occurs where control device efficiencies are extremely high. Some categories of control devices routinely operate at efficiencies of 99% or greater (e.g., baghouses, thermal oxidizers). For these activities, even small adjustments through the application of RE can cause a dramatic increase in reported emissions. As an example, a process with a control device of 99.9% efficiency may report controlled emissions of 10 tons. If an RE rate of 85% were applied to this process, the adjusted emissions would total 1,508.5 tons (an increase of nearly 15,000%). In these types of instances, the department evaluated the affected processes on a case-by-case basis to determine the appropriateness of applying an RE adjustment. 2011 Ozone Precursor Emission Inventory B–1 February 2014 2. Calculating Rule Effectiveness Rates for Title V Facilities and Non-Title V Facilities The observed compliance rate in some cases, such as multi-source Title V and non-Title V facilities, can be better described as a rate at which inspection staff issue violations. Inspection staff has a range of experience and training which influences their proficiency in issuing appropriate violations. There may be instances when a rule violation goes unnoticed by staff, or conversely a violation may be issued in error. Even when a compliance rate has a high statistical measure of accuracy, it can fail to reflect a number of programmatic measures that affect overall rule effectiveness; measures like the strength of rule language, departmental enforcement and penalty actions, inspector training programs, educational and public outreach efforts, etc. This reality is reflected in earlier US EPA guidance: A percentage effectiveness rating is not enough to describe the compliance effectiveness of a rule for a source category. An SSCD [Stationary Source Compliance Division] study should attempt to link the rating to a regulatory agency’s overall effort. The study should address the factors that affect the percentage effectiveness rating such as the compliance rate of the sources in a category, inspection frequency and thoroughness, the language of the rule (i.e., whether or not it has loopholes), and the reporting and recordkeeping by the regulatory agency. Evaluating these factors will provide a more complete evaluation of the effectiveness of a rule. (US EPA, 1994) In order to incorporate all the salient factors described above, a matrix was created to produce a final RE rate. US EPA’s latest guidance (2005) provides a listing of factors that can impact rule effectiveness rates (e.g., inspector training, frequency of inspections, media outreach, enforcement policies, recordkeeping requirements, etc.), grouped into major categories such as most important factors, important factors and other factors. The department used these suggested factors as the basis for developing the RE matrices contained in Tables B–2 and B–3. In brief, the compliance rate developed from inspection data accounts for 70% of the overall RE rate, while all other factors account for the remaining 30%. Each factor is scored individually, based upon the department’s success in implementing that factor. As an example, the score for the factor “Compliance History” is the compliance rate developed from the study period inspection data, while the score for “Enforcement Penalties” is based upon the department’s timely response to, and settlement of, observed violations associated with the subject rule or source category. The complete matrices for each applicable rule or source category for which rule effectiveness was addressed, are contained in Tables B–2 and B–3. The following sections describe in further detail the data and methods used in the development of the remaining RE factors for Title V and non-Title V permitted facilities; results are summarized in Table B–1 below. Table B–1. Rule effectiveness rate, by source category analyzed. Source Category Compliance Rate Rule Effectiveness (RE) Rate Title V Facilities 90.45% * 91.81% Non-Title V Facilities 85.92% * 87.81% * Compliance rates for both Title V and Non-Title V facilities are based upon 2010-2011 inspection data, and reflect compliance self-monitoring recordkeeping practice, in addition to violation data. 2011 Ozone Precursor Emission Inventory B–2 February 2014 For the remaining emission processes that include a control device or technique that limits ozone formation, separate multi-rule RE rates have been calculated for permitted Title V and non-Title V facilities. Factor-based matrices have been utilized to develop RE rates for Title V and nonTitle V facilities. Compliance rates for these sources are based upon two full years of data (2010 through 2011), as compliance information for these sources tends to be more detailed (as reflected in the matrix). The compliance rate for these facilities also includes data on selfmonitoring recordkeeping practices in addition to inspection data. The combined scores of the monitoring data and inspection data divided by the 70% of the overall RE rate comprise the ‘compliance rate’ section of the RE calculation matrix. The combined compliance rate for Title V facilities is 90.45% and 85.92% for non-Title V facilities, resulting in RE rates of 91.81% and 87.81% for Title V and non-Title V facilities, respectively, as shown in Tables B–2 and B–3 below. 3 References US EPA, 1994. Rule Effectiveness Guidance: Integration of Inventory, Compliance and Assessment Applications. EPA Rep. 452/R-94-001, January 1994. US EPA, 2005. Emissions Inventory Guidance for Implementation of Ozone and Particulate Matter National Ambient Air Quality Standards (NAAQS) and Regional Haze Regulations. EPA Rep. 454/R-05-001, November 2005. 2011 Ozone Precursor Emission Inventory B–3 February 2014 Table B–2. Rule Effectiveness Matrix for Title V Facilities A. Most important factors (2 criteria, each assigned weighting of 35% of total): Factor Range Midpt. value 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% < 70% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Monitoring Compliance History Description Source specific monitoring used for compliance purposes, and monitoring records filed with regulatory agency at least every 4 months. Source specific monitoring used as an indicator of compliance, and monitoring records filed with regulatory agency every 6 to 9 months. Source specific monitoring used as an indicator of compliance, and monitoring records filed with regulatory agency each year. General guidance exists for source specific enhanced monitoring, and monitoring records required but aren’t submitted to regulatory agency. No requirements for any type of monitoring. The facility has been in compliance for the past eight quarters. The facility is believed to have been in compliance for the past eight quarters, although inspection frequency is such that this can’t be positively confirmed. On schedule; the facility is meeting its compliance schedule. In Violation; facility is in violation of emissions and/or procedural requirements. High Priority Violator (HPV): the facility is in significant violation of one or more applicable requirement of the CAA. Weight Value Score assigned to (= weight × MCAQD value) 35% 90% 31.5% 12 of 21 facilities 19.4% 7 of 21 facilities 11.3% 2 of 21 facilities Sum: 1.2% 31.8% 35% Overall Compliance Rate for Title V facilities: 90.45% B. Other important factors (4 criteria, each assigned weighting of 3% of total): Type of Inspection Operation & Maintenance 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% < 70% 75% 35% Inspections involve compliance test methods with a high degree of accuracy, such as stack testing or other types of precise emissions measurement. Inspections involve detailed review of process parameters & inspection of control equipment. Inspections involve review of process and inspection of control equipment. Inspections generally consist of only a records review. Inspections most likely consist of visual inspection (e.g., opacity), or drive by. Control equipment operators follow and sign daily O&M instructions. Control equipment operators follow daily O&M instructions. Control equipment operators follow daily or weekly O&M instructions. O&M requirements exist, but on no specific schedule. No specific O&M requirements. 2011 Ozone Precursor Emission Inventory B–4 3% 97% 2.9% 3% 90% 2.7% February 2014 Factor Unannounced Inspections Range 94% 100% 87% 93% 81% 86% 70% 80% < 70% Midpt. value 97% 90% 84% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Enforcement Penalties Description Routinely conducted. Sometimes done. Done, but infrequently. Rarely done. Never done. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency does not have sufficient authority to impose punitive measures towards violators. Weight 3% Value Score assigned to (= weight × MCAQD value) 97% 2.9% 3% 97% 2.91% 2% 97% 1.94% 2% 97% 1.94% 2% 97% 1.94% C. Other factors (9 criteria, each assigned weighting of 2% of total): Compliance Certifications Inspection Frequency EPA HPV Enforcement 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 70% 86% 80% < 70% 84% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Source subject to Title V or other type of compliance certification. Source subject to Title V or other type of compliance certification. Source not subject to any type of compliance certification. Source not subject to any type of compliance certification. Source not subject to any type of compliance certification. Source(s) are inspected once every 2 years or more frequently. Source(s) are inspected once every 3 years or more frequently. Source(s) are inspected once every 5 years or more frequently. Inspection of source(s) infrequent; > every 5 years. Inspections rarely, if ever, performed. Agency has sufficient resources to implement EPA’s 12/22/98 HPV policy. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy in most instances. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy in most instances. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy more often than not. Resource constraints prohibit agency from implementing EPA’s 12/22/98 HPV policy in most instances. 2011 Ozone Precursor Emission Inventory B–5 February 2014 Factor Operator Training Media Publicity Range Midpt. value 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 0.8 75% < 70% 35% Description Control equipment operators complete a formal training program on use of the equipment, and such program is kept up to date and has been reviewed by the regulatory agency. Control equipment operators complete formal training program, and such program is kept up to date and available for review by the regulatory agency upon request. Control equipment operators complete some amount of formal training. Control equipment operators receive only on the job training. Control equipment operators receive no specific training. 100% 93% 86% 80% < 70% 97% 90% 84% 75% 35% Media publicity of enforcement actions. Media publicity of enforcement actions. Media publicity of enforcement actions. Media publicity of enforcement actions. No media publicity of enforcement actions. 94% 87% 81% 70% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Regulatory Workshops 94% Inspector Training 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Regulatory workshops are available annually, and/or the implementing agency mails regulatory information packages each year. Regulatory workshops are available every 1-2 years, and/or the implementing agency mails regulatory information packages every 1-2 years. Regulatory workshops are available every 2-3 years, and/or the implementing agency mails regulatory information packages once every 2-3 years. Regulatory workshop not routinely available, but implementing agency mails regulatory information packages out about once every 2-3 years. Regulatory workshops not routinely available. Implementing agency mails regulatory information packages infrequently, if ever. Inspectors must undergo 2 weeks of comprehensive basic training, and 1 to 2 weeks of source specific training, and such training is updated each year. Inspectors must undergo 1 to 2 weeks of basic training and 1 week of source specific training and such training is updated every 1-2 years. Inspectors must undergo 1 to 2 weeks of basic training and 3 to 5 days of source specific training, and such training is updated every 1-2 years. Inspectors must undergo 1 to 2 weeks of basic training and 1 to 3 days of source specific training, and such training is updated every 1-2 years. Inspectors must undergo less than 5 days of basic training less than 3 days of source specific training, and such training is updated only every 2 years or less frequently. 2011 Ozone Precursor Emission Inventory B–6 Weight Value Score assigned to (= weight × MCAQD value) 2% 84% 1.68% 2% 97% 1.94% 2% 97% 1.94% 2% 90% 1.80% February 2014 Factor Range 94% Testing Guidelines Follow-up Inspections Midpt. value 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Description Specific guidelines and schedule for testing and test methods exist. Specific guidelines on testing and test methods exist, but no schedule for testing. Specific guidelines on testing and test methods exist, but no schedule for testing. Specific guidelines on testing and test methods, but no schedule for testing. Only general guidance on testing, or no mention of testing requirements. Follow-up inspections always or almost always conducted (90 % of the time or more). Follow-up inspections usually conducted (approximately 75% of the time). Follow-up inspections sometimes conducted (approximately 50% of the time). Follow-up inspections infrequently conducted (approximately 25% of the time). Follow-up inspections rarely or never conducted (10% of the time or less) Overall rule effectiveness score for Title V facilities: 2011 Ozone Precursor Emission Inventory B–7 Weight 2% 2% Value Score assigned to (= weight × MCAQD value) 97% 1.94% 97% 1.94% 91.81% February 2014 Table B–3. Rule Effectiveness Matrix for Non-Title V Facilities A. Most important factors (2 criteria, each assigned weighting of 35% of total): Factor Range Midpt. value 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% < 70% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Monitoring Compliance History Description Source specific monitoring used for compliance purposes, and monitoring records filed with regulatory agency at least every 4 months. Source specific monitoring used as an indicator of compliance, and monitoring records filed with regulatory agency every 6 to 9 months. Source specific monitoring used as an indicator of compliance, and monitoring records filed with regulatory agency each year. General guidance exists for source specific enhanced monitoring, and monitoring records required but aren’t submitted to regulatory agency. No requirements for any type of monitoring. The facility has been in compliance for the past eight quarters. The facility is believed to have been in compliance for the past eight quarters, although inspection frequency is such that this can’t be positively confirmed. On schedule; the facility is meeting its compliance schedule. In Violation; facility is in violation of emissions and/or procedural requirements. High Priority Violator (HPV): the facility is in significant violation of one or more applicable requirement of the CAA. Weight 35% 35% Value Score assigned to (= weight MCAQD × value) 75% 191 of 268 facilities 24.2% 19 of 268 facilities 2.2% 77 of 268 facilities 7.5% 0 of 268 facilities Sum: 0.0% 33.9% Overall Compliance Rate for Non-Title V facilities: B. 26.3% 85.92% Other important factors (4 criteria, each assigned weighting of 3% of total): Type of Inspection Operation & Maintenance 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% < 70% 75% 35% Inspections involve compliance test methods with a high degree of accuracy, such as stack testing or other types of precise emissions measurement. Inspections involve detailed review of process parameters & inspection of control equipment. Inspections involve review of process and inspection of control equipment. Inspections generally consist of only a records review. Inspections most likely consist of visual inspection (e.g., opacity), or drive by. Control equipment operators follow and sign daily O&M instructions. Control equipment operators follow daily O&M instructions. Control equipment operators follow daily or weekly O&M instructions. O&M requirements exist, but on no specific schedule. No specific O&M requirements. 2011 Ozone Precursor Emission Inventory B–8 3% 90% 2.7% 3% 90% 2.7% February 2014 Factor Unannounced Inspections Range 94% 100% 87% 93% 81% 86% 70% 80% < 70% Midpt. value 97% 90% 84% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Enforcement Penalties Description Routinely conducted. Sometimes done. Done, but infrequently. Rarely done. Never done. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency does not have sufficient authority to impose punitive measures towards violators. Weight 3% Value Score assigned to (= weight MCAQD × value) 97% 2.91% 3% 97% 2.91% 2% 75% 1.5% 2% 97% 1.94% 2% 97% 1.94% C. Other factors (9 criteria, each assigned weighting of 2% of total): Compliance Certifications Inspection Frequency EPA HPV Enforcement 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 70% 86% 80% < 70% 84% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Source subject to Title V or other type of compliance certification. Source subject to Title V or other type of compliance certification. Source not subject to any type of compliance certification. Source not subject to any type of compliance certification. Source not subject to any type of compliance certification. Source(s) are inspected once every 2 years or more frequently. Source(s) inspected every 3 years or more frequently. Source(s) inspected every 5 years or more frequently. Inspection of source(s) infrequent; > every 5 years. Inspections rarely, if ever, performed. Agency has sufficient resources to implement EPA’s 12/22/98 HPV policy. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy in most instances. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy in most instances. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy more often than not. Resource constraints prohibit agency from implementing EPA’s 12/22/98 HPV policy in most instances. 2011 Ozone Precursor Emission Inventory B–9 February 2014 Factor Operator Training Media Publicity Midpt. value Range 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 0.8 75% < 70% 35% Description Control equipment operators complete a formal training program on use of the equipment; the program is kept up to date and has been reviewed by the regulatory agency. Control equipment operators complete formal training program, and such program is kept up to date and available for review by the regulatory agency upon request. Control equipment operators complete some amount of formal training. Control equipment operators receive only on the job training. Control equipment operators receive no specific training. 100% 93% 86% 80% < 70% 97% 90% 84% 75% 35% Media publicity of enforcement actions. Media publicity of enforcement actions. Media publicity of enforcement actions. Media publicity of enforcement actions. No media publicity of enforcement actions. 94% 87% 81% 70% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Regulatory Workshops Inspector Training 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Regulatory workshops are available annually, and/or the implementing agency mails regulatory information packages each year. Regulatory workshops are available every 1-2 years, and/or the implementing agency mails regulatory information packages every 1-2 years. Regulatory workshops are available every 2-3 years, and/or the implementing agency mails regulatory information packages once every 2-3 years. Regulatory workshop not routinely available, but implementing agency mails regulatory information packages out about once every 2-3 years. Regulatory workshops not routinely available. The implementing agency mails regulatory information packages infrequently, if ever. Inspectors must undergo 2 weeks of comprehensive basic training, and 1 to 2 weeks of source specific training, and such training is updated each year. Inspectors must undergo 1 to 2 weeks of basic training and 1 week of source specific training and such training is updated every 1-2 years. Inspectors must undergo 1 to 2 weeks of basic training and 3 to 5 days of source specific training, and such training is updated every 1-2 years. Inspectors must undergo 1 to 2 weeks of basic training and 1 to 3 days of source specific training, and such training is updated every 1-2 years. Inspectors must undergo less than 5 days of basic training less than 3 days of source specific training, and such training is updated only every 2 years or less frequently. 2011 Ozone Precursor Emission Inventory B–10 Weight Value assigned to MCAQD Score(= weight × value) 2% 75% 1.50% 2% 97% 1.94% 2% 97% 1.94% 2% 90% 1.80% February 2014 Factor Testing Guidelines Follow-up Inspections Midpt. value Range 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Description Specific guidelines and schedule for testing and test methods exist. Specific guidelines on testing and test methods exist, but no schedule for testing. Specific guidelines on testing and test methods exist, but no schedule for testing. Specific guidelines on testing and test methods, but no schedule for testing. Only general guidance on testing, or no mention of testing requirements. Follow-up inspections always or almost always conducted (90 % of the time or more). Follow-up inspections usually conducted (approximately 75% of the time). Follow-up inspections sometimes conducted (approximately 50% of the time). Follow-up inspections infrequently conducted (approximately 25% of the time). Follow-up inspections rarely or never conducted (10% of the time or less) Overall rule effectiveness score for non-Title V facilities: 2011 Ozone Precursor Emission Inventory B–11 Weight Value assigned to MCAQD Score(= weight × value) 2% 97% 1.94% 2% 97% 1.94% 87.81% February 2014 Appendix C. MOVES2010b Local Input Data and RunSpecs In order to calculate the 2011 annual and ozone season-day onroad source emissions, MOVES2010b was executed using local input data for each month of the year and each geographical area (the eight-hour ozone NAA and Maricopa County). A portion of the MOVES2010b RunSpec Summary, RunSpec, and local input data for Maricopa County are provided in this appendix as an example. 2011 Ozone Precursor Emission Inventory C–1 February 2014 MOVES2010b RunSpec Summary (Maricopa County, December 2011) * Output Database Server Name: [using default] * Scale: Domain/Scale: County Calculation Type: Inventory * Time Spans: Time Aggregation Level: Hour Years: 2011 Months: December Days: Weekend & Weekdays Hours: Start Hour 00:00 - 00:59 | End Hour 23:00 - 23:59 * Geographic Bounds: Region: County Selections: ARIZONA - Maricopa County Domain Input Database: pei_mc_2011_may2011_m2010b_in_v1 * Vehicles/Equipment On Road Vehicle Equipment: Diesel Fuel - Combination Long-haul Truck Diesel Fuel - Combination Short-haul Truck Diesel Fuel - Intercity Bus Diesel Fuel - Light Commercial Truck Diesel Fuel - Motor Home Diesel Fuel - Motorcycle Diesel Fuel - Passenger Car Diesel Fuel - Passenger Truck Diesel Fuel - Refuse Truck Diesel Fuel - School Bus Diesel Fuel - Single Unit Long-haul Truck Diesel Fuel - Single Unit Short-haul Truck Diesel Fuel - Transit Bus Gasoline - Combination Long-haul Truck Gasoline - Combination Short-haul Truck Gasoline - Intercity Bus Gasoline - Light Commercial Truck Gasoline - Motor Home Gasoline - Motorcycle Gasoline - Passenger Car Gasoline - Passenger Truck Gasoline - Refuse Truck Gasoline - School Bus Gasoline - Single Unit Long-haul Truck Gasoline - Single Unit Short-haul Truck Gasoline - Transit Bus Compressed natural Gas (CNG) - Combination Long-haul Truck Compressed natural Gas (CNG) - Combination Short-haul Truck Compressed natural Gas (CNG) - Intercity Bus Compressed natural Gas (CNG) - Light Commercial Truck Compressed natural Gas (CNG) - Motor Home Compressed natural Gas (CNG) - Motorcycle Compressed natural Gas (CNG) - Passenger Car Compressed natural Gas (CNG) - Passenger Truck Compressed natural Gas (CNG) - Refuse Truck Compressed natural Gas (CNG) - School Bus Compressed natural Gas (CNG) - Single Unit Long-haul Truck Compressed natural Gas (CNG) - Single Unit Short-haul Truck Compressed natural Gas (CNG) - Transit Bus * Road Type Off-Network Rural Restricted Access Rural Unrestricted Access Urban Restricted Access Urban Unrestricted Access * Pollutants and Processes 2011 Ozone Precursor Emission Inventory Total Gaseous Hydrocarbons - Running Exhaust Total Gaseous Hydrocarbons - Start Exhaust Total Gaseous Hydrocarbons - Evap Permeation Total Gaseous Hydrocarbons - Evap Fuel Vapor Venting Total Gaseous Hydrocarbons - Evap Fuel Leaks Total Gaseous Hydrocarbons - Crankcase Running Exhaust Total Gaseous Hydrocarbons - Crankcase Start Exhaust Total Gaseous Hydrocarbons - Crankcase Extended Idle Exhaust Total Gaseous Hydrocarbons - Refueling Displacement Vapor Loss Total Gaseous Hydrocarbons - Refueling Spillage Loss Total Gaseous Hydrocarbons - Extended Idle Exhaust Carbon Monoxide (CO) - Running Exhaust Carbon Monoxide (CO) - Start Exhaust Carbon Monoxide (CO) - Crankcase Running Exhaust Carbon Monoxide (CO) - Crankcase Start Exhaust Carbon Monoxide (CO) - Crankcase Extended Idle Exhaust Carbon Monoxide (CO) - Extended Idle Exhaust Oxides of Nitrogen (NOx) - Running Exhaust Oxides of Nitrogen (NOx) - Start Exhaust Oxides of Nitrogen (NOx) - Crankcase Running Exhaust Oxides of Nitrogen (NOx) - Crankcase Start Exhaust Oxides of Nitrogen (NOx) - Crankcase Extended Idle Exhaust Oxides of Nitrogen (NOx) - Extended Idle Exhaust Methane (CH4) - Running Exhaust Methane (CH4) - Start Exhaust Methane (CH4) - Crankcase Running Exhaust Methane (CH4) - Crankcase Start Exhaust Methane (CH4) - Crankcase Extended Idle Exhaust Methane (CH4) - Refueling Displacement Vapor Loss Methane (CH4) - Refueling Spillage Loss Methane (CH4) - Extended Idle Exhaust Non-Methane Hydrocarbons - Running Exhaust Non-Methane Hydrocarbons - Start Exhaust Non-Methane Hydrocarbons - Evap Permeation Non-Methane Hydrocarbons - Evap Fuel Vapor Venting Non-Methane Hydrocarbons - Evap Fuel Leaks Non-Methane Hydrocarbons - Crankcase Running Exhaust Non-Methane Hydrocarbons - Crankcase Start Exhaust Non-Methane Hydrocarbons - Crankcase Extended Idle Exhaust Non-Methane Hydrocarbons - Refueling Displacement Vapor Loss Non-Methane Hydrocarbons - Refueling Spillage Loss Non-Methane Hydrocarbons - Extended Idle Exhaust Non-Methane Organic Gases - Running Exhaust Non-Methane Organic Gases - Start Exhaust Non-Methane Organic Gases - Evap Permeation Non-Methane Organic Gases - Evap Fuel Vapor Venting Non-Methane Organic Gases - Evap Fuel Leaks Non-Methane Organic Gases - Crankcase Running Exhaust Non-Methane Organic Gases - Crankcase Start Exhaust Non-Methane Organic Gases - Crankcase Extended Idle Exhaust Non-Methane Organic Gases - Refueling Displacement Vapor Loss Non-Methane Organic Gases - Refueling Spillage Loss Non-Methane Organic Gases - Extended Idle Exhaust Total Organic Gases - Running Exhaust Total Organic Gases - Start Exhaust Total Organic Gases - Evap Permeation Total Organic Gases - Evap Fuel Vapor Venting Total Organic Gases - Evap Fuel Leaks Total Organic Gases - Crankcase Running Exhaust Total Organic Gases - Crankcase Start Exhaust Total Organic Gases - Crankcase Extended Idle Exhaust Total Organic Gases - Refueling Displacement Vapor Loss Total Organic Gases - Refueling Spillage Loss Total Organic Gases - Extended Idle Exhaust Volatile Organic Compounds - Running Exhaust Volatile Organic Compounds - Start Exhaust Volatile Organic Compounds - Evap Permeation Volatile Organic Compounds - Evap Fuel Vapor Venting Volatile Organic Compounds - Evap Fuel Leaks Volatile Organic Compounds - Crankcase Running Exhaust C–2 February 2014 Volatile Organic Compounds - Crankcase Start Exhaust Volatile Organic Compounds - Crankcase Extended Idle Exhaust Volatile Organic Compounds - Refueling Displacement Vapor Loss Volatile Organic Compounds - Refueling Spillage Loss Volatile Organic Compounds - Extended Idle Exhaust * Manage Input Data Sets Selections: / StageII_Input / Stage II Refueling Input * Output General Output: 2011 Ozone Precursor Emission Inventory Output Database: pei_mc_2011_may2011_m2010b_out_v1 Units: Mass Units (Grams) | Energy Units (Joules) | Distance Units (Miles) Activity: Distance Traveled | Source Hours | Source Hours Idling | Source Hours Operating | Source Hours Parked | Population | Starts Output Emissions Detail: Always: Time (Month) | Location (NATION) | Pollutant For All Vehicle/Equipment Categories: Fuel Type | Emission Process On Road: SCC C–3 February 2014 MOVES2010b RunSpec (Maricopa County, December 2011) 2011 Ozone Precursor Emission Inventory C–5 February 2014 2011 Ozone Precursor Emission Inventory C–6 February 2014 2011 Ozone Precursor Emission Inventory C–7 February 2014 MOVES2010b Local Input Data (Maricopa County, December 2011) [FuelFormulation] Fuel Fuel Formulatio Subtyp n e 11100 12 11101 12 11102 13 11103 12 11104 14 11105 12 11106 11 11107 14 11108 11 11109 14 11110 13 11111 13 11112 12 21100 12 21101 12 21102 13 21103 12 21104 14 21105 12 21106 11 21107 14 21108 11 21109 14 21110 13 21111 13 21112 12 31000 20 31001 20 31002 20 31003 20 31004 20 31005 20 31006 20 31007 20 31008 20 31009 20 31010 20 31011 20 31012 20 30 30 RVP 8.02 8.81 8.79 10.7 6.94 8.02 6.54 6.80 6.64 6.69 8.16 8.49 8.53 8.02 8.81 8.79 10.7 6.94 8.02 6.54 6.80 6.64 6.69 8.16 8.49 8.53 0 0 0 0 0 0 0 0 0 0 0 0 0 0 MTBE Sulfur ETOH Volum Level Volume e 20.2 10. 0 15.4 10. 0 14.7 10. 0 15.0 10. 0 24.6 10. 0 26.0 10. 0 22.0 10. 0 23.3 10. 0 27.2 10. 0 24.5 10. 0 19.3 10. 0 18.7 10. 0 16.3 10. 0 20.2 0.0 0 15.4 0.0 0 14.7 0.0 0 15.0 0.0 0 24.6 0.0 0 26.0 0.0 0 22.0 0.0 0 23.3 0.0 0 27.2 0.0 0 24.5 0.0 0 19.3 0.0 0 18.7 0.0 0 16.3 0.0 0 5.71 0 0 5.25 0 0 5.58 0 0 5.88 0 0 5.00 0 0 5.00 0 0 5.00 0 0 5.00 0 0 5.00 0 0 5.00 0 0 5.88 0 0 7.10 0 0 5.60 0 0 0 0 0 ETBE Volume 0.00194 0 0 0 0.00428 0 0 0 0.02142 0 0 0 0 0.00194 0 0 0 0.00428 0 0 0 0.02142 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 TAME Volume 0.05179 0 0 0 0.11395 0 0 0.36666 0.08571 0.11739 0 0 0 0.05179 0 0 0 0.11395 0 0 0.36666 0.08571 0.11739 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Aromati Olefin Benzen c Conten e Content t Content 19.6 9.2 1.2 17.5 6.5 0.9 20.1 9.1 0.9 31.9 14. 1.9 19.6 9.9 0.9 19.9 6.8 0.8 17.6 10. 0.7 21.4 10. 1.2 19.9 11. 0.8 19.2 10. 0.7 17.0 8.5 0.9 15.2 6.4 0.8 16.0 6.4 3.7 19.6 9.2 1.2 17.5 6.5 0.9 20.1 9.1 0.9 31.9 14. 1.9 19.6 9.9 0.9 19.9 6.8 0.8 17.6 10. 0.7 21.4 10. 1.2 19.9 11. 0.8 19.2 10. 0.7 17.0 8.5 0.9 15.2 6.4 0.8 16.0 6.4 3.7 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 e20 0 47.9 53.3 54.6 54.0 42.7 46.0 45.0 44.3 39.0 39.3 47.8 51.5 51.6 47.9 53.3 54.6 54.0 42.7 46.0 45.0 44.3 39.0 39.3 47.8 51.5 51.6 0 0 0 0 0 0 0 0 0 0 0 0 0 0 e30 volToWt 0 PercentOxy 88.0 2.1717 90.7 3.7575 89.4 3.1457 86.0 3.5900 86.7 0.7805 90.0 3.7400 85.5 0.0000 86.0 0.1000 86.3 0.0171 85.8 0.0454 88.3 2.6418 90.1 3.2706 90.3 3.5806 88.0 2.1717 90.7 3.7575 89.4 3.1457 86.0 3.5900 86.7 0.7805 90.0 3.7400 85.5 0.0000 86.0 0.1000 86.3 0.0171 85.8 0.0454 88.3 2.6418 90.1 3.2706 90.3 3.5806 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 BioDiese PAH Cetane Conten l Index Ester t 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 T50 197.721 185.333 177.636 170 212.908 210 209 212 217 216.543 195.941 191.117 190.363 197.721 185.333 177.636 170 212.908 210 209 212 217 216.543 195.941 191.117 190.363 0 0 0 0 0 0 0 0 0 0 0 0 0 0 T90 309.431 295.25 302.727 317 315.856 297 320 322 319 321.282 310.647 300.294 298.545 309.431 295.25 302.727 317 315.856 297 320 322 319 321.282 310.647 300.294 298.545 0 0 0 0 0 0 0 0 0 0 0 0 0 0 [HPMSvTypeYear] HPMSVtypeID 10 20 30 40 50 60 yearID 2011 2011 2011 2011 2011 2011 VMTGrowthFactor 0 0 0 0 0 0 HPMSBaseYearVMT 623037600.1 15806675171 12967244959 118381498.4 1281267928 1646318085 baseYearOffNetVMT 0 0 0 0 0 0 [SourceTypeYear] yearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 sourceTypeID 11 21 31 32 41 42 43 51 52 53 54 61 62 sourceTypePopulation 75309 2044983 440595.7 172099 1172.42 718.58 7592.578 585.7895 21663.06 1344.71 3344.705 9859.552 8092.895 2011 Ozone Precursor Emission Inventory C–8 February 2014 [FuelSupply] countyID 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 fuelYearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 [ZoneMonthHour] monthGroupID 1 1 1 1 2 2 2 2 3 3 3 3 4 4 4 4 5 5 5 5 6 6 6 6 7 7 7 7 8 8 8 8 9 9 9 9 10 10 10 10 11 11 11 11 12 12 12 12 fuelFormulationID 21101 11101 31001 30 21102 11102 31002 30 21103 11103 31003 30 21104 11104 31004 30 21105 11105 31005 30 21106 11106 31006 30 21107 11107 31007 30 21108 11108 31008 30 21109 11109 31009 30 21110 11110 31010 30 21111 11111 31011 30 21112 11112 31012 30 2011 Ozone Precursor Emission Inventory marketShare 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 0.05 0.95 1 1 marketShareCV 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 C–9 monthID 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 12 zoneID 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 40130 HourID temperature relHumidity 1 48 62 2 47 65 3 47 64 4 47 64 5 46 66 6 46 66 7 45 68 8 46 67 9 48 62 10 52 54 11 55 48 12 57 43 13 59 40 14 60 38 15 61 36 16 62 35 17 61 37 18 58 42 19 56 47 20 54 51 21 53 52 22 52 56 23 50 59 24 49 60 1 48 62 February 2014 [SourceTypeAgeDistribution] Source TypeID 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 11 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 31 YearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 AgeID 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 AgeFraction 0.029892 0.036417 0.083781 0.101569 0.116094 0.105884 0.08115 0.058941 0.067783 0.054942 0.046522 0.038838 0.031681 0.023471 0.018524 0.017472 0.014525 0.011157 0.010525 0.007262 0.005157 0.005263 0.005052 0.004631 0.004245 0.003891 0.003567 0.00327 0.002997 0.002748 0.002748 0.043696 0.053295 0.042596 0.068793 0.083192 0.080592 0.077392 0.070493 0.065393 0.061294 0.056294 0.051995 0.043696 0.034097 0.029997 0.022198 0.021098 0.015798 0.012199 0.009499 0.008099 0.006399 0.005299 0.004 0.003019 0.002278 0.001719 0.001298 0.000979 0.000739 0.022565 0.040367 0.036952 0.023272 0.060977 0.080902 0.086168 0.070426 0.071799 0.060662 0.054761 0.061661 0.055069 0.041776 0.034756 0.036143 0.02573 0.02484 0.022254 0.014775 0.010328 0.008996 0.007982 0.008785 Source TypeID 31 31 31 31 31 31 31 31 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 32 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 41 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 2011 Ozone Precursor Emission Inventory YearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 AgeID 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 AgeFraction 0.006661 0.005076 0.003888 0.003002 0.002329 0.001818 0.001418 0.036429 0.043709 0.037275 0.024506 0.063116 0.086828 0.091952 0.071425 0.069687 0.057689 0.051358 0.058053 0.055657 0.041337 0.03425 0.036441 0.02487 0.023712 0.02089 0.013959 0.009727 0.008543 0.007639 0.00826 0.006259 0.004777 0.00368 0.002847 0.002226 0.001755 0.001411 0.036162 0.038296 0.015698 0.027397 0.064494 0.149585 0.139386 0.09579 0.060294 0.043396 0.034397 0.044396 0.055294 0.052495 0.028097 0.027297 0.025797 0.024298 0.014999 0.009599 0.007199 0.006299 0.009299 0.006299 0.0048 0.003657 0.002786 0.002123 0.001617 0.001232 0.000939 0.002744 0.038296 0.015698 0.027397 0.064494 0.149585 0.139386 0.09579 0.060294 0.043396 0.034397 0.044396 0.055294 0.052495 0.028097 0.027297 C–10 Source TypeID 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 43 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 51 52 52 52 52 52 52 52 YearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 AgeID 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 AgeFraction 0.025797 0.024298 0.014999 0.009599 0.007199 0.006299 0.009299 0.006299 0.0048 0.003657 0.002786 0.002123 0.001617 0.001232 0.000939 0.002744 0.075389 0.040094 0.037195 0.085088 0.147379 0.151778 0.083488 0.051493 0.030696 0.020197 0.024996 0.063691 0.038794 0.030796 0.041094 0.017397 0.013008 0.00801 0.005722 0.003933 0.004121 0.004475 0.003412 0.002644 0.002026 0.001526 0.001172 0.000893 0.000686 0.000527 0.008281 0.075401 0.0401 0.0372 0.085101 0.147402 0.151802 0.083501 0.051501 0.0307 0.0202 0.025 0.063701 0.0388 0.0308 0.0411 0.0174 0.013199 0.008099 0.0059 0.003999 0.004199 0.004499 0.003399 0.002599 0.001988 0.00152 0.001162 0.000889 0.00068 0.00052 0.007638 0.066214 0.039334 0.03318 0.078132 0.128378 0.132775 0.079084 February 2014 Source TypeID 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 52 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 53 YearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 AgeID 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 AgeFraction 0.056074 0.038042 0.02878 0.034102 0.060507 0.038954 0.031317 0.039113 0.019306 0.016191 0.011791 0.008363 0.005691 0.005513 0.005414 0.004802 0.003655 0.00283 0.002259 0.00176 0.001429 0.001176 0.001073 0.02476 0.074869 0.040084 0.036613 0.08406 0.144792 0.148968 0.082261 0.050975 0.030557 0.02016 0.024955 0.062595 0.038177 0.030303 0.040308 0.017217 0.013996 0.008668 0.006817 0.004401 0.004658 0.004706 0.003492 0.002575 0.002017 0.001726 0.001332 Source TypeID 53 53 53 53 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 54 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 2011 Ozone Precursor Emission Inventory YearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 AgeID 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 AgeFraction 0.001106 0.000916 0.000861 0.015836 0.075419 0.04011 0.037209 0.085122 0.147438 0.151839 0.083521 0.051513 0.030708 0.020205 0.025006 0.063716 0.03881 0.030808 0.04111 0.017404 0.012531 0.007698 0.005268 0.003727 0.003917 0.004384 0.003365 0.002681 0.002082 0.001515 0.00117 0.000884 0.000678 0.000526 0.009633 0.075521 0.040164 0.03726 0.085237 0.147637 0.152044 0.083634 0.051583 0.030749 0.020232 0.02504 0.063802 0.038862 0.030849 0.041166 0.017428 C–11 Source TypeID 61 61 61 61 61 61 61 61 61 61 61 61 61 61 61 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 62 YearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 AgeID 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 AgeFraction 0.013144 0.00788 0.005826 0.003897 0.004157 0.004432 0.003239 0.002455 0.001916 0.001465 0.001114 0.000846 0.00063 0.000485 0.007306 0.075452 0.040127 0.037225 0.085158 0.147501 0.151904 0.083557 0.051535 0.030721 0.020214 0.025017 0.063744 0.038827 0.030821 0.041128 0.017412 0.013178 0.008015 0.005871 0.003959 0.00418 0.00447 0.003336 0.00254 0.001955 0.001495 0.001141 0.00087 0.000659 0.000505 0.007485 February 2014 [IMCoverage] polProcess ID 101 101 101 101 101 101 101 101 101 101 102 102 102 102 102 102 102 102 102 102 112 112 112 112 112 112 112 113 113 113 113 113 113 113 201 201 201 201 201 201 201 201 201 201 202 202 202 202 202 202 202 202 202 202 301 301 301 301 301 301 301 301 301 301 302 302 302 302 302 302 302 302 302 302 101 101 101 101 101 101 101 101 101 101 102 102 102 102 102 102 102 State ID 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 County ID 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 yearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 sourceTypeID 21 21 21 31 31 31 32 32 32 52 21 21 21 31 31 31 32 32 32 52 21 21 31 31 32 32 52 21 21 31 31 32 32 52 21 21 21 31 31 31 32 32 32 52 21 21 21 31 31 31 32 32 32 52 21 21 21 31 31 31 32 32 32 52 21 21 21 31 31 31 32 32 32 52 21 21 21 31 31 31 32 32 32 52 21 21 21 31 31 31 32 fuelTypeID 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2011 Ozone Precursor Emission Inventory IMProgramID 3 6 10 3 6 10 3 6 10 3 3 6 10 3 6 10 3 6 10 3 8 9 8 9 8 9 7 8 9 8 9 8 9 7 3 6 10 3 6 10 3 6 10 3 3 6 10 3 6 10 3 6 10 3 3 6 10 3 6 10 3 6 10 3 3 6 10 3 6 10 3 6 10 3 103 106 110 103 106 110 103 106 110 103 103 106 110 103 106 110 103 Beg ModelYearID 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1996 1981 1996 1981 1996 1981 1967 1996 1981 1996 1981 1996 1981 1967 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1967 1981 1996 1967 1981 1996 1967 C–12 End ModelYearID 1980 1995 2005 1980 1995 2005 1980 1995 2005 2005 1980 1995 2005 1980 1995 2005 1980 1995 2005 2005 2005 1995 2005 1995 2005 1995 2005 2005 1995 2005 1995 2005 1995 2005 1980 1995 2005 1980 1995 2005 1980 1995 2005 2005 1980 1995 2005 1980 1995 2005 1980 1995 2005 2005 1980 1995 2005 1980 1995 2005 1980 1995 2005 2005 1980 1995 2005 1980 1995 2005 1980 1995 2005 2005 1980 1995 2007 1980 1995 2007 1980 1995 2007 2007 1980 1995 2007 1980 1995 2007 1980 inspectFreq 1 2 2 1 2 2 1 2 2 1 1 2 2 1 2 2 1 2 2 1 2 1 2 1 2 1 1 2 1 2 1 2 1 1 1 2 2 1 2 2 1 2 2 1 1 2 2 1 2 2 1 2 2 1 1 2 2 1 2 2 1 2 2 1 1 2 2 1 2 2 1 2 2 1 1 2 2 1 2 2 1 2 2 1 1 2 2 1 2 2 1 Test StandardsID useIMyn 13 N 33 N 51 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 43 N 44 N 43 N 44 N 43 N 44 N 41 N 43 N 44 N 43 N 44 N 43 N 44 N 41 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 33 N 51 N 13 N 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y Compliance Factor 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 95.8845 57.6164 64.12 90.0428 57.6164 64.12 90.0428 57.6164 64.12 90.0428 87.2032 57.6164 64.12 90.0428 57.6164 64.12 90.0428 57.6164 February 2014 polProcess ID 102 102 102 112 112 112 112 112 112 112 113 113 113 113 113 113 113 201 201 201 201 201 201 201 201 201 201 202 202 202 202 202 202 202 202 202 202 301 301 301 301 301 301 301 301 301 301 302 302 302 302 302 302 302 302 302 302 State ID 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 County ID 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 yearID 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 2011 sourceTypeID 32 32 52 21 21 31 31 32 32 52 21 21 31 31 32 32 52 21 21 21 31 31 31 32 32 32 52 21 21 21 31 31 31 32 32 32 52 21 21 21 31 31 31 32 32 32 52 21 21 21 31 31 31 32 32 32 52 fuelTypeID 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2011 Ozone Precursor Emission Inventory IMProgramID 106 110 103 108 109 108 109 108 109 107 108 109 108 109 108 109 107 103 106 110 103 106 110 103 106 110 103 103 106 110 103 106 110 103 106 110 103 103 106 110 103 106 110 103 106 110 103 103 106 110 103 106 110 103 106 110 103 Beg ModelYearID 1981 1996 1967 1996 1981 1996 1981 1996 1981 1981 1996 1981 1996 1981 1996 1981 1981 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 1967 1981 1996 1967 1981 1996 1967 1981 1996 1967 C–13 End ModelYearID 1995 2007 2007 2007 1995 2007 1995 2007 1995 2007 2007 1995 2007 1995 2007 1995 2007 1980 1995 2007 1980 1995 2007 1980 1995 2007 2007 1980 1995 2007 1980 1995 2007 1980 1995 2007 2007 1980 1995 2007 1980 1995 2007 1980 1995 2007 2007 1980 1995 2007 1980 1995 2007 1980 1995 2007 2007 inspectFreq 2 2 1 2 2 2 2 2 2 1 2 2 2 2 2 2 1 1 2 2 1 2 2 1 2 2 1 1 2 2 1 2 2 1 2 2 1 1 2 2 1 2 2 1 2 2 1 1 2 2 1 2 2 1 2 2 1 Test StandardsID useIMyn 31 Y 51 Y 13 Y 43 Y 44 Y 43 Y 44 Y 43 Y 44 Y 41 Y 43 Y 44 Y 43 Y 44 Y 43 Y 44 Y 41 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y 31 Y 51 Y 13 Y Compliance Factor 64.12 90.0428 87.2032 83.814 64.12 83.814 64.12 83.814 64.12 86.2872 83.814 64.12 83.814 64.12 83.814 64.12 86.2872 57.6164 64.12 90.0428 57.6164 64.12 90.0428 57.6164 64.12 90.0428 87.2032 57.6164 64.12 90.0428 57.6164 64.12 90.0428 57.6164 64.12 90.0428 87.2032 57.6164 64.12 90.0428 57.6164 64.12 90.0428 57.6164 64.12 90.0428 87.2032 57.6164 64.12 90.0428 57.6164 64.12 90.0428 57.6164 64.12 90.0428 87.2032 February 2014 [RoadType] roadTypeID 2 4 rampFraction 0.054636 0.111569 [RoadTypeDistribution] sourceTypeID 11 11 11 11 11 21 21 21 21 21 31 31 31 31 31 32 32 32 32 32 41 41 41 41 41 42 42 42 42 42 43 43 43 43 43 51 51 51 51 51 52 52 52 52 52 53 53 53 53 53 54 54 54 54 54 61 61 61 61 61 62 62 62 62 62 roadTypeID 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 1 2 3 4 5 roadTypeVMTFraction 0 0.013318 0.05643 0.290786 0.639467 0 0.021036 0.039609 0.296909 0.642446 0 0.050257 0.044142 0.371289 0.534312 0 0.050257 0.044142 0.371289 0.534312 0 0.030808 0.032603 0.500175 0.436415 0 0.030808 0.032603 0.500175 0.436415 0 0.030808 0.032603 0.500175 0.436415 0 0.043408 0.027296 0.52444 0.404856 0 0.043408 0.027296 0.52444 0.404856 0 0.043408 0.027296 0.52444 0.404856 0 0.043408 0.027296 0.52444 0.404856 0 0.081128 0.02854 0.528464 0.361868 0 0.081128 0.02854 0.528464 0.361868 2011 Ozone Precursor Emission Inventory C–14 February 2014 [MonthVMTFraction] sourceTypeID 11 21 31 32 41 42 43 51 52 53 54 61 62 isLeapYear N N N N N N N N N N N N N monthID 12 12 12 12 12 12 12 12 12 12 12 12 12 monthVMTFraction 0.083229 0.083229 0.083229 0.083229 0.083229 0.083229 0.083229 0.083229 0.083229 0.083229 0.083229 0.083229 0.083229 [DayVMTFraction] Source Month Road Day TypeID ID TypeID dayID VMTFraction 11 12 1 5 0.767488 21 12 1 5 0.767488 31 12 1 5 0.767488 32 12 1 5 0.767488 41 12 1 5 0.767488 42 12 1 5 0.767488 43 12 1 5 0.767488 51 12 1 5 0.767488 52 12 1 5 0.767488 53 12 1 5 0.767488 54 12 1 5 0.767488 61 12 1 5 0.767488 62 12 1 5 0.767488 11 12 2 5 0.768458 21 12 2 5 0.768458 31 12 2 5 0.768458 32 12 2 5 0.768458 41 12 2 5 0.768458 42 12 2 5 0.768458 43 12 2 5 0.768458 51 12 2 5 0.768458 52 12 2 5 0.768458 53 12 2 5 0.768458 54 12 2 5 0.768458 61 12 2 5 0.768458 62 12 2 5 0.768458 11 12 3 5 0.766507 21 12 3 5 0.766507 31 12 3 5 0.766507 32 12 3 5 0.766507 41 12 3 5 0.766507 42 12 3 5 0.766507 43 12 3 5 0.766507 51 12 3 5 0.766507 52 12 3 5 0.766507 53 12 3 5 0.766507 54 12 3 5 0.766507 61 12 3 5 0.766507 62 12 3 5 0.766507 11 12 4 5 0.768458 21 12 4 5 0.768458 31 12 4 5 0.768458 32 12 4 5 0.768458 41 12 4 5 0.768458 42 12 4 5 0.768458 Source Month Road Day TypeID ID TypeID dayID VMTFraction 43 12 4 5 0.768458 51 12 4 5 0.768458 52 12 4 5 0.768458 53 12 4 5 0.768458 54 12 4 5 0.768458 61 12 4 5 0.768458 62 12 4 5 0.768458 11 12 5 5 0.766507 21 12 5 5 0.766507 31 12 5 5 0.766507 32 12 5 5 0.766507 41 12 5 5 0.766507 42 12 5 5 0.766507 43 12 5 5 0.766507 51 12 5 5 0.766507 52 12 5 5 0.766507 53 12 5 5 0.766507 54 12 5 5 0.766507 61 12 5 5 0.766507 62 12 5 5 0.766507 11 12 1 2 0.232512 21 12 1 2 0.232512 31 12 1 2 0.232512 32 12 1 2 0.232512 41 12 1 2 0.232512 42 12 1 2 0.232512 43 12 1 2 0.232512 51 12 1 2 0.232512 52 12 1 2 0.232512 53 12 1 2 0.232512 54 12 1 2 0.232512 61 12 1 2 0.232512 62 12 1 2 0.232512 11 12 2 2 0.231542 21 12 2 2 0.231542 31 12 2 2 0.231542 32 12 2 2 0.231542 41 12 2 2 0.231542 42 12 2 2 0.231542 43 12 2 2 0.231542 51 12 2 2 0.231542 52 12 2 2 0.231542 53 12 2 2 0.231542 54 12 2 2 0.231542 61 12 2 2 0.231542 2011 Ozone Precursor Emission Inventory C–15 Source Month Road Day TypeID ID TypeID dayID VMTFraction 62 12 2 2 0.231542 11 12 3 2 0.233493 21 12 3 2 0.233493 31 12 3 2 0.233493 32 12 3 2 0.233493 41 12 3 2 0.233493 42 12 3 2 0.233493 43 12 3 2 0.233493 51 12 3 2 0.233493 52 12 3 2 0.233493 53 12 3 2 0.233493 54 12 3 2 0.233493 61 12 3 2 0.233493 62 12 3 2 0.233493 11 12 4 2 0.231542 21 12 4 2 0.231542 31 12 4 2 0.231542 32 12 4 2 0.231542 41 12 4 2 0.231542 42 12 4 2 0.231542 43 12 4 2 0.231542 51 12 4 2 0.231542 52 12 4 2 0.231542 53 12 4 2 0.231542 54 12 4 2 0.231542 61 12 4 2 0.231542 62 12 4 2 0.231542 11 12 5 2 0.233493 21 12 5 2 0.233493 31 12 5 2 0.233493 32 12 5 2 0.233493 41 12 5 2 0.233493 42 12 5 2 0.233493 43 12 5 2 0.233493 51 12 5 2 0.233493 52 12 5 2 0.233493 53 12 5 2 0.233493 54 12 5 2 0.233493 61 12 5 2 0.233493 62 12 5 2 0.233493 February 2014 [HourVMTFraction] (SourceTypeID 21: Passenger Car) Source Road TypeID TypeID dayID hourID 21 1 5 1 21 1 5 2 21 1 5 3 21 1 5 4 21 1 5 5 21 1 5 6 21 1 5 7 21 1 5 8 21 1 5 9 21 1 5 10 21 1 5 11 21 1 5 12 21 1 5 13 21 1 5 14 21 1 5 15 21 1 5 16 21 1 5 17 21 1 5 18 21 1 5 19 21 1 5 20 21 1 5 21 21 1 5 22 21 1 5 23 21 1 5 24 21 2 5 1 21 2 5 2 21 2 5 3 21 2 5 4 21 2 5 5 21 2 5 6 21 2 5 7 21 2 5 8 21 2 5 9 21 2 5 10 21 2 5 11 21 2 5 12 21 2 5 13 21 2 5 14 21 2 5 15 21 2 5 16 21 2 5 17 21 2 5 18 21 2 5 19 21 2 5 20 21 2 5 21 21 2 5 22 21 2 5 23 21 2 5 24 21 3 5 1 21 3 5 2 21 3 5 3 21 3 5 4 21 3 5 5 21 3 5 6 21 3 5 7 21 3 5 8 21 3 5 9 21 3 5 10 21 3 5 11 21 3 5 12 21 3 5 13 21 3 5 14 21 3 5 15 21 3 5 16 21 3 5 17 21 3 5 18 21 3 5 19 21 3 5 20 21 3 5 21 21 3 5 22 21 3 5 23 21 3 5 24 21 4 5 1 21 4 5 2 21 4 5 3 21 4 5 4 21 4 5 5 21 4 5 6 21 4 5 7 21 4 5 8 21 4 5 9 21 4 5 10 21 4 5 11 21 4 5 12 21 4 5 13 hourVMT Fraction 0.007957 0.005448 0.004973 0.006014 0.013468 0.034281 0.054676 0.06466 0.060292 0.052697 0.050973 0.054873 0.057626 0.059009 0.064762 0.06924 0.070039 0.07009 0.05904 0.04192 0.033428 0.029157 0.02144 0.013936 0.009807 0.006923 0.00651 0.007961 0.017302 0.042783 0.060321 0.059377 0.057361 0.055026 0.052104 0.05478 0.05683 0.059985 0.065538 0.065523 0.061668 0.059173 0.054281 0.040837 0.033031 0.030836 0.024921 0.017121 0.006081 0.003952 0.003413 0.004039 0.009578 0.025656 0.04895 0.07002 0.063264 0.050335 0.049826 0.054967 0.058433 0.058019 0.063976 0.073011 0.07853 0.081166 0.063868 0.043018 0.033831 0.027454 0.017909 0.010705 0.009807 0.006923 0.00651 0.007961 0.017302 0.042783 0.060321 0.059377 0.057361 0.055026 0.052104 0.05478 0.05683 Source Road TypeID TypeID dayID hourID 21 4 5 14 21 4 5 15 21 4 5 16 21 4 5 17 21 4 5 18 21 4 5 19 21 4 5 20 21 4 5 21 21 4 5 22 21 4 5 23 21 4 5 24 21 5 5 1 21 5 5 2 21 5 5 3 21 5 5 4 21 5 5 5 21 5 5 6 21 5 5 7 21 5 5 8 21 5 5 9 21 5 5 10 21 5 5 11 21 5 5 12 21 5 5 13 21 5 5 14 21 5 5 15 21 5 5 16 21 5 5 17 21 5 5 18 21 5 5 19 21 5 5 20 21 5 5 21 21 5 5 22 21 5 5 23 21 5 5 24 21 1 2 1 21 1 2 2 21 1 2 3 21 1 2 4 21 1 2 5 21 1 2 6 21 1 2 7 21 1 2 8 21 1 2 9 21 1 2 10 21 1 2 11 21 1 2 12 21 1 2 13 21 1 2 14 21 1 2 15 21 1 2 16 21 1 2 17 21 1 2 18 21 1 2 19 21 1 2 20 21 1 2 21 21 1 2 22 21 1 2 23 21 1 2 24 21 2 2 1 21 2 2 2 21 2 2 3 21 2 2 4 21 2 2 5 21 2 2 6 21 2 2 7 21 2 2 8 21 2 2 9 21 2 2 10 21 2 2 11 21 2 2 12 21 2 2 13 21 2 2 14 21 2 2 15 21 2 2 16 21 2 2 17 21 2 2 18 21 2 2 19 21 2 2 20 21 2 2 21 21 2 2 22 21 2 2 23 21 2 2 24 21 3 2 1 21 3 2 2 hourVMT Fraction 0.059985 0.065538 0.065523 0.061668 0.059173 0.054281 0.040837 0.033031 0.030836 0.024921 0.017121 0.006081 0.003952 0.003413 0.004039 0.009578 0.025656 0.04895 0.07002 0.063264 0.050335 0.049826 0.054967 0.058433 0.058019 0.063976 0.073011 0.07853 0.081166 0.063868 0.043018 0.033831 0.027454 0.017909 0.010705 0.020872 0.014804 0.013016 0.010079 0.011715 0.018691 0.027033 0.033174 0.040089 0.048519 0.05524 0.060009 0.064796 0.06555 0.064719 0.064355 0.064852 0.064713 0.061678 0.050477 0.043519 0.040777 0.035718 0.025605 0.020431 0.014508 0.012577 0.009828 0.011013 0.01751 0.025995 0.031456 0.038799 0.047714 0.054712 0.060251 0.065575 0.066506 0.065746 0.065312 0.065948 0.066767 0.064137 0.050196 0.042573 0.040589 0.036012 0.025845 0.021315 0.015101 Source Road TypeID TypeID dayID hourID 21 3 2 3 21 3 2 4 21 3 2 5 21 3 2 6 21 3 2 7 21 3 2 8 21 3 2 9 21 3 2 10 21 3 2 11 21 3 2 12 21 3 2 13 21 3 2 14 21 3 2 15 21 3 2 16 21 3 2 17 21 3 2 18 21 3 2 19 21 3 2 20 21 3 2 21 21 3 2 22 21 3 2 23 21 3 2 24 21 4 2 1 21 4 2 2 21 4 2 3 21 4 2 4 21 4 2 5 21 4 2 6 21 4 2 7 21 4 2 8 21 4 2 9 21 4 2 10 21 4 2 11 21 4 2 12 21 4 2 13 21 4 2 14 21 4 2 15 21 4 2 16 21 4 2 17 21 4 2 18 21 4 2 19 21 4 2 20 21 4 2 21 21 4 2 22 21 4 2 23 21 4 2 24 21 5 2 1 21 5 2 2 21 5 2 3 21 5 2 4 21 5 2 5 21 5 2 6 21 5 2 7 21 5 2 8 21 5 2 9 21 5 2 10 21 5 2 11 21 5 2 12 21 5 2 13 21 5 2 14 21 5 2 15 21 5 2 16 21 5 2 17 21 5 2 18 21 5 2 19 21 5 2 20 21 5 2 21 21 5 2 22 21 5 2 23 21 5 2 24 hourVMT Fraction 0.013457 0.010331 0.01242 0.019876 0.028075 0.034899 0.041383 0.049326 0.05577 0.059766 0.064014 0.064591 0.063689 0.063394 0.063753 0.062652 0.05921 0.050759 0.044469 0.040966 0.035423 0.025364 0.020431 0.014508 0.012577 0.009828 0.011013 0.01751 0.025995 0.031456 0.038799 0.047714 0.054712 0.060251 0.065575 0.066506 0.065746 0.065312 0.065948 0.066767 0.064137 0.050196 0.042573 0.040589 0.036012 0.025845 0.021315 0.015101 0.013457 0.010331 0.01242 0.019876 0.028075 0.034899 0.041383 0.049326 0.05577 0.059766 0.064014 0.064591 0.063689 0.063394 0.063753 0.062652 0.05921 0.050759 0.044469 0.040966 0.035423 0.025364 [AvgSpeedDistribution] (SourceTypeID 21: Passenger Car and RoadTypeID 2: Rural Restricted Access) Source Road Hour TypeID TypeID DayID 21 2 15 21 2 15 avgSpeed BinID 1 2 avgSpeed Fraction 2.51E-05 0 Source Road Hour TypeID TypeID DayID 21 2 15 21 2 15 2011 Ozone Precursor Emission Inventory avgSpeed BinID 3 4 C–16 avgSpeed Fraction 0 0 Source Road Hour TypeID TypeID DayID 21 2 15 21 2 15 avgSpeed BinID 5 6 avgSpeed Fraction 0 0 February 2014 Source Road Hour TypeID TypeID DayID 21 2 15 21 2 15 21 2 15 21 2 15 21 2 15 21 2 15 21 2 15 21 2 15 21 2 15 21 2 15 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 25 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 35 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 45 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 55 21 2 65 21 2 65 21 2 65 21 2 65 21 2 65 21 2 65 21 2 65 21 2 65 21 2 65 21 2 65 21 2 65 21 2 65 21 2 65 avgSpeed BinID 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 avgSpeed Fraction 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 Source Road Hour TypeID TypeID DayID 21 2 65 21 2 65 21 2 65 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 75 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 85 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 95 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 105 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 115 21 2 125 21 2 125 21 2 125 21 2 125 2011 Ozone Precursor Emission Inventory avgSpeed BinID 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 C–17 avgSpeed Fraction 0.083438 0.102646 0.160812 1.98E-05 0 0 0 0 0 0 0 0 0.057069 0.140623 0.248507 0.169045 0.075169 0.111641 0.197927 1.98E-05 0 0 0 0 0 0 0 0 0.057069 0.140623 0.248507 0.169045 0.075169 0.111641 0.197927 1.98E-05 0 0 0 0 0 0 0 0 0.057069 0.140623 0.248507 0.169045 0.075169 0.111641 0.197927 1.78E-05 0 0 0 0 0 0 0 0 0.059729 0.129919 0.24385 0.049713 0.140357 0.191024 0.18539 1.78E-05 0 0 0 0 0 0 0 0 0.059729 0.129919 0.24385 0.049713 0.140357 0.191024 0.18539 1.78E-05 0 0 0 Source Road Hour TypeID TypeID DayID 21 2 125 21 2 125 21 2 125 21 2 125 21 2 125 21 2 125 21 2 125 21 2 125 21 2 125 21 2 125 21 2 125 21 2 125 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 135 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 145 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 155 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 165 21 2 175 21 2 175 21 2 175 21 2 175 21 2 175 21 2 175 21 2 175 21 2 175 21 2 175 21 2 175 21 2 175 avgSpeed BinID 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 avgSpeed Fraction 0 0 0 0 0 0.059729 0.129919 0.24385 0.049713 0.140357 0.191024 0.18539 1.78E-05 0 0 0 0 0 0 0 0 0.059729 0.129919 0.24385 0.049713 0.140357 0.191024 0.18539 1.78E-05 0 0 0 0 0 0 0 0 0.059729 0.129919 0.24385 0.049713 0.140357 0.191024 0.18539 1.78E-05 0 0 0 0 0 0 0 0 0.059729 0.129919 0.24385 0.049713 0.140357 0.191024 0.18539 1.69E-05 0 0 0 0 0 0 0 0 0 0 0.000288 0.094046 0.274366 0.241766 0.389518 1.69E-05 0 0 0 0 0 0 0 0 0 0 February 2014 Source Road Hour TypeID TypeID DayID 21 2 175 21 2 175 21 2 175 21 2 175 21 2 175 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 185 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 195 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 205 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 215 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 225 21 2 235 21 2 235 avgSpeed BinID 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 avgSpeed Fraction 0.000288 0.094046 0.274366 0.241766 0.389518 1.69E-05 0 0 0 0 0 0 0 0 0 0 0.000288 0.094046 0.274366 0.241766 0.389518 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 Source Road Hour TypeID TypeID DayID 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 235 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 245 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 12 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 22 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 32 21 2 42 21 2 42 21 2 42 21 2 42 21 2 42 21 2 42 21 2 42 21 2 42 21 2 42 2011 Ozone Precursor Emission Inventory avgSpeed BinID 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 C–18 avgSpeed Fraction 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 Source Road Hour TypeID TypeID DayID 21 2 42 21 2 42 21 2 42 21 2 42 21 2 42 21 2 42 21 2 42 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 52 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 62 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 72 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 82 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 21 2 92 avgSpeed BinID 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 avgSpeed Fraction 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 February 2014 Source Road Hour TypeID TypeID DayID 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 102 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 112 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 122 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 132 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 142 21 2 152 21 2 152 21 2 152 21 2 152 21 2 152 avgSpeed BinID 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 avgSpeed Fraction 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 Source Road Hour TypeID TypeID DayID 21 2 152 21 2 152 21 2 152 21 2 152 21 2 152 21 2 152 21 2 152 21 2 152 21 2 152 21 2 152 21 2 152 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 162 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 172 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 182 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 192 21 2 202 21 2 202 21 2 202 21 2 202 21 2 202 21 2 202 21 2 202 21 2 202 21 2 202 21 2 202 2011 Ozone Precursor Emission Inventory avgSpeed BinID 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 C–19 avgSpeed Fraction 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 Source Road Hour TypeID TypeID DayID 21 2 202 21 2 202 21 2 202 21 2 202 21 2 202 21 2 202 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 212 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 222 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 232 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 21 2 242 avgSpeed BinID 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 avgSpeed Fraction 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 2.51E-05 0 0 0 0 0 0.019619 0.097646 0.131977 0.203234 0.087838 0.07357 0.039194 0.083438 0.102646 0.160812 February 2014 [AVFT] (SourceTypeID 42: Transit Bus) Source TypeID 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 Model Fuel Eng YearID TypeID TechID 1960 2 1 1961 2 1 1962 2 1 1963 2 1 1964 2 1 1965 2 1 1966 2 1 1967 2 1 1968 2 1 1969 2 1 1970 2 1 1971 2 1 1972 2 1 1973 2 1 1974 2 1 1975 2 1 1976 2 1 1977 2 1 1978 2 1 1979 2 1 1980 2 1 1981 2 1 1982 2 1 1983 2 1 1984 2 1 1985 2 1 1986 2 1 1987 2 1 1988 2 1 1989 2 1 1990 2 1 1990 3 1 1991 2 1 1991 3 1 1992 1 1 1992 2 1 1992 3 1 1993 1 1 1993 2 1 1993 3 1 1994 1 1 1994 2 1 1994 3 1 1995 1 1 1995 2 1 1995 3 1 1996 1 1 1996 2 1 1996 3 1 1997 1 1 1997 2 1 1997 3 1 1998 1 1 1998 2 1 1998 3 1 1999 1 1 1999 2 1 1999 3 1 2000 1 1 2000 2 1 2000 3 1 2001 1 1 2001 2 1 2001 3 1 2002 1 1 2002 2 1 2002 3 1 2003 1 1 2003 2 1 2003 3 1 2004 1 1 2004 2 1 2004 3 1 2005 1 1 2005 2 1 fuelEng Fraction 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 0.993 0.007 0.982 0.018 0.01 0.944 0.046 0.01 0.914 0.076 0.01 0.905 0.085 0.01 0.837 0.153 0.01 0.892 0.098 0 1 0 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0.08 0.92 0 0.397059 0.602941 0 1 2011 Ozone Precursor Emission Inventory Source TypeID 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 Model Fuel Eng YearID TypeID TechID 2005 3 1 2006 1 1 2006 2 1 2006 3 1 2007 1 1 2007 2 1 2007 3 1 2008 1 1 2008 2 1 2008 3 1 2009 1 1 2009 2 1 2009 3 1 2010 1 1 2010 2 1 2010 3 1 2011 1 1 2011 2 1 2011 3 1 2012 1 1 2012 2 1 2012 3 1 2013 1 1 2013 2 1 2013 3 1 2014 1 1 2014 2 1 2014 3 1 2015 1 1 2015 2 1 2015 3 1 2016 1 1 2016 2 1 2016 3 1 2017 1 1 2017 2 1 2017 3 1 2018 1 1 2018 2 1 2018 3 1 2019 1 1 2019 2 1 2019 3 1 2020 1 1 2020 2 1 2020 3 1 2021 1 1 2021 2 1 2021 3 1 2022 1 1 2022 2 1 2022 3 1 2023 1 1 2023 2 1 2023 3 1 2024 1 1 2024 2 1 2024 3 1 2025 1 1 2025 2 1 2025 3 1 2026 1 1 2026 2 1 2026 3 1 2027 1 1 2027 2 1 2027 3 1 2028 1 1 2028 2 1 2028 3 1 2029 1 1 2029 2 1 2029 3 1 2030 1 1 2030 2 1 C–20 fuelEng Fraction 0 0.089744 0.128205 0.782051 0.149533 0.850467 0 0 0.479592 0.520408 0.121212 0.030303 0.848485 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 Source TypeID 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 42 Model Fuel Eng YearID TypeID TechID 2030 3 1 2031 1 1 2031 2 1 2031 3 1 2032 1 1 2032 2 1 2032 3 1 2033 1 1 2033 2 1 2033 3 1 2034 1 1 2034 2 1 2034 3 1 2035 1 1 2035 2 1 2035 3 1 2036 1 1 2036 2 1 2036 3 1 2037 1 1 2037 2 1 2037 3 1 2038 1 1 2038 2 1 2038 3 1 2039 1 1 2039 2 1 2039 3 1 2040 1 1 2040 2 1 2040 3 1 2041 1 1 2041 2 1 2041 3 1 2042 1 1 2042 2 1 2042 3 1 2043 1 1 2043 2 1 2043 3 1 2044 1 1 2044 2 1 2044 3 1 2045 1 1 2045 2 1 2045 3 1 2046 1 1 2046 2 1 2046 3 1 2047 1 1 2047 2 1 2047 3 1 2048 1 1 2048 2 1 2048 3 1 2049 1 1 2049 2 1 2049 3 1 2050 1 1 2050 2 1 2050 3 1 fuelEng Fraction 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 0 1 0 February 2014 [CountyYear] countyID 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 4013 yearID 1999 2000 2001 2002 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018 2019 2020 2021 2022 2023 2024 2025 2026 2027 2028 2029 2030 2031 2032 2033 2034 2035 2036 2037 2038 2039 2040 2041 2042 2043 2044 2045 2046 2047 2048 2049 2050 refuelingVaporProgramAdjust 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 refuelingSpillProgramAdjust 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 0.46 2011 Ozone Precursor Emission Inventory C–21 February 2014 Appendix D. Public Comment Period Documentation Site Map | Search | Phone Directory | Departments | Services text sizer News Calendar Brown Bag Events Calendar < M-info Rapid Response Notification Search Air Quality Web Site Go February 2014 > S M T W T F S 26 27 28 29 30 31 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 1 2 3 4 7 8 5 6 Public Workshop Air Quality Department, Bob Huhn, PIO The Maricopa County Air Quality Department is holding a public workshop to discuss the draft 2011 Periodic Emissions Inventory for Ozone Precursors, published in January 2014. The inventory includes emissions estimates for volatile organic compounds (VOC), nitrogen oxides (NOx) and carbon monoxide (CO). Emissions are calculated for both Maricopa County and the eighthour ozone nonattainment area. Annual totals as well as season-day emissions are provided for all source categories. The emissions inventory report will undergo a 30-day public review period. The document is available in electronic format (PDF files) on the department’s website (see link below). The department is accepting written comments on the draft emissions inventory report through the close of business on Friday, February 21, 2014. The public workshop is an informal meeting for all interested parties, is free of charge, and requires no advance registration or RSVP. *All visitors to the MCAQD offices at 1001 N. Central Ave, Phoenix, AZ are kindly requested to check in at the reception area in Suite 125. Date: 2/14/2014 Time: 2:00 PM Registration Required: No Fee: None More Info: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/reports/Default.aspx Contact: Bob Downing Emissions Inventory Unit Manager 602-506-6790 bdowning@mail.maricopa.gov Location: Maricopa County Air Quality Department Address: 1001 N. Central Ave. Suite 125 Phoenix, AZ 85004 Maricopa County Air Quality Department 1001 North Central Avenue, Suite 125, Phoenix AZ 85004 (602) 506-6010 © 2014 Maricopa County Maricopa Home Site Map Legal Information Privacy/Security Policies Maricopa County || 301 W. Jefferson St. || Phoenix, AZ 85003 602-506-3011