2008 PM10 Periodic Emissions Inventory for the Maricopa County, Arizona, Nonattainment Area June 2010 2008 PM10 Periodic Emission Inventory for the Maricopa County, Arizona Nonattainment Area June 2010 Table of Contents 1. Introduction ....................................................................................................................................1 1.1 1.2 1.3 1.4 1.5 1.6 1.7 Overview.......................................................................................................................................1 Agencies responsible for the emissions inventory ........................................................................1 Temporal scope .............................................................................................................................2 Geographic scope..........................................................................................................................2 Overview of local demographic and land use data .......................................................................3 1.5.1 Demographic profile ..........................................................................................................3 1.5.2 Land use data .....................................................................................................................3 Emissions overview by source category .......................................................................................4 1.6.1 Point sources ......................................................................................................................4 1.6.2 Area sources .......................................................................................................................4 1.6.3 Nonroad mobile sources ....................................................................................................5 1.6.4 Onroad mobile sources ......................................................................................................5 1.6.5 Biogenic sources ................................................................................................................6 1.6.6 Summary of all source categories ......................................................................................6 Public review process .................................................................................................................10 2. Point Sources ................................................................................................................................11 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 Introduction and scope ................................................................................................................11 Identification of point sources ....................................................................................................11 Procedures for estimating emissions from point sources............................................................12 2.3.1 Calculation of PM2.5 emissions ........................................................................................13 2.3.2 Application of rule effectiveness .....................................................................................13 Detailed overview of point source emissions .............................................................................13 Emission reduction credits ..........................................................................................................14 Summary of point source emissions ...........................................................................................15 Quality assurance / quality control procedures ...........................................................................15 2.7.1 Emission survey preparation and data collection.............................................................15 2.7.2 Submission processing .....................................................................................................16 2.7.3 Analysis of annual point source emissions data for this inventory ..................................17 References ...................................................................................................................................17 3. Area Sources .................................................................................................................................19 3.1 3.2 Scope and methodology ..............................................................................................................19 Fuel combustion..........................................................................................................................20 3.2.1 Industrial natural gas ........................................................................................................21 3.2.2 Industrial fuel oil ..............................................................................................................22 3.2.3 Commercial/institutional natural gas ...............................................................................24 2008 Maricopa Co. PM10 Emission Inventory i June 2010 3.3 3.4 3.5 3.2.4 Commercial/institutional fuel oil .....................................................................................25 3.2.5 Residential natural gas .....................................................................................................27 3.2.6 Residential wood combustion ..........................................................................................28 3.2.7 Residential fuel oil ...........................................................................................................29 3.2.8 Summary of all area-source fuel combustion ..................................................................30 Industrial processes .....................................................................................................................30 3.3.1 Chemical manufacturing ..................................................................................................30 3.3.2 Food and kindred products...............................................................................................31 3.3.2.1 Commercial cooking ..........................................................................................31 3.3.2.2 Grain handling/processing..................................................................................34 3.3.2.3 Ammonia cold storage .......................................................................................35 3.3.3 Secondary metal production ............................................................................................35 3.3.4 Non-metallic mineral processes .......................................................................................36 3.3.5 Mining and quarrying ......................................................................................................36 3.3.6 Wood product manufacturing ..........................................................................................37 3.3.7 Rubber/plastics manufacturing ........................................................................................38 3.3.8 Fabricated metal products manufacturing ........................................................................39 3.3.9 Construction .....................................................................................................................41 3.3.10 Electrical equipment manufacturing ................................................................................44 3.3.11 State-permitted portable sources ......................................................................................45 3.3.12 Paved/unpaved road travel on industrial sites ..................................................................46 3.3.13 Industrial processes not elsewhere classified (NEC) .......................................................46 3.3.14 Summary of all area-source industrial processes .............................................................47 Waste treatment and disposal .....................................................................................................48 3.4.1 On-site incineration ..........................................................................................................48 3.4.2 Open burning ...................................................................................................................49 3.4.3 Landfills ...........................................................................................................................52 3.4.4 Publicly owned treatment works (POTWs) .....................................................................52 3.4.5 Other industrial waste disposal ........................................................................................52 3.4.6 Summary of all area-source waste disposal .....................................................................53 Miscellaneous area sources .........................................................................................................53 3.5.1 Other combustion .............................................................................................................53 3.5.1.1 Wildfires .............................................................................................................53 3.5.1.2 Prescribed fires ...................................................................................................56 3.5.1.3 Structure fires .....................................................................................................57 3.5.1.4 Vehicle fires .......................................................................................................59 3.5.1.5 Engine testing .....................................................................................................60 3.5.2 Agricultural activities.......................................................................................................60 3.5.2.1 Tilling .................................................................................................................60 3.5.2.2 Harvesting ..........................................................................................................64 3.5.2.3 Travel on unpaved agricultural roads .................................................................67 3.5.2.4 Cotton ginning ....................................................................................................69 3.5.2.5 Fertilizer application ............................................................................................69 3.5.3 Livestock ..........................................................................................................................70 3.5.4 Health services: crematories ............................................................................................72 3.5.5 Accidental releases ...........................................................................................................72 3.5.6 Humans ............................................................................................................................72 3.5.7 Leaf blower fugitive dust .................................................................................................73 3.5.8 Offroad recreation vehicles fugitive dust .........................................................................74 2008 Maricopa Co. PM10 Emission Inventory ii June 2010 3.6 3.7 3.8 3.5.9 Unpaved parking lots fugitive dust ..................................................................................76 3.5.10 Windblown dust ...............................................................................................................79 3.5.11 Summary of all miscellaneous area sources ....................................................................80 Summary of all area sources .......................................................................................................81 Quality assurance/quality control procedures .............................................................................83 References ...................................................................................................................................85 4. Nonroad Mobile Sources .............................................................................................................89 4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 4.9 4.10 4.11 4.12 4.13 4.14 4.15 Introduction .................................................................................................................................89 Agricultural equipment ...............................................................................................................91 Airport ground support equipment and auxiliary power units ....................................................92 Commercial equipment ...............................................................................................................93 Construction and mining equipment ...........................................................................................94 Industrial equipment ...................................................................................................................94 Lawn and garden equipment .......................................................................................................95 Pleasure craft...............................................................................................................................95 Railway maintenance equipment ................................................................................................96 Recreational equipment ..............................................................................................................96 Aircraft ........................................................................................................................................97 Locomotives..............................................................................................................................101 Summary of all nonroad mobile source emissions ...................................................................103 Quality assurance procedures ...................................................................................................103 References .................................................................................................................................103 5. Onroad Mobile Sources .............................................................................................................105 5.1 5.2 5.3 5.4 5.5 5.6 5.7 5.8 Introduction ...............................................................................................................................105 VMT estimation ........................................................................................................................106 Speed estimation .......................................................................................................................107 Monthly VMT factors ...............................................................................................................108 Emission factor estimation........................................................................................................109 5.5.1 MOBILE6.2 emission factor model ...............................................................................109 5.5.1.1 MOBILE6.2 inputs ...........................................................................................109 5.5.1.2 MOBILE6.2 outputs .........................................................................................109 5.5.1.3 MOBILE6.2 emission estimates ......................................................................110 5.5.2 Fugitive dust emissions ..................................................................................................115 5.5.2.1 Paved road fugitive dust emissions ..................................................................115 5.5.2.2 Unpaved road and alley fugitive dust emissions ..............................................117 Summary of particulate emissions from onroad mobile sources ..............................................119 Quality assurance process .........................................................................................................119 5.7.1 VMT estimates ...............................................................................................................119 5.7.2 Emission factor estimates ..............................................................................................119 5.7.3 Draft particulate matter emissions inventory .................................................................119 References .................................................................................................................................120 6. Biogenic Sources.........................................................................................................................121 6.1 6.2 Introduction ...............................................................................................................................121 Modeling domain ......................................................................................................................121 2008 Maricopa Co. PM10 Emission Inventory iii June 2010 6.3 6.4 6.5 6.6 Input data ..................................................................................................................................121 6.3.1 Land cover data ..............................................................................................................122 6.3.2 Weather data ..................................................................................................................123 Emissions estimation ................................................................................................................124 Summary of biogenic source emissions....................................................................................126 References .................................................................................................................................126 List of Tables Table 1.2–1. Table 1.5–1. Table 1.5–2. Table 1.6–1. Table 1.6–2. Table 1.6–3. Table 1.6–4. Table 1.6–5. Table 1.6–6. Table 1.6–7. Table 1.6–8. Table 1.6–9. Table 1.6–10. Table 2.2–1. Table 2.4–1. Table 2.5–1. Table 2.6–1. Table 3.1–1. Table 3.2–1. Table 3.2–2. Table 3.2–3. Table 3.2–4. Table 3.2–5. Table 3.2–6. Chapter authors and QA/QC contacts for this report. ....................................................1 Demographic profile of Maricopa County and the PM10 nonattainment area. ..............3 Land use categories used to apportion emissions. .........................................................4 Summary of annual and typical daily emissions from point sources in Maricopa County. ..........................................................................................................4 Summary of annual and typical daily emissions from area sources in Maricopa County. ...........................................................................................................................4 Summary of annual and typical daily emissions from area sources in the PM10 NAA. ..............................................................................................................................5 Annual and typical daily emissions from nonroad mobile sources in Maricopa County. ...........................................................................................................................5 Annual and typical daily emissions from all nonroad mobile sources in the PM10 NAA. ....................................................................................................................5 Annual and average daily emissions from all onroad mobile sources in Maricopa County. ..........................................................................................................6 Annual and typical daily emissions from all onroad mobile sources in the PM10 NAA. ....................................................................................................................6 Annual and season-day NOx emissions from biogenic sources. ....................................6 Annual and typical daily emissions from all sources in Maricopa County. ..................7 Annual and typical daily emissions from all sources in the PM10 nonattainment area. ........................................................................................................9 Name and location of all point sources in Maricopa County.......................................12 Annual and typical daily point source emissions, by facility. .....................................14 Emission reduction credits. ..........................................................................................14 Annual and typical daily point source emissions (including emission reduction credits)..........................................................................................................................15 List of area-source categories included in this PM10 inventory. ..................................19 Maricopa County natural gas sales data by supply company and end-user category. .......................................................................................................................20 Natural gas usage, emission factors, and annual emissions from area-source industrial natural gas combustion, by combustion type. ..............................................21 Annual and typical daily emissions from area-source industrial natural gas combustion. ..................................................................................................................22 Emission factors and annual emissions from area-source industrial fuel oil combustion, by combustion type. ................................................................................23 Annual and typical daily emissions from area-source industrial fuel oil combustion. ..................................................................................................................24 Emission factors and annual emissions from area-source commercial/institutional natural gas combustion, by combustion type. ......................24 2008 Maricopa Co. PM10 Emission Inventory iv June 2010 Table 3.2–7. Annual and typical daily emissions from area-source commercial/institutional natural gas combustion. ...............................................................................................25 Table 3.2–8. Emission factors and annual emissions from area-source commercial/institutional fuel oil combustion, by combustion type. ............................26 Table 3.2–9. Annual and typical daily emissions from area-source commercial/institutional fuel oil combustion. .....................................................................................................27 Table 3.2–10. Residential natural gas combustion emission factors. .................................................27 Table 3.2–11. Annual and typical daily emissions from residential natural gas combustion. ............27 Table 3.2–12. Annual wood usage, emission factors, and annual emissions from residential wood combustion. ........................................................................................................28 Table 3.2–13. Annual and typical daily emissions from residential wood combustion. ....................29 Table 3.2–14. Annual and typical daily emissions from residential fuel oil combustion. ..................29 Table 3.2–15. Annual and typical daily emissions from area-source fuel combustion in Maricopa County. ........................................................................................................30 Table 3.2–16. Annual and typical daily emissions from all area-source fuel combustion for the PM10 NAA..............................................................................................................30 Table 3.3–1. NAICS codes and descriptions for chemical manufacturing. ......................................30 Table 3.3–2. Annual and typical daily emissions from area-source chemical manufacturing. ........31 Table 3.3–3. Number of Maricopa County restaurants, by restaurant type. .....................................32 Table 3.3–4. Percentages of restaurants with each type of cooking equipment. ..............................32 Table 3.3–5. Average number of equipment pieces per restaurant, by type. ....................................32 Table 3.3–6. Total pieces of cooking equipment, by restaurant type. ..............................................33 Table 3.3–7. Meat cooked weekly per restaurant (in pounds), by equipment type. .........................33 Table 3.3–8. Total meat cooked weekly (in tons), by equipment type. ............................................33 Table 3.3–9. PM10and PM2.5 emission factors for commercial cooking equipment, by device type. ..............................................................................................................................34 Table 3.3–10. Annual and daily emissions from commercial cooking equipment in Maricopa County. .........................................................................................................................34 Table 3.3–11. Annual and daily PM emissions from commercial cooking equipment in the PM10 NAA. ..................................................................................................................34 Table 3.3–12. Annual and typical daily emissions from area-source grain handling and processing. ...................................................................................................................34 Table 3.3–13. Annual and typical daily ammonia emissions from ammonia cold storage. ...............35 Table 3.3–14. Annual and typical daily emissions from secondary metal production. ......................36 Table 3.3–15. Annual and typical daily emissions from area-source non-metallic mineral products. .......................................................................................................................36 Table 3.3–16. Annual and typical daily emissions from area-source mining and quarrying operations. ....................................................................................................................37 Table 3.3–17. County-level employment estimates for wood product manufacturing, by NAICS code. ................................................................................................................37 Table 3.3–18. Annual and typical daily emissions from area-source wood product manufacturing. .............................................................................................................38 Table 3.3–19. County-level employment estimates for rubber and plastic manufacturing, by NAICS code. ................................................................................................................39 Table 3.3–20. Annual and typical daily emissions from area-source rubber/plastic product manufacturing. .............................................................................................................39 Table 3.3–21. Annual and typical daily emissions from area-source fabricated metal product manufacturing. .............................................................................................................40 Table 3.3–22. Maricopa County dust control permits issued in 2008, by type. .................................41 2008 Maricopa Co. PM10 Emission Inventory v June 2010 Table 3.3–23. Average project duration and emission factor, by project type. ..................................42 Table 3.3–24. Annual emissions from construction in Maricopa County, by project type. ...............43 Table 3.3–25. Annual emissions from construction within the Maricopa County portion of the PM10 nonattainment area, by project type. .............................................................43 Table 3.3–26. Annual emissions from construction in the Pinal County portion of the PM10 NAA, by project type. ..................................................................................................44 Table 3.3–27. Annual and typical daily emissions from construction in Maricopa County and the PM10 NAA..............................................................................................................44 Table 3.3–28. Annual and typical daily emissions from area-source electric equipment manufacturing. .............................................................................................................44 Table 3.3–29. Annual and typical daily emissions from ADEQ-permitted portable sources.............46 Table 3.3–30. Annual and typical daily emissions from paved and unpaved road travel at industrial facilities........................................................................................................46 Table 3.3–31. Annual and typical daily emissions from other industrial processes not elsewhere classified. ....................................................................................................46 Table 3.3–32. Annual and daily emissions from all area-source industrial processes in Maricopa County. ........................................................................................................47 Table 3.3–33. Annual and typical daily emissions from all area-source industrial processes in the PM10 NAA..............................................................................................................48 Table 3.4–1. Annual and typical daily emissions from on-site incineration.....................................49 Table 3.4–2. Summary of 2008 Maricopa County burn permit activity. ..........................................49 Table 3.4–3. Emission and fuel loading factors for open burning. ...................................................50 Table 3.4–4. Annual and typical daily emissions from open burning in Maricopa County. ............51 Table 3.4–5. Surrogate land use classes and County:NAA activity ratios for burn permit categories. ....................................................................................................................51 Table 3.4–6. Annual and typical daily emissions from open burning in the PM10 NAA. ................51 Table 3.4–7. Annual and typical daily emissions from landfills. .....................................................52 Table 3.4–8. NH3 emissions from publicly-owned treatment works (POTWs). ..............................52 Table 3.4–9. Annual and typical daily emissions from other industrial waste disposal. ..................52 Table 3.4–10. Annual and typical daily emissions from all area-source waste disposal for Maricopa County. ........................................................................................................53 Table 3.4–11. Annual and typical daily emissions from all area-source waste disposal for the PM10 NAA. ..................................................................................................................53 Table 3.5–1. Sources and input data used to estimate emissions from fires in Maricopa County. .........................................................................................................................54 Table 3.5–2. NFDRS fuel model categories and fuel loading factors for 2008 Maricopa County wildfires...........................................................................................................54 Table 3.5–3. Summary of data on fire occurrence, total acres burned, and total material burned in 2008. ............................................................................................................55 Table 3.5–4. Summary of emission factors for prescribed fire. ........................................................55 Table 3.5–5. Annual emissions from wildfires in Maricopa County and the PM10 NAA. ...............55 Table 3.5–6. Average daily emissions from wildfires in Maricopa County and the PM10 NAA. ............................................................................................................................56 Table 3.5–7. Summary of data used to estimate emissions from prescribed fires. ...........................56 Table 3.5–8. Emission factors for prescribed fires. ..........................................................................56 Table 3.5–9. Annual and typical daily emission from prescribed fire in Maricopa County and the PM10 NAA. ......................................................................................................57 Table 3.5–10. Material burned, emission and fuel loading factors for structure fires. .......................58 Table 3.5–11. Annual and typical daily emissions from structure fires in Maricopa County 2008 Maricopa Co. PM10 Emission Inventory vi June 2010 and the NAA. ...............................................................................................................58 Table 3.5–12. Estimated material burned, fuel loading factors, and emission factors for vehicle fires. .................................................................................................................59 Table 3.5–13. Annual and typical daily emissions from vehicle fires. ...............................................59 Table 3.5–14. Annual and typical daily emissions from engine testing. ............................................60 Table 3.5–15. 2008 crop acreage, activity, and annual uncontrolled PM10 emissions in Maricopa County. ........................................................................................................61 Table 3.5–16. Annual emissions from agricultural tillage in Maricopa County and Area A (tons/yr). .......................................................................................................................63 Table 3.5–17. Annual emissions from agricultural tillage in the PM10 NAA (tons/yr). .....................63 Table 3.5–18. Controlled typical daily emissions from tillage (in lbs/day). .......................................64 Table 3.5–19. Maricopa County harvested acres and emission factors. .............................................64 Table 3.5–20. Annual emissions from harvesting in Maricopa County and Area A (in tons/yr). ........................................................................................................................66 Table 3.5–21. Annual emissions from harvesting in the PM10 NAA (tons/yr). ..................................66 Table 3.5–22. Typical daily emissions from harvesting, by crop (in lbs/day). ...................................67 Table 3.5–23. Annual and typical daily emissions from travel on unpaved agricultural roads. .........69 Table 3.5–24. Annual and typical daily emissions from area-source cotton ginning. ........................69 Table 3.5–25. Annual and typical daily NH3 emissions from fertilizer application. ..........................70 Table 3.5–26. Maricopa County cattle populations and PM emission factors. ..................................71 Table 3.5–27. Maricopa County cattle inventory for 2002 and 2008. ................................................71 Table 3.5–28. Annual and typical daily NH3 emissions from livestock in Maricopa County. ...........71 Table 3.5–29. Annual and typical daily emissions from livestock. ....................................................72 Table 3.5–30. Annual and typical daily emissions from crematories. ................................................72 Table 3.5–31. Annual and typical daily emissions from accidental releases. .....................................72 Table 3.5–32. Annual and typical daily NH3 emissions from human activity....................................73 Table 3.5–33. Leaf blower equipment populations, activity levels and emission factors for Maricopa County. ........................................................................................................73 Table 3.5–34. Annual and typical daily emissions from leaf blower fugitive dust. ...........................74 Table 3.5–35. 2008 offroad recreational vehicle travel on unpaved surfaces in Maricopa County. .........................................................................................................................75 Table 3.5–36. 2008 uncontrolled emissions from offroad recreational vehicles. ...............................75 Table 3.5–37. Benefits of measures that reduce offroad recreational vehicle emissions. ..................76 Table 3.5–38. 2008 controlled emissions from offroad recreational vehicles. ...................................76 Table 3.5–39. 2008 uncontrolled emissions from vehicles traveling on unpaved parking lots. .........78 Table 3.2–40. Benefits of measure that reduces unpaved parking lot emissions................................78 Table 3.5–41. Annual and typical daily controlled emissions from unpaved parking lots. ................78 Table 3.5–42. Annual and typical daily emissions from fugitive windblown dust for Maricopa County. ........................................................................................................79 Table 3.5–43. Annual and typical daily emissions from fugitive windblown dust for the PM10 NAA. ..................................................................................................................79 Table 3.5–44. Annual and typical daily emissions from all miscellaneous area sources for Maricopa County. ........................................................................................................80 Table 3.5–45. Annual and typical daily emissions from all miscellaneous area sources for the PM10 NAA. ..................................................................................................................80 Table 3.6–1. Summary of annual and typical daily emissions from all area sources in Maricopa County. ........................................................................................................81 Table 3.6–2. Summary of annual and typical daily emissions from all area sources in the PM10 NAA. ..................................................................................................................82 2008 Maricopa Co. PM10 Emission Inventory vii June 2010 Table 4.1–1. Table 4.1–2. Table 4.2–1. Table 4.2–2. Table 4.2–3. Table 4.2–4. Table 4.3–1. Table 4.3–2. Table 4.4–1. Table 4.4–2. Table 4.5–1. Table 4.5–2. Table 4.6–1. Table 4.6–2. Table 4.7–1. Table 4.7–2. Table 4.8–1. Table 4.8–2. Table 4.9–1. Table 4.9–2. Table 4.10–1. Table 4.10–2. Table 4.11–1. Table 4.11–2. Table 4.11–3. Table 4.11–4. Table 4.11–5. Table 4.12–1. Table 4.12–2. Table 4.12–3. Table 4.12–4. Table 4.12–5. Table 4.13–1. Table 4.13–2. Table 5.2–1. Table 5.2–2. Table 5.2–3. Table 5.2–4. Table 5.3–1. NONROAD model county temperature- and fuel-related inputs. ...............................90 Default weekday and weekend day activity allocation fractions. ................................91 Annual emissions (tons/yr) from agricultural equipment in Maricopa County. ..........91 Annual emissions (tons/yr) from agricultural equipment in the PM10 NAA. ..............91 Typical daily emissions (lbs/day) from agricultural equipment in Maricopa County. .........................................................................................................................91 Typical daily emissions (lbs/day) from agricultural equipment in the PM10 nonattainment area. ......................................................................................................92 Annual emissions (tons/yr) from all airport ground support equipment (GSE) and auxiliary power units (APUs)................................................................................93 Typical daily emissions (lb) from airport GSE and APU usage. .................................93 Annual emissions (tons/yr) from commercial equipment usage..................................93 Typical daily emissions (lbs/day) from commercial equipment usage. .......................93 Annual emissions (tons/yr) from construction and mining equipment usage..............94 Typical daily emissions (lbs/day) from construction and mining equipment usage. ...........................................................................................................................94 Annual emissions (tons/yr) from industrial equipment usage. ....................................94 Typical daily emissions (lbs/day) from industrial equipment usage. ..........................94 Annual emissions (tons/yr) from lawn and garden equipment. ...................................95 Typical daily emissions (lbs/day) from lawn and garden equipment. .........................95 Annual emissions (tons/yr) from pleasure craft equipment. ........................................95 Typical daily emissions (lbs/day) from pleasure craft equipment. ..............................95 Annual emissions (tons/yr) from railway maintenance equipment. ............................96 Typical daily emissions (lbs/day) from railway maintenance equipment. ..................96 Annual emissions (tons/yr) from recreational equipment. ...........................................96 Typical daily emissions (lbs/day) from recreational equipment. .................................96 Annual airport operations (by aircraft category), and related data sources. ................98 Example showing how most common aircraft-specific activity was grown for EDMS modeling. .........................................................................................................99 EPA’s default PM10 emission factors for aircraft, by activity type. ............................99 Annual and average daily emissions, by airport and aircraft type, from airports within the PM10 NAA. ...............................................................................................100 Annual and average daily emissions, by aircraft type, from airports outside the PM10 NAA. ................................................................................................................101 Emission factors for locomotives...............................................................................101 Total diesel use and annual emissions from locomotives in Maricopa County. ........101 Annual emissions (in tons/yr) from locomotives in the PM10 NAA. .........................102 Typical daily emissions (in lbs/day) from locomotives in Maricopa County. ...........102 Typical daily emissions (in lbs/day) from locomotives in the PM10 nonattainment area. ....................................................................................................102 Annual and typical daily emissions from nonroad mobile sources in Maricopa County. .......................................................................................................................103 Annual and typical daily emissions from nonroad mobile sources in the PM10 NAA. ..........................................................................................................................103 2008 daily VMT by facility type (annual average daily traffic). ...............................107 2008 VMT by silt loading category for paved roads. ................................................107 2008 VMT on unpaved roads in the PM10 NAA and Maricopa County. ..................107 2008 VMT on all roads in the PM10 NAA and Maricopa County. ............................107 Average daily speeds for the 2008 periodic emissions inventory..............................108 2008 Maricopa Co. PM10 Emission Inventory viii June 2010 Table 5.4–1. Average daily VMT adjustment factors by month. ...................................................108 Table 5.5–1. Annual and average daily onroad mobile source emissions by facility type and vehicle class in the PM10 NAA. .................................................................................111 Table 5.5–2. Annual and average daily onroad mobile source emissions by facility type and vehicle class in Maricopa County. .............................................................................113 Table 5.5–3. Fugitive dust emission factors for paved roads..........................................................116 Table 5.5–4. Daily uncontrolled fugitive dust emissions from paved roads...................................116 Table 5.5–5. 2008 benefits of measures that reduce paved road fugitive dust in the PM10 NAA. ..........................................................................................................................116 Table 5.5–6. Annual controlled fugitive dust emissions from paved roads. ...................................117 Table 5.5–7. Daily uncontrolled unpaved road and alley fugitive dust emissions. ........................117 Table 5.5–8. 2008 benefits of measures that reduce unpaved road and alley fugitive dust in the PM10 NAA............................................................................................................118 Table 5.5–9. Annual and average daily controlled fugitive dust emissions from unpaved roads. ..........................................................................................................................118 Table 5.6–1. Annual and average daily emissions from all onroad mobile sources in Maricopa County. ......................................................................................................119 Table 5.6–2. Annual and average daily emissions from all onroad mobile sources in the PM10 NAA. ................................................................................................................119 Table 6.2–1. Two modeling domains defined in the UTM coordinate system. ..............................121 Table 6.4–1. Daily mean biogenic emissions of NOx in the PM10 NAA and Maricopa County, by month.......................................................................................................125 Table 6.4–2. Monthly biogenic emissions of NOx in the PM10 NAA and Maricopa County. ........126 Table 6.5–1. Daily mean and annual total NOx emissions from biogenic sources. ........................126 List of Figures Figure 1.4–1. Map of Maricopa County and the PM10 nonattainment area. ........................................2 Figure 2.7–1. Data flow for annual point source emission inventory reporting. ...............................16 Figure 6.3–1. Mask of the PM10 NAA in the 4-km modeling domain (top) and mask of Maricopa County in the 12-km modeling domain (bottom). .....................................122 Figure 6.3–2. Boundaries of the PM10 NAA (red line), the 4-km eight-hour ozone modeling domain (pink line), Maricopa County (blue line), and the meteorological observation site (red star). ..........................................................................................123 Figure 6.3–3. Annual mean diurnal cycles of measured temperature (top panel) and downward short wave radiation (bottom panel) in 2008. ..........................................124 Figure 6.4–1. Monthly emissions of NOx in Maricopa County (pink solid line, abbreviated as “MC”) and the PM10 NAA (blue solid line, abbreviated as “NA”). ......................125 2008 Maricopa Co. PM10 Emission Inventory ix June 2010 Appendices Appendix 1 Public Comment Period Documentation ............................................................ A1-1 – MCAQD News Release re: Publication of Draft Report (April 26, 2010) – Announcement of Public Workshop at MCAQD (May 14, 2010) Appendix 2 Instructions for Reporting 2008 Annual Air Pollution Emissions ................... A2-1 Appendix 3 Rule Effectiveness (RE) Studies........................................................................... A3-1 Executive Summary ................................................................................................ A3-1 Background ............................................................................................................. A3-2 Calculation of Rule Effectiveness (RE) Rates ........................................................ A3-4 A. Rule 310 RE Rate........................................................................................ A3-4 B. Rule 310.01 RE Rate................................................................................... A3-4 C. Rule 316 RE Rate........................................................................................ A3-5 D. Agricultural Activities RE Rate .................................................................. A3-5 E. Title V and Non-Title V RE Rates .............................................................. A3-6 References ............................................................................................................... A3-6 Appendix 3A. Rule Effectiveness Matrix for Rule 310 .......................................... A3-7 Appendix 3B. Rule Effectiveness Matrix for Rule 310.01 ..................................... A3-9 Appendix 3C. Rule Effectiveness Matrix for Rule 316 ........................................ A3-11 Appendix 3D. Rule Effectiveness Matrix for Agricultural Activities .................. A3-13 Appendix 3E. Rule Effectiveness Matrix for Title V Facilities............................ A3-15 Appendix 3F. Rule Effectiveness Matrix for non-Title V Facilities .................... A3-19 Appendix 4 Windblown Dust Emission Estimation Methodology ........................................ A4-1 Introduction ............................................................................................................. A4-1 Meteorological Data................................................................................................ A4-2 Wind Speed ....................................................................................................... A4-3 Precipitation ...................................................................................................... A4-7 Land Use Data......................................................................................................... A4-8 Determination of Emission Rates ........................................................................... A4-9 Estimating Emissions from Harvested Agricultural Areas ................................... A4-12 Summary of Windblown Dust Emissions Estimates ............................................ A4-12 References ............................................................................................................. A4-13 Appendix 5 MOBILE6.2 Inputs, Outputs, and Emission Factors ........................................ A5-1 Table A5–1. Sample of MOBILE6.2 Input Files. .................................................. A5-1 Table A5–2. Sample of MOBILE6.2 Output Files ............................................... .A5-7 Table A5–3. MOBILE6.2 Emission Factors for Maricopa County ..................... A5-14 2008 Maricopa Co. PM10 Emission Inventory x June 2010 1. Introduction 1.1 Overview This 2008 periodic PM10 emissions inventory was developed to meet requirements set forth in Title I of the Clean Air Act Amendments of 1990 (CAAA). The CAAA require development of a baseline emission inventory and periodic revisions for areas that fail to meet the National Ambient Air Quality Standards (NAAQS). A portion of Maricopa County is classified as serious nonattainment for PM10. PM10 is defined as particulate matter less than or equal to ten micrometers in diameter. This inventory includes primary emissions of PM10 and PM2.5 as well as three particulate matter precursors: nitrogen oxides (NOx), sulfur dioxides (SOx) and ammonia (NH3). The inventory provides emission estimates from point, area, nonroad mobile, onroad mobile and biogenic sources. Note that totals shown in tables may not equal the sum of individual values due to independent rounding. 1.2 Agencies responsible for the emissions inventory Maricopa County Air Quality Department (MCAQD) has primary responsibility for preparing and submitting the 2008 Periodic PM10 Emissions Inventory for Maricopa County. Point sources and the majority of area, and nonroad mobile source emission estimates were prepared by MCAQD. The Maricopa Association of Governments (MAG) prepared the emission estimates for onroad mobile, biogenic, and some area and nonroad mobile source categories. Table 1.2–1 lists those responsible for inventory preparation and quality assurance/ quality control activities, which are described in the respective chapters. Table 1.2–1. Chapter authors and QA/QC contacts for this report. Chapter Author(s) QA/QC contacts 2. Point Sources Matt Poppen, MCAQD (602) 506-6790 –Eric Raisanen and Dena Konopka MCAQD (602) 506-6790 3. Area Sources –Matt Poppen, Eric Raisanen and Dena Konopka, MCAQD (602) 506-6790 –Cathy Arthur, MAG (602) 254-6300 –Bob Downing, MCAQD (602) 506-6790 4. Nonroad Mobile Sources –Cathy Arthur, MAG (602) 254-6300 Matt Poppen and Bob Downing MCAQD (602) 506-6790 –Cathy Arthur, MAG (602) 254-6300 –Eric Raisanen and Dena Konopka MCAQD (602) 506-6790 5. Onroad Mobile Sources Ieesuck Jung and Cathy Arthur MAG (602) 254-6300 –Cathy Arthur, MAG (602) 254-6300 Bob Downing and Dena Konopka MCAQD (602) 506-6790 6. Biogenic Sources Feng Liu MAG (602) 254-6300 Bob Downing and Dena Konopka MCAQD (602) 506-6790 2008 Maricopa Co. PM10 Emission Inventory 1 June 2010 1.3 Temporal scope Annual and typical daily emissions were estimated for the year 2008, for Maricopa County and the Maricopa County PM10 nonattainment area (NAA). 1.4 Geographic scope This inventory includes emission estimates for Maricopa County and for the Maricopa County PM10 nonattainment area. Maricopa County encompasses approximately 9,223 square miles of land area, while the Maricopa County PM10 nonattainment area is approximately 2,880 square miles or approximately 31 percent of the Maricopa County land area. A map of Maricopa County and the PM10 nonattainment area is provided in Figure 1.4–1. Figure 1.4–1. Map of Maricopa County and the PM10 nonattainment area. 2008 Maricopa Co. PM10 Emission Inventory 2 June 2010 1.5 Overview of local demographic and land use data Many of the emissions estimates generated in this report were calculated using demographic and land use data provided by the Maricopa Association of Governments (MAG). These data were used to apportion and/or scale Maricopa County emissions estimates to the nonattainment area and vice versa. (For example, county-level emissions from residential natural gas usage in Maricopa County were apportioned to the nonattainment area using the ratio of total population in each area). Detailed explanations of how emission estimates were apportioned or scaled are presented in each of the following chapters, along with the data sources used. 1.5.1 Demographic profile The demographic data provided by MAG included population, employment data, and single family/multi-family splits for calendar year 2008, for both Maricopa County and the PM10 nonattainment area. Table 1.5–1 provides an overview of the demographic data used in this report. As noted throughout the text, these data are frequently used to derive estimates of activity or emissions within the PM10 NAA from county-level calculations. It is important to note, however, that the nonattainment area includes a portion of Pinal County, AZ (Apache Junction) as shown in Figure 1.4–1. Thus in some cases (e.g., those source categories calculated based on total population), the multiplier used to derive nonattainment area estimates from County-level values may be greater than 1, and thus the resulting NAA emission totals are larger than the County-level estimates from which they are derived. Table 1.5–1. Demographic profile of Maricopa County and the PM10 nonattainment area. Maricopa Percent within Demographic variable County PM10 NAA PM10 NAA Total resident population 4,026,000 4,024,530 99.96% Total non-resident population 253,760 272,610 107.43% Total population: 4,279,760 4,297,140 100.41% Retail employment Office employment Industrial employment Public employment Other employment Construction Work at Home Total employment: 537,430 444,170 412,580 278,610 191,770 79,680 65,620 2,009,860 Single Family/Multi-Family Household Split: Single Family 75% Multi-Family 25% 536,100 444,980 411,520 274,500 189,010 78,980 64,940 2,000,030 99.75% 100.18% 99.74% 98.52% 98.56% 99.12% 98.96% 99.51% 75% 25% Source: Maricopa Association of Governments 1.5.2 Land use data MAG provided draft 2009 land use data (as of March 2010). The draft 2009 land use data was assumed to be representative of 2008. Table 1.5–2 presents a summary of the land use categories and acreage used to develop emission estimates for this inventory. 2008 Maricopa Co. PM10 Emission Inventory 3 June 2010 Table 1.5–2. Land use categories used to apportion emissions. Acreage in Maricopa Land Use Category County General/active open space/golf course (e.g., parks) 228,295 Passive/restricted open space (e.g., mountain preserves) 2,373,545 Lakes 12,525 Agriculture 295,509 Vacant (e.g., developable land) 2,227,981 1.6 Emissions overview by source category 1.6.1 Point sources Acreage within PM10 NAA 223,290 302,999 9,510 130,445 472,831 Percentage within PM10 NAA 97.81% 12.77% 75.93% 44.14% 21.22% The point source category includes those stationary sources that emit a significant amount of pollution into the air such as power plants, industrial processes and large manufacturing facilities. MCAQD utilizes the US EPA’s Annual Emissions Reporting Requirements (AERR) Rule to define which stationary sources are listed as point sources. A detailed definition of a point source can be found in Section 2.1 of Chapter 2. Table 1.6–1 summarizes annual and typical daily emissions from point sources in Maricopa County and the PM10 nonattainment area, respectively. A detailed breakdown of emissions calculations for all point sources is contained in Chapter 2. Table 1.6–1. Summary of annual and typical daily emissions from point sources in Maricopa County. Annual (tons/yr) Typical day (lbs/day) Geographic Area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Maricopa County 601.27 555.15 2,206.71 81.15 279.06 3,323.2 3,069.1 12,161.4 449.3 1,534.2 PM10 NAA 149.84 132.94 1,319.65 28.76 132.18 841.2 747.7 7,264.2 158.2 727.0 1.6.2 Area sources Area sources are facilities or activities whose individual emissions do not qualify them as point sources. Area sources represent numerous facilities or activities that individually release small amounts of a given pollutant, but collectively they can release significant amounts of a pollutant. Emissions from stationary sources that were not identified as point sources in this report have been included in the area source inventory. Examples of area source categories include residential wood burning, commercial cooking, waste incineration and wildfires. Tables 1.6–2 and 1.6–3 summarize annual and season-day emissions of the chief area source categories, for Maricopa County and the PM10 nonattainment area, respectively. A detailed breakdown of emissions calculations for each area source category is contained in Chapter 3. Table 1.6–2. Category Summary of annual and typical daily emissions from area sources in Maricopa County. Annual emissions (tons/yr) Typical daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Fuel combustion 1,303.61 1,271.30 12,289.62 898.83 51.27 Industrial processes 14,928.89 3,268.45 362.58 129.60 1,731.34 Waste treatmt./disposal 230.52 204.35 77.47 58.20 1,488.07 Misc. area sources 135,133.31 14,269.99 126.52 32.64 13,059.05 All area sources: 151,596.33 19,014.09 12,856.18 1,119.27 16,329.74 2008 Maricopa Co. PM10 Emission Inventory 4 9,673.4 96,246.9 1,613.0 758,826.5 866,359.8 9,370.0 21,076.1 1,438.8 83,717.8 115,602.7 78,161.3 2,816.5 515.3 1,676.1 83,169.2 5,773.3 328.7 1,005.8 11,077.2 320.0 8,131.5 446.4 71,686.1 7,545.5 91,223.5 June 2010 Table 1.6–3. Category Summary of annual and typical daily emissions from area sources in the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Fuel combustion Industrial processes Waste treatmt./disposal Misc. area sources All area sources: 1.6.3 1,300.65 13,327.74 120.77 26,097.92 40,847.07 1,268.35 12,248.07 895.83 3,047.62 360.48 129.58 95.42 50.30 56.85 3,268.14 115.94 29.74 7,679.53 12,774.79 1,112.00 51.11 1,724.27 1,494.12 7,693.04 10,962.54 9,653.8 85,937.0 799.8 156,539.2 252,929.8 9,350.6 19,656.9 630.5 25,024.8 54,662.7 77,895.2 2,802.3 309.9 2,318.0 83,325.3 5,754.1 327.6 1,005.7 11,034.4 312.6 8,164.6 622.4 42,455.4 7,694.7 61,982.0 Nonroad mobile sources Nonroad mobile sources include off-highway vehicles and engines that move or are moved within a 12-month period. Tables 1.6–4 and 1.6–5 summarize annual and season-day emissions from nonroad mobile sources, for Maricopa County and the PM10 nonattainment area, respectively. A detailed breakdown of emissions calculations for each source category is contained in Chapter 4. Table 1.6–4. Category Annual and typical daily emissions from nonroad mobile sources in Maricopa County. Annual emissions (tons/yr) Typical daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx Agricultural Airport GSE (+APU) Commercial Construction & mining Industrial Lawn and garden Pleasure craft Railway maintenance Recreational equipment Aircraft Locomotives All nonroad mobile sources: Table 1.6–5. Category 33.24 365.55 26.68 586.73 112.98 1,395.23 1,220.75 14,796.63 98.96 2,593.13 168.79 798.14 8.54 77.74 1.10 9.23 41.98 63.80 181.41 2,625.94 65.53 1,854.62 0.14 26.43 2.40 6.60 3.22 3.16 0.85 0.00 0.42 317.64 18.72 0.67 21.12 28.10 56.23 19.63 1.73 0.02 2.10 2,038.46 1,959.95 25,166.75 379.58 NH3 213.1 145.8 724.2 7,825.3 634.4 1,156.9 114.9 7.6 358.8 991.3 358.1 2,343.3 3,206.1 8,943.8 94,850.2 16,622.7 5,571.5 1,046.5 63.9 545.3 14,349.4 10,134.5 0.9 144.4 15.4 42.3 20.6 23.1 11.4 0.0 3.6 1,735.8 102.3 135.4 180.1 360.5 144.6 23.3 0.1 18.0 4.45 219.7 148.7 756.2 8,083.2 651.8 1,250.1 124.5 7.8 389.6 1,026.8 383.6 4.3 134.06 13,042.0 12,530.3 157,677.4 2,099.8 890.6 24.3 Annual and typical daily emissions from all nonroad mobile sources in the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Agricultural Airport GSE (+APU) Commercial Construction & mining Industrial Lawn and garden Pleasure craft Railway maintenance Recreational equipment Aircraft Locomotives All nonroad mobile sources: 1.6.4 34.27 27.21 117.97 1,260.98 101.69 182.28 9.25 1.13 45.58 187.91 70.21 15.13 26.99 117.66 1,249.88 101.42 183.02 7.02 1.13 7.68 183.80 34.16 14.67 161.35 26.48 578.95 112.69 1,391.61 1,210.00 14,666.42 98.71 2,586.39 169.48 801.41 6.48 59.03 1.10 9.26 7.08 10.76 177.60 2,620.31 31.88 907.76 0.06 26.22 2.39 6.55 3.21 3.17 0.64 0.00 0.07 316.00 9.11 0.30 21.06 27.85 56.09 19.71 1.32 0.02 0.35 2.16 97.0 147.5 754.2 8,012.1 650.1 1,255.3 94.5 7.8 65.7 1,004.3 186.7 1,927.89 1,856.17 23,793.26 367.42 128.87 12,275.2 94.0 144.7 722.4 7,756.4 632.7 1,161.6 87.3 7.6 60.5 970.5 174.2 1,034.3 3,163.7 8,920.6 94,015.6 16,579.4 5,594.4 794.6 64.1 91.9 14,318.6 4,960.4 0.4 143.3 15.3 42.0 20.6 23.2 8.6 0.0 0.6 1,726.8 49.8 1.9 135.0 178.5 359.5 145.2 17.7 0.1 3.0 11,811.9 149,537.7 2,030.5 852.9 11.8 Onroad mobile sources Emissions from onroad mobile sources were calculated for the PM10 nonattainment area located primarily within Maricopa County, as well as for Maricopa County as a whole. A detailed breakout of emissions calculations for each area source category is contained in Chapter 5. Tables 1.6–6 and 1.6–7 summarize annual and typical daily emissions from onroad mobile sources in Maricopa County and the PM10 nonattainment area, respectively. 2008 Maricopa Co. PM10 Emission Inventory 5 June 2010 Table 1.6–6. Annual and average daily emissions from all onroad mobile sources in Maricopa County. Emission Category Exhaust, tire wear, and brake wear Paved road fugitive dust Unpaved road and alley fugitive dust Totals: Table 1.6–7. PM10 Annual emissions (tons/year) PM2.5 NOx SOx 1,601.53 18,556.4 12,358.2 32,516.13 NH3 999.17 51,609.08 309.83 3,330.43 617.4 — — — 1,233.6 — — — 2,850.17 51,609.08 309.83 3,330.43 PM10 Average daily emissions (lbs/day) PM2.5 NOx SOx NH3 8,752.0 5,459.7 282,017.2 1,692.6 18,199.0 101,401.2 3,373.8 — — — — 282,017.2 — 1,692.6 — 18,199.0 67,530.9 6,741.0 177,684.1 15,574.5 Annual and typical daily emissions from all onroad mobile sources in the PM10 NAA. Annual emissions (tons/year) Average daily emissions (lbs/day) Emission Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Exhaust, tire wear, and brake wear 1,529.54 954.23 49,142.49 295.90 3,180.66 8,357.7 5,213.8 268,538.4 1,616.4 17,380.4 Paved road fugitive dust 17,245.1 547.9 — — — 94,235.7 2,994.2 — — — Unpaved road and alley fugitive dust 11,710.7 1,169.0 — — — 63,993.1 6,387.8 — — — Totals: 30,485.34 2,671.13 49,142.49 295.90 3,180.66 166,586.5 14,595.8 268,538.4 1,616.4 17,380.4 1.6.5 Biogenic sources The biogenic source category includes emissions from all vegetation (e.g., crops, indigenous vegetation, landscaping, etc.) in Maricopa County and the PM10 nonattainment area. Emissions were estimated using the Model of Emissions of Gases and Aerosols from Nature (MEGAN). MEGAN is a state-of-the-art biogenic emissions model developed by the National Center for Atmospheric Research (NCAR). Some corrections and improvements were made in the latest version of MEGAN2.04. MEGAN2.04 was used to compute biogenic emissions in Maricopa County and the PM10 nonattainment area. Annual and daily NOx emissions from biogenic sources are shown in Table 1.6–8 for Maricopa County and the PM10 nonattainment area. Table 1.6–8. Annual and season-day NOx emissions from biogenic sources. Annual emissions Typical daily emissions Geographic area (tons/yr) (lbs/day) Maricopa County 896.27 4,890.0 PM10 NAA 332.77 1,815.3 1.6.6 Summary of all source categories Tables 1.6–9 and 1.6–10 provide summary totals of annual and typical daily emissions from all emission sources in Maricopa County and the PM10 nonattainment area, respectively. 2008 Maricopa Co. PM10 Emission Inventory 6 June 2010 Table 1.6–9. Annual and typical daily emissions from all sources in Maricopa County. Section Point Sources Area Sources: Fuel combustion Industrial natural gas Industrial fuel oil Comm./ind. natural gas Comm./ind. fuel oil Residential natural gas Residential wood Residential fuel oil All combustion Industrial Processes Chemical manufacturing Food products Commercial cooking Grain handling Ammonia storage Secondary metal prod. Mineral processes (concrete batch, etc.) Mining & quarry (sand & gravel) Wood products Rubber/plastics mfg. Fabricated metal mfg. Residential const. Commercial const. Road construction Construction – other Electric equip. mfg. ADEQ portables Unpaved road travel Industrial proc. NEC All Ind. Processes Waste Treatment/Disp. On-site incineration Open burning Landfills POTWs Other waste All Waste Treat/Disp. PM10 601.27 Annual emissions (tons/yr) PM2.5 NOx SOx 555.15 2,206.71 81.15 Typical daily emissions (lbs/day) PM2.5 NOx SOx 3,069.1 12,161.4 449.3 NH3 279.06 PM10 3,323.2 197.3 2,941.0 426.5 1,436.8 337.5 4,030.8 0.1 9,370.0 3,687.7 40,865.9 8,122.5 20,983.3 4,173.8 325.7 2.3 78,161.3 15.5 3,907.8 33.5 1,738.9 26.6 50.1 0.9 5,773.3 81.4 168.3 26.9 52.1 0.0 2.6 0.9 358.8 142.7 10,759.2 0.0 30.78 458.79 66.54 224.14 61.75 461.59 0.01 1,303.61 30.78 458.79 66.54 224.14 61.75 429.28 0.01 1,271.30 575.29 6,375.08 1,267.11 3,273.40 763.81 34.69 0.25 12,289.62 2.42 609.61 5.23 271.27 4.88 5.34 0.10 898.83 12.70 26.25 4.20 8.13 51.27 197.3 2,941.0 426.5 1,436.8 337.5 4,334.2 0.1 9,673.4 187.43 151.42 0.00 0.34 0.03 1,445.8 1,164.5 988.99 20.59 917.18 6.71 5,434.0 149.3 5,039.5 49.5 60.56 52.16 442.7 386.2 195.81 97.28 1,357.4 671.7 210.39 217.26 140.94 51.48 2,451.72 5,739.18 3,580.67 258.16 13.94 59.00 608.17 144.60 14,928.89 59.56 203.25 105.96 42.62 245.17 573.92 358.07 25.82 9.64 29.50 282.95 107.24 3,268.45 1,442.1 1,668.6 953.3 538.1 15,716.1 36,789.6 22,953.0 1,654.9 76.9 492.9 4,178.8 953.3 96,246.9 390.8 1,548.3 698.8 460.6 1,571.6 3,679.0 2,295.3 165.5 53.2 246.5 1,928.8 726.4 21,076.1 0.06 111.46 86.21 0.7 902.15 486.1 49.73 18.65 1,678.43 0.04 4.50 20.45 282.18 0.18 88.93 31.55 10.22 362.58 21.49 129.60 16.79 1,731.34 0.04 111.46 75.92 5.01 29.96 24.11 0.01 32.78 230.52 16.93 204.35 18.39 77.47 50.62 58.20 470.39 0.51 15.04 30.04 0.18 2,059.00 136.93 1,739.52 17.90 403.43 0.51 15.04 30.04 0.17 308.85 20.54 173.95 5.11 103.79 0.39 1.95 1.20 6.74 28.46 0.11 455.80 0.93 0.01 50.14 0.62 0.01 891.36 336.41 7.57 1,488.07 1,488.07 193.7 69.6 2,816.5 137.7 1,005.8 94.6 11,077.2 0.4 902.15 425.4 38.9 242.37 132.9 0.1 41.7 224.1 1,613.0 110.9 1,438.8 101.0 515.3 278.1 320.0 6,271.8 169.3 82.2 164.1 1.3 22,932.4 3,938.9 11,150.8 103.8 5,379.0 169.3 82.2 164.1 1.2 3,439.9 590.8 1,115.1 29.7 1,383.8 131.2 10.7 6.6 50.5 379.4 36.0 2,490.7 7.0 0.1 274.0 4.7 0.1 4,870.8 1,838.3 1,200.11 66,022.5 6,558.0 4,445.36 112,788.23 135,133.31 446.24 11,278.82 14,269.99 126.52 32.64 13,059.05 24,291.6 616,329.1 758,826.5 All Area Sources: 151,596.33 19,014.09 12,856.18 1,119.27 16,329.74 866,359.8 2008 Maricopa Co. PM10 Emission Inventory 1.58 2,276.43 9,583.89 1,176.93 7 28.9 1.1 721.7 12,082.12 12.39 0.06 2.49 328.7 112.4 2,275.7 Misc. Area Sources Wildfires Prescribed fires Structure fires Vehicle fires Aircraft engine testing Tilling Harvesting Unpaved agric. roads Cotton ginning Fertilizer application Livestock Crematories Accidental releases Humans Leaf blowers fugitive Offroad rec. vehicles fugitive dust Travel on unpaved parking lots Windblown dust All Misc. Area Sources 21.76 0.03 NH3 1,534.2 8,131.5 8,131.5 290.2 10.6 19.0 12,439.5 52,514.5 93.1 0.3 11.9 2,438.5 61,632.9 83,717.8 1,676.1 446.4 71,686.1 115,602.7 83,169.2 7,545.5 91,223.5 6,431.3 June 2010 Table 1.6–9 (continued). Annual and typical daily emissions from all sources in Maricopa County. Section Nonroad Sources: Agricultural equipment Airport GSE (+APU) Commercial equipment Construction and mining equipment Industrial equipment Lawn and garden equipment Pleasure craft Railway maintenance equipment Recreational equipment Aircraft Locomotives All Nonroad Sources Onroad Sources: Exhaust, tire wear, and brake wear Paved road fugitive dust Unpaved road and alley fugitive dust All Mobile Sources: PM10 Annual emissions (tons/yr) PM2.5 NOx SOx PM10 NH3 0.67 213.1 145.8 724.2 2,343.3 3,206.1 8,943.8 0.9 144.4 15.4 135.4 34.27 27.21 117.97 33.24 26.68 112.98 365.55 586.73 1,395.23 0.14 26.43 2.40 21.12 219.7 148.7 756.2 1,260.98 101.69 1,220.75 98.96 14,796.63 2,593.13 6.60 3.22 28.10 56.23 8,083.2 651.8 7,825.3 634.4 94,850.2 16,622.7 42.3 20.6 180.1 360.5 182.28 9.25 168.79 8.54 798.14 77.74 3.16 0.85 19.63 1.73 1,250.1 124.5 1,156.9 114.9 5,571.5 1,046.5 23.1 11.4 144.6 23.3 1.13 45.58 187.91 70.21 2,038.46 1.10 41.98 181.41 65.53 1,959.95 9.23 63.80 2,625.94 1,854.62 25,166.75 0.00 0.42 317.64 18.72 379.58 0.02 2.10 7.6 358.8 991.3 358.1 12,530.3 63.9 545.3 14,349.4 10,134.5 157,677.4 0.0 3.6 1,735.8 102.3 2,099.8 0.1 18.0 4.45 134.06 7.8 389.6 1,026.8 383.6 13,042.0 24.3 890.6 1,601.53 999.17 51,609.08 309.83 3,330.43 8,752.0 5,459.7 282,017.2 1,692.6 18,199.0 18,556.4 617.4 101,401.2 3,373.8 12,358.2 32,516.13 1,233.6 2,850.17 67,530.9 177,684.1 6,741.0 15,574.5 282,017.2 1,692.6 18,199.0 11,787.1 111,847.3 51,609.08 Biogenic Sources: TOTAL, All Sources: Typical daily emissions (lbs/day) PM2.5 NOx SOx NH3 309.83 3,330.43 896.27 186,752.18 24,379.36 91,838.72 2008 Maricopa Co. PM10 Emission Inventory 4.3 4,890.0 1,889.83 8 20,073.28 1,060,409.1 146,776.6 535,025.1 June 2010 Table 1.6–10. Annual and typical daily emissions from all sources in the PM10 nonattainment area. Section Point Sources Area Sources: Fuel combustion Industrial natural gas Industrial fuel oil Comm./ind. natural gas Comm./ind. fuel oil Residential natural gas Residential wood Residential fuel oil All combustion Industrial Processes Chemical manufacturing Food products Commercial cooking Grain handling Ammonia storage Secondary metal prod. Mineral processes (concrete batch, etc.) Mining & quarry (sand & gravel) Wood products Rubber/plastics mfg. Fabricated metal mfg. Residential const. Commercial const. Road construction Construction – other Electric equip. mfg. ADEQ portable sources Unpaved road travel Industrial proc. NEC All Ind. Processes Waste Treatment/Disp. On-site incineration Open burning Landfills POTWs Other waste All Waste Treat/Disp. PM10 149.84 Annual emissions (tons/yr) PM2.5 NOx SOx 132.94 1,319.65 28.76 Typical daily emissions (lbs/day) PM2.5 NOx SOx 747.7 7,264.2 158.2 NH3 132.18 PM10 841.2 196.8 2,933.3 424.4 1,429.5 337.3 4,029.2 0.1 9,350.6 3,678.2 40,759.6 8,081.1 20,876.3 4,172.2 325.6 2.3 77,895.2 15.5 3,897.6 33.3 1,730.0 26.6 50.1 0.9 5,754.1 81.2 167.9 26.8 51.8 0.0 2.6 0.9 358.8 142.7 10,731.2 0.0 30.70 457.60 66.20 223.00 61.73 461.41 0.01 1,300.65 30.70 457.60 66.20 223.00 61.73 429.11 0.01 1,268.35 573.79 6,358.50 1,260.65 3,256.70 763.51 34.67 0.25 12,248.07 2.41 608.03 5.20 269.88 4.87 5.33 0.10 895.83 12.66 26.19 4.18 8.09 51.11 196.8 2,933.3 424.4 1,429.5 337.3 4,332.5 0.1 9,653.8 186.94 151.03 0.00 0.34 0.03 1,442.0 1,161.5 993.04 16.73 920.94 5.68 5,456.3 125.3 5,060.1 43.0 60.56 52.16 442.7 386.2 190.45 93.72 1,320.7 647.9 184.25 216.69 140.57 51.35 2,245.39 5,380.95 2,724.87 215.70 13.94 59.00 511.29 136.00 13,327.74 50.64 202.72 105.68 42.51 224.54 538.10 272.49 21.57 9.64 29.50 227.58 99.12 3,047.62 1,266.6 1,664.3 950.9 536.7 14,465.2 34,382.4 17,471.4 1,385.5 76.9 492.9 3,551.3 906.0 85,937.0 331.9 1,544.3 697.0 459.4 1,446.5 3,438.2 1,747.1 138.6 53.2 246.5 1,573.8 681.7 19,656.9 0.06 27.67 60.25 0.7 232.6 342.4 49.73 18.65 1,674.07 0.04 4.49 20.45 282.18 0.18 88.93 31.55 8.12 360.48 21.47 129.58 14.10 1,724.27 0.04 27.67 50.78 5.01 7.44 19.47 0.01 32.78 120.77 16.93 95.42 18.39 50.30 50.62 56.85 423.56 0.21 15.10 30.16 0.18 834.20 54.14 731.03 4.86 363.27 0.21 15.10 30.16 0.17 125.13 8.12 73.10 1.39 93.46 0.16 1.96 1.21 6.74 25.62 0.04 260.95 0.93 0.01 28.70 0.62 0.01 894.98 337.78 6.22 1,494.12 1,494.12 193.7 55.4 2,802.3 137.6 1,005.7 79.8 11,034.4 0.4 232.6 286.6 38.9 62.5 107.4 0.1 34.3 224.1 799.8 110.9 630.5 101.0 309.9 278.1 312.6 9,412.5 104.0 82.5 164.81 1.3 9,327.3 1,560.0 4,686.1 26.7 8,072.7 104.0 82.5 164.81 1.2 1,399.1 234.0 468.6 7.6 2,076.8 80.6 10.7 6.59 50.5 569.4 22.1 1,426.0 7.0 0.1 156.9 4.6 0.1 4,890.6 1,845.8 200.09 11,006.4 1,093.4 2,368.07 18,468.36 26,100.92 237.45 1,846.84 3,268.14 115.94 29.74 7,693.04 12,923.9 100,920.0 156,539.2 All Area Sources: 40,847.07 7,679.53 12,774.79 1,112.00 10,962.54 252,929.8 2008 Maricopa Co. PM10 Emission Inventory 1.58 1,004.82 5,486.90 1,181.71 9 28.8 1.1 721.7 2,014.17 12.36 0.06 2.49 327.6 112.4 2,275.7 Misc. Area Sources Wildfires Prescribed fires Structure fires Vehicle fires Aircraft engine testing Tilling Harvesting Unpaved agric. roads Cotton ginning Fertilizer application Livestock Crematories Accidental releases Humans Leaf blowers fugitive Offroad rec. vehicles fugitive dust Travel on unpaved parking lots Windblown dust All Misc. Area Sources 19.60 0.01 NH3 727.0 8,164.6 8,164.6 435.5 6.5 19.0 5,490.8 30,065.2 92.6 0.3 11.8 1,297.5 10,092.0 25,024.8 2,318.0 622.4 42,455.4 54,662.7 83,325.3 7,694.7 61,982.0 6,457.5 June 2010 Table 1.6–10 (cont’d). Annual and typical daily emissions from all sources in the PM10 nonattainment area. Section Nonroad Sources: Agricultural equipment Airport GSE (+APU) Commercial equipment Construction and mining equipment Industrial equipment Lawn and garden equipment Pleasure craft Railway maintenance equipment Recreational equipment Aircraft Locomotives All Nonroad Sources: Onroad Sources: Exhaust, tire wear, and brake wear Paved road fugitive dust Unpaved road and alley fugitive dust All Mobile Sources: PM10 Annual emissions (tons/yr) PM2.5 NOx SOx NH3 PM10 15.13 14.67 161.35 0.06 0.30 97.0 94.0 1,034.3 0.4 26.99 26.48 578.95 26.22 147.5 144.7 3,163.7 143.3 117.66 112.69 1,391.61 2.39 21.06 754.2 722.4 8,920.6 15.3 135.0 1,249.88 101.42 1,210.00 98.71 14,666.42 2,586.39 6.55 3.21 27.85 56.09 8,012.1 650.1 7,756.4 632.7 94,015.6 16,579.4 42.0 20.6 178.5 359.5 183.02 7.02 169.48 6.48 801.41 59.03 3.17 0.64 19.71 1.32 1,255.3 94.5 1,161.6 87.3 5,594.4 794.6 23.2 8.6 145.2 17.7 1.13 1.10 9.26 0.00 0.02 7.8 7.6 64.1 0.0 0.1 7.68 183.80 34.16 7.08 177.60 31.88 10.76 2,620.31 907.76 0.07 316.00 9.11 0.35 60.5 970.5 174.2 91.9 14,318.6 4,960.4 0.6 1,726.8 49.8 3.0 2.16 65.7 1,004.3 186.7 11.8 1,927.89 1,856.17 23,793.26 367.42 128.87 12,275.2 11,811.9 149,537.7 2,030.5 852.9 1,529.54 954.23 49,142.49 295.90 3,180.66 8,357.7 5,213.8 268,538.4 1,616.4 17,380.4 17,245.1 547.9 94,235.7 2,994.2 11,710.7 30,485.34 1,169.0 2,671.13 63,993.1 166,586.5 6,387.8 14,595.8 268,538.4 1,616.4 17,380.4 11,499.8 80,942.3 Biogenic Sources: TOTAL, All Sources: 1.7 49,142.49 295.90 3,180.66 Typical daily emissions (lbs/day) PM2.5 NOx SOx 332.77 73,410.15 12,339.77 87,030.19 NH3 1.9 1,815.3 1,804.08 14,404.25 432,632.7 81,818.2 508,665.6 Public review process Maricopa County Air Quality Department released a draft version of this document, its 2008 PM10 emission inventory, for a 30-day public review and comment period on April 26, 2010. (The department’s news release announcing the availability of the draft report, and outlining the schedule for public review and comment, is contained in Appendix 1). The department held a public workshop on May 14, 2010 to discuss the draft inventory. No formal comments were received during the 30-day public comment period. 2008 Maricopa Co. PM10 Emission Inventory 10 June 2010 2. Point Sources 2.1 Introduction and scope This inventory of PM10 and related pollutants is one of a number of emission inventories being prepared to meet US EPA reporting requirements. In addition to preparing periodic emissions inventories for the PM10 nonattainment area (NAA) as a commitment under the current PM10 State Implementation Plan (SIP), the federal Air Emission Reporting Requirements (AERR) rule requires that state and local agencies prepare emissions estimates on a county basis, and submit data electronically to the US EPA for inclusion in the National Emission Inventory (NEI) for 2008. This inventory is being developed concurrently with similar inventories for CO and ozone precursors (VOC, NOx, and CO), as part of Maricopa County's requirements under the respective SIPs. In order to provide consistency among all these inventories, it was decided to standardize the definition of a “point source” by adopting the designation of point sources as outlined in the AERR: We are basing the requirement for point source format reporting on whether the source is major under 40 CFR part 70 for the pollutants for which reporting is required, i.e., CO, VOC, NOx, SO2, PM2.5, PM10, lead and NH3 but without regard to emissions of HAPs…this approach will result in a more stable universe of reporting point sources, which in turn will facilitate elimination of overlaps and gaps in estimating point source emissions, as compared to nonpoint source emissions. Under this requirement, states will know well in advance of the start of the inventory year which sources will need to be reported. (US EPA, 2008) Additionally, EPA guidance requires emission inventories prepared for SIP development purposes to consider point sources with 25 miles of the nonattainment area boundary. No additional point sources met this reporting threshold. Several tables have been constructed to provide the point source emissions and category totals. Table 2.2–1 provides an alphabetical listing of all point sources and their location. Table 2.4–1 shows the 2008 annual and typical day emissions of PM10, PM2.5, NOx, SOx and NH3 for those point sources which reported emissions of one or more of these pollutants broken out by facility. Table 2.6–1 summarizes point source emissions by source category for the county and PM10 nonattainment area. Note that totals shown in the tables may not equal the sum of individual values due to independent rounding. 2.2 Identification of point sources The Maricopa County Air Quality Department (MCAQD) identified point sources within Maricopa County through its electronic permit system database, EMS, and the 2008 annual emissions reports submitted to the department. A total of 25 stationary sources were identified as point sources using the definition described in Section 2.1. There are no additional point sources within the 25-mile boundary around the PM10 nonattainment area with permits issued by the Pinal County Air Quality Control District (PCAQCD). While the Arizona Department of Environmental Quality (ADEQ) retains permitting authority for a limited number of industrial 2008 Maricopa Co. PM10 Emission Inventory 11 June 2010 source categories in Maricopa County, no ADEQ-permitted facilities are considered point sources, and are addressed instead as area sources. Table 2.2–1 contains an alphabetical listing of all point sources, including a unique business identification number, NAICS industry classification code, business name, and physical address. Table 2.2–1. Name and location of all point sources in Maricopa County. ID # NAICS Business name Address 245 337122 AF Lorts Manufacturing Company 8120 W Harrison St 3313 221112 APS West Phx Power Plant 4606 W Hadley St 43063 221112 Dynegy Arlington Valley LLC 39027 W Elliot Rd 44439 221112 Gila River Power Station 1250 E Watermelon Rd 1418 326299 Goodrich Aircraft Interior Products 3414 S 5th St 355 336412 Honeywell-Engines Systems & Services 111 S 34th St 3300 92811 Luke AFB – 56th Fighter Wing 14002 W Marauder St 62 33711 Mastercraft Cabinets Inc 305 S Brooks 44186 221112 Mesquite Generating Station 37625 W Elliot Rd 43530 221112 New Harquahala Generating Co 2530 N 491st Ave 20706 32614 New Wincup Holdings Inc 7980 W Buckeye Rd 1331 337122 Oak Canyon Manufacturing Inc 3021 N 29th Dr 52382 221112 Ocotillo Power Plant 1500 E University Dr 1341 33992 Penn Racquet Sports Inc 306 S 45th Ave 42956 221112 Redhawk Generating Facility 11600 S 363rd Ave 303 332431 Rexam Beverage Can Company 211 N 51st Ave 3315 221112 Santan Generating Station 1005 S Val Vista Rd 4175 424710 SFPP LP Phoenix Terminal 49 N 53rd Ave 3316 221112 SRP Agua Fria Generating Station 7302 W Northern Ave 3317 221112 SRP Kyrene Generating Station 7005 S Kyrene Rd 552 337122 Thornwood Furniture Mfg 5125 E Madison St 1210 337122 Trendwood Inc (S. 15th Ave.) 2402 S 15th Ave 1211 337122 Trendwood Inc (E. University) 261 E University Dr 174 325998 W R Meadows of Az Inc 4220 S Sarival Ave 1382 33711 Woodcase Fine Cabinetry Inc 3255 W Osborn Rd City Tolleson Phoenix Arlington Gila Bend Phoenix Phoenix Glendale Mesa Arlington Tonopah Phoenix Phoenix Tempe Phoenix Arlington Phoenix Gilbert Phoenix Glendale Tempe Phoenix Phoenix Phoenix Goodyear Phoenix ZIP 85353 85043 85322 85337 85040 85034 85309 85202 85322 85354 85043 85017 85281 85043 85322 85043 85296 85043 85303 85283 85034 85007 85004 85338 85017 * * * * * * = Facility is outside the PM10 nonattainment area. 2.3 Procedures for estimating emissions from point sources Annual and typical daily emission estimates were determined from annual source emission reports, MCAQD investigation reports, permit files and logs, or telephone contacts with sources. For most of the sources, material balance methods were used for determining emissions. Emissions were estimated using the emission factors from AP–42, source tests, engineering calculations, or manufacturers' specifications. MCAQD distributes annual emissions survey forms to nearly all facilities for which MCAQD has issued an operating permit. Facilities are required to report detailed information on stacks, control devices, operating schedules, and process-level information concerning their annual activities. (See Appendix 2 for a copy of the instructions to complete the emissions inventory.) These instructions include examples and explanations on how to complete the annual emissions reporting forms that facilities must submit to MCAQD. After a facility has submitted an annual emissions report to MCAQD, emissions inventory staff check all reports for missing and questionable data, and check the accuracy and reasonableness of all emissions calculations with AP–42, the Factor Information and REtrieval (webFIRE) 2008 Maricopa Co. PM10 Emission Inventory 12 June 2010 software, and other EPA documentation. Control efficiencies are determined by source tests when available, or by AP–42 factors, engineering calculations, or manufacturers' specifications. MCAQD has conducted annual emissions surveys for permitted facilities since 1988, and the department's database system, EMS, contains numerous automated quality assurance/quality control checks for data input and processing. 2.3.1 Calculation of PM2.5 emissions For all county-permitted sources that submitted an annual emission inventory report, all processlevel emissions for PM10, NOx, SOx, and NH3 were calculated for each facility. Actual emissions for these pollutants were calculated using reported emission factors (from AP–42 or source test results) and reflecting any control devices installed. PM2.5 was calculated using a variety of methods, depending on the Source Classification Code (SCC) of the process reported: 1. For those SCCs and control device combinations included in EPA’s WebFIRE, this database was used to calculate PM2.5, using EPA-recommended emission factors and typical control efficiencies. 2. For processes with no PM10 controls, emission factors for PM2.5 published by the California Air Resources Board (CARB, 2004) were used where available. 3. For all other processes (where neither of the above resources provided guidance), PM2.5 was assumed equal to PM10 as a conservative estimate. 2.3.2 Application of rule effectiveness Rule effectiveness reflects the actual ability of a regulatory program to achieve the emission reductions required by regulation. The concept of applying rule effectiveness in a SIP emission inventory has evolved from the observation that regulatory programs may be less than 100 percent effective for some source categories. Rule effectiveness (“RE”) is applied to those sources affected by a regulation and for which emissions are determined by means of emission factors and control efficiency estimates. MCAQD has estimated RE for three distinct groups of industrial processes. (See Appendix 3 for details on the methods and data used in computing RE rates): • For manually controlled processes that are regulated under Maricopa County Rule 316 (Nonmetallic Mineral Processing), the analysis showed an overall rule effectiveness of 49.62%. • For most other processes that claimed emissions reductions through the use of a control device, RE calculations were performed separately for Title V and non-Title V sources. Overall RE values of 90.94% (for Title V processes) and 84.27% (for non-Title V) were calculated. 2.4 Detailed overview of point source emissions Table 2.4–1 provides a summary of annual and typical daily emissions from all point sources, within and outside the PM10 nonattainment area. Sources for which rule effectiveness has been applied (for PM10 emissions) are noted. Values of “0.00” and “0.0” for annual and daily emissions denote a value below the level of significance (0.005 tons/yr and 0.05 lbs/day, respectively). 2008 Maricopa Co. PM10 Emission Inventory 13 June 2010 Table 2.4–1. ID # 245 3313 43063 44439 1418 355 3300 62 44186 43530 20706 1331 52382 1341 42956 303 3315 4175 3316 3317 552 1210 1211 174 1382 Annual and typical daily point source emissions, by facility. Business name AF Lorts Manufacturing Company APS West Phx Power Plant Dynegy Arlington Valley LLC Gila River Power Station Goodrich Aircraft Interior Products Honeywell-Engines Systems & Srvs. Luke AFB – 56th Fighter Wing Mastercraft Cabinets Inc Mesquite Generating Station New Harquahala Generating Co New Wincup Holdings Inc Oak Canyon Manufacturing Inc Ocotillo Power Plant Penn Racquet Sports Inc Redhawk Generating Facility Rexam Beverage Can Company Santan Generating Station SFPP LP Phoenix Terminal SRP Agua Fria Generating Station SRP Kyrene Generating Station Thornwood Furniture Mfg Trendwood Inc (S. 15th Ave.) Trendwood Inc (E. University) W R Meadows of Az Inc Woodcase Fine Cabinetry Inc * †* † * * † † * † * * PM10 2.69 22.94 6.40 99.50 0.16 3.17 0.60 0.18 152.65 116.35 0.94 0.01 8.37 1.74 76.53 0.33 51.88 0.63 25.21 26.24 2.66 0.05 0.01 0.01 0.23 Annual emissions (tons/yr) PM2.5 NOx SOx 2.68 0.01 0.00 19.47 394.24 4.51 3.58 35.50 2.20 92.13 343.01 17.36 0.16 0.42 0.00 3.16 51.42 9.91 0.59 7.15 0.15 0.14 0.04 0.00 144.01 243.09 17.12 116.11 86.29 6.46 0.94 12.42 0.07 0.00 0.00 0.00 6.48 64.45 0.29 1.74 3.51 0.02 66.38 179.16 9.25 0.33 4.39 0.03 50.33 313.85 10.59 0.61 4.96 0.24 18.01 392.20 0.58 25.64 60.60 2.19 2.42 0.10 0.00 0.05 0.00 0.00 0.01 0.00 0.00 0.01 0.12 0.00 0.18 0.00 0.00 NH3 0.00 81.39 5.38 5.77 0.01 0.65 0.02 0.00 15.56 93.52 0.40 0.00 1.67 0.11 26.65 0.14 35.55 0.00 3.67 8.56 0.00 0.00 0.00 0.00 0.00 PM10 20.7 126.0 36.5 546.9 1.5 17.7 3.7 1.4 838.8 639.3 5.2 0.0 46.0 13.4 420.5 1.8 285.1 3.5 138.5 144.2 20.5 0.4 0.1 0.1 1.8 Typical daily (lbs/day) PM2.5 NOx SOx 20.6 0.1 0.0 107.0 2,166.1 24.8 20.9 214.4 15.2 506.4 1,887.5 95.4 1.5 3.2 0.0 17.6 282.5 54.5 3.7 43.1 1.0 1.1 0.3 0.0 791.3 1,336.4 94.1 638.0 474.1 35.5 5.2 68.3 0.4 0.0 0.0 0.0 35.6 354.1 1.6 13.4 27.0 0.2 364.7 984.8 50.9 1.8 24.1 0.1 276.5 1,724.4 58.2 3.3 27.2 1.3 98.9 2,154.9 3.2 140.9 333.0 12.1 18.6 0.8 0.0 0.4 0.0 0.0 0.0 0.0 0.0 0.1 1.5 0.0 1.4 0.0 0.0 NH3 0.0 447.2 29.6 31.8 0.1 4.0 0.1 0.0 85.5 513.9 2.2 0.0 9.2 0.9 146.4 0.8 195.3 0.0 20.1 47.0 0.0 0.0 0.0 0.0 0.0 † = Facility is outside the PM10 nonattainment area. * = Facility for which rule effectiveness has been applied. 2.5 Emission reduction credits A major source or major modification planned in a nonattainment area must obtain emissions reductions as a condition for approval. These emissions reductions, generally obtained from existing sources located in the vicinity of a proposed source must offset the emissions increase from the new source or modification. The obvious purpose of acquiring offsetting emissions decreases is to allow an area to move towards attainment of the national ambient air quality standards while still allowing some industrial growth. In order for these emission reductions to be available in the future for offsetting, they must be: 1) explicitly included and quantified as growth in projection year inventories required in rate of progress plans or attainment demonstrations that were based on 1990 actual inventories, and 2) meet the requirements outlined in MCAQD Rule 240 (Permit Requirements for New Major Sources and Major Modification to Existing Major Sources). Table 2.5–1 provides a list of emission reduction credits for PM10, NOx, and SOx. Only one previously operational facility maintains emission reduction credits that are still valid for inclusion in this report and the rate of progress plan. Table 2.5–1. Emission reduction credits. Emission reduction credits (tons/yr) ID 1151 Facility Freescale Semiconductor, Inc. (formerly Motorola Mesa) 2008 Maricopa Co. PM10 Emission Inventory 14 PM10 NOx SOx 1.80 9.80 0.16 June 2010 2.6 Summary of point source emissions Table 2.6–1 provides an overview of source category contributions to point source emissions for Maricopa County and the PM10 nonattainment area. Table 2.6–1. Annual and typical daily point source emissions (including emission reduction credits). Annual (tons/yr) Typical day (lbs/day) Geographic Area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Maricopa County 599.47 555.15 2,196.91 80.99 279.06 3,313.4 3,069.1 12,107.8 448.4 1,534.2 PM10 NAA 148.04 132.94 1,309.85 28.60 132.18 831.4 747.7 7,210.6 157.3 727.0 2.7 Quality assurance / quality control procedures 2.7.1 Emission survey preparation and data collection The MCAQD's Emissions Inventory (EI) Unit annually collects point source criteria pollutant emission data from sources in the county. MCAQD annually reviews EPA guidance, documents from the Emission Inventory Improvement Program (EIIP), and other source materials to ensure that the most current emission factors and emission calculation methods are used for each year's survey. Each January, the EI Unit prepares a pre-populated hard copy of the preceding year’s submissions and mails reporting forms to permitted sources, along with detailed instructions for completing the forms. (A copy of these instructions is included as Appendix 2). The EI Unit asks sources to verify and update the data. The EI Unit also holds workshops from February through April to assist businesses in completing EI forms. The general data flow for data collection and inventory preparation is shown in Figure 2.7–1. 2008 Maricopa Co. PM10 Emission Inventory 15 June 2010 Figure 2.7–1. Data flow for annual point source emission inventory reporting. EI Reporting Forms • • Hard Copy Forms/ Instructions Instruction on Web EI Reporting Forms Log In EI reports/ Issue Receipts Issue NOVs for late submitters • • • Data Entry EMS Code/field check Range checks Referential value checks Create Inventory files Automated QA checks Technical QA/ QC Using completed survey data Finalized Inventory Data Reconciliation 2.7.2 Submission processing Submitted EI reports are logged in as they are received, and receipts are issued for emissions fees paid. The data are input “as received” into the department's data base. During data entry, a variety of automated quality control (QC) checks are performed, including: • • • • • pull-down menus to minimize data entry errors (e.g., city, pollutant, emission factor unit, etc.) mandatory data field requirement checks (e.g., a warning screen appears if a user tries to save an emission record with a missing emission factor). range checks (e.g., were valid SCC, Tier, SIC, and NAICS codes entered?) referential value checks (e.g., emission factor units, annual throughput units) automatic formatting of date, time, telephone number fields, etc. Automated quality assurance (QA) checks on the report that has been entered include the following: • • Comparing reported emission factors to SCC reference lists Comparing reported emission factors to material name reference list 2008 Maricopa Co. PM10 Emission Inventory 16 June 2010 • • Checking the report for calculation errors. This includes annual throughput, emission factors, unit conversion factors (e.g., BTU to therms), capture efficiency, primary / secondary control device efficiency, and any offsite recycling credits claimed. Checking the report for completeness of required data. When data entry is complete, an electronic version of the original data is preserved separately to document changes made during the technical review and QA/QC process. When errors are flagged, the businesses are contacted and correct information is obtained and input to the EMS. Outstanding reporting issues are documented. Confidential business information (CBI) is identified by a checkbox on the form, and these data elements are flagged during data entry and are not transmitted to the EPA. To prepare the inventory for submittal to the National Emissions Inventory (NEI), the EI Unit runs Microsoft Access queries on the data in the EMS to pull fields for the NEI Input format (NIF) tables. 2.7.3 Analysis of annual point source emissions data for this inventory Two air quality planners checked inventory accuracy and reasonableness, and assured that all point sources had been identified and that the methodology applied to calculate emissions was appropriate and that the calculations were correct. Other reasonableness checks were conducted by recalculating emissions using methods other than those used to make the initial emissions calculations and then comparing results. QA was conducted by checking all emissions reports submitted to MCAQD for the year 2008 for missing and questionable data and by checking the accuracy and reasonableness of all emissions calculations made for such reports. Notes concerning follow-up calls and corrections to calculations were documented on each 2008 annual emissions report. The QA point source coordinator reviewed and checked calculations, identified errors, and performed completeness, reasonableness and accuracy checks. 2.8 References CARB, 2004. Speciation Profiles and Size Fractions. Available at: http://www.arb.ca.gov/ei/ speciate/speciate.htm. US EPA, 2008. Air Emissions Reporting Requirements. 73 Fed. Reg. 76539. Available at: http://www.epa.gov/ttn/chief/aerr/final_published_aerr.pdf. 2008 Maricopa Co. PM10 Emission Inventory 17 June 2010 This page intentionally blank. 2008 Maricopa Co. PM10 Emission Inventory 18 June 2010 3. Area Sources 3.1 Scope and methodology This chapter considers all stationary sources which are too small or too numerous to be treated as point sources. EPA guidance documents, including “Introduction to Area Source Inventory Development” (US EPA, 2001a) as well as permit and emissions data in the MCAQD’s Environmental Management System (EMS) database, and previous SIP inventories, were evaluated to develop the list of area-source categories for inclusion. Some source categories were deemed “insignificant” because there are no large production facilities and/or very few small sources, and therefore emissions were not quantified. MCAQD prepared the area-source emission estimates for all area sources and provided quality assurance checks on all data. Table 3.1–1 contains a list of all area-source categories, with Source Classification Codes (SCCs), addressed in this chapter. Table 3.1–1. List of area-source categories included in this PM10 inventory. SCC Code Category Description Section Fuel combustion: 2102006000 Industrial natural gas 3.2.1 2102004000 Industrial fuel oil 3.2.2 2103006000 Commercial/institutional natural gas 3.2.3 2103004000 Commercial/institutional fuel oil 3.2.4 2104006000 Residential natural gas 3.2.5 2104008000 Residential wood 3.2.6 2104004000 Residential fuel oil 3.2.7 2301010000 2302002000 2302040000 2302080000 2304000000 2305000000 2325000000 2307000000 2308000000 2309000000 2311010000 2311020000 2311030000 n/a 2312000000 n/a n/a 2399000000 Industrial processes: Chemical manufacturing Commercial cooking Grain handling/processing Ammonia cold storage Secondary metal production Non-metallic mineral processes Mining and quarrying Wood product manufacturing Rubber/plastics manufacturing Fabricated metal products manufacturing Residential construction Commercial construction Road construction Other construction Electrical equipment manufacturing State-permitted portable sources Paved/unpaved road travel on industrial sites Industrial processes not elsewhere classified (NEC) 3.3.1 3.3.2.1 3.3.2.2 3.3.2.3 3.3.3 3.3.4 3.3.5 3.3.6 3.3.7 3.3.8 3.3.9 3.3.9 3.3.9 3.3.9 3.3.10 3.3.11 3.3.12 3.3.13 2601000000 2610000000 2620000000 2630000000 2650000000 Waste treatment and disposal: On-site incineration Open burning Landfills Publicly owned treatment works (POTWs) Other industrial waste disposal 3.4.1 3.4.2 3.4.3 3.4.4 3.4.5 2810001000 2810014000 Miscellaneous area sources: Wildfires Prescribed fires 3.5.1.1 3.5.1.2 2008 Maricopa Co. PM10 Emission Inventory 19 June 2010 Table 3.1–1. (continued) List of area-source categories. SCC Code Category Description Miscellaneous area sources: (continued) 2810030000 Structure fires 2810050000 Vehicle fires 2810040000 Engine testing 2801000003 Tilling 2801000005 Harvesting n/a Travel on unpaved agricultural roads 2801000000 Cotton ginning 2801700000 Fertilizer application 2810060000 Livestock 2810060000 Health services: crematories 2830000000 Accidental releases 2810010000 Humans n/a Leaf blower fugitive dust n/a Offroad recreational vehicle fugitive dust n/a Unpaved parking lots fugitive dust 2730100000 Windblown dust Section 3.5.1.3 3.5.1.4 3.5.1.5 3.5.2.1 3.5.2.2 3.5.2.3 3.5.2.4 3.5.2.5 3.5.3 3.5.4 3.5.5 3.5.6 3.5.7 3.5.8 3.5.9 3.5.10 For nearly all categories, emissions were calculated in one of the following ways: • Emissions estimates for some categories were developed by conducting surveys on local usage (e.g., natural gas consumption) or derived from state-wide data (e.g., fuel oil use). • For some widespread or diverse categories (e.g., ammonia cold storage), emissions were calculated using published per-capita or per-employee emission factors. • For source categories with some information available from annual emissions reports (e.g., wood product manufacturing), these data were combined with employment data to “scale up” reported emissions to reflect the entire source category. • For those source categories that have detailed emissions data available from most or all of the significant sources in the category, emissions were calculated based on the detailed process-level and operational data provided by these sources. The specific emissions estimation methodologies used for each source category (including the derivation and application of rule effectiveness) are described in greater detail in the respective sections. 3.2 Fuel combustion Area-source emissions for the following seven categories of fuel consumption were calculated: Industrial natural gas, industrial fuel oil, commercial/institutional natural gas, commercial/ institutional fuel oil, residential natural gas, residential wood, and residential fuel oil. Data for emissions calculations from natural gas combustion came from a survey of the three natural gas suppliers in Maricopa County. Table 3.2–1 summarizes the natural gas sales data received from Maricopa County natural gas suppliers. Table 3.2–1. Maricopa County natural gas sales data by supply company and end-user category. Sales by end user category (in MMCF/yr) Electric Commercial/ Natural gas Utilities Industrial Institutional Residential Transport* Other* supplier Southwest Gas 17.07 1,543.27 15,643.15 14,911.67 6,487.35 n/a City of Mesa 6.52 93.02 1,609.12 1,339.62 n/a 244.97 El Paso 227,608.92 201.90 n/a n/a n/a 6.07 * For emissions calculations, sales from transport and other were grouped with industrial sales. 2008 Maricopa Co. PM10 Emission Inventory 20 June 2010 Area-source emissions for wood and fuel oil combustion were calculated from Arizona statelevel sales and consumption data as described in the following subsections. Area-source emissions from coal and liquid petroleum gas were not calculated, as emissions from these categories were determined to be insignificant. 3.2.1 Industrial natural gas All natural gas suppliers in Maricopa County were surveyed to gather information on the volume of natural gas distributed, by user category, within the county in 2008. Area-source industrial natural gas usage for the county is based on the reported total volume of natural gas sold to industrial sources, minus natural gas used by industrial point sources: County area-source industrial natural gas usage = Total reported industrial natural gas sales – Industrial point source natural gas usage = 8,576.57 MMCF – 516.15 MMCF = 8,060.43 MMCF Natural gas is used for both external combustions (boilers and heaters) and internal combustion (generators), each of which have different emission factors. Thus the area-source natural gas usage derived above must be divided between these two categories. This apportionment was based on the percentages of external and internal natural gas combustion reported by all industrial area sources in 2008. Annual emissions for the county and the PM10 nonattainment area were calculated by multiplying natural gas usage by the respective AP-42 emission factors for external and internal combustion, as in this example for PM10 emissions from external natural gas combustion: PM10 emissions from external natural gas combustion = External industrial natural × PM10 emission factor for ÷ 2,000 lbs/ton gas usage (MMCF) external natural gas combustion (lb/MMCF) = 7,934.68 × 7.6 ÷ 2,000 = 30.78 tons PM10/yr Table 3.2–2. Natural gas usage, emission factors, and annual emissions from area-source industrial natural gas combustion, by combustion type. Emission factors (lb/MMCF) Annual emissions (tons/yr) Type of % of Natural gas Combustion total use (MMCF) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 External 98.44 7,934.68 7.6 7.6 100 0.6 3.2 30.15 30.15 396.73 2.38 12.70 Internal 1.56 125.74 10.0 10.0 2840 0.6 n/a 0.63 0.63 178.55 0.04 n/a Total: 100.00 8,060.43 30.78 30.78 575.29 2.42 12.70 Typical daily emissions for the county were calculated by dividing annual emissions by the number of days that activity occurs throughout the year: Typical daily PM10 emissions from industrial natural gas (lbs/day) = Annual PM10 emissions ÷ (days/week × wks/yr) × 2,000 lbs/ton = 30.78 tons/yr ÷ (6 × 52) × 2,000 = 197.3 lbs PM10/day 2008 Maricopa Co. PM10 Emission Inventory 21 June 2010 Annual and typical daily emissions within the PM10 nonattainment area were calculated by applying the ratio of industrial employment in the nonattainment area to county-level emission calculations. (See Section 1.5.1 for a discussion of the employment data used). Emissions from area-source industrial natural gas combustion = Annual county PM10 × NAA:County industrial employment ratio emissions (tons/yr) in the PM10 NAA = 30.78 × 0.9974 = 30.70 tons PM10/yr Table 3.2–3. Annual and typical daily emissions from area-source industrial natural gas combustion. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Maricopa County 30.78 30.78 575.29 2.42 12.70 197.3 197.3 3,687.7 15.5 81.4 PM10 NAA 30.70 30.70 573.79 2.41 12.66 196.8 196.8 3,678.2 15.5 81.2 3.2.2 Industrial fuel oil Area-source emissions from industrial fuel oil combustion were calculated by a multi-step process which allocates Arizona state-level industrial fuel oil sales as reported by the U.S. Department of Energy, Energy Information Administration (US DOE, 2010a) to Maricopa County. To derive industrial fuel oil usage in Maricopa County, reported Arizona state-level sales of high-sulfur diesel for 2008 are first subtracted from Arizona state-level total industrial fuel oil sales, as it is presumed that no high-sulfur diesel fuel is used in Maricopa County due to local air quality regulations and market conditions. State industrial fuel oil sales other than high-sulfur diesel (in thousand gallons, or Mgal) = Reported state total – Reported state high-sulfur diesel sales industrial fuel oil sales = 137,044 Mgal – 224 Mgal = 136,820 Mgal/yr Arizona state industrial fuel oil sales (less high-sulfur diesel fuel) are then multiplied by the ratio of industrial employment in Maricopa County to Arizona State (0.70), as determined by data from the US Census Bureau (2010a) to estimate annual Maricopa County-level industrial fuel oil sales, as follows: Maricopa County = Arizona state industrial fuel × Maricopa County:State industrial fuel oil sales oil sales less high-sulfur diesel industrial employment ratio = 136,820 Mgal × 0.7007 = 95,869.77 Mgal/yr To avoid double-counting, industrial fuel oil use attributable to stationary point sources (addressed in Chapter 2) and nonroad mobile sources (addressed in Chapter 4) are subtracted from County industrial fuel oil sales to estimate county fuel oil usage by area sources: 2008 Maricopa Co. PM10 Emission Inventory 22 June 2010 Maricopa County area = Maricopa County – Fuel oil used by industrial – Fuel oil used by industrial source fuel oil sales industrial fuel oil sales nonroad mobile equipment stationary point sources = 95,869.77 Mgal – 11,596.87 Mgal – 136.82 Mgal = 84,136.09 Mgal/yr Industrial fuel oil is used for both external combustions (boilers, heaters) and internal combustion (generators), each of which have different emission factors. Thus the area-source industrial fuel oil sales derived above must be apportioned between these two categories. This apportionment was based on the percentages of external and internal fuel oil combustion reported by all industrial area sources surveyed in 2008 (shown in Table 3.2–4 below). Annual emissions for the county and the PM10 nonattainment area were calculated by multiplying industrial fuel oil sales by the respective AP-42 emission factors for external and internal combustion, as in this example for PM10 emissions from external fuel oil combustion: Annual PM10 emissions = External industrial fuel from external industrial oil sales (Mgal) fuel oil combustion = 65,634.56 × PM10 emission factor for external ÷ 2,000 lbs/ton fuel oil combustion (lb/Mgal) × 2 ÷ 2,000 = 65.63 tons PM10/yr Table 3.2–4. Emission factors and annual emissions from area-source industrial fuel oil combustion, by combustion type. Emission factors (lb/Mgal) Annual emissions (tons/yr) Annual Combustion % of sales type total (Mgal) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 External 78.01 65,634.56 2.0 2.0 24 7.39 0.8 65.63 65.63 787.61 242.36 26.25 Internal 21.99 18,501.53 42.5 42.5 604 39.70 – 393.16 393.16 5,587.46 367.26 n/a Totals: 100.00 84,136.09 458.79 458.79 6,375.08 609.61 26.25 Typical daily emissions for the county were calculated by dividing annual emissions by the number of days during which activity occurs throughout the year, as recommended by EIIP guidance (US EPA, 2001a): Typical daily PM10 emissions from industrial fuel oil = Annual PM10 emissions (tons/yr) ÷ (days/week × wks/yr) × 2,000 lbs/ton = 458.79 ÷ (6 × 52) × 2,000 = 2,941.0 lbs PM10/day Annual and typical daily emissions in the PM10 nonattainment area were calculated by applying the ratio of industrial employment in the nonattainment area to county-level emission calculations. (See Section 1.5.1 for a discussion of the employment data used). PM10 NAA emissions from area source industrial fuel oil combustion = Annual county PM10 emissions × NAA:County industrial employment ratio = 458.79 tons/yr × 0.9974 = 457.60 tons PM10/yr 2008 Maricopa Co. PM10 Emission Inventory 23 June 2010 Table 3.2–5. Annual and typical daily emissions from area-source industrial fuel oil combustion. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Maricopa County 458.79 458.79 6,375.08 609.61 26.25 2,941.0 2,941.0 40,865.9 3,907.8 168.3 PM10 NAA 457.60 457.60 6,358.50 608.03 26.19 2,933.3 2,933.3 40,759.6 3,897.6 167.9 3.2.3 Commercial/institutional natural gas All natural gas suppliers in Maricopa County were surveyed to gather information on the volume of natural gas distributed, by user category, within the county in 2008. Area-source commercial and institutional (C&I) natural gas usage for the county is based on the reported total volume of natural gas sold to C&I sources, minus natural gas used by C&I point sources: County area-source C&I = Reported C&I natural gas sales natural gas usage = 17,503.31 MMCF – C&I point source natural gas usage – 84.08 MMCF = 17,419.23 MMCF Natural gas is used for both external combustion (boilers, heaters) and internal combustion (generators), each of which have different emission factors. Thus the area-source natural gas usage derived above must be apportioned between these two categories. This apportionment was based on the percentages of external and internal natural gas combustion reported by all C&I area sources in 2008. Annual emissions for the county were calculated by multiplying natural gas usage by the respective AP-42 emission factors for external and internal combustion, as in this example for PM10 emissions from external natural gas combustion: Annual PM10 emissions = External C&I natural from external natural gas gas usage (MMCF) combustion = 17,130.07 × PM10 emission factor for ÷ 2,000 lbs/ton external natural gas combustion (lb/MMCF) × 7.6 ÷ 2,000 = 65.09 tons PM10/yr Table 3.2–6. Emission factors and annual emissions from area-source commercial/institutional natural gas combustion, by combustion type. C&I natural Emission factors (lb/MMCF) Annual emissions (tons/yr) Combustion % of gas usage type total (MMCF) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 External 98.34 17,130.07 7.6 7.6 100 0.6 0.49 65.09 65.09 856.50 5.14 4.20 Internal 1.66 289.16 10.0 10.0 2840 0.6 n/a 1.45 1.45 410.61 0.09 n/a Total: 100.00 17,419.23 66.54 66.54 1,267.11 5.23 4.20 Typical daily emissions for the county were calculated by dividing annual emissions by the number of days that activity occurs throughout the year: Typical daily PM10 emissions from comm./inst. natural gas = Annual PM10 emissions ÷ (days/week × wks/yr) (tons/yr) = 66.54 ÷ (6 × 52) × 2,000 lbs/ton × 2,000 = 426.54 lbs/day 2008 Maricopa Co. PM10 Emission Inventory 24 June 2010 Annual and typical daily emissions within the PM10 nonattainment area were calculated by applying the combined ratio of retail, office, public and other employment in the nonattainment area to county-level emission calculations. (See Section 1.5.1 for a discussion of the employment data used). PM10 NAA emissions from area-source = Annual county PM10 emissions × NAA:County C&I employment ratio comm./inst. natural gas combustion (tons/yr) = 66.54 × 0.9949 = 66.20 tons PM10/yr Table 3.2–7. combustion. Annual and typical daily emissions from area-source commercial/institutional natural gas Geographic area Maricopa County PM10 NAA 3.2.4 PM10 66.54 66.20 Annual emissions (tons/yr) PM2.5 NOx SOx 66.54 1,267.11 5.23 66.20 1,260.65 5.20 NH3 4.20 4.18 Typical daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 426.5 426.5 8,122.5 33.5 26.9 424.4 424.4 8,081.1 33.3 26.8 Commercial/institutional fuel oil Area-source emissions from commercial and institutional (C&I) fuel oil combustion were calculated by a multi-step process of allocating Arizona state-level C&I fuel oil sales as reported by the U.S. Department of Energy, Energy Information Administration (US DOE, 2010b) to Maricopa County. To derive commercial/institutional fuel oil usage in Maricopa County, reported Arizona statelevel sales of high-sulfur diesel for 2008 are first subtracted from Arizona state-level total C&I fuel oil sales, as it is presumed that no high-sulfur diesel fuel is used in Maricopa County due to local clean air act requirements and market conditions. State C&I fuel oil sales other than high-sulfur diesel (in thousand gallons, or Mgal) = Reported state total C&I fuel oil sales – Reported state high-sulfur diesel sales = 47,586 Mgal – 367 Mgal = 47,219 Mgal/yr Arizona state commercial/institutional fuel oil sales (less high-sulfur diesel fuel) are then multiplied by the ratio of C&I employment in Maricopa County to Arizona state (0.80), as determined by data from the US Census Bureau (2010a) to estimate annual Maricopa Countylevel commercial/institutional fuel oil sales, as follows: Maricopa County C&I fuel oil sales = Arizona state C&I fuel oil sales (less high-sulfur diesel) × Maricopa County:state commercial/ institutional employment ratio = 47,219 Mgal × 0.7973 = 37,647.71 Mgal/yr To avoid double-counting, C&I fuel oil use attributable to stationary point sources (addressed in Chapter 2) and nonroad mobile sources (addressed in Chapter 4) are subtracted from County C&I fuel oil sales to estimate county fuel oil usage used by area sources: 2008 Maricopa Co. PM10 Emission Inventory 25 June 2010 Annual Maricopa County commercial/institutional area-source fuel oil sales = Maricopa County C&I fuel oil sales – Fuel oil used by C&I – Fuel oil used by C&I nonroad mobile equipment stationary point sources = 37,647.71 Mgal – 7,291.00 Mgal – 3.94 Mgal = 30,352.78 Mgal/yr Fuel oil is used for both external combustions (boilers, heaters) and internal combustion (generators), each of which have different emission factors. Thus the area-source C&I fuel oil sales derived above must be apportioned between these two categories. This apportionment was based on the percentages of external and internal fuel oil combustion reported by all commercial and institutional area sources surveyed in 2008 (shown in Table 3.2–8 below). Annual emissions for the county were calculated by multiplying comm./inst. fuel oil sales by the respective AP-42 emission factors for external and internal combustion, as in this example for PM10 emissions from external fuel oil combustion: Annual PM10 emissions from = External C&I fuel oil external fuel oil combustion sales (Mgal) = 20,321.18 × PM10 emission factor for external fuel oil combustion (lb/Mgal) ÷ 2,000 lbs/ton × 1.08 ÷ 2,000 = 10.97 tons PM10/yr Table 3.2–8. Emission factors and annual emissions from area-source commercial/institutional fuel oil combustion, by combustion type. Emission factors (lb/Mgal) Annual emissions (tons/yr) Combustion % of C&I fuel oil NOx SOx NH3 type total sales (Mgal) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 External 66.95 20,321.18 1.08 1.08 24 7.1 0.8 10.97 10.97 243.85 72.14 8.13 Internal 33.05 10,031.59 42.5 42.5 604 39.7 n/a 213.17 213.17 3,029.54 199.13 n/a Total: 100.00 30,352.78 224.14 224.14 3,273.40 271.27 8.13 Typical daily emissions for the county were calculated by dividing annual emissions by the number of days activity occurs throughout the year, as recommended by EIIP guidance (US EPA, 2001a): Typical daily PM10 emissions = Annual PM10 emissions from C&I fuel oil combustion (tons/yr) ÷ (days/week × wks/yr) × 2,000 lbs/ton = 224.14 ÷ (6 × 52) × 2,000 = 1,436.8 lbs/day Annual and typical daily emissions within the PM10 nonattainment area were calculated by applying the combined ratio of retail, public, office and other employment in the nonattainment area to county-level emission calculations. (See Section 1.5.1 for a discussion of the employment data used). PM10 NAA emissions from area source C&I fuel oil combustion = Annual county PM10 × NAA:County C&I employment ratio emissions (tons/yr) = 224.14 × 0.9949 = 223.00 tons PM10/yr 2008 Maricopa Co. PM10 Emission Inventory 26 June 2010 Table 3.2–9. combustion. Annual and typical daily emissions from area-source commercial/institutional fuel oil Geographic area Maricopa County PM10 NAA 3.2.5 PM10 224.14 223.00 Annual emissions (tons/yr) PM2.5 NOx SOx 224.14 3,273.40 271.27 223.00 3,256.70 269.88 NH3 8.13 8.09 Typical daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 1,436.8 1,436.8 20,983.3 1,738.9 52.1 1,429.5 1,429.5 20,876.3 1,730.0 51.8 Residential natural gas All natural gas suppliers in Maricopa County were surveyed to gather information on the volume of natural gas sold, by user category, within the county. Annual emissions from residential natural gas combustion emissions were calculated by multiplying residential natural gas sales by emission factors for residential natural gas combustion summarized in the table below (US EPA, 1998a), as follows: Table 3.2–10. Residential natural gas combustion emission factors. Emission Factors (lb/MMCF) PM10 PM2.5 NOx SOx 7.6 7.6 94 0.6 Annual PM10 emissions from residential natural gas combustion = Annual sales of residential natural gas (MMCF) × PM10 emission factor for ÷ 2,000 lbs/ton residential natural gas (lbs/MMCF) = 16,251.29 × 7.6 ÷ 2,000 = 61.75 tons PM10/yr Typical daily emissions were calculated by dividing annual emissions by the number of days (366) that activity occurs for residential natural gas combustion, as follows: Typical daily PM10 emissions from residential natural gas combustion = Annual PM10 emissions × 2,000 lbs/ton ÷ days/yr = 61.75 tons/yr ÷ 366 × 2, 000 = 337.4 lbs PM10/day Annual and typical daily residential natural gas emissions in the PM10 nonattainment area were calculated by multiplying county-level emissions by the percentage of total residential population in the PM10 nonattainment area as follows: Annual PM10 emissions = Annual PM10 emissions from residential natural gas in Maricopa County combustion in the NAA = 61.75 × % of County residential population in the NAA × 99.96% = 61.73 tons PM10/yr Table 3.2–11. Annual and typical daily emissions from residential natural gas combustion. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Maricopa County 61.75 61.75 763.81 4.88 337.5 337.5 4,173.8 26.6 PM10 NAA 61.73 61.73 763.51 4.87 337.3 337.3 4,172.2 26.6 2008 Maricopa Co. PM10 Emission Inventory 27 June 2010 3.2.6 Residential wood combustion Area-source emissions from residential wood combustion were calculated based on the amount of wood burned in fireplaces and woodstoves in Maricopa County, as recommended by EIIP guidance (US EPA, 2001b). Residential wood combustion in the county is estimated by multiplying data on statewide residential wood combustion usage from the US Department of Energy (US DOE, 2010c) by the ratio of county to state households that report use of wood for heating from the US Census Bureau (2010b). The latest available data on residential wood use for household heating from the US Department of Energy is for the calendar year 2007. Since all fireplaces in homes constructed since 1999 are required by Arizona statute to be clean-burning, it is assumed that these new homes have negligible emissions. Thus, year 2007 data is assumed to be representative of 2008 emissions. Maricopa County residential = Arizona residential × Ratio of county:state households wood usage (cords/yr) wood usage (cords/yr) using wood for heat = 651,000 × 1,457 / 44,330 = 21,397 cords/yr To calculate emissions, the amount of wood used is converted to tons by multiplying cords by the number of cubic feet of wood in a cord and by the density of the wood used (US EPA, 2001b). Wood density is determined by weighted average of types of wood used for residential combustion in Maricopa County, provided by the US Forest Service (USFS, 1993). County residential = County wood × avg. ft3 wood/cord × Wood density (lbs/ ft3) ÷ 2,000 lbs/ton wood usage (tons/yr) usage (cords) = 21,397 × 79 × 31.57 ÷ 2,000 = 26,682 tons Annual emissions from residential wood combustion were calculated by multiplying the tons of wood used by the PM10 emission factor for residential woodstoves and fireplaces from Table 2.4 –1 of US EPA (2001b). Annual PM10 emissions from residential = Residential wood usage × PM10 emission factor ÷ 2,000 lbs/ton wood combustion (tons/yr) (tons) (lbs/ton) = 26,682 × 34.6 ÷ 2,000 = 461.59 tons PM10/yr Table 3.2–12. Annual wood usage, emission factors, and annual emissions from residential wood combustion. Residential wood Emission factors (lbs/ton) Annual emissions (tons/yr) usage (tons/yr) PM10 PM2.5* NOx SOx PM10 PM2.5* NOx SOx 26,681.76 34.6 32.2 2.6 0.4 461.59 429.28 34.69 5.34 *PM2.5 is assumed to be 93% of PM10 (Houck and Tiegs, 1998). Typical daily emissions were calculated by apportioning wood burning activity based on heating degree days (i.e., the number of degrees per day that the daily average temperature is below 65°F). Data provided by Arizona Department of Commerce (ADOC, 2010) indicated that there were five months (April, plus June–September, totaling 152 days) in 2008 where no heating degree days were recorded. Assuming that no wood burning activity took place during those months, it is assumed that all residential wood burning occurred during the remaining 213 days 2008 Maricopa Co. PM10 Emission Inventory 28 June 2010 of the year. Thus, typical daily emissions were calculated by dividing annual emissions by the number of days residential wood burning occurred, as follows: Typical daily PM10 emissions = Annual PM10 emissions × 2,000 lbs/ton from residential wood combustion (tons/yr) (lbs/day) = 461.59 × 2,000 ÷ no. days wood burning occurred ÷ 213 = 4,334.2 lbs PM10/day Annual and typical daily emissions within the PM10 nonattainment area (presented in Table 3.2– 13) were calculated by multiplying county totals by the ratio of residential population in the nonattainment area to the residential population in the county. See Section 1.5.1 for a further discussion of the population used. Annual emissions from residential wood = County annual emissions combustion in the PM10 NAA (tons/yr) = 461.59 × NAA:county residential population ratio × 0.9996 = 461.41 tons PM10/yr Table 3.2–13. Annual and typical daily emissions from residential wood combustion. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Maricopa County 461.59 429.28 34.69 5.34 4,334.2 4,030.8 325.7 50.1 PM10 NAA 461.41 429.11 34.67 5.33 4,332.5 4,029.2 325.6 50.1 3.2.7 Residential fuel oil Emissions from residential fuel oil use were calculated using an approach similar to that used for residential wood combustion described in Section 3.2.6. County-level residential fuel oil use was derived from statewide totals (US EIA, 2010) using the ratio of county to state households that report fuel oil use from the US Census Bureau (2010c): Maricopa County residential = Arizona residential × Ratio of county:state households fuel oil usage (Mgal/yr) fuel oil use (Mgal/yr) reporting fuel oil use = 91 × 573 / 1,881 = 27.72 Mgal/yr Annual and daily emissions were calculated using AP-42 emission factors (shown below in Table 3.2-14) and data on heating degree days and residential housing units described in Section 3.2.6. Annual and daily emissions are shown below in Table 3–2.14. Table 3.2–14. Annual and typical daily emissions from residential fuel oil combustion. Emission factors Annual emissions Typical daily emissions (lb/Mgal) (tons/yr) (lbs/day) Geographic area PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Maricopa County 0.4 0.4 18 7.1 0.01 0.01 0.25 0.10 0.1 0.1 2.3 0.9 PM10 NAA 0.4 0.4 18 7.1 0.01 0.01 0.25 0.10 0.1 0.1 2.3 0.9 2008 Maricopa Co. PM10 Emission Inventory 29 June 2010 3.2.8 Summary of all area-source fuel combustion Tables 3.2–15 and 3.2–16 provide a summary of annual and typical daily emissions from all fuel combustion, for Maricopa County and the PM10 nonattainment area, respectively. Table 3.2–15. Annual and typical daily emissions from area-source fuel combustion in Maricopa County. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Fuel combustion type PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Industrial natural gas 30.78 30.78 575.29 2.42 12.70 197.3 197.3 3,687.7 15.5 81.4 Industrial fuel oil 458.79 458.79 6,375.08 609.61 26.25 2,941.0 2,941.0 40,865.9 3,907.8 168.3 Comm./inst. natural gas 66.54 66.54 1,267.11 5.23 4.20 426.5 426.5 8,122.5 33.5 26.9 Comm./inst. fuel oil 224.14 224.14 3,273.40 271.27 8.13 1,436.8 1,436.8 20,983.3 1,738.9 52.1 Residential natural gas 61.75 61.75 763.81 4.88 337.5 337.5 4,173.8 26.6 Residential wood 461.59 429.28 34.69 5.34 4,334.2 4,030.8 325.7 50.1 Residential fuel oil 0.01 0.01 0.25 0.10 0.1 0.1 2.3 0.9 1,303.61 1,271.30 12,289.62 898.83 51.27 9,673.4 9,370.0 78,161.3 5,773.3 328.7 Total: Table 3.2–16. Annual and typical daily emissions from all area-source fuel combustion for the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Fuel combustion type PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Industrial natural gas 30.70 30.70 573.79 2.41 12.66 196.8 196.8 3,678.2 15.5 81.2 Industrial fuel oil 457.60 457.60 6,358.50 608.03 26.19 2,933.3 2,933.3 40,759.6 3,897.6 167.9 Comm./inst. natural gas 66.20 66.20 1,260.65 5.20 4.18 424.4 424.4 8,081.1 33.3 26.8 Comm./inst. fuel oil 223.00 223.00 3,256.70 269.88 8.09 1,429.5 1,429.5 20,876.3 1,730.0 51.8 Residential natural gas 61.73 61.73 763.51 4.87 337.3 337.3 4,172.2 26.6 Residential wood 461.41 429.11 34.67 5.33 4,332.5 4,029.2 325.6 50.1 Residential fuel oil 0.01 0.01 0.25 0.10 0.1 0.1 2.3 0.9 1,300.65 1,268.35 12,248.07 895.83 51.11 9,653.8 9,350.6 77,895.2 5,754.1 327.6 Total: 3.3 Industrial processes 3.3.1 Chemical manufacturing Emissions from area-source chemical manufacturing were calculated by the “scaling up” method as described in EPA emission inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from the US Census Bureau (2010a) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2007 employment were used. Table 3.3–1 shows the NAICS codes and employment data used to calculate emissions from chemical manufacturing. Table 3.3–1. NAICS codes and descriptions for chemical manufacturing. NAICS US Census Code Description employment data 325 Chemical Manufacturing 3,930 42469 Other Chemical and Allied Products Merchant Wholesalers 1,093 424910 Farm Supplies Merchant Wholesalers 229 33312 Construction Machinery Manufacturing 212 Total: 5,464 2008 Maricopa Co. PM10 Emission Inventory 30 June 2010 There were no point sources in this category. Area-source employment estimate were used to “scale up” emissions reported from those facilities surveyed in 2008 as follows: Area-source PM10 = Emissions from surveyed area sources × Total area-source employment emissions from Employment at surveyed area sources chemical mfg. = 35.71 tons of PM10/yr × 5,464 employees 1,041 employees = 187.43 tons PM10/yr Typical daily emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and typical daily emissions for the PM10 nonattainment area were calculated by multiplying the Maricopa County emission totals by the percentage industrial employment within the nonattainment area. (See Section 1.5.1 for a discussion of the employment data used.) PM10 emissions from area-source = Annual Maricopa County emissions × NAA:county ratio of (tons/yr) industrial employment chemical mfg. in the PM10 NAA (tons/yr) = 187.43 × 0.9974 = 186.94 tons PM10/yr Table 3.3–2 summarizes annual and typical daily emissions from chemical manufacturing in both Maricopa County and the PM10 nonattainment area. Table 3.3–2. Annual and typical daily emissions from area-source chemical manufacturing. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx NHx PM10 PM2.5 NOx SOx NHx Maricopa County 187.43 151.42 0.00 0.34 0.03 1,445.8 1,164.5 0.0 2.6 0.9 PM10 NAA 186.94 151.03 0.00 0.34 0.03 1,442.0 1,161.5 0.0 2.6 0.9 3.3.2 Food and kindred products 3.3.2.1 Commercial cooking Emissions from commercial cooking were estimated for five types of commercial cooking equipment using EPA methodology (US EPA, 2006a). The equipment types include: chain-driven charbroilers, under-fired charbroilers, deep-fat fryers, flat griddles, and clamshell griddles. EPA’s methodology estimates commercial cooking activity rates for restaurants with each type of cooking equipment (ethnic, family, fast food, seafood, and steak & barbeque) based on an average number of equipment pieces in each restaurant type, and also the and average quantity of meat cooked on each type of equipment per week (steak, hamburger, poultry, pork, and seafood). The estimates number of restaurants in Maricopa County for the five restaurant types was obtained from a commercial database (www.selectoryonline.com) and is shown in Table 3.3–3. 2008 Maricopa Co. PM10 Emission Inventory 31 June 2010 Table 3.3–3. Number of Maricopa County restaurants, by restaurant type. Restaurant Type No. of restaurants Ethnic food 907 Fast food 1,068 Family 253 Seafood 37 Steak and barbecue 75 All restaurants: 2,340 Using EPA’s emissions estimation methodology (US EPA, 2006a), commercial cooking activity data were estimated by first multiplying the county number of restaurants that use commercial cooking equipment in each category (ethnic, fast food, family, seafood, and steak and barbeque) by the percentage of restaurants with each type of cooking equipment (Table 3.3–4). Number of ethnic food restaurants with underfired charbroilers = Number of ethnic food × % ethnic food restaurants restaurants in Maricopa County with underfired charbroilers = 907 × 47.5% = 431 Table 3.3–4. Percentages of restaurants with each type of cooking equipment. Chain-driven Underfired Deep Fat Restaurant Type Charbroilers Charbroilers Fryers Flat Griddles Ethnic 3.5% 47.5% 81.9% 62.7% Family 10.1% 60.9% 91.4% 82.9% Fast Food 18.6% 30.8% 96.8% 51.9% Seafood 0.0% 52.6% 100.0% 36.8% Steak and Barbeque 6.9% 55.2% 82.8% 89.7% Clamshell Griddles 4.0% 1.4% 14.7% 10.5% 0.0% The resulting product was then multiplied by the average number of equipment pieces by restaurant type (shown in Table 3.3–5) to derive an estimate of the total number of each cooking equipment type in Maricopa County restaurants (Table 3.3–6). Table 3.3–5. Average number of equipment pieces per restaurant, by type. Chain-driven Underfired Deep Fat Restaurant Type Charbroilers Charbroilers Fryers Flat Griddles Ethnic 1.62 1.54 1.63 1.88 Family 1.71 1.29 2.34 2.03 Fast Food 1.07 1.58 3.10 1.43 Seafood — 1.10 2.47 1.11 Steak and Barbeque — 1.63 2.42 1.35 Number of underfired charbroilers = number of ethnic food restaurants at ethnic food restaurants with underfired charbroilers = 431 Clamshell Griddles 1.80 — 2.09 1.50 — × average number of underfired charbroilers per ethnic food restaurant × 1.54 = 664 2008 Maricopa Co. PM10 Emission Inventory 32 June 2010 Table 3.3–6. Total pieces of cooking equipment, by restaurant type. Chain-driven Underfired Deep Fat Restaurant Type Charbroilers Charbroilers Fryers Ethnic 51.43 663.47 1,210.82 Family 43.70 198.76 541.11 Fast Food 212.55 519.73 3204.85 Seafood — 21.41 91.39 Steak and Barbeque — 67.48 150.28 Totals: 307.68 1,470.85 5,198.45 Flat Griddles 1,069.14 425.77 792.64 15.11 90.82 2,393.47 Clamshell Griddles 65.30 — 328.12 5.83 — 399.25 The total number of each type of cooking equipment is then multiplied by average pounds of meat cooked on each type of equipment per week (Table 3.3–7) to derive the total estimate of the amount of meat cooked in Maricopa County each week (Table 3.3–8). Table 3.3–7. Meat cooked weekly per restaurant (in pounds), by equipment type. Chain-driven Underfired Deep Fat Type of Meat Charbroilers Charbroilers Fryers Flat Griddles Steak 236 180 181 166 Hamburger 798 270 274 362 Poultry, with Skin 147 144 365 88 Poultry, Skinless 266 179 208 111 Pork 57.6 148 58.6 112 Seafood 119 143 159 92.1 Other 0 41.5 274 57.5 Total steak cooked on all underfired charbroilers (tons/wk) Clamshell Griddles 94 1314 113 108 118 632 0 = Steak cooked on each under- × Total number of under-fired ÷ 2,000 lbs/ton fired charbroiler (lbs/wk) charbroilers at all restaurants = 180 lbs/ week × 1,470.85 ÷ 2,000 = 132.38 tons/week Table 3.3–8. Total meat cooked weekly (in tons), by equipment type. Chain-driven Underfired Deep Fat Type of Meat Charbroilers Charbroilers Fryers Steak 36.31 132.38 470.46 Hamburger 122.76 198.56 712.19 Poultry, with Skin 22.61 105.90 948.72 Poultry, Skinless 40.92 131.64 540.64 Pork 8.86 108.84 152.31 Seafood 18.31 105.17 413.28 Other 0.00 30.52 712.19 Totals: 249.77 813.01 3,949.78 Flat Griddles 198.66 433.22 105.31 132.84 134.03 110.22 68.81 1,183.09 Clamshell Griddles 18.76 262.31 22.56 21.56 23.56 126.16 0.00 474.91 The total amount of meat cooked in Maricopa County restaurants weekly (as shown in Table 3.3–8, (Table 3.3–8) was then multiplied by the appropriate emission factor from Table 3.3–9 (US EPA, 2006a). The results were then summed to estimate annual emissions for each type of cooking equipment, shown in Table 3.3–10. Commercial cooking is assumed to occur uniformly throughout both the week (i.e., 7 days/week) and year. 2008 Maricopa Co. PM10 Emission Inventory 33 June 2010 Table 3.3–9. PM10and PM2.5 emission factors for commercial cooking equipment, by device type. Equipment type PM10 (lb/ton) PM2.5 (lb/ton) Chain-driven charbroilers 15.996058 15.506208 Underfired charbroilers 32.666124 31.577929 Deep fat fryers 0.00 0.00 Flat griddle fryers 5.922517 4.501113 Clamshell griddles 1.006137 0.852257 Table 3.3–10. Annual and daily emissions from commercial cooking equipment in Maricopa County. Annual Emissions (tons/yr) Typical Daily Emissions (lbs/day) PM10 PM2.5 PM10 PM2.5 Equipment type Chain-driven charbroilers 103.88 100.70 570.8 553.3 Underfired charbroilers 690.51 667.51 3,794.0 3,667.6 Deep fat fryers 0.00 0.00 0.0 0.0 Flat griddles 182.18 138.46 1,001.0 760.7 Clamshell griddles 12.42 10.52 68.3 57.8 Totals: 988.99 917.18 5,434.0 5,039.5 Annual and typical daily emissions for the PM10 nonattainment area were calculated by multiplying the county totals by the ratio of total population in the nonattainment area to the total population in the county (100.41%) (See Section 1.5.1 for a discussion of the population data used.) Table 3.3–11 summarizes the annual and typical daily emissions from commercial cooking for the PM10 NAA. Table 3.3–11. Annual and daily PM emissions from commercial cooking equipment in the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Equipment type PM10 PM2.5 PM10 PM2.5 Chain-driven charbroilers 104.31 101.11 573.11 555.55 Underfired charbroilers 693.34 670.24 3,809.55 3,682.65 Deep fat fryers 0.00 0.00 0.00 0.00 Flat griddles 182.93 139.02 1,005.09 763.87 Clamshell griddles 12.47 10.57 68.54 58.06 Totals: 993.04 920.94 5,456.29 5,060.13 3.3.2.2 Grain handling/processing Annual emissions from area-source grain handling and processing operations were derived from annual emission reports submitted by permitted sources. It was assumed that there were no significant unpermitted sources within Maricopa County. Typical daily emissions were calculated based on reported activity data (days per week) for each individual process, and then summed. Nearly all processes reported operating on either a 5- or 6day week. Annual and typical daily emissions for the PM10 nonattainment area were derived based on the location data of the individual facilities. Annual and typical daily emissions for both the County and the PM10 NAA are shown in Table 3.3–12. Table 3.3–12. Annual and typical daily emissions from area-source grain handling and processing. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic Area PM10 PM2.5 PM10 PM2.5 Maricopa County 20.59 6.71 149.3 49.5 PM10 NAA 16.73 5.68 125.3 43.0 2008 Maricopa Co. PM10 Emission Inventory 34 June 2010 3.3.2.3 Ammonia cold storage Area-source emissions from ammonia cold storage are estimates of ammonia emissions from food and kindred products industrial sources that use ammonia for refrigeration of food products. Emission calculations are based on the number of employees in the food and kindred products industry classification (NAICS codes 311, 312) as reported by the 2007 County Business Patterns (US Census Bureau, 2010a). Annual emissions were calculated by multiplying employment numbers by the emission factor for ammonia cold storage as listed in Table 6-5 of “Development and Selection of Ammonia Emission Factors” (Battye et al., 1994) as follows: Annual NH3 emissions = Number of employees from ammonia cold in relevant industries storage (tons/yr) (from CBP) = 8,128 = 1,678.43 tons NH3/yr × NH3 emission ÷ 2,000 lbs/ton factor (lb/employee-yr) × 413 ÷ 2,000 Typical daily emissions were calculated by dividing annual emissions by the number of days per year that activity occurred, as follows: Typical daily = Annual emissions (tons/yr) × 2,000 lbs/ton NH3 emissions (lbs/day) = 1,678.43 × 2,000 = 10,759.2 lbs NH3/day ÷ (weeks/year × days/week) ÷ (52 × 6) Annual and typical daily emissions for the PM10 nonattainment area (shown in Table 3.3–13 below) were calculated by multiplying Maricopa County emissions by the ratio of County industrial employment that occurs in the PM10 nonattainment area. (See Section 1.5.1 for a more detailed discussion of the employment data used). Annual NH3 emissions from ammonia cold storage in the PM10 NAA (tons/yr) = Annual county emissions (tons/yr) × NAA:County industrial employment ratio = 1,678.43 = 1,674.07 tons NH3/yr × 0.9974 Table 3.3–13. Annual and typical daily ammonia emissions from ammonia cold storage. Geographic area Annual emissions (tons/yr) Typical daily emissions (lbs/day) Maricopa County 1,678.43 10,759.2 PM10 NAA 1,674.07 10,731.2 3.3.3 Secondary metal production Annual emissions from secondary metal production facilities were derived from annual emission reports from permitted sources. As this category consists primarily of foundries, it was assumed that there were no significant unpermitted sources within Maricopa County. Since all facilities considered in this section are located within the PM10 nonattainment area, total emission values for the county and the PM10 NAA from area-source secondary metal production are equal. Annual and daily emissions are shown in Table 3.3–14. 2008 Maricopa Co. PM10 Emission Inventory 35 June 2010 Table 3.3–14. Annual and typical daily emissions from secondary metal production. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Maricopa County 60.56 52.16 49.73 18.65 0.04 442.7 386.2 358.8 142.7 0.0 PM10 NAA 60.56 52.16 49.73 18.65 0.04 442.7 386.2 358.8 142.7 0.0 3.3.4 Non-metallic mineral processes The primary contributors to this source category include concrete batch plants, ceramic clay and tile manufacturing, brick manufacturing, and gypsum mining. Emissions from this source were derived from annual emission reports from permitted facilities. Since all permitted facilities in this category were surveyed in 2008, it was assumed that there were no significant unpermitted sources within Maricopa County. Some portable concrete batch operations which operate within Maricopa County for only part of the year are issued air quality permits by the Arizona Department of Environmental Quality (ADEQ). All state-permitted portable sources are addressed in Section 3.3.11. Typical daily emissions were calculated based on the operating schedule data reported by surveyed facilities. Annual and typical daily emissions for the PM10 nonattainment area were derived based on the location data of the individual facilities. County-permitted portable sources with no location data were assumed to operate within the PM10 nonattainment area as a conservative estimate. Table 3.3–15 summarizes annual and typical daily emissions from non-metallic mineral processing activities in both Maricopa County and the PM10 nonattainment area. Table 3.3–15. Annual and typical daily emissions from area-source non-metallic mineral products. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 PM10 PM2.5 Maricopa County 195.81 97.28 1,357.4 671.7 PM10 NAA 190.45 93.72 1,320.7 647.9 3.3.5 Mining and quarrying Annual emissions from area-source mining and quarrying (sand and gravel) operations were derived from annual emission reports submitted by permitted sources. It was assumed that there were no significant unpermitted sources within Maricopa County. Some portable mining and quarrying operations which operate within Maricopa County for only part of the year are issued air quality permits by the Arizona Department of Environmental Quality (ADEQ). All statepermitted portable sources are addressed in Section 3.3.11. Typical daily emissions were calculated based on reported activity data (days per week) for each individual process, and then summed. Nearly all processes reported operating on either a 5- or 6day week. Emissions within the PM10 nonattainment area were identified using information on the location of each permitted facility. County-permitted portable sources with no location data were assumed to operate within the PM10 nonattainment area as a conservative estimate. Annual and daily emissions are shown in Table 3.3–16. 2008 Maricopa Co. PM10 Emission Inventory 36 June 2010 Table 3.3–16. Annual and typical daily emissions from area-source mining and quarrying operations. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic Area PM10 PM2.5 PM10 PM2.5 Maricopa County 210.39 59.56 1,442.1 390.8 PM10 NAA 184.25 50.64 1,266.6 331.9 3.3.6 Wood product manufacturing Emissions from wood product manufacturing were calculated by the “scaling up” method as described in EPA emission inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from the US Census Bureau (2010a) to estimate an annual per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent employment estimates (for the year 2007) from the US Census Bureau’s County Business Patterns (CBP) were used. Table 3.3–17 shows the NAICS codes and employment estimates used to calculate emissions from wood product manufacturing. Table 3.3–17. County-level employment estimates for wood product manufacturing, by NAICS code. NAICS Code NAICS Code Description 2007 employment estimate 321--Wood products manufacturing 6,917 337--Furniture and related products manufacturing 7,153 Total: 14,070 Since some larger facilities in this category are considered point sources, they have been included in the point source calculations presented earlier in Chapter 2. To avoid doublecounting, employment at point sources was subtracted from total employment as follows: Total area-source employment in wood products = Total County employment for the sector – Employment reported from facilities reported as point sources = 14,070 = 13,140 employees – 930 Annual emissions for the entire wood product manufacturing sector were calculated by “scaling up” detailed area-source emissions reported from those facilities surveyed in 2008 as follows: Total area-source = Emissions from surveyed area sources × Total area-source employment emissions Employment at surveyed area sources Area-source PM10 = 102.99 tons PM10/yr emissions from 6,229 employees wood products = 217.26 tons PM10/yr × 13,140 employees Typical daily emissions were calculated in the same method, using surveyed daily emissions estimates from the subset of surveyed area sources. From these County totals, emissions estimates for the PM10 nonattainment area were calculated by multiplying the County totals by the percentage of industrial employment within the nonattainment area. (See Section 1.5.1 for a discussion of the employment data used.) 2008 Maricopa Co. PM10 Emission Inventory 37 June 2010 PM10 emissions from area-source wood product manufacturing in the PM10 NAA (tons/yr) = Total County emissions × NAA:county ratio for industrial employment = 217.26 tons/yr × 0.9974 = 216.69 tons PM10/yr Table 3.3–18 summarizes annual and typical daily emissions from wood products manufacturing in both Maricopa County and the PM10 nonattainment area. Table 3.3–18. Annual and typical daily emissions from area-source wood product manufacturing. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic Area PM10 PM2.5 PM10 PM2.5 Maricopa County 217.26 203.25 1,668.6 1,548.3 PM10 NAA 216.69 202.72 1,664.3 1,544.3 3.3.7 Rubber/plastics manufacturing Emissions from area-source rubber and plastic manufacturing facilities were calculated by the “scaling up” method as described in EPA emission inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from the US Census Bureau (2010a) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2007 employment were used. Where CBP employment estimates were presented as a range, the midpoint values were chosen for these calculations. Table 3.3–19 lists the NAICS codes and employment data used to calculate emissions from rubber and plastic manufacturing facilities. Some facilities in this category are considered point sources, and have been addressed in Chapter 2. To avoid double-counting, employment at point sources is subtracted from total employment as follows: Total area-source employment = Total employment (from US in rubber & plastic product Census’ County Business Patterns) manufacturing = 11,380 – Employment at point sources (from annual emission reports) – 896 = 10,484 employees This area-source employment estimate is used to “scale up” emissions reported from those facilities surveyed in 2008 as follows: Total area-source PM10 emissions from rubber/plastic product mfg. = Emissions from surveyed area sources Employment at surveyed area sources × Area-source employment = 30.37 tons PM10/yr 2,256 employees × 10,484 employees = 140.94 tons PM10/yr 2008 Maricopa Co. PM10 Emission Inventory 38 June 2010 Table 3.3–19. County-level employment estimates for rubber and plastic manufacturing, by NAICS code. NAICS Code NAICS Code Description 2007 employment estimate 32614 Polystyrene Foam Product Manufacturing 351 32619 Other Plastics Product Manufacturing 4,178 32622 Rubber & Plastics Hoses & Belting Manufacturing 60 33992 Sporting & Athletic Goods Manufacturing 1,750 42461 Plastics Materials & Basic Forms & Shapes Merchant 368 Wholesalers 325211 Plastics Material & Resin Manufacturing 10 325520 Adhesive Manufacturing 123 325991 Custom Compounding of Purchased Resins 194 326113 Unlaminated Plastics Film & Sheet (except Packaging) Mfg. 60 326122 Plastics Pipe & Pipe Fitting Manufacturing 144 326140 Polystyrene Foam Product Manufacturing 351 326160 Plastics Bottle Manufacturing 175 326199 All Other Plastics Product Manufacturing 175 326212 Tire Retreading 42 326299 All Other Rubber Product Manufacturing 71 327991 Cut Stone & Stone Product Manufacturing 583 332913 Plumbing Fixture Fitting & Trim Manufacturing 10 336612 Boat Building 53 337920 Blind & Shade Manufacturing 286 339113 Surgical Appliance & Supplies Manufacturing 88 339115 Ophthalmic Goods Manufacturing 60 441320 Tire Dealers 2,248 Typical daily emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and typical daily emissions for the PM10 nonattainment area were calculated by multiplying the Maricopa County emission totals by the percentage industrial employment within the nonattainment area. (See Section 1.5.1 for a discussion of the employment data used.) PM10 emissions from area-source plastic/rubber in the PM10 NAA (tons/yr) = Annual Maricopa County emissions × NAA:county ratio of industrial employment = 140.94 tons PM10/yr × 0.9974 = 140.57 tons PM10/yr Table 3.3–20 summarizes annual and typical daily emissions from rubber/plastic products manufacturing in both Maricopa County and the PM10 nonattainment area. Table 3.3–20. Annual and typical daily emissions from area-source rubber/plastic product manufacturing. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic Area PM10 PM2.5 PM10 PM2.5 Maricopa County 140.94 105.96 953.3 698.8 PM10 NAA 140.57 105.68 950.9 697.0 3.3.8 Fabricated metal products manufacturing Emissions from fabricated metal products manufacturing were calculated by the “scaling up” method as described in EPA emission inventory guidance (US EPA, 2001a). This method combines detailed emissions data from a subset of sources, and county-level employment data from 2008 Maricopa Co. PM10 Emission Inventory 39 June 2010 the US Census Bureau (2010a) to develop a per-employee emission factor that is then used to estimate emissions from all sources in an industry category. The most recent data from the US Census Bureau’s County Business Patterns (CBP) for 2007 employment were used. CBP employment data for NAICS code 332* (fabricated metal products manufacturing) indicated that there were 16,138 employees in this industry in Maricopa County. Some facilities in this category are considered point sources, and have been addressed in Chapter 2. To avoid double-counting, employment at point sources is subtracted from total employment as follows: Total area-source employment in fab. metal products = Total employment (from US – Employment at point sources Census’ County Business Patterns) (from annual emission reports) = 16,138 = 12,138 employees – 4,000 Annual emissions were calculated by “scaling up” area-source emissions reported from those facilities surveyed in 2007 as follows: Total area-source = Emissions from surveyed area sources × Total area-source employment emissions Employment at surveyed area sources Area-source PM10 = emissions from fab. metal products = 18.07 tons of PM10/yr 4,261 employees × 12,138 employees 51.48 tons PM10/yr Typical daily emissions were calculated in the same method as annual emissions, only using surveyed daily emissions instead of annual totals. Annual and typical daily emissions for the PM10 nonattainment area were calculated by multiplying the Maricopa County emission totals by the percentage of industrial employment within the nonattainment area. (See Section 1.5.1 for a discussion of the employment data used.) PM10 emissions from area-source fabricated metal production in the PM10 NAA (tons/yr) = Annual Maricopa County × NAA:County ratio of emissions (tons/yr) industrial employment = 51.48 tons/yr × 0.9974 = 51.35 tons PM10/yr Table 3.3–21 summarizes annual and typical daily emissions from fabricated metal products manufacturing in both Maricopa County and the PM10 nonattainment area. Table 3.3–21. Annual and typical daily emissions from area-source fabricated metal product manufacturing. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic Area PM10 PM2.5 NHx PM10 PM2.5 NHx Maricopa County 51.48 42.62 4.50 538.1 460.6 28.9 PM10 NAA 51.35 42.51 4.49 536.7 459.4 28.8 2008 Maricopa Co. PM10 Emission Inventory 40 June 2010 3.3.9 Construction Maricopa County’s air quality permits database was used to identify all dust control permits issued during 2008. A total of 4,622 permits were issued, comprising a total of 42,130 acres (Table 3.3–22). Data requested on each dust control permit application includes the project type and acreage. It was assumed there is no unpermitted earthmoving activity. Table 3.3–22. Maricopa County dust control permits issued in 2008, by type. Total Acreage, by Project Type Reported Acres Residential (single- and multi-family) 20,437.0 Commercial 10,850.0 Road construction 4,449.0 Trenching 3,396.1 Demolition 1,970.6 Weed control 687.0 Site prep / land development 218.9 Temp. storage yard 122.4 Totals: 42,130.9 The Western Regional Air Partnership (WRAP) Fugitive Dust Handbook (WRAP, 2006a) provides different emission factors for residential (single-family houses and apartment buildings), nonresidential, road, and general construction. MCAQD used the WRAP-suggested emission factors except for the following activities: • The WRAP Fugitive Dust Handbook recommended using 0.42 ton PM10/acre-month for road construction to account for the large amount of dirt moved during the construction of roadways. However, both the South Coast Air Quality Management District (SCAQMD) and the Clark County Department of Air Quality and Environmental Management have estimated that a certain percentage of their road construction projects do not involve large-scale earthmoving activities, and thus have developed average emission factors for road construction projects (0.1895 ton PM10/acre-month and 0.265 ton PM10/acre-month, respectively). Since Maricopa County and Clark County have similar population growth rates, climatic conditions, and PM10 sources, MCAQD used the Clark County road construction emission factor of 0.265 tons/acre-month to estimate emissions from road construction projects (Clark County, 2001). • Specific emission factors were not available in the WRAP Fugitive Dust Handbook for trenching, demolition, weed control, and temporary storage yard activities; thus, the general construction emission factor of 0.11 tons PM10/acre-month was used to estimate emissions from these activities. Information was not readily available regarding the breakout of residential construction activity between single-family and multi-family residential construction; thus, acreage for residential construction was allocated based on single-family and multi-family household percentages (See Section 1.5.1 for single-family and multi-family household percentages used). Estimates for the duration of house and apartment construction were obtained from EIIP guidance (US EPA, 2002). Estimates for the duration of nonresidential construction and road construction were obtained from the WRAP Fugitive Dust Handbook (WRAP, 2006a). No estimates for the duration of trenching, demolition, weed control, site prep/land development, and temporary storage yard activities were available; thus, MCAQD assumed the following: 2008 Maricopa Co. PM10 Emission Inventory 41 June 2010 • • • 1-month duration for trenching, demolition, and weed control. 8-month duration for site prep/land development activities (weighted average of residential and commercial duration) because the duration depends on the project type and size. 12-month duration for temporary storage yard activities because these activities are frequently associated with road construction. The average duration of construction activity and emission factors for each project type are shown below in Table 3.3–23. Table 3.3–23. Average project duration and emission factor, by project type. Average Duration Emission factor Project Type (months) (tons PM10/acre-month) 6 Residential: single-family 0.032 12 Residential: multi-family 0.11 11 Commercial 0.19 12 Road construction 0.265 1 Trenching 0.11 1 Demolition 0.11 1 Weed control 0.11 8 Site prep / land development 0.11 12 Temp. storage yard 0.11 County-wide annual uncontrolled PM10 emissions for each construction category were then calculated as follows: Annual uncontrolled PM10 emissions Example: Annual uncontrolled PM10 emissions from single-family residential construction = total acres/yr × no. months × emission factor = 15,327.8 acres/yr × 6 months × 0.032 tons PM10/acre-month = 2,942.93 tons PM10/yr As in prior years, a control efficiency of 90% was applied to the uncontrolled emissions calculations. This factor is in line with values applied in a number of earlier SIP documents for Maricopa and Clark Counties, including: • Revised MAG 1999 Serious Area Particulate Plan for PM10 (Appendices volume two, page V-9, and vol. four), Feb. 2000. • Revised MAG 1999 Serious Area Particulate Plan for PM10, (Appendix C, Exhibit 3: Evaluation for Compliance with 24-Hour PM10 Standard for West Chandler and Gilbert Microscale Sites, Arizona Department of Environmental Quality, June 1999, pp. 3-5 and 39), Feb. 2000. • “Evaluation of Fugitive Dust Control in the Maricopa Co. PM10 Nonattainment Area”, report by ENSR in: Final Plan for Attainment of the 24-hour PM10 Standard, ADEQ, May 1997, Appendix B. • Clark Co. PM10 State Implementation Plan, June 2001, pg. L-5. (An 87% emission reduction percentage is assumed for watering at construction activities.) A recent rule effectiveness study by Maricopa County (contained in Appendix 3) indicated an 83% compliance rate with Maricopa County Rule 310 on dust control at construction sites. 2008 Maricopa Co. PM10 Emission Inventory 42 June 2010 Thus, an overall control effectiveness of 74.7% (= 90% × 83%) was applied. Controlled PM10 emissions were calculated as follows: Annual controlled PM10 emissions = Uncontrolled PM10 emissions (tons/yr) × [1 – (control efficiency × rule effectiveness)] Example: Annual controlled PM10 emissions from single-family residential construction = 2,942.93 tons/yr × [1 – (90% control × 83% rule effectiveness)] = 744.83 tons PM10/yr PM2.5 emissions were estimated to comprise 10% of PM10 emissions (WRAP, 2006a). Table 3.3–24 summarizes the calculations for each dust control permit category. Table 3.3–24. Annual emissions from construction in Maricopa County, by project type. Total acreEmission factor Uncontrolled Controlled Project Type months (tons/acre-month) PM10 PM10 Residential: single-family 91,966.5 0.032 2,942.93 744.83 Residential: multi-unit 61,311.0 0.11 6,744.21 1,706.89 Commercial 119,349.7 0.19 22,676.44 5,739.18 Road construction 53,388.0 0.265 14,147.82 3,580.67 Trenching 3,396.1 0.11 373.57 94.55 Demolition 1,970.6 0.11 216.76 54.86 Weed control 687.0 0.11 75.56 19.12 Site prep/land development 1,750.9 0.11 192.60 48.74 Temporary storage yard 1,468.7 0.11 161.55 40.89 Totals: 47,531.45 12,029.74 Controlled PM2.5 74.48 170.69 573.92 358.07 9.45 5.49 1.91 4.87 4.09 1,202.97 Dust control permit site location data were used to determine construction activity that occurred in the Maricopa County PM10 nonattainment area. The same average duration of construction activity and emission factors used to estimate Maricopa County emissions (see Table 3.3–18) were applied to construction activity in the Maricopa County PM10 nonattainment area. Table 3.3–25 summarizes Maricopa County PM10 nonattainment area construction activity and calculations for each project type. Table 3.3–25. Annual emissions from construction within the Maricopa County portion of the PM10 nonattainment area, by project type. Total Total acreEF (tons/ Uncontrolled Controlled Controlled Project Type Acres months acre-month) PM10 PM10 PM2.5 Residential: single-family 13,989.0 83,934.0 0.032 2,685.89 679.77 67.98 Residential: multi-unit 4,663.0 55,956.0 0.11 6,155.16 1,557.81 155.78 Commercial 10,125.2 111,376.9 0.19 21,161.61 5,355.79 535.58 Road construction 3,383.9 40,606.8 0.265 10,760.80 2,723.45 272.35 Trenching 1,938.2 1,938.2 0.11 213.20 53.96 5.40 Demolition 1,949.0 1,949.0 0.11 214.39 54.26 5.43 Weed control 638.5 638.5 0.11 70.23 17.78 1.78 Site prep/land development 218.9 1,750.9 0.11 192.60 48.74 4.87 Temporary storage yard 122.4 1,468.7 0.11 161.55 40.89 4.09 Totals: 37,027.9 41,615.42 10,532.45 1,053.24 In addition, the Pinal County Air Quality Department (PCAQD) provided construction emission estimates for the Pinal County portion of the PM10 nonattainment. PCAQD estimated that approximately 0.8 percent of the Pinal County construction activity occurred in the Pinal County portion of the PM10 nonattainment area, thus, annual and typical daily emission for the Pinal 2008 Maricopa Co. PM10 Emission Inventory 43 June 2010 County portion of the PM10 nonattainment area was calculated by multiplying the Pinal County emission totals by 0.8 percent. The PCAQD estimates (presented in Table 3.3–26 below) incorporated the same assumptions concerning relevant input variables such as the average duration of construction activity, emission factors, control efficiency, and rule effectiveness as Maricopa County's estimates. Table 3.3–26. Annual emissions from construction in the Pinal County portion of the PM10 NAA, by project type. Project Type PM10 PM2.5 Residential: single-family 7.65 0.77 Residential: multi-family 0.16 0.02 Commercial 25.16 2.52 Road construction 1.42 0.14 Trenching 0.08 0.00 Totals: 34.47 3.45 To calculate average daily emissions from construction activity, It was assumed that construction activity typically occurs 6 days per week and remains relatively even throughout the year. Thus, typical daily emissions were calculated by dividing annual emissions for each category were divided by 312 (= 6 days/wk × 52 wks/yr) to derive the daily emissions estimates shown in Table 3.3–27. Table 3.3–27. Annual and typical daily emissions from construction in Maricopa County and the PM10 NAA. Construction Type Residential Commercial Road construction All other* Total: Maricopa County Annual emissions Typical daily emissions (tons/yr) (lbs/day) PM10 PM2.5 PM10 PM2.5 2,451.72 5,739.18 3,580.67 258.16 12,029.73 245.17 573.92 358.07 25.82 1,202.97 15,716.1 36,789.6 22,953.0 1,654.9 77,113.7 1,571.6 3,679.0 2,295.3 165.5 7,711.4 PM10 NAA Annual emissions Typical daily emissions (tons/yr) (lbs/day) PM10 PM2.5 PM10 PM2.5 2,245.39 5,380.95 2,724.87 215.70 10,566.91 224.54 538.10 272.49 21.57 1,056.70 14,465.2 34,382.4 17,471.4 1,385.5 67,704.5 1,446.5 3,438.2 1,747.1 138.6 6,770.5 *Includes: trenching, demolition, weed control, site prep/land development, and temporary storage yard. 3.3.10 Electrical equipment manufacturing Annual and typical daily emissions from electric equipment manufacturing were derived from annual emission reports submitted by permitted sources. It was assumed that there were no significant unpermitted sources within Maricopa County and all electrical equipment manufacturing permitted sources are reported here as area-sources. As all facilities addressed in this source category are located within the PM10 nonattainment area, emission totals for both areas are equal. Annual and typical daily emissions are shown in Table 3.3–28. Table 3.3–28. Annual and typical daily emissions from area-source electric equipment manufacturing. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Maricopa County 13.94 9.64 20.45 0.18 31.55 76.9 53.2 112.4 1.1 193.7 PM10 NAA 13.94 9.64 20.45 0.18 31.55 76.9 53.2 112.4 1.1 193.7 2008 Maricopa Co. PM10 Emission Inventory 44 June 2010 3.3.11 State-permitted portable sources The Arizona Department of Environmental Quality (ADEQ) retains the authority to permit certain categories of sources within Maricopa County, including portable sources. MCAQD requested information from ADEQ for all ADEQ-permitted sources that reported any activity in Maricopa County during 2008. Annual total emissions for most pollutants were provided, along with information on the facility type, and information on the location of the site(s) during the year. Permits were classified into four major types: asphalt batch, concrete batch, crushing/ screening, and other (including soil remediation, generators, etc.). From this information, emissions that occurred within Maricopa County were estimated as in the following example. Data provided: Source information: Permit type: Operating schedule: Total annual emissions: (tons/yr) McNeil Brothers - Erie Strayer Portable Plant Concrete batch plant Operated from 1/1-5/15 in Mesa at SR202 and McKellips (SE Corner); operated from 10/16-12/31 in Goodyear at Northside I-10 east of Estrella. PM10 0.923 PM2.5 * 0.461 NOx 8.429 SOx 2.306 * PM2.5 was assumed to be 50% of reported PM10 for crushing/screening operations. Using this information, calculations were made to determine: Total operating days in 2008: 136 = 31 (Jan.) + 29 (Feb.) + …16 (Oct.) + 30 (Nov.) + 31 (Dec.) Total operating days in Maricopa County: 136 = 31 (Jan.) + 29 (Feb.) + …16 (Oct.) + 30 (Nov.) + 31 (Dec.) All emissions were assumed to be equally distributed among all reported days of operation. First, emissions attributable to activity within Maricopa County were calculated as follows: Annual PM10 emissions = Total annual emissions × operating days in Maricopa County in Maricopa County (tons/yr) total operating days in 2008 = 0.923 × 136 136 = 0.923 tons PM10/yr Typical daily emissions were then calculated as follows: Typical daily =total emissions attributable to activity in Maricopa County × 2,000 lbs emissions number of operating days in Maricopa County ton (lbs/day) = 0.923 tons × 2,000 lbs 136 days ton = 13.6 lbs PM10/day Table 3.3–29 summarizes the annual and typical daily emissions for all ADEQ-permitted portable sources that operated within Maricopa County at some point during 2008. Since precise location data was not available for all permits, all emissions are conservatively assumed to have originated within the PM10 nonattainment area; thus emission estimates for Maricopa County and the PM10 nonattainment area are equal. 2008 Maricopa Co. PM10 Emission Inventory 45 June 2010 Table 3.3–29. Annual and typical daily emissions from ADEQ-permitted portable sources. Annual emissions (tons/yr) Typical daily emissions (lbs/day) PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx 59.00 29.50 282.18 88.93 492.9 246.5 2,275.7 88.9 Total: 3.3.12 Paved/unpaved road travel on industrial sites This section addresses emissions from travel on paved and unpaved roads within the boundaries of a permitted facility. Emissions from motor vehicle travel on public and private roads is addressed in Chapter 5, Mobile Sources, and road travel emissions from facilities considered point sources are addressed in Chapter 2, Point Sources. PM10 emissions from this source category were derived from annual emission reports from permitted sources, using AP-42 equations based on vehicle size and average speed (US EPA, 1997; 1998b). It is assumed that there are no unpermitted sources with significant emissions from on-site road travel. PM2.5 emissions were calculated from PM10 using a ratio derived from California Air Resources Board’s (CARB) PM2.5 Fraction Table (CARB, 2006). Typical daily emissions were calculated using operating schedule information for each reported process (normally a 5 or 6-day week), which were then summed to provide total daily emissions for the county. Emissions totals for the PM10 nonattainment area were determined from the site locations of each facility. Results for each geographic area are shown in Table 3.3–30. Table 3.3–30. Annual and typical daily emissions from paved and unpaved road travel at industrial facilities. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 PM10 PM2.5 Maricopa County 608.17 282.95 4,178.8 1,928.8 PM10 NAA 511.29 227.58 3,551.3 1,573.8 3.3.13 Industrial processes not elsewhere classified (NEC) Annual area-source emissions from other industrial processes NEC were derived from annual emissions reports from permitted facilities. Other industrial processes include a wide array of industrial activities that are often specific to the permitted facility that reported the process. For this reason, it is assumed there are no significant emissions from other industrial processes, other than those reported by permitted facilities on their annual emissions reports. Typical daily emissions were calculated based on operating schedule information provided by individual facilities through MCAQD’s annual emissions reporting program. Emissions estimates for the PM10 nonattainment area were derived using data on the location of the facilities that report other industrial processes. Emissions totals are presented in Table 3.3–31. Table 3.3–31. Annual and typical daily emissions from other industrial processes not elsewhere classified. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Maricopa County 144.60 107.24 10.22 21.49 16.79 953.3 726.4 69.6 137.7 94.6 PM10 NAA 136.00 99.12 8.12 21.47 14.10 906.0 681.7 55.4 137.6 79.8 2008 Maricopa Co. PM10 Emission Inventory 46 June 2010 3.3.14 Summary of all area-source industrial processes Tables 3.3–32 and 3.3–33 provide a summary of annual and typical daily emissions from all industrial sources, for Maricopa County and the PM10 nonattainment area, respectively. Table 3.3–32. Annual and daily emissions from all area-source industrial processes in Maricopa County. Annual emissions (tons/yr) Source category PM10 PM2.5 NOx SOx NH3 Chemical manufacturing 187.43 151.42 0.00 0.34 0.03 Commercial cooking 988.99 917.18 Grain handling/processing 20.59 6.71 Ammonia cold storage 1,678.43 Secondary metal production 60.56 52.16 49.73 18.65 .004 Non-metallic mineral processes 195.81 97.28 Mining and quarrying 210.39 59.56 Wood product manufacturing. 217.26 203.25 Rubber/plastic product manufacturing 140.94 105.96 Fabricated metal product manufacturing 51.48 42.62 Residential construction 2,451.72 245.17 Commercial construction 5,739.18 573.92 Road construction 3,580.67 358.07 Other construction 258.18 25,82 Electrical equipment manufacturing 13.94 9.64 20.45 0.18 31.55 ADEQ-permitted portable sources 59.00 29.50 282.18 88.93 Road travel at industrial sites 608.17 282.95 Industrial processes NEC 144.60 107.24 10.22 21.49 16.79 All industrial processes: 14,928.89 3,268.45 362.58 129.60 1,731.34 Source category Chemical manufacturing Commercial cooking Grain handling/processing Ammonia cold storage Secondary metal production Non-metallic mineral processes Mining and quarrying Wood product manufacturing. Rubber/plastic product manufacturing Fabricated metal product manufacturing Residential construction Commercial construction Road construction Other construction Electrical equipment manufacturing ADEQ-permitted portable sources Road travel at industrial sites Industrial processes NEC All industrial processes: 2008 Maricopa Co. PM10 Emission Inventory Typical daily emissions (lbs/day) PM2.5 NOx SOx 1,164.5 0.0 2.6 5,039.5 49.5 PM10 1,445.8 5,434.0 149.3 442.7 1,357.4 1,442.1 1,668.6 953.3 538.1 15,716.1 36,789.6 22,953.0 1,654.9 76.9 492.9 4,178.8 953.3 96,246.9 386.2 671.7 390.8 1,548.3 698.8 460.6 1,571.6 3,679.0 2,295.3 165.5 53.2 246.5 1,928.8 726.4 21,076.1 47 358.8 142.7 NH3 0.6 10,759.2 0.0 28.9 112.4 2,275.7 1.1 721.7 193.7 69.6 2,816.5 137.7 1,005.8 94.6 11,077.2 June 2010 Table 3.3–33. Annual and typical daily emissions from all area-source industrial processes in the PM10 NAA. Annual emissions (tons/yr) Source category PM10 PM2.5 NOx SOx NH3 Chemical manufacturing 186.94 151.03 0.00 0.34 0.03 Commercial cooking 993.04 920.94 Grain handling/processing 16.73 5.68 Ammonia cold storage 1,674.1 Secondary metal production 60.56 52.16 49.73 18.65 0.04 Non-metallic mineral processes 190.45 93.72 Mining and quarrying 184.25 50.64 Wood product manufacturing. 216.69 202.72 Rubber/plastic product manufacturing 140.57 105.68 Fabricated metal product manufacturing 51.35 42.51 4.49 Residential construction 2,245.39 224.54 Commercial construction 5,380.95 538.10 Road construction 2,724.87 272.49 Other construction 215.70 21.57 Electrical equipment manufacturing 13.94 9.64 20.45 0.18 31.55 ADEQ-permitted portable sources 59.00 29.50 282.18 88.93 Road travel at industrial sites 511.29 227.58 Industrial processes NEC 136.00 99.12 8.12 21.47 14.10 All industrial processes: 13,327.74 3,047.62 360.48 129.58 1,724.27 Source category Chemical manufacturing Commercial cooking Grain handling/processing Ammonia cold storage Secondary metal production Non-metallic mineral processes Mining and quarrying Wood product manufacturing. Rubber/plastic product manufacturing Fabricated metal product manufacturing Residential construction Commercial construction Road construction Other construction Electrical equipment manufacturing ADEQ-permitted portable sources Road travel at industrial sites Industrial processes NEC All industrial processes: 3.4 Waste treatment and disposal 3.4.1 On-site incineration Typical daily emissions (lbs/day) PM2.5 NOx SOx 1,161.5 0.0 2.6 5,060.1 43.0 PM10 1,442.0 5,456.3 125.3 442.7 1,320.7 1,266.6 1,664.3 950.9 536.7 14,465.2 34,382.4 17,471.4 1,385.5 76.9 492.9 3,551.3 906.0 85,937.0 386.2 647.9 331.9 1,544.3 697.0 459.4 1,446.5 3,438.2 1,747.1 138.6 53.2 246.5 1,573.8 681.7 19,656.9 358.8 142.7 NH3 0.9 10,731.2 0.0 28.8 112.4 2,275.7 1.1 721.7 193.7 55.4 2,802.3 137.6 1,005.7 79.8 11,034.4 This section includes emissions from on-site industrial incinerators, primarily burn-off ovens used to reclaim electric wire or other materials. Emissions from human and animal crematories are addressed in Section 3.5.4. There were no incinerators at residential (e.g., apartment complexes) or commercial/institutional facilities (e.g., hospitals, service establishments) in operation during 2008. 2008 Maricopa Co. PM10 Emission Inventory 48 June 2010 Emissions from on-site incineration were determined from annual emission inventory reports. It is assumed that all incinerator emissions are accounted for, since all permitted incinerators received surveys in 2008. All surveyed facilities are located within the PM10 nonattainment area, thus total emissions for the county and NAA are equal. Table 3.4–1. Annual and typical daily emissions from on-site incineration. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Maricopa County 0.06 0.04 5.01 0.01 0.7 0.4 38.9 0.1 PM10 NAA 0.06 0.04 5.01 0.01 0.7 0.4 38.9 0.1 3.4.2 Open burning Emissions from controlled open burning are regulated by Maricopa County Air Pollution Control Regulations Rule 314 (Open Outdoor Fires), which requires a burn permit for open burning in Maricopa County. Burn permits are issued primarily for purposes of agricultural ditch bank and fence row burning, tumbleweed burning, land clearance, air curtain destructor burning of trees, and fire fighting training. Maricopa County’s burn permit data base was used to identify all burn permits issued during 2008. A total of 55 permits were issued during the year; however, not all permit applications contained the requested information that is needed to calculate emissions. Where data were missing, activity data for each permit category was grown from those permits that contained the necessary information, as follows: Total activity = ∑ activity reported × total number of permits issued number of permits with activity data Example: Total ditch 32 burn permits issued = 787,398 linear ft bank/fencerows = 541,336 linear ft (reported) × 22 permits with data Reported and estimated activity data for each open burning category are summarized in Table 3.4–2. Permits issued for firefighting training are addressed Section 3.5.1.2. Table 3.4–2. Summary of 2008 Maricopa County burn permit activity. Number of Total reported permits with Category Unit of measure activity activity data Ditchbank/fencerow Linear ft 541,336 22 Land clearance Acres 564 5 Air curtain Tons of Material Burned 70* 0 Tumbleweeds Piles 14 2 Total permits issued 32 12 7 4 Estimated total annual activity level 787,398 1,354 70 28 * Assumed that air curtain destructors burn 10 tons/day of brush/trees/vegetation. The above activity data were converted to tons material burned using fuel loading factors from AP-42, Table 2.5–5 (US EPA, 1992). The emission and loading factors used are shown in Table 3.4–3. As a conservative estimate, all particulate matter is presumed to be PM10 (and PM2.5). 2008 Maricopa Co. PM10 Emission Inventory 49 June 2010 Table 3.4–3. Emission and fuel loading factors for open burning. Emission factors (lbs/ton burned) Category PM10 PM2.5 NOx SOx NH3 Weeds, unspecified 15 15 4 N/A N/A Russian Thistle (tumbleweeds) 22 22 4 N/A N/A Orchard crops: Citrus 6 6 4 N/A N/A Fuel loading factor (tons/acre) 3.2 0.1 1.0 The following assumptions were made based on previous Maricopa County emission inventory and information from MCAQD's open burn program staff: • Ditch banks and fence rows in Maricopa County average 7 feet in width and are burned twice per year (MCESD, 1999). • A pile of tumbleweeds 15 feet in diameter and 5 feet high weighs 200 lbs (MCESD, 1993). This is equivalent to the AP-42 fuel loading factor for tumbleweeds (0.1 tons/acre). • Air curtain destructors burn between 7–10 tons of material per day (MCAQD, 2006). To calculate the annual amount of material burned on ditch banks and fence rows in Maricopa County, MCAQD estimated the area burned and then applied AP-42 fuel loading factor. The tons of material burned in ditch banks and fence rows in Maricopa County were estimated as follows: Material burned from = 787,398 ft length × 7 ft width × 3.2 tons/acre × 2 times/yr ditchbanks and fence rows 43,560 ft2/acre = 809.81 tons/yr Activity data for the other categories were similarly converted to derive the total mass of material burned using AP-42 fuel loading factors. Annual emissions were then calculated by multiplying the amount of material burned by AP-42 emission factors (listed in Table 3.4–3) for each open burning category. To account for unpermitted illegal outdoor burning, all calculated emissions estimates were multiplied by a factor of 2.87, based on complaints received in 2008 reporting suspected open or illegal outside burning in the County (158 complaints were received in 2008; thus 158 complaints/55 open burn permits = 2.87). Annual PM10 emissions from ditchbank and fence row burning = Total material burned × emission factor × unit conversion factor = 809.81 tons × 15 lbs/ton × 1 ton / 2,000 lbs = 6.07 tons/yr Total annual PM10 emissions including unpermitted burning = Calculated emissions from permit data × unpermitted burning adjustment factor = 6.07 tons/yr × 2.87 = 17.43 tons PM10/yr 2008 Maricopa Co. PM10 Emission Inventory 50 June 2010 Table 3.4–4 summarizes the 2008 emissions in Maricopa County from each category of open burning activity. Table 3.4–4. Annual and typical daily emissions from open burning in Maricopa County. Annual emissions (tons/yr) Typical daily emissions (lbs/day) NOx NOx Category Ton-equivalents PM10 PM2.5 PM10 PM2.5 Ditchbank/fencerow 809.8 17.45 17.45 4.65 179.0 179.0 47.7 Land clearance 4,331.5 93.32 93.32 24.89 717.9 717.9 191.4 Air curtain 70.0 0.60 0.60 0.40 4.6 4.6 3.1 Tumbleweeds 2.8 0.09 0.09 0.02 0.7 0.7 0.1 Totals: 111.46 111.46 29.96 902.2 902.2 242.4 It was assumed that open burning occurs 5 days per week (most burn permits are issued for weekdays but permits may be issued on weekends depending on circumstances). Open burning occurs year-round with the exception of ditch bank and fence row burning, which is not allowed during the CO season (November through January). PM10 typical daily emissions for Maricopa County were derived as follows: Typical daily PM10 emissions =annual PM10 emissions (tons/yr) × 2000 lbs/ton (burn days/week) × (burn weeks/year) Typical daily PM10 emissions from = 17.45 tons/yr × 2000 lbs/ton ditchbank/ fence row burning 5 days/wk × 39 wks/yr = 179.0 lbs PM10/day Table 3.4–4 above summarizes the typical daily emissions for Maricopa County from each open burning category. Annual and daily emissions for the nonattainment area were calculated by multiplying the percentage of agricultural and/or vacant land use within the PM10 nonattainment area by the County wide emissions estimates, results are shown in Table 3.4–5. (See Section 1.5.1 for a discussion of the land use data used.) Table 3.4–6 summarizes the annual emissions for the PM10 nonattainment area. Table 3.4–5. Surrogate land use classes and County:NAA activity ratios for burn permit categories. Surrogate land 2008 NAA:county Category use categories land use ratio Ditchbank/fencerow Agriculture 44.14 % Land clearance Vacant 21.22 % Air curtain Agriculture and vacant 23.91 % Tumbleweeds Agriculture and vacant 23.91 % Table 3.4–6. Annual and typical daily emissions from open burning in the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Category PM10 PM2.5 NOx PM10 PM2.5 NOx Ditchbank/fencerow 7.70 7.70 2.05 79.0 79.0 21.1 Land clearance 19.81 19.81 5.28 152.4 152.4 40.6 Air curtain 0.14 0.14 0.10 1.1 1.1 0.7 Tumbleweeds 0.02 0.02 0.00 0.2 0.2 0.0 Totals: 27.67 27.67 7.44 232.6 232.6 62.5 2008 Maricopa Co. PM10 Emission Inventory 51 June 2010 3.4.3 Landfills Emissions from municipal solid waste (MSW) landfills come from uncontrolled landfill gas emissions as well as from cover operations and combustion from control measures, such as a flare. Total emissions were calculated from annual emissions inventory reports from all landfills located within the county; results are shown in Table 3.4–7 below. No landfills were considered point sources; thus all MSW landfills are reported here as an area-source activity. Table 3.4–7. Annual and typical daily emissions from landfills. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Maricopa County 86.21 75.92 24.11 7.57 486.07 425.39 132.93 41.71 PM10 NAA 60.25 50.78 19.47 6.22 342.45 286.57 107.42 34.29 3.4.4 Publicly owned treatment works (POTWs) Emissions from publicly owned treatment works (POTWs) were calculated by multiplying percapita emission factors (Battye et al., 1994) by population estimates and per-capita wastewater usage estimates of 100 gallons per day per person (Tchobanoglous, 1979), as shown in Table 3.4–8. Typical daily emissions were calculated by dividing annual emissions by 366 days, as activity is assumed to occur uniformly throughout the year. Table 3.4–8. NH3 emissions from publicly-owned treatment works (POTWs). Annual NH3 Typical daily NH3 2008 NH3 emission factor emissions emissions Geographic area Population (lbs/106 gals treated) (tons/yr) (lbs/day) Maricopa County 4,279,760 19.0 1,488.07 8,131.5 PM10 NAA 4,297,140 19.0 1,494.12 8,164.6 3.4.5 Other industrial waste disposal Annual area-source emissions from other industrial waste disposal were derived from annual emissions reports from permitted facilities. Other industrial waste disposal processes include a wide array of industrial activities that are often specific to the permitted facility that reported the process. For this reason, it is assumed there are no significant emissions from this category, other than those reported by permitted facilities on their annual emissions reports. Typical daily emissions were calculated based on operating schedule information provided by the facilities in their annual emissions report. Emission estimates are shown in Table 3.4–9 below. All facilities that reported area-source emissions from other industrial waste disposal are located inside the PM10 nonattainment area, therefore emissions for Maricopa County and the PM10 NAA are equal. Table 3.4–9. Annual and typical daily emissions from other industrial waste disposal. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Maricopa County 32.78 16.93 18.39 50.62 224.1 110.9 101.0 278.2 PM10 NAA 32.78 16.93 18.39 50.62 224.1 110.9 101.0 278.2 2008 Maricopa Co. PM10 Emission Inventory 52 June 2010 3.4.6 Summary of all area-source waste disposal Tables 3.4–10 and 3.4–11 provide a summary of annual and typical daily emissions from all waste disposal activity, for Maricopa County and the PM10 nonattainment area, respectively. Table 3.4–10. Annual and typical daily emissions from all area-source waste disposal for Maricopa County. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 On-site incineration 0.06 0.04 5.01 0.01 0.7 0.4 38.9 0.1 Open burning 111.46 111.46 29.96 902.2 902.2 242.4 Landfills 86.21 75.92 24.11 7.57 486.1 425.4 132.9 41.7 POTWs 1,488.07 8,131.5 Other 32.78 16.93 18.39 50.62 224.1 110.9 101.0 278.1 Total: 230.52 204.35 77.47 58.20 1,488.07 1,613.0 1,438.8 515.3 320.0 8,131.5 Table 3.4–11. Annual and typical daily emissions from all area-source waste disposal for the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 On-site incineration 0.06 0.04 5.01 0.01 0.7 0.4 38.9 0.1 Open burning 27.67 27.67 7.44 232.62 232.62 62.46 Landfills 60.25 50.78 19.47 6.22 342.4 286.6 107.4 34.3 POTWs 1,494.12 8,164.6 Other 32.78 16.93 18.39 50.62 224.1 110.9 101.0 278.1 Total: 120.77 95.42 50.30 56.85 1,494.12 799.8 630.5 309.9 312.6 8,164.6 3.5 Miscellaneous area sources 3.5.1 Other combustion 3.5.1.1 Wildfires Data on wildfires in 2008 within Maricopa County were obtained from the Arizona State Land Department (ASLD) Forestry Division (ASLD, 2009); the Arizona Department of Fire, Building, and Life Safety (DFBLS, 2009); and the Federal Fire Occurrence website (FFOW, 2009). The ASLD Forestry Division provides for the prevention and suppression of wildfires on state and private lands located outside of incorporated municipalities. The wildfire data provided by ASLD includes wildfires that occur outside of local fire districts and municipalities on State, private, and U.S. Bureau of Land Management (BLM) land in 2008. The ASLD reported 25 wildfires in 2008 in Maricopa County, encompassing a total of nearly 750 acres. Wildfire data provided by ASLD were compared to that data reported in the Geospatial Multi-Agency Coordination Group (GeoMAC) Wildland Fire Support database 1 and 2008 Incident Status Summary reports (ICS-209) to identify wildfires that may have occurred outside of ASLD jurisdiction. GeoMAC and ICS-209 reports only include large wildfires, generally fires greater than 100 acres. Three Maricopa County wildfires were reported in GeoMAC and on ICS-209 reports in 2008 (USDA, 2008a; USGS, 2008). Two of these fires were included in the ASLD data, one fire, the Ethan fire, was not captured in the ASLD data because it occurred on tribal lands. The Ethan fire encompassed 6,660 acres. 1. The GeoMAC, is an internet-based mapping application designed for fire managers to access online maps of current fire locations and perimeters in the conterminous 48 States and Alaska. Historical fire data is also housed in the GeoMac database http://www.geomac.gov/. 2008 Maricopa Co. PM10 Emission Inventory 53 June 2010 The DFBLS coordinates reporting to the National Fire Incident Reporting System (NFIRS) for Arizona fire departments. NFIRS is a national reporting system used by fire departments to report fires and other incidents to which they respond and to maintain records of these incidents in a uniform manner. Twenty-one of thirty-six fire departments in Maricopa County reported over 10,000 fires to NFIRS in 2008. This included ten “forest, woods or wildland fires”. The ten “forest, woods or wildland fires” were analyzed for inclusion in the wildfire emission estimates. First, the DFBLS fires were culled for duplicates by comparing the incident dates and locations with wildfires reported by ASLD. One DFBLS fire was excluded from combined dataset because it may have been a duplicate already captured in the ASLD data. Because only four of the ten DFBLS fires included acreage, an average number of acres burned per fire (= 1.05 acres) were determined from the fires with reported acreage. This average number of acres burned was then applied to the fires with no reported acreage. The Federal Fire Occurrence Website is an official government website that provides users with the ability to query, research and download wildland fire occurrence data. The data available through this website contains over 548,000 fire records collected by Federal land management agencies for fires that occurred from 1980 through 2008 in the United States. The 2008 data for Maricopa County included eighty-one fires. The federal wildland fire occurrence data were culled for duplicates by comparing the incident names, dates and locations with wildfires reported by ASLD and DFBLS. Thirteen fires were excluded from the combined dataset as they appeared to be duplicates already captured in either the ASLD or DFBLS data and seven fires contained no acreage data. The final 2008 dataset listed 96 fires encompassing over 7,400 acres. Table 3.5–1 summarizes fire data obtained from each data source. Table 3.5–1. Sources and input data used to estimate emissions from fires in Maricopa County. Number of Total Data Source Fires in 2008 Acreage Arizona State Land Department (ASLD) 25 747.25 Arizona Department of Fire, Building, and Life Safety (DFBLS) 9 9.45 Federal Fire Occurrence website (FFOW) 61 16.79 ICS-209 1 6,660.00 Total: 96 7,433.49 Estimates for fuel loading rates were assigned using fuel model codes from the National Fire Danger Rating System (NFDRS) and a table of fuel loading values for NFDRS fuel model categories (WGA/WRAP, 2005). The department used the NFDRS Fuel Model map in ArcGIS to identify NFDRS fuel types for fires with latitude and longitude data. Table 3.5–2. NFDRS fuel model categories and fuel loading factors for 2008 Maricopa County wildfires. Fuel Loading Factor (tons/acre) NFDRS Model Category 2008 Fires Total Acreage Agriculture* 33 744.05 4.5 California chaparral 1 0.01 19.5 Barren* 2 0.4 0.5 Pine-grass savanna 1 0.01 4.7 Intermediate brush 17 2.87 15.0 Sagebrush grass 42 6,686.15 4.5 Total 96 7,433.49 — * “Agriculture” and “barren” NFDRS model descriptions were not included in WGA/WRAP 2002 fuel loading values for NFDRS fuel model categories. Therefore, it was assumed that “Agriculture” is similar to "sagebrush grass" and “Barren” is similar to “western grasses (annual) and fuel loadings were assigned accordingly. 2008 Maricopa Co. PM10 Emission Inventory 54 June 2010 Estimates of the material burned were derived by multiplying the number of acres burned for each category by the applicable fuel loading factor. Table 3.5–3 shows the number of wildfires and acres burned within both Maricopa County and the PM10 nonattainment area during 2008, as well as estimates of total material burned. Table 3.5–3. Summary of data on fire occurrence, total acres burned, and total material burned in 2008. Total Acres Material Burned Geographic Area No. of Fires Burned (tons) 96 7,433 33,479 Maricopa County 55 6,699 30,147 PM10 NAA The prescribed-fire emission factors listed in Table 3.5–4 were obtained from the Western Regional Air Partnership's (WRAP) 2002 Fire Emission Inventory (WGA/WRAP, 2005). Table 3.5–4. Summary of emission factors for prescribed fire. PM10 PM2.5 WRAP Emission Factors for Wildfires and Prescribed Broadcast Burning (lbs/ton) 28.1 24.1 NOx SOx NH3 6.2 1.7 1.3 Source: WGA/WRAP, 2005 Annual emissions from wildfires for each geographic area were calculated as follows: Annual PM10 emissions from wildfires in Maricopa County = material burned × emission factor (lbs/ton) 2,000 lbs/ton = 33,479 tons of material burned × 28.1 lbs PM10/ton 2,000 lbs/ton = 470.38 tons PM10/yr The majority of fire data included fire locations in latitude and longitude. For those fires without longitude and latitude, the fire location address was used to determine latitude and longitude. This latitude and longitude data was used to determine the number of acres burned inside of the nonattainment areas. Fifty-five wildfires occurred within the PM10 nonattainment area, resulting in nearly 6,700 acres burned. The largest fire within the PM10 nonattainment area was the Ethan fire which occurred in July 2008 and resulted in more than 6,600 acres burned. Annual emissions from wildfires within the nonattainment area were calculated in the same method as Maricopa County annual emissions. Table 3.5–5. Annual emissions from wildfires in Maricopa County and the PM10 NAA. Annual emissions (tons/yr) Geographic Area PM10 PM2.5 NOx SOx NH3 Maricopa County 470.39 403.43 103.79 28.46 21.76 PM10 NAA 423.56 363.27 93.46 25.62 19.60 Average daily emissions were estimated by dividing annual emissions by the number of burn days in 2008. There were 150 burn days in Maricopa County and 90 burn days in the PM10 nonattainment area in 2008; thus: Average daily PM10 emissions from = 470.39 tons PM10/yr × 2,000 lbs/ton wildfires in Maricopa County 150 days/yr = 6,271.8 lbs PM10/day 2008 Maricopa Co. PM10 Emission Inventory 55 June 2010 Table 3.5–6. Average daily emissions from wildfires in Maricopa County and the PM10 NAA. Number of Average daily emissions (lbs/day) Burn Days Geographic Area PM10 PM2.5 NOx SOx NH3 Maricopa County 150 6,271.8 5,379.0 1,383.8 379.4 290.2 PM10 NAA 90 9,412.5 8,072.7 2,076.8 569.4 435.5 3.5.1.2 Prescribed fires Prescribed fires data were obtained from the U. S. Forest Service (USFS, 2009). The USFS reported that six prescribed fires occurred in Maricopa County in 2008. Twenty-nine acres of piled fuels were burned. Four of six prescribed fires occurred inside the PM10 nonattainment area. Because all 2008 prescribed fires were piled fuels, material burned was derived by multiplying the number of acres burned by tons of piles per acre for each fire. The data provided by the USFS, the resulting material burned for each fire, and whether the fire occurred within the nonattainment area are shown below in Table 3.5–7. Table 3.5–7. Burn Date 01/13/2008 03/13/2008 04/04/2008 04/09/2008 09/25/2008 11/06/2008 Summary of data used to estimate emissions from prescribed fires. Burn Burn Acres Tons of Material Number Location Treated Piles/ Acre Burned (tons) TNF0106 T6N,R7E,S28 3 1 3 TNF0106P T6N,R7E,S28 3 3 9 TNF0302 T3N,R7E,S34 2 5 10 TNF0302 T3N,R8E,S28 5 5 25 TNF0302 T3N,R8E,S31 10 5 50 TNF0302 T2N,R7E,S18 6 5 30 29 24 127 Within NAA? Yes Yes Yes No No Yes Prescribed fire emission factors for “piled fuels” were obtained from the Western Regional Air Partnership’s (WRAP) 2002 Fire Emission Inventory (WGA/WRAP, 2005). The emission factors are listed below in Table 3.5–8. Table 3.5–8. Emission factors for prescribed fires. Emission factors (lbs/ton burned) PM10 PM2.5 NOx SOx NH3 Type of fire Prescribed fire (piled fuels) 8.0 8.0 6.2 1.7 0.5 2008 Maricopa Co. PM10 Emission Inventory 56 June 2010 Annual emissions from prescribed fires in Maricopa County were calculated as follows. Annual PM10 emissions = material burned (tons/acre) × emission factor (lbs/ton) from prescribed fires 2,000 lbs/ton in Maricopa County = 127 tons/acres× 8.0 lbs/ton 2,000 lbs/ton = 0.508 tons PM10/yr It was assumed that each prescribed fire lasted one day. Thus, daily emissions from prescribed fires were determined by dividing the annual emissions (converted to lbs/yr) by the number of burn days. Because six prescribed fires occurred in Maricopa County in 2008, it was assumed that there were 6 burn days in 2008. Typical daily PM10 emissions = annual PM10 emissions (lbs) from prescribed fires Number of burn days = 1,016 lbs PM10 6 burn days = 169.3 lbs PM10/day Since the prescribed fire data provided by USFS (2009) included burn location, GIS was used to determine the fires that burned inside the nonattainment area. Fifty-two of the one-hundred twenty-seven acres burned were within the nonattainment area. Thus, annual emissions from prescribed fires for the nonattainment area were determined using the formula shown above with the material burned within the nonattainment area. Results are shown in Table 3.5–9 below. Table 3.5–9. Annual and typical daily emission from prescribed fire in Maricopa County and the PM10 NAA. Annual emissions (tons/yr) Typical daily emission (lbs/day) Geographic Area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Maricopa County 0.51 0.51 0.39 0.11 0.03 169.3 169.3 131.2 36.0 10.6 PM10 NAA 0.21 0.21 0.16 0.04 0.01 104.0 104.0 80.6 22.1 6.5 3.5.1.3 Structure fires 2008 structure fire data were from the Arizona Department of Fire, Building, and Life Safety (DFBLS; DFBLS, 2009). The DFBLS coordinates reporting to the National Fire Incident Reporting System (NFIRS) for Arizona fire departments. The NFIRS is a national reporting system used by fire departments to report fires and other incidents to which they respond and to maintain records of these incidents in a uniform manner. Twenty-one of thirty-six fire departments in Maricopa County reported over 10,000 fires to NFIRS in 2008. This included nearly 2,150 reported structure fires. Because the DFBLS data only included data reported by twentyone of thirty-six fire departments in Maricopa County, the number of structure fires reported were scaled up to the entire inventory area based on population. The most recent population estimates for Maricopa County were used to scale up the number of structure fires (ADC, 2008). Seven open burn permits were issued in 2008 for fire training; these were included in the total number of estimated structure fires for 2008. It was estimated that 2,422 structure fires occurred in Maricopa County in 2008. 2008 Maricopa Co. PM10 Emission Inventory 57 June 2010 Estimates of the material burned in a structure fire were determined by multiplying the number of structure fires by a fuel loading factor of 1.15 tons of material per fire, which factors in the estimated percentage of structural loss and content loss (US EPA, 2001c). The amount (tons) of material burned was estimated as follows: Material burned in structure fires (tons/yr) = 2,422 fires/yr × 1.15 tons/fire = 2,785 tons material burned/yr Table 3.5–10. Material burned, emission and fuel loading factors for structure fires. Emission factors (lbs/ton) Estimated number Fuel loading Material burned of structure fires factor (tons/fire) (tons) PM10 PM2.5* NOx SOx 2,422 1.15 2,785 10.8 10.8 1.4 n/a NH3 n/a * All PM10 is assumed to be PM2.5. Annual emissions were then calculated by multiplying the amount of material burned by the emission factors listed in Table 3.5–10 (from US EPA, 2001c), as follows: Annual PM10 emissions from structure fires in Maricopa County = Quantity of material burned × emission factor × unit conversion factor = 2,785 tons × 10.8 lbs/ton × (1 ton/2,000 lbs) = 15.04 tons PM10/yr Annual emissions for the PM10 nonattainment area were derived by multiplying Maricopa County annual emissions by the percentage of total residential population within the PM10 nonattainment area (100.41%), as shown in the example below. See Section 1.5.2 for a discussion of the population data used. Annual PM10 emissions = Annual PM10 emissions × Percentage residential population within the NAA for Maricopa County within the PM10 NAA = 15.04 tons/yr × 100.41% = 15.10 tons PM10/yr Typical daily emissions for both Maricopa County and the PM10 nonattainment area were calculated by dividing annual emissions by 366, as activity is assumed to take place 7 days a week. Typical daily emissions for Maricopa County were derived using the following formula: Typical daily PM10 emissions from structure fires = annual PM10 emissions (lbs) 366 days/yr = 30,080 lbs 366 = 82.2 lbs/day Table 3.5–11. Annual and typical daily emissions from structure fires in Maricopa County and the NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx PM10 PM2.5 NOx Maricopa County 15.04 15.04 1.95 82.2 82.2 10.7 PM10 NAA 15.10 15.10 1.96 82.5 82.5 10.7 2008 Maricopa Co. PM10 Emission Inventory 58 June 2010 3.5.1.4 Vehicle fires 2008 vehicle fire data were from the Arizona Department of Fire, Building, and Life Safety (DFBLS) (DFBLS, 2009). The DFBLS coordinates reporting to the National Fire Incident Reporting System (NFIRS) for Arizona fire department. NFIRS is a national reporting system used by fire departments to report fires and other incidents to which they respond and to maintain records of these incidents in a uniform manner. Twenty-one of thirty-six fire departments in Maricopa County reported over 10,000 fires to NFIRS in 2008. This included over 2,100 reported vehicle fires. Because the DFBLS data only included data reported by twenty-one of thirty-six fire departments in Maricopa County, the number of vehicle fires reported were scaled up to the entire inventory area based on population. The most recent population estimates for Maricopa County were used to scale up the number of vehicle fires (ADC, 2008). It was estimated that 2,403 vehicle fires occurred in Maricopa County in 2008. Annual emissions from vehicle fires were calculated by first multiplying the number of vehicle fires by a fuel loading factor of per vehicle fire to estimate the annual amount of material burned in vehicle fires (US EPA, 2000). The amount of annual material burned in vehicle fires is then multiplied by emission factors for open burning of automobile components from AP-42 as listed in table 3.5–12 (US EPA, 1992). Annual PM10 emissions = annual number × fuel loading factor × emission factor × unit conversion factor from vehicle fires of vehicle fires = 2,403 × 0.25 tons/vehicle × 100 lbs/ton × (1 ton / 2,000 lbs) = 30.04 tons PM10/yr Table 3.5–12. Estimated material burned, fuel loading factors, and emission factors for vehicle fires. Emission factors (lbs/ton) Vehicle fires Fuel loading Material PM10 PM2.5* NOx SOx NH3 reported factor (tons/fire) burned (tons) 2,403 0.25 600.75 100 100 4 n/a n/a * All PM10 is assumed to be PM2.5. Annual emissions for the PM10 nonattainment area were derived by multiplying Maricopa County annual emissions by the percentage of total residential population within the PM10 nonattainment area (100.41%). See Section 1.5.1 for a discussion of the population data used. Annual PM10 emissions from vehicle fires in the PM10 NAA = annual PM10 emissions for Maricopa County × percentage of total residential population within the PM10 NAA = 30.04 tons/yr = 30.16 tons/yr × 100.41% It is assumed that vehicle fires occur evenly throughout the year. Thus, typical daily emissions were derived by dividing the Maricopa County and nonattainment area annual emissions by 366 days/year. The results are shown in Table 3.5–13 below. Table 3.5–13. Annual and typical daily emissions from vehicle fires. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx PM10 PM2.5 NOx Maricopa County 30.04 30.04 1.20 164.1 164.1 6.6 PM10 NAA 30.16 30.16 1.21 164.8 164.8 6.6 2008 Maricopa Co. PM10 Emission Inventory 59 June 2010 3.5.1.5 Engine testing Annual emissions from engine testing facilities were derived from annual emission reports from permitted sources that were not considered point sources in this inventory. It was assumed that there were no significant unpermitted sources within Maricopa County. Typical daily emissions were calculated based on operating schedule information provided in the facilities’ annual emission reports. Since all facilities considered in this section are located within the PM10 nonattainment area, total emission values for the county and the PM10 NAA are equal. Results are shown in Table 3.5–14. Table 3.5–14. Annual and typical daily emissions from engine testing. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Maricopa County 0.18 0.17 6.74 2.49 1.3 1.2 50.5 19.0 PM10 NAA 0.18 0.17 6.74 2.49 1.3 1.2 50.5 19.0 3.5.2 Agricultural activities 3.5.2.1 Tilling Tillage emissions were estimated using the tillage emission factor equation and Maricopa County specific soil silt content for agricultural land (URS and ERG, 2001). The majority of planted acres were obtained from the 2008 Arizona Agricultural Statistics Bulletin (AASS, 2009). Planted acres for potatoes and sorghum for grain were obtained from the USDA National Agricultural Statistics Service for 2008 (USDA, 2008b) and vegetables and citrus acreage were obtained from the 2007 Census of Agriculture (USDA, 2007a). Crop-specific annual land preparation operations data were obtained from the Technical Support Document for Quantification of Agricultural Best Management Practices (URS and ERG, 2001). The agricultural tillage emission factor was calculated as follows: EF = k (4.8) s0.6 where: EF = Agricultural emission tillage factor (lbs PM10/acre-pass) k = Particle size multiplier (value of 0.15 for PM10) s = Silt content of soil (%) = 35.2% (URS and ERG, 2001) Thus: EF = 0.15 × 4.8 × (35.2)0.6 = 6.10 lbs PM10/acre-pass 2008 Maricopa Co. PM10 Emission Inventory 60 June 2010 Annual PM10 emissions from agricultural tillage were calculated for each crop category using the following equation (URS and ERG, 2001; Pollack et al., 2003): TillageCrop = EF × APCrop × ACrop where: TillageCrop EF APCrop ACrop = = = = Annual PM10 emissions from tilling each crop type (lbs) Tillage emission factor (lbs PM10/acre-pass) Number of tillage passes per crop (passes) Total number of tilled acres for each crop type (acres) For example, annual PM10 emissions from cotton tilling were calculated using: EF APcotton APcotton = 6.10 lbs PM10/acre-pass = 8.8 tillage passes for a cotton crop = 19,300 acres cotton Thus: Tillagecotton = 6.10 × 8.8 × 19,300 = 1,036,024 lbs/yr = 518.01 tons/yr Table 3.5–15 lists crop types and acreage; typical number of land preparation operations and acre-passes; and annual uncontrolled PM10 emissions from agricultural tillage for Maricopa County. Table 3.5–15. 2008 crop acreage, activity, and annual uncontrolled PM10 emissions in Maricopa County. No. of land Acres preparation Annual uncontrolled Crop Planted operations/yr Acre-passes PM10 emissions (tons/yr) Cotton 19,300 8.8 169,978 518.43 Corn 11,500 7.3 84,180 256.75 Wheat 30,500 3.1 93,488 285.14 Barley 10,100 2.1 20,856 63.61 Alfalfa (stand establishment)1 21,875 5.1 110,469 336.93 Potatoes 1,400 10.6 14,805 45.16 Sorghum for grain 16,500 3.1 50,575 154.25 Vegetables2 16,072 14.0 224,888 685.91 Citrus3 425 5.0 2,124 6.48 Totals: 127,672 2,352.66 1. 2. 3. Alfalfa is a multi-year crop and alfalfa stand establishment is assumed to occur once every 4 years to approximately 25% of the total alfalfa acreage (URS and ERG, 2001). Including melons, not including potatoes. 15 to 20% of citrus orchard acreage is non-bearing in a given year (URS and ERG, 2001); therefore, tillage is assumed to occur in 20% of the reported harvested acreage. In November 2007, the agricultural PM10 general permit (Arizona Administrative Code R18-2610 and R18-2-611) was expanded to apply to commercial farming practices within the Maricopa County portion of Area A. Previously this rule only applied to the Maricopa County PM10 NAA. The agricultural PM10 general permit revisions also resulted in the requirement for commercial farmers to implement six agricultural best management practices (BMP) (up from 3 BMPs) to control PM10 emissions generated from tillage and harvest, non-cropland, and cropland. Because no data is available on the additional BMPs being implemented, MCAQD used the net control efficiencies from the implementation of agricultural BMPs developed by 2008 Maricopa Co. PM10 Emission Inventory 61 June 2010 URS and ERG (2001) in the Technical Support Document for Quantification of Agricultural BMPs. URS and ERG quantified three BMPs for tillage: 1) combining tractor operations, 2) limited activity during high-wind events, and 3) multi-year crops. URS and ERG (2001) derived net control efficiencies by multiplying mid-point BMP control efficiency by a compliance factor and a relevancy factor for applicable crops. MCAQD has used the same mid-point BMP control efficiency and relevancy factor with a revised compliance factor of 55% (from 80%). The revised compliance factor was derived based on latest EPA rule effectiveness guidance (US EPA, 2005) which eliminates use of the 80% default rule effectiveness value. (Rule effectiveness calculations for agricultural activities are included as Appendix 3). To estimate controlled tillage emissions from agricultural operations taking place within the Maricopa County portion of Area A, the mid-point net control efficiency for each BMP were applied to 63.09% (the percent of agricultural land in the Maricopa County portion of Area A) of the uncontrolled annual emissions (MAG, 2009) as follows: Controlled annual = Annual uncontrolled PM10 emissions tillageCrop emissions × (100% – mid-point net control efficiencycrop) × % agricultural land in the Area A Controlled annual = 518.01 tons PM10/yr tillageCotton emissions = 252.30 tons PM10/yr × (100% – 22.8%) × 63.09% The uncontrolled portion of tillage emissions from agricultural operations taking place outside Area A but within Maricopa County were estimated by multiplying the uncontrolled annual PM10 emissions by the percentage of agricultural land located within Maricopa County but outside of Area A (100% – 63.09%) as follows: Uncontrolled annual = Uncontrolled annual PM10 emissions tillageCrop emissions = 518.01 tons PM10/yr = 191.20 tons PM10/yr × 36.91% × 36.91% Controlled and uncontrolled emissions were then summed to estimate total annual PM10 emissions from agricultural tillage in Maricopa County. Annual PM2.5 emissions from agricultural tillage were calculated by multiplying the annual PM10 emissions by a conversion factor of 0.15 (WRAP, 2006b). Annual PM10 and PM2.5 emissions from agricultural tillage in Maricopa County and Area A are shown in Table 3.5–16. 2008 Maricopa Co. PM10 Emission Inventory 62 June 2010 Table 3.5–16. Annual emissions from agricultural tillage in Maricopa County and Area A (tons/yr). Net Outside control Area A Area A Maricopa Co. (Area efficiency (controlled) (uncontrolled) A + outside Area A) Crop (%) PM10 PM2.5 PM10 PM10 PM2.5 Cotton 22.8% 252.36 37.85 191.35 443.72 66.56 Corn 22.8% 124.98 18.75 94.77 219.75 32.96 Wheat 22.8% 138.80 20.82 105.24 244.04 36.61 Barley 22.8% 30.96 4.64 23.48 54.44 8.17 Alfalfa (stand establishment) 13.8% 183.23 27.49 124.36 307.60 46.14 Potatoes 16.8% 21.98 3.30 16.67 38.65 5.80 Sorghum for grain 22.8% 75.09 11.26 56.94 132.02 19.80 Vegetables 16.8% 359.82 53.97 253.17 612.99 91.95 Citrus 16.8% 3.40 0.51 2.39 5.79 0.87 Totals: 1,190.63 178.59 868.37 2,059.00 308.85 *Includes melons, excludes potatoes. Annual PM10 emissions from agricultural tillage in the PM10 NAA were calculated in the same manner as the annual PM10 emissions for the Maricopa County portion of Area A; the only difference being the percent of agricultural land located within the Maricopa County PM10 NAA is 44.14% (rather than 63.09% for Area A). Results are shown in Table 3.5–17. Table 3.5–17. Annual emissions from agricultural tillage in the PM10 NAA (tons/yr). Net Control Fraction of PM10 NAA Efficiency Ag Land in annual emissions Crop (%) PM10 NAA PM10 PM2.5 Cotton 22.8% 44.14% 176.56 26.48 Corn 22.8% 44.14% 87.44 13.12 Wheat 22.8% 44.14% 97.11 14.57 Barley 22.8% 44.14% 21.66 3.25 Alfalfa (stand establishment) 13.8% 44.14% 128.20 19.23 Potatoes 16.8% 44.14% 16.57 2.49 Sorghum for grain 22.8% 44.14% 52.53 7.88 Vegetables 16.8% 44.14% 251.75 37.76 Citrus 16.8% 44.14% 2.38 0.36 Totals: 834.20 125.13 Typical daily emissions for Maricopa County, Area A, and the PM10 NAA were calculated by dividing the annual emissions by estimated days per year of tillage operation by crop. The number of days of tillage operations was estimated using the calendar of tillage operations by crop in the Technical Support Document for Quantification of Agricultural BMPs (URS and ERG, 2001) and assuming tillage activities occur 7 days per week during the months of tillage operations. Results are shown in Table 3.5–18. The calendar of tillage operations did not include months of tillage operations for citrus, thus, a conservative estimate of three (3) months per year was assumed. 2008 Maricopa Co. PM10 Emission Inventory 63 June 2010 Table 3.5–18. Controlled typical daily emissions from tillage (in lbs/day). Tillage Tillage Maricopa County Area A operations1 operations Crop (months/yr) (days/yr) PM10 PM2.5 PM10 PM2.5 Cotton 12 364 2,438.0 365.7 1,386.6 208.0 Corn 5 152 2,897.8 434.7 1,648.1 247.2 Wheat 8 243 2,011.3 301.7 1,143.9 171.6 Barley 8 243 448.7 67.3 255.2 38.3 Alfalfa (stand establishment) 3 91 6,760.3 1,014.1 4,027.1 604.1 Potatoes 6 182 424.7 63.7 241.6 36.2 Sorghum for grain 8 243 1,088.1 163.2 618.9 92.8 Vegetables 6 182 6,736.2 1,010.4 3,954.1 593.1 Citrus 3 91 127.2 19.1 37.3 5.6 Totals: 22,932.4 3,439.9 13,312.8 1,996.9 1 PM10 NAA PM10 970.1 1,153.1 800.3 178.6 PM2.5 145.5 173.0 120.1 26.8 2,817.5 182.1 433.0 2,766.4 26.1 9,327.3 422.6 27.3 64.9 415.0 3.9 1,399.1 Source: URS and ERG (2001), Table 3-2, p. 3-5. 3.5.2.2 Harvesting Harvest emissions were estimated using crop-specific emission factors (CARB, 2003). The majority of harvest acres were obtained from the 2008 Arizona Agricultural Statistics Bulletin (AASS, 2009). Harvest acres for potatoes were obtained from the USDA National Agricultural Statistics Service for 2008 (USDA, 2008b) and vegetables and citrus were obtained from the 2007 Census of Agriculture (USDA, 2007a). Table 3.5–19 lists the crop types, acres harvested and associated PM10 emission factors used to calculate emissions from agricultural harvesting. Table 3.5–19. Maricopa County harvested acres and emission factors. PM10 emission 2008 factor (lb/acre-yr) Acreage Crop Cotton 3.4 18,800 Wheat 5.8 30,100 Barley 5.8 9,900 Alfalfa Hay 0.0 83,000 Other Hay 1.68 4,500 Corn 1.68 700 Sorghum for Grain** 5.8 2,200 Potatoes 2.7 1,400 Vegetables* 0.08 16,072 Citrus 0.08 2,124 Total 168,796 *Includes melons, exclude potatoes. ** Assumed same emission factor, control efficiency, and number of harvest days per year as wheat and barley. Annual PM10 emissions from agricultural harvesting were calculated using the following equation: Uncontrolled annual harvestCrop emissions = EF×ACrop×ton / 2,000 lb where: harvestCrop EFCrop ACrop = harvest emissions for each crop type (tons PM10/yr) = harvest emission factor (lbs PM10/acre) = number of harvested acres for each crop type per year Example: EFCotton = 3.4 lbs PM10/acre for cotton 2008 Maricopa Co. PM10 Emission Inventory 64 June 2010 ACotton = 18,800 acres of cotton Uncontrolled annual HarvestCotton Emissions = 3.4 lbs PM10/acre ×18,800 acres × 1 ton/2,000 lbs = 31.96 tons PM10/yr In November 2007, the agricultural PM10 general permit program (Arizona Administrative Code R18-2-610 and 611) was expanded to apply to commercial farming practices within the Maricopa County portion of Area A. (Previously this requirement had only applied to the Maricopa County PM10 NAA.) The agricultural PM10 general permit revisions also resulted in the requirement for commercial farmers to implement six agricultural best management practices (BMP) (up from 3 BMPs) to control PM10 emissions generated from tillage and harvest, noncropland, and cropland. Because no data is available on the additional BMPs being implemented, MCAQD used the net control efficiencies from the implementation of agricultural BMPs developed by URS and ERG (2001) in the Technical Support Document for Quantification of Agricultural BMPs. URS and ERG quantified two BMPs for harvesting: 1) combining tractor operations, and 2) reduced harvest activity. URS and ERG (2001) derived net control efficiencies by multiplying mid-point BMP control efficiency by a compliance factor and a relevancy factor for applicable crops. MCAQD has used the same mid-point BMP control efficiency and relevancy factor with a revised compliance factor of 55% (from 80%). The revised compliance factor was derived based on latest EPA rule effectiveness guidance (US EPA, 2005) which eliminates use of the 80% default rule effectiveness value. (Rule effectiveness calculations for agricultural activities are included as Appendix 3). To estimate controlled harvest emissions from agricultural operations taking place within the Maricopa County portion of Area A, the mid-point net control efficiency for each BMP were applied to 63.09% of the uncontrolled annual emissions (the percent of agricultural land in the Maricopa County portion of Area A) (MAG, 2009) as follows: Controlled annual harvestCrop emissions Controlled annual harvestCotton emissions from within the Maricopa Co. portion of Area A = annual uncontrolled PM10 emissions × (100% – mid-point net × % agricultural land control efficiencycrop) in the Maricopa Co. portion of Area A = 31.96 tons PM10/yr ×(100% – 25.6%) × 63.09% = 15.01 tons PM10/yr The uncontrolled portion of harvest emissions from agricultural operations outside the Maricopa County portion of Area A but within Maricopa County were estimated by multiplying the uncontrolled annual PM10 emissions by the percent of agricultural land located within Maricopa County but outside of the Area A (100% – 63.09%) as follows: Uncontrolled annual HarvestCotton emission from outside the Maricopa Co. portion of Area A = Uncontrolled PM10 emissions × 36.91% = 31.96 tons PM10/yr × 36.91% = 11.80 tons PM10/yr The total controlled and uncontrolled annual emissions were then summed to estimate total annual PM10 emissions from agricultural harvesting in Maricopa County as follows: 2008 Maricopa Co. PM10 Emission Inventory 65 June 2010 Total annual harvestCotton = Uncontrolled annual emissions for Maricopa harvestCotton emissions County from outside Area A = 11.80 + Controlled annual harvestCotton emissions from within the Maricopa Co. portion of Area A + 15.01 = 26.81 tons PM10/yr Annual PM2.5 emissions from agricultural harvesting were calculated by multiplying the annual PM10 emissions by a conversion factor of 0.15 (WRAP, 2006c). Annual PM10 and PM2.5 emissions from harvesting in Maricopa Co. and Area A are shown in Table 3.5–20. Table 3.5–20. Annual emissions from harvesting in Maricopa County and Area A (in tons/yr). Net Maricopa Outside Area control Co. Area A A Maricopa Co. (Area Crop efficiency Uncontrolled (controlled) (uncontrolled) A + outside Area A) (%) PM10 PM10 PM2.5 PM10 PM10 PM2.5 25.5% 31.96 15.02 2.25 11.80 26.81 4.02 Cotton 23.5% 87.29 42.15 6.32 32.22 74.37 11.16 Wheat 23.5% 28.71 13.86 2.08 10.60 24.46 3.67 Barley 27.6% 0.00 0.00 0.00 0.00 0.00 0.00 Alfalfa Hay 27.6% 3.78 1.73 0.26 1.40 3.12 0.47 Other Hay 23.5% 0.59 0.28 0.04 0.22 0.50 0.08 Corn 23.5% 6.38 3.08 0.46 2.35 5.44 0.82 Sorghum for Grain** 23.5% 1.89 0.91 0.14 0.70 1.61 0.24 Potatoes 23.5% 0.64 0.31 0.05 0.24 0.55 0.08 Vegetables* 23.5% 0.08 0.04 0.01 0.03 0.07 0.01 Citrus Total 161.33 77.39 11.61 59.54 136.93 20.54 *Includes melons, excludes potatoes. ** Assumed same emission factor, control efficiency, and number of harvest days per year as wheat and barley. Annual PM10 emissions from agricultural harvesting in the PM10 NAA were calculated in the same manner as the annual PM10 emissions for the Maricopa County portion of Area A. The only difference being the percent of agricultural land located within the Maricopa County PM10 NAA is 44.14% (rather than 63.09% for Area A). Results are shown in Table 3.5–21. Table 3.5–21. Annual emissions from harvesting in the PM10 NAA (tons/yr). Net control Fraction of PM10 NAA Crop efficiency Ag land in (controlled) (%) PM10 NAA PM10 PM2.5 25.5% 44.1% 10.51 1.58 Cotton 23.5% 44.1% 29.49 4.42 Wheat 23.5% 44.1% 9.70 1.45 Barley 27.6% 44.1% 0.00 0.00 Alfalfa Hay 27.6% 44.1% 1.21 0.18 Other Hay 23.5% 44.1% 0.20 0.03 Corn 23.5% 44.1% 2.16 0.32 Sorghum for Grain** 23.5% 44.1% 0.64 0.10 Potatoes 23.5% 44.1% 0.22 0.03 Vegetables* 23.5% 44.1% 0.03 0.00 Citrus Total 54.14 8.12 *Includes melons, excludes potatoes. ** Assumed same emission factor, control efficiency, and number of harvest days per year as wheat and barley. 2008 Maricopa Co. PM10 Emission Inventory 66 June 2010 Typical daily emissions for Maricopa County, Area A, and the PM10 NAA were calculated by dividing the annual emissions by the number of harvest days per year and multiplying the result by 2000 lbs/ton (URS and ERG, 2001). Because acres harvested were not reported for individual vegetables and citrus fruit, an average number of harvest days per year were used for vegetables and citrus (116 and 188 harvest days per year, respectively). Results are shown in Table 3.5–22. Table 3.5–22. Typical daily emissions from harvesting, by crop (in lbs/day). Area A Harvest Maricopa County PM10 PM2.5 PM10 PM2.5 Crop days/yr 143 375.0 56.2 210.0 31.5 Cotton 60 2,479.0 371.8 1,405.1 210.8 Wheat 60 815.3 122.3 462.2 69.3 Barley 294 0.0 0.0 0.0 0.0 Alfalfa Hay 294 21.2 3.2 11.7 1.8 Other Hay 91 11.0 1.7 6.2 0.9 Corn 60 181.2 27.2 102.7 15.4 Sorghum for Grain** 70 46.0 6.9 26.1 3.9 Potatoes 116 9.4 1.4 5.3 0.8 Vegetables* 188 0.8 0.1 0.4 0.1 Citrus Total 3,938.9 590.8 2,229.9 334.5 PM10 NAA PM10 PM2.5 146.9 22.0 983.0 147.5 323.3 48.5 0.0 0.0 8.2 1.2 4.4 0.7 71.8 10.8 18.2 2.7 3.7 0.6 0.3 0.0 1,560.0 234.0 *Includes melons, excludes potatoes. ** Assumed same emission factor, control efficiency, and number of harvest days per year as wheat and barley. 3.5.2.3 Travel on unpaved agricultural roads Resuspended PM10 emissions from travel on unpaved agricultural roads were estimated using an unpaved road emission factor derived from AP-42 13.2.2 (US EPA, 2006b). The unpaved road emission factor equation is shown below: Unpaved road emission factor (EF) (lb/VMT) = k (s/12)a (W/3)b where: s W k a b = = = = = surface material silt content mean vehicle weight (tons) 1.5 (PM10 constant; US EPA, 2006b) 0.9 (PM10 constant; US EPA, 2006b) 0.45 (PM10 constant; US EPA, 2006b) = 11.90% (MAG, 2000) = 2.80 (URS and ERG, 2001) Unpaved road emission factor (lb/VMT) = 1.5 (11.9/12)0.9 (2.8/3)0.45 = 1.444 lb/VMT Emissions were estimated using farm vehicle activity data obtained from the Technical Support Document for Quantification of Agricultural Best Management Practices (URS and ERG, 2001). URS and ERG (2001) estimated average daily vehicle miles traveled per 1,000 acres to be 49.5 VMT. Daily emissions from travel on unpaved agricultural roads were then estimated as follows: Daily uncontrolled PM10 = unpaved road EF × VMT/1000 acres × 2008 harvested acres 2008 Maricopa Co. PM10 Emission Inventory 67 June 2010 emissions from ag roads = 1.444 lbs/VMT ×49.5 VMT/1000 acres × 168,796 acres = 12,065 lbs/day In November 2007, the agricultural PM10 general permit (Arizona Administrative Codes R18-2610 and 611) was expanded to apply to commercial farming practices within the Maricopa County portion of Area A. Previously this rule only applied to the Maricopa County PM10 NAA. The agricultural PM10 general permit revisions also resulted in the requirement for commercial farmers to implement six agricultural best management practices (BMP) (up from 3 BMPs) to control PM10 emissions generated from tillage and harvest, non-cropland, and cropland. Because no data is available on the additional BMPs being implemented, MCAQD used the net control efficiencies from the implementation of agricultural BMPs developed by URS and ERG (2001) in the Technical Support Document for quantification of Agricultural BMPs. Two BMPs were quantified for unpaved road travel: 1) access restriction and 2) reduced vehicle speed. A 2001 study (URS and ERG, 2001) estimated net control efficiencies by multiplying a midpoint BMP control efficiency by a compliance factor and a relevancy factor for applicable crops. MCAQD has used the same mid-point BMP control efficiency and relevancy factor with a revised compliance factor of 55% (from 80%). The revised compliance factor was derived based on latest EPA rule effectiveness guidance (US EPA, 2005) which eliminates use of the 80% default rule effectiveness value. (Rule effectiveness calculations for agricultural activities are included as Appendix 3). To estimate controlled daily emissions from travel on unpaved agricultural roads within Area A, the mid-point net control efficiency for each BMP (0.4% and 11.6 %, respectively) were applied to 63.09 % (the percent of agricultural land in Area A) of the uncontrolled daily PM10 emissions as follows: Controlled daily unpaved ag road emissions within Area A = Daily uncontrolled PM10 emissions × (100%-mid-point net control efficiency) × % agricultural land in Area A = 12,065 lbs/day × (100% – 12.0%) × 63.09% = 6,698.4 lbs/day The uncontrolled portion of unpaved agricultural road daily emissions outside the Maricopa County portion of Area A but within Maricopa County were estimated by multiplying uncontrolled daily PM10 emissions by the percent of agricultural land located within Maricopa County but outside of Area A (100% – 63.09%) as follows: Uncontrolled daily unpaved ag road emissions from outside of Area A = Uncontrolled PM10 emissions × (100% - 63.09%) = 12,065 lbs/day × 36.91% = 4,453 lbs/day Total controlled and uncontrolled daily emissions were then summed to estimate total daily PM10 emissions from travel on unpaved agricultural roads in Maricopa County as follows: Total daily unpaved = Uncontrolled daily ag road emissions for unpaved ag road emissions Maricopa County from outside Area A + Controlled daily unpaved ag road emissions from within Area A = 4,453 2008 Maricopa Co. PM10 Emission Inventory + 68 6,698 June 2010 = 11,151 lbs PM10/day Daily PM10 emissions from unpaved agricultural roads in the PM10 NAA were calculated in the same manner as the daily PM10 emissions for the Maricopa County portion of Area A. The only difference being the percent of agricultural land located within the Maricopa County PM10 NAA is 44.14% (rather than 63.09% for Area A). Results are shown in Table 3.5–21. Annual emissions for Maricopa County, Area A and the PM10 NAA were calculated by multiplying daily emission estimates by 312 (=6 days per week × 52 weeks per year). Annual and daily PM2.5 emission from travel on unpaved agricultural roads were calculated by multiplying the annual and daily PM10 emissions by a conversion factor of 0.10 (WRAP, 2006c). Annual and daily PM10 and PM2.5 emissions from unpaved agricultural roads are shown in Table 3.5–23. Table 3.5–23. Annual and typical daily emissions from travel on unpaved agricultural roads. Annual emissions Typical daily emissions (tons/yr) (lbs/day) PM10 PM2.5 PM10 PM2.5 Geographic area Maricopa County (Area A + outside Area A) 1,739.52 173.95 11,150.8 1,115.1 Area A (controlled) 1,044.92 104.49 6,698.2 669.8 PM10 NAA (controlled) 731.03 73.10 4,686.1 468.6 3.5.2.4 Cotton ginning Annual emissions from cotton ginning were derived from annual emission reports from all permitted cotton gins in the county. Typical daily emissions were calculated based on the operating schedule data reported by surveyed facilities. Annual and typical daily emissions for the PM10 nonattainment area were derived based on the location data of the individual facilities. Table 3.5–24 summarizes annual and typical daily emissions from cotton gins in both Maricopa County and the PM10 nonattainment area. Table 3.5–24. Annual and typical daily emissions from area-source cotton ginning. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 PM10 PM2.5 Maricopa County 17.90 5.11 103.8 29.7 PM10 NAA 4.86 1.39 26.7 7.6 3.5.2.5 Fertilizer application Annual NH3 emissions from synthetic nitrogen fertilizers for 2008 were obtained from the US EPA 2008 National Emissions Inventory (US EPA, 2010). In 2005, MCAQD used the CMU Ammonia Model v.3.6 to calculate NH3 emissions from synthetic nitrogen fertilizers (MCAQD, 2007). The CMU Ammonia Model used semiannual sales data for 2002 from the Association of American Plant Food Control Officials and crop calendar information from National Agricultural Statistics Service (NASS) to estimate monthly 2008 Maricopa Co. PM10 Emission Inventory 69 June 2010 fertilizer application rates for each county. The activity data in the CMU Ammonia Model v.3.6 has not been updated and therefore, MCAQD was unable to use the model to calculated 2008 NH3 emissions. EPA, however, obtained county-level fertilizer consumption data for 2002 and 2007 from the Fertilizer Institute’s Commercial Fertilizer 2002 and 2007 reports and calculated the percent change in county-level fertilizer quantities applied between 2002 and 2007. EPA used the percent change in applied fertilizer quantity to grow the fertilizer activity files provided with the CMU Ammonia Model v.3.6. EPA then ran the CMU Ammonia Model with the updated county-level fertilizer quantities to calculate NH3 emissions. Typical daily NH3 emissions were derived by dividing annual emissions by 366 days/year. Annual and typical daily emissions for the PM10 nonattainment area were derived by multiplying the county annual and typical daily emissions by the percentage of agricultural land located in the PM10 NAA (44.1%). See Section 1.5.2 for a discussion of the land use data used. Annual and typical daily NH3 emissions from fertilizer application are shown in Table 3.5–25. Table 3.5–25. Annual and typical daily NH3 emissions from fertilizer application. Maricopa County PM10 NAA Fertilizer Category Anhydrous ammonia Aqueous ammonia Ammonium nitrate Ammonium sulfate Ammonium thiosulfate N-P-K (multi-grade nutrient fertilizers) Calcium ammonium nitrate Nitrogen solutions Urea Diammonium phosphate Monoammonium phosphate Liquid ammonium polyphosphate Potassium nitrate Miscellaneous Total 3.5.3 Annual Emissions (tons/year) 70.64 3.75 0.00 74.40 0.00 Daily NH3 Emissions (lbs/day) 386.0 20.5 0.0 406.5 0.0 Annual NH3 Emissions (tons/year) 31.18 1.65 0.00 32.84 0.00 Daily NH3 Emissions (lbs/day) 170.4 9.0 0.0 179.5 0.0 0.00 0.00 1,397.66 496.42 2.66 71.77 0.0 0.0 7637.5 2712.7 14.6 392.2 0.00 0.00 616.93 219.12 1.18 31.68 0.0 0.0 3371.2 1197.4 6.4 173.1 38.94 0.95 119.24 2,276.43 212.8 5.2 651.6 12,439.5 17.19 0.42 52.63 1,004.82 93.9 2.3 287.6 5,490.8 Livestock PM10 and PM2.5 emissions estimates were derived using Maricopa County cattle inventory estimates for 2008 from Arizona Agricultural Statistics Bulletin (AASS, 2009) and emission factor for PM10 for dairy cattle, and feedlot cattle from the California Air Resources Board (CARB, 2004). PM2.5 was presumed to be 11% of PM10 per WRAP Fugitive Dust Handbook (WRAP, 2006d). The number of “cattle on feed” was not available from the Arizona Agricultural Statistics Bulletin (AASS, 2009) for 2005 through 2008; therefore, 2004 numbers were used. Beef cows were excluded from the inventory as information provided by Arizona Agricultural Statistics staff (Koong, 2004) indicated that the majority of beef cows that are not on feed are grazed on range and pastures. Cattle on feed, milk cows, and other cattle (heifers, steers, bulls, and calves on dairies and ranches) were included in the PM10 and PM2.5 emission estimates for livestock. 2008 Maricopa Co. PM10 Emission Inventory 70 June 2010 The 2008 Maricopa County cattle inventory and applicable PM emission factors are contained in Table 3.5–26. Table 3.5–26. Maricopa County cattle populations and PM emission factors. Animal type Cattle on feed Milk cows Other cattle Total: No. of Head 5,000 100,000 58,000 170,000 PM10 Emission Factor (lb/1000 head/day ) 28.9 6.7 28.9 PM2.5:PM10 Ratio 0.11 0.11 0.11 Typical daily PM10 emissions from livestock in Maricopa County were calculated using the following formula: Typical daily emissions (lbs/day) from dairy cattle = milk cow inventory (1,000 head) × emission factor (lbs PM10/1,000 head/day) = 100 × 6.7 = 670.0 lbs PM10/day It was assumed that livestock emissions occur evenly throughout the year. Annual PM10 and PM2.5 emissions were derived by multiplying typical daily emissions by 366 days/year. NH3 emissions from livestock in Maricopa County were estimated by growing the 2005 NH3 emissions by the percentage change in Maricopa County cattle and calve numbers from 2002 to 2008 (AASS, 2003; AASS, 2009) 2. The cattle and calf populations declined 8.11% from 2002 to 2008; as shown in Table 3.5–27 below. The estimated 2005 and 2008 NH3 emissions from livestock emissions are shown in Table 3.5–28. Table 3.5–27. Maricopa County cattle inventory for 2002 and 2008. Maricopa Co. Percentage 2002 2008 Change All cattle & calves 185,000 170,000 -8.1% Table 3.5–28. Annual and typical daily NH3 emissions from livestock in Maricopa County. Annual emissions Typical daily (tons/year) emissions (lbs/day) 2005 Emissions 10,429.53 57,148.1 % Change in cattle and calves, 2002 to 2008 –8.11% -8.11% 2008 Emissions 9,583.89 52,514.5 MCAQD determined through GIS analysis of confined animal feeding operation (CAFO) locations and animal numbers in Maricopa County that 57.3% of CAFO animals are located within the nonattainment area. Therefore, annual and typical daily emissions for the nonattainment area were calculated by multiplying the Maricopa County emission totals by 57.3%. Table 3.5–29 summarizes the annual and typical daily emissions from livestock for Maricopa County and the PM10 nonattainment area. 2. The 2005 NH3 emissions were calculated using the CMU Ammonia Model (CMU, 2004). The activity levels in the CMU model are based on the 2002 Census of Agriculture; therefore, emissions were grown using the percentage change in cattle and calve numbers from 2002 to 2008. 2008 Maricopa Co. PM10 Emission Inventory 71 June 2010 Table 3.5–29. Annual and typical daily emissions from livestock. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NH3 PM10 PM2.5 NH3 Maricopa County 455.80 50.14 9,583.89 2,490.7 274.0 52,514.5 PM10 NAA 260.95 28.70 5,486.90 1,426.0 156.9 30,065.2 3.5.4 Health services: crematories Emissions from human and animal crematories were calculated from annual emissions inventory reports from all crematories located within the county. Typical daily emissions were calculated based on the operating schedule data reported by surveyed facilities. Annual and typical daily emissions for the PM10 nonattainment area were derived based on the location data of the individual facilities. Table 3.5–30 summarizes annual and typical daily emissions from crematories in both Maricopa County and the PM10 nonattainment area. Table 3.5–30. Annual and typical daily emissions from crematories. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Maricopa County 0.93 0.62 12.39 1.58 7.0 4.7 93.1 11.9 PM10 NAA 0.93 0.62 12.36 1.58 7.0 4.6 92.6 11.8 3.5.5 Accidental releases As part of its air quality permit compliance program, MCAQD keeps an “upset log”, for each calendar year that records excess emissions and accidental releases at permitted facilities. Annual emissions inventory reports also provide for recording of accidental releases. Data from these two sources documented the release of 0.01 tons of PM10 and 0.06 tons of NOx for the year 2008. To be conservative, PM2.5 amounts are assumed to be equal to PM10 amounts. (No accidental releases of SOx or NH3 were reported). Typical daily emissions were calculated by summing reported releases and dividing the total by 366 days. Emissions in the PM10 nonattainment area were calculated based on locations of facilities that reported releases. The resulting estimates are shown in Table 3-5–31 below. Table 3.5–31. Annual and typical daily emissions from accidental releases. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5* NOx PM10 PM2.5* NOx Maricopa County 0.01 0.01 0.06 0.1 0.1 0.3 PM10 NAA 0.01 0.01 0.06 0.1 0.1 0.3 * As a conservative estimate, all PM10 emissions are assumed to be PM2.5. 3.5.6 Humans A literature review by Battye et al. (1994) recommended using a per-capita emission factor developed for the National Acid Precipitation Assessment Program (NAPAP) inventory in 1985. This factor was applied to MAG population estimates for the county and PM10 nonattainment areas (see section 1.5 for population information). Daily emissions were calculated by dividing annual values by 366. The resulting estimates are shown in Table 3-5–32. 2008 Maricopa Co. PM10 Emission Inventory 72 June 2010 Table 3.5–32. Annual and typical daily NH3 emissions from human activity. Emission factor Annual NH3 Typical daily NH3 Geographic Area Population (lbs/ person-yr) emissions (tons/yr) emissions (lbs/day) Maricopa County 4,279,760 0.55 1,176.93 6,431.3 PM10 NAA 4,297,140 0.55 1,181.71 6,457.5 3.5.7 Leaf blower fugitive dust Fugitive dust emissions from leaf blowers are the result of blowing loose material from the area being cleared by the leaf blowers. Exhaust emissions from gasoline-powered leaf blowers are covered under the Nonroad Mobile Sources section of this report (Chapter 4). Fugitive dust emission estimates are developed with the use of three sources: EPA’s NONROAD model, California Air Resources Board report to legislature on leaf blowers (CARB, 2000), and a recent research effort done by the University of Riverside (Fitz et al., 2005). EPA’s 2008NONROAD model was used to estimate the number of gasoline-powered leaf blowers in Maricopa County (n = 109,787), along with the average activity figures for those leaf blowers. Total leaf blower population estimates were derived from CARB (2000), which estimated that 60% of all leaf blowers sold are electric. Thus assuming the remaining 40% are gasoline-powered, the total population was estimated as: Total leaf blower population = Gas-powered leaf blower population ÷ 40% = 109,787 ÷ 0.4 = 274,468 units The remaining 164,681 units [= 274,468 – 109,787] are thus assumed to be electric-powered. Fitz et al. (2005) developed emission factors for PM10 and PM2.5 fugitive dust emissions from leaf blowers. For this report, the most conservative (highest) emission factors were chosen to estimate emissions. Given these two data sources, Table 3.5–33 lists the equipment population numbers, activity estimates and emission factors for leaf blowers in Maricopa County. Table 3.5–33. Leaf blower equipment populations, activity levels and emission factors for Maricopa County. Annual activity PM10 emission PM2.5 Emission Leaf blower description Population (hrs/yr) factors (mg/m2) factors (mg/m2) Commercial 2-stroke gasoline 3,345 626 70 30 Commercial 4-stroke gasoline 1,639 626 70 30 Residential 2-stroke gasoline 99,624 10 70 30 Residential 4-stroke gasoline 5,179 10 70 30 Electric 164,681 10 130 40 n/a n/a n/a Total: 274,468 2008 Maricopa Co. PM10 Emission Inventory 73 June 2010 CARB (2000) estimates that approximately 1600m2 of surface can be cleared in one hour of leaf blower operation. Therefore, annual emission estimates were calculated by using the following formula, as in this example for electric leaf blowers: Annual PM10 emissions = population × activity from electric leaf blowers (hrs/yr) = 164,681 × 10 hrs/yr × emission factor (mg/m2) × area covered (m2/hr) × 130 mg/m2 × 1600 m2/hr = 342,536,480,000 mg/yr = 377.24 tons PM10/yr The activity hours associated with leaf blowers can occur at any time during the year in Maricopa County due to the temperate climate, with no substantial seasonal variation. Therefore, typical daily emissions were estimated by dividing annual totals by 366 days per year. Emissions for the PM10 nonattainment area are allocated based on the ratio of population in the County to the nonattainment area (see Section 1.5 for information on population). Table 3.5–34 lists annual and daily fugitive emissions from leaf blowers for Maricopa County and the PM10 nonattainment area. Table 3.5–34. Annual and typical daily emissions from leaf blower fugitive dust. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 PM10 PM2.5 Maricopa County 891.36 336.41 4,870.8 1,838.3 PM10 NAA 894.98 337.78 4,890.6 1,845.8 3.5.8 Offroad recreation vehicles fugitive dust The EPA NONROAD2008 model estimates exhaust emissions for offroad recreational vehicles. These emissions are included in the nonroad emissions category of the 2008 particulate emissions inventory. Particulate emissions are also generated by recreational vehicles traveling on unpaved surfaces. For the 2008 periodic inventory, these emissions were estimated by MAG using mileage and activity data for offroad recreational vehicles in Maricopa County from the NONROAD2008 model. The methodology and assumptions for calculating fugitive dust emissions from offroad recreational vehicles traveling are described in this section. The EPA NONROAD2008 model provides annual mileage and number of vehicles by county for all-terrain vehicles (ATVs), offroad motorcycles (ORMs), and specialty vehicles/carts (SVCs). The NONROAD2008 default values for annual mileage and number of vehicles by type for Maricopa County in 2008 are shown in Table 3.5–35. To be consistent with the 2005 Periodic Emissions Inventory for PM10 (MCAQD, 2007), it was assumed that 75 percent of the annual travel by offroad recreational vehicles occurs on unpaved surfaces inside Maricopa County, with the remaining 25 percent occurring on paved surfaces within Maricopa County and paved and unpaved surfaces outside of Maricopa County. The product of the mileage, number of vehicles, and 75 percent produces the annual vehicle miles traveled (VMT) on unpaved surfaces, shown in Table 3.5–35. Dividing annual VMT totals by 366 produces a daily estimated offroad recreational vehicle travel on unpaved surfaces in Maricopa County in 2008. 2008 Maricopa Co. PM10 Emission Inventory 74 June 2010 Table 3.5–35. 2008 offroad recreational vehicle travel on unpaved surfaces in Maricopa County. Annual Number of 2008 Annual 2008 Daily Vehicle Type Mileage Vehicles VMT VMT ATV 1,608 30,424 36,691,344 100,250 ORM 1,600 7,359 8,830,800 24,128 SVC (Non-Diesel) 65 1,718 83,753 229 SVC (Diesel) 435 150 48,938 134 The VMTs above were multiplied by emission factors for unpaved industrial roads from AP-42 (US EPA, 2006b), assuming a silt content of 11.9 percent and an average vehicle weight of onehalf of a ton. The resultant PM10 emission factor for ATVs and SVCs is 0.594 pounds per vehicle mile traveled. This emission factor was reduced by 50 percent for ORMs (i.e., 0.297 pounds per mile) to account for two wheels generating dust instead of four. Applying the AP-42 equation results in a PM2.5 emission factor for ATVs and SVCs of 0.059 pounds per mile, while the comparable PM2.5 emission factor for ORMs is 0.0295 pounds per mile. The AP-42 emission rates were multiplied by the annual and daily VMTs in Table 3.5–36 to obtain uncontrolled fugitive dust emissions in pounds per day and tons per year. The results for Maricopa County are shown in Table 3.5–37. The emissions for the PM10 nonattainment area were derived by applying geographic information systems (GIS) to MAG 2009 land use data 1 to obtain the acreage of passive open space in the PM10 nonattainment area and Maricopa County. Passive open space includes open desert, mountains and washes. The detailed calculations for deriving the PM10 nonattainment area emissions are shown below: Passive Open Space in the PM10 nonattainment area (NAA) = 262,662 acres Passive Open Space in Maricopa County = 1,476,922 acres Ratio of Passive Open Space in PM10 NAA vs. Maricopa County = 17.8% PM10 NAA Emissions = 0.178 × Maricopa County Emissions Application of the ratio above to Maricopa County emissions produces the uncontrolled annual and typical daily PM10 NAA emissions shown in Table 3.5–36. The PM10 and PM2.5 emissions for all offroad recreational vehicle types (i.e., ATVs, ORMs and SVCs) are summed in this table. These uncontrolled emissions do not include the 2008 emission reductions attributed to the committed measures in the MAG 2007 Five Percent Plan. Table 3.5–36. 2008 uncontrolled emissions from offroad recreational vehicles. Annual emissions (tons/yr) Typical Daily Emissions (lbs/day) Geographic Area PM10 PM2.5 PM10 PM2.5 Maricopa County 12,248.11 1,216.56 66,929.6 6,647.9 PM10 NAA 2,180.16 216.55 11,913.5 1,183.3 Two committed measures that reduce emissions from offroad recreational vehicles were quantified in the MAG 2007 Five Percent Plan for PM10 (MAG, 2007). The benefit taken in 2008 for these measures in the Five Percent Plan is shown in Table 3.5–37. 1. Draft, as of March 24, 2010. 2008 Maricopa Co. PM10 Emission Inventory 75 June 2010 Table 3.5–37. Benefits of measures that reduce offroad recreational vehicle emissions. 2008 PM10 Emission Reductions Committed Measures in Five Percent Plan tons/yr lbs/day 1. Reduce offroad vehicle use in areas with high offroad vehicle activity (Measure 19) 140.3 766.5 2. Ban ATV use on high pollution days (Measure 23) 25.7 140.6 Total 2008 PM10 emission reductions for offroad recreational vehicles 166.0 907.0 The emission benefits in Table 3.5–37 were subtracted from the uncontrolled PM10 emissions in Table 3.5–36. The 2008 PM-10 emission reduction of 166.0 tons per year represents 7.6% of the uncontrolled emissions in the PM-10 NAA of 2,180.16 tons per year. This percent reduction was applied to the uncontrolled PM2.5 emissions in the PM10 NAA; then the absolute reduction in PM2.5 emissions due to the control measures was applied to the uncontrolled PM2.5 emissions in Maricopa County. The annual and daily controlled emission estimates are shown in Table 3.5-38 below. Table 3.5–38. 2008 controlled emissions from offroad recreational vehicles. Annual Emissions (tons/yr) Typical Daily Emissions (lbs/day) Geographic Area PM10 PM2.5 PM10 PM2.5 Maricopa County 12,082.12 1,200.11 66,022.5 6,558.0 PM10 NAA 2,014.17 200.09 11,006.4 1,093.4 3.5.9 Unpaved parking lots fugitive dust Fugitive dust emissions from vehicles traveling on unpaved parking lots were developed by MAG based on land area devoted to unpaved parking lots, vehicle activity on unpaved parking lots, and emission rates from AP-42 (US EPA, 2006b). The methodology, assumptions and calculations involved in estimating fugitive dust from vehicles traveling on unpaved parking lots are described in this section. The vehicle miles traveled on unpaved parking lots in the PM10 nonattainment area (NAA) were derived using assumptions from the Phase I windblown dust modeling for the Western Regional Air Partnership (ENVIRON, 2004). This study estimated that eight percent of the vacant land in core urban areas is disturbed and thirty percent of the land under development is disturbed. For the 2008 periodic emissions inventory, the core urban area is defined as the carbon monoxide maintenance area. In addition, the thirty percent of disturbed land under development has been reduced by two-thirds (i.e., from thirty percent to ten percent) to mirror a 67 percent decline in total permitted construction acreage in the PM10 NAA between 2005 and 2008. GIS was applied to 2009 MAG land use data 2 to estimate that there are 171,785 acres of vacant land in the core urbanized area and 64,519 acres of land under development in the PM10 NAA. Multiplying the vacant disturbed percentages by these land areas produces: 171,785 acres × 0.08 = 13,743 acres of vacant disturbed land in the urbanized core 64,519 acres × 0.10 = 6,452 acres of vacant disturbed land under development Summing the vacant disturbed acres in the urbanized core and areas under development produces a total of 20,195 acres of vacant disturbed land in the PM10 NAA. In estimating fugitive dust emissions from unpaved parking lots, the MAG Serious Area PM10 Plan assumed that 24 percent 2. Ibid. 2008 Maricopa Co. PM10 Emission Inventory 76 June 2010 of the disturbed vacant non-agricultural land is devoted to unpaved parking areas (MAG, 2000). Applying this percentage to the acres of vacant disturbed land results in 4,847 acres of unpaved parking lots in the PM10 NAA. The MAG Serious Area PM10 Plan also assumed that the average size of an unpaved parking lot is 625 square meters (i.e., 0.154 acres), an average of ten vehicles travel on each lot per day, and each vehicle travels an average distance of 0.031 miles on a lot. Multiplying 10 vehicles per day times 0.031 miles per vehicle and dividing by 0.154 acres produces 2.0 vehicle miles of travel (VMT) per acre per day. Multiplying 2.0 by 4,847 acres yields 9,694 VMT per day on unpaved parking lots in the PM10 NAA. The emission factors for unpaved parking lots were derived from the AP-42 equation for unpaved industrial roads (US EPA, 2006b), assuming a silt content of 11.9 percent and an average vehicle weight of 3.18 tons. The resultant AP-42 emission factors are 1.365 pounds per mile for PM10 and 0.137 pounds per mile for PM2.5. These AP-42 emission factors were applied to the unpaved parking lot VMT of 9,694 to obtain uncontrolled emissions in pounds per day. The pounds per day were converted to tons per year, assuming 366 days in 2008. The results for the PM10 NAA are shown in Table 3.5–40. To estimate emissions for Maricopa County, GIS was applied to 2009 MAG land use data 3 to obtain 2,227,981 acres of vacant land in Maricopa County. Removing the vacant land in the Maricopa County portion of the PM10 NAA (i.e., 466,553 acres) results in 1,761,428 vacant acres located inside Maricopa County, but outside the PM10 NAA. Assuming one percent of the vacant land outside the PM10 NAA is disturbed (Clark County, 2006) and 24 percent of the disturbed vacant land is unpaved parking areas (MAG, 2000), results in 4,227 acres of unpaved parking areas inside Maricopa County, but outside the PM10 NAA. Multiplying by 2.0 VMT per acre per day results in 8,454 VMT per day. Applying the AP-42 emission rates produces the unpaved parking lot emissions inside Maricopa County, but outside the PM10 NAA of 11,539.7 pounds per day of PM10 and 1,158.2 pounds per day of PM2.5. The final step in estimating Maricopa County emissions requires removing the Pinal County portion of the PM10 NAA. The unpaved parking lot emissions in the Pinal County portion of the PM10 NAA are assumed to be proportional to the acres of vacant land. These were derived using GIS and 2009 MAG land use data 4, with the results shown below: Vacant land in the Pinal County portion of the PM10 NAA = 6,278 acres Vacant land in the PM10 NAA = 472,831 acres Ratio = 6,278/472,831 = 1.3%; Pinal County portion = 1.3% × PM10 NAA emissions Pinal County portion of PM10 emissions = 1.3% × 13,232.3 = 172.0 pounds per day Pinal County portion of PM2.5 emissions = 1.3% × 1,158.2 = 17.3 pounds/day Adding the emissions inside and outside the PM10 NAA and subtracting the Pinal County portion produces total Maricopa County emissions attributable to vehicles traveling on unpaved parking 3. Ibid. 4. Ibid. 2008 Maricopa Co. PM10 Emission Inventory 77 June 2010 lots in pounds per day. Pounds per day were multiplied by 366 [= no. days in 2008] to derive annual totals. The resultant 2008 uncontrolled emissions for Maricopa County are shown in Table 3.5–39. Uncontrolled emissions do not include the 2008 emission reductions attributed to the committed measure in the MAG 2007 Five Percent Plan. Table 3.5–39. 2008 uncontrolled emissions from vehicles traveling on unpaved parking lots. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 PM10 PM2.5 Maricopa County 4,501.80 451.83 24,600.0 2,469.0 PM10 NAA 2,421.51 243.04 13,232.3 1,328.1 One committed measure that reduces emissions from unpaved parking lots was quantified in the MAG 2007 Five Percent Plan for PM10 (MAG, 2007). The benefit taken in 2008 for this measure in the Five Percent Plan is shown in Table 3.5–40. Table 3.2–40. Benefits of measure that reduces unpaved parking lot emissions. Committed Measure in Five Percent Plan 1. Pave or stabilize existing unpaved parking lots (Measure 25) 2008 PM10 emission reduction tons/yr lbs/day 56.4 308.4 The emission benefit in Table 3.5-40 was subtracted from the uncontrolled PM10 emissions in Table 3.5-39. The 2008 PM10 emission reduction of 56.4 tons per year represents 2.3% of the uncontrolled emissions in the PM10 NAA of 2,421.51 tons per year. This percent reduction was applied to the uncontrolled PM2.5 emissions in the PM10 NAA; then the absolute reduction in PM2.5 emissions due to the control measure was applied to the uncontrolled PM2.5 emissions in Maricopa County. The annual and daily controlled emission estimates are shown in Table 3.5-41 below. Table 3.5–41. Annual and typical daily controlled emissions from unpaved parking lots. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Geographic area PM10 PM2.5 PM10 PM2.5 Maricopa County 4,445.36 446.24 24,291.6 2,438.5 PM10 NAA 2,365.07 237.45 12,923.9 1,297.5 2008 Maricopa Co. PM10 Emission Inventory 78 June 2010 3.5.10 Windblown dust Windblown dust emissions were calculated using a combination of local meteorology conditions, land use and vertical flux emission rates. A full description of the methodology is included as Appendix 4. Tables 3.5–42 and 3.5–43 summarize annual and typical daily emissions from windblown dust by major land use category for Maricopa County and the PM10 nonattainment area. Table 3.5–42. Annual and typical daily emissions from fugitive windblown dust for Maricopa County. Annual Emissions (tons/yr) Avg. Daily Emissions (lb/day) Land Use Category PM10 PM2.5 PM10 PM2.5 Agriculture, harvested 1,711.76 171.18 9,353.9 935.4 Agriculture, unharvested 1,349.51 134.95 7,374.4 737.4 Developing 3,334.78 333.48 18,222.8 1,822.3 Landfill, Sand & Gravel, Automotive Test Tracks 1,646.51 164.65 8,997.3 899.7 Passive/Restricted Open Space 44,174.80 4,417.48 241,392.4 24,139.2 Vacant 60,570.87 6,057.09 330,988.4 33,098.8 Total 112,788.23 11,278.82 616,329.1 61,632.9 Table 3.5–43. Annual and typical daily emissions from fugitive windblown dust for the PM10 NAA. Annual Emissions (tons/yr) Avg. Daily Emissions (lb/day) Land Use Category PM10 PM2.5 PM10 PM2.5 Agriculture, harvested 755.57 75.56 4,128.8 412.9 Agriculture, unharvested 327.69 32.77 1,790.7 179.1 Developing 2,664.48 266.45 14,560.0 1,456.0 Landfill, Sand & Gravel, Automotive Test Tracks 1,435.81 143.58 7,845.9 784.6 Passive/Restricted Open Space 3,762.38 376.24 20,559.5 2,056.0 Vacant 9,522.43 952.24 52,035.2 5,203.5 Total 18,468.36 1,846.84 100,920.0 10,092.0 2008 Maricopa Co. PM10 Emission Inventory 79 June 2010 3.5.11 Summary of all miscellaneous area sources Tables 3.5–44 and 3.5–45 provide a summary of annual and typical daily emissions from all miscellaneous area sources, for Maricopa County and the PM10 nonattainment area, respectively. Table 3.5–44. Annual and typical daily emissions from all miscellaneous area sources for Maricopa County. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Source Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Wildfires Prescribed fires Structure fires Vehicle fires Engine testing Tilling Harvesting Unpaved ag roads Cotton ginning Fertilizer Livestock Crematories Accidental releases Humans Leaf blowers dust Offroad rec. veh. dust Unpaved parking lots Windblown dust Total: 470.39 0.51 15.04 30.04 0.18 2,059.00 136.93 1,739.52 17.90 403.43 0.51 15.04 30.04 0.17 308.85 20.54 173.95 5.11 455.80 0.93 0.01 50.14 0.62 0.01 891.36 12,082.12 4,445.36 112,788.23 135,133.31 336.41 1,200.11 446.24 11,278.82 14,269.99 103.79 0.39 1.95 1.20 6.74 28.46 0.11 21.76 0.03 2.49 2,276.43 9,583.89 12.39 0.06 1.58 6,271.8 169.3 82.2 164.1 1.3 22,932.4 3,938.9 11,150.8 103.8 5,379.0 169.3 82.2 164.1 1.2 3,439.9 590.8 1,115.1 29.7 2,490.7 7.0 0.1 274.0 4.7 0.1 4,870.8 66,022.5 24,291.6 616,329.1 758,826.5 1,838.3 6,558.0 2,438.5 61,632.9 83,717.8 1,383.8 131.2 10.7 6.6 50.5 379.4 36.0 19.0 12,439.5 52,514.5 93.1 0.3 11.9 1,176.93 126.52 32.64 13,059.05 290.2 10.6 6,431.3 1,676.1 446.4 71,686.1 Table 3.5–45. Annual and typical daily emissions from all miscellaneous area sources for the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Source Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Wildfires Prescribed fires Structure fires Vehicle fires Engine testing Tilling Harvesting Unpaved ag roads Cotton ginning Fertilizer Livestock Crematories Accidental releases Humans Leaf blowers dust Offroad rec. veh. dust Unpaved parking lots Windblown dust Total: 423.56 0.21 15.10 30.16 0.18 834.20 54.14 731.03 4.86 363.27 0.21 15.10 30.16 0.17 125.13 8.12 73.10 1.39 260.95 0.93 0.01 28.70 0.62 0.01 894.98 2,014.17 2,365.07 18,468.36 26,097.92 337.78 200.09 237.45 1,846.84 3,268.14 93.46 0.16 1.96 1.21 6.74 25.62 0.04 19.60 0.01 2.49 1,004.82 5,486.90 12.36 0.06 1.58 9,412.5 104.0 82.5 164.81 1.3 9,327.3 1,560.0 4,686.1 26.7 8,072.7 104.0 82.5 164.81 1.2 1,399.1 234.0 468.6 7.6 1,426.0 7.0 0.1 156.9 4.6 0.1 4,890.6 11,006.4 12,923.9 100,920.0 156,539.2 1,845.8 1,093.4 1,297.5 10,092.0 25,024.8 2,076.8 80.6 10.7 6.59 50.5 569.4 22.1 19.0 5,490.8 30,065.2 92.6 0.3 11.8 1,181.71 115.94 2008 Maricopa Co. PM10 Emission Inventory 29.74 7,693.04 80 435.5 6.5 6,457.5 2,318.0 622.4 61,982.0 June 2010 3.6 Summary of all area sources Tables 3.6–1 and 3.6–2 summarize the total annual and typical daily emissions from all area sources addressed in this chapter, for both Maricopa County and the PM10 nonattainment area, respectively. Table 3.6–1. Summary of annual and typical daily emissions from all area sources in Maricopa County. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Source Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Fuel Combustion Industrial natural gas Industrial fuel oil Comm./inst. natural gas Comm./inst. fuel oil Residential natural gas Residential wood Residential fuel oil All fuel combustion Industrial Processes Chemical manufacturing Commercial cooking Grain processing Cold storage Secondary metal prod. Mineral processes Mining & quarrying Wood product mfg. Rubber/plastic mfg. Fabricated metal mfg. Residential construction Commercial construction Road construction Other construction Electrical equip mfg. ADEQ-permitted portable sources Road travel at industrial sites Industrial processes NEC All Industrial Processes Waste Treatment/disposal On-site incineration Open burning Landfills POTWs Other waste All Waste Treatment/ Disposal 30.78 458.79 66.54 224.14 61.75 461.59 0.01 1,303.61 30.78 575.29 458.79 6,375.08 66.54 1,267.11 224.14 3,273.40 61.75 763.81 429.28 34.69 0.01 0.25 1,271.30 12,289.62 2.42 609.61 5.23 271.27 4.88 5.34 0.10 898.83 12.70 26.25 4.20 8.13 51.27 187.43 988.99 20.59 151.42 917.18 6.71 0.00 0.34 0.03 60.56 195.81 210.39 217.26 140.94 51.48 2,259.80 5,364.98 2,725.90 216.23 13.94 52.16 97.28 59.56 203.25 105.96 42.62 225.98 536.50 272.59 21.62 9.64 49.73 18.65 1,678.43 .004 20.45 0.18 59.00 29.50 282.18 88.93 608.17 144.60 14,928.89 282.95 107.24 3,268.45 10.22 362.58 21.49 129.60 0.06 111.46 86.21 0.04 111.46 75.92 5.01 29.96 24.11 0.01 31.55 16.79 1,731.34 7.57 197.3 2,941.0 426.5 1,436.8 337.5 4,334.2 0.1 9,673.4 197.3 2,941.0 426.5 1,436.8 337.5 4,030.8 0.1 9,370.0 3,687.7 40,865.9 8,122.5 20,983.3 4,173.8 325.7 2.3 78,161.3 15.5 3,907.8 33.5 1,738.9 26.6 50.1 0.9 5,773.3 81.4 168.3 26.9 52.1 1,445.8 5,434.0 149.3 1,164.5 5,039.5 49.5 0.0 2.6 0.6 442.7 1,357.4 1,442.1 1,668.6 953.3 538.1 14,343.5 34,332.0 17,458.0 1,382.2 76.9 386.2 671.7 390.8 1,548.3 698.8 460.6 1,434.3 3,433.2 1,745.8 138.2 53.2 358.8 142.7 10.759.2 0.0 112.4 1.1 492.9 246.5 2.275.7 721.7 4,178.8 953.3 96,246.9 1,928.8 726.4 21,076.1 69.6 2,816.5 137.7 1,005.8 0.7 902.2 486.1 0.4 902.2 425.4 38.9 242.4 132.9 0.1 41.7 224.1 110.9 101.0 278.1 1,613.0 1,438.8 515.3 320.0 28.9 1,484.01 32.78 16.93 18.39 50.62 230.52 204.35 77.47 58.20 2008 Maricopa Co. PM10 Emission Inventory 81 1,484.01 328.7 193.7 94.6 11,077.2 8,131.5 8,131.5 June 2010 Table 3.6–1. Category Summary of annual and typical daily emissions from all area sources in Maricopa County. Annual emissions (tons/yr) Typical daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Misc. Area Sources Wildfires fires Prescribed fires Structure fires Vehicle fires Engine testing Tilling Harvesting Unpaved ag roads Cotton ginning Fertilizer application Livestock Crematories Accidental releases Humans Leaf blowers dust Offroad rec. veh. dust Unpaved parking lots Windblown dust All Misc. Sources TOTAL, ALL AREA SOURCES Table 3.6–2. Category 470.39 0.51 15.04 30.04 0.18 2,059.00 136.93 1,739.52 17.90 403.43 0.51 15.04 30.04 0.17 308.85 20.54 173.95 5.11 103.79 0.39 1.95 1.20 6.74 28.46 0.11 455.80 0.93 0.01 50.14 0.62 0.01 891.36 12,082.12 4,445.36 112,788.23 135,133.31 336.41 1,200.11 446.24 11,278.82 14,269.99 32.64 151,596.33 19,014.09 12,856.18 1,119.27 21.76 0.03 6,271.8 169.3 82.2 164.1 1.3 22,932.4 3,938.9 11,150.8 103.8 5,379.0 169.3 82.2 164.1 1.2 3,439.9 590.8 1,115.1 29.7 2,490.7 7.0 0.1 274.0 4.7 0.1 13,059.05 4,870.8 66,022.5 24,291.6 616,329.1 758,826.5 1,838.3 6,558.0 2,438.5 61,632.9 83,717.8 1,676.1 446.4 71,686.1 16,329.74 866,359.8 115,602.7 83,169.2 7,545.5 91,223.5 2.49 2,276.43 9,583.89 12.39 0.06 1.58 1,383.8 131.2 10.7 6.6 50.5 379.4 36.0 19.0 12,439.5 52,514.5 93.1 0.3 11.9 1,176.93 126.52 290.2 10.6 6,431.3 Summary of annual and typical daily emissions from all area sources in the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Fuel Combustion Industrial natural gas Industrial fuel oil Comm./inst. natural gas Comm./inst. fuel oil Residential natural gas Residential wood Residential fuel oil All fuel combustion Industrial Processes Chemical manufacturing Commercial cooking Grain processing Cold storage Secondary metal prod. Mineral processes Mining & quarrying Wood product mfg. Rubber/plastic mfg. Fabricated metal mfg. Residential construction Commercial construction Road construction Other construction Electrical equip mfg ADEQ-permitted portable sources Road travel at industrial sites Industrial processes NEC All Industrial Processes 30.70 457.60 66.20 223.00 61.73 461.41 0.01 1,300.65 30.70 573.79 457.60 6,358.50 66.20 1,260.65 223.00 3,256.70 61.73 763.51 429.11 34.67 0.01 0.25 1,268.35 12,248.07 2.41 608.03 5.20 269.88 4.87 5.33 0.10 895.83 12.66 26.19 4.18 8.09 51.11 186.94 993.04 16.73 151.03 920.94 5.68 0.00 0.34 0.03 60.56 190.45 184.25 216.69 140.57 51.35 2,245.39 5,380.95 2,724.87 215.70 13.94 52.16 93.72 50.64 202.72 105.68 42.51 224.54 538.10 272.49 21.57 9.64 49.73 18.65 1,674.1 0.04 20.45 0.18 59.00 29.50 282.18 88.93 511.29 136.00 13,327.74 227.58 99.12 3,047.62 8.12 360.48 21.47 129.58 2008 Maricopa Co. PM10 Emission Inventory 4.49 82 31.55 14.10 1,724.27 196.8 2,933.3 424.4 1,429.5 337.3 4,332.5 0.1 9,653.8 196.8 2,933.3 424.4 1,429.5 337.3 4,029.2 0.1 9,350.6 3,678.2 40,759.6 8,081.1 20,876.3 4,172.2 325.6 2.3 77,895.2 15.5 3,897.6 33.3 1,730.0 26.6 50.1 0.9 5,754.1 81.2 167.9 26.8 51.8 1,442.0 5,456.3 125.3 1161.5 5,060.1 43.0 0.0 2.6 0.9 442.7 1,320.7 1,266.6 1,664.3 950.9 536.7 14,465.2 34,382.4 17,471.4 1,385.5 76.9 386.2 647.9 331.9 1,544.3 697.0 459.4 1,446.5 3,438.2 1,747.1 138.6 53.2 358.8 142.7 10,731.2 0.0 112.4 1.1 492.9 246.5 2,275.7 721.7 3,551.3 906.0 85,937.0 1,573.8 681.7 19,656.9 55.4 2,802.3 137.6 1,005.7 327.6 28.8 193.7 79.8 11,034.4 June 2010 Table 3.6–2 (cont’d). Summary of annual and typical daily emissions from all area sources in the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Fuel Combustion Waste Treatment/disposal On-site incineration Open burning Landfills POTWs Other waste All Waste Treatment/ Disposal Misc. Area Sources Wildfires Prescribed fires Structure fires Vehicle fires Engine testing Tilling Harvesting Unpaved ag roads Cotton ginning Fertilizer application Livestock Crematories Accidental releases Humans Leaf blowers dust Offroad rec. veh. dust Unpaved parking lots Windblown dust All Misc. Sources TOTAL, ALL AREA SOURCES: 3.7 0.06 27.67 60.25 0.04 27.67 50.78 5.01 7.44 19.47 0.01 6.22 0.7 232.6 342.4 0.4 232.6 286.6 38.9 62.5 107.4 0.1 34.3 224.1 110.9 101.0 278.1 1,494.12 8,164.6 32.78 16.93 18.39 50.62 120.77 95.42 50.30 56.85 1,494.12 799.8 630.5 309.9 312.6 8,164.6 423.56 0.21 15.10 30.16 0.18 834.20 54.14 731.03 4.86 363.27 0.21 15.10 30.16 0.17 125.13 8.12 73.10 1.39 93.46 0.16 1.96 1.21 6.74 25.62 0.04 19.60 0.01 9,412.5 104.0 82.5 164.81 1.3 9,327.3 1,560.0 4,686.1 26.7 8,072.7 104.0 82.5 164.81 1.2 1,399.1 234.0 468.6 7.6 2,076.8 80.6 10.7 6.59 50.5 569.4 22.1 435.5 6.5 260.95 0.93 0.01 28.70 0.62 0.01 1,426.0 7.0 0.1 156.9 4.6 0.1 894.98 2,014.17 2,365.07 18,468.36 26,097.92 337.78 200.09 237.45 1,846.84 3,268.14 115.94 29.74 7,693.04 4,890.6 11,006.4 12,923.9 100,920.0 156,539.2 1,845.8 1,093.4 1,297.5 10,092.0 25,024.8 2,318.0 622.4 42,455.4 40,847.07 7,679.53 12,774.79 1,112.00 10,962.54 252,929.8 54,662.7 83,325.3 7,694.7 61,982.0 2.49 1,004.82 5,486.90 12.36 0.06 1.58 19.0 5,490.8 30,065.2 92.6 0.3 11.8 1,181.71 6,457.5 Quality assurance/quality control procedures Quality assurance and quality control (QA/QC) activities for the area source emissions inventory were driven by the goal of creating a comprehensive, accurate, representative and comparable inventory of area source emissions for Maricopa County and the nonattainment area. During each step of creating, building and reviewing the area source emissions inventory, quality checks and assurances were performed to establish confidence in the inventory structure and data. Area source categories were selected for inclusion in the inventory based on the latest Emission Inventory Improvement Program (EIIP) guidance available. EPA’s guidance for area source categories included in the draft 2002 National Emission Inventory (NEI) was also evaluated, as area source emissions from this inventory will be submitted to EPA for the 2008 NEI. The list of area source categories developed based on these guidance documents was modified to fit the characteristics of Maricopa County, with some area source categories determined to be insignificant (such as industrial coal combustion and oil and gas production). The 1999 Maricopa County Periodic Ozone and Carbon Monoxide Emission Inventories and other regional emission inventories were also consulted to confirm the completeness of the area source categories chosen for inclusion. Data for area source emission calculations were gathered from a wide universe of resources. Whenever applicable, local surveyed data (such as annual emissions report) was used as this data best reflects activity in the county and the nonattainment area. When local data was not 2008 Maricopa Co. PM10 Emission Inventory 83 June 2010 available, state data from Arizona State agencies (such as the Arizona Department of Transportation) and regional bodies (such as the Western Regional Air Partnership, WRAP) were used. National level data (such as the US Census Bureau) was used when no local, state or regional data was available. In addition, the most recent EIIP guidance for area sources was consulted for direction in determining the most relevant data source for use in emissions calculations. Emissions calculations for area sources were performed by three air quality planners and one unit manager. All area source emission estimates were calculated in spreadsheets to ensure the calculations could be verified and reproduced. Whenever possible or available, the “preferred method” described in the most recent EIIP guidance documents for area sources was used to calculate emissions. Emissions were estimated using emission factors from EIIP guidance, AP42, and local source testing. Local seasonal and activity data were used when available, with EPA and EIIP guidance used when no local seasonal or activity data existed. All calculations were evaluated to ensure that emissions from point sources were not being double-counted and to determine if rule effectiveness applied. Once area source emission estimates had been produced, several quality control checks were performed to substantiate the calculations. Most area source calculations were peer-reviewed by two other planners, with all area sources being reviewed by at least one other planner. Peer review ensured that all emission calculations were reasonable and could be reproduced. Sensitivity analyses and computational method checks were performed on area sources when emissions seemed to be outside the expected ranges. When errors were found, the appropriate changes were made by the author of the calculations to ensure consistency of the emissions calculations. The peer-reviewed emissions estimates were combined into a draft area source chapter. This draft chapter was read through in its entirety by the unit manager and the three air quality planners for final review, with any identified errors corrected by the author of the section. The draft version of the area source chapter was sent to the Arizona Department of Environmental Quality, the Arizona Department of Transportation, and the Maricopa Association of Governments for a quality assurance review. These agencies provided comments which were addressed and incorporated into the final area source chapter. Further quality analysis was performed by inputting the emission estimates into EPA’s “QA/QC basic format and content checker”, prior to submitting the data to the 2008 NEI. The QA/QC activities described here have produced high levels of confidence in the area source emissions estimates detailed in this chapter, and represent the best efforts of the inventory preparers. 2008 Maricopa Co. PM10 Emission Inventory 84 June 2010 3.8 References AASS, 2003. 2002 Arizona Agricultural Statistics Bulletin, Arizona Agricultural Statistics Service, September 2003. AASS, 2009. 2008 Arizona Agricultural Statistics Bulletin, Arizona Agricultural Statistics Service, September 2009. ADC, 2008. July 1, 2008 Population Estimates for Arizona’s Counties, Incorporated Places and Balance of County, Population Statistics Unit, Research Administration, Arizona Department of Commerce, December 12, 2008. Internet address: http://www.azcommerce.com/doclib/ econinfo/FILES/2008AZestimates.pdf ADOC, 2010. Arizona Department of Commerce. Heating Degree Days: Phoenix. Internet address: http://www.azcommerce.com/doclib/ENERGY/Degreedays.pdf ASLD, 2009. Glen Buettner [glenbuettner@azstatefire.org], Forestry Division, Arizona State Land Department, Re: 2008 wildland fire data for Maricopa County, e-mail message, April 20, 2009. Battye, R., W. Battye, C. Overcash and S. Fudge, 1994. Development and Selection of Ammonia Emission Factors, p. 6-3. Prepared for U.S. Environmental Protection Agency, Atmospheric Research and Exposure Assessment Laboratory by EC/R Inc., Durham, NC, Internet address: http://www.sraproject.org/wp-content/uploads/2007/12/ developmentandselectionofammoniaemissionfactors.pdf CARB, 2000. A report to the California legislature on the potential health and environmental impacts of leaf blowers. February, 2000 CARB, 2003. Area-wide Source Methodologies, Section 7.5 Agricultural Harvest Operations, revised January 2003. Internet address: http://www.arb.ca.gov/ei/areasrc/index7.htm. CARB, 2004. Area Source Methodologies – Section 7.6 (Cattle Feedlot Dust). California Air Resources Board, Sacramento, CA. Revised May 2004. Internet address: http://www.arb.ca.gov/ei/areasrc/fullpdf/FULL7-6.PDF. CARB, 2006 Speciation Profiles and Size Fractions. California Air Resources Board, Sacramento, CA. Internet address: http://www.arb.ca.gov/emisinv/speciate/speciate.htm. Clark County, 2001. PM10 State Implementation Plan for Clark County (Nevada), Appendix B: Emissions Inventory Methodology, Emission Factors, and Emission Estimates, June 2001, p. B-59. Internet address: http://www.co.clark.nv.us/daqem/aq/plans/pm10sip2001.html. Clark County, 2006. Inventory of Vacant Land Soil Stability and Unpaved Private Roads in the Las Vegas Valley Using Remote Sensing Imagery. Prepared by Environmental Quality Management, Inc. and Midwest Research Institute for the Clark County (Nevada) Department of Finance. December 2006. CMU, 2004. Carnegie Mellon University Ammonia Model Version 3. Internet address: http://www.cmu.edu/ammonia/. DFBLS, 2009. Frank Fisher [frank.fisher@dfbls.az.gov] , Arizona Department of Fire, Building, and Life Safety (DFBLS), Re: data request - 2008 fire data for Maricopa County, e-mail message, May 4, 2009. ENVIRON, 2004. Final Report, Determining Fugitive Dust Emissions From Wind Erosion. Prepared by ENVIRON for the Western Governors’ Association. March 12, 2004. FFOW, 2009. Federal Fire Occurrence website, http://wildfire.cr.usgs.gov/firehistory/data.html, federal wildland fire occurrence data downloaded on Aug. 18, 2009. Fitz, Dennis, D. Pankrath, S. Pederson, J. Bristow, and G. Arcemont, 2005. Determination [of] Particulate Emission Rates from Leaf Blowers. Center for Environmental Research and Technology, University of California Riverside. Internet address: http://www.epa.gov/ttn/ chief/conference/ei15/ session5/fitz.pdf 2008 Maricopa Co. PM10 Emission Inventory 85 June 2010 Koong, 2004. Dennis Koong, Arizona Agricultural Statistical Service, pers. commun. February 3, 2004. MAG, 2000. Draft Final Report 1994 Regional PM10 Emission Inventory for the Maricopa County Nonattainment Area, Revised MAG 1999 Serious Area Particulate Plan for PM10 for the Maricopa County Nonattainment Area, Appendices Volume One. Maricopa Association of Governments, Phoenix, AZ, Feb. 2000. MAG, 2000a. Revised MAG 1999 Serious Area Particulate Plan for PM10 for the Maricopa County Nonattainment Area. Prepared by the Maricopa Association of Governments. February 2000. MAG, 2007. MAG 2007 Five Percent Plan for PM10 for the Maricopa County Nonattainment Area. Prepared by the Maricopa Association of Governments. December 2007. MAG, 2009. Maricopa Association of Governments, Anubhav Bagley (abagley@mag.maricopa.gov), “Agricultural Land in Area A”, e-mail message, December 11, 2009. MCAQD, 2007. 2005 Periodic Emissions Inventory for PM10 for the Maricopa County, Arizona, Nonattainment Area. Prepared by the Maricopa County Air Quality Department. May 2007. MCESD, 1993. 1990 Base Year Ozone Emission Inventory for Maricopa County, Arizona, Nonattainment Area, Draft Submittal, Maricopa County Environmental Quality & Community Services Agency, Phoenix, AZ, March 1993. MCESD, 1999. 1999 Periodic Ozone Emissions Inventory for the Maricopa County, Arizona Nonattainment Area, Maricopa County Environmental Services Department, Phoenix AZ, Rev. Aug. 2002. MCESD, 2009. Hans Moesbergen, Maricopa County Environmental Services Department, “Permit Average 2008”, e-mail message, February13, 2009. MCAQD, 2006. Personal communications with George Mills, Dust Compliance Division, MCAQD, and Dena Konopka, MCAQD, November 2006. MCAQD, 2007. Maricopa County Air Quality Department, 2005 Periodic Emissions Inventory for PM10 for the Maricopa County, Arizona, Nonattainment Area, May 2007, Available at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/reports/Defaul t.aspx Tchobanoglous, G., 1979. Wastewater Engineering: Treatment, Disposal, and Reuse. McGrawHill Science/Engineering/Math, New York. URS and ERG, 2001. Technical Support Document of Quantification of Agricultural Best Management Practices, Final, URS Corporation and Eastern Research Group, Inc., June 8, 2001 US Census Bureau, 2010a. 2007 County Business Patterns (NAICS). Internet address: http://censtats.census.gov/cgi-bin/cbpnaic/cbpsect.pl. US Census Bureau, 2010b. Selected Housing Characteristics: 2008, 2008 American Community Survey 1-Year Estimates, House Heating Fuel for Maricopa County and Arizona State. Internet address: http://factfinder.census.gov US Census Bureau, 2010c. B25117. Tenure by House Heating Fuel – Universe: Occupied Housing Units. 2008 American Community 1-Year Estimates, Fuel oil, kerosene, etc. for Maricopa County and Arizona State [Owner occupied and renter occupied]. Internet address: http://factfinder.census.gov USDA, 2007a. United States Department of Agriculture, National Agricultural Statistics Service, 2007 Census of Agriculture, Volume 1, Chapter 2: County Level Data. Table 32. Fruits and Nuts: 2007 and 2002, and Table 28. Other Crops: 2007 and 2002. Available at: http://www.agcensus.usda.gov/Publications/2007/Full_Report/Volume_1,_Chapter_2_Count y_Level/Arizona/index.asp. 2008 Maricopa Co. PM10 Emission Inventory 86 June 2010 USDA, 2007b. United States Department of Agriculture, National Agricultural Statistics Service, 2007 Census of Agriculture, Volume 1, Chapter 2: County Level Data. Table 42. Fertilizers and Chemicals Applied: 2007 and 2002, Available at: http://www.agcensus.usda.gov/Publications/2007/Full_Report/Volume_1,_Chapter_2_Count y_Level/Arizona/index.asp. USDA, 2008a. U.S. Department of Agriculture, Forest Service, Fire and Aviation Management Web Applications (FAMWEB), Previous Years ICS-209s. Internet address: http://fam.nwcg.gov/fam-web/. USDA, 2008b. United States Department of Agriculture National Agricultural Statistics Service, Quick Stats, U.S. & All States County Data – Crops, Potatoes, 2008. Available at: http://www.nass.usda.gov/Data_and_Statistics/Quick_Stats/index.asp. US DOE, 2010a. US Department of Energy, Energy Information Administration. Adjusted Sales for Industrial Use: Distillate Fuel Oil, Residual Fuel Oil, and Kerosene, 2008 (Table 21) US DOE, 2010b. US Department of Energy, Energy Information Administration. Adjusted Sales for Commercial Use: Distillate Fuel Oil, Residual Fuel Oil, and Kerosene, 2008 (Table 20) US DOE, 2010c. US Department of Energy, Energy Information Administration. State Energy Data 2007: Consumption, Table 8–Residential Sector Energy Consumption Estimates, 1960– 2007, Arizona. Internet address: http://www.eia.doe.gov/emeu/states/sep_use/notes/use_print2007.pdf US EIA, 2010. U.S. Energy Information Administration, Arizona Total Distillate Sales/Deliveries to Residential Consumers. Internet address: http://tonto.eia.doe.gov/dnav/pet/hist/LeafHandler.ashx?n=PET&s=KD0VRSSAZ1&f=A. US EPA, 1992. Compilation of Air Pollution Emission Factors (AP-42). Fifth Ed. Vol. I: Stationary Point and Area Sources. Section 2.5: Open Burning. US Environmental Protection Agency, Office of Air Quality Planning and Standards, Research Triangle Park, NC. US EPA, 1997. Compilation of Air Pollution Emission Factors (AP-42). Fifth Ed. Vol. I: Stationary Point and Area Sources. Section 13.2.1: Paved Roads. US Environmental Protection Agency, Office of Air Quality Planning and Standards, Research Triangle Park, NC. US EPA, 1998a. Compilation of Air Pollution Emission Factors (AP-42). Fifth Ed. Vol. I: Stationary Point and Area Sources. Section 1.4: Natural Gas Combustion. US Environmental Protection Agency, Office of Air Quality Planning and Standards, Research Triangle Park, NC. Internet address: http://www.epa.gov/ttn/chief/ap42/ch01/final/ c01s04.pdf. US EPA, 1998b. Compilation of Air Pollution Emission Factors (AP-42). Fifth Ed. Vol. I: Stationary Point and Area Sources. Section 13.2.2: Unpaved Roads. US Environmental Protection Agency, Office of Air Quality Planning and Standards, Research Triangle Park, NC. US EPA, 2000. Area Source Category Method Abstract: Vehicle Fires. Emission Inventory Improvement Program (EIIP), May 2000. Internet address: http://www.epa.gov/ttn/chief/eiip/techreport/volume03/vehclf13.pdf US EPA, 2001a. Introduction to Area Source Emission Inventory Development. Emission Inventory Improvement Program (EIIP) Vol. III, Chap. 1. Prepared by Eastern Research Group, Revised Final, Jan. 2001. Internet address: http://www.epa.gov/ttn/chief/eiip/ techreport/volume03/iii01_apr2001.pdf. 2008 Maricopa Co. PM10 Emission Inventory 87 June 2010 US EPA, 2001b. Residential Wood Combustion. Emission Inventory Improvement Program (EIIP) Vol. III, Chap. 2. Revised Final, Jan. 2001. Prepared by Eastern Research Group, Inc. for the Area Source Committee, EIIP. Internet address: http://www.epa.gov/ttn/chief/eiip/ techreport/volume03/iii02_apr2001.pdf. US EPA, 2001c. Structure Fires. Emission Inventory Improvement Program (EIIP) Vol. III, Chap. 18. Revised Final, Jan. 2001. Prepared by Eastern Research Group, Inc. for the Area Source Committee, EIIP. Internet address: http://www.epa.gov/ttn/chief/eiip/techreport/ volume03/iii18_apr2001.pdf. US EPA, 2002. Residential Construction – Fugitive Dust. Emission Inventory Improvement Program (EIIP) Vol. IX: Particulate Emissions. Internet address: http://www.epa.gov/ttn/ chief/eiip/techreport/volume09/residn3.pdf. US EPA, 2005. Emissions Inventory Guidance for Implementation of Ozone and Particulate Matter National Ambient Air Quality Standards (NAAQS) and Regional Haze Regulations. USEPA Office of Air Quality Planning and Standards, Research Triangle Park, NC. August 2005, updated Nov. 2005. Available at: http://www.epa.gov/ttn/chief/eidocs/eiguid/. US EPA, 2006a. Documentation for the 2002 Preliminary Nonpoint Source National Emission Inventory for Criteria and Hazardous Air Pollutants (Feb. 2006 Version). Appendix A: Criteria and HAP Emissions Estimation Methodology, Commercial Cooking, pp. A-16. Prepared by E.H. Pechan & Associates, Inc. for Emission Factor and Inventory Group. Internet address: ftp://ftp.epa.gov/EmisInventory/2002finalnei/documentation/nonpoint/2002nei_final_nonpoi nt_documentation0206version.pdf US EPA, 2006b. Compilation of Air Pollution Emission Factors (AP-42). Fifth Ed. Vol. I: Stationary Point and Area Sources. Section 13.2.2: Unpaved Roads. November 2006. Internet address: http://www.epa.gov/ttn/chief/ap42/ch13/final/c13s0202.pdf USGS, 2008. United States Geological Survey, GeoMAC (Geospatial Multi-Agency Coordination) Wildland Fire Support database. Internet address: http://www.geomac.gov/ USFS, 1993. Cliff Dills, US Forest Service, Payson Ranger Station, Payson AZ, pers. comm. USFS, 2009. Ronald Sherron [Sherron.Ronald@azdeq.gov], US Forest Service , Re: Data Request - 2008 Maricopa County Prescribed Fire Data and Tonto Natl Forest Wildfire Data Needed, e-mail message, July 28, 2009. WGA/WRAP, 2005. 2002 Fire Emission Inventory for the WRAP Region – Phase II. Project No. 178-6. Western Governors Association/Western Regional Air Partnership. July 22, 2005. Tables 5 and 6. Internet address: http://www.wrapair.org/forums/fejf/documents/WRAP_2002_PhII_EI_Report_20050722.pdf WRAP 2006a. Fugitive Dust Handbook. Chapter 3.0 Construction and Demolition, September 2006. Internet address: http://wrapair.org/forums/dejf/fdh/index.html. WRAP 2006b. Fugitive Dust Handbook. Chapter 2.0 Agricultural Tilling, September 2006. Internet address: http://wrapair.org/forums/dejf/fdh/index.html. WRAP 2006c. Fugitive Dust Handbook. Chapter 10.0 Agricultural Harvesting, September 2006. Internet address: http://wrapair.org/forums/dejf/fdh/index.html. WRAP 2006c. Fugitive Dust Handbook. Chapter 6.0 Unpaved Roads, September 2006. Internet address: http://wrapair.org/forums/dejf/fdh/index.html. WRAP 2006d. Fugitive Dust Handbook. Chapter 13.0 Livestock Husbandry, September 2006. Internet address: http://wrapair.org/forums/dejf/fdh/index.html. 2008 Maricopa Co. PM10 Emission Inventory 88 June 2010 4. Nonroad Mobile Sources 4.1 Introduction Nonroad mobile sources are defined as those that move or are moved within a 12-month period and are not licensed or certified as highway vehicles. Nonroad mobile sources are vehicles and engines that fall under the following categories: • • • • • • • • • • • • • Agricultural equipment, such as tractors, combines and balers; Airport ground support equipment, such as baggage tugs and terminal tractors; Commercial equipment, such as generators and pumps; Industrial equipment, such as forklifts and sweepers; Construction and mining equipment, such as graders, back hoes and trenchers; Lawn and garden equipment, such as leaf blowers and lawn mowers; Logging equipment (not present in Maricopa County); Pleasure craft, such as power boats and personal watercraft; Railway maintenance equipment, such as rail straighteners; Recreational equipment, such as all-terrain vehicles and off-road motorcycles; Underground mining and oil field equipment (not present in Maricopa County); Aircraft, such as jet and piston engines; and Locomotives, such as switching and line haul trains. Emission calculations for most nonroad mobile source categories except aircraft, airport ground support equipment (GSE) and locomotives were derived using EPA’s NONROAD model, ver. 2008.1.0 (Core version 2008, April 2009). Aircraft and airport GSE emission estimates were made using the Federal Aviation Administration’s EDMS (Emissions Dispersion Modeling System) model, ver. 5.1.1. Locomotive emission calculations were derived from surveys of the three railroad companies that have operations in the county (Burlington Northern Santa Fe, Union Pacific and Amtrak). County specific temperature and fuel-related inputs are required for the operation of the NONROAD model. Monthly temperature and fuel data were provided by the Arizona Department of Weights and Measures. The following table lists the local county inputs used: 2008 Maricopa Co. PM10 Emission Inventory 89 June 2010 Table 4.1–1. Month January February March April May June July August September October November December NONROAD model county temperature- and fuel-related inputs. Fuel Diesel Gasoline Temperatures (°F) ETOH RVP Sulfur Sulfur Max. Min. Average (psi) (ppm) (ppm) (Vol%) 64 45 54.90 8.8 6 35 9.47 69 48 58.45 8.4 6 23 9.24 79 54 66.84 8.4 7 49 9.18 87 61 74.23 7.8 7 23 5.57 91 66 78.74 6.8* 6* 27* 0.00* 107 80 93.40 6.6 6 25 0.00 106 84 95.16 7.0 4 19 0.00 104 82 93.16 6.8 6 29 0.00 101 79 90.07 6.5 6 35 0.00 91 65 78.13 7.9 7† 25 6.79 81 56 68.67 8.4 7† 15 8.78 65 46 56.03 8.3† 7 28† 8.17† Ethanol Blend Market Total Oxygen Share (%) (wt%) 100 3.49 100 3.42 100 3.41 100 2.06 0* 0.00* 0 0.00 0 0.00 0 0.00 0 0.00 100 2.52 100 3.27 100† 3.03† * Since measurements were not available, the average of June, July, August and September data was used. † Since measurements were not available, the average of October, November, January, February, March and April data was used. EPA recommends adjusting default NONROAD model values (such as equipment population, activity levels of equipment, growth factors, etc.) where local data is available, as the default values in the model are derived from national averages. The NONROAD model defaults were adjusted in the following manner: • Equipment population numbers and activity levels for commercial lawn and garden equipment were adjusted based on 2003 survey results of the commercial lawn and garden industry performed by ENVIRON as part of an inventory developed to study the impact of visibility impairing pollutants (ENVIRON et al., 2003). Survey results show that for most categories of lawn and garden equipment, the equipment populations for Maricopa County are significantly lower than EPA default values, while the average annual hours of operation for most equipment types are slightly higher than EPA's values. Using these new local data results is a considerable decrease in emissions from this category, compared with earlier results using EPA default data. The NONROAD model does not calculate emission values for NH3. Ammonia emission calculations for the NONROAD model were derived by using a multiplier of NOx emissions developed by ENVIRON (2003). Spatial allocation factors were developed (based on EPA guidance documents) to apportion nonroad emissions to the PM10 nonattainment area. The approaches used are described in each section of this chapter. Temporal allocations (used to calculate PM10 average-day emissions) for nonroad equipment categories modeled in the NONROAD model come from EPA recommendations on weekday and weekend day activity levels for each nonroad equipment category (US EPA, 1999). Table 4.1–2 lists the weighted activity level allocation fractions for each equipment class for weekdays and weekend days. For this report, the most conservative (highest) allocation fraction in each nonroad equipment class was used to calculate average-day emissions. 2008 Maricopa Co. PM10 Emission Inventory 90 June 2010 Table 4.1–2. Default weekday and weekend day activity allocation fractions. Equipment category Weekday Weekend day Agricultural 0.1666667 0.0833334 Airport ground support 0.1428571 0.1428571 Commercial 0.1666667 0.0833334 Construction and mining 0.1666667 0.0833334 Industrial 0.1666667 0.0833334 Lawn and garden (residential) 0.1111111 0.2222222 Lawn and garden (commercial) 0.1600000 0.1000000 Logging 0.1666667 0.0833334 Pleasure craft 0.0600000 0.3500000 Railway maintenance 0.1800000 0.0500000 Recreational 0.1111111 0.2222222 4.2 Agricultural equipment Annual emissions from agricultural equipment in Maricopa County were calculated using EPA’s NONROAD model as discussed above. County-wide results are shown in Table 4.2–1. Table 4.2–1. PM10 34.27 Annual emissions (tons/yr) from agricultural equipment in Maricopa County. PM2.5 NOx SOx NH3 33.24 365.55 0.14 0.67 Annual emissions for the PM10 nonattainment area were calculated based on EIIP guidance (US EPA, 2002) which recommends using the ratio of agricultural land inside the nonattainment area to agricultural land inside the county. See Section 1.5.2 for a discussion of land use data used. PM10 NAA emissions from = Total County PM10 emissions agricultural equipment from agricultural equipment = 34.27 tons × Agricultural land use allocation factor × 44.14% = 15.13 tons PM10 /yr Table 4.2–2. PM10 15.13 Annual emissions (tons/yr) from agricultural equipment in the PM10 NAA. PM2.5 NOx SOx NH3 14.67 161.35 0.06 0.30 County average-day emissions were calculated by multiplying annual emissions (generated by the NONROAD model) by the most conservative weekday/weekend day activity allocation factor for agricultural equipment listed in Table 4.1–2, and dividing the product by the number of weeks (52) in the year (US EPA, 1999), as follows: Average County PM10 = Annual PM10 daily emissions emissions (lbs/day) (tons/yr) = 34.27 × daily activity allocation factor for agricultural equipment (week/day) × 2000 ÷ 52 (lbs/ton) (wks/yr) × 0.166667 × 2000 ÷ 52 = 219.7 lbs/day Table 4.2–3. PM10 219.7 Typical daily emissions (lbs/day) from agricultural equipment in Maricopa County. PM2.5 NOx SOx NH3 213.1 2,343.3 0.9 4.3 2008 Maricopa Co. PM10 Emission Inventory 91 June 2010 PM10 nonattainment area average-day emissions were calculated by multiplying County averageday emissions by the agricultural land use allocation factor: PM10 NAA average- = Maricopa County PM10 × Agricultural land use allocation factor day emissions average-day emissions = 219.7 lbs/day × 44.14% = 100.4 lbs/day Table 4.2–4. PM10 97.0 4.3 Typical daily emissions (lbs/day) from agricultural equipment in the PM10 nonattainment area. PM2.5 NOx SOx NH3 94.0 1,034.3 0.4 1.9 Airport ground support equipment and auxiliary power units Annual emissions from airport ground support equipment (GSE) and auxiliary power units (APUs) at most airports in the county were estimated using the Emissions Dispersion Modeling System (EDMS, v. 5.1.1) from the U.S. Federal Aviation Administration (FAA). The model can estimate emissions from affiliated ground support equipment (GSE) and auxiliary power units (APUs), by using either default equipment profiles, or user-specified data on equipment populations and activity patterns. In most cases, activity data on 2008 aircraft operations and GSE / APU usage was obtained from individual airport surveys issued by MAG and/or MCAQD. Where survey responses were incomplete or information was otherwise unavailable, activity data was estimated using commercially available data, and EDMS default assumptions where appropriate. Further details concerning the modeling input data and results are presented in Section 4.11 of this report. For Luke Air Force Base (AFB), emissions estimates for ground support equipment were obtained from a recent base-wide mobile source emissions inventory for calendar year 2008 that had recently been completed for the US Air Force (Weston, 2010). Using data on the frequency and intensity of usage for each type of equipment, annual emissions were calculated as in the following example for a light card equipped with a diesel engine: Epol = ELHP × OT × LF × EF / CF where: Epol = Annual emissions of a particular pollutant (lb/yr) ELHP = Maximum horsepower rating of engine (hp) OT = Operating time (hr/yr) LF = Typical load factor that the engine operates (% of max) EF = Emission factor (g/hp-hr) CF = Conversion factor to convert grams to pounds e.g. 10.7 hp e.g. 52,560 hr/yr e.g. 51% e.g. 7.8 g/hp-hr (453.59 g/lb) Thus, total annual NOx emissions all similar pieces of this type of GSE was calculated as: ENOx = 10.7 (hp) × 52,560 (hrs/yr) × 51% × 7.8 (g/hp-hr) / 453.59 (g/lb) = 4,932 (lb/yr) / 2,000 (lb/ton) = 2.47 tpy 2008 Maricopa Co. PM10 Emission Inventory 92 June 2010 GSE emissions from the Luke AFB study were added to the EDMS-estimated emissions from the other airports in the County. (The Luke study assumed APU usage, and thus emissions, to be negligible.) A simplifying assumption was made for all airports; i.e., that activity is spread fairly evenly throughout the week and year; thus daily emissions were estimated by dividing annual totals by 366 (= days/yr in 2008). Tables 4.3–1 and 4.3–2 below present the totals for all airport GSE and APU usage within both Maricopa County and the PM10 nonattainment area, on an annual and typical daily basis, respectively. Table 4.3–1. Annual emissions (tons/yr) from all airport ground support equipment (GSE) and auxiliary power units (APUs). Maricopa County PM10 nonattainment area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 14.92 14.39 497.97 13.62 * 14.72 14.21 490.28 13.42 * GSE 12.29 12.29 88.76 12.82 * 12.27 12.27 88.68 12.80 * APUs Total: 27.21 26.68 586.73 26.43 26.99 26.48 578.95 26.22 * At present, EDMS does not include calculation of ammonia emissions from aircraft operations. Table 4.3–2. Typical daily emissions (lb) from airport GSE and APU usage. Maricopa County PM10 nonattainment area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 81.5 78.7 2,721.1 74.4 * 80.4 77.7 2,679.1 73.3 67.1 67.1 485.0 70.0 * 67.1 67.1 484.6 70.0 148.7 145.8 3,206.1 144.4 147.5 144.7 3,163.7 143.3 GSE APUs Total: NH3 * * * At present, EDMS does not include calculation of ammonia emissions from aircraft operations. 4.4 Commercial equipment Annual emissions from commercial equipment in Maricopa County were calculated using EPA’s NONROAD model, as described in Section 4.1. Annual emissions for the PM10 nonattainment area for this category were derived by applying the ratio of industrial employment in the nonattainment area to Maricopa County-level totals, as data on the number of wholesale establishments recommended by EIIP guidance (US EPA, 2002) was not available. See Section 1.5.1 for a discussion of the industrial employment data used. Table 4.4–1. PM10 117.97 Annual emissions (tons/yr) from commercial equipment usage. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 112.98 1,395.23 2.40 21.12 117.66 112.69 1,391.61 2.39 NH3 21.06 County average-day emissions were calculated by multiplying Maricopa County annual emissions (generated by the NONROAD model) by the most conservative weekday/weekend day activity allocation factor for commercial equipment (0.1666667) listed in Table 4.1–2, and dividing the product by the number of weeks (52) in the year (US EPA, 1999). PM10 nonattainment area average-day emissions were calculated based on industrial employment ratios as described above. Table 4.4–2. PM10 756.2 Typical daily emissions (lbs/day) from commercial equipment usage. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 724.2 8,943.8 15.4 135.4 754.2 722.4 8,920.6 15.3 2008 Maricopa Co. PM10 Emission Inventory 93 NH3 135.0 June 2010 4.5 Construction and mining equipment Annual emissions from construction and mining equipment in Maricopa County were calculated using EPA’s NONROAD model as described in Section 4.1. Annual emissions for the PM10 nonattainment area for this category were derived by applying the ratio of construction employment in the nonattainment area to Maricopa County-level totals as a conservative estimate, as the EIIP-recommended allocation factor of total dollar value of construction was unavailable (US EPA, 2002). See Section 1.5.1 for a discussion of the employment data used. Table 4.5–1. Annual emissions (tons/yr) from construction and mining equipment usage. Maricopa County PM10 nonattainment area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 1,260.98 1,220.75 14,796.63 6.60 28.10 1,249.88 1,210.00 14,666.42 6.55 NH3 27.85 County average-day emissions were calculated by multiplying Maricopa County annual emissions (generated by the NONROAD model) by the most conservative weekday/weekend day activity allocation factor for construction/mining equipment (0.1666667) listed in Table 4.1–2, and dividing the product by the number of weeks (52) in the year (US EPA, 1999). PM10 nonattainment area average-day emissions were calculated based on population ratios as described above. Table 4.5–2. PM10 8,083.2 4.6 Typical daily emissions (lbs/day) from construction and mining equipment usage. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 7,825.3 94.850.2 42.3 180.1 8,012.1 7,756.4 94,015.6 42.0 178.5 Industrial equipment Annual emissions from industrial equipment in Maricopa County were calculated using EPA’s NONROAD model, as described in Section 4.1. Annual emissions for the PM10 nonattainment area for this category were derived by applying the ratio of industrial employment in the nonattainment area to Maricopa County-level totals as a conservative estimate, as the number of employees in manufacturing recommended by EIIP guidance (US EPA, 2002) was unavailable. See Section 1.5.1 for a discussion of the industrial employment data used. Table 4.6–1. PM10 101.69 Annual emissions (tons/yr) from industrial equipment usage. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 98.96 2,593.13 3.22 56.23 101.42 98.71 2,586.39 3.21 NH3 56.09 County average-day emissions were calculated by multiplying Maricopa County annual emissions (generated by the NONROAD model) by the most conservative weekday/weekend day activity allocation factor for industrial equipment (0.1666667) listed in Table 4.1–2, and dividing the product by the number of weeks (52) in the year (US EPA, 1999). PM10 nonattainment area average-day emissions were calculated based on industrial employment ratios as described above. Table 4.6–2. PM10 651.8 Typical daily emissions (lbs/day) from industrial equipment usage. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 634.4 16,622.7 20.6 360.5 650.1 632.7 16,579.4 20.6 2008 Maricopa Co. PM10 Emission Inventory 94 NH3 359.5 June 2010 4.7 Lawn and garden equipment Annual emissions from lawn and garden equipment in Maricopa County were calculated using EPA’s NONROAD model, as described in Section 4.1. These results reflect revised equipment population and usage estimates from survey work done in early 2003 for the Arizona Department of Environmental Quality (discussed in further detail in Section 4.1). Annual emissions for the PM10 nonattainment area for this category were derived by applying the ratio of population in the nonattainment area to Maricopa County-level totals (since data on housing units was unavailable, it was not possible to implement the EIIP-recommended calculation approach (US EPA, 2002). See Section 1.5.1 for a discussion of the population data used. Table 4.7–1. PM10 182.28 Annual emissions (tons/yr) from lawn and garden equipment. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 168.79 798.14 3.16 19.63 183.02 169.48 801.41 3.17 NH3 19.71 County average-day emissions were calculated by multiplying Maricopa County annual emissions (generated by the NONROAD model) by the most conservative weekday/weekend day activity allocation factor for lawn and garden equipment (0.1600000 for the commercial segment, 0.2222222 for residential) listed in Table 4.1–2, and dividing the product by 52 (the number of weeks in a year; US EPA, 1999). PM10 nonattainment area average-day emissions were calculated by applying a population-based ratio as described in Section 4.7 above. Table 4.7–2. PM10 1,250.1 4.8 Typical daily emissions (lbs/day) from lawn and garden equipment. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 1,156.9 5,571.5 23.1 144.6 1,255.3 1,161.6 5,594.4 23.2 NH3 145.2 Pleasure craft Annual emissions from pleasure craft equipment in Maricopa County were calculated using EPA’s NONROAD model, as described in Section 4.1. Annual emissions for the PM10 nonattainment area for this category were derived by applying the ratio of water surface area in the nonattainment area to Maricopa County-level totals, as recommended by EIIP guidance (US EPA, 2002). See Section 1.5.2 for a discussion of the land use data used. Table 4.8–1. PM10 9.25 Annual emissions (tons/yr) from pleasure craft equipment. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 8.54 77.74 0.85 1.73 7.02 6.48 59.03 0.64 NH3 1.32 County average-day emissions were calculated by multiplying Maricopa County annual emissions (generated by the NONROAD model) by the most conservative weekday/weekend day activity allocation factor for pleasure craft (0.3500000) listed in Table 4.1–2, and dividing the product by the number of weeks (52) in the year (US EPA, 1999). PM10 nonattainment area average-day emissions were calculated based on water surface area as described above. Table 4.8–2. PM10 124.5 Typical daily emissions (lbs/day) from pleasure craft equipment. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 114.9 1,046.5 11.4 23.3 94.5 87.3 794.6 8.6 2008 Maricopa Co. PM10 Emission Inventory 95 NH3 17.7 June 2010 4.9 Railway maintenance equipment Annual emissions from railway maintenance equipment in Maricopa County were calculated using EPA’s NONROAD model, as described in Section 4.1. Annual emissions for the PM10 nonattainment area for this category were derived by applying the ratio of population in the nonattainment area to Maricopa County-level totals, as recommended by EIIP guidance (US EPA, 2002). See Section 1.5.1 for a discussion of the population data used. Table 4.9–1. PM10 1.13 Annual emissions (tons/yr) from railway maintenance equipment. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 1.09 9.23 0.00 0.02 1.13 1.10 9.26 0.00 NH3 0.02 County average-day emissions were calculated by multiplying Maricopa County annual emissions (generated by the NONROAD model) by the most conservative weekday/weekend day activity allocation factor for railway maintenance equipment (0.1800000) listed in Table 4.1–2, and dividing the product by the number of weeks (52) in the year (US EPA, 1999). PM10 nonattainment area average-day emissions were calculated based on the population ratio as described above. Table 4.9–2. PM10 7.8 4.10 Typical daily emissions (lbs/day) from railway maintenance equipment. Maricopa County PM10 nonattainment area PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 7.6 63.9 0.0 0.1 7.8 7.6 64.1 0.0 NH3 0.1 Recreational equipment Annual emissions from recreational equipment in Maricopa County were calculated using EPA’s NONROAD model, as described in Section 4.1. Annual emissions for the PM10 nonattainment area for this category were derived by applying the ratio of passive open space and vacant land use in the nonattainment area to Maricopa County-level totals as recommended by EIIP guidance (US EPA, 2002). See Section 1.5.2 for a discussion of the land use data used. Table 4.10–1. Annual emissions (tons/yr) from recreational equipment. Maricopa County PM10 nonattainment area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 45.58 41.98 63.80 0.42 2.10 7.68 7.08 10.76 0.07 NH3 0.35 County average-day emissions were calculated by multiplying Maricopa County annual emissions (generated by the NONROAD model) by the most conservative weekday/weekend day activity allocation factor for recreational equipment (0.2222222) listed in Table 4.1–2, and dividing the product by the number of weeks (52) in the year (US EPA, 1999). PM10 nonattainment area average-day emissions were calculated based on land use as described above. Table 4.10–2. Typical daily emissions (lbs/day) from recreational equipment. Maricopa County PM10 nonattainment area PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx 389.6 358.8 545.3 3.6 18.0 65.7 60.5 91.9 0.6 2008 Maricopa Co. PM10 Emission Inventory 96 NH3 3.0 June 2010 4.11 Aircraft Emissions from aircraft operations at the largest civilian airports in Maricopa County were estimated using the Federal Aviation Administration’s Emissions and Dispersion Model (EDMS, v. 5.1.1). The EDMS model combines specified aircraft and activity levels with default emission factors in order to estimate annual emissions inventories for a specific airport. The model calculates emissions of sulfur oxides (SOx), oxides of nitrogen (NOx), carbon monoxide (CO), and volatile organic compounds (VOC), and (for a small subset of aircraft and engine types), PM10 and PM2.5 as well. The model also estimates emissions from affiliated ground support equipment (GSE) and auxiliary power units (APUs); these emissions are reported separately and are summarized in Section 4.3.) MCAQD surveyed all medium-size and large airports in Maricopa County to gather data on the types and levels of aircraft activity (specifically the number of landing and takeoff cycles, or LTO’s) or touch and go operations (TGOs) where applicable, along with information on the types of aircraft that comprise the airport’s typical fleet mix, and other operational data, such as typical usage patterns of ground support equipment (GSE) and auxiliary power units (APUs), average taxi/idle times, etc. Where survey responses were unavailable or incomplete, aircraft activity data from publicly accessible databases, such as the FAA’s Air Traffic Activity System (ATADS) and Enhanced Traffic Management System Counts (ETMSC), were used. All emission estimates in this section have been developed using the EDMS model, with the exception of Luke Air Force Base (AFB), whose emissions calculations have been prepared as part of a base-wide 2008 mobile source emissions inventory that has recently been completed (Weston, 2010). Luke AFB’s emissions reported here as ‘aircraft activity’ actually comprise three distinct, though related, types of activity: (1) the operation of aircraft stationed at the base, (2) a much smaller level of “transient” aircraft traffic within Luke’s airspace, and (3) emissions produced during on-wing engine testing – considered a “mobile source” emission category. As with all other airports included in this inventory, emissions from ground support equipment (GSE) at Luke AFB are addressed in Section 4.3, Airport ground support equipment and auxiliary power units. In addition to the LTOs (and occasional TGO activity) reported by other airports in the area, Luke reported two additional, types of aircraft operations: aircraft low fly bys (LFB), and aircraft low fly patterns (LFP). Each of these types of operations can be characterized by a distinctive combination of the times in mode (TIM); (e.g., approach, taxi in/out, takeoff and climb out.) For F-16 activity, Luke’s emissions are based not on the number of LTOs, but rather the aggregate annual operational time in modes (TIMs) for all aircraft of this type. For the F-16, an LTO cycle includes five modes of operation: idle (taxi in/out), intermediate, approach, military and afterburner. The F-16 emissions were estimated using the annual TIMs provided by Luke AFB and emission factors from military guidance documents. Table 4.11–1 lists the data sources for each airport’s activity level, as well as fleet mix. The total number of aircraft operations in 2008 is also listed. For all airports other than Luke AFB, aircraft emissions were estimated for four aircraft categories: • Air carriers (abbreviated “AC”): Larger commercial aircraft with at least 60 seats or 18,000 lbs payload capacity, used for scheduled service to transport passengers and/or freight; • Air taxis (“AT”): Smaller commercial turbine- or piston-powered aircraft with less than 60 seats or 18,000 lbs payload capacity; 2008 Maricopa Co. PM10 Emission Inventory 97 June 2010 • • General aviation (“GA”): Aircraft used on an unscheduled basis for recreational flying, personal transportation, and other activities, including business travel; and Military (“ML”): Aircraft used to support military operations. Table 4.11–1. Annual airport operations (by aircraft category), and related data sources. Airport Operations Data Fleet Mix Data Aircraft 2008 Airport Code Source1 Source2 Type Operations Buckeye Municipal BXK airnav.com Generic GA profile GA 26,535 Chandler Municipal CHD FAA/ATADS FAA/ETMSC AT 2,882 GA 233,713 ML 247 Falcon Field FFZ FAA/ATADS FAA/ETMSC AC 6 AT 3,813 GA 313,448 ML 2,152 Gila Bend Municipal E63 airnav.com Generic GA profile GA 1,768 Glendale Municipal GEU FAA/ATADS, FAA/ETMSC AT 1,873 Survey response GA 134,282 ML 57 Luke Air Force Base LUF [ Emission totals provided by Luke AFB are based on times-in-mode. ] Phoenix Deer Valley DVT Survey response Survey response, AC 284 FAA/ETMSC AT 6,217 GA 370,003 * ML 130 Phoenix Goodyear GYR Survey response Survey response, AC 140 FAA/ETMSC AT 1962 GA 169,177 * ML 6,747 Phoenix-Mesa Gateway IWA FAA/ATADS, FAA/ETMSC AC 3,876 (formerly Williams Survey response AT 5,937 Gateway) GA 211,674 ML 5,939 Phoenix Sky Harbor PHX Survey response Survey response, AC 391,518 FAA/ETMSC AT 77,354 GA 30,868 ML 2,759 Pleasant Valley P48 airnav.com Generic GA profile GA 23,535 Scottsdale SDL FAA/ATADS FAA/ETMSC AT 11,232 GA 179,619 ML 560 Sky Ranch at Carefree 18AZ Survey response Generic GA profile GA 1,515 Stellar Airpark P19 airnav.com Generic GA profile GA 19,528 Wickenburg Municipal E25 Survey responses Generic GA profile GA 6,000 1. FAA/ATADS: Federal Aviation Administration’s Air Traffic Activity Data System (database); http://aspm.faa.gov. 2. FAA/ETMSC: Federal Aviation Administration’s Enhanced Traffic Management System Counts (database); http://aspm.faa.gov. * includes touch-and-go (TGO) operations levels reported by the airport. The following section describes how activity and emissions were estimated for a representative airport, Chandler Municipal (CHD). Data from FAA’s Air Traffic Activity System (ATADS, http://www.aspm.faa.gov) provided data on 2008 activity by aircraft type; these results are contained in Table 4.11–1. While ATADS reported a total of 233,713 general aviation operations at this airport in 2008, further information on the aircraft types comprising this activity was needed. The FAA’s Enhanced Traffic Management System Counts (ETMSC) database was used to “grow” available aircraft-specific operational data as described below. 2008 Maricopa Co. PM10 Emission Inventory 98 June 2010 The ETMSC database on general aviation activity at CHD in 2008 comprises 152 different aircraft types, totaling 3,589 operations, (See Table 4.11–2). To simplify modeling input requirements, this aircraft-specific activity data was ranked in order of decreasing frequency and activity data for the most frequently reported aircraft was then grown to represent all general aviation (“GA”) activity, as shown in Table 4.11–2 below. Table 4.11–2. Example showing how most common aircraft-specific activity was grown for EDMS modeling. ETMSC% of total “Grown” reported reported Cumulative operations for Rank Aircraft Type operations operations Percent EDMS modeling 1 BE20 - Beech 200 Super King 240 6.7% 21,919 2 BE58 - Beech 58 233 6.5% 21,280 3 PA28 - Piper Cherokee 233 6.5% 21,280 4 C525 - Cessna CitationJet/CJ1 232 6.5% 21,189 5 C182 - Cessna Skylane 182 203 5.7% 31.8% 18,540 6 C172 - Cessna Skyhawk 172/Cutlass 194 5.4% 17,718 7 TBM7 - Socata TBM-7 166 4.6% 15,161 8 R22 - Robinson R-22 Mariner 138 3.8% 12,604 9 BE9L - Beech King Air 90 106 3.0% 9,681 10 BE36 - Beech Bonanza 36 97 2.7% 51.3% 8,859 11 BE55 - Beech Baron 55 90 2.5% 8,220 12 BE35 - Beech Bonanza 35 87 2.4% 7,946 13 C210 - Cessna 210 Centurion 75 2.1% 6,850 14 PA32 - Piper Cherokee Six 73 2.0% 6,667 15 P28R - Cherokee Arrow/Turbo 71 2.0% 62.4% 6,484 16 P46T - Piper Malibu Meridian 67 1.9% 6,119 17 SR22 - Cirrus SR 22 67 1.9% 6,119 18 BE30 - Raytheon 300 Super King Air 65 1.8% 5,936 19 MO20 - Mooney M-20 62 1.7% 5,662 20 C560 - Cessna Citation V/Ultra/Encore 60 1.7% 71.3% 5,480      152 XL2 - Liberty XL-2 1 < 0.1% 100.0% (n/a) Totals: 3,589 233,713 This approach of ranking reported activity, and then growing the most frequently occurring subset of aircraft typically resulted in a set comprised of 10 to 30 aircraft types being modeled for each airport/aircraft class combination, representing 60 to 100% of all reported activity. Since the EDMS model includes estimates of PM10 emissions only for a relatively small number of aircraft/engine types, all model output files were reviewed for missing data. For those aircraft/engine combinations for which the EDMS model indicated zero PM10 emissions, the default EPA emission factors listed in Table 4.11–3 (US EPA, 2003) were incorporated into the EDMS output data files, and total PM emissions recalculated. Table 4.11–3. EPA’s default PM10 emission factors for aircraft, by activity type. Activity type PM10 Emission Factor (lb/LTO) Air Carrier, Air Taxi, Military 0.60333 General Aviation 0.2367 Following EPA guidance (US EPA, 2003), PM2.5 emissions were estimated to be 92% of PM10 levels. For ease in modeling computation and the assessment of emissions, all activity was assumed to occur evenly throughout the year. Thus, average daily emissions were calculated by dividing annual totals by 366 (= days per year in 2008). Tables 4.11–4 and 4.11–5 list the total 2008 Maricopa Co. PM10 Emission Inventory 99 June 2010 annual emissions and average daily emissions, for each airport and aircraft type, for airports within and outside the PM10 NAA, respectively. Table 4.11–4. Annual and average daily emissions, by airport and aircraft type, from airports within the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) CateAirport gory PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Chandler Municipal AT 0.27 0.27 0.94 0.24 1.5 1.5 5.1 1.3 GA 12.68 11.79 18.51 6.43 69.3 64.4 101.1 35.1 ML 0.04 0.04 0.12 0.02 0.2 0.2 0.6 0.1 Total 12.99 12.10 19.56 6.68 71.0 66.1 106.9 36.5 Falcon Field AC 0.00 0.00 0.00 0.0 0.0 0.0 0.0 AT 0.23 0.23 2.94 0.49 1.3 1.2 16.0 2.7 GA 18.49 17.07 14.34 6.16 101.0 93.3 78.3 33.7 ML 0.31 0.29 0.40 0.13 1.7 1.6 2.2 0.7 Total 19.03 17.59 17.67 6.78 104.0 96.1 96.6 37.0 Glendale Municipal AT 1.06 1.05 9.70 2.43 5.8 5.7 53.0 13.3 GA 6.90 6.41 5.51 2.20 37.7 35.0 30.1 12.0 ML 0.01 0.01 0.12 0.02 0.0 0.0 0.6 0.1 Total 8.17 7.66 15.51 4.71 44.6 41.8 84.8 25.7 Luke Air Force Base† ML 62.82 62.82 382.40 31.81 343.3 343.3 2,089.6 173.8 Phoenix Deer Valley AC 0.04 0.04 0.05 0.01 0.2 0.2 0.3 0.1 AT 0.41 0.41 3.97 0.76 2.2 2.2 21.7 4.2 GA 10.10 9.43 62.81 14.61 55.2 51.5 343.2 79.8 ML 0.02 0.02 0.07 0.02 0.1 0.1 0.4 0.1 Total 10.57 9.90 66.91 15.40 57.8 54.1 365.6 84.1 Phoenix Goodyear AC 0.02 0.01 0.36 0.05 0.1 0.1 1.9 0.3 AT 0.19 0.19 1.61 0.28 1.1 1.0 8.8 1.5 GA 0.66 0.66 18.86 5.25 3.6 3.6 103.0 28.7 ML 0.96 0.89 3.66 1.07 5.2 4.8 20.0 5.8 Total 1.83 1.74 24.48 6.64 10.0 9.5 133.8 36.3 Phoenix Sky Harbor AC 22.38 22.38 1,751.85 185.77 122.3 122.3 9,573.0 1,015.2 Intl. AT 4.24 4.02 116.92 17.51 23.2 22.0 638.9 95.7 GA 3.37 3.21 12.81 2.83 18.4 17.6 70.0 15.4 ML 0.45 0.43 23.48 2.34 2.5 2.4 128.3 12.8 30.45 30.05 1,905.06 208.45 166.4 164.2 10,410.2 1,139.1 Phoenix-Mesa AC 0.16 0.15 13.25 1.72 0.9 0.8 72.4 9.4 Gateway Airport AT 0.63 0.62 3.02 0.64 3.4 3.4 16.5 3.5 GA 12.99 12.04 17.41 5.48 71.0 65.8 95.2 29.9 ML 0.58 0.55 26.56 3.14 3.2 3.0 145.1 17.1 14.35 13.36 60.24 10.98 78.4 73.0 329.2 60.0 Pleasant Valley GA 0.36 0.33 1.65 0.34 1.9 1.8 9.0 1.8 Scottsdale AT 1.03 1.02 7.84 1.37 5.7 5.6 42.8 7.5 GA 19.83 18.86 116.13 21.79 108.4 103.1 634.6 119.1 ML 0.08 0.08 0.24 0.06 0.5 0.4 1.3 0.3 20.95 19.96 124.21 23.22 114.5 109.1 678.8 126.9 Skyranch at Carefree GA 0.18 0.17 0.39 0.10 1.0 0.9 2.1 0.5 Stellar Airpark GA 2.31 2.13 2.42 0.97 12.6 11.6 13.2 5.3 PM10 NAA totals: 183.80 177.61 2,620.31 316.00 1,004.3 970.5 14,318.6 1,726.8 † Sum of emissions from the following categories, as reported in Weston (2010): (1) aircraft stationed at Luke AFB, (2) transient aircraft, and (3) on-wing aircraft engine testing. 2008 Maricopa Co. PM10 Emission Inventory 100 June 2010 Table 4.11–5. Annual and average daily emissions, by aircraft type, from airports outside the PM10 NAA. Annual emissions (tons/yr) Average daily emissions (lbs/day) CateFacility gory PM10 PM2.5 NOx SOx PM10 PM2.5 NOx SOx Buckeye Municipal GA 3.14 2.89 2.70 0.97 17.2 15.8 14.8 5.3 Gila Bend Municipal GA 0.21 0.19 0.18 0.06 1.1 1.1 1.0 0.3 Wickenburg Municipal GA 0.77 0.73 2.75 0.61 4.2 4.0 15.0 3.3 Maricopa County totals: 187.91 181.42 2,625.94 317.64 1,026.8 991.4 14,349.4 1,735.8 4.12 Locomotives Annual emissions from locomotives were calculated based on diesel fuel usage data provided by Burlington Northern/Santa Fe Railway (BNSF), Union Pacific Railway (UP) and Amtrak. Railway operations from these companies fall into two categories: Class I haul lines and yard/ switching operations. Annual emissions from these two activity categories were calculated by multiplying diesel fuel usage by the emission factors listed in Table 4.12–1 (US EPA, 2009). Table 4.12–1. Emission factors for locomotives. Emission factors (lbs/gal diesel) Activity type PM10 PM2.5 NOx SOx Class I haul line 0.015 0.014 0.394 0.004 Yard/switch operations 0.015 0.014 0.421 0.004 NH3 0.0001 0.0001 The example below illustrates how emissions were calculated for each locomotive activity type. Fuel use reported by railroads, and emission totals are summarized in Table 4.12–2. PM10 emissions from = Diesel use (gals/yr) UP Class I haul lines = 7,780,284 gals/yr × PM10 emission factor (lbs/gal) ÷ 2,000 lbs/ton × 0.015 lbs/gal ÷ 2,000 lbs/ton = 58.35 tons PM10/yr Table 4.12–2. Total diesel use and annual emissions from locomotives in Maricopa County. Annual emissions (tons/yr) Diesel use Locomotive type (gals/yr) PM10 PM2.5 NOx SOx NH3 BNSF Class I haul line 750,094 5.63 5.25 147.77 1.50 0.36 UP Class I haul line 7,780,284 58.35 54.46 1,532.72 15.56 3.70 BNSF yard/switch operations 400,000 3.00 2.80 84.20 0.80 0.19 UP yard/switch operations 378,199 2.84 2.65 79.61 0.76 0.18 Amtrak 52,416 0.39 0.37 10.33 0.10 0.02 Totals: 9,360,993 70.21 65.53 1,854.62 18.72 4.45 PM10 nonattainment area emissions were calculated by multiplying Maricopa County emissions by the percentage of track miles within the PM10 nonattainment area, determined by GIS mapping. Results are shown in Table 4.12–3. PM10 nonattainment area emissions = County PM10 emissions from UP Class I haul lines (tons/yr) (tons/yr) = 56.99 tons PM10/yr × Percentage of track miles within the PM10 nonattainment area × 44.27% = 25.83 tons PM10/yr 2008 Maricopa Co. PM10 Emission Inventory 101 June 2010 Table 4.12–3. Annual emissions (in tons/yr) from locomotives in the PM10 NAA. Track in Annual emissions (tons/yr) nonattainment Locomotive type area (%) PM10 PM2.5 NOx SOx BNSF Class I haul line 44.27 2.49 2.32 65.42 0.66 UP Class I haul line 44.27 25.83 24.11 678.53 6.89 BNSF yard/switch operations 100.00 3.00 2.80 84.20 0.80 UP yard/switch operations 100.00 2.84 2.65 79.61 0.76 Amtrak 0.00 0.00 0.00 0.00 0.00 Totals: 34.16 31.88 907.76 9.11 NH3 0.16 1.64 0.19 0.18 0.00 2.16 PM10 typical daily emissions for both the county (shown in Table 4.12–4) and the PM10 nonattainment area (Table 4.12–5) were calculated by dividing annual totals by 366 days (since 2008 was a leap year), as locomotive activity is assumed to be uniform throughout the year. PM10 typical daily = Annual PM10 emissions (tons) × 2000 lbs/ton emissions from haul lines × 2000 lbs/ton = 58.35 tons PM10/yr = 312.3 lbs PM10/day ÷ 366 days ÷ 366 days Table 4.12–4. Typical daily emissions (in lbs/day) from locomotives in Maricopa County. Locomotive type PM10 PM2.5 NOx SOx NH3 BNSF Class I haul line 30.7 28.7 807.5 8.2 1.9 UP Class I haul line 318.9 297.6 8,375.5 85.0 20.2 BNSF yard/switch operations 16.4 15.3 460.1 4.4 1.0 UP yard/switch operations 15.5 14.5 435.0 4.1 1.0 Amtrak 2.1 2.0 56.4 0.6 0.1 Totals: 383.6 358.1 10,134.5 102.3 24.3 Table 4.12–5. Typical daily emissions (in lbs/day) from locomotives in the PM10 nonattainment area. Locomotive type PM10 PM2.5 NOx SOx NH3 BNSF Class I haul line 13.6 12.7 357.5 3.6 0.9 UP Class I haul line 141.2 131.8 3,707.8 37.6 8.9 BNSF yard/switch operations 16.4 15.3 460.1 4.4 1.0 UP yard/switch operations 15.5 14.5 435.0 4.1 1.0 Amtrak 0.0 0.0 0.0 0.0 0.0 Totals: 186.7 174.2 4,960.4 49.8 11.8 2008 Maricopa Co. PM10 Emission Inventory 102 June 2010 4.13 Summary of all nonroad mobile source emissions Table 4.13–1 summarizes annual and daily emissions of PM10, PM2.5, NOx, SOx and NH3 from nonroad mobile sources in Maricopa County. Table 4.13–2 shows annual and typical daily emissions for these pollutants for the PM10 nonattainment area. Table 4.13–1. Annual and typical daily emissions from nonroad mobile sources in Maricopa County. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Agricultural Airport GSE Commercial Construction & mining Industrial Lawn & garden Pleasure craft Railway maintenance Recreational Aircraft Locomotives Totals: 34.27 27.21 117.97 1,260.98 101.69 182.28 9.25 1.13 45.58 187.91 70.21 2,038.46 33.24 365.55 26.68 586.73 112.98 1,395.23 1,220.75 14,796.63 98.96 2,593.13 168.79 798.14 8.54 77.74 1.10 9.23 41.98 63.80 181.41 2,625.94 65.53 1,854.62 1,959.95 25,166.75 0.14 26.43 2.40 6.60 3.22 3.16 0.85 0.00 0.42 317.64 18.72 379.58 0.67 21.12 28.10 56.23 19.63 1.73 0.02 2.10 4.45 134.06 219.7 148.7 756.2 8,083.2 651.8 1,250.1 124.5 7.8 389.6 1,026.8 383.6 13,042.0 213.1 145.8 724.2 7,825.3 634.4 1,156.9 114.9 7.6 358.8 991.3 358.1 12,530.3 2,343.3 3,206.1 8,943.8 94,850.2 16,622.7 5,571.5 1,046.5 63.9 545.3 14,349.4 10,134.5 157,677.4 0.9 144.4 15.4 42.3 20.6 23.1 11.4 0.0 3.6 1,735.8 102.3 2,099.8 4.3 135.4 180.1 360.5 144.6 23.3 0.1 18.0 24.3 890.6 Table 4.13–2. Annual and typical daily emissions from nonroad mobile sources in the PM10 NAA. Annual emissions (tons/yr) Typical daily emissions (lbs/day) Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Agricultural Airport GSE Commercial Construction & mining Industrial Lawn & garden Pleasure craft Railway maintenance Recreational Aircraft Locomotives Totals: 4.14 15.13 26.99 117.66 1,249.88 101.42 183.02 7.02 1.13 7.68 183.80 34.16 1,927.89 14.67 161.35 26.48 578.95 112.69 1,391.61 1,210.00 14,666.42 98.71 2,586.39 169.48 801.41 6.48 59.03 1.10 9.26 7.08 10.76 177.60 2,620.31 31.88 907.76 1,856.17 23,793.26 0.06 26.22 2.39 6.55 3.21 3.17 0.64 0.00 0.07 316.00 9.11 367.42 0.30 21.06 27.85 56.09 19.71 1.32 0.02 0.35 2.16 128.87 97.0 147.5 754.2 8,012.1 650.1 1,255.3 94.5 7.8 65.7 1,004.3 186.7 12,275.2 94.0 144.7 722.4 7,756.4 632.7 1,161.6 87.3 7.6 60.5 970.5 174.2 11,811.9 1,034.3 3,163.7 8,920.6 94,015.6 16,579.4 5,594.4 794.6 64.1 91.9 14,318.6 4,960.4 149,537.7 0.4 143.3 15.3 42.0 20.6 23.2 8.6 0.0 0.6 1,726.8 49.8 2,030.5 1.9 135.0 178.5 359.5 145.2 17.7 0.1 3.0 11.8 852.9 Quality assurance procedures Established procedures were used to check, and correct when necessary, the nonroad mobile sources emissions estimates. All NONROAD model input and output files, and Excel spreadsheets used to calculate the emissions, were checked by personnel not involved in developing the modeling inputs/outputs and spreadsheets being reviewed. In addition, the emissions estimates were reviewed for reasonableness by external agency staff. 4.15 References ENVIRON et al., 2003. Maricopa County 2002 Comprehensive Emission Inventory for the Cap and Trade Oversight Committee, Final Rep. prepared for Arizona Dept. of Environmental Quality, Oct. 9, 2003. ERG, 2001. Documentation for the Draft 1999 Base Year Aircraft, Commercial Marine Vessels, and Locomotive National Emissions Inventory for Criteria and Hazardous Air Pollutants. Prepared by Eastern Research Group, Morrisville, NC for the US Environmental Protection Agency, Office of Air Quality Planning and Standards, Research Triangle Park, NC, Oct. 29, 2001. Available at: http://www.epa.gov/ttn/chief/eidocs/partllsec4.pdf. 2008 Maricopa Co. PM10 Emission Inventory 103 June 2010 US EPA, 1992. Procedures for Emission Inventory Preparation – Vol. IV: Mobile Sources. Office of Air and Radiation, EPA Rep. EPA420-R-92-009, December. US EPA, 1998. National Air Pollutant Emission Trends Procedures Document, 1900-1996. Office of Air Quality Planning and Standards, Rep. EPA-454/R-98-008, Research Triangle Park, NC. May. US EPA, 1999. Weekday and Weekend Day Temporal Allocation of Activity in the NONROAD Model. EPA Office of Transportation and Air Quality, Rep. EPA420-P-99-033, March. Available at: http://www.epa.gov/otaq/models/nonrdmdl/p99033.pdf. US EPA, 2002. Geographic Allocation of State Level Nonroad Engine Population Data to the County Level. EPA Office of Transportation and Air Quality, Rep. EPA420-P-02-009, July. Available at: http://www.epa.gov/otaq/models/nonrdmdl/p02009.pdf. US EPA, 2003. Documentation for the NONROAD Model Criteria Air Pollutant Component of the National Emissions Inventory (NEI) for Base Years 1970–2001. Rept. prepared by E.H. Pechan & Associates for US EPA Office of Air Quality Planning and Standards, Sept. 2003. Available at: ftp://ftp.epa.gov/EmisInventory/finalnei99ver3/criteria/documentation/nonroad/ nonroad_neimethods.pdf. US EPA, 2010. 2008 National Emissions Inventory, Nonpoint: Fertilizer Application, May 2010. Internet address: http://www.epa.gov/ttn/chief/net/2008inventory.html. US EPA, 2009. Emission Factors for Locomotives. Office of Transportation and Air Quality. Rep. EPA420-F-09-025, April 2009. Internet address: http://www.epa.gov/otaq/regs/ nonroad/locomotv/420f09025.pdf. Weston Solutions Inc., 2010. 2008 Mobile Source Air Emissions Inventory for Luke Air Force Base. Rept. prepared for Air Education and Training Command (AETC), US Air Force, Randolph AFB, TX. June 2010. 2008 Maricopa Co. PM10 Emission Inventory 104 June 2010 5. Onroad Mobile Sources 5.1 Introduction Onroad mobile source emissions have been calculated for particulate matter for the 2008 Periodic Emissions Inventory (PEI) for the Maricopa County area. For the purposes of this particulate matter inventory, the following pollutants were included: PM10, PM2.5, nitrogen oxides (NOx), sulfur oxides (SOx), and ammonia (NH3). PM10 refers to all particles less than or equal to 10 micrometers in diameter and PM2.5 refers to particles less than or equal to 2.5 micrometers in diameter. Onroad mobile source emissions were estimated for the PM10 nonattainment area (NAA) (approximately 3,000 square miles), as well as for Maricopa County (approximately 9,000 square miles). Emission factors were calculated using MOBILE6.2, which is the latest version in a series of models developed by the U.S. Environmental Protection Agency (EPA) for the purpose of estimating motor vehicle emission factors, and AP-42, which is the EPA Compilation of Air Pollutant Emission Factors. AP-42 emission factors were used to calculate fugitive dust emissions, while MOBILE6.2 was used to estimate exhaust, tire wear, and brake wear emissions. The MOBILE6.2 modeling accounted for the oxygenated fuel and the Arizona Vehicle Inspection/ Maintenance (I/M) programs applied in Maricopa County in 2008. The fuel use assumptions, including oxygen content and Reid Vapor Pressure (RVP), were derived from the 2008 testing results provided by the Arizona Department of Weight and Measures. In order to develop the onroad mobile source emissions, the 2008 vehicle miles of travel (VMT) estimates were derived from the 2008 Highway Performance Monitoring System (HPMS) data provided by the Arizona Department of Transportation (ADOT). The distribution of VMT by vehicle type is based on the July 2008 vehicle registration data for Maricopa County provided by ADOT. The VMT by vehicle class was multiplied by the appropriate MOBILE6.2 emission factors to produce 2008 onroad exhaust, tire wear, and brake wear emissions. Paved road fugitive dust emissions estimates were derived from the AP-42 emission factors and the 2008 traffic assignment produced by the Maricopa Association of Governments (MAG) travel demand model. The 2008 VMTs for freeways, high-traffic arterials, and low-traffic arterials were derived from the 2008 traffic assignment. Low-traffic arterials carry less than 10,000 vehicles on an average weekday, while high-traffic arterials carry 10,000 or more vehicles on an average weekday. These traffic assignment VMTs were normalized to 2008 HPMS VMTs and multiplied by the appropriate particulate emission factors derived from the AP-42 equation for paved roads. The 2008 benefits of the committed measures in the MAG 2007 Five Percent Plan for the Maricopa County PM10 Nonattainment Area (MAG, 2007) were applied to estimate 2008 paved road particulate emissions for the PEI. Unpaved road VMT for 2008 was derived from the MAG 2009 Unpaved Road Inventory (MAG, 2010). Unpaved alley VMT for 2008 was derived from a GIS analysis of 2009 aerial photographs conducted by MAG. The unpaved road and alley VMTs were multiplied by the appropriate AP-42 emission factors for unpaved roads and alleys, respectively. The 2008 benefits of the committed measures in the MAG 2007 Five Percent Plan were applied to estimate 2008 unpaved road and alley particulate emissions for the PEI. 2008 Maricopa Co. PM10 Emission Inventory 105 June 2010 The main references for preparing the onroad mobile source portion of the 2008 emissions inventory were: • Emission Inventory Requirements for Ozone State Implementation Plans (US EPA, 1991); • Procedures for Emission Inventory Preparation Volume IV: Mobile Sources (US EPA, 1992a); • Technical Guidance on the Use of MOBILE6 for Emission Inventory Preparation (US EPA, 2002); • User's Guide to MOBILE6.1 and MOBILE6.2 (Mobile Source Emission Factor Model), (US EPA, 2003); and • Compilation of Air Pollutant Emissions Factors, AP-42 (US EPA, 2006). 5.2 VMT estimation MAG prepared the 2008 VMT estimates for the PM10 NAA and Maricopa County. The VMTs used to develop vehicle exhaust, tire wear, brake wear, and paved road fugitive dust emissions were derived from 2008 HPMS data provided by ADOT. The 2008 HPMS VMTs for the PM10 NAA and Maricopa County are 87,153,000 miles per day and 91,257,000 miles per day, respectively. The 2008 VMTs by facility type were used to estimate onroad exhaust, tire wear, and brake wear emissions. The VMT distribution by facility type for the PM10 NAA and Maricopa County was obtained from the 2007 Maricopa County Estimates of Daily Vehicle Travel by Highway Functional Classification derived from 2007 HPMS data by ADOT. The 2007 VMT distributions were multiplied by the estimated 2008 VMT for the PM10 NAA and Maricopa County. The resultant VMT estimates by facility type for the PM10 NAA and Maricopa County are shown in Table 5.2–1. The 2008 VMTs by silt loading category were used to estimate paved road fugitive dust emissions. Daily VMTs by silt loading category for the PM10 NAA and Maricopa County are shown in Table 5.2–2. The VMTs were derived by applying geographic information systems (GIS) to a 2008 traffic assignment output by the MAG travel demand model, TransCAD. The 2008 weekday traffic volumes output by TransCAD was normalized to 2008 HPMS VMTs for the PM10 NAA and Maricopa County to produce the VMTs by silt loading category shown in Table 5.2–2. The 2008 VMTs for unpaved roads and alleys were used to estimate unpaved road fugitive dust emissions. The 2008 daily VMTs on unpaved roads and alleys in the PM10 NAA and Maricopa County are shown in Table 5.2–3. The 2008 VMT for unpaved roads in the PM10 NAA was derived from the MAG 2009 Unpaved Road Inventory (MAG, 2010). The 2008 VMT for unpaved alleys in the PM10 NAA was derived by multiplying a MAG GIS-derived estimate of 650 miles of dirt alleys by an annual average daily traffic estimate of 9.1 vehicles per day. The 2008 Maricopa County VMTs were obtained by applying a ratio of 1.047 to the PM10 NAA VMTs in Table 5.2–3. This ratio represents 2008 VMT on all roads in Maricopa County to 2008 VMT on all roads in the PM10 NAA, as shown in Table 5.2–4. The VMTs in Table 5.2–4 represent 2008 HPMS data submitted to the Federal Highway Administration by ADOT in August 2009. 2008 Maricopa Co. PM10 Emission Inventory 106 June 2010 2008 daily VMT by facility type (annual average daily traffic). PM10 NAA Maricopa County Facility Type (thousand miles/day) (thousand miles/day) Interstate 2,458 3,163 Other Principal Arterial 937 1,205 Minor Arterial 391 503 Major Collector 1,149 1,478 Minor Collector 163 210 Local 1,188 1,529 Interstate 11,208 11,527 Other Freeway/Expressway 19,079 19,622 Other Principal Arterial 22,074 22,703 Minor Arterial 14,472 14,884 Collector 4,781 4,917 Local 9,253 9,516 Totals: 87,153 91,257 Urban Rural Table 5.2–1. Table 5.2–2. 2008 VMT by silt loading category for paved roads. Daily VMT Maricopa County Silt Loading Category PM10 NAA Freeways 30,835,329 32,526,693 High-Traffic Arterials 42,498,543 43,586,568 Low-Traffic Arterials 15,143,740 13,819,127 Totals: 87,153,000 91,257,000 Table 5.2–3. 2008 VMT on unpaved roads in the PM10 NAA and Maricopa County. 2008 Annual Average Daily VMT Area Unpaved Roads Unpaved Alleys PM10 NAA 47,984 5,915 Maricopa County 50,239 6,193 Table 5.2–4. 2008 VMT on all roads in the PM10 NAA and Maricopa County. 2008 Annual Average Daily VMT Ratio to 2008 Annual Average (in thousands) Daily VMT in the PM10 NAA Area PM10 NAA 87,153 1.000 Maricopa County 91,257 1.047 5.3 Speed estimation Vehicle speeds have no effect on the emission factors for exhaust particulate matter, re-entrained dust from paved roads, brake wear, tire wear, or exhaust NH3, but they have a significant impact on exhaust NOx emissions and re-entrained dust from unpaved roads, and a slight impact on SO2 and SO4. For onroad mobile source exhaust emissions, the 2008 traffic assignment data provided by the MAG Transportation Group in June 2008 were applied to develop the speed estimates for all facility types, except local roadways. To develop the speed estimates, VMTs and vehicle hours of travel (VHTs) were accumulated separately for three facility type groups (i.e., freeway, arterial, and collector) and two area types (i.e., urban and rural) across all four time periods (i.e., AM peak, midday, PM peak, and nighttime) in Maricopa County. Then, average daily speeds for the three facility type groups and two area types were calculated by dividing VMTs by VHTs. The same methodology was applied to develop the speed estimates for the PM10 NAA. For local 2008 Maricopa Co. PM10 Emission Inventory 107 June 2010 roadways, a default speed of 12.9 miles per hour was assumed by MOBILE6.2. Table 5.3–1 presents average daily speeds applied for the MOBILE6.2 runs. An average speed of 25 miles per hour was assumed on all unpaved roads. Urban Rural Table 5.3–1. 5.4 Average daily speeds for the 2008 periodic emissions inventory. PM10 NAA HPMS Facility Type (mph) Principal Arterial - Interstate 46.8 Principal Arterial - Other 36.0 Minor Arterial 36.0 Major Collector 30.0 Minor Collector 30.0 Local 12.9 Principal Arterial - Interstate 44.1 Freeway and Expressway 44.1 Principal Arterial - Other 29.5 Minor Arterial 29.5 Collector 24.3 Local 12.9 Maricopa County (mph) 51.5 38.1 38.1 30.3 30.3 12.9 44.4 44.4 30.1 30.1 24.2 12.9 Monthly VMT factors For exhaust, tire wear, and brake wear emissions, annual emissions were calculated by aggregating estimated monthly emissions, which were derived by applying monthly emission factors to monthly VMTs. The monthly VMTs were calculated as the product of annual average daily VMT, monthly VMT adjustment factors, and the number of days for a given month. Since VMT varies by month, annual average daily VMT was adjusted by the monthly VMT adjustment factors to derive daily VMT for each month. The monthly VMT adjustment factors were developed from data recorded by continuous traffic counters on freeways (ADOT Freeway Management System) and arterials (Phoenix Automatic Traffic Recorders) during the year 2007. These monthly factors are shown in Table 5.4–1. These factors indicate, as an example, that an average day in February has four percent more traffic on arterials than an annual average day, while an average day in July has two percent less traffic on freeways than an annual average day. Table 5.4–1. Month January February March April May June July August September October November December Average daily VMT adjustment factors by month. Arterials Freeways 0.99 1.00 1.04 1.03 1.03 1.03 1.04 1.02 1.02 1.01 0.97 1.01 0.91 0.98 0.97 0.97 1.01 0.97 1.01 0.99 1.02 1.00 1.00 1.00 2008 Maricopa Co. PM10 Emission Inventory 108 June 2010 5.5 Emission factor estimation Vehicle exhaust emission factors for PM10, PM2.5, NOx, SOx, and NH3 were calculated using MOBILE6.2, as well as tire wear and brake wear emission factors for PM10 and PM2.5. The exhaust PM10 and PM2.5 estimates include the components of lead, sulfate, and carbon (organic, elemental, and total). The MOBILE6.2 emission factors were combined with VMT estimates to produce total emission estimates for onroad vehicle exhaust, tire wear, and brake wear emissions. The MOBILE6.2 runs were executed by MAG. The contact person for the MOBILE6.2 emission estimates is Ieesuck Jung (602-254-6300). In order to calculate vehicle emission factors for the 2008 annual average day, two MOBILE6.2 runs reflecting vehicles registered locally (subject to the I/M program) and those not registered locally (not participating in the I/M program) were executed using fuel and temperature data for each month of the year. Fugitive dust emission factors were derived from AP-42 by MAG. The derivation of paved and unpaved road emission factors is discussed in Section 5.5.2. The contact person for the fugitive dust emission estimates is Cathy Arthur (602-254-6300). 5.5.1 MOBILE6.2 emission factor model The emission factors not related to fugitive dust were calculated using MOBILE6.2. The emission factors estimated with these runs were combined to reflect the actual proportions of vehicles subject to the specified levels of inspection. The term “I/M vehicles” denotes vehicles which are required to undergo an emission test and/or inspection under the Arizona Vehicle Inspection/ Maintenance Program. It is important to note that participation in the I/M program is required for all vehicles registered in the PM10 NAA, with the exception of certain model years and vehicle classes. However, it is assumed that only 91.6 percent of the vehicles operating within the PM10 NAA and Maricopa County participate in the I/M program and the remaining 8.4 percent do not participate in the program. These percentages reflect the control measures “Tougher Enforcement of Vehicle Registration and Emissions Test Compliance” and “Expansion of Area A Boundaries”, described in the MAG Eight-Hour Ozone Redesignation Request and Maintenance Plan for the Maricopa Nonattainment Area (MAG, 2009). In the absence of any additional data, this percentage split is assumed to apply directly to VMT as well. 5.5.1.1 MOBILE6.2 inputs In order to accurately reflect the state of the I/M program in the PM10 NAA, several MOBILE6.2 runs were performed and the emission factors from those runs weighted together. The specific model run inputs to the MOBILE6.2 model are described in Appendix 5. 5.5.1.2 MOBILE6.2 outputs MOBILE6.2 was executed with the inputs described in Appendix 5 to obtain composite emission factors in grams per mile (g/mi) for PM10, PM2.5, NOx, SOx, and NH3. These values were obtained for the following eight vehicle classes: light-duty gas vehicles (LDGV), light-duty gas trucks of gross vehicle weight under 6000 pounds (LDGT1/LDGT2; LDGT12) and 6000 pounds 2008 Maricopa Co. PM10 Emission Inventory 109 June 2010 or more (LDGT3/LDGT4; LDGT34), heavy-duty gas vehicles (HDGV), light-duty diesel vehicles (LDDV), light-duty diesel trucks (LDDT), heavy-duty diesel vehicles (HDDV), and motorcycles (MC); by the following twelve facility types: rural interstate, rural other principal arterial, rural minor arterial, rural major collector, rural minor collector, rural local, urban interstate, urban other freeway/expressway, urban other principal arterial, urban minor arterial, urban collector, and urban local. The emission factors generated for each month of the year in 2008 are presented in Appendix 5. These values were subsequently used in developing emission estimates. 5.5.1.3 MOBILE6.2 emission estimates MOBILE6.2 was used to generate onroad emission factors and VMT mix by vehicle class and facility type. Daily VMTs for an annual average day (Table 5.2–1) were then multiplied by the VMT mix by vehicle class and the appropriate emission factor (Appendix 5) to estimate emissions. VMT mix refers to the fraction of total onroad vehicle miles of travel from a particular vehicle type. The 2008 vehicle registration data for Maricopa County was input to MOBILE6.2 to obtain the VMT mix. Tables 5.5–1 and 5.5–2 show the calculated annual and average daily PM10, PM2.5, NOx, SOx, and NH3 emissions by facility type and vehicle class in the PM10 NAA and Maricopa County, respectively. Emission estimates for PM10 and PM2.5 in these tables represent exhaust, tire wear, and brake wear emissions. 2008 Maricopa Co. PM10 Emission Inventory 110 June 2010 Table 5.5–1. Annual and average daily onroad mobile source emissions by facility type and vehicle class in the PM10 NAA. Rural Interstate Rural Other Principal Arterial Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Vehicle Class LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV SCC 2201001110 2201020110 2201040110 2201070110 2201080110 2230001110 2230060110 2230070110 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001130 2201020130 2201040130 2201070130 2201080130 2230001130 2230060130 2230070130 2201001150 2201020150 2201040150 2201070150 2201080150 2230001150 2230060150 2230070150 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001170 2201020170 2201040170 2201070170 2201080170 2230001170 2230060170 2230070170 2201001190 2201020190 2201040190 2201070190 2201080190 2230001190 2230060190 2230070190 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001210 2201020210 2201040210 2201070210 2201080210 2230001210 2230060210 2230070210 PM10 Annual emissions (tons/yr) PM2.5 NOx SOx 9.04 8.52 3.56 2.49 0.17 0.05 0.17 19.12 3.45 3.25 1.36 0.95 0.07 0.02 0.06 7.29 1.44 1.35 0.57 0.40 0.03 0.01 0.03 3.04 4.23 3.99 1.67 1.16 0.08 0.02 0.08 8.94 0.60 0.57 0.24 0.16 0.01 0.00 0.01 1.27 4.39 4.13 1.72 1.20 0.08 0.02 0.08 9.24 2008 Maricopa Co. PM10 Emission Inventory 4.14 3.96 1.65 1.80 0.10 0.04 0.13 15.09 1.58 1.51 0.63 0.68 0.04 0.01 0.05 5.75 0.66 0.63 0.26 0.29 0.02 0.01 0.02 2.40 1.93 1.86 0.77 0.84 0.05 0.02 0.06 7.05 0.27 0.26 0.11 0.12 0.01 0.00 0.01 1.00 2.02 1.92 0.80 0.86 0.05 0.02 0.06 7.29 214.04 301.17 135.02 91.03 6.95 0.29 1.45 740.19 77.74 109.22 49.26 31.95 2.47 0.10 0.49 227.12 32.44 45.58 20.56 13.33 1.03 0.04 0.20 94.77 97.56 135.78 61.24 37.34 2.90 0.12 0.60 279.39 13.84 19.26 8.69 5.30 0.41 0.02 0.08 39.63 100.79 137.58 62.38 33.26 2.52 0.17 0.83 361.90 111 2.47 2.96 1.62 0.64 0.02 0.00 0.01 0.64 0.94 1.13 0.62 0.24 0.01 0.00 0.00 0.25 0.39 0.47 0.26 0.10 0.00 0.00 0.00 0.10 1.15 1.38 0.76 0.30 0.01 0.00 0.00 0.30 0.16 0.20 0.11 0.04 0.00 0.00 0.00 0.04 1.18 1.42 0.77 0.31 0.01 0.00 0.00 0.31 NH3 Average daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 36.93 33.96 14.17 1.74 0.05 0.00 0.01 2.84 14.08 12.94 5.40 0.66 0.02 0.00 0.01 1.08 5.87 5.40 2.25 0.28 0.01 0.00 0.00 0.45 17.26 15.87 6.62 0.81 0.02 0.00 0.01 1.33 2.45 2.25 0.94 0.12 0.00 0.00 0.00 0.19 17.85 16.41 6.85 0.84 0.03 0.00 0.01 1.37 49.4 46.6 19.4 13.6 1.0 0.2 0.9 104.5 18.8 17.7 7.4 5.2 0.4 0.1 0.4 39.8 7.9 7.4 3.1 2.2 0.2 0.0 0.1 16.6 23.1 21.8 9.1 6.3 0.4 0.1 0.4 48.8 3.3 3.1 1.3 0.9 0.1 0.0 0.1 6.9 24.0 22.6 9.4 6.5 0.5 0.1 0.4 50.5 22.6 21.6 9.0 9.8 0.5 0.2 0.7 82.5 8.6 8.2 3.4 3.7 0.2 0.1 0.3 31.4 3.6 3.4 1.4 1.6 0.1 0.0 0.1 13.1 10.6 10.1 4.2 4.6 0.2 0.1 0.3 38.5 1.5 1.4 0.6 0.6 0.0 0.0 0.0 5.5 11.0 10.5 4.4 4.7 0.3 0.1 0.3 39.9 1,169.6 1,645.7 737.8 497.4 38.0 1.6 7.9 4,044.7 424.8 596.8 269.2 174.6 13.5 0.5 2.7 1,241.1 177.3 249.1 112.3 72.9 5.6 0.2 1.1 517.9 533.1 742.0 334.7 204.0 15.9 0.7 3.3 1,526.7 75.6 105.3 47.5 28.9 2.2 0.1 0.5 216.6 550.8 751.8 340.8 181.8 13.8 0.9 4.5 1,977.6 13.5 16.2 8.8 3.5 0.1 0.0 0.0 3.5 5.1 6.2 3.4 1.3 0.0 0.0 0.0 1.3 2.1 2.6 1.4 0.6 0.0 0.0 0.0 0.6 6.3 7.6 4.1 1.6 0.0 0.0 0.0 1.6 0.9 1.1 0.6 0.2 0.0 0.0 0.0 0.2 6.4 7.7 4.2 1.7 0.0 0.0 0.0 1.7 201.8 185.6 77.5 9.5 0.3 0.0 0.1 15.5 76.9 70.7 29.5 3.6 0.1 0.0 0.0 5.9 32.1 29.5 12.3 1.5 0.0 0.0 0.0 2.5 94.3 86.7 36.2 4.4 0.1 0.0 0.0 7.3 13.4 12.3 5.1 0.6 0.0 0.0 0.0 1.0 97.5 89.7 37.4 4.6 0.1 0.0 0.0 7.5 June 2010 Table 5.5–1. Annual and average daily onroad mobile source emissions by facility type and vehicle class in the PM10 NAA (continued). Facility Type Urban Interstate Urban Other Freeway And Expressway Urban Other Principal Arterial Urban Minor Arterial Urban Collector Urban Local Vehicle Class LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV SCC 2201001230 2201020230 2201040230 2201070230 2201080230 2230001230 2230060230 2230070230 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001250 2201020250 2201040250 2201070250 2201080250 2230001250 2230060250 2230070250 2201001270 2201020270 2201040270 2201070270 2201080270 2230001270 2230060270 2230070270 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001290 2201020290 2201040290 2201070290 2201080290 2230001290 2230060290 2230070290 2201001310 2201020310 2201040310 2201070310 2201080310 2230001310 2230060310 2230070310 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001330 2201020330 2201040330 2201070330 2201080330 2230001330 2230060330 2230070330 PM10 41.23 38.85 16.23 11.34 0.80 0.21 0.77 87.19 70.18 66.13 27.63 19.31 1.36 0.35 1.32 148.41 81.19 76.65 32.02 22.28 1.57 0.41 1.52 171.73 53.23 50.25 20.99 14.61 1.03 0.27 1.00 112.59 17.66 16.63 6.94 4.82 0.34 0.09 0.33 37.20 34.17 32.19 13.42 9.31 0.66 0.17 0.64 71.99 Annual emissions (tons/year) PM2.5 NOx SOx NH3 18.88 18.04 7.54 8.19 0.44 0.17 0.60 68.80 32.13 30.71 12.83 13.94 0.75 0.29 1.02 117.12 37.17 35.68 14.84 16.08 0.87 0.33 1.18 135.53 24.37 23.39 9.73 10.54 0.57 0.22 0.77 88.86 8.09 7.73 3.21 3.47 0.19 0.07 0.26 29.35 15.72 14.95 6.25 6.71 0.37 0.14 0.50 56.81 2008 Maricopa Co. PM10 Emission Inventory 966.38 1,359.1 0 610.22 406.42 30.63 1.27 6.27 3,208.5 1,645.00 2,313.54 1,038.75 6 691.83 52.15 2.16 10.67 5,461.7 1,882.33 7 2,616.8 1,180.21 9 714.80 55.62 2.33 11.53 5,386.8 1,234.16 1,715.61 1 773.81 468.63 36.46 1.53 7.56 3,531.6 9 429.01 590.53 266.16 148.35 11.40 0.53 2.62 1,223.6 0 785.04 1,071.5 4 485.82 259.07 19.64 1.30 6.43 2,818.7 2 112 11.26 13.51 7.38 2.92 0.07 0.00 0.02 2.94 19.17 23.00 12.56 4.98 0.12 0.00 0.04 5.00 22.17 26.61 14.53 5.76 0.14 0.00 0.05 5.79 14.54 17.44 9.52 3.77 0.09 0.00 0.03 3.80 4.80 5.70 3.15 1.25 0.03 0.00 0.01 1.25 9.16 11.03 6.04 2.43 0.06 0.00 0.02 2.43 168.40 154.84 64.63 7.94 0.24 0.01 0.07 12.94 286.65 263.59 110.02 13.52 0.41 0.02 0.11 22.04 331.62 304.91 127.26 15.64 0.48 0.02 0.13 25.49 217.41 199.90 83.43 10.25 0.31 0.02 0.09 16.71 71.83 66.04 27.56 3.39 0.10 0.01 0.03 5.52 139.01 127.81 53.34 6.56 0.20 0.01 0.05 10.68 Average daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 225.3 212.3 88.7 62.0 4.4 1.1 4.2 476.4 383.5 361.3 151.0 105.5 7.4 1.9 7.2 811.0 443.7 418.8 175.0 121.8 8.6 2.2 8.3 938.4 290.9 274.6 114.7 79.8 5.6 1.5 5.5 615.2 96.5 90.9 37.9 26.3 1.9 0.5 1.8 203.3 186.7 175.9 73.3 50.9 3.6 0.9 3.5 393.4 103.1 98.6 41.2 44.7 2.4 0.9 3.3 376.0 175.6 167.8 70.1 76.2 4.1 1.6 5.6 640.0 203.1 195.0 81.1 87.9 4.8 1.8 6.5 740.6 133.2 127.8 53.2 57.6 3.1 1.2 4.2 485.5 44.2 42.2 17.6 19.0 1.0 0.4 1.4 160.4 85.9 81.7 34.1 36.7 2.0 0.8 2.7 310.4 5,280.8 7,426.8 3,334.5 2,220.9 167.4 6.9 34.3 17,532. 8 8,989.3 12,642. 3 5,676.3 3,780.5 285.0 11.8 58.3 29,845. 5 10,286. 2 14,299. 5 6,449.7 3,906.0 303.9 12.8 63.0 29,436. 4 6,743.8 9,374.9 4,228.5 2,560.8 199.3 8.4 41.3 19,298. 9 2,344.3 3,227.0 1,454.4 810.6 62.3 2.9 14.3 6,686.3 4,289.8 5,855.4 2,654.8 1,415.7 107.3 7.1 35.1 15,402. 9 61.5 73.8 40.3 16.0 0.4 0.0 0.1 16.0 104.7 125.7 68.6 27.2 0.7 0.0 0.2 27.3 121.2 145.4 79.4 31.5 0.8 0.0 0.3 31.6 79.4 95.3 52.0 20.6 0.5 0.0 0.2 20.7 26.2 31.1 17.2 6.9 0.2 0.0 0.1 6.9 50.0 60.3 33.0 13.3 0.3 0.0 0.1 13.3 920.2 846.1 353.2 43.4 1.3 0.1 0.4 70.7 1,566.4 1,440.4 601.2 73.9 2.3 0.1 0.6 120.4 1,812.1 1,666.2 695.4 85.5 2.6 0.1 0.7 139.3 1,188.1 1,092.4 455.9 56.0 1.7 0.1 0.5 91.3 392.5 360.9 150.6 18.5 0.6 0.0 0.2 30.2 759.6 698.4 291.5 35.8 1.1 0.1 0.3 58.4 June 2010 Table 5.5–2. Annual and average daily onroad mobile source emissions by facility type and vehicle class in Maricopa County. Facility Type Rural Interstate Rural Other Principal Arterial Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Vehicle Class LDGV LDGT12 SCC 2201001110 2201020110 LDGT34 2201040110 HDGV MC LDDV LDDT HDDV 2201070110 2201080110 2230001110 2230060110 2230070110 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001130 2201020130 2201040130 2201070130 2201080130 2230001130 2230060130 2230070130 2201001150 2201020150 2201040150 2201070150 2201080150 2230001150 2230060150 2230070150 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001170 2201020170 2201040170 2201070170 2201080170 2230001170 2230060170 2230070170 2201001190 2201020190 2201040190 2201070190 2201080190 2230001190 2230060190 2230070190 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001210 2201020210 2201040210 2201070210 2201080210 2230001210 2230060210 2230070210 PM10 Annual emissions (tons/year) PM2.5 NOx SOx NH3 Average daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 11.64 10.96 5.33 5.09 280.13 394.47 3.18 3.81 47.52 43.70 63.6 59.9 29.1 27.8 1,530.8 2,155.6 17.4 20.8 259.7 238.8 4.58 3.20 0.22 0.06 0.22 24.60 4.43 4.18 1.74 1.22 0.09 0.02 0.08 9.37 1.85 1.74 0.73 0.51 0.04 0.01 0.03 3.91 5.44 5.13 2.14 1.49 0.11 0.03 0.10 11.50 0.77 0.73 0.30 0.21 0.01 0.00 0.01 1.63 5.65 5.32 2.22 1.54 0.11 0.03 0.11 11.90 2.13 2.31 0.12 0.05 0.17 19.42 2.03 1.94 0.81 0.88 0.05 0.02 0.06 7.40 0.85 0.81 0.34 0.37 0.02 0.01 0.03 3.09 2.49 2.39 0.99 1.08 0.06 0.02 0.08 9.07 0.35 0.34 0.14 0.15 0.01 0.00 0.01 1.29 2.60 2.47 1.03 1.11 0.06 0.02 0.08 9.39 176.49 121.33 9.77 0.43 2.11 1,063.5 1 100.45 141.23 63.64 41.77 3.22 0.13 0.63 295.20 41.93 58.95 26.56 17.43 1.34 0.05 0.26 123.22 125.26 174.46 78.69 48.16 3.75 0.16 0.77 359.17 17.80 24.79 11.18 6.84 0.53 0.02 0.11 51.03 129.72 177.06 80.28 42.81 3.25 0.21 1.06 465.78 2.08 0.82 0.02 0.00 0.01 0.83 1.21 1.45 0.79 0.31 0.01 0.00 0.00 0.32 0.51 0.61 0.33 0.13 0.00 0.00 0.00 0.13 1.48 1.78 0.97 0.39 0.01 0.00 0.00 0.39 0.21 0.25 0.14 0.05 0.00 0.00 0.00 0.06 1.51 1.82 1.00 0.40 0.01 0.00 0.00 0.40 18.24 2.24 0.07 0.00 0.02 3.65 18.10 16.64 6.95 0.85 0.03 0.00 0.01 1.39 7.56 6.95 2.90 0.36 0.01 0.00 0.00 0.58 22.20 20.42 8.52 1.05 0.03 0.00 0.01 1.71 3.15 2.90 1.21 0.15 0.00 0.00 0.00 0.24 22.97 21.12 8.81 1.08 0.03 0.00 0.01 1.77 25.0 17.5 1.2 0.3 1.2 134.5 24.2 22.8 9.5 6.7 0.5 0.1 0.5 51.2 10.1 9.5 4.0 2.8 0.2 0.1 0.2 21.4 29.7 28.0 11.7 8.2 0.6 0.1 0.6 62.8 4.2 4.0 1.7 1.2 0.1 0.0 0.1 8.9 30.9 29.1 12.1 8.4 0.6 0.2 0.6 65.0 11.6 12.6 0.7 0.3 0.9 106.1 11.1 10.6 4.4 4.8 0.3 0.1 0.4 40.4 4.6 4.4 1.8 2.0 0.1 0.0 0.1 16.9 13.6 13.1 5.4 5.9 0.3 0.1 0.4 49.6 1.9 1.9 0.8 0.8 0.0 0.0 0.1 7.0 14.2 13.5 5.6 6.1 0.3 0.1 0.4 51.3 964.4 663.0 53.4 2.3 11.5 5,811.5 548.9 771.7 347.8 228.2 17.6 0.7 3.5 1,613.1 229.1 322.1 145.2 95.3 7.3 0.3 1.4 673.4 684.5 953.3 430.0 263.2 20.5 0.9 4.2 1,962.7 97.3 135.5 61.1 37.4 2.9 0.1 0.6 278.9 708.9 967.6 438.7 233.9 17.7 1.2 5.8 2,545.2 11.4 4.5 0.1 0.0 0.0 4.5 6.6 7.9 4.3 1.7 0.0 0.0 0.0 1.7 2.8 3.3 1.8 0.7 0.0 0.0 0.0 0.7 8.1 9.7 5.3 2.1 0.1 0.0 0.0 2.1 1.2 1.4 0.8 0.3 0.0 0.0 0.0 0.3 8.3 10.0 5.5 2.2 0.1 0.0 0.0 2.2 99.7 12.2 0.4 0.0 0.1 20.0 98.9 91.0 38.0 4.7 0.1 0.0 0.0 7.6 41.3 38.0 15.8 1.9 0.1 0.0 0.0 3.2 121.3 111.6 46.6 5.7 0.2 0.0 0.0 9.3 17.2 15.9 6.6 0.8 0.0 0.0 0.0 1.3 125.5 115.4 48.2 5.9 0.2 0.0 0.0 9.6 2008 Maricopa Co. PM10 Emission Inventory 113 June 2010 Table 5.5–2. Annual and average daily onroad mobile source emissions by facility type and vehicle class in Maricopa County (continued). Facility Type Urban Interstate Urban Other Freeway And Expressway Urban Other Principal Arterial Urban Minor Arterial Urban Collector Urban Local Vehicle Class LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV SCC 2201001230 2201020230 2201040230 2201070230 2201080230 2230001230 2230060230 2230070230 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001250 2201020250 2201040250 2201070250 2201080250 2230001250 2230060250 2230070250 2201001270 2201020270 2201040270 2201070270 2201080270 2230001270 2230060270 2230070270 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001290 2201020290 2201040290 2201070290 2201080290 2230001290 2230060290 2230070290 2201001310 2201020310 2201040310 2201070310 2201080310 2230001310 2230060310 2230070310 LDGV LDGT12 LDGT34 HDGV MC LDDV LDDT HDDV 2201001330 2201020330 2201040330 2201070330 2201080330 2230001330 2230060330 2230070330 PM10 42.40 39.95 16.69 11.66 0.82 0.21 0.80 89.67 72.18 68.01 28.41 19.86 1.39 0.36 1.36 152.64 83.51 78.83 32.93 22.94 1.61 0.42 1.57 176.62 54.75 51.68 21.59 15.04 1.06 0.27 1.03 115.79 18.16 17.11 7.13 4.96 0.35 0.09 0.34 38.25 35.14 33.11 13.80 9.58 0.68 0.18 0.66 74.03 Annual emissions (tons/year) PM2.5 NOx SOx NH3 19.41 18.55 7.75 8.42 0.45 0.17 0.62 70.76 33.05 31.59 13.20 14.34 0.77 0.30 1.05 120.45 38.23 36.69 15.26 16.54 0.90 0.34 1.21 139.39 25.06 24.06 10.01 10.84 0.59 0.22 0.80 91.38 8.32 7.95 3.31 3.57 0.19 0.07 0.26 30.19 16.17 15.38 6.43 6.90 0.38 0.14 0.51 58.43 2008 Maricopa Co. PM10 Emission Inventory 995.06 1,399.3 6 628.29 419.01 31.64 1.31 6.50 3,319.7 1,693.89 2,382.05 1,069.58 2 713.27 53.85 2.24 11.06 5,651.1 1,926.37 2,681.93 1,209.60 7 738.38 57.42 2.39 11.81 5,518.9 1,262.89 1,758.29 5 793.05 484.08 37.65 1.57 7.74 3,618.2 3 441.76 607.95 273.97 152.46 11.71 0.55 2.70 1,260.0 8 807.35 1,101.9 9 499.63 266.44 20.20 1.33 6.61 2,898.8 4 114 11.58 13.90 7.59 3.01 0.07 0.00 0.03 3.02 19.71 23.65 12.92 5.12 0.12 0.00 0.04 5.14 22.81 27.36 14.94 5.92 0.14 0.01 0.05 5.95 14.95 17.94 9.79 3.88 0.09 0.00 0.03 3.90 4.94 5.86 3.24 1.29 0.03 0.00 0.01 1.29 9.42 11.34 6.21 2.50 0.06 0.00 0.02 2.50 173.19 159.25 66.47 8.17 0.25 0.01 0.07 13.31 294.81 271.09 113.15 13.90 0.42 0.02 0.12 22.66 341.07 313.60 130.88 16.08 0.49 0.02 0.13 26.22 223.60 205.59 85.81 10.54 0.32 0.02 0.09 17.19 73.87 67.92 28.35 3.48 0.11 0.01 0.03 5.68 142.96 131.45 54.86 6.74 0.21 0.01 0.06 10.99 Average daily emissions (lbs/day) PM10 PM2.5 NOx SOx NH3 231.7 218.3 91.2 63.7 4.5 1.2 4.4 490.0 394.4 371.6 155.3 108.5 7.6 2.0 7.4 834.1 456.3 430.8 180.0 125.3 8.8 2.3 8.6 965.2 299.2 282.4 118.0 82.2 5.8 1.5 5.6 632.8 99.2 93.5 39.0 27.1 1.9 0.5 1.9 209.0 192.0 180.9 75.4 52.3 3.7 1.0 3.6 404.5 106.1 101.4 42.4 46.0 2.5 1.0 3.4 386.7 180.6 172.6 72.1 78.3 4.2 1.6 5.7 658.2 208.9 200.5 83.4 90.4 4.9 1.9 6.6 761.7 137.0 131.5 54.7 59.2 3.2 1.2 4.4 499.4 45.5 43.4 18.1 19.5 1.1 0.4 1.4 165.0 88.3 84.0 35.1 37.7 2.1 0.8 2.8 319.3 5,437.5 7,646.8 3,433.3 2,289.7 172.9 7.2 35.5 18,140. 9 9,256.0 13,016. 8 5,844.4 3,897.7 294.3 12.2 60.4 30,880. 7 10,526. 4 14,655. 2 6,610.2 4,034.9 313.8 13.1 64.6 30,158. 4 6,901.1 9,607.9 4,333.6 2,645.3 205.7 8.6 42.3 19,771. 7 2,414.0 3,322.1 1,497.1 833.1 64.0 3.0 14.7 6,885.7 4,411.8 6,021.8 2,730.2 1,455.9 110.4 7.3 36.1 15,840. 7 63.3 75.9 41.5 16.4 0.4 0.0 0.1 16.5 107.7 129.3 70.6 28.0 0.7 0.0 0.2 28.1 124.6 149.5 81.6 32.3 0.8 0.0 0.3 32.5 81.7 98.0 53.5 21.2 0.5 0.0 0.2 21.3 27.0 32.0 17.7 7.0 0.2 0.0 0.1 7.0 51.5 62.0 33.9 13.6 0.3 0.0 0.1 13.6 946.4 870.2 363.2 44.6 1.4 0.1 0.4 72.8 1,611.0 1,481.3 618.3 76.0 2.3 0.1 0.6 123.8 1,863.8 1,713.7 715.2 87.9 2.7 0.1 0.7 143.3 1,221.9 1,123.5 468.9 57.6 1.8 0.1 0.5 93.9 403.7 371.1 154.9 19.0 0.6 0.0 0.2 31.0 781.2 718.3 299.8 36.8 1.1 0.1 0.3 60.0 June 2010 5.5.2 Fugitive dust emissions While exhaust, tire wear, and brake wear emissions were calculated using the EPA MOBILE6.2 model, fugitive dust emissions from paved and unpaved roads were calculated using the equations found in sections 13.2.1 and 13.2.2 of the EPA Compilation of Air Pollutant Emission Factors, AP-42 (US EPA, 2006). 5.5.2.1 Paved road fugitive dust emissions In the AP-42 equations, paved road fugitive dust emissions are a function of silt loading values on road surfaces. Paved roads have been classified as freeways, high-traffic arterials, and lowtraffic arterials to reflect different silt loading assumptions. An arterial carrying a traffic volume of less than 10,000 vehicles per average weekday is classified as low-traffic; all other roads that are not freeways are classified as high-traffic arterials. The silt loading levels, in grams per square meter, are 0.02 for freeways, 0.067 for high-traffic arterials, and 0.23 for low-traffic arterials. These silt loadings and the average vehicle weight are consistent with assumptions in the MAG 2007 Five Percent Plan. The fugitive dust emission factors for paved roads were derived by applying the following AP-42 equation:   sL  E = k     2  0 . 65 W  ×   3 1 .5  P  − C  1 −  4N   where: E = annual average particulate emission factor (g/mile), k = particle size multiplier for particle size range (7.3 g/mile for PM10 and 1.1 g/mile for PM2.5), sL = road surface silt loading (0.02 g/m2 for freeways, 0.067 g/m2 for high-traffic arterials, and 0.23 g/m2 for low-traffic arterials), W = average weight of the vehicles traveling on the roads (3.18 tons), C = emission factor for 1980's vehicle fleet exhaust, brake wear and tire wear (0.2119 g/mile for PM10 and 0.1617 g/mile for PM2.5), P = annual number of “wet” days with at least 0.254 mm (0.01 in) of precipitation (39 days 3 in 2008), and N = annual number of days (366 days in 2008). The annual average PM10 and PM2.5 emission factors for paved roads derived from the AP-42 equation are presented in Table 5.5–3. Applying the emission factors in Table 5.5–3 to the VMTs in Table 5.2–2 and converting to pounds per day produces the 2008 uncontrolled particulate emissions from paved roads for the PM10 NAA and Maricopa County, shown in Table 5.5–4. These uncontrolled emissions do not include the 2008 emission reductions attributed to the committed measures in the MAG 2007 Five Percent Plan. 3. Precipitation data for 2008 were obtained from National Oceanic and Atmospheric Administration (NOAA) in the form of local climatological data at Phoenix Sky Harbor Airport. 2008 Maricopa Co. PM10 Emission Inventory 115 June 2010 Table 5.5–3. Fugitive dust emission factors for paved roads. Silt Loading Category Freeways High-Traffic Arterials Low-Traffic Arterials Emission factors (g/mi) PM10 PM2.5 0.18 0.00 0.65 0.00 1.69 0.13 Table 5.5–4. Daily uncontrolled fugitive dust emissions from paved roads. PM10 NAA (lbs/day) Maricopa County (lbs/day) Silt Loading Category PM10 PM2.5 PM10 PM2.5 Freeways 12,236.3 0.0 12,907.5 0.0 High-Traffic Arterials 60,900.0 0.0 62,459.1 0.0 Low-Traffic Arterials 51,486.9 3,960.5 56,422.2 4,340.2 Totals: 124,623.3 3,960.5 131,788.8 4,340.2 The MAG 2007 Five Percent Plan contains a number of committed measures that reduce paved road fugitive dust emissions in the PM10 NAA. Five committed measures that reduce paved road particulate emissions were quantified in the MAG 2007 Five Percent Plan. Table 5.5–5 shows the emission reductions attributed to these committed measures based on their implementation status in 2008. In addition, Table 5.5–5 includes emission reduction credit for 97 PM10 certified street sweepers purchased by December 31, 2007 with FY 2001-2006 MAG Congestion Mitigation and Air Quality Improvement (CMAQ) funds. Reductions for the sweepers that were purchased with FY 2001-2006 CMAQ funds were also applied to base case uncontrolled paved road emissions in the MAG 2007 Five Percent Plan. Table 5.5–5. 2008 benefits of measures that reduce paved road fugitive dust in the PM10 NAA. PM10 emission reduction Annual Average daily Committed Measures in the MAG 2007 Five Percent Plan (tons/yr) (lbs/day) 4 5 1. Public education and outreach program (Measure 1) 19.80 108.2 2. Reduce trackout onto paved roads (Measures 14/15/17) 1,487.0 8,125.7 3. Sweep streets with PM10-certified sweepers (Measure 24) 427.9 2,338.1 4. Pave or stabilize existing unpaved shoulders (Measure 28) 598.1 3,268.2 5. Additional $5M in FY07 MAG TIP for paving roads/shoulders (Measure 43) 6 21.0 115.0 3,007.1 16,432.4 97 PM10-certified sweepers purchased with FY 2001-2006 CMAQ funds: Total 2008 PM10 emission reductions for paved roads: 5,560.9 30,387.6 The emission benefits in Table 5.5-5 were subtracted from the uncontrolled PM10 emissions in Table 5.5-4. The total 2008 PM10 emission reduction of 30,387.6 pounds per day in the PM10 NAA represents 24.4 percent of the uncontrolled PM10 emissions of 124,623.3 pounds per day. This percent reduction was applied to the uncontrolled PM2.5 emissions in the PM10 NAA; then the absolute reduction in PM2.5 emissions due to the control measures was applied to the uncontrolled PM2.5 emissions in Maricopa County. The controlled emissions in tons per year and pounds per day are shown in Table 5.5-6. 4. 366 days were used to convert tons per year to pounds per day in 2008. 5. Measure benefit reflects a 0.1% reduction in 2008 uncontrolled paved road emissions in the MAG 2007 Five Percent Plan. 6. Measure benefit includes only the projects that paved unpaved shoulders in 2008. 2008 Maricopa Co. PM10 Emission Inventory 116 June 2010 Table 5.5–6. Annual controlled fugitive dust emissions from paved roads. Annual emissions Average daily emissions (tons/year) (lbs/day) Area PM10 PM2.5 PM10 PM2.5 PM10 NAA 17,245.1 547.9 94,235.7 2,994.2 Maricopa County 18,556.4 617.4 101,401.2 3,373.8 5.5.2.2 Unpaved road and alley fugitive dust emissions AP-42 emission factors were applied to unpaved road and alley VMTs to estimate fugitive dust emissions (US EPA, 2006). The unpaved road particulate emission factors were derived from the following AP-42 equation for publicly accessible unpaved roads, assuming a silt content of 11.9%, a soil moisture content of 0.5%, and an average speed of 25 miles per hour: 𝑠 1 𝑆 0.5 𝑘 �12� � � 𝑃 30 𝐸=� − 𝐶� �1 − � 0.2 𝑁 𝑀 � � 0.5 where: E = annual average particulate emission factor extrapolated for natural mitigation (lb/mile), k = particle size multiplier for particle size range (1.8 lb/mile for PM10 and 0.18 lb/mile for PM2.5), s = surface material silt content (11.9%), S = mean vehicle speed (25 mph), M = surface material moisture content (0.5%), C = emission factor for 1980's vehicle fleet exhaust, brake wear and tire wear (0.00047 lb/mile for PM10 and 0.00036 lb/mile for PM2.5), P = annual number of “wet” days with at least 0.254 mm (0.01 in) of precipitation (39 days in 2008), and N = number of days/year (366 days in 2008). The unpaved road emission factors resulting from the above equation are 1.4554 pounds per mile for PM10 and 0.1453 pounds per mile for PM2.5. The same equation was applied to estimate unpaved alley emission factors, substituting a mean vehicle speed of 10 mph. The resultant unpaved alley emission factors are 0.9203 pounds per mile for PM10 and 0.0918 pounds per mile for PM2.5. Multiplying these emission factors by the VMTs in Table 5.2–3 results in the uncontrolled emissions shown in Table 5.5–7. These uncontrolled emissions do not include the 2008 emission reductions attributed to the committed measures in the MAG 2007 Five Percent Plan for PM10. Table 5.5–7. Daily uncontrolled unpaved road and alley fugitive dust emissions. PM10 (lbs/day) PM2.5 (lbs/day) Area Unpaved Roads Unpaved Alleys Unpaved Roads Unpaved Alleys PM10 NAA 69,835.9 5,443.6 6,972.1 543.0 Maricopa County 73,117.8 5,699.4 7,299.7 568.5 2008 Maricopa Co. PM10 Emission Inventory 117 June 2010 The MAG 2007 Five Percent Plan contains a number of committed measures that reduce unpaved road and alley fugitive dust emissions in the PM10 NAA (MAG, 2007). Four committed measures that reduce unpaved road and alley PM10 emissions were quantified in the MAG 2007 Five Percent Plan. The 2008 emission reductions attributed to these measures are shown in Table 5.5–8. Table 5.5–8. 2008 benefits of measures that reduce unpaved road and alley fugitive dust in the PM10 NAA. PM10 emission reductions Annual Average daily Committed Measures in the MAG 2007 Five Percent Plan (tons/yr) (lbs/day) 7 8 1. Public education and outreach program (Measure 1) 17.5 95.6 2. Pave or stabilize existing public dirt roads and alleys (Measure 26) 1,488.0 8,131.2 3. Limit speeds to 15 mph on high-traffic dirt roads (Measure 27) 390.4 2,133.4 4. Additional $5M in FY07 MAG TIP for paving roads/shoulders (Measure 43) 9 169.5 926.2 Total 2008 PM10 emission reductions for unpaved roads: 2,065.4 11,286.4 The reductions in Table 5.5-8 were subtracted from the uncontrolled PM10 emissions in Table 5.5-7. The total 2008 PM10 emission reduction of 11,286.4 pounds per day represents 15.0 percent of the total uncontrolled unpaved road and alley PM10 emissions of 75,279.5 pounds per day in the PM10 NAA. This percent reduction was applied to the uncontrolled PM2.5 emissions in the PM10 NAA; then the absolute reduction in PM2.5 emissions due to the control measures was applied to the uncontrolled PM2.5 emissions in Maricopa County. The controlled emissions in tons per year and pounds per day are shown in Table 5.5-9. Table 5.5–9. Annual and average daily controlled fugitive dust emissions from unpaved roads. Annual emissions Average daily emissions (tons/year) (lbs/day) Area PM10 PM2.5 PM10 PM2.5 PM10 NAA 11,710.70 1,169.00 63,993.1 6,387.8 Maricopa County 12,358.20 1,233.60 67,530.9 6,741.0 7. 366 days were used to convert tons per year to pounds per day in 2008. 8. Measure benefit reflects a 0.1% reduction in 2008 uncontrolled paved road emissions in the MAG 2007 Five Percent Plan. 9. Measure benefit includes only the projects that paved unpaved roads in 2008. 2008 Maricopa Co. PM10 Emission Inventory 118 June 2010 5.6 Summary of particulate emissions from onroad mobile sources Table 5.6–1 summarizes the annual emissions and the average daily emissions for PM10, PM2.5, NOx, SOx, and NH3 from all onroad mobile sources in Maricopa County in 2008. Similar data for the PM10 NAA are presented in Table 5.6–2. Table 5.6–1. Annual and average daily emissions from all onroad mobile sources in Maricopa County. Emission Category Exhaust, tire wear, and brake wear Paved road fugitive dust Unpaved road and alley fugitive dust Totals: Table 5.6–2. PM10 1,601.53 18,556.4 12,358.2 32,516.13 Annual emissions (tons/year) PM2.5 NOx SOx NH3 999.17 51,609.08 309.83 3,330.43 617.4 — — — 1,233.6 — — — 2,850.17 51,609.08 309.83 3,330.43 PM10 Average daily emissions (lbs/day) PM2.5 NOx SOx NH3 8,752.0 5,459.7 282,017.2 1,692.6 18,199.0 101,401.2 3,373.8 — — — — 282,017.2 — 1,692.6 — 18,199.0 67,530.9 6,741.0 177,684.1 15,574.5 Annual and average daily emissions from all onroad mobile sources in the PM10 NAA. Annual emissions (tons/year) Average daily emissions (lbs/day) Emission Category PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 Exhaust, tire wear, and brake wear 1,529.54 954.23 49,142.49 295.90 3,180.66 8,357.7 5,213.8 268,538.4 1,616.4 17,380.4 Paved road fugitive dust 17,245.1 547.9 — — — 94,235.7 2,994.2 — — — Unpaved road and alley fugitive dust 11,710.7 1,169.0 — — — 63,993.1 6,387.8 — — — Totals: 30,485.34 2,671.13 49,142.49 295.90 3,180.66 166,586.5 14,595.8 268,538.4 1,616.4 17,380.4 5.7 Quality assurance process 5.7.1 VMT estimates Normal quality assurance procedures, including automated and manual consistency checks, were conducted by MAG in developing the 2008 TransCAD traffic assignment network used to generate the VMT data. The VMT estimates using the MAG travel demand model have been validated against approximately 2,200 traffic counts collected in 2006–2008. 5.7.2 Emission factor estimates The quality assurance process performed on the MOBILE6.2 analyses included accuracy, completeness, and reasonableness checks. For accuracy and completeness, all calculations were checked by an independent reviewer. Any errors found were corrected and the changes were then rechecked by the reviewer. 5.7.3 Draft particulate matter emissions inventory The draft onroad mobile source portion of the 2008 periodic ozone precursor emissions inventory was reviewed using published EPA quality review guidelines for base year emission inventories (US EPA, 1992b). The procedure review (Levels I, II, and III) included checks for completeness, consistency, and the correct use of appropriate procedures. 2008 Maricopa Co. PM10 Emission Inventory 119 June 2010 5.8 References MAG, 2007. MAG 2007 Five Percent Plan for PM10 for the Maricopa County Nonattainment Area, December 2007. MAG, 2009. MAG Eight-Hour Ozone Redesignation Request and Maintenance Plan for the Maricopa Nonattainment Area, February 2009. MAG, 2010. VMT Estimation for the 2009 MAG Unpaved Road Inventory. Memorandum prepared by Cathy Arthur, MAG Air Quality Policy Manager. January 26, 2010. US EPA, 1991. Emission Inventory Requirements for Ozone State Implementation Plans, EPA450/4-91-010, March 1991. US EPA, 1992a. Procedures for Emission Inventory Preparation Volume IV: Mobile Sources, EPA-450/4-81-026d (Revised), 1992. US EPA, 1992b. Quality Review Guidelines for 1990 Base Year Emission Inventories, EPA454/R-92-007, July 1992. US EPA, 2002. Technical Guidance on the Use of MOBILE6 for Emission Inventory Preparation, January 2002. US EPA, 2003. User's Guide to MOBILE6.1 and MOBILE6.2 (Mobile Source Emission Factor Model), EPA420-R-03-010, August 2003. US EPA, 2006. Compilation of Air Pollutant Emission Factors, AP-42, Fifth Edition, Vol. I: Stationary, Point and Area Sources. Section 13.2.1: Paved Roads and Section 13.2.2: Unpaved Roads. November 2006 (http://www.epa.gov/ttn/chief/ap42/ch13/index.html). 2008 Maricopa Co. PM10 Emission Inventory 120 June 2010 6. 6.1 Biogenic Sources Introduction Biogenic emissions have been estimated for the 2008 Periodic Emissions Inventory for particulate matter in Maricopa County (9,223 square miles) and the PM10 Nonattainment Area (NAA) (2,887 square miles). The Model of Emissions of Gases and Aerosols from Nature (MEGAN) has been used to estimate the biogenic emissions. MEGAN is a state-of-the-art biogenic emissions model developed by the National Center for Atmospheric Research (NCAR). Some important corrections and improvements were made in the latest version of MEGAN2.04 (Guenther, 2007) compared to previous versions (Guenther, 2006, 2006a and 2006b). MEGAN2.04 was applied to compute biogenic emissions in Maricopa County and the PM10 NAA. Among the chemical species included in MEGAN, only nitric oxide (NO) is attributable to particulate matter formation. Therefore, only NOx emissions are included in the inventory. The MEGAN runs were executed by the Maricopa Association of Governments. The contact person for the MEGAN emission estimates is Feng Liu (602-254-6300). 6.2 Modeling domain As a numerical model, the MEGAN inputs and outputs are given in user-defined two-dimensional grid cells. To develop biogenic emissions for the 2008 Periodic Emission Inventory for particulate matter, the 4-km and 12-km modeling domains developed for the MAG eight-hour ozone plans for the Maricopa Nonattainment Area (MAG, 2007 and 2009), were employed for the PM10 NAA and Maricopa County, respectively. The definitions of these two domains in the Universal Transverse Mercator (UTM) coordinate system are presented in Table 6.2–1. Since MEGAN estimates biogenic emissions for entire modeling domains rather than specific areas, additional input files, masking areas covered by the PM10 NAA and Maricopa County, were developed by applying Geographic Information Systems (GIS) to calculate emissions for those two target areas. In order to represent the target area, the masking file assigns 1.0 for the grid cells fully covered by the target area, a fractional value for grid cells partially covered by the target area, and 0.0 for grid cells outside the target area. As shown in Figure 6.3–1, biogenic emissions for the PM10 NAA and Maricopa County were extracted from MEGAN runs for the masked grid cells in the 4-km and 12-km modeling domains, respectively. Table 6.2–1. Two modeling domains defined in the UTM coordinate system. Grid Horizontal Resolution Grid Size Domain Range (km) Target Area 4-km 50 × 29 (297,3652) to (497,3768) PM10 NAA 12-km 111 × 84 (-275, 3188) to (1057,4196) Maricopa County 6.3 Input data To calculate biogenic emissions using MEGAN, the following gridded input files for land cover and meteorological data were prepared: 1. EFMAP_LAI file: This file provides emission factors (EF) for 20 MEGAN species including NO, and monthly average leaf index (LAI) for 12 months for each grid cell. 2008 Maricopa Co. PM10 Emission Inventory 121 June 2010 2. PFTF file: This input file gives percentage of four plant function types (PFT) including broadleaf trees (BT), needle leaf trees (NT), grass and crops (HB) and shrubs (SB) for each model domain grid location. 3. METCRO2D file: This file contains meteorological parameters including temperature, short wave radiation, wind speed, humidity and soil moisture for each grid. 29 28 27 26 25 24 23 22 21 20 19 18 17 16 15 14 13 12 11 10 9 8 7 6 5 4 3 2 1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 81 76 71 66 61 56 51 46 41 36 31 26 21 16 11 6 1 1 6 11 16 21 26 31 36 41 46 51 56 61 66 71 76 81 86 91 96 101 106 111 Figure 6.3–1. Mask of the PM10 NAA in the 4-km modeling domain (top) and mask of Maricopa County in the 12-km modeling domain (bottom). 6.3.1 Land cover data The land cover data, including the monthly LAI, PFT, and EF, are provided by the EFMAP_LAI and PFTF files. These input data were derived from the MEGAN land cover database available 2008 Maricopa Co. PM10 Emission Inventory 122 June 2010 at a base resolution of 30 seconds latitude by 30 seconds longitude (~1×km2) in ArcGIS format (http://acd.ucar.edu/~guenther/MEGAN/MEGAN.htm). For the MEGAN runs, however, the default land cover data during the summer season (June to August) were replaced by local datasets, which were developed by a field study conducted by Dr. Guenther in June 2006 (ENVIRON, 2006). The substitution was made because the default database systematically underestimated the LAIs in Maricopa County. 6.3.2 Weather data The weather data used by MEGAN are temperature, downward short wave radiation, wind speed, humidity and soil moisture. The Measurement and Instrumentation Data Center (MIDC) collects irradiance and meteorological data from nation-wide stations, one of which is located in northern Phoenix (33.83° N, 112.17° W, denoted by red star in Figure 6.3–2), and is operated by the Phoenix Federal Correction Institution (PFCI). The archived hourly temperature, wind speed, humidity and radiation data from this site are available to the public. Monthly mean diurnal cycles of the weather parameters were calculated based on hourly data for the year 2008, and a netCDF file representing 24-hour data for each month was prepared for MEGAN inputs. Figure 6.3–2. Boundaries of the PM10 NAA (red line), the 4-km eight-hour ozone modeling domain (pink line), Maricopa County (blue line), and the meteorological observation site (red star). Biogenic NO is mainly emitted from wetted soil. The emission rate is dependent not only upon temperature and downward short wave radiation but also on soil moisture. Due to dry conditions year round in Maricopa County, the NO flux from the surface is very low compared to other states with higher precipitation. Only moisture delivery by Arizona monsoons leads to precipitation during the summer. This precipitation, in turn, increases soil moisture and humidity. According to weather records at the Phoenix Sky Harbor International Airport, the precipitation 2008 Maricopa Co. PM10 Emission Inventory 123 June 2010 in the Phoenix area was 0.0 and 2.15 inches in June and July 2008, respectively. Therefore, maximum monthly NO emissions occurred in July 2008. In general, however, NO emissions in the Maricopa County area are temperature and radiation dominated during the year. Figure 6.3– 3 shows annual mean diurnal cycles of temperature and radiation. The peak temperature around 4:00-5:00 pm lags three hours behind the peak radiation. The delay is due to the fact that heating of the air occurs not from the sun’s rays, but from heating of the earth and infrared radiation leaving the ground in the form of heat. As a result, maximum hourly emission rates take place in the afternoon because the emission rates are positively related to both temperature and short wave radiation (Guenther, 2006). 85 Temperature (F) 80 75 70 65 60 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 Hour of the day 800 Downward short wave radiation (W/m2) 700 600 500 400 300 200 100 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 -100 Hour of the day Figure 6.3–3. Annual mean diurnal cycles of measured temperature (top panel) and downward short wave radiation (bottom panel) in 2008. 6.4 Emissions estimation MEGAN runs for the two modeling domains provide hourly emission outputs for the year 2008. Daily mean emissions for each month in 2008 were derived by using the hourly outputs for each month. In addition, monthly total emissions were obtained by multiplying the daily mean emissions for each month by the number of days in the month. The daily mean emissions for the 12 months of 2008 are shown in Table 6.4–1. 2008 Maricopa Co. PM10 Emission Inventory 124 June 2010 Table 6.4–1. Month January February March April May June July August September October November December Daily mean biogenic emissions of NOx in the PM10 NAA and Maricopa County, by month. PM10 NAA Maricopa County kg/day lbs/day kg/day lbs/day 127.2 280.4 355.2 783.1 168.0 370.4 480.9 1,060.2 413.3 911.2 1,131.0 2,493.4 601.7 1,326.5 1,658.8 3,657.0 721.0 1,589.5 1,923.1 4,239.7 1,818.8 4,009.8 4,729.4 10,426.5 1,878.7 4,141.8 4,930.0 10,868.8 1,702.0 3,752.3 4,485.1 9,888.0 1,331.9 2,936.3 3,784.7 8,343.8 651.1 1,435.4 1,839.9 4,056.3 328.5 724.2 910.8 2,008.0 138.6 305.6 388.0 855.4 Monthly mean emissions for Maricopa County and the PM10 NAA are illustrated in Figure 6.4– 1. Monthly emission values are presented in Table 6.4–2. It can be seen that the monthly NOx emissions reached the highest values in July. This is because biogenic emissions of nitric oxide (NO) are mainly from wetted soil. Thus, the NO emission rate depends not only on temperature and radiation, but also on soil moisture, which is related to precipitation. As discussed in Section 6.3, there were 2.15 inches of precipitation in July, but no precipitation in June, 2008. There is also one more day in July than June; therefore, the total NOx monthly emissions in July are higher than in June. 180.0 NA_NOx MC_NOx Total NOx emissions (tonnes/month) 160.0 140.0 120.0 100.0 80.0 60.0 40.0 20.0 0.0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month, 2008 Figure 6.4–1. Monthly emissions of NOx in Maricopa County (pink solid line, abbreviated as “MC”) and the PM10 NAA (blue solid line, abbreviated as “NA”). 2008 Maricopa Co. PM10 Emission Inventory 125 June 2010 Table 6.4–2. Month January February March April May June July August September October November December Totals: 6.5 Monthly biogenic emissions of NOx in the PM10 NAA and Maricopa County. PM10 NAA Maricopa County Metric tons/mo Tons/mo Metric tons/mo Tons/mo 3.94 4.35 11.01 12.14 4.87 5.37 13.95 15.37 12.81 14.12 35.06 38.65 18.05 19.90 49.76 54.85 22.35 24.64 59.62 65.72 54.56 60.15 141.88 156.40 58.24 64.20 152.83 168.46 52.76 58.16 139.04 153.27 39.96 44.05 113.54 125.16 20.18 22.26 57.04 62.87 9.86 10.86 27.32 30.12 4.30 4.74 12.03 13.26 301.88 332.77 813.08 896.27 Summary of biogenic source emissions Daily mean and annual total biogenic NOx emissions for Maricopa County and the PM10 NAA in 2008 are summarized in Table 6.5–1. Due to the incorporation of land cover data that are more characteristic of plants located in the desert southwest, as well as improvements to the MEGAN model, the 2008 data shown in Table 6.5–1 represent a substantial improvement over previous biogenic emission estimates for Maricopa County and the PM10 NAA. Table 6.5–1. Daily mean and annual total NOx emissions from biogenic sources. Daily mean Annual total Geographic Area kg/day lbs/day Metric tons/yr Tons/yr Maricopa County 2,218.1 4,890.0 813.08 896.27 PM10 NAA 823.4 1,815.3 301.88 332.77 6.6 References ENVIRON International Corp., 2006. Final Report, Maricopa Association of Governments 2006 Biogenics Study. Guenther, A., T. Karl, P. Harley, C. Wiedinmyer, P. I. Palmer, and C. Geron, 2006. Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature), Atmos. Chem. Phys., 6, 1-30. Guenther, A., 2006a. User’s Guide to Processing Driving Variables for Model of Emissions of Gases and Aerosols from Nature (MEGAN). Guenther, A., 2006b. User’s Guide to the Model of Emissions of Gases and Aerosols from Nature (MEGAN) Version MEGAN-VBA-2.0. Guenther, 2007. Corrigendum to "Estimates of global terrestrial isoprene emissions using MEGAN (Model of Emissions of Gases and Aerosols from Nature)" Atmos. Chem. Phys., 6, 3181–3210, 2006, Atmos. Chem. Phys., 7, p. 4327. MAG, 2007. Eight-Hour Ozone Plan for the Maricopa Nonattainment Area. Maricopa Association of Governments, Phoenix AZ MAG, 2009. MAG Eight-Hour Ozone Redesignation Request and Maintenance Plan for the Maricopa Nonattainment Area. Maricopa Association of Governments, Phoenix AZ. 2008 Maricopa Co. PM10 Emission Inventory 126 June 2010 Appendix 1. Public Comment Period Documentation Maricopa County Air Quality Department NEWS RELEASE Public Information Officer Maricopa County Air Quality 1001 N. Central Avenue Suite 900 Phoenix, Arizona 85004 (602) 506-6713, desk (602) 526-7307, cell April 26, 2010 Contact: Holly Ward: 602-506-6713/desk * 602-526-7307/cell FOR IMMEDIATE RELEASE Emissions Inventory Public Review Draft Released Document details sources of air pollution emissions within Maricopa County; public workshop to be held May 14 The Maricopa County Air Quality Department announced today the release of its draft 2008 Periodic Emissions Inventory for PM10 for the Maricopa County PM10 Nonattainment Area. The document is now available for an informal 30-day public review period. The PM10 emissions inventory includes emissions estimates for PM10 and PM2.5 as well as three particulate matter precursors: nitrogen oxides (NOx), sulfur oxides (SOx) and ammonia (NH3). The inventory provides emission estimates from point, area, nonroad mobile, onroad mobile and biogenic sources. The report is divided into six chapters, as follows: Chapter 1: Introduction Chapter 2: (Stationary) point sources (large manufacturing facilities, power plants) Chapter 3: Area (non-point) sources (widespread, similar sources, such as fuel combustion, fires, etc.) Chapter 4: Nonroad mobile sources (aircraft, locomotives, lawn movers, tractors, etc.) Chapter 5: Onroad mobile sources (cars, trucks, other vehicles) Chapter 6: Biogenic sources (crops, indigenous vegetation, landscaping, etc.) The latter two chapters were prepared by the Maricopa Association of Governments (MAG). The document is available in electronic format (PDF files) on the department’s website at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Defau lt.aspx The Air Quality Department will hold a public workshop to discuss the draft 2008 Periodic Emissions Inventory for PM10. The workshop will be held at 9 AM at the department’s offices at 1001 N. Central Ave., Suite 560, on Friday, May 14, 2010. (continued on next page) A1-1 NEWS RELEASE: Maricopa County Air Quality Department Emissions Inventory Public Review Draft Released April 26, 2010 The department is also accepting written comments on the draft inventory through Wednesday, May 26, 2010, 5:00 PM. Comments may be submitted to: Maricopa County Air Quality Department Emissions Inventory Unit 1001 N. Central Avenue, Suite 595 Phoenix, AZ 85004 E-mail: EmisInv@mail.maricopa.gov Questions may be addressed to Bob Downing at bdowning@mail.maricopa.gov. #### About Maricopa County Air Quality Department The Maricopa County Air Quality Department is a regulatory agency whose goal is to ensure federal clean air standards are achieved and maintained for the residents and visitors of Maricopa County. The department is governed by the Maricopa County Board of Supervisors and follows air quality standards set forth by the federal Clean Air Act. Calendar - Maricopa County Air Quality Department Page 1 of 1 Site Map | Search | Phone Directory | Departments | Services | Email Alerts text sizer Calendar News Calendar < M-info Search Air Quality Web Site Go May 2010 S M T W 25 26 27 2 3 4 5 9 10 11 12 T > F S 30 1 6 7 8 13 14 15 28 29 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 1 2 3 4 5 Emissions Inventory Public Review Draft Workshop Air Quality Public Review 30-day Period Now Open The Maricopa County Air Quality Department announces the release of its draft 2008 Periodic Emissions Inventory for PM10 for the Maricopa County PM10 Nonattainment Area. The document is now available for an informal 30-day public review period. The PM10 emissions inventory includes emissions estimates for PM10 and PM2.5 as well as three particulate matter precursors: nitrogen oxides (NOx), sulfur oxides (SOx) and ammonia (NH3). The document is available in electronic format (PDF files) on the department’s website at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx The Air Quality Department will hold a public workshop to discuss the draft 2008 Periodic Emissions Inventory for PM10. The workshop will be held at 9 AM at the department’s offices at 1001 N. Central Ave., Suite 560, on Friday, May 14, 2010. (continued on next page) The department is also accepting written comments on the draft inventory through Wednesday, May 26, 2010, 5:00 PM. Comments may be submitted to: Maricopa County Air Quality Department Emissions Inventory Unit 1001 N. Central Avenue, Suite 595 Phoenix, AZ 85004 E-mail: EmisInv@mail.maricopa.gov Questions may be addressed to Bob Downing at bdowning@mail.maricopa.gov. Date: 5/14/2010 Time: 9:00 AM Registration Required: No Fee: None More Info: http://www.maricopa.gov/pr_detail.aspx?releaseID=1424 Contact: Bob Downing bdowning@mail.maricopa.gov Location: Maricopa County Air Quality Department Address: 1001 North Central Ave, suite 595 Phoenix, AZ 85004 Maricopa County Air Quality Department 1001 North Central Avenue, Suite 125, Phoenix AZ 85004 (602) 506-6010 ©2010 Maricopa County Maricopa Home Site Map Legal Information Privacy/Security Policies Maricopa County || 301 W. Jefferson St. || Phoenix, AZ 85003 602-506-3011 http://www.maricopa.gov/aq/EventsDetailPublishers.aspx?date=5/14/2010 06/28/2010 This page intentionally blank. Appendix 2. Instructions for Reporting 2008 Annual Air Pollution Emissions INSTRUCTIONS FOR REPORTING 2008 ANNUAL AIR POLLUTION EMISSIONS January 2009 Emissions Inventory Unit 1001 North Central Avenue, Suite 595 Phoenix, Arizona 85004 (602) 506-6790 (602) 506-6179 (Fax) Copies of this document, related forms and other reference materials are available online at our web site: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx A2-1 TABLE OF CONTENTS WHAT’S NEW FOR 2008? .............................................................................................................. 1 I. INTRODUCTION ............................................................................................................................. 2 Steps to Complete Your 2008 Maricopa County Emissions Inventory II. REPORTING REQUIREMENTS ................................................................................................... 3 - Pollutants to be Reported - Emission Calculation Method Hierarchy III. CONFIDENTIALITY OF DATA SUBMITTED ............................................................................ 5 - Arizona State Statue and Maricopa County Rule IV. HELPFUL HINTS AND INFORMATION ..................................................................................... 6 - What is a Process? - Processes and Materials That Do Not Have to be Reported - Grouping Materials and/or Equipment Under One Process ID - Assigning Identification Numbers (IDs) - Industry-Specific Instructions - Commonly Used Conversion Factors - Additional Resources and Assistance V. INSTRUCTIONS AND EXAMPLES FOR EMISSIONS REPORTING FORMS Business Form ..................................................................................................................................... 8 Stack Form ......................................................................................................................................... 9 Control Device Form ....................................................................................................................... 10 General Process Form ....................................................................................................................... 11 Evaporative Process Form ................................................................................................................ 15 Off-Site Recycling/Disposal Form.................................................................................................... 19 Documentation of Emission Factor Calculations ............................................................................. 20 Data Certification Form (for NON-Title V sources) ........................................................................ 21 How to Calculate an Emission Fee (for Title V sources ONLY)...................................................... 22 Data Certification/Fee Calculation Form (for Title V sources ONLY) ............................................ 23 Maricopa County Emissions Inventory Unit ii Instructions for Reporting 2008 Emissions WHAT'S NEW FOR 2008? Reporting forms:  Some preprinted information on your report may be different from last year’s version. Please review the enclosed forms carefully, and verify all preprinted information.  Many of our reporting forms have changed in past years. If you use your own forms, or a computerized reproduction of our forms, the forms used MUST conform to the current information requirements and FORMAT as supplied on our preprinted forms. “Homemade” reporting forms that vary significantly from the preprinted forms sent to you will not be accepted.  Please VERIFY that your reporting forms match the preprinted forms. Miscellaneous:  If this is the first emissions inventory for your permit and your business did not operate in 2008, you must still submit a completed Business Form and a signed Data Certification Form stating that there were no operations at your facility during 2008.  In accordance with Maricopa County Air Pollution Control Rule 280 (Fees), the 2008 annual emission fee for Title V sources only is $38.25/ton. NOTE: Only Title V sources (those whose air quality permit numbers have a “V” prefix) are subject to this annual emissions fee. Maricopa County Emissions Inventory Unit 1 Instructions for Reporting 2008 Emissions I. INTRODUCTION An annual emissions inventory is a document submitted by a business that: (1) lists all processes emitting reportable air pollutants and (2) provides details about each of those processes. Submitting the emissions inventory report is required as a condition of your Maricopa County Air Quality Permit. A separate emissions report is required for each business location with its own air quality permit. Follow these steps to complete your 2008 Maricopa County emissions inventory: STEP 1: Determine which forms are needed for your business. There are eight different forms available, but not all are required for every type of business. For most permitted sources, the packet you received from us contains the necessary preprinted forms based on your site’s most recent emissions inventory. 1. 2. 3. 4. 5. 6. 7. 8. Business Form: Contains general contact information about the permitted site. This form is required for all businesses. Stack Form: Only required if your business location annually emits over 10 tons of a single pollutant (CO, VOC, NOx, PM10, or SOx). A “stack” is defined as a stack, pipe, vent or opening through which a significant percentage of emissions (from one or more processes) are released into the atmosphere. See the “Stack Form Instructions” on page 9 for specific requirements. Control Device Form: Required only if there is one or more emission control devices used at the business location. General Process Form and Either or both will be required for all businesses. Evaporative Process Form: Off-Site Recycling/Disposal Form: Required if you want to claim off-site recycling or disposal. Emission Factor Calculations: Required as attachment for each process for which you calculated your own emission factors. Data Certification Form or Data Certification/Fee Calculation Form: Only sources with a Title V (permit number would start with “V”) permit are required to pay a fee for their emissions and need to use the Data Certification/Fee Calculation Form. All other sources use the Data Certification Form. } STEP 2: Complete the applicable forms. Verify all preprinted information, and make corrections where necessary. When making corrections, strike out the preprinted data and write in corrections beside it. Please make all changes readily noticeable. Detailed information on how to complete the most common forms is included in this document. The packet you received also contains information about other resources (workshops, one-on-one assistance, etc.) available to help you in completing the necessary forms. STEP 3: Make a copy of your completed emissions inventory report. Make sure to KEEP COPIES of all forms submitted and copies of all records and calculations used in completing the forms. Air pollution control regulations require that you keep all documentation for at least FIVE YEARS at the location where pollution is being emitted. STEP 4: Make sure the Data Certification Form (or Data Certification/Fee Calculation Form for Title V sources) is signed by a company representative. Include your air quality permit number on all correspondence and applicable checks submitted with your report. Return the original, signed copy of your annual emission report, with payment for any applicable emission fees to: MCAQD One Stop Shop Emissions Inventory Intake 501 N. 44th St. Suite 200 Phoenix AZ 85008-6538 Maricopa County Emissions Inventory Unit 2 Instructions for Reporting 2008 Emissions II. REPORTING REQUIREMENTS POLLUTANTS TO BE REPORTED: Your emissions inventory must include your business’s emissions of the following air pollutants: CO NOx PM10 SOx VOC HAP&NON NHx Pb = = = = = = = = Carbon monoxide Nitrogen oxides Particulate matter less than 10 microns Sulfur oxides Volatile organic compounds * Hazardous Air Pollutant (HAP) that is also NOT a volatile organic compound (VOC)** Ammonia and ammonium compounds Lead * A volatile organic compound (VOC) is defined as any compound of carbon that participates in atmospheric photochemical reactions. This definition excludes: carbon monoxide, carbon dioxide, acetone, carbonic acid, metallic carbides or carbonates, and ammonium carbonate, as well as certain other organic compounds. (See Maricopa County Air Pollution Control Rule 100, Sections 200.69 and 200.110 for a full definition.) EPA has re-designated the chemical t-butyl acetate (CAS Number 540-88-5) as a VOC for record-keeping requirements and emissions reporting, but not for emission limitations or content requirements. County Rule 100, Section 200.69b states: “The following compound(s) are VOC for purposes of all recordkeeping, emissions reporting, photochemical dispersion modeling and inventory requirements which apply to VOC and shall be uniquely identified in emission reports, but are not VOC for purposes of VOC emissions limitations or VOC content requirements: t-butyl acetate (540-88-5).” Therefore, if your facility uses t-butyl acetate, it is necessary to report t-butyl acetate as a separate material on the evaporative process form, not as part of a grouped material (e.g., solvents, thinners, activators, etc.). T-butyl acetate will continue to be identified as a VOC on your emission report and count towards any applicable emission fees. ** HAP&NON: Usage of certain materials that are: (1) a Hazardous Air Pollutant (HAP) and (2) not also a VOC (that is, not also an ozone precursor) should also be reported if: (a) your site is subject to a Federal MACT (Maximum Achievable Control Technology) standard or (b) your air quality permit contains specific quantitative limits for HAP emissions. The most common materials categorized as “HAP&NON” include:  methylene chloride (dichloromethane)  perchloroethylene  111-trichloroethane (111-TCA or methyl chloroform)  hydrochloric acid  hydrofluoric acid NOTE: HAPs that are also considered volatile organic compounds are reported as VOC. Maricopa County Emissions Inventory Unit 3 Instructions for Reporting 2008 Emissions EMISSION CALCULATION METHOD HIERARCHY: When preparing emission information for your report, the most accurate method for calculating actual emissions must be used. The hierarchy listed below outlines the preferred methods for calculating emission estimates (taken from County Rule 280, Section 305.1). (1) Whenever available, emissions estimates should be calculated from continuous emissions monitors certified under 40 CFR Part 75, Subpart C, or data quality assured pursuant to Appendix F of 40 CFR, Part 60. (2) When sufficient data obtained using the methods described in paragraph 1 is not available, emissions estimates should be calculated from source performance tests conducted pursuant to Rule 270 in Maricopa County’s Air Pollution Control Rules and Regulations. (3) When sufficient data obtained using the methods described in paragraphs 1 or 2 is not available, emissions estimates should be calculated from material balance using engineering knowledge of the process. (4) When sufficient data obtained using the methods described in paragraphs 1 through 3 is not available, emissions estimates shall be calculated using emissions factors from EPA Publication No. AP-42 "Compilation of Air Pollutant Emission Factors," Volume I: Stationary Point and Area Sources. (5) When sufficient data obtained using the methods described in paragraphs 1 through 4 is not available, emissions estimates should be calculated by equivalent methods supported by back-up documentation that will substantiate the chosen method. Maricopa County Emissions Inventory Unit 4 Instructions for Reporting 2008 Emissions III. CONFIDENTIALITY OF DATA SUBMITTED Information submitted in your annual emissions reports must be made available to the public unless it meets certain criteria of Arizona State Statutes and Maricopa County Rules. Applicable excerpts concerning confidentiality of data are reproduced below. ARS § 49-487 D. ...the following information shall be available to the public:… 2. The chemical constituents, concentrations and amounts of any emission of any air contaminant. ... MARICOPA COUNTY AIR POLLUTION CONTROL RULES AND REGULATIONS, Rule 100: § 200.107 TRADE SECRETS - Information to which all of the following apply: a. A person has taken reasonable measures to protect from disclosure and the person intends to continue to take such measures. b. The information is not, and has not been, reasonably obtainable without the person’s consent by other persons, other than governmental bodies, by use of legitimate means, other than discovery based on a showing of special need in a judicial or quasi-judicial proceeding. c. No statute, including ARS §49-487, specifically requires disclosure of the information to the public. d. The person has satisfactorily shown that disclosure of the information is likely to cause substantial harm to the business’s competitive position. § 402 CONFIDENTIALITY OF INFORMATION: 402.2 Any records, reports or information obtained from any person under these rules shall be available to the public ... unless a person: a. Precisely identifies the information in the permit(s), records, or reports which is considered confidential. b. Provides sufficient supporting information to allow the Control Officer to evaluate whether such information satisfies the requirements related to trade secrets as defined in Section 200.107 of this rule. For emissions inventory information to be deemed confidential, the following steps must be followed:  Specific data which you request be held confidential must be identified by marking an “X” in the corresponding gray confidentiality box(es) on the relevant report forms.  Provide a written explanation which gives factual information satisfactorily describing why releasing this information could cause substantial harm to the business’s competitive position.  Use the gray-shaded boxes on the reporting forms to indicate which data are to be held confidential. Do NOT stamp “Confidential”, highlight data, or otherwise mark the page. No data can be held confidential without proper justification. Maricopa County Emissions Inventory Unit 5 Instructions for Reporting 2008 Emissions IV. HELPFUL HINTS AND INFORMATION Be sure to verify all preprinted information on forms. If any information is incorrect or blank, please provide correct information. Making a change on the Business Form will NOT transfer the permit ownership or location. You must contact the Department's One Stop Shop at (602) 506-6464 to accomplish this. WHAT IS A PROCESS? A process is a business activity at your location that emits one or more of the pollutants listed on page 3, and has only one material type as input and one operating schedule. For each applicable process at your business, you must assign a unique Process ID number to differentiate each process. PROCESSES AND MATERIALS THAT DO NOT HAVE TO BE REPORTED:  Welding.  Acetone usage.  Fuel use for forklifts or other vehicles. (NOTE: Fuel use in non-vehicle engines is reportable.)  Soil remediation activities. (Note: Other periodic reporting requirements may exist; consult your permit.)  Storage emissions from fuels or organic chemicals in any tank with a capacity of 250 gallons or less.  Storage emissions of diesel and Jet A fuel in underground tanks of any size.  Storage emissions of diesel and Jet A fuel in aboveground tanks, with throughput < 4,000,000 gal/yr.  Routine pesticide usage, housekeeping cleaners, and routine maintenance painting at your facility. Please group all similar equipment and materials together before applying the following limitations:  Internal combustion engines (e.g., emergency generators) or external combustion equipment (e.g., boilers and heaters) that operated less than 100 hrs. and burned less than 200 gals. diesel or gas, or less than 100,000 cubic feet of natural gas.  Materials with usage of less than 15 gallons or 100 pounds per year. GROUPING MATERIALS AND/OR EQUIPMENT UNDER ONE PROCESS ID: You can group together under one process ID:  All internal combustion engines less than 600 hp if they burn the same fuel and have similar operating schedules.  All external combustion equipment (boilers, heaters) with a capacity of less than 10,000,000 Btu per hour if they burn the same fuel and have similar operating schedules.  All similar evaporative materials with similar emission factors that have similar operating schedules and process descriptions. For example, group low-VOC red paint, green paint and white paint together as one material: “Paint: Low-VOC.” Do not group dissimilar materials together, such as thinners and paints. Attach documentation (see example, p. 20) showing how the grouped emission factor was determined.  All underground tanks with the same fuel and same type of vapor recovery system. ASSIGNING IDENTIFICATION NUMBERS (IDs): Unique IDs are required for the following report elements: Stacks, Control Devices and Processes. For processes, that means a process ID number may be used only once on each General Process form and for each material reported on the Evaporative Process Forms. These numbers are usually assigned by the person who prepares the original report. If you are adding a new item to a preprinted report, assign a number not already in use. Once an ID number is assigned, continue Maricopa County Emissions Inventory Unit 6 Instructions for Reporting 2008 Emissions using the same number for that item each year. If that item is no longer reportable, mark it with ‘DELETE’ and return the preprinted form with a brief explanation. Do not use that ID number again. INDUSTRY-SPECIFIC INSTRUCTIONS: Additional help sheets, detailed examples, and special instructions are available for a number of specific processes or industries listed below. To get copies of any of these documents, please visit our web site at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx or call (602) 506-6790.      Bakeries Concrete Batch Plants Fuel Storage and Handling Incinerators and Crematories Lg. Aboveground Storage Tanks      Natural Gas Boilers/Heaters Polyester Resin Printing Plants Roofing Asphalt Sand and Gravel Plants     Using EPA's TANKS 4.09d Program Vehicle Refinishing Vehicle Travel on Unpaved Roads Woodworking COMMONLY USED CONVERSION FACTORS: 1 gram/liter = 0.00834 lbs/gal 1 foot = 0.0001894 mile 1 liter = 0.2642 gallon (US) 1 square foot = 0.000022957 acre 1 therm = 0.0000952 MMCF 1 pound = 0.0005 ton NOTE: MM = 1,000,000 Example: MMCF = 1,000,000 cubic feet M = 1,000 Example: MGAL = 1,000 gallons ADDITIONAL RESOURCES AND ASSISTANCE: The Maricopa County Emissions Inventory web site at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx contains additional reference materials, such as:  blank copies of most emissions reporting forms.  an updated list of emission factors for a large number of industrial processes, including SCC codes.  a list of Tier Codes for industrial processes.  detailed help sheets for a number of specific industries or processes. To receive any of the above materials by fax or mail, or for additional information or assistance in how to calculate and report your emissions, please call us at (602) 506-6790. Maricopa County Emissions Inventory Unit 7 Instructions for Reporting 2008 Emissions V. INSTRUCTIONS AND EXAMPLES FOR COMPLETING EMISSIONS REPORTING FORMS Business Form Instructions Verify all preprinted information, and make corrections where necessary. When making corrections, strike out the preprinted data and write in corrections beside it. Please make all changes readily noticeable. NOTE: Indicating a change in ownership or business location on the Business Form will not serve to transfer the permit ownership or location. You must contact the MCAQD One Stop Shop at (602) 506-6464 to accomplish this. Data fields: 6 Number of employees: This should be the annual average number of full-time equivalent (FTE) employee positions at this business location. 9 NAICS Code: This 5- or 6-digit North American Industrial Classification System (NAICS) code has been introduced to replace the 4-digit Standard Industrial Classification (SIC) codes. Please list the primary and secondary NAICS codes for your business, if known. (Consult our website, at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx, for a link to a full list of NAICS codes.) 10 Preparer of the Inventory (primary contact for technical questions concerning this report): This should be the person who knows the most about the data in the report. If this person has an e-mail address used for business purposes, please provide it. Maricopa County Emissions Inventory Unit 8 Instructions for Reporting 2008 Emissions Stack Form Instructions A “stack” is defined as a stationary stack, pipe, vent or opening through which a significant percentage of emissions (from one or more processes) are released into the atmosphere (with or without a control device). NOTE: Stack information is required only if your business location annually emits over 10 tons of any one individual pollutant. If so, you must complete a Stack Form for:  each stack connected to a control device.  any stack that discharges annually more than 5 tons of combined pollutant emissions (such as a paint booth exhaust). EXAMPLE Stack Form Information: 1 2 Stack ID Stack Type Code* 3 1 W 30 ft 2 V 14 ft 4 5a OR 5b 6a OR 6b & 6c 7 Stack Exit Gas Velocity Flow Rate Diameter Length / Width Height** Temperature feet/sec acfm inside inch inside inch * Stack Type Codes: 90 200 o F o F Stack Name/Description. Include lat/long coordinates of stack (in decimal degrees) 20,000 36 paint booth Lat: N33.5276 19,186 40 thermal oxidizer, Bldg. 2 Long: W112.2626 Lat:N33.5259 Long:W112.2611 V = Vertical unobstructed D = Downward unobstructed W = Obstructed vertical (e.g. weather cap) H = Horizontal unobstructed G = Gooseneck ** Stack height is calculated relative to the surrounding terrain. For instance, the stack height of a 10-foot stack on top of a 20-foot tall building is 30 feet. Data fields: 1 Stack ID: (See “Assigning Identification Numbers” on page 6.) A number (up to three digits, numeric only) which identifies a specific stack. It is suggested you start with 1, then 2, etc. 4 Exit Gas Temperature: Should represent average operating conditions, in degrees Fahrenheit. DO NOT report “ambient”. 5a Exit Gas Velocity: OR 5b Gas Flow Rate: Provide EITHER the exit velocity (in feet per second) OR the flow rate of gas (in actual cubic feet per minute) exiting the stack during normal operations. Preprinted information provides both. 6a Inside Stack Diameter: For round stacks, provide Inside Stack Diameter in inches. OR 6b & 6c Inside Stack Length and Width: For square or rectangular stacks, provide inside Length and inside Width in inches. 7 Stack Name/Description and Lat/Long Coordinates: Provide a brief text description of the stack along with the latitude and longitude coordinates of the stack (in decimal degrees). Maricopa County Emissions Inventory Unit 9 Instructions for Reporting 2008 Emissions Control Device Form Instructions EXAMPLE Control Device Form Information 1 2 3 4 Control ID Installation/ Reconstruction* Date Size or Rated Capacity** Control Type Code 5 Control Device Name/Description 1 05/09/98 25,000.0 cfm 021 Thermal oxidizer 4 03/10/97 cfm 153 Watering with water trucks 6 Stack ID 2 Data fields: 1 Control ID: (See “Assigning Identification Numbers” on page 6.) A unique number (up to three digits) that you assign to identify a specific control device. 2 Installation/Reconstruction Date: The completion date (given in mm/dd/yy format) of installation or the most recent reconstruction of the identified control device. This is not a date on which routine repair or maintenance was done. “Reconstruction” means any component of the control device was replaced and the cost (fixed capital) of the new component(s) was more than half of what it would have cost to purchase or construct a new control device. 3 Size or Rated Capacity: Report the air or water flow rate in cubic feet per minute. Some devices (e.g., water trucks for dust control) will not include a value in this field. 4 Control Type Code: A 3-digit code designating the type of control device. A complete list of all EPA control device codes can be found on the Web at: http://www.maricopa.gov/aq/divisions/ planning_analysis/emissions inventory/Default.aspx or call (602) 506-6790 for assistance. 6 Stack ID: Not all businesses require a Stack ID. This is required if the Stack Form is used for your site (see page 9) and the control device is vented through that identified stack. This is the ID number shown in column 1 of the Stack Form. The Stack ID can be entered on this form after the Stack Form has been filled out. Maricopa County Emissions Inventory Unit 10 Instructions for Reporting 2008 Emissions General Process Form Instructions The General Process Form is used to record data on all emissions-producing processes except evaporative processes. A “general process” is normally characterized by the burning or handling of a material. One form reports all the pollutants for one process. For example, several pollutants are produced by burning fuel, and PM10 is emitted by processing rock products, processing materials such as wood or cotton, and driving on unpaved areas. Data fields: (See sample forms on pages 13 and 14.) 1 Process ID: A number (up to three digits) that is preprinted or you assign. (See “Assigning Identification Numbers” on page 6.) This Process ID number can not be used for any other process at this location. 2 Process Type/Description: Brief details on the type of activity that is occurring. 3 Stack ID(s): The stack ID number(s) shown in column 1 of the Stack Form that identify the stack(s) which vent pollution created by this process. Not all businesses are required to report stacks. This is only required if the Stack Form is required for your site (see page 9) and the process has a stack. 4 Process Tier Code and 5 SCC Code: 6 If these codes are not preprinted on your form, please consult the section “Other Resources” on our web site, or call (602) 506-6790. Seasonal Throughput Percent: Enter the percent of total annual operating time that occurred per season, rounded to the nearest percent. For example, “Dec-Feb 30% ” means 30% of total annual activity occurred in January, February and December 2008. The total for all four seasons must equal 100%. 7 Normal Operating Schedule and 8 Typical Hours of Operation: 9 These reflect the normal daily, weekly, and annual operating parameters of this process during 2008. Emissions Based on: Provide the name of the material used, fuel used, product produced, or whatever was measured for the purpose of calculating emissions, such as “natural gas”, “hours of operation,” “vehicle miles traveled,” or “acres.” 10 Used, Produced or Existing: Indicate whether calculated emissions are based on a material type or fuel used (an input, such as “paint” or “natural gas”), or an output (such as “sawdust produced” or “finished product”). Use “Existing” if the parameter reported on line 9 is not directly used or produced in the process (such as “vehicle miles traveled” or “acres”). 11 Annual Amount: The annual amount (a number) of material that was used, fuel combusted, product produced, hours of operation, vehicle miles traveled, or acres. 12 Fuel Sulfur Content (in percent): For processes that involve the combustion of oil or diesel fuels, report the sulfur content of the fuel as a decimal value. Example: 0.05 % (= 500 ppm) 13 Unit of Measure: Units of the material used, fuel used or product produced shown on line 9. For example: gallons, pounds, tons, therms, acres, vehicle miles traveled, units produced. 14 Unit Conversion Factor: You must provide this if you use an emission factor with an emission factor unit (see item 17 below) that is not the same as the unit of measure (from line 13). This is the standard number you would multiply your amount (line 11) by to convert it to the units of the emission factor. See page 7 for a list of commonly used conversion factors. Maricopa County Emissions Inventory Unit 11 Instructions for Reporting 2008 Emissions General Process Form Instructions (continued) 15 Pollutant: See page 3 for a list of pollutants that need to be reported. 16 Emission Factor (EF): The number to be multiplied by the annual amount (line 11) to determine how much of the pollutant was emitted. If you calculate your own emission factor or change the preprinted emission factor, you must provide details of your calculations in an attachment. 17 Emission Factor (EF) Units: Enter the appropriate Emission Factor Units in pounds (lb) per unit; e.g., lb/ton, lb/MMCF, lb/gal. 18 Controlled Emission Factor (EF)? YES or NO: Indicate “YES” if: 1) you have your own emission factor from testing and included the control device efficiency within the factor, or 2) the emission factor used is clearly identified as a controlled emission factor. A “YES” response requires the use of Formula A (see #25 below). Indicate “NO” if: 1) there is no emission control device, or 2) the emission factor represents emission rates before controls. A “NO” response requires the use of Formula B (see #25 below). 19 Calculation Method: Enter the number code (listed at the bottom of the General Process Form) which best describes the method you used to obtain this emission factor. Code 5, “AP-42/FIRE Method or Emission Factor” means that the factor comes from EPA documents or software. NOTE: If you have continuous emissions monitors (CEM) data or conducted a source test that was required and approved by the County for a specific process or piece of equipment, you must use the emission data from the CEM or the test results. Report “1” in this column for CEM data or “4” for performance test data. 20 through 24: Leave blank if there is no control device. 20 Capture % Efficiency: The percent of the pollutant that is captured and sent to the primary control device in this process. Be sure to list capture efficiency separately for each pollutant affected. 21 Primary Control Device ID: If this pollutant is being controlled in this process, enter the Control Device ID number which represents the first control device affecting the pollutant. 22 Secondary Control Device ID: If this pollutant is being controlled sequentially by 2 devices, enter the Control Device ID number which represents the second control device; otherwise leave this field blank. 23 Control Device(s) % Efficiency: Enter the total control efficiency of the control device(s). Be sure to list control device efficiency separately for each pollutant affected. If you report control device efficiency, you must also show capture efficiency in column 20. 24 Efficiency Reference Code: Enter the code (1 through 6) that best describes how you determined the control device efficiency. A list of possible codes is included at the bottom of the form. 25 Estimated Actual Emissions (in pounds/year): You may round the calculated emissions values to the nearest pound. Calculate as follows: A. Emissions with no controls or controls are reflected in the emission factor: Column 25 = line 11  line 14  column 16 B. Emissions after control: Column 25 = line 11  line 14  column 16  (1 – [column 20  column 23]) Use the decimal equivalent for columns 20 and 23. Example: 96.123% = 0.96123 Maricopa County Emissions Inventory Unit 12 Instructions for Reporting 2008 Emissions General Process Form 2008 Permit number(s) EXAMPLE: Internal Combustion V99999 Place an X in any gray cell to mark data requested to be held confidential. See page 5 for requirements for information to be deemed confidential. 1- Process ID 80 2- Process Type/Description: 3 ENGINES FOR CRUSHING (EACH LESS THAN 600 HP) 3- Stack ID(s) (only if required on Stack Form) ________ 020599 4- Process TIER Code: 5- SCC Code _______ 20200102 ________ IND:DIESEL-RECIPROCATING (8 digit number) 25 Dec-Feb 7- Normal Operating Schedule: Hours/Day (military time) % 8 Days/Week 0700 Start 25 Mar-May % 5 Jun-Aug Hours/Year  Used (input) 11- Annual Amount: or Produced (output) or CO NOx PM-10 SOx VOC Emission Factor (EF) Information 16 17 18 Emission Factor (EF) (number) 130 604 42.5 39.7 49.3 Emission Factor Unit (lb per) M M M M M 19 20 Controlled EF? Yes or No Calculation Method Code* Capture % Efficiency N N N N N 5 5 5 5 5 GALS GALS GALS GALS GALS * Calculation Method Codes: 1 = Continuous Emissions Monitoring Measurements 2 = Best Guess / Engineering Judgment 3 = Material Balance 4 = Source Test Measurements (Stack Test) 5 = AP-42 / FIRE Method or Emission Factor Maricopa County Emissions Inventory Unit 25 Sep-Nov Weeks/Year % 52 x DIESEL __0.05_______% GALLONS 14- Unit Conversion Factor (if needed to convert Unit of Measure to correlate with emission factor units) 15 2080 12- Fuel Sulfur Content (in percent) 13- Unit of Measure: (for example: tons, gallons, million cu ft, acres, units produced, etc.) Pollutant % Existing (e.g. VMT, acres) 16,250 (a number) 25 1530 End 9- Emissions based on (name of material or other parameter, e.g. “rock”, “diesel”, “vehicle miles traveled”) 10- ________ FUEL COMB. INDUSTRIAL: INTERNAL COMBUSTION 6- Seasonal Throughput Percent: 8- Typical Hours of Operation: ________ 0.001 Control Device Information 21 22 23 Primary Control Device ID Secondary Control Device ID Control Device(s) % Efficiency 24 25 Efficiency Reference Code** Estimated Actual Emissions 2,113 9,815 691 645 801 6 = State or Local Agency Emission Factor 7 = Manufacturer Specifications 8 = Site-Specific Emission Factor 9 = Vendor Emission Factor 10 = Trade Group Emission Factor 13 lbs lbs lbs lbs lbs ** Control Efficiency Reference Codes: 1 = Tested efficiency / EPA reference method 2 = Tested efficiency / other source test method 3 = Design value from manufacturer 4 = Best guess / engineering estimate 5 = Calculated based on material balance 6 = Estimated, based on a published value Instructions for Reporting 2008 Emissions General Process Form 2008 Permit number(s) EXAMPLE: Unpaved Road Travel V99999 Place an X in any gray cell to mark data requested to be held confidential. See page 5 for requirements for information to be deemed confidential. 1- Process ID 28 2- Process Type/Description: UNPAVED ROAD TRAVEL: HEAVY-DUTY TRUCKS @ 15 MPH _______ 3- Stack ID(s) (only if required on Stack Form) 4- Process TIER Code: 5- SCC Code ________ 140799 30502504 6- Seasonal Throughput Percent: 8- Typical Hours of Operation: ________ SAND/GRAVEL: HAULING 25 Dec-Feb 8 Hours/Day (military time) % % Used (input) 11- Annual Amount: or Produced (output) Hours/Year Sep-Nov Weeks/Year 25 % 52 x VEHICLE MILES TRAVELED (VMT)  Existing (e.g. VMT, acres) 7,500 (a number) 2080 % 1530 End or 25 Jun-Aug 5 Days/Week 0700 Start 25 Mar-May 9- Emissions based on (name of material or other parameter, e.g. “rock”, “diesel”, “vehicle miles traveled”) 10- ________ MISCELLANEOUS: FUGITIVE DUST (8 digit number) 7- Normal Operating Schedule: ________ 12- Fuel Sulfur Content (in percent) ______________% VMT 13- Unit of Measure: (for example: tons, gallons, million cu ft, acres, units produced, etc.) 14- Unit Conversion Factor (if needed to convert Unit of Measure to correlate with emission factor units) 15 Pollutant PM-10 Emission Factor (EF) Information 16 17 18 Emission Factor (EF) (number) 3.2 Emission Factor Unit (lb per) Control Device Information 21 22 23 19 20 Controlled EF? Yes or No Calculation Method Code* Capture % Efficiency Primary Control Device ID N 6 100 4 VMT Secondary Control Device ID 24 25 Control Device(s) % Efficiency Efficiency Reference Code** Estimated Actual Emissions 70 6 7200 lbs lbs lbs lbs lbs lbs NOTE: Emissions in col. 25 are calculated as follows: * Calculation Method Codes: 1 = Continuous Emissions Monitoring Measurements 2 = Best Guess / Engineering Judgment 3 = Material Balance 4 = Source Test Measurements (Stack Test) 5 = AP-42 / FIRE Method or Emission Factor Maricopa County Emissions Inventory Unit (line 11  col. 16)  (1 – [col. 20  col. 23]) 6 = State or Local Agency Emission Factor 7 = Manufacturer Specifications 8 = Site-Specific Emission Factor 9 = Vendor Emission Factor 10 = Trade Group Emission Factor 14 ** Control Efficiency Reference Codes 1 = Tested efficiency / EPA reference method 2 = Tested efficiency / other source test method 3 = Design value from manufacturer 4 = Best guess / engineering estimate 5 = Calculated based on material balance 6 = Estimated, based on a published value Instructions for Reporting 2008 Emissions Evaporative Process Form Instructions The Evaporative Process Form is used to report all emissions produced by evaporation. Examples include: cleaning with solvents, painting and other coatings, printing, using resin, evaporation of fuels from storage tanks, ammonia use, etc. All other processes should be shown on the General Process Form. One Evaporative Process Form may be used to report numerous materials, with each material given a separate process ID number, as long as the information on lines 1–5 apply to all items on that form. Use a separate form for each group of materials that has a different Process Type/Description (shown on line 1), different Tier Code (line 2) or different operating schedule (lines 3, 4, or 5). Data fields: (See sample forms on pages 17 and 18.) 1 Process Type/Description: Brief details of the activity in which the listed materials were used. 2 Process Tier Code: If this 6-digit code is not preprinted on your form, please refer to the Tier Code list at: http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx or call (602) 506-6790. 3 Seasonal Throughput Percent: Enter the percent of total annual operating time that occurred per season (rounded to the nearest percent). For example, “Dec-Feb 30% ” means 30% of the total annual activity occurred during January, February and December 2008. The total for all four seasons must equal 100%. 4 5 Normal Operating Schedule and Typical Hours of Operation: 6 Process ID: A number (up to three digits) that represents this specific material (process). Each process on one form must have the same tier code and operating schedule as that shown in the top portion of the form. This Process ID number can not be used for any other process at this business location. See page 6 of these instructions for more explanation of ID numbers and for exclusions and guidance on grouping materials. 7 Stack ID(s): The stack ID number(s) shown in column 1 of the Stack Form that identify the stack(s) which vent pollution created by this process. Not all businesses are required to report stacks. This is only required if the Stack Form is required for your site (see page 9) and the process has a stack. 8 Material Type: Provide the name of the material used in this process. Give the chemical name for pure chemicals or a name that reflects its use (paint, ink, etc.), rather than just a brand name or code number. Examples of materials include: paint, thinner, degreasing solvent (plus its common name), ink, fountain solution, ammonia, alcohol, ETO (ethylene oxide), gasoline (in a storage tank). 9 Annual Material Usage/Input: Amount of this material used during the year. In most cases, the amount purchased is suitable. Write in “lbs” or “gal” (pounds or gallons). These represent the usual number of hours, time of day and weeks per year when this process occurred during the calendar year. 10 Pollutant: The only pollutants reported on this form are VOC, HAP&NON and NHX (see definitions on page 3). When one process (or material) has more than one of these pollutants, list each pollutant on a separate line, using the same process ID number. Maricopa County Emissions Inventory Unit 15 Instructions for Reporting 2008 Emissions Evaporative Process Form (continued) 11 Emission Factor (EF): An emission factor is a number used to calculate the pounds of pollutant emitted based on the quantity of material used in a process. Emission factors can be obtained from your supplier (usually provided on a Material Safety Data Sheet or environmental data sheet), and must correspond with the material units reported in column 9. If the material unit is “gal,” then the emission factor must be in pounds of pollutant per gallon. If the material unit is “lb,” then the emission factor must be in pounds of pollutant per pound of material. Verify (and correct, where necessary) all preprinted emission factors, as the composition of materials used may have changed since your last report. A “lb/gal” emission factor is almost always less than 8 and never greater than 14. A “lb/lb” emission factor is never larger than 1.0. 12 Pounds of pollutant sent off-site: Required only if you wish to take credit for reduced emissions because waste of this material is sent off-site for recycling or disposal. Only waste generated during the report year may be claimed. The Off-Site Recycling/Disposal Form must be completed if you wish to claim a credit. The number of pounds reported in column 12 must equal the number of pounds reported on the Off-Site Recycling/Disposal Form(s) for the same Process ID number. 13 and 14: Leave these fields blank if there is no control device present. 13 Capture % Efficiency: The percent of the pollutant from this process that is captured and sent to the control device. 14 Control ID: If this pollutant is being controlled in this process, enter the Control Device ID number from column 1 of the Control Device Form. Control % Efficiency: Enter the percent of this pollutant that is controlled by this control device. Code: Select the Control Efficiency Reference Code from the list at the bottom of the form. 15 Estimated Emissions (lbs/yr): Estimated pounds of the pollutant emitted during the year, after off-site recycling/disposal and controls if applicable. Credit will not be given for off-site recycling/disposal unless it is shown on the Off-Site Recycling/Disposal Form. Round to the nearest pound. If the answer is 0, give a decimal answer to the first significant digit. Column 15 is calculated as follows: Emissions without off-site recycling/disposal or controls: Column 15 = column 9  column 11 Emissions with off-site recycling/disposal: Column 15 = (column 9  column 11) – column 12 Emissions with off-site recycling/disposal and controls: Column 15 = ([column 9  column 11] – column 12)  (1 – [column 13  column 14]) Use the decimal equivalent for columns 13 and 14. Example: 96.123% = 0.96123 Maricopa County Emissions Inventory Unit 16 Instructions for Reporting 2008 Emissions EXAMPLE: Coating and Painting Evaporative Process Form 2008 Permit number(s) V99999 Place an X in any gray cell to mark data requested to be held confidential. See page 5 for requirements for information to be deemed confidential. 1- Process Type/Description: 2- Process TIER Code: Coating metal parts 080415 3- Seasonal Throughput Percent: 4- Normal Operating Schedule: 5- Typical Hours of Operation SOLVENT USE: SURFACE COATING - MISC METAL PARTS Dec-Feb Hours/Day 25 % 8 Days/Week (military time) 6 7 8 Process ID Stack ID(s) Material Type 800 1 801 1 802 1 803 1 804 1 Start 9 % 25 5 Hours/Year End 0800 Jun-Aug 2080 25 % Sep-Nov 25 % Weeks/Year 52__ 1700 10 11 Emission Factor EF Units (lbs per) 12 13 Pounds of pollutant* sent off site Capture Efficiency % 14 Control ID 15 Control Efficiency % Control Efficiency Code** Estimated Emissions (lbs/yr) lb or gal VOC, HAP&NON or NHx 95 gl VOC 4.7 gal % % 447 120 gl VOC 7.1 gal % % 852 940 gl VOC 4.2 gal % % 3,948 707 gl VOC 7.0 gal % % 4,949 20,200 lb VOC 0.001 lb % % % % Annual Usage Input Lacquer 6455-06 lacq thinner Paint red 4039-03 paint thinner powder paint 8730-11 Mar-May 20 Note: Do NOT change preprinted Process ID numbers. See page 6 of these instructions for information on how to delete materials that are no longer used, or to assign Process ID numbers for new materials. * If you have off-site recycling/disposal of any of the materials listed above, you must complete an Off-site Recycling/Disposal Form to receive credit for reduced emissions. NOTE: Emissions in col. 15 are calculated as follows: ** Control Efficiency Reference Codes 1 = Tested efficiency / EPA reference method 4 = Best guess / engineering estimate Maricopa County Emissions Inventory Unit ([col. 9  col. 11] – col. 12)  (1 – [col. 13  col. 14]) 2 = Tested efficiency / other source test method 5 = Calculated based on material balance 17 3 = Design value from manufacturer 6 = Estimated, based on a published value. Instructions for Reporting 2008 Emissions EXAMPLE: Cleaning solvent (with recycling) Evaporative Process Form 2008 Permit number(s) V99999 Place an X in any gray cell to mark data requested to be held confidential. See page 5 for requirements for information to be deemed confidential. 1- Process Type/Description: 2- Process TIER Code: CLEANING METAL PARTS 080103 3- Seasonal Throughput Percent: Dec-Feb 4- Normal Operating Schedule: 5- Typical Hours of Operation SOLVENT USE: DEGREASING - COLD CLEANING Hours/Day 25 % 8 Days/Week (military time) 6 7 8 Process ID Stack ID(s) Material Type 3 2 Mar-May Start 9 % 25 Hours/Year 5 End 1300 Jun-Aug 25 % 2080 Sep-Nov % 25 Weeks/Year 52__ 1700 10 11 Emission Factor EF Units (lbs per) 12 13 Pounds of pollutant* sent off site Capture Efficiency % 14 Control ID 15 Control Efficienc y % Control Efficiency Code** Estimated Emissions (lbs/yr) Annual Usage Input lb or gal VOC, HAP&NON or NHx SANITIZER 716 lb VOC 1.0 lb 6 GUN CLEANER 180 gl VOC 7.2 gl 569 % % 727 7 XYZ STRIPPER 1300 gl VOC 3.3 gl 1,884 % % 2,406 8 CLEANING SOLVENTS MEGASOLVE 358 gl VOC 6.4 gl 1,006 % % 1,285 2258 gl VOC 6.8 gl 6,741 % % 8,613 % % 9 95 % 1 80 % 3 172 Note: Do NOT change preprinted Process ID numbers. See page 6 of these instructions for information on how to delete materials that are no longer used, or to assign Process ID numbers for new materials. * If you have off-site recycling/disposal of any of the materials listed above, you must complete an Off-site Recycling/Disposal Form to receive credit for reduced emissions. NOTE: This example shows the case where 2,400 of the original 4,096 gallons of materials #6 through 9 were captured for off-site recycling, and the pollutant content of the waste material was estimated to be 75% of the original. The pounds of pollutant sent off-site shown in column 12 is calculated on the example Off-Site Recycling/Disposal Form on the next page. Maricopa County Emissions Inventory Unit 18 Instructions for Reporting 2008 Emissions EXAMPLE Off-Site Recycling/Disposal Form 2008 Permit number(s) V99999 NOTE: If you need blank copies of this form, call the Emissions Inventory Unit at (602) 506-6790 or consult our web page at http://www.maricopa.gov/aq/divisions/planning_analysis/emissions_inventory/Default.aspx Provide one off-site recycling/disposal form for each waste stream at your business location. A waste stream is the waste from one or more processes mixed together to make one waste product before it is taken off site for recycling, disposal or combustion. 1) Assign a unique two-digit ID number to identify the waste stream that will be described below. 01 (Start with ID# 01 for first waste stream. Make copies of a blank Off-Site Recycling/Disposal form and use 02 for second, etc.) Check one: pounds gallons 2,400 2) What was the quantity of this waste stream in 2008? Indicate whether this quantity is reported in pounds or gallons. Keep waste disposal company manifests as proof that this amount of waste was taken off-site. 3) What was the average pollutant content of the waste stream? NOTE: Report in the same units (pounds or gallons) as used in line 2. VOC 4.25 lbs/unit HAP&NON lbs/ unit NHx lbs/ unit NOTE: Waste normally has less pollutant content than the new product. Some of the pollutant evaporates during the use of the product, and there is usually dirt, water or other contaminants in the waste stream. The estimated pollutant content of the waste is usually between 50% and 95% of the new product. This example estimates an average VOC content (on line 3) to be 75% of the original VOC content of 5.67 lbs/gal., to account for evaporation and contaminants. See page 20 to calculate a weighted average. 4) Calculate the total annual pollutant content of the waste in this waste stream. (volume of waste, from Line 2)  (pollutant content, from Line 3) = Total pollutants in waste stream, in lbs/yr. VOC 10,200 lbs/yr HAP&NON lbs/yr NHx lbs/yr 5) List the process ID numbers of the processes contributing to this waste stream. Also estimate the pounds of pollutant that each process contributed to this waste stream. NOTE: In this example, the amount each process material contributed to total pollutants in the waste stream (Line 4) is based on the percentage, by weight, of each material that contributed to the waste stream (e.g., Process ID #6 contributed 5.6%, therefore 5.6% × 10,200 lbs/yr = 569 lbs. See example on page 20). NOTE: Column totals in the table below must equal the total for each pollutant type reported on line 4. The quantities you report below for each pollutant and process must also be reported in column 12 on the Evaporative Process Form. Process ID 6 Contributed about 7 Contributed about 8 Contributed about 9 Contributed about Annual VOC (lbs) 569 1,884 1,006 6,741 Maricopa County Emissions Inventory Unit Annual HAP&NON (lbs) lbs lbs lbs lbs 19 Annual NHx (lbs) lbs lbs lbs lbs lbs lbs lbs lbs Instructions for Reporting 2008 Emissions EXAMPLE: Documentation of Emission Factor Calculations Identify the process ID number(s) and pollutant(s). Show calculations made to obtain the emission factors used for the process(es). Include references to data sources used, including the document name, date published, page numbers, etc. Emission Factor Calculation Process ID Permit number 201 V99999 Emission factors derived from source test performed 12/2/00 by XYZ Engineering Company (copy of summary tables also attached). Outlet (after controls): CO = 0.43 lb/hr  1 hr/60 min  1 min/77.9 cu. ft  1,000,000 cu. ft/MMCF = 92.0 lb/MMCF = 0.09 lb/hr  1 hr/60 min  1 min/77.9 cu. ft  1,000,000 cu. ft/MMCF = 19.3 lb/MMCF NOx Weighted average sample calculation NOTE: The example below shows how the weighted average of the materials going into the waste stream is calculated. A weighted-average emission factor has been calculated by listing usage amounts and emission factors for each material, summing each column, and then dividing the total emissions by the total gallons used. In this example: 23,231 lbs  4,096 gal = 5.67 lb/gal average VOC content. This emission factor is then used to calculate the average pollutant content in the Offsite Recycling / Disposal Form example. This process can also be used to find the weighted average emission factor for similar materials if you are reporting them together as a single line item on the Evaporative Process form. Refer to the explanation of “grouping” on page 6. Process ID # 6 7 8 9 Material Type gun cleaner xyz stripper cleaning solvent MEGASOLVE Totals: Average VOC content: Maricopa County Emissions Inventory Unit 2008 Usage Units 180 1,300 358 2,258 4,096 gal gal gal gal gal VOC (lbs/unit) 7.2 3.3 6.4 6.8 23,231 lbs. 4,096 gals 20 VOC Emissions (= Usage  VOC content) 1,296 lbs. 4,290 lbs. 2,291 lbs. 15,354 lbs. 23,231 lbs. = Percent contributed to waste stream 5.6 % 18.5 9.9 66.1 100.0 % % % % 5.67 lb/gal Instructions for Reporting 2008 Emissions EXAMPLE (for all sources except Title V sources) Data Certification Form 2008 Permit number 999999 For EACH pollutant listed, total up all emissions recorded on your General Process and Evaporative Process Forms. Enter these numbers in column 1, “Totals from Process Forms.” Report any emissions from accidental releases in column 2. Add the figures in each row across, and enter the result in column 3, “Total Emissions”. NOTE: “Accidental Releases” reported in column 2 should include all excess emissions reported to the Department under Rule 140, Section 500. (1) Totals from Process Forms Summary of 2008 Annual Emissions: 2,113 0 0 0 24,220 9,815 645 7,891 CO NHx Lead HAP&NON VOC NOx SOx PM10 (2) + Accidental Releases 0 0 0 0 0 0 0 0 (3) = TOTAL 2008 Emissions 2,113 0 0 0 24,220 9,815 645 7,891 NOTE: Review specific requirements for data confidentiality on page 5. We cannot hold any data confidential without the required documentation. TO COMPLETE YOUR EMISSIONS INVENTORY REPORT: - Complete the Confidentiality Statement below. Sign and date this form below where indicated. Send the original copy of your completed forms to: Maricopa County Air Quality Department, One Stop Shop, Emissions Inventory Intake, 501 N. 44th Street, Suite 200, Phoenix, AZ 85008-6538. Keep a copy of all forms for your records. CONFIDENTIALITY STATEMENT: This annual emissions report contains requests to keep some data confidential. YES NO If you check “YES”, you must submit documentation and meet certain requirements before your data can be deemed confidential. See enclosed instructions for further details. NOTE: The Data Certification form must be signed by a responsible company official. CERTIFICATION STATEMENT: I declare under penalty of perjury that the data (e.g. inputs, emission factors, controls, and annual emissions) presented herein represents the best available information and is true, accurate and complete to the best of my knowledge. ___________________________________________________________________________________________________________ Signature of owner/business officer Date of signature Telephone number ___________________________________________________________________________________________________________ Type or print full name of owner/business officer Type or print full title Maricopa County Emissions Inventory Unit 21 Instructions for Reporting 2008 Emissions How to calculate an emission fee (for Title V sources only): 1. For each pollutant listed on the “Data Certification/Fee Calculation” form, total up all emissions recorded on your General Process and Evaporative Process Forms. Enter these numbers in column 1, “Totals from Process Forms.” NOTE: While most processes that generate PM10 should be reported on line 5 of the Data Certification/Fee Calculation form, “[f]ugitive emissions of PM10 from activities other than crushing, belt transfers, screening, or stacking” (County Rule 280, § 305.2d) are NOT subject to annual emission fees. The most common occurrences of these PM10-producing activities that are NON-billable are listed below: SCC codes and description of PM10-producing processes that are NOT subject to emission fees SCC 30200814 30400737 30500120 30500121 30500134 30500135 30500141 30500143 30500203 30500212 30500213 30500290 30500303 30500608 30500708 30501710 30502007 30502011 30502504 30502507 30502760 30531090 30532007 30704002 31100199 31100299 50100401 50100402 50100403 50100404 50100405 Major Category Subcategory Facility / Process Type Process Description Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Industrial Processes Waste Disposal Waste Disposal Waste Disposal Waste Disposal Waste Disposal Feed Manufacture Steel Foundries Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Roofing Manufacture Asphalt Concrete Asphalt Concrete Asphalt Concrete Asphalt Concrete Brick Manufacture Cement Manufacturing (Dry Process) Cement Manufacturing (Wet Process) Mineral Wool Stone Quarrying - Processing Stone Quarrying - Processing Construction Sand and Gravel Construction Sand and Gravel Industrial Sand and Gravel Coal Mining, Cleaning, Material Handling Stone Quarrying - Processing Bulk Handling and Storage - Wood/Bark Construction: Building Contractors Demolitions/Special Trade Contracts Landfill Dump Landfill Dump Landfill Dump Landfill Dump Landfill Dump Storage Raw Material Silo Storage Bins: Ferric Chloride Storage Bins: Mineral Stabilizer Blown Saturant Storage Blown Coating Storage Granules Storage Mineral Dust Storage Storage Piles Heated Asphalt Storage Tanks Storage Silo Haul Roads: General Storage of Raw Materials Raw Material Piles Raw Material Piles Storage of Oils and Binders Open Storage Hauling Hauling Storage Piles Sand Handling, Transfer, & Storage Haul Roads: General Open Storage Stockpiles Other Not Classified Other Construction/Demolition Unpaved Road Traffic Fugitive Emissions Area Method Trench Method Ramp Method Food and Agriculture Secondary Metal Production Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Mineral Products Pulp and Paper & Wood Pdts. Building Construction Building Construction Solid Waste Disposal Solid Waste Disposal Solid Waste Disposal Solid Waste Disposal Solid Waste Disposal 2. Report any accidental releases in column 2. Add columns 1 and 2 together for each pollutant, and enter the sum in column 3. Sum lines 1 through 5 together, and enter the total on line 6. 3. Divide your facility's total billable emissions (on line 6) by 2000 to convert pounds into tons. Round to the nearest ton. Enter this value on line 7. Multiply this number by $38.25, and enter the result on line 8. This is your 2008 emission fee. Maricopa County Emissions Inventory Unit 22 Instructions for Reporting 2008 Emissions EXAMPLE (for Title V sources only) Data Certification/Fee Calculation Form 2008 Permit number V99999 For EACH pollutant listed, total up all emissions recorded on your General Process and Evaporative Process Forms. Enter these numbers in column 1, “Totals from Process Forms.” Report any emissions from accidental releases in column 2. Add the figures in each row across, and enter the result in column 3, “Total Emissions”. Carefully follow the instructions on lines 6 through 8 to calculate any emission fee owed. NOTE: “Accidental Releases” reported in column 2 should include all excess emissions reported to the Department under Rule 140, Section 500. (1) Totals from Process Forms Summary of 2008 Annual Emissions: 2,113 0 0 7,200 CO NHx Lead PM10 (non-billable; see page 22) (2) + Accidental Releases (3) = TOTAL 2008 Emissions 0 0 0 0 2,113 0 0 7,200 Emissions fees are based on your emissions of the following pollutants ONLY: 1 2 3 4 5 6 7 8 0 24,220 9,815 645 691 HAP&NON VOC NOx SOx PM10 (billable; see page 22) 0 0 0 0 0 0 24,220 9,815 645 691 35,371 Add “TOTAL” column from lines 1 through 5 ONLY: Divide the total on line 6 by 2000 (pounds per ton) to get tons, and round the number to the nearest ton. (Drop any decimal of .499 or less. Increase to the next whole number any decimal of .500 or more.) Enter the resulting WHOLE NUMBER here. Multiply line 7 (a WHOLE number) by $ 38.25. This is your 2008 ANNUAL EMISSION FEE. 18 $ lbs. TONS 688.50 NOTE: Review specific requirements for data confidentiality on page 5. We cannot hold any data confidential without the required documentation. TO COMPLETE YOUR EMISSIONS INVENTORY REPORT: - Include a check (made payable to Maricopa County Air Quality Department) for the amount calculated on line 8 above. Complete the Confidentiality Statement below. Sign and date this form below where indicated. Send the original copy of your completed forms, along with any emission fee due to: Maricopa County Air Quality Department, One Stop Shop, Emissions Inventory Intake, 501 N. 44th Street, Suite 200, Phoenix, AZ 85008-6538. Keep a copy of all forms for your records. CONFIDENTIALITY STATEMENT: This annual emissions report contains requests to keep some data confidential. YES NO If you check “YES”, you must submit documentation and meet certain requirements before your data can be deemed confidential. See enclosed instructions for further details. NOTE: The Data Certification form must be signed by a responsible company official. CERTIFICATION STATEMENT: I declare under penalty of perjury that the data (e.g. inputs, emission factors, controls, and annual emissions) presented herein represents the best available information and is true, accurate and complete to the best of my knowledge. ___________________________________________________________________________________________________________ Signature of owner/business officer Date of signature Telephone number ___________________________________________________________________________________________________________ Type or print full name of owner/business officer Type or print full title Maricopa County Emissions Inventory Unit 23 Instructions for Reporting 2008 Emissions This page intentionally blank. Appendix 3. Rule Effectiveness (RE) Studies Executive Summary Rule effectiveness (RE) studies are methods designed to assess the success of regulatory rules at controlling their targeted emissions. It is acknowledged that facilities and source categories subject to control techniques and devices mandated by rules do not always achieve 100% compliance with those requirements. Given this reality, the US EPA recommends the use of rule effectiveness studies to improve the quality of emission estimates presented in emission inventories. Rule effectiveness studies adjust the emissions from subject facilities and source categories to account for times of non-compliance and control device equipment failure. Of particular importance to Maricopa County are those rules that control particulate matter release and ozone formation, since parts of the county have been designated as nonattainment areas in regards to US EPA PM10 and 8-hour ozone standards. Consequently, the rule effectiveness studies presented here deal with the control of criteria pollutants PM10, PM2.5, and the precursors to ozone formation (VOC, NOx and CO). In general, rule effectiveness studies incorporate compliance history at regulated facilities and sources, along with agency programs and policies (i.e., inspection frequencies, enforcement penalties, public outreach efforts, etc.), to ascribe a percentage rate (RE rate) at which the subject rule(s) attains the intended emissions reductions. For these studies, data from inspections conducted from July 2008 through June 2009 was used to determine the rate of compliance of subject facilities and source categories with the rules. The resulting compliance rate was then combined with data on the effectiveness of Maricopa County Air Quality Department (MCAQD) programs and policies to derive a final rule effectiveness rate, which has then been used to adjust the emissions inventory estimates. Both source-specific and multi-source rule effectiveness studies were undertaken as part of this project. Source-specific studies address Rule 310 (fugitive dust from dust-generating operations), Rule 310.01 (fugitive dust from non-traditional sources of fugitive dust), Rule 316 (nonmetallic mineral processing), and agricultural activities (best management practices). For all other regulated processes that control particulates and the formation of ozone, multi-source RE rates were calculated separately for Title V and non-Title V permitted facilities. Final compliance rates and RE rates are listed in Table A3–1 below. Table A3–1. Compliance and rule effectiveness rates, by rule or source category. Rule/Source Category Compliance Rate Rule Effectiveness (RE) Rate Rule 310 87.01% 82.99% Rule 310.01 95.15% 80.87% Rule 316 35.29% 49.62% Agricultural Activities Unknown 55.33% Title V Facilities 89.14% * 90.94% Non-Title V Facilities 81.00% * 84.27% * Compliance rates for both Title V and Non-Title V facilities are based upon 2008-2009 inspection data, and reflect compliance self-monitoring recordkeeping practice, in addition to violation data. The resulting RE rates shown above have been applied to relevant point and area source inventory categories and are reflected in the emission estimates presented in applicable sections of Chapters 2 and 3. 2008 Maricopa Co. PM10 Emission Inventory A3–1 June 2010 Background The US EPA has provided a number of guidance documents that detail the use and formulation of rule effectiveness studies (US EPA, 2005; 1994; 1992). The most recent of these documents states, “First and foremost, an agency responsible for emissions inventory preparation should attempt to obtain facility specific data from as many sources as possible, and use the collected information to make a refined source or source category RE determination” (US EPA, 2005). Given this directive, MCAQD developed a rule effectiveness study methodology that utilizes all available compliance and department programmatic data to produce a RE rate that best reflects the field effectiveness of the rule. By using the entire population of data for the prescribed time period, (July 2008 – June 2009) the statistical validity of the RE rate greatly improves. This approach deviates from previous rule effectiveness studies conducted by MCAQD that were based upon a small sample pool of targeted inspections (MCAQD, 2007). The RE rates presented here are developed from statistical examination of recorded inspection data, supplemented with data on department programs and policies that impact the enforcement and creation of the rules under study. Assessment of inspection records provides the major component of the RE rate known as a compliance rate. This is the rate at which inspection staff is observing facility and source category compliance in the field. While this provides the most direct measure of rule effectiveness, it is still an incomplete picture of overall rule effectiveness. In actuality, the observed compliance rate is better described as a rate at which inspection staff issue violations. Inspection staff has a range of experience and training which influences their proficiency in issuing appropriate violations. There may be instances when a rule violation goes unnoticed by staff, or conversely a violation may be issued in error. Even with a compliance rate that has a high statistical measure of accuracy, it fails to reflect a number of programmatic measures that affect overall rule effectiveness; measures like the strength of rule language, departmental enforcement and penalty actions, inspector training programs, educational and public outreach efforts, etc. This reality is reflected in earlier US EPA guidance: A percentage effectiveness rating is not enough to describe the compliance effectiveness of a rule for a source category. An SSCD [Stationary Source Compliance Division] study should attempt to link the rating to a regulatory agency’s overall effort. The study should address the factors that affect the percentage effectiveness rating such as the compliance rate of the sources in a category, inspection frequency and thoroughness, the language of the rule (i.e., whether or not it has loopholes), and the reporting and recordkeeping by the regulatory agency. Evaluating these factors will provide a more complete evaluation of the effectiveness of a rule. (US EPA, 1994) In order to incorporate all the salient factors described above, a matrix was created to produce a final RE rate. US EPA’s latest guidance (2005) provides a listing of factors that can impact rule effectiveness rates (e.g., inspector training, frequency of inspections, media outreach, enforcement policies, recordkeeping requirements, etc.), grouped into major categories such as most important factors, important factors and other factors. MCAQD used these suggested factors as the base structure for creating the RE matrices contained in Appendices 3A through 3F. In brief, the compliance rate developed from inspection data (labeled “Compliance History” in the matrix) accounts for 70% of the overall RE rate, while all other factors account for the remaining 30%. (An exception to these values applies in the case of agricultural activities.) Each factor is scored individually, based upon the department’s success in implementing that factor. As an example, the score for the factor “Compliance History” is the compliance rate developed from the study period inspection data, while the score for “Enforcement Penalties” is based upon the department’s timely response to, and settlement of, observed violations associated with the 2008 Maricopa Co. PM10 Emission Inventory A3–2 June 2010 subject rule or source category. The complete matrices for each rule or source category for which rule effectiveness was addressed, are contained in Appendices 3A through 3F. Once an RE rate has been calculated, its value is applied to relevant sources at an individual process level, thus adjusting (i.e., increasing) emission estimates to reflect a lower degree of control efficiency. The formulas below illustrate how inclusion of rule effectiveness can significantly affect the resulting emission estimates: Emissions before the application of rule effectiveness: Uncontrolled Emissions × [1 – (Control Efficiency)] = Emissions with Control 100 tons × [ 1 – (0.90) ] = 10.0 tons Emissions after the application of rule effectiveness: Uncontrolled Emissions × [1 – (Control Efficiency × RE)] 100 tons × [ 1 – (0.90 × 0.83) ] = Emissions with Control = 25.3 tons In general, the RE rate is applied to all processes where a control device or control technique is in use. There are however some limitations to this blanket rule, as expressed in US EPA’s most recent guidance: …not all emission estimates involving use of a control device or technique need to be adjusted to account for RE…For example, a state or local agency may conclude that a control device that operates in conjunction with a continuous emissions monitor, or is equipped with an automatic shutdown device, may provide a sufficient level of assurance that intended emission reductions will be achieved, and therefore an adjustment for rule effectiveness is not necessary. Another example would be in instances where a direct determination of emissions, such as via a mass balance calculation, can be made. (US EPA, 2005) Another hindrance to the application of a blanket RE percentage rate occurs when the control device efficiency reported is high. Control device efficiencies are routinely reported at efficiencies of 99% or greater (e.g., baghouses, thermal oxidizers). For these activities, even small adjustments through the application of RE can cause a dramatic increase in reported emissions. As an example, a process with a control device of 99.9% efficiency may report controlled emissions of 10 tons. If an RE rate of 85% were applied to this process, the adjusted emissions would total 1,508.5 tons (an increase of nearly 15,000%). In these types of instances, MCAQD evaluated the affected processes on a case-by-case basis to determine the appropriateness of applying an RE adjustment. A total of six distinct rule effectiveness rates were calculated for use in this emissions inventory: four source-specific rule effectiveness determinations (Rule 310, Rule 310.01, Rule 316 and agricultural activities) along with two multi-rule determinations (Title V and non-Title V permitted facilities). The following sections describe in further detail the data and methods used in the development of each of these RE factors. 2008 Maricopa Co. PM10 Emission Inventory A3–3 June 2010 Calculation of Rule Effectiveness (RE) Rates A. Rule 310 RE Rate: Sources subject to MCAQD Rule 310 (Fugitive Dust from Dust-Generating Operations) are most often those construction sites where the disturbance of earth is occurring. The RE rate for Rule 310 sources is developed as a weighted average between the observed compliance rate of permitted sites and the effectiveness of department programs and policies related to Rule 310 implementation. The complete RE matrix for Rule 310 is shown in Appendix 3A. The compliance rate for Rule 310 sources uses inspection data of issued dust permits between July 2008 and June 2009. Only inspections that result in a finding of compliance or noncompliance (i.e., “in violation”) are considered in the compliance rate. Inspections conducted solely to confirm the closing of a permit, or inspections where a compliance determination could not be made, were not including in the development of the compliance rate. Using these criteria, a total of 12,290 inspections were conducted on 5,458 issued permits, out of a possible pool of 7,974 issued permits. Dust Control Permits are only valid for 12 months, and expire on the anniversary of their issue date; for instance a permit issued on July 22, 2007 expired on July 22, 2008. This permit would therefore only have “operated” 22 days in the inspection period on which this compliance data is based. Some issued permits also experience limited operations, perhaps only a month or two, but in most cases these permits are left open by the permit holder for the entire 12 months. Given these realities, it is not unexpected that 2,516 out of the pool of 7,974 permits received no compliance determination inspection during the 12-month period of July 2008–June 2009. Conversely, over 58% of all issued permits were inspected two or more times, with some sites receiving as many as 13 compliance determination inspections during the time period. Of the inspected sources listed above, individual compliance rates are determined on a permit by permit basis. Any permit that received at least one violation during any conducted inspection in July 2008 through June 2009 received a compliance rate of 0%. Permitted sites that had no recorded violations during the study period received a compliance rate of 100%. Of the violations noted, 42% of the violations were emissions-related (track-out, visible emissions, silt content, etc.), with the remaining 58% of the violations being procedural (recordkeeping, inadequate dust control plan, etc.). The permit-specific compliance rates were summed and averaged to produce an overall grouped compliance rate of 87.01%. Applying this 87.01% compliance rate into the matrix shown in Appendix 3A yields an overall RE rate of 82.99% for this category of sources. B. Rule 310.01 RE Rate: The majority of sources subject to Rule 310.01 (Fugitive Dust from Non-Traditional Sources of Fugitive Dust) are vacant lots. It is estimated that there are presently more than 100,000 vacant lots in Maricopa County. Rule 310.01 sources generally do not require a permit, unlike Rule 310 and Rule 316 sources. The RE rate for Rule 310.01 sources is calculated based upon vacant lot inspection compliance rates, as well as the effectiveness of department policies and programs that address Rule 310.01 implementation. The complete matrix for Rule 310.01 is contained in Appendix 3B. 2008 Maricopa Co. PM10 Emission Inventory A3–4 June 2010 During the study period (July 2008 – June 2009), MCAQD inspectors performed a total of 12,370 inspections of vacant lots in Maricopa County. The primary purpose of a Rule 310.01 inspection is to verify whether or not the vacant lot in question has a stabilized surface. If the surface is determined to be stable (through a variety of tests), the lot is deemed to be in compliance. Conversely, if the lot’s surface is deemed to be unstable, then a violation of Rule 310.01 has occurred. As with Rule 310, a compliance rate is determined individually for each vacant lot, and then summed and averaged to produce a group compliance rate. The overall compliance rate for Rule 310.01 sites is 95.15%. All the violations noted by inspectors were emissionsrelated violations, as all the violations are for unstable soil conditions. Factoring this compliance rate into the matrix shown in Appendix 3B, yield an overall RE rate for this category of sources of 80.87%. C. Rule 316 RE Rate: Facilities subject to Rule 316 (Nonmetallic Mineral Processing) include industries involved in the mining of sand and gravel and the production of concrete products. All Rule 316 sites are required to have either a Title V or non-Title V permit issued by MCAQD. At present, all facilities that are subject to Rule 316 have only non-Title V permits. (One class of sources that is an exception to this has long been made for portable sources that may operate in more than one county during the life of the permit; thus these sources are issued permits by the Arizona Department of Environmental Quality. The RE rate for Rule 316 sites is determined in a similar fashion as for Rules 310 and 310.01 – developing a weighted average between the observed compliance rate of permitted sites and the effectiveness of departmental programs and policies related to Rule 316 implementation. The completed matrix for Rule 316 is contained in Appendix 3C. Inspection data for the period July 2008 through June 2009 reveal that there were 136 issued permits for Rule 316 facilities. All of these facilities were inspected at least once during this study period, with a compliance determination made for each facility. Overall, 525 inspections that resulted in a compliance determination were performed during the study period. As with Rules 310 and 310.01, a compliance rate is computed for each facility, and then summed and averaged for the group, resulting in an overall compliance rate of 35.29%. Of the violations noted, 44% were emissions-related, with the remaining 56% primarily procedural in nature. This compliance rate is factored into the RE matrix contained in Appendix 3C to yield an overall RE rate of 49.62%. D. Agricultural Activities RE Rate: Agricultural activities in most parts of Maricopa County are subject to the Best Management Practices program administered by the Arizona Department of Environmental Quality (ADEQ). This program is largely a self-monitoring program, in which participants indicate which management practices were chosen to be used during various operations (e.g., harvesting, tilling). No compliance rate estimates for this program were noted during the study period. ADEQ does indicate that after a site has been visited, 100% of the sources return to compliance. Since compliance with this program is verified only on a complaint-driven basis, the weight given to compliance history was lowered, from 70% to 25%, in the matrix contained in Appendix 3D, which indicates an overall RE rate of 55.30% for agricultural activities. 2008 Maricopa Co. PM10 Emission Inventory A3–5 June 2010 E. Title V and Non-Title V RE Rates: For the remaining emission processes (not regulated by Rules 310, 310.01 and/or 316) that include a control device or technique that limits particulate matter or ozone formation, a separate multi-rule RE rate has been developed for permitted Title V and non-Title V facilities. Factorbased matrices similar to those developed for Rules 310, 310.01 and 316 have been utilized to develop RE rates for Title V and non-Title V facilities. Compliance rates for these sources is based upon two full years of data (2008 through 2009), as compliance information for these sources tends to be more detailed (as reflected in the matrix). The compliance rate for these facilities also includes data on self-monitoring recordkeeping practices in addition to inspection data. The combination of monitoring data and inspection data comprise the ‘compliance rate’ section of the RE calculation matrix, and still account for 70% of the overall RE rate. The combined compliance rate for Title V facilities is 89.14% and 81.00% for non-Title V facilities. Appendices 3E and 3F indicate RE rates of 90.94% and 84.27% for Title V and non-Title V facilities, respectively. References MCAQD, 2007. 2005 Periodic Emissions Inventory for PM10 for the Maricopa County, Arizona, Nonattainment Area. US EPA, 1992. Guidelines for Estimating and Applying Rule Effectiveness for Ozone/CO State Implementation Plan Base Year Inventories. EPA Rep. 452/R-92-010, November 1992. US EPA, 1994. Rule Effectiveness Guidance: Integration of Inventory, Compliance and Assessment Applications. EPA Rep. 452/R-94-001, January 1994. US EPA, 2005. Emissions Inventory Guidance for Implementation of Ozone and Particulate Matter National Ambient Air Quality Standards (NAAQS) and Regional Haze Regulations. EPA Rep. 454/R-05-001, November 2005. 2008 Maricopa Co. PM10 Emission Inventory A3–6 June 2010 APPENDIX 3A. Rule Effectiveness Matrix for Rule 310 A. Most important factor (1 criterion, assigned weighting of 70% of total): Factor Compliance History Range Midpt. value 86% 100% 93% 70% 85% 78% < 70% 35% Description Over 90% of facilities inspected in the source category are in compliance. Over 75% of facilities inspected in the source category are in compliance. Over 60% of facilities inspected in the source category are in compliance. Weight Value Score assigned to (= weight × MCAQD value) 70% 87% 60.91% 4% 0% 0.00% 4% 78% 3.12% 4% 93% 3.72% 4% 93% 3.72% 4% 78% 3.12% 4% 78% 3.12% B. Other important factors (6 criteria, each assigned weighting of 4% of total): Compliance Certifications Type of Inspection Inspection Frequency/ Percentage Unannounced Inspections Enforcement Penalties 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% < 70% 78% 35% Compliance Assistance Source is subject to some type of compliance certification. Source is subject to some type of compliance certification. Source is not subject to any type of compliance certification. Inspections are thorough and detailed, and include close examination of control equipment, and a detailed records review. Inspections consist of a records review, and sometimes inspection of control equipment. Inspections generally consist of a records review only. Percent of facilities inspected in the sector in a given year is 25% or greater. Percent of facilities inspected in the sector in a given year is 15% or greater. Percent of facilities inspected in the sector in a given year is less than 15%. Unannounced inspections are sometimes done. Unannounced inspections are done, but infrequently. Unannounced inspections are never done. Agency takes prompt enforcement action, including monetary fines, against violators. Agency usually takes enforcement action, including monetary fines, against violators. Agency usually does not take enforcement action against violators. A compliance assistance program exists and is adequately staffed, and includes such things as workshops, mailings, web-based tutorials, etc. A compliance assistance program exists and is minimally staffed. The program occasionally makes workshops, mailings, web-based tutorials, etc., available. A compliance assistance program does not exist. 2008 Maricopa Co. PM10 Emission Inventory A3–7 June 2010 C. Other factors (3 criteria, each assigned weighting of 2% of total): Factor Monitoring Requirements Follow-up Inspections Media Publicity Range Midpt. value 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% 78% < 70% 35% Description Monitoring requirements exist and must be reported to regulatory agency at least once a year. Monitoring requirements exist but records don’t have to be filed with regulatory agency. Monitoring requirements do not exist. Follow-up inspections are done when violations are noted most (>75%) of the time. Follow-up inspections are done when violations are noted some of the time. Follow-up inspections are not routinely done. Media publicity of enforcement actions is routinely conducted. Media publicity of enforcement actions is sometimes done. Media publicity of enforcement actions is rarely done. Weight Value Score assigned to (= weight × MCAQD value) 2% 78% 1.56% 2% 93% 1.86% 2% 93% 1.86% Overall rule effectiveness score for Rule 310 sites: 82.99% 2008 Maricopa Co. PM10 Emission Inventory June 2010 A3–8 APPENDIX 3B. Rule Effectiveness Matrix for Rule 310.01 A. Most important factor (1 criterion, assigned weighting of 70% of total): Factor Compliance History Range Midpt. value 86% 100% 93% 70% 85% 78% < 70% 35% Description Over 90% of facilities inspected in the source category are in compliance. Over 75% of facilities inspected in the source category are in compliance. Over 60% of facilities inspected in the source category are in compliance. Weight Value Score assigned to (= weight × MCAQD value) 70% 95% 66.61% 4% 0% 0.00% 4% 78% 3.12% 4% 35% 1.40% 4% 78% 3.12% 4% 35% 1.40% 4% 35% 1.40% B. Other important factors (6 criteria, each assigned weighting of 4% of total): Compliance Certifications Type of Inspection Inspection Frequency/ Percentage Unannounced Inspections Enforcement Penalties 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% 78% < 70% 35% Source is subject to some type of compliance certification. Source is subject to some type of compliance certification. Source is not subject to any type of compliance certification. Inspections are thorough and detailed, and include close examination of control equipment, and a detailed records review. Inspections consist of a records review, and sometimes inspection of control equipment. Inspections generally consist of a records review only. Percent of facilities inspected in the sector in a given year is 25% or greater. Percent of facilities inspected in the sector in a given year is 15% or greater. Percent of facilities inspected in the sector in a given year is less than 15%. Unannounced inspections are sometimes done. Unannounced inspections are done, but infrequently. Unannounced inspections are never done. Agency takes prompt enforcement action, including monetary fines, against violators. Agency usually takes enforcement action, including monetary fines, against violators. Agency usually does not take enforcement action against violators. 86% 100% 93% 70% 85% 78% A compliance assistance program exists and is adequately staffed, and includes such things as workshops, mailings, web-based tutorials, etc. A compliance assistance program exists and is minimally staffed. The program occasionally makes workshops, mailings, web-based tutorials, etc., available. < 70% 35% A compliance assistance program does not exist. Compliance Assistance 2008 Maricopa Co. PM10 Emission Inventory A3–9 June 2010 C. Other factors (3 criteria, each assigned weighting of 2% of total): Factor Monitoring Requirements Follow-up Inspections Media Publicity Range Midpt. value 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% 78% < 70% 35% Description Monitoring requirements exist and must be reported to regulatory agency at least once a year. Monitoring requirements exist but records don’t have to be filed with regulatory agency. Monitoring requirements do not exist. Follow-up inspections are done when violations are noted most (>75%) of the time. Follow-up inspections are done when violations are noted some of the time. Follow-up inspections are not routinely done. Media publicity of enforcement actions is routinely conducted. Media publicity of enforcement actions is sometimes done. Media publicity of enforcement actions is rarely done. Weight Value Score assigned to (= weight × MCAQD value) 2% 78% 1.56% 2% 78% 1.56% 2% 35% 0.70% Overall rule effectiveness score for Rule 310.01 sites: 80.87% 2008 Maricopa Co. PM10 Emission Inventory June 2010 A3–10 APPENDIX 3C. Rule Effectiveness Matrix for Rule 316 A. Most important factor (1 criterion, assigned weighting of 70% of total): Factor Compliance History Range Midpt. value 86% 100% 93% 70% 85% 78% < 70% 35% Description Over 90% of facilities inspected in the source category are in compliance Over 75% of facilities inspected in the source category are in compliance Over 60% of facilities inspected in the source category are in compliance Weight Value Score assigned to (= weight × MCAQD value) 70% 35% 24.70% 4% 78% 3.12% 4% 78% 3.12% 4% 86% 3.44% 4% 93% 3.72% 4% 78% 3.12% 4% 78% 3.12% B. Other important factors (6 criteria, each assigned weighting of 4% of total): Compliance Certifications Type of Inspection Inspection Frequency/ Percentage Unannounced Inspections Enforcement Penalties 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% 78% < 70% 35% Source is subject to some type of compliance certification; Source is subject to some type of compliance certification; Source is not subject to any type of compliance certification; Inspections are thorough and detailed, and include close examination of control equipment, and a detailed records review Inspections consist of a records review, and sometimes inspection of control equipment; Inspections generally consist of a records review only; Percent of facilities inspected in the sector in a given year is 25% or greater; Percent of facilities inspected in the sector in a given year is 15% or greater; Percent of facilities inspected in the sector in a given year is less than 15% Unannounced inspections are sometimes done; Unannounced inspections are done, but infrequently; Unannounced inspections are never done; Agency takes prompt enforcement action, including monetary fines, against violators; Agency usually takes enforcement action, including monetary fines, against violators; Agency usually does not take enforcement action against violators; 86% 100% 93% 70% 85% 78% A compliance assistance program exists and is adequately staffed, and includes such things as workshops, mailings, web-based tutorials, etc. A compliance assistance program exists and is minimally staffed. The program occasionally makes workshops, mailings, web-based tutorials, etc., available. < 70% 35% A compliance assistance program does not exist Compliance Assistance 2008 Maricopa Co. PM10 Emission Inventory A3–11 June 2010 C. Other factors (3 criteria, each assigned weighting of 2% of total): Factor Monitoring Requirements Follow-up Inspections Media Publicity Range Midpt. value 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% 78% < 70% 35% Description Monitoring requirements exist and must be reported to regulatory agency at least once a year; Monitoring requirements exist but records don’t have to be filed with regulatory agency; Monitoring requirements do not exist; Follow-up inspections are done when violations are noted most (>75%) of the time; Follow-up inspections are done when violations are noted some of the time; Follow-up inspections are not routinely done; Media publicity of enforcement actions is routinely conducted. Media publicity of enforcement actions is sometimes done. Media publicity of enforcement actions is rarely done. Weight Value Score assigned to (= weight × MCAQD value) 2% 78% 1.56% 2% 93% 1.86% 2% 93% 1.86% Overall rule effectiveness score for Rule 316 sites: 49.62% 2008 Maricopa Co. PM10 Emission Inventory June 2010 A3–12 APPENDIX 3D. Rule Effectiveness Matrix for Agricultural Activities A. Most important factor (1 criterion, assigned weighting of 25% of total): Factor Compliance History Type of Inspection Range Midpt. value 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% 78% < 70% 35% Description Over 90% of facilities inspected in the source category are in compliance Over 75% of facilities inspected in the source category are in compliance Over 60% of facilities inspected in the source category are in compliance Inspections are thorough and detailed, and include close examination of control equipment, and a detailed records review Inspections consist of a records review, and sometimes inspection of control equipment; Inspections generally consist of a records review only; Weight Value Score assigned to (= weight × MCAQD value) 25% 93% 23.25% 10% 35% 3.5% B. Other important factors (6 criteria, each assigned weighting of 10% of total): Compliance Certifications Inspection Frequency/ Percentage Unannounced Inspections Enforcement Penalties 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% 78% < 70% 35% 86% 100% 93% 70% 85% < 70% 78% 35% Compliance Assistance Source is subject to some type of compliance certification; Source is subject to some type of compliance certification; Source is not subject to any type of compliance certification; 10% 35% 3.5% Percent of facilities inspected in the sector in a given year is 25% or greater; Percent of facilities inspected in the sector in a given year is 15% or greater; Percent of facilities inspected in the sector in a given year is less than 15% 10% 35% 3.5% Unannounced inspections are sometimes done; Unannounced inspections are done, but infrequently; Unannounced inspections are never done; 10% 35% 3.5% Agency takes prompt enforcement action, including monetary fines, against violators; Agency usually takes enforcement action, including monetary fines, against violators; Agency usually does not take enforcement action against violators; 10% 35% 3.5% 10% 93% 9.3% A compliance assistance program exists and is adequately staffed, and includes such things as workshops, mailings, web-based tutorials, etc. A compliance assistance program exists and is minimally staffed. The program occasionally makes workshops, mailings, web-based tutorials, etc., available. A compliance assistance program does not exist 2008 Maricopa Co. PM10 Emission Inventory A3–13 June 2010 C. Other factors (3 criteria, each assigned weighting of 5% of total): Factor Monitoring Requirements Follow-up Inspections Media Publicity Range Midpt. value 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% < 70% 78% 35% 86% 100% 93% 70% 85% 78% < 70% 35% Description Monitoring requirements exist and must be reported to regulatory agency at least once a year; Monitoring requirements exist but records don’t have to be filed with regulatory agency; Monitoring requirements do not exist; Weight Value Score assigned to (= weight × MCAQD value) 5% 35% 1.75% Follow-up inspections are done when violations are noted most (>75%) of the time; Follow-up inspections are done when violations are noted some of the time; Follow-up inspections are not routinely done; 5% 35% 1.75% Media publicity of enforcement actions is routinely conducted. Media publicity of enforcement actions is sometimes done. Media publicity of enforcement actions is rarely done. 5% 35% 1.75% Overall rule effectiveness score for agricultural activities: 55.30% 2008 Maricopa Co. PM10 Emission Inventory June 2010 A3–14 APPENDIX 3E. Rule Effectiveness Matrix for Title V Facilities A. Most important factors (2 criteria, each assigned weighting of 35% of total): Factor Range Midpt. value 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% < 70% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Monitoring Compliance History Description Source specific monitoring used for compliance purposes, and monitoring records filed with regulatory agency at least every 4 months. Source specific monitoring used as an indicator of compliance, and monitoring records filed with regulatory agency every 6 to 9 months. Source specific monitoring used as an indicator of compliance, and monitoring records filed with regulatory agency each year. General guidance exists for source specific enhanced monitoring, and monitoring records required but aren’t submitted to regulatory agency. No requirements for any type of monitoring. The facility has been in compliance for the past eight quarters. The facility is believed to have been in compliance for the past eight quarters, although inspection frequency is such that this can’t be positively confirmed. On schedule; the facility is meeting its compliance schedule. In Violation; facility is in violation of emissions and/or procedural requirements. High Priority Violator (HPV): the facility is in significant violation of one or more applicable requirement of the CAA. Weight Value Score assigned to (= weight × MCAQD value) 35% 90% 31.5% 10 of 19 facilities 17.9% 8 of 19 facilities 12.4% 1 of 19 facilities Sum: 0.6% 30.9% 35% B. Other important factors (4 criteria, each assigned weighting of 3% of total): Type of Inspection Operation & Maintenance 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% < 70% 75% 35% Inspections involve compliance test methods with a high degree of accuracy, such as stack testing or other types of precise emissions measurement. Inspections involve detailed review of process parameters & inspection of control equipment. Inspections involve review of process and inspection of control equipment. Inspections generally consist of only a records review. Inspections most likely consist of visual inspection (e.g., opacity), or drive by. Control equipment operators follow and sign daily O&M instructions. Control equipment operators follow daily O&M instructions. Control equipment operators follow daily or weekly O&M instructions. O&M requirements exist, but on no specific schedule. No specific O&M requirements. 2008 Maricopa Co. PM10 Emission Inventory A3–15 3% 97% 2.9% 3% 90% 2.7% June 2010 Factor Unannounced Inspections Range 94% 100% 87% 93% 81% 86% 70% 80% < 70% Midpt. value 97% 90% 84% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Enforcement Penalties Description Routinely conducted. Sometimes done. Done, but infrequently. Rarely done. Never done. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency does not have sufficient authority to impose punitive measures towards violators. Weight 3% Value Score assigned to (= weight × MCAQD value) 97% 2.9% 3% 97% 2.91% 2% 97% 1.94% 2% 97% 1.94% 2% 97% 1.94% C. Other factors (9 criteria, each assigned weighting of 2% of total): Compliance Certifications Inspection Frequency EPA HPV Enforcement 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 70% 86% 80% < 70% 84% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Source subject to Title V or other type of compliance certification. Source subject to Title V or other type of compliance certification. Source not subject to any type of compliance certification. Source not subject to any type of compliance certification. Source not subject to any type of compliance certification. Source(s) are inspected once every 2 years or more frequently. Source(s) are inspected once every 3 years or more frequently. Source(s) are inspected once every 5 years or more frequently. Inspection of source(s) infrequent; > every 5 years. Inspections rarely, if ever, performed. Agency has sufficient resources to implement EPA’s 12/22/98 HPV policy. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy in most instances. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy in most instances. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy more often than not. Resource constraints prohibit agency from implementing EPA’s 12/22/98 HPV policy in most instances. 2008 Maricopa Co. PM10 Emission Inventory A3–16 June 2010 Factor Operator Training Media Publicity Range Midpt. value 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 0.8 75% < 70% 35% Description Control equipment operators complete a formal training program on use of the equipment, and such program is kept up to date and has been reviewed by the regulatory agency. Control equipment operators complete formal training program, and such program is kept up to date and available for review by the regulatory agency upon request. Control equipment operators complete some amount of formal training. Control equipment operators receive only on the job training. Control equipment operators receive no specific training. 100% 93% 86% 80% < 70% 97% 90% 84% 75% 35% Media publicity of enforcement actions. Media publicity of enforcement actions. Media publicity of enforcement actions. Media publicity of enforcement actions. No media publicity of enforcement actions. 94% 87% 81% 70% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Regulatory Workshops 94% Inspector Training 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Regulatory workshops are available annually, and/or the implementing agency mails regulatory information packages each year. Regulatory workshops are available every 1-2 years, and/or the implementing agency mails regulatory information packages every 1-2 years. Regulatory workshops are available every 2-3 years, and/or the implementing agency mails regulatory information packages once every 2-3 years. Regulatory workshop not routinely available, but implementing agency mails regulatory information packages out about once every 2-3 years. Regulatory workshops not routinely available. Implementing agency mails regulatory information packages infrequently, if ever. Inspectors must undergo 2 weeks of comprehensive basic training, and 1 to 2 weeks of source specific training, and such training is updated each year. Inspectors must undergo 1 to 2 weeks of basic training and 1 week of source specific training and such training is updated every 1-2 years. Inspectors must undergo 1 to 2 weeks of basic training and 3 to 5 days of source specific training, and such training is updated every 1-2 years. Inspectors must undergo 1 to 2 weeks of basic training and 1 to 3 days of source specific training, and such training is updated every 1-2 years. Inspectors must undergo less than 5 days of basic training less than 3 days of source specific training, and such training is updated only every 2 years or less frequently. 2008 Maricopa Co. PM10 Emission Inventory A3–17 Weight Value Score assigned to (= weight × MCAQD value) 2% 84% 1.68% 2% 97% 1.94% 2% 97% 1.94% 2% 90% 1.80% June 2010 Factor Range 94% Testing Guidelines Follow-up Inspections Midpt. value 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Description Specific guidelines and schedule for testing and test methods exist. Specific guidelines on testing and test methods exist, but no schedule for testing. Specific guidelines on testing and test methods exist, but no schedule for testing. Specific guidelines on testing and test methods, but no schedule for testing. Only general guidance on testing, or no mention of testing requirements. Follow-up inspections always or almost always conducted (90 % of the time or more). Follow-up inspections usually conducted (approximately 75% of the time). Follow-up inspections sometimes conducted (approximately 50% of the time). Follow-up inspections infrequently conducted (approximately 25% of the time). Follow-up inspections rarely or never conducted (10% of the time or less) Weight 2% 2% Value Score assigned to (= weight × MCAQD value) 97% 97% 1.94% 1.94% Overall rule effectiveness score for Title V facilities: 90.94% 2008 Maricopa Co. PM10 Emission Inventory June 2010 A3–18 APPENDIX 3F. Rule Effectiveness Matrix for Non-Title V Facilities A. Most important factors (2 criteria, each assigned weighting of 35% of total): Factor Range Midpt. value 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% < 70% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Monitoring Compliance History B. Description Source specific monitoring used for compliance purposes, and monitoring records filed with regulatory agency at least every 4 months. Source specific monitoring used as an indicator of compliance, and monitoring records filed with regulatory agency every 6 to 9 months. Source specific monitoring used as an indicator of compliance, and monitoring records filed with regulatory agency each year. General guidance exists for source specific enhanced monitoring, and monitoring records required but aren’t submitted to regulatory agency. No requirements for any type of monitoring. The facility has been in compliance for the past eight quarters. The facility is believed to have been in compliance for the past eight quarters, although inspection frequency is such that this can’t be positively confirmed. On schedule; the facility is meeting its compliance schedule. In Violation; facility is in violation of emissions and/or procedural requirements. High Priority Violator (HPV): the facility is in significant violation of one or more applicable requirement of the CAA. Weight 35% 35% Value Score assigned to (= weight MCAQD × value) 75% 26.3% 156 of 298 facilities 17.8% 10 of 298 facilities 1.1% 130 of 298 facilities 11.5% 2 of 298 facilities Sum: 0.1% 30.4% Other important factors (4 criteria, each assigned weighting of 3% of total): Type of Inspection Operation & Maintenance 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% < 70% 75% 35% Inspections involve compliance test methods with a high degree of accuracy, such as stack testing or other types of precise emissions measurement. Inspections involve detailed review of process parameters & inspection of control equipment. Inspections involve review of process and inspection of control equipment. Inspections generally consist of only a records review. Inspections most likely consist of visual inspection (e.g., opacity), or drive by. Control equipment operators follow and sign daily O&M instructions. Control equipment operators follow daily O&M instructions. Control equipment operators follow daily or weekly O&M instructions. O&M requirements exist, but on no specific schedule. No specific O&M requirements. 2008 Maricopa Co. PM10 Emission Inventory A3–19 3% 90% 2.7% 3% 90% 2.7% June 2010 Factor Unannounced Inspections Range 94% 100% 87% 93% 81% 86% 70% 80% < 70% Midpt. value 97% 90% 84% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Enforcement Penalties Description Routinely conducted. Sometimes done. Done, but infrequently. Rarely done. Never done. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency has the authority to impose punitive measures, including monetary fines, towards violators such as in delegated Title V Operating Permit programs. Agency does not have sufficient authority to impose punitive measures towards violators. Weight 3% Value Score assigned to (= weight MCAQD × value) 97% 2.91% 3% 97% 2.91% 2% 75% 1.5% 2% 97% 1.94% 2% 97% 1.94% C. Other factors (9 criteria, each assigned weighting of 2% of total): Compliance Certifications Inspection Frequency EPA HPV Enforcement 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 70% 86% 80% < 70% 84% 75% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Source subject to Title V or other type of compliance certification. Source subject to Title V or other type of compliance certification. Source not subject to any type of compliance certification. Source not subject to any type of compliance certification. Source not subject to any type of compliance certification. Source(s) are inspected once every 2 years or more frequently. Source(s) inspected every 3 years or more frequently. Source(s) inspected every 5 years or more frequently. Inspection of source(s) infrequent; > every 5 years. Inspections rarely, if ever, performed. Agency has sufficient resources to implement EPA’s 12/22/98 HPV policy. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy in most instances. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy in most instances. Agency’s resources allow it to implement EPA’s 12/22/98 HPV policy more often than not. Resource constraints prohibit agency from implementing EPA’s 12/22/98 HPV policy in most instances. 2008 Maricopa Co. PM10 Emission Inventory A3–20 June 2010 Factor Operator Training Media Publicity Midpt. value Range 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 0.8 75% < 70% 35% Description Control equipment operators complete a formal training program on use of the equipment; the program is kept up to date and has been reviewed by the regulatory agency. Control equipment operators complete formal training program, and such program is kept up to date and available for review by the regulatory agency upon request. Control equipment operators complete some amount of formal training. Control equipment operators receive only on the job training. Control equipment operators receive no specific training. 100% 93% 86% 80% < 70% 97% 90% 84% 75% 35% Media publicity of enforcement actions. Media publicity of enforcement actions. Media publicity of enforcement actions. Media publicity of enforcement actions. No media publicity of enforcement actions. 94% 87% 81% 70% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Regulatory Workshops Inspector Training 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Regulatory workshops are available annually, and/or the implementing agency mails regulatory information packages each year. Regulatory workshops are available every 1-2 years, and/or the implementing agency mails regulatory information packages every 1-2 years. Regulatory workshops are available every 2-3 years, and/or the implementing agency mails regulatory information packages once every 2-3 years. Regulatory workshop not routinely available, but implementing agency mails regulatory information packages out about once every 2-3 years. Regulatory workshops not routinely available. The implementing agency mails regulatory information packages infrequently, if ever. Inspectors must undergo 2 weeks of comprehensive basic training, and 1 to 2 weeks of source specific training, and such training is updated each year. Inspectors must undergo 1 to 2 weeks of basic training and 1 week of source specific training and such training is updated every 1-2 years. Inspectors must undergo 1 to 2 weeks of basic training and 3 to 5 days of source specific training, and such training is updated every 1-2 years. Inspectors must undergo 1 to 2 weeks of basic training and 1 to 3 days of source specific training, and such training is updated every 1-2 years. Inspectors must undergo less than 5 days of basic training less than 3 days of source specific training, and such training is updated only every 2 years or less frequently. 2008 Maricopa Co. PM10 Emission Inventory A3–21 Weight Value assigned to MCAQD Score(= weight × value) 2% 75% 1.5% 2% 97% 1.94% 2% 97% 1.94% 2% 90% 1.80% June 2010 Factor Testing Guidelines Follow-up Inspections Midpt. value Range 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% 94% 100% 97% 87% 93% 90% 81% 86% 84% 70% 80% 75% < 70% 35% Description Specific guidelines and schedule for testing and test methods exist. Specific guidelines on testing and test methods exist, but no schedule for testing. Specific guidelines on testing and test methods exist, but no schedule for testing. Specific guidelines on testing and test methods, but no schedule for testing. Only general guidance on testing, or no mention of testing requirements. Follow-up inspections always or almost always conducted (90 % of the time or more). Follow-up inspections usually conducted (approximately 75% of the time). Follow-up inspections sometimes conducted (approximately 50% of the time). Follow-up inspections infrequently conducted (approximately 25% of the time). Follow-up inspections rarely or never conducted (10% of the time or less) Weight Value assigned to MCAQD Score(= weight × value) 2% 97% 1.94% 2% 97% 1.94% Overall rule effectiveness score for non-Title V facilities: 84.27% 2008 Maricopa Co. PM10 Emission Inventory June 2010 A3–22 Appendix 4. Windblown Dust Emission Estimation Methodology Introduction Emissions from windblown dust occur through an intricate relationship between wind speeds and the physical characteristics of the subject soils. Several methodologies for estimating windblown dust emissions have been developed to try and express these complex relationships (WGA, 2006). For this analysis, a GIS-based approach was developed that utilizes location-specific data on wind speed, precipitation, land use and locally developed emission factors. GIS was chosen as the driver of the methodology to help reflect the wide range of wind speeds, soil types and land uses that occur in an area as large as Maricopa County. A GIS-based method also allows for the mapping of PM10 emissions from windblown dust, as opposed to simply “smearing” a single emission value across the entire county (or nonattainment area). Emissions mapping can assist in the development of microscale emission inventories, modeling exercises, and can focus rule development and compliance activities in known problem areas. As an example, Figure A4–1 depicts the estimated annual PM10 emissions across the PM10 nonattainment area that result by applying the methods described herein. Figure A4–1. PM10 emissions rates (tons/acre-year) from windblown dust in the PM10 nonattainment area. 2008 Maricopa Co. PM10 Emission Inventory A4–1 June 2010 The following sections describe the meteorological, land use, and emission rate (vertical fluxes) data used to develop PM10 emissions from windblown dust in Maricopa County and the PM10 nonattainment area. A summary of PM10 emissions is included in the section “Summary of Windblown Dust Emissions Estimates”. Meteorological Data A total of 34 meteorological stations encompass the source of calendar year 2008 wind speed and precipitation data used in this inventory of windblown dust. This includes 11 stations operated by the Arizona Meteorological Network (AZMET), 22 stations operated by the Maricopa County Air Quality Department (MCAQD), and 1 station operated by the Pinal County Air Quality Control District (PCAQCD). Stations operated by the National Weather Service (NWS) in and around Maricopa County were not chosen for inclusion in this analysis due to differences in wind speed data collection methods that preclude “apples-to-apples” comparisons with data from those meteorological stations included in this work 1. Figure A4–2 displays the location of the included meteorological stations. Figure A4–2. Location of meteorological stations. 1. National Weather Service (NWS) stations report wind speeds in 2-minute averages at the time of posting, while AZMET, MCAQD and PCAQCD all report wind speed in hourly averages at the top of each hour. 2008 Maricopa Co. PM10 Emission Inventory A4–2 June 2010 Wind Speed Data For this analysis, 5-minute average wind speeds form the basis of the wind data used in calculating windblown dust emissions. Data recorded as a 5-minute average was chosen over hourly average data because the finer time resolution allows a better representation of potential emissions caused by wind gusts that can create significant emissions, yet be overshadowed in hourly data. This approach also allows for the computation of emissions by wind speed bin classes: 15– 20 mph, 20–25 mph, 25–30 mph and 30–35 mph. As compared to hourly data, the 5-minute bin classes better reflect the change in emission rates (vertical fluxes) as a function of increasing wind speeds. Outlined below are the steps necessary to prepare the wind speed data for inclusion in windblown dust emission calculations. As an initial step wind speeds were uniformly adjusted to speeds at 10 meters (to account for the difference in anemometer heights) through use of a standard wind profile power-law equation: 𝑈𝑧 = 𝑈𝑟 (𝑍/𝑍𝑟 )𝑝 where Uz is wind speed (in mph) at 10 meters, Ur is wind speed (in mph) at referenced anemometer height, Z is 10 meters, Zr is the height (in meters) of the reference anemometer, and p is the power-law exponent. Determination of p was made by comparing wind speeds at neighboring stations with different anemometer heights (e.g., AZMET’s Buckeye station at 3 meters compared with MCAQD’s Buckeye station at 10 meters) through a simple adaptation of the power-law equation: 𝑝= ln(𝑈) − ln(𝑈𝑟 ) ln(𝑍) − ln(𝑍𝑟 ) Comparison of hourly average wind speeds greater than 9 mph yielded an average value for p of 0.06 for urban stations and 0.12 for rural stations. (Only those hours with average winds speeds greater than 9 mph were chosen, as applying the approach described above for hours with calm winds tends to over-inflate the value of p.) Table A4–1 lists the frequency of hourly average wind speeds over 15 mph (after adjustment to 10 meters) for all meteorological stations. In addition to correcting for height, adjustments to wind speed were performed to gap-fill missing data and interpolate 5-minute average values as necessary. All of the meteorological stations report hourly average wind speeds at the top of each hour. In addition, 13 of the MCAQD stations also report 5-minute average wind speeds, with data completion rates of 75% or better. The data from these stations were (1) counted and assigned to one of four wind speed “bin classes” of 15–20 mph, 20–25 mph, 25–30 mph, and 30–35 mph; and (2) “grown” to compensate for missing data, based upon the data completion rate of each station. Thus (e.g.) a station that reported 124 hourly periods that were assigned to a bin with a data completion rate of 90.63%, would result in a “grown” bin value of 137 [124 periods divided by 90.63%]). Table A4–2 presents the 5-minute values and the resulting bin class assignments, for each of the 13 MCAQD meteorological stations that were considered. 2008 Maricopa Co. PM10 Emission Inventory A4–3 June 2010 Table A4–1. Number of hours in 2008 with average wind speeds greater than 15 mph (at uniform height of 10 meters), by site. Number of hourly average Anemometer Station Name wind speeds > 15 mph height (m) AZMET Aguila 284 3 AZMET Buckeye 149 3 AZMET Desert Ridge 70 3 AZMET Harquahala 274 3 AZMET Maricopa 118 3 AZMET Mesa 5 3 AZMET Paloma 224 3 AZMET Phoenix Encanto 1 3 AZMET Phoenix Greenway 6 3 AZMET Queen Creek 161 3 AZMET Waddell 4 3 MCAQD Blue Point 60 10 MCAQD Buckeye 146 10 MCAQD Cave Creek 69 10 MCAQD Central Phoenix 43 15 MCAQD Coyote Lakes 54 10 MCAQD Durango Complex 50 10 MCAQD Dysart 64 10 MCAQD Falcon Field 58 13 MCAQD Fountain Hills 1 10 MCAQD Glendale 19 13 MCAQD Greenwood 1 10 MCAQD Higley 42 10 MCAQD Mesa 42 10 MCAQD North Phoenix 4 10 MCAQD Pinnacle Peak 51 16 MCAQD South Phoenix 6 10 MCAQD South Scottsdale 3 10 MCAQD Tempe 0 10 MCAQD West 43rd Ave 65 10 MCAQD West Chandler 23 10 MCAQD West Indian School 19 10 MCAQD West Phoenix 5 10 PCAQCD Apache Junction 134 10 For the stations that do not record 5-minute average wind speeds 2, regression equations were developed (based upon those MCAQD stations that do report 5-minute average wind speeds) to interpolate 5-minute average values. The equations were derived by regressing each bin class (dependent [y]) against hourly average wind speeds over 15 mph (independent [x]). All of the regression equations proved to be statistically significant at the 95% confidence level. The results of the regression equations for each bin class are shown in Table A4–3. The resulting 5minute average wind speeds (by bin class) for all meteorological stations in this study are shown in Table A4–4. 2. AZMET and PCAQCD stations report average wind speed only on an hourly basis, and another nine MCAQD stations that measure wind speed on a 5-minute average had data completion rates less than 75% for 2008. 2008 Maricopa Co. PM10 Emission Inventory A4–4 June 2010 Table A4–2. Number of recorded and grown 5-minute average wind speeds, by bin category and station. Recorded 5-minute averages Grown 5-minute averages 15–20 20–25 25–30 30–35 Data 15–20 20–25 25–30 30–35 MCAQD Station mph mph mph mph completeness mph mph mph mph Buckeye 1679 296 54 12 99.62% 1685 297 54 12 Coyote Lakes 840 77 1 0 98.71% 851 78 1 0 Durango Complex 618 33 10 1 96.39% 641 34 10 1 Dysart 784 92 6 0 78.16% 1003 118 8 0 Falcon Field 758 95 2 1 76.77% 987 124 3 1 Greenwood 124 11 1 0 90.63% 137 12 1 0 Higley 766 50 8 1 91.02% 842 55 9 1 North Phoenix 80 8 2 0 77.59% 103 10 3 0 South Phoenix 169 9 0 1 99.19% 170 9 0 1 Tempe 5 0 0 0 86.38% 6 0 0 0 West Chandler 515 42 3 1 99.09% 520 42 3 1 West Forty-third 1042 83 13 6 98.44% 1059 84 13 6 West Phoenix 111 8 1 0 92.47% 120 9 1 0 Table A4–3. Regression equation, p-value, and R2 for interpolating 5-minute average wind speeds, by bin. 5-minute average wind speed bin Regression equation p-value R2 15–20 mph y = 150.05 + 11.92x 0.00000006 93.77% 20–25 mph y = –8.34 + 1.39x 0.00000021 92.09% 25–30 mph y = –4.20 + 0.31x 0.00009300 76.42% 30–35 mph y = –0.99 + 0.07x 0.00047000 68.57% Table A4–4. Number of interpolated 5-minute average wind speeds, by station and wind speed bin. (Shaded cells denote interpolated values.) Number of hourly Number of 5-minute average values between: average values Station Name > 15 mph 15–20 mph 20–25 mph 25–30 mph 30–35 mph AZMET Aguila 284 3535 386 84 19 AZMET Buckeye 149 1926 199 42 9 AZMET Desert Ridge 70 984 89 18 4 AZMET Harquahala 274 3416 373 81 18 AZMET Maricopa 118 1557 156 32 7 AZMET Mesa 5 210 0 0 0 AZMET Paloma 224 2820 303 65 15 AZMET Phoenix Encanto 1 162 0 0 0 AZMET Phoenix Greenway 6 222 0 0 0 AZMET Queen Creek 161 2069 215 46 10 AZMET Waddell 4 198 0 0 0 MCAQD Blue Point 60 865 75 14 3 MCAQD Buckeye 146 1685 297 54 12 MCAQD Cave Creek 69 973 88 17 4 MCAQD Central Phoenix 43 663 51 9 2 MCAQD Coyote Lakes 54 851 78 1 0 MCAQD Durango Complex 50 641 34 10 1 MCAQD Dysart 64 1003 118 8 0 MCAQD Falcon Field 58 987 124 3 1 MCAQD Fountain Hills 1 162 0 0 0 MCAQD Glendale 19 377 18 2 0 MCAQD Greenwood 1 137 12 1 0 MCAQD Higley 42 842 55 9 1 MCAQD Mesa 42 651 50 9 2 MCAQD North Phoenix 4 103 10 3 0 2008 Maricopa Co. PM10 Emission Inventory A4–5 June 2010 Table A4–4 (continued). Number of interpolated 5-minute average wind speeds, by meteorological station and wind speed bin. (Shaded cells denote interpolated values.) Number of hourly Number of 5-minute average values between: average values Station Name > 15 mph 15–20 mph 20–25 mph 25–30 mph 30–35 mph MCAQD Pinnacle Peak 51 758 63 12 3 MCAQD South Phoenix 6 170 9 0 1 MCAQD South Scottsdale 3 186 0 0 0 MCAQD Tempe 0 6 0 0 0 MCAQD West 43rd Ave 65 1059 84 13 6 MCAQD West Chandler 23 520 42 3 1 MCAQD West Indian School 19 377 18 2 0 MCAQD West Phoenix 5 120 9 1 0 PCAQCD Apache Junction 134 1747 178 37 8 Lastly, in order to assign the bin class wind speeds to the underlying land use acreages, Thiessen polygons 3 were created for each bin class (after Pulugurtha and James, 2006). Figure A4–3 shows the resulting Thiessen polygon for the 5-minute average 15–20 mph wind speed bin class. Figure A4–3. Thiessen polygon depiction of the number of values for the 15–20 mph wind speed bin class. 3. A “Thiessen polygon” depicts an area whose boundaries define the region that is closest to a given point, relative to all other given points. 2008 Maricopa Co. PM10 Emission Inventory A4–6 June 2010 Precipitation Data AZMET meteorological station report hourly rain totals when precipitation occurs. For those MCAQD and PCAQCD stations that do not report precipitation, rain totals from the closest AZMET station was used as a surrogate. Table A4–5 lists the number of hours during which precipitation was recorded at each station. Table A4–5. Number of hours in 2008 during which any precipitation was recorded at each station. Hours in 2008 with Station Name Recorded Precipitation Aguila 140 Buckeye 91 Desert Ridge 155 Harquahala 110 Maricopa 134 Mesa 154 Paloma 90 Phx. Encanto 139 Phx. Greenway 146 Queen Creek 150 Waddell 113 Blue Point 154 Buckeye 91 Cave Creek 155 Central Phoenix 139 Coyote Lakes 113 Durango Complex 139 Dysart 113 Falcon Field 154 Fountain Hills 155 Glendale 146 Greenwood 139 Higley 150 Mesa 154 North Phoenix 146 Pinnacle Peak 155 South Phoenix 139 South Scottsdale 154 Tempe 154 West Chandler 154 West Forty Third 139 West Indian School Road 139 West Phoenix 139 Apache Junction 150 Average: 138 The resulting average value of 138 hours/year shown above was then used to estimate the percentage of the time during calendar year 2008 for which no windblown dust emissions are assumed to occur. (1.57%; =138 hrs ÷ 8,784 total hours in 2008). 2008 Maricopa Co. PM10 Emission Inventory A4–7 June 2010 Land Use Data The Maricopa Association of Governments (MAG) provided draft 2009 GIS data on land use coverage for use in determining the location and extent of land capable of producing windblown dust. A total of 18 land use categories were provided, six of which were deemed to have the potential to emit windblown dust. Table A4–6 lists the 18 land use categories considered, their acreages within both Maricopa County and the PM10 nonattainment area, and the assessment of each category’s potential to produce windblown dust, considering a variety of typical characteristics for each category. Figure A4–4 depicts the extent and distribution of the six land use categories determined to have the potential to emit windblown dust. Table A4–6. Land use categories, 2009 acreages, and factors determining potential to emit windblown dust. Maricopa PM10 Potential to MAG Land Use County NAA emit windCategory acreage acreage blown dust? Rationale for Determination Built environment, limited presence of natural soils, Residential 353,610 334,413 No limited opportunity for disturbance of soils. Built environment, limited presence of natural soils, Commercial 36,742 35,791 No limited opportunity for disturbance of soils. Built environment, limited presence of natural soils, Industrial 25,933 26,028 No limited opportunity for disturbance of soils. Built environment, limited presence of natural soils, Office 8,289 8,284 No limited opportunity for disturbance of soils. Tourist and Visitor Built environment, limited presence of natural soils, Accommodations 2,679 2,512 No limited opportunity for disturbance of soils. Built environment, limited presence of natural soils, Educational 18,216 18,099 No limited opportunity for disturbance of soils. Built environment, limited presence of natural soils, Institutional 12,210 12,045 No limited opportunity for disturbance of soils. Public Facilities, Built environment, limited presence of natural soils, Military, Special Events 35,308 22,931 No limited opportunity for disturbance of soils. Multiple Use/Business Built environment, limited presence of natural soils, Park 423 13,273 No limited opportunity for disturbance of soils. Transportation and Built environment, limited presence of natural soils, Parking 158,500 141,025 No limited opportunity for disturbance of soils. Built environment, limited presence of natural soils, Airports 11,302 9,558 No limited opportunity for disturbance of soils. General/Active Open Acreage largely parks and golf courses, limited Space/Golf Courses 228,295 223,290 No opportunity for disturbance of natural soils. Passive/Restricted Open Acreage uncovered, unbuilt. Soils subject to Space, Water 2,373,545 302,999 sporadic disturbance. Water coverage removed. Yes Landfill, Sand & Gravel, Acreage uncovered, unbuilt. Soils subject to Automotive Test Tracks 43,924 29,011 frequent disturbance. Yes Acreage uncovered, unbuilt. Soils subject to Agriculture 295,509 130,445 sporadic disturbance. Yes Acreage uncovered, unbuilt. Soils subject to Vacant 2,227,981 472,831 sporadic disturbance. Yes Acreage uncovered, unbuilt. Soils subject to Developing Residential 55,152 50,082 frequent disturbance. Yes Developing NonAcreage uncovered, unbuilt. Soils subject to residential 15,142 14,437 frequent disturbance. Yes 2008 Maricopa Co. PM10 Emission Inventory A4–8 June 2010 Figure A4–4. Distribution of land use categories capable of producing windblown dust emissions. To facilitate the calculation of windblown dust emissions from these land use categories, GIS tools were used to subdivide the land use polygons into smaller, 40-acre cells. This technique allows for the land use acreage in each category to be accurately joined with the wind speed data as represented using Thiessen polygons. Each 40-acre cell is assigned the wind speed bin value of the Thiessen polygon that overlays it. Ultimately, the eligible land use acreage in each cell, combined with the overlaid wind speed values and land use-specific vertical fluxes (emission rates as explained next) produce the windblown dust emissions in each 40-acre cell. Determination of Emission Rates The rate at which soil produces windblown dust emissions can be described as a vertical flux. The two primary components of this vertical flux are: (1) the threshold friction velocity (i.e., the wind speed at which dust emissions are initiated) and (2) the physical characteristics of soils that allow or impede the production of windblown dust (usually termed surface roughness). The equations used to determine vertical flux for the present study have been derived from wind tunnel studies (Nickling and Gillies 1986, 1989) conducted in Maricopa County as well as other parts of Arizona, and that address specific land use categories. 2008 Maricopa Co. PM10 Emission Inventory A4–9 June 2010 These wind tunnel studies resulted in land use-specific vertical flux estimates for a total of five separate land use categories: natural and disturbed desert, fluvial sites, construction sites, mine tailings, and agricultural sites. Table A4–7 below lists the vertical fluxes and the land use categories they are associated with in this analysis. For agriculture land use categories, the vertical flux values used have been applied only to those lands assumed to have been fallow for the entire year. Conversely, emissions generated from activities related to agricultural harvesting are estimated using techniques developed by the U.S. Department of Agriculture (USDA) and discussed later in the text. Table A4–7. Vertical flux rates, by land use category (cf. Nickling and Gillies 1986, 1989). Vertical Flux (in g/cm2-sec)† MAG Land Use Category Landfill, Sand and gravel, Fluvial sites = 1.59 × 10-13u*3.32 Automotive test track facilities Natural desert = 7.99 × 10-13u*2.99 Natural desert = 7.99 × 10-13u*2.99 Passive/restricted open space Agriculture = 3.36 × 10-30U 6.92 Unharvested, fallow agriculture†† Natural desert = 7.99 × 10-13u*2.99 Vacant Developing, residential Construction sites = 5.82 × 10-15u*4.24 Developing, non-residential Construction sites = 5.82 × 10-15u*4.24 † Where u* = threshold friction velocity (in cm/sec). †† Applies only to unharvested agricultural lands; here U is assumed to be equal to that at 10 meters. Category-specific estimates of threshold friction velocity (u*) were developed based on earlier area wind tunnel studies described above (Nickling and Gillies; 1986, 1989). From these studies’ descriptions of the local soil conditions, it became apparent that estimates for some land use categories were apparently based on disturbed soils, while similar estimates for certain other land use categories were clearly values recorded using stabilized soils. In ENVIRON’s work designed to developing a windblown dust model, ENVIRON developed a comparison of threshold friction velocities between disturbed and undisturbed land use categories (WGA, 2006). The resulting ratios have been used to determine threshold friction velocities for both disturbed and undisturbed land use categories for the present study. Table A4–8 below lists the averaged threshold friction velocity values from Nickling and Gillies for each land use category, at a height of 10 meters. Table A4–8. Threshold friction velocities, by land use category and disturbance class. Threshold friction velocity Threshold friction velocity for undisturbed areas for disturbed areas Land Use Category (at 10-m. height, in mph) (at 10-m. height, in mph) Landfill, Sand and Gravel, Automotive Test Tracks 22 * 13 Passive/Restricted Open Space 46 * 22 Unharvested, Fallow Agriculture 40 * 17 Vacant 46 * 22 Developing, Residential 25 12 * Developing, Non-residential 25 12 * *These values have been developed based on the ratio of disturbed vs. undisturbed land use categories as developed by ENVIRON (in WGA, 2006). 2008 Maricopa Co. PM10 Emission Inventory A4–10 June 2010 To determine the percentage of land that was ‘disturbed’ vs. ‘undisturbed’, the appropriate rule effectiveness (RE) rate was applied to the total acreage value. (Appendix 3 provides further details about the rule effectiveness studies conducted for use in developing 2008 emission estimates.) For example, the RE value of 80.87% for sites subject to County Rule 310.01 was then used to determine the ratio of disturbed vs. undisturbed areas for land use categories ‘vacant’ and ‘passive/restricted open space’ 4. Similarly, the Rule 310 RE value (82.99%) was used to apportion disturbed vs. undisturbed acreage for the “Developing” land use categories. To apportion “Landfill, sand and gravel, and test tracks”, either the Rule 316 RE rate of 49.62% (for sand and gravel), or the Rule 310.01 RE rate of 80.87% (for landfills and test tracks) was used. The assignment of disturbed vs. undisturbed acreage for unharvested agriculture acreage is a two-step process: first, the percentage of unharvested acreage is determined (42.88%). This value is then adjusted by the Agricultural Best Management Practices (BMP) RE value (55.33%) to produce a percentage of 19.15% for unharvested, disturbed agricultural acreage. Using the RE values to apportion disturbed and undisturbed lands maximizes the amount of disturbed acreage, as this method assumes that any non-compliant activity at these sites results in disturbed soils. Thus the estimates presented here reflect quite conservative estimates of windblown dust emissions. By applying the vertical flux equations, threshold velocities, and recorded surface roughness values 5, PM10 emission factors for each land use category were developed for each wind speed bin. The midpoint of each wind speed bin (17.5, 22.5, 27.5, and 32.5 mph) was used to develop each bin-specific emission factor 6. Table A4–9 lists the resulting emission factors for each wind speed bin and land use category. Table A4–9. PM10 emission factors by land use type, disturbance status, and wind speed bin category. % of Land PM10 emission factors (in tons/acre-5-minute) Disturbed (“D”) or Land Use Category(ies) 15–20 mph 20–25 mph 25–30 mph 30–35 mph Undisturbed (“U”) Sand and gravel 49.62% (D) n/a* 3.20×10-4 6.23×10-4 1.09×10-3 -4 -4 -4 Sand and gravel 50.38% (U) 1.39×10 3.20×10 6.23×10 1.09×10-3 Passive/restricted open space, Vacant, Landfill and 80.87% (U) n/a* n/a* n/a* n/a* Automotive test tracks Passive/restricted open space, Vacant, Landfill and 19.13% (D) n/a* 7.77×10-4 1.41×10-3 2.33×10-3 Automotive test tracks All other agriculture 80.85% † (U) n/a* n/a* n/a* n/a* Unharvested, fallow agriculture 19.15% (D) 4.73×10-6 2.69×10-5 1.08×10-4 3.43×10-4 All developing 82.99% (U) n/a* n/a* 8.94×10-4 1.82×10-3 All developing 17.01% (D) 1.32×10-4 3.82×10-4 8.94×10-4 1.82×10-3 * “n/a” = Category’s emissions are not generated, as wind speeds are less than threshold friction velocity. See Table A4–8. † Value includes those harvested acres for which emissions have been calculated using a different methodology. 4. The RE rate of 80.87% was used for ‘Vacant’ and ‘Passive/restricted open space’ in the PM10 NAA only. When applied to the county as a whole, the nominal RE rate (90.43%) was halved, since large areas outside the PM10 NAA include areas to which access is quite restricted (e.g., Goldwater Bombing Range, Tonto National Forest); thus the potential to disturb the soil is also limited. 5. Recorded by Nickling and Gillies (1986, 1989) during wind tunnel tests. 6. The fluid dynamics Prandtl equation: 𝑈 = speeds by solving for u*: (𝑢∗ = 𝑈 𝑘 𝑙𝑛 𝑧 𝑧𝑜 𝑢∗ 𝑘 𝑙𝑛 𝑧 𝑧𝑜 allows for the calculation of u* at various 10-meter wind ), where U is wind speed at 10 meters, k is Von Karman’s constant (0.4), z is 10 meters, and zo is measured surface roughness value. 2008 Maricopa Co. PM10 Emission Inventory A4–11 June 2010 By combining the emission rates listed in Table A4–9, information on the land use type(s) and acreage(s) within each 40-acre grid cell, the associated wind speed bin values, and after incorporation of a correction factor for precipitation (as described earlier), emissions of windblown dust have been estimated for each land use category, with the exception of harvested agricultural fields (discussed in further detail below). Estimating Emissions from Harvested Agricultural Areas Windblown dust from harvested agricultural fields has been calculated using a soil erodibility formula developed by the US Department of Agriculture (in EPA, 1974): Es = a I C K L’ V’ where Es equals suspended PM in tons/acre-year, a is a constant (0.0125) representing the portion of PM as PM10, I is soil erodibility, C is a climatic factor, K is surface roughness, L' is unsheltered field width and V' is vegetative cover. Table A4–10 lists the crop-specific values for each variable, and is taken from the 1999 Serious Area PM-10 Plan (MAG, 2000). Table A4–10. Harvested agricultural acreage and default values for USDA equation variables, by crop type. 2008 Crop Acreage a I C K L' V' Es Cotton 18,800 0.0125 63.6 0.318 0.5 0.74 0.7 0.065 Alfalfa 83,000 0.0125 63.6 0.318 1 0.76 0 0 Other hay 4,500 0.0125 63.6 0.318 0.8 0.83 0 0 Wheat 30,100 0.0125 63.6 0.318 0.6 0.77 0 0 Barley 9,900 0.0125 63.6 0.318 0.6 0.77 0 0 Corn 700 0.0125 63.6 0.318 0.6 0.77 0.44 0.051 Potatoes 1,400 0.0125 63.6 0.318 0.8 0.70 0.6 0.085 Sorghum 2,200 0.0125 63.6 0.318 0.6 0.77 0 0 Other vegetables 16,072 0.0125 63.6 0.318 0.6 0.48 0.77 0.056 Citrus 2,124 0.0125 63.6 0.318 0.6 0.48 0.77 0.056 In addition to applying the USDA formula, a control factor of 72.28% was applied to harvested agricultural emission estimates to reflect the effectiveness of the agricultural BMP program. This control factor is a combination of the rule effectiveness of the BMP program (55.33%; see Appendix 3) and the estimated control effectiveness of the BMP program (50.10%) 7, for an overall effectiveness of 27.72%. Summary of Windblown Dust Emissions Estimates Using the emission methodologies listed above, annual PM10 emissions for Maricopa County and the PM10 nonattainment area can be calculated. PM2.5 emissions are assumed to be 10% of PM10 emissions. Daily emissions are obtained by dividing annual emissions by the number of days in calendar year 2008 (i.e., 366). Annual and daily emissions for Maricopa County and the PM10 nonattainment area are shown in Tables A4–11 and A4–12, respectively. 7. Derived from Table 4-2 of the Technical Support Document for Quantification of Agricultural Best Management Practices, prepared for ADEQ by URS and ERG, June 2001. 2008 Maricopa Co. PM10 Emission Inventory A4–12 June 2010 Table A4–11. Annual and daily PM10 and PM2.5 emissions from windblown dust in Maricopa County, by land use category. Annual emissions (tons/yr) Average daily emissions (lbs/day) PM10 PM2.5 PM10 PM2.5 Land use category Agriculture, harvested 1,711.76 171.18 9,353.9 935.4 Agriculture, unharvested 1,349.51 134.95 7,374.4 737.4 Developing 3,334.78 333.48 18,222.8 1,822.3 Landfill, sand and gravel, auto. test tracks 1,646.51 164.65 8,997.3 899.7 Passive/restricted open space 44,174.80 4,417.48 241,392.4 24,139.2 Vacant 60,570.87 6,057.09 330,988.4 33,098.8 Totals: 112,788.23 11,278.82 616,329.1 61,632.9 Table A4–12. Annual and daily PM10 and PM2.5 emissions from windblown dust in the PM10 NAA, by land use category. Annual emissions (tons/yr) Average daily emissions (lbs/day) Land use category PM10 PM2.5 PM10 PM2.5 Agriculture, harvested 755.57 75.56 4,128.8 412.9 Agriculture, unharvested 327.69 32.77 1,790.7 179.1 Developing 2,664.48 266.45 14,560.0 1,456.0 Landfill, sand and gravel, auto. test tracks 1,435.81 143.58 7,845.9 784.6 Passive/restricted open space 3,762.38 376.24 20,559.5 2,056.0 Vacant 9,522.43 952.24 52,035.2 5,203.5 Totals: 18,468.36 1,846.84 100,920.0 10,092.0 References MAG, 2000. Revised MAG 1999 Serious Area Particulate Plan for PM-10 for the Maricopa County Nonattainment Area. Maricopa Association of Governments, Phoenix AZ. February, 2000. Nickling, W. G. and J. A. Gillies, 1986. Table 2.5. Threshold Data for Test Sites. In: Engineering-Science, Refinement of PM10 Emissions Inventory Data for the Maricopa and Pima Planning Areas. EPA Contract 68-02-3888, Work Assignment 69, October, 1987. Nickling, W. G. and J. A. Gillies, 1989. Emissions of Fine-Grained Particulates from Desert Soils. In: Leinen, M. and M. Sarntheim (eds.), Paleoclimatology and Paleometeorology: Modern and Past Patterns of Global Atmospheric Transport. Kluwer Academic Publishing, Dordrecht, 1989. Pulugurtha, S. S. and D. E. James, 2006. Estimating windblown PM-10 emissions from vacant urban land using GIS. Journal of Hazardous Materials, April 2006, 132:1, pp. 47–57. US EPA, 1974. Development of Emission Factors for Fugitive Dust Sources, EPA450/3-74-037, U.S. EPA, Research Triangle Park, NC, June. Updated in September 1988 in Control of Open Fugitive Dust Sources, EPA-450/3-88-008. WGA (Western Governors’ Association), 2006. Open Area Wind Erosion. Chap. 8 In: WRAP Fugitive Dust Handbook, prepared by Countess Environmental, WGA Contract No. 30204– 111, September, 2006. Available at: http://www.wrapair.org/forums/dejf/fdh/index.html. 2008 Maricopa Co. PM10 Emission Inventory A4–13 June 2010 This page intentionally blank. Appendix 5. MOBILE6.2 Inputs, Outputs, and Emission Factors In order to calculate vehicle emission factors for the 2008 annual average day for the PM10 NAA and Maricopa County, two MOBILE6.2 runs were performed for each month as follows: • I/M program in place • No I/M program in place A portion of the MOBILE6.2 input and output files for Maricopa County are provided in this appendix as examples. Scenarios for each facility type were distinguished by average speed and the roadway scenario in the input file. The MOBILE6.2 emission factors (in g/mi) produced by the runs were subsequently weighted together using the appropriate proportions as described in Section 5.5 “Emission factor estimation” in the main report. Table A5–1. Sample of MOBILE6.2 input files. MOBILE6 INPUT FILE : PARTICULATES : RUN DATA STAGE II REFUELING : 94 1 46. 46. I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M I/M PROGRAM MODEL YEARS VEHICLES STRINGENCY COMPLIANCE WAIVER RATES GRACE PERIOD PROGRAM MODEL YEARS VEHICLES STRINGENCY COMPLIANCE WAIVER RATES GRACE PERIOD CUTPOINTS PROGRAM MODEL YEARS VEHICLES COMPLIANCE WAIVER RATES GRACE PERIOD PROGRAM MODEL YEARS VEHICLES STRINGENCY COMPLIANCE WAIVER RATES GRACE PERIOD PROGRAM MODEL YEARS VEHICLES COMPLIANCE WAIVER RATES GRACE PERIOD PROGRAM MODEL YEARS VEHICLES STRINGENCY COMPLIANCE WAIVER RATES GRACE PERIOD PROGRAM MODEL YEARS VEHICLES COMPLIANCE WAIVER RATES GRACE PERIOD : 1 1995 2050 1 T/O LOADED/IDLE : 1 1967 1980 : 1 22222 22222222 2 : 1 37.5 : 1 62.9 : 1 0.709 0.781 : 1 5 : 2 1995 2050 2 T/O IM240 : 2 1981 1995 : 2 22222 11111111 1 : 2 37.5 : 2 70. : 2 0.709 0.781 : 2 5 : 2 CUTPNT08.d : 3 1995 2050 2 T/O FP & GC : 3 1981 1995 : 3 22222 11111111 1 : 3 70. : 3 0.709 0.781 : 3 5 : 4 2002 2050 2 T/O OBD I/M : 4 1996 2050 : 4 22222 11111111 1 : 4 37.5 : 4 91.5 : 4 0.709 0.781 : 4 5 : 5 2002 2050 2 T/O EVAP OBD & GC : 5 1996 2050 : 5 22222 11111111 1 : 5 98.3 : 5 0.709 0.781 : 5 5 : 6 1989 2050 1 T/O LOADED/IDLE : 6 1981 2050 : 6 11111 22222222 2 : 6 37.5 : 6 95.2 : 6 0.709 0.781 : 6 5 : 7 1992 2050 1 T/O GC : 7 1981 2050 : 7 11111 22222222 2 : 7 94.2 : 7 0.709 0.781 : 7 5 ANTI-TAMP PROG : 87 75 80 22222 22222222 2 11 80.7 22111222 ANTI-TAMP PROG : 87 81 03 11111 22222222 2 11 90.7 22111222 REG DIST : 087Reg08.d DIESEL FRACTIONS : 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.0009 0.0006 0.0001 0.0003 0.0006 0.0013 0.0004 0.0004 0.0001 0.0027 0.0032 0.0097 0.0162 2008 Maricopa Co. PM10 Emission Inventory A5–1 June 2010 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0126 0.0126 0.0072 0.0126 0.0126 0.0072 0.1998 0.1998 0.1756 0.6774 0.6774 0.7488 0.8606 0.8606 0.5647 0.4647 0.4647 0.1043 0.6300 0.6300 0.4216 0.8563 0.8563 0.7184 0.9992 0.9992 0.9969 1.0000 1.0000 1.0000 0.9585 0.9585 0.7502 0.0000 0.0000 0.0007 0.0000 0.0000 0.0007 0.0126 0.0126 0.0082 0.0126 0.0126 0.0082 0.1998 0.1998 0.1958 0.6774 0.6774 0.7789 0.8606 0.8606 0.3178 0.4647 0.4647 0.0610 0.6300 0.6300 0.4734 0.8563 0.8563 0.7588 0.9992 0.9992 0.9978 1.0000 1.0000 1.0000 0.9585 0.9585 0.7345 0.0000 0.0000 0.0033 0.0000 0.0000 0.0033 0.0126 0.0126 0.0124 0.0126 0.0126 0.0124 0.1998 0.1998 0.2726 0.6774 0.6774 0.7842 0.8606 0.8606 0.2207 0.4647 0.4647 0.0383 0.6300 0.6300 0.4705 0.8563 0.8563 0.7567 0.9992 0.9992 0.9980 1.0000 1.0000 1.0000 0.9585 0.9585 0.6733 0.0000 0.0000 0.0048 0.0000 0.0000 0.0048 0.0126 0.0110 0.0135 0.0126 0.0110 0.0135 0.1998 0.2578 0.2743 0.6774 0.7710 0.6145 0.8606 0.8473 0.1968 0.4647 0.4384 0.0333 0.6300 0.6078 0.4525 0.8563 0.8443 0.7431 0.9992 0.9989 0.9979 1.0000 1.0000 1.0000 0.9585 0.8857 0.5105 0.0000 0.0000 0.0120 0.0000 0.0000 0.0120 0.0126 0.0111 0.0169 0.0126 0.0111 0.0169 0.1998 0.2510 0.3004 0.6774 0.7910 0.5139 0.8606 0.8048 0.1070 0.4647 0.3670 0.0255 0.6300 0.5246 0.4310 0.8563 0.7943 0.7261 0.9992 0.9987 0.9976 1.0000 1.0000 1.0000 0.9585 0.8525 0.3845 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 0.0126 0.0126 0.0126 0.0126 0.0126 0.0145 0.0110 0.0129 0.0096 0.0083 0.0126 0.0126 0.0126 0.0126 0.0126 0.0145 0.0110 0.0129 0.0096 0.0083 0.1998 0.1998 0.1998 0.1998 0.1998 0.3263 0.2784 0.2963 0.2384 0.2058 0.6774 0.6774 0.6774 0.6774 0.6774 0.8105 0.8068 0.8280 0.8477 0.7940 0.8606 0.8606 0.8606 0.8606 0.8606 0.8331 0.7901 0.7316 0.7275 0.7108 0.4647 0.4647 0.4647 0.4647 0.4647 0.4125 0.3462 0.2771 0.2730 0.2616 0.6300 0.6300 0.6300 0.6300 0.6300 0.5767 0.5289 0.5788 0.5617 0.4537 0.8563 0.8563 0.8563 0.8563 0.8563 0.8266 0.7972 0.8279 0.8177 0.7440 0.9992 0.9992 0.9992 0.9992 0.9992 0.9989 0.9977 0.9984 0.9982 0.9979 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 1.0000 0.9585 0.9585 0.9585 0.9585 0.9585 0.8795 0.9900 0.9105 0.8760 0.7710 ********************** PM10 ************************ ** Rural: Principal Arterial - Interstate SCENARIO RECORD : I/M Rural Principal Arterial - Interstate (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 51.5 Freeway VMT BY FACILITY : allfwy.def FUEL PROGRAM : 2 S ** Rural: Principal Arterial - Other SCENARIO RECORD : I/M Rural Principal Arterial - Other (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 38.1 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Rural: Minor Arterial SCENARIO RECORD : I/M Rural Minor Arterial (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 38.1 Arterial VMT BY FACILITY : allart.def : 2 S FUEL PROGRAM ** Rural: Major Collector SCENARIO RECORD : I/M Rural Major Collector (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 30.3 Arterial 2008 Maricopa Co. PM10 Emission Inventory A5–2 June 2010 VMT BY FACILITY FUEL PROGRAM : allart.def : 2 S ** Rural: Minor Collector SCENARIO RECORD : I/M Rural Minor Collector (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 30.3 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Rural: Local SCENARIO RECORD : I/M Rural Local (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 VMT BY FACILITY : allloc.def FUEL PROGRAM : 2 S ** Urban: Principal Arterial - Interstate SCENARIO RECORD : I/M Urban Principal Arterial - Interstate (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 44.4 Freeway VMT BY FACILITY : allfwy.def FUEL PROGRAM : 2 S ** Urban: Freeways & Expressways SCENARIO RECORD : I/M Urban Freeways & Expressways (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 44.4 Freeway VMT BY FACILITY : allfwy.def FUEL PROGRAM : 2 S ** Urban: Principal Arterial - Other SCENARIO RECORD : I/M Urban Principal Arterial - Other (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 30.1 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Urban: Minor Arterial : I/M Urban Minor Arterial (PM10), July 2008 SCENARIO RECORD PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 30.1 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S 2008 Maricopa Co. PM10 Emission Inventory A5–3 June 2010 ** Urban: Collector SCENARIO RECORD : I/M Urban Collector (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 24.2 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Urban: Local SCENARIO RECORD : I/M Urban Local (PM10), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 10.0 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 VMT BY FACILITY : allloc.def FUEL PROGRAM : 2 S ********************** PM2.5 ************************ ** Rural: Principal Arterial - Interstate SCENARIO RECORD : I/M Rural Principal Arterial - Interstate (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 51.5 Freeway VMT BY FACILITY : allfwy.def FUEL PROGRAM : 2 S ** Rural: Principal Arterial - Other SCENARIO RECORD : I/M Rural Principal Arterial - Other (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 38.1 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Rural: Minor Arterial SCENARIO RECORD : I/M Rural Minor Arterial (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 38.1 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Rural: Major Collector SCENARIO RECORD : I/M Rural Major Collector (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV : 2.5 PARTICLE SIZE DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 30.3 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Rural: Minor Collector 2008 Maricopa Co. PM10 Emission Inventory A5–4 June 2010 SCENARIO RECORD : I/M Rural Minor Collector (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 30.3 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Rural: Local SCENARIO RECORD : I/M Rural Local (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 VMT BY FACILITY : allloc.def FUEL PROGRAM : 2 S ** Urban: Principal Arterial - Interstate SCENARIO RECORD : I/M Urban Principal Arterial - Interstate (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 44.4 Freeway VMT BY FACILITY : allfwy.def FUEL PROGRAM : 2 S ** Urban: Freeways & Expressways SCENARIO RECORD : I/M Urban Freeways & Expressways (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 44.4 Freeway VMT BY FACILITY : allfwy.def FUEL PROGRAM : 2 S ** Urban: Principal Arterial - Other SCENARIO RECORD : I/M Urban Principal Arterial - Other (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 30.1 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Urban: Minor Arterial SCENARIO RECORD : I/M Urban Minor Arterial (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 : 4.20 DIESEL SULFUR CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 30.1 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Urban: Collector SCENARIO RECORD : I/M Urban Collector (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 2008 Maricopa Co. PM10 Emission Inventory A5–5 June 2010 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 AVERAGE SPEED : 24.2 Arterial VMT BY FACILITY : allart.def FUEL PROGRAM : 2 S ** Urban: Local SCENARIO RECORD : I/M Urban Local (PM2.5), July 2008 PARTICULATE EF : PMGZML.CSV PMGDR1.CSV PMGDR2.CSV PMDZML.CSV PMDDR1.CSV PMDDR2.CSV PARTICLE SIZE : 2.5 DIESEL SULFUR : 4.20 CALENDAR YEAR : 2008 EVALUATION MONTH : 7 ALTITUDE : 1 HOURLY TEMPERATURES: 87.0 89.0 92.0 94.0 96.0 99.0 100.0 102.0 103.0 104.0 103.0 103.0 101.0 99.0 97.0 95.0 93.0 91.0 90.0 89.0 88.0 88.0 87.0 86.0 RELATIVE HUMIDITY : 45.0 41.0 37.0 34.0 30.0 27.0 25.0 23.0 22.0 21.0 23.0 23.0 24.0 26.0 30.0 32.0 35.0 38.0 39.0 41.0 42.0 43.0 44.0 46.0 BAROMETRIC PRES : 28.63 FUEL RVP : 7.1 VMT BY FACILITY : allloc.def FUEL PROGRAM : 2 S END OF RUN 2008 Maricopa Co. PM10 Emission Inventory A5–6 June 2010 Table A5–2. Sample of MOBILE6.2 output files. * * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Rural Principal Arterial - Interstate (PM10), July 2008 File 13, Run 1, Scenario 1. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0041 0.0043 0.0043 0.0043 0.0392 ---------------0.0205 0.0052 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0043 0.0048 0.0047 0.0048 0.0410 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0249 0.0253 0.0253 0.0253 0.0622 0.1123 0.0766 0.1721 0.0371 0.0425 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * LDGV # # # # # # # # # # # # # # # # # # # # # # # # # I/M Rural Principal Arterial - Other (PM10), July 2008 File 13, Run 1, Scenario 2. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0041 0.0043 0.0043 0.0043 0.0392 ---------------0.0205 0.0052 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0043 0.0048 0.0047 0.0048 0.0410 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0249 0.0253 0.0253 0.0253 0.0622 0.1123 0.0766 0.1721 0.0371 0.0425 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Rural Minor File 13, Run 1, # # # # # # # # # # # # # # # # # # # # # # # # # Arterial (PM10), July 2008 Scenario 3. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0041 0.0043 0.0043 0.0043 0.0392 ---------------0.0205 0.0052 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0043 0.0048 0.0047 0.0048 0.0410 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0249 0.0253 0.0253 0.0253 0.0622 0.1123 0.0766 0.1721 0.0371 0.0425 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Rural Major File 13, Run 1, # # # # # # # # # # # # # # # # # # # # # # # # # Collector (PM10), July 2008 Scenario 4. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: LDGV LDGT12 LDGT34 2008 Maricopa Co. PM10 Emission Inventory LDGT HDGV LDDV A5–7 LDDT HDDV MC All Veh June 2010 GVWR: <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0041 0.0043 0.0042 0.0043 0.0392 ---------------0.0205 0.0052 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0003 0.0005 0.0005 0.0005 0.0016 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0044 0.0048 0.0047 0.0048 0.0409 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0249 0.0253 0.0253 0.0253 0.0621 0.1123 0.0766 0.1721 0.0371 0.0425 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Rural Minor File 13, Run 1, # # # # # # # # # # # # # # # # # # # # # # # # # Collector (PM10), July 2008 Scenario 5. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0041 0.0043 0.0042 0.0043 0.0392 ---------------0.0205 0.0052 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0003 0.0005 0.0005 0.0005 0.0016 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0044 0.0048 0.0047 0.0048 0.0409 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0249 0.0253 0.0253 0.0253 0.0621 0.1123 0.0766 0.1721 0.0371 0.0425 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Rural Local File 13, Run 1, # # # # # # # # LDGV # # # # # # # # # # # # # # # # # (PM10), July 2008 Scenario 6. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0040 0.0042 0.0042 0.0042 0.0394 ---------------0.0205 0.0051 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0005 0.0006 0.0006 0.0006 0.0012 0.0000 0.0001 0.0003 0.0002 0.0006 Total Exhaust PM: 0.0045 0.0048 0.0048 0.0048 0.0406 0.0918 0.0561 0.1332 0.0207 0.0201 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0250 0.0254 0.0253 0.0254 0.0619 0.1123 0.0766 0.1721 0.0372 0.0426 SO2: 0.0067 0.0087 0.0114 0.0095 0.0167 0.0008 0.0016 0.0037 0.0033 0.0081 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Urban Principal Arterial - Interstate (PM10), July 2008 File 13, Run 1, Scenario 7. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0041 0.0043 0.0043 0.0043 0.0392 ---------------0.0205 0.0052 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0043 0.0048 0.0047 0.0048 0.0410 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0249 0.0253 0.0253 0.0253 0.0622 0.1123 0.0766 0.1721 0.0371 0.0425 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------- 2008 Maricopa Co. PM10 Emission Inventory A5–8 June 2010 * * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Urban Freeways & Expressways (PM10), July 2008 File 13, Run 1, Scenario 8. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0041 0.0043 0.0043 0.0043 0.0392 ---------------0.0205 0.0052 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0043 0.0048 0.0047 0.0048 0.0410 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0249 0.0253 0.0253 0.0253 0.0622 0.1123 0.0766 0.1721 0.0371 0.0425 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * LDGV # # # # # # # # # # # # # # # # # # # # # # # # # I/M Urban Principal Arterial - Other (PM10), July 2008 File 13, Run 1, Scenario 9. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0041 0.0043 0.0042 0.0043 0.0392 ---------------0.0205 0.0052 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0003 0.0005 0.0005 0.0005 0.0016 0.0000 0.0001 0.0003 0.0001 0.0005 Total Exhaust PM: 0.0044 0.0048 0.0047 0.0048 0.0409 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0249 0.0253 0.0253 0.0253 0.0621 0.1123 0.0766 0.1721 0.0371 0.0425 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Urban Minor File 13, Run 1, # # # # # # # # # # # # # # # # # # # # # # # # # Arterial (PM10), July 2008 Scenario 10. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0041 0.0043 0.0042 0.0043 0.0392 ---------------0.0205 0.0052 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0003 0.0005 0.0005 0.0005 0.0016 0.0000 0.0001 0.0003 0.0001 0.0005 Total Exhaust PM: 0.0044 0.0048 0.0047 0.0048 0.0409 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0249 0.0253 0.0253 0.0253 0.0621 0.1123 0.0766 0.1721 0.0371 0.0425 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Urban Collector (PM10), July 2008 File 13, Run 1, Scenario 11. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT <6000 >6000 (All) --------------------VMT Distribution: 0.3626 0.3400 0.1439 2008 Maricopa Co. PM10 Emission Inventory HDGV LDDV LDDT HDDV MC All Veh ------------------------------0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 A5–9 June 2010 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0040 0.0043 0.0042 0.0042 0.0393 ---------------0.0205 0.0051 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0004 0.0006 0.0006 0.0006 0.0014 0.0000 0.0001 0.0003 0.0001 0.0005 Total Exhaust PM: 0.0044 0.0048 0.0048 0.0048 0.0407 0.0918 0.0561 0.1332 0.0206 0.0200 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0250 0.0254 0.0253 0.0254 0.0620 0.1123 0.0766 0.1721 0.0372 0.0425 SO2: 0.0068 0.0087 0.0115 0.0096 0.0167 0.0008 0.0016 0.0037 0.0033 0.0081 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Urban Local File 13, Run 1, # # # # # # # # # # # # # # # # # # # # # # # # # (PM10), July 2008 Scenario 12. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 10.00 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0040 0.0042 0.0042 0.0042 0.0394 ---------------0.0205 0.0051 ECARBON: -------------------------0.0716 0.0230 0.0882 -----0.0095 OCARBON: -------------------------0.0202 0.0330 0.0448 -----0.0049 SO4: 0.0005 0.0006 0.0006 0.0006 0.0012 0.0000 0.0001 0.0003 0.0002 0.0006 Total Exhaust PM: 0.0045 0.0048 0.0048 0.0048 0.0406 0.0918 0.0561 0.1332 0.0207 0.0201 Brake: 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 0.0125 Tire: 0.0080 0.0080 0.0080 0.0080 0.0087 0.0080 0.0080 0.0263 0.0040 0.0100 Total PM: 0.0250 0.0254 0.0253 0.0254 0.0619 0.1123 0.0766 0.1721 0.0372 0.0426 SO2: 0.0067 0.0087 0.0114 0.0095 0.0167 0.0008 0.0016 0.0037 0.0033 0.0081 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Rural Principal Arterial - Interstate (PM2.5), July 2008 File 13, Run 1, Scenario 13. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0038 0.0039 0.0039 0.0039 0.0352 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0040 0.0044 0.0044 0.0044 0.0370 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0117 0.0117 0.0117 0.0445 0.0918 0.0589 0.1345 0.0206 0.0262 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Rural Principal Arterial - Other (PM2.5), July 2008 File 13, Run 1, Scenario 14. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0038 0.0039 0.0039 0.0039 0.0352 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0040 0.0044 0.0044 0.0044 0.0370 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0117 0.0117 0.0117 0.0445 0.0918 0.0589 0.1345 0.0206 0.0262 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* # # # # # # # # # # # # # # # # # # # # # # # # # * I/M Rural Minor Arterial (PM2.5), July 2008 2008 Maricopa Co. PM10 Emission Inventory A5–10 June 2010 * File 13, Run 1, Scenario 15. * # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0038 0.0039 0.0039 0.0039 0.0352 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0040 0.0044 0.0044 0.0044 0.0370 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0117 0.0117 0.0117 0.0445 0.0918 0.0589 0.1345 0.0206 0.0262 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Rural Major File 13, Run 1, # # # # # # # # # # # # # # # # # # # # # # # # # Collector (PM2.5), July 2008 Scenario 16. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0037 0.0039 0.0039 0.0039 0.0353 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0003 0.0005 0.0005 0.0005 0.0016 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0041 0.0044 0.0044 0.0044 0.0369 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0118 0.0117 0.0117 0.0444 0.0918 0.0589 0.1345 0.0206 0.0262 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Rural Minor File 13, Run 1, # # # # # # # # # # # # # # # # # # # # # # # # # Collector (PM2.5), July 2008 Scenario 17. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0037 0.0039 0.0039 0.0039 0.0353 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0003 0.0005 0.0005 0.0005 0.0016 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0041 0.0044 0.0044 0.0044 0.0369 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0118 0.0117 0.0117 0.0444 0.0918 0.0589 0.1345 0.0206 0.0262 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Rural Local File 13, Run 1, # # # # # # # # # # # # # # # # # # # # # # # # # (PM2.5), July 2008 Scenario 18. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 2008 Maricopa Co. PM10 Emission Inventory A5–11 June 2010 GASPM: 0.0036 0.0039 0.0038 0.0039 0.0354 ---------------0.0142 0.0046 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0005 0.0006 0.0006 0.0006 0.0012 0.0000 0.0001 0.0003 0.0002 0.0006 Total Exhaust PM: 0.0042 0.0045 0.0044 0.0045 0.0367 0.0845 0.0516 0.1226 0.0144 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0115 0.0118 0.0118 0.0118 0.0442 0.0918 0.0589 0.1345 0.0207 0.0263 SO2: 0.0067 0.0087 0.0114 0.0095 0.0167 0.0008 0.0016 0.0037 0.0033 0.0081 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Urban Principal Arterial - Interstate (PM2.5), July 2008 File 13, Run 1, Scenario 19. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0038 0.0039 0.0039 0.0039 0.0352 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0040 0.0044 0.0044 0.0044 0.0370 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0117 0.0117 0.0117 0.0445 0.0918 0.0589 0.1345 0.0206 0.0262 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Urban Freeways & Expressways (PM2.5), July 2008 File 13, Run 1, Scenario 20. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0038 0.0039 0.0039 0.0039 0.0352 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0002 0.0005 0.0005 0.0005 0.0018 0.0000 0.0001 0.0003 0.0001 0.0004 Total Exhaust PM: 0.0040 0.0044 0.0044 0.0044 0.0370 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0117 0.0117 0.0117 0.0445 0.0918 0.0589 0.1345 0.0206 0.0262 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Urban Principal Arterial - Other (PM2.5), July 2008 File 13, Run 1, Scenario 21. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0037 0.0039 0.0039 0.0039 0.0353 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0003 0.0005 0.0005 0.0005 0.0016 0.0000 0.0001 0.0003 0.0001 0.0005 Total Exhaust PM: 0.0041 0.0044 0.0044 0.0044 0.0369 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0118 0.0117 0.0117 0.0444 0.0918 0.0589 0.1345 0.0206 0.0262 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Urban Minor File 13, Run 1, # # # # # # # # LDGV # # # # # # # # # # # # # # # # # Arterial (PM2.5), July 2008 Scenario 22. # # # # # # # # # # # # # # # # # 2008 Maricopa Co. PM10 Emission Inventory A5–12 June 2010 Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0037 0.0039 0.0039 0.0039 0.0353 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0003 0.0005 0.0005 0.0005 0.0016 0.0000 0.0001 0.0003 0.0001 0.0005 Total Exhaust PM: 0.0041 0.0044 0.0044 0.0044 0.0369 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0118 0.0117 0.0117 0.0444 0.0918 0.0589 0.1345 0.0206 0.0262 SO2: 0.0068 0.0088 0.0115 0.0096 0.0166 0.0008 0.0016 0.0037 0.0033 0.0082 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # # # # # # # # # # # # # # # # # # I/M Urban Collector (PM2.5), July 2008 File 13, Run 1, Scenario 23. # # # # # # # # # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0037 0.0039 0.0038 0.0039 0.0354 ---------------0.0142 0.0047 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0004 0.0006 0.0006 0.0006 0.0014 0.0000 0.0001 0.0003 0.0001 0.0005 Total Exhaust PM: 0.0041 0.0045 0.0044 0.0044 0.0368 0.0845 0.0516 0.1226 0.0143 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0114 0.0118 0.0117 0.0118 0.0443 0.0918 0.0589 0.1345 0.0207 0.0262 SO2: 0.0068 0.0087 0.0115 0.0096 0.0167 0.0008 0.0016 0.0037 0.0033 0.0081 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------* * * * # # # # # # # # I/M Urban Local File 13, Run 1, # # # # # # # # # # # # # # # # # # # # # # # # # (PM2.5), July 2008 Scenario 24. # # # # # # # # # # # # # # # # # Calendar Year: 2008 Month: July Gasoline Fuel Sulfur Content: 30. ppm Diesel Fuel Sulfur Content: 4. ppm Particle Size Cutoff: 2.50 Microns Reformulated Gas: Yes Vehicle Type: GVWR: LDGV LDGT12 LDGT34 LDGT HDGV LDDV LDDT HDDV MC All Veh <6000 >6000 (All) --------------------------------------------------VMT Distribution: 0.3626 0.3400 0.1439 0.0392 0.0004 0.0022 0.1069 0.0048 1.0000 ----------------------------------------------------------------------------------------------------------------------Composite Emission Factors (g/mi): Lead: 0.0000 0.0000 0.0000 0.0000 0.0000 ---------------0.0000 0.0000 GASPM: 0.0036 0.0039 0.0038 0.0039 0.0354 ---------------0.0142 0.0046 ECARBON: -------------------------0.0658 0.0211 0.0812 -----0.0087 OCARBON: -------------------------0.0186 0.0304 0.0412 -----0.0045 SO4: 0.0005 0.0006 0.0006 0.0006 0.0012 0.0000 0.0001 0.0003 0.0002 0.0006 Total Exhaust PM: 0.0042 0.0045 0.0044 0.0045 0.0367 0.0845 0.0516 0.1226 0.0144 0.0184 Brake: 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 0.0053 Tire: 0.0020 0.0020 0.0020 0.0020 0.0022 0.0020 0.0020 0.0066 0.0010 0.0025 Total PM: 0.0115 0.0118 0.0118 0.0118 0.0442 0.0918 0.0589 0.1345 0.0207 0.0263 SO2: 0.0067 0.0087 0.0114 0.0095 0.0167 0.0008 0.0016 0.0037 0.0033 0.0081 NH3: 0.1017 0.1009 0.1008 0.1009 0.0451 0.0068 0.0068 0.0270 0.0113 0.0904 ----------------------------------------------------------------------------------------------------------------------- 2008 Maricopa Co. PM10 Emission Inventory A5–13 June 2010 Table A5–3. MOBILE6.2 Emission Factors for Maricopa County (by month, in g/mi) January 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.635 0.007 0.102 0.025 0.011 0.586 0.007 0.102 0.025 0.011 0.586 0.007 0.102 0.025 0.011 0.588 0.007 0.102 0.025 0.011 0.588 0.007 0.102 0.025 0.012 0.561 0.007 0.102 0.025 0.011 0.614 0.007 0.102 0.025 0.011 0.614 0.007 0.102 0.025 0.011 0.588 0.007 0.102 0.025 0.011 0.588 0.007 0.102 0.025 0.012 0.616 0.007 0.102 0.025 0.012 0.561 0.007 0.102 LDGT12 0.025 0.012 0.978 0.009 0.101 0.025 0.012 0.915 0.009 0.101 0.025 0.012 0.915 0.009 0.101 0.025 0.012 0.918 0.009 0.101 0.025 0.012 0.918 0.009 0.101 0.025 0.012 0.888 0.009 0.101 0.025 0.012 0.950 0.009 0.101 0.025 0.012 0.950 0.009 0.101 0.025 0.012 0.919 0.009 0.101 0.025 0.012 0.919 0.009 0.101 0.025 0.012 0.959 0.009 0.101 0.025 0.012 0.888 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 1.092 0.012 0.101 0.025 0.012 1.029 0.012 0.101 0.025 0.012 1.029 0.012 0.101 0.025 0.012 1.033 0.012 0.101 0.025 0.012 1.033 0.012 0.101 0.025 0.012 1.005 0.011 0.101 0.025 0.012 1.064 0.012 0.101 0.025 0.012 1.064 0.012 0.101 0.025 0.012 1.034 0.012 0.101 0.025 0.012 1.034 0.012 0.101 0.025 0.012 1.077 0.012 0.101 0.025 0.012 1.005 0.011 0.101 A5–14 HDGV 0.067 0.049 2.588 0.017 0.045 0.067 0.049 2.338 0.017 0.045 0.067 0.049 2.338 0.017 0.045 0.067 0.048 2.198 0.017 0.045 0.067 0.048 2.198 0.017 0.045 0.066 0.048 1.889 0.017 0.045 0.067 0.049 2.452 0.017 0.045 0.067 0.049 2.452 0.017 0.045 0.067 0.048 2.194 0.017 0.045 0.067 0.048 2.194 0.017 0.045 0.066 0.048 2.092 0.017 0.045 0.066 0.048 1.889 0.017 0.045 LDDV 0.116 0.096 0.850 0.003 0.007 0.116 0.096 0.670 0.003 0.007 0.116 0.096 0.670 0.003 0.007 0.116 0.096 0.665 0.003 0.007 0.116 0.096 0.665 0.003 0.007 0.116 0.096 0.883 0.003 0.007 0.116 0.096 0.719 0.003 0.007 0.116 0.096 0.719 0.003 0.007 0.116 0.096 0.665 0.003 0.007 0.116 0.096 0.665 0.003 0.007 0.116 0.096 0.701 0.003 0.007 0.116 0.096 0.883 0.003 0.007 LDDT 0.083 0.065 0.806 0.006 0.007 0.083 0.065 0.633 0.006 0.007 0.083 0.065 0.633 0.006 0.007 0.083 0.065 0.627 0.006 0.007 0.083 0.065 0.627 0.006 0.007 0.083 0.065 0.838 0.006 0.007 0.083 0.065 0.680 0.006 0.007 0.083 0.065 0.680 0.006 0.007 0.083 0.065 0.628 0.006 0.007 0.083 0.065 0.628 0.006 0.007 0.083 0.065 0.662 0.006 0.007 0.083 0.065 0.838 0.006 0.007 HDDV 0.192 0.153 8.196 0.014 0.027 0.192 0.153 5.959 0.014 0.027 0.192 0.153 5.959 0.014 0.027 0.192 0.153 5.911 0.014 0.027 0.192 0.153 5.911 0.014 0.027 0.192 0.153 7.391 0.014 0.027 0.192 0.153 7.025 0.014 0.027 0.192 0.153 7.025 0.014 0.027 0.192 0.153 5.913 0.014 0.027 0.192 0.153 5.913 0.014 0.027 0.192 0.153 6.233 0.014 0.027 0.192 0.153 7.391 0.014 0.027 MC 0.037 0.021 1.930 0.003 0.011 0.037 0.021 1.660 0.003 0.011 0.037 0.021 1.660 0.003 0.011 0.037 0.021 1.580 0.003 0.011 0.037 0.021 1.580 0.003 0.011 0.037 0.021 1.320 0.003 0.011 0.037 0.021 1.710 0.003 0.011 0.037 0.021 1.710 0.003 0.011 0.037 0.021 1.580 0.003 0.011 0.037 0.021 1.580 0.003 0.011 0.037 0.021 1.480 0.003 0.011 0.037 0.021 1.320 0.003 0.011 June 2010 February 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.610 0.007 0.102 0.025 0.011 0.563 0.007 0.102 0.025 0.011 0.563 0.007 0.102 0.025 0.011 0.564 0.007 0.102 0.025 0.011 0.564 0.007 0.102 0.025 0.012 0.538 0.007 0.102 0.025 0.011 0.590 0.007 0.102 0.025 0.011 0.590 0.007 0.102 0.025 0.011 0.565 0.007 0.102 0.025 0.011 0.565 0.007 0.102 0.025 0.012 0.590 0.007 0.102 0.025 0.012 0.538 0.007 0.102 LDGT12 0.025 0.012 0.939 0.009 0.101 0.025 0.012 0.877 0.009 0.101 0.025 0.012 0.877 0.009 0.101 0.025 0.012 0.880 0.009 0.101 0.025 0.012 0.880 0.009 0.101 0.025 0.012 0.850 0.009 0.101 0.025 0.012 0.911 0.009 0.101 0.025 0.012 0.911 0.009 0.101 0.025 0.012 0.880 0.009 0.101 0.025 0.012 0.880 0.009 0.101 0.025 0.012 0.918 0.009 0.101 0.025 0.012 0.850 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 1.048 0.012 0.101 0.025 0.012 0.986 0.012 0.101 0.025 0.012 0.986 0.012 0.101 0.025 0.012 0.990 0.012 0.101 0.025 0.012 0.990 0.012 0.101 0.025 0.012 0.962 0.011 0.101 0.025 0.012 1.021 0.012 0.101 0.025 0.012 1.021 0.012 0.101 0.025 0.012 0.991 0.012 0.101 0.025 0.012 0.991 0.012 0.101 0.025 0.012 1.032 0.012 0.101 0.025 0.012 0.962 0.011 0.101 A5–15 HDGV 0.067 0.049 2.581 0.017 0.045 0.067 0.049 2.332 0.017 0.045 0.067 0.049 2.332 0.017 0.045 0.067 0.048 2.193 0.017 0.045 0.067 0.048 2.193 0.017 0.045 0.066 0.048 1.884 0.017 0.045 0.067 0.049 2.446 0.017 0.045 0.067 0.049 2.446 0.017 0.045 0.067 0.048 2.189 0.017 0.045 0.067 0.048 2.189 0.017 0.045 0.066 0.048 2.086 0.017 0.045 0.066 0.048 1.884 0.017 0.045 LDDV 0.116 0.096 0.850 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.883 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.701 0.001 0.007 0.116 0.096 0.883 0.001 0.007 LDDT 0.083 0.065 0.806 0.002 0.007 0.083 0.065 0.633 0.002 0.007 0.083 0.065 0.633 0.002 0.007 0.083 0.065 0.627 0.002 0.007 0.083 0.065 0.627 0.002 0.007 0.083 0.065 0.838 0.002 0.007 0.083 0.065 0.680 0.002 0.007 0.083 0.065 0.680 0.002 0.007 0.083 0.065 0.628 0.002 0.007 0.083 0.065 0.628 0.002 0.007 0.083 0.065 0.662 0.002 0.007 0.083 0.065 0.838 0.002 0.007 HDDV 0.191 0.152 8.196 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 7.391 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 6.233 0.006 0.027 0.191 0.152 7.391 0.006 0.027 MC 0.037 0.021 1.860 0.003 0.011 0.037 0.021 1.600 0.003 0.011 0.037 0.021 1.600 0.003 0.011 0.037 0.021 1.520 0.003 0.011 0.037 0.021 1.520 0.003 0.011 0.037 0.021 1.270 0.003 0.011 0.037 0.021 1.650 0.003 0.011 0.037 0.021 1.650 0.003 0.011 0.037 0.021 1.520 0.003 0.011 0.037 0.021 1.520 0.003 0.011 0.037 0.021 1.430 0.003 0.011 0.037 0.021 1.270 0.003 0.011 June 2010 March 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.609 0.007 0.102 0.025 0.011 0.567 0.007 0.102 0.025 0.011 0.567 0.007 0.102 0.025 0.011 0.571 0.007 0.102 0.025 0.011 0.571 0.007 0.102 0.025 0.012 0.555 0.007 0.102 0.025 0.011 0.591 0.007 0.102 0.025 0.011 0.591 0.007 0.102 0.025 0.011 0.572 0.007 0.102 0.025 0.011 0.572 0.007 0.102 0.025 0.012 0.600 0.007 0.102 0.025 0.012 0.555 0.007 0.102 LDGT12 0.025 0.012 0.926 0.009 0.101 0.025 0.012 0.868 0.009 0.101 0.025 0.012 0.868 0.009 0.101 0.025 0.012 0.873 0.009 0.101 0.025 0.012 0.873 0.009 0.101 0.025 0.012 0.849 0.009 0.101 0.025 0.012 0.901 0.009 0.101 0.025 0.012 0.901 0.009 0.101 0.025 0.012 0.873 0.009 0.101 0.025 0.012 0.873 0.009 0.101 0.025 0.012 0.911 0.009 0.101 0.025 0.012 0.849 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 1.033 0.012 0.101 0.025 0.012 0.976 0.012 0.101 0.025 0.012 0.976 0.012 0.101 0.025 0.012 0.983 0.012 0.101 0.025 0.012 0.983 0.012 0.101 0.025 0.012 0.961 0.011 0.101 0.025 0.012 1.008 0.012 0.101 0.025 0.012 1.008 0.012 0.101 0.025 0.012 0.983 0.012 0.101 0.025 0.012 0.983 0.012 0.101 0.025 0.012 1.025 0.012 0.101 0.025 0.012 0.961 0.011 0.101 A5–16 HDGV 0.067 0.049 2.543 0.017 0.045 0.067 0.049 2.298 0.017 0.045 0.067 0.049 2.298 0.017 0.045 0.067 0.048 2.160 0.017 0.045 0.067 0.048 2.160 0.017 0.045 0.066 0.048 1.856 0.017 0.045 0.067 0.049 2.410 0.017 0.045 0.067 0.049 2.410 0.017 0.045 0.067 0.048 2.156 0.017 0.045 0.067 0.048 2.156 0.017 0.045 0.066 0.048 2.056 0.017 0.045 0.066 0.048 1.856 0.017 0.045 LDDV 0.116 0.096 0.850 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.883 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.701 0.001 0.007 0.116 0.096 0.883 0.001 0.007 LDDT 0.083 0.065 0.806 0.003 0.007 0.083 0.065 0.633 0.003 0.007 0.083 0.065 0.633 0.003 0.007 0.083 0.065 0.627 0.003 0.007 0.083 0.065 0.627 0.003 0.007 0.083 0.065 0.838 0.003 0.007 0.083 0.065 0.680 0.003 0.007 0.083 0.065 0.680 0.003 0.007 0.083 0.065 0.628 0.003 0.007 0.083 0.065 0.628 0.003 0.007 0.083 0.065 0.662 0.003 0.007 0.083 0.065 0.838 0.003 0.007 HDDV 0.191 0.152 8.196 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 7.391 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 6.233 0.006 0.027 0.191 0.152 7.391 0.006 0.027 MC 0.037 0.021 1.820 0.003 0.011 0.037 0.021 1.570 0.003 0.011 0.037 0.021 1.570 0.003 0.011 0.037 0.021 1.490 0.003 0.011 0.037 0.021 1.490 0.003 0.011 0.037 0.021 1.250 0.003 0.011 0.037 0.021 1.620 0.003 0.011 0.037 0.021 1.620 0.003 0.011 0.037 0.021 1.490 0.003 0.011 0.037 0.021 1.490 0.003 0.011 0.037 0.021 1.400 0.003 0.011 0.037 0.021 1.250 0.003 0.011 June 2010 April 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.608 0.007 0.102 0.025 0.011 0.573 0.007 0.102 0.025 0.011 0.573 0.007 0.102 0.025 0.011 0.582 0.007 0.102 0.025 0.011 0.582 0.007 0.102 0.025 0.012 0.580 0.007 0.102 0.025 0.011 0.593 0.007 0.102 0.025 0.011 0.593 0.007 0.102 0.025 0.011 0.582 0.007 0.102 0.025 0.011 0.582 0.007 0.102 0.025 0.011 0.614 0.007 0.102 0.025 0.012 0.580 0.007 0.102 LDGT12 0.025 0.012 0.945 0.009 0.101 0.025 0.012 0.892 0.009 0.101 0.025 0.012 0.892 0.009 0.101 0.025 0.012 0.897 0.009 0.101 0.025 0.012 0.897 0.009 0.101 0.025 0.012 0.882 0.009 0.101 0.025 0.012 0.922 0.009 0.101 0.025 0.012 0.922 0.009 0.101 0.025 0.012 0.898 0.009 0.101 0.025 0.012 0.898 0.009 0.101 0.025 0.012 0.939 0.009 0.101 0.025 0.012 0.882 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 0.969 0.012 0.101 0.025 0.012 0.920 0.012 0.101 0.025 0.012 0.920 0.012 0.101 0.025 0.012 0.927 0.012 0.101 0.025 0.012 0.927 0.012 0.101 0.025 0.012 0.915 0.011 0.101 0.025 0.012 0.948 0.012 0.101 0.025 0.012 0.948 0.012 0.101 0.025 0.012 0.928 0.012 0.101 0.025 0.012 0.928 0.012 0.101 0.025 0.012 0.968 0.012 0.101 0.025 0.012 0.915 0.011 0.101 A5–17 HDGV 0.062 0.045 2.316 0.017 0.045 0.062 0.045 2.093 0.017 0.045 0.062 0.045 2.093 0.017 0.045 0.062 0.044 1.968 0.017 0.045 0.062 0.044 1.968 0.017 0.045 0.062 0.044 1.691 0.017 0.045 0.062 0.045 2.195 0.017 0.045 0.062 0.045 2.195 0.017 0.045 0.062 0.044 1.964 0.017 0.045 0.062 0.044 1.964 0.017 0.045 0.062 0.044 1.872 0.017 0.045 0.062 0.044 1.691 0.017 0.045 LDDV 0.112 0.092 0.820 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.852 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.676 0.001 0.007 0.112 0.092 0.852 0.001 0.007 LDDT 0.077 0.059 0.736 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.765 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.605 0.002 0.007 0.077 0.059 0.765 0.002 0.007 HDDV 0.172 0.135 7.524 0.006 0.027 0.172 0.135 5.494 0.006 0.027 0.172 0.135 5.494 0.006 0.027 0.172 0.135 5.450 0.006 0.027 0.172 0.135 5.450 0.006 0.027 0.172 0.135 6.851 0.006 0.027 0.172 0.135 6.440 0.006 0.027 0.172 0.135 6.440 0.006 0.027 0.172 0.135 5.452 0.006 0.027 0.172 0.135 5.452 0.006 0.027 0.172 0.135 5.748 0.006 0.027 0.172 0.135 6.851 0.006 0.027 MC 0.037 0.021 1.740 0.003 0.011 0.037 0.021 1.500 0.003 0.011 0.037 0.021 1.500 0.003 0.011 0.037 0.021 1.420 0.003 0.011 0.037 0.021 1.420 0.003 0.011 0.037 0.021 1.190 0.003 0.011 0.037 0.021 1.540 0.003 0.011 0.037 0.021 1.540 0.003 0.011 0.037 0.021 1.420 0.003 0.011 0.037 0.021 1.420 0.003 0.011 0.037 0.021 1.340 0.003 0.011 0.037 0.021 1.190 0.003 0.011 June 2010 May 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.584 0.007 0.102 0.025 0.011 0.553 0.007 0.102 0.025 0.011 0.553 0.007 0.102 0.025 0.011 0.564 0.007 0.102 0.025 0.011 0.564 0.007 0.102 0.025 0.012 0.570 0.007 0.102 0.025 0.011 0.571 0.007 0.102 0.025 0.011 0.571 0.007 0.102 0.025 0.011 0.565 0.007 0.102 0.025 0.011 0.565 0.007 0.102 0.025 0.011 0.599 0.007 0.102 0.025 0.012 0.570 0.007 0.102 LDGT12 0.025 0.012 0.903 0.009 0.101 0.025 0.012 0.851 0.009 0.101 0.025 0.012 0.851 0.009 0.101 0.025 0.012 0.858 0.009 0.101 0.025 0.012 0.858 0.009 0.101 0.025 0.012 0.845 0.009 0.101 0.025 0.012 0.880 0.009 0.101 0.025 0.012 0.880 0.009 0.101 0.025 0.012 0.858 0.009 0.101 0.025 0.012 0.858 0.009 0.101 0.025 0.012 0.898 0.009 0.101 0.025 0.012 0.845 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 0.925 0.012 0.101 0.025 0.012 0.877 0.012 0.101 0.025 0.012 0.877 0.012 0.101 0.025 0.012 0.885 0.012 0.101 0.025 0.012 0.885 0.012 0.101 0.025 0.012 0.876 0.011 0.101 0.025 0.012 0.904 0.012 0.101 0.025 0.012 0.904 0.012 0.101 0.025 0.012 0.885 0.012 0.101 0.025 0.012 0.885 0.012 0.101 0.025 0.012 0.927 0.012 0.101 0.025 0.012 0.876 0.011 0.101 A5–18 HDGV 0.062 0.045 2.344 0.017 0.045 0.062 0.045 2.118 0.017 0.045 0.062 0.045 2.118 0.017 0.045 0.062 0.044 1.991 0.017 0.045 0.062 0.044 1.991 0.017 0.045 0.062 0.044 1.711 0.017 0.045 0.062 0.045 2.221 0.017 0.045 0.062 0.045 2.221 0.017 0.045 0.062 0.044 1.987 0.017 0.045 0.062 0.044 1.987 0.017 0.045 0.062 0.044 1.895 0.017 0.045 0.062 0.044 1.711 0.017 0.045 LDDV 0.112 0.092 0.820 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.852 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.676 0.001 0.007 0.112 0.092 0.852 0.001 0.007 LDDT 0.077 0.059 0.736 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.765 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.605 0.002 0.007 0.077 0.059 0.765 0.002 0.007 HDDV 0.172 0.135 7.524 0.005 0.027 0.172 0.135 5.494 0.005 0.027 0.172 0.135 5.494 0.005 0.027 0.172 0.135 5.450 0.005 0.027 0.172 0.135 5.450 0.005 0.027 0.172 0.135 6.851 0.005 0.027 0.172 0.135 6.440 0.005 0.027 0.172 0.135 6.440 0.005 0.027 0.172 0.135 5.452 0.005 0.027 0.172 0.135 5.452 0.005 0.027 0.172 0.135 5.748 0.005 0.027 0.172 0.135 6.851 0.005 0.027 MC 0.037 0.021 1.610 0.003 0.011 0.037 0.021 1.390 0.003 0.011 0.037 0.021 1.390 0.003 0.011 0.037 0.021 1.320 0.003 0.011 0.037 0.021 1.320 0.003 0.011 0.037 0.021 1.100 0.003 0.011 0.037 0.021 1.430 0.003 0.011 0.037 0.021 1.430 0.003 0.011 0.037 0.021 1.310 0.003 0.011 0.037 0.021 1.310 0.003 0.011 0.037 0.021 1.240 0.003 0.011 0.037 0.021 1.100 0.003 0.011 June 2010 June 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.636 0.007 0.102 0.025 0.011 0.612 0.007 0.102 0.025 0.011 0.612 0.007 0.102 0.025 0.011 0.631 0.007 0.102 0.025 0.011 0.631 0.007 0.102 0.025 0.012 0.663 0.007 0.102 0.025 0.011 0.625 0.007 0.102 0.025 0.011 0.625 0.007 0.102 0.025 0.011 0.632 0.007 0.102 0.025 0.011 0.632 0.007 0.102 0.025 0.011 0.677 0.007 0.102 0.025 0.012 0.663 0.007 0.102 LDGT12 0.025 0.012 0.953 0.009 0.101 0.025 0.012 0.902 0.009 0.101 0.025 0.012 0.902 0.009 0.101 0.025 0.012 0.912 0.009 0.101 0.025 0.012 0.912 0.009 0.101 0.025 0.012 0.911 0.009 0.101 0.025 0.012 0.931 0.009 0.101 0.025 0.012 0.931 0.009 0.101 0.025 0.012 0.913 0.009 0.101 0.025 0.012 0.913 0.009 0.101 0.025 0.012 0.959 0.009 0.101 0.025 0.012 0.911 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 0.976 0.012 0.101 0.025 0.012 0.930 0.012 0.101 0.025 0.012 0.930 0.012 0.101 0.025 0.012 0.942 0.012 0.101 0.025 0.012 0.942 0.012 0.101 0.025 0.012 0.945 0.011 0.101 0.025 0.012 0.957 0.012 0.101 0.025 0.012 0.957 0.012 0.101 0.025 0.012 0.943 0.012 0.101 0.025 0.012 0.943 0.012 0.101 0.025 0.012 0.989 0.012 0.101 0.025 0.012 0.945 0.011 0.101 A5–19 HDGV 0.062 0.045 2.309 0.017 0.045 0.062 0.045 2.086 0.017 0.045 0.062 0.045 2.086 0.017 0.045 0.062 0.044 1.961 0.017 0.045 0.062 0.044 1.961 0.017 0.045 0.062 0.044 1.685 0.017 0.045 0.062 0.045 2.188 0.017 0.045 0.062 0.045 2.188 0.017 0.045 0.062 0.044 1.957 0.017 0.045 0.062 0.044 1.957 0.017 0.045 0.062 0.044 1.866 0.017 0.045 0.062 0.044 1.685 0.017 0.045 LDDV 0.112 0.092 0.820 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.852 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.676 0.001 0.007 0.112 0.092 0.852 0.001 0.007 LDDT 0.077 0.059 0.736 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.765 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.605 0.002 0.007 0.077 0.059 0.765 0.002 0.007 HDDV 0.172 0.135 7.524 0.005 0.027 0.172 0.135 5.494 0.005 0.027 0.172 0.135 5.494 0.005 0.027 0.172 0.135 5.450 0.005 0.027 0.172 0.135 5.450 0.005 0.027 0.172 0.135 6.851 0.005 0.027 0.172 0.135 6.440 0.005 0.027 0.172 0.135 6.440 0.005 0.027 0.172 0.135 5.452 0.005 0.027 0.172 0.135 5.452 0.005 0.027 0.172 0.135 5.748 0.005 0.027 0.172 0.135 6.851 0.005 0.027 MC 0.037 0.021 1.400 0.003 0.011 0.037 0.021 1.210 0.003 0.011 0.037 0.021 1.210 0.003 0.011 0.037 0.021 1.150 0.003 0.011 0.037 0.021 1.150 0.003 0.011 0.037 0.021 0.960 0.003 0.011 0.037 0.021 1.240 0.003 0.011 0.037 0.021 1.240 0.003 0.011 0.037 0.021 1.140 0.003 0.011 0.037 0.021 1.140 0.003 0.011 0.037 0.021 1.080 0.003 0.011 0.037 0.021 0.960 0.003 0.011 June 2010 July 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.560 0.007 0.102 0.025 0.011 0.539 0.007 0.102 0.025 0.011 0.539 0.007 0.102 0.025 0.011 0.557 0.007 0.102 0.025 0.011 0.557 0.007 0.102 0.025 0.012 0.590 0.007 0.102 0.025 0.011 0.551 0.007 0.102 0.025 0.011 0.551 0.007 0.102 0.025 0.011 0.558 0.007 0.102 0.025 0.011 0.558 0.007 0.102 0.025 0.011 0.602 0.007 0.102 0.025 0.012 0.590 0.007 0.102 LDGT12 0.025 0.012 0.832 0.009 0.101 0.025 0.012 0.784 0.009 0.101 0.025 0.012 0.784 0.009 0.101 0.025 0.012 0.793 0.009 0.101 0.025 0.012 0.793 0.009 0.101 0.025 0.012 0.791 0.009 0.101 0.025 0.012 0.811 0.009 0.101 0.025 0.012 0.811 0.009 0.101 0.025 0.012 0.794 0.009 0.101 0.025 0.012 0.794 0.009 0.101 0.025 0.012 0.836 0.009 0.101 0.025 0.012 0.791 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 0.852 0.012 0.101 0.025 0.012 0.809 0.012 0.101 0.025 0.012 0.809 0.012 0.101 0.025 0.012 0.819 0.012 0.101 0.025 0.012 0.819 0.012 0.101 0.025 0.012 0.821 0.011 0.101 0.025 0.012 0.834 0.012 0.101 0.025 0.012 0.834 0.012 0.101 0.025 0.012 0.820 0.012 0.101 0.025 0.012 0.820 0.012 0.101 0.025 0.012 0.863 0.012 0.101 0.025 0.012 0.821 0.011 0.101 A5–20 HDGV 0.062 0.045 2.309 0.017 0.045 0.062 0.045 2.086 0.017 0.045 0.062 0.045 2.086 0.017 0.045 0.062 0.044 1.961 0.017 0.045 0.062 0.044 1.961 0.017 0.045 0.062 0.044 1.685 0.017 0.045 0.062 0.045 2.188 0.017 0.045 0.062 0.045 2.188 0.017 0.045 0.062 0.044 1.957 0.017 0.045 0.062 0.044 1.957 0.017 0.045 0.062 0.044 1.866 0.017 0.045 0.062 0.044 1.685 0.017 0.045 LDDV 0.112 0.092 0.820 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.852 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.676 0.001 0.007 0.112 0.092 0.852 0.001 0.007 LDDT 0.077 0.059 0.736 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.765 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.605 0.002 0.007 0.077 0.059 0.765 0.002 0.007 HDDV 0.172 0.135 7.524 0.004 0.027 0.172 0.135 5.494 0.004 0.027 0.172 0.135 5.494 0.004 0.027 0.172 0.135 5.450 0.004 0.027 0.172 0.135 5.450 0.004 0.027 0.172 0.135 6.851 0.004 0.027 0.172 0.135 6.440 0.004 0.027 0.172 0.135 6.440 0.004 0.027 0.172 0.135 5.452 0.004 0.027 0.172 0.135 5.452 0.004 0.027 0.172 0.135 5.748 0.004 0.027 0.172 0.135 6.851 0.004 0.027 MC 0.037 0.021 1.180 0.003 0.011 0.037 0.021 1.020 0.003 0.011 0.037 0.021 1.020 0.003 0.011 0.037 0.021 0.970 0.003 0.011 0.037 0.021 0.970 0.003 0.011 0.037 0.021 0.820 0.003 0.011 0.037 0.021 1.050 0.003 0.011 0.037 0.021 1.050 0.003 0.011 0.037 0.021 0.970 0.003 0.011 0.037 0.021 0.970 0.003 0.011 0.037 0.021 0.910 0.003 0.011 0.037 0.021 0.820 0.003 0.011 June 2010 August 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.547 0.007 0.102 0.025 0.011 0.525 0.007 0.102 0.025 0.011 0.525 0.007 0.102 0.025 0.011 0.543 0.007 0.102 0.025 0.011 0.543 0.007 0.102 0.025 0.012 0.574 0.007 0.102 0.025 0.011 0.538 0.007 0.102 0.025 0.011 0.538 0.007 0.102 0.025 0.011 0.544 0.007 0.102 0.025 0.011 0.544 0.007 0.102 0.025 0.011 0.587 0.007 0.102 0.025 0.012 0.574 0.007 0.102 LDGT12 0.025 0.012 0.813 0.009 0.101 0.025 0.012 0.764 0.009 0.101 0.025 0.012 0.764 0.009 0.101 0.025 0.012 0.774 0.009 0.101 0.025 0.012 0.774 0.009 0.101 0.025 0.012 0.771 0.009 0.101 0.025 0.012 0.792 0.009 0.101 0.025 0.012 0.792 0.009 0.101 0.025 0.012 0.775 0.009 0.101 0.025 0.012 0.775 0.009 0.101 0.025 0.012 0.816 0.009 0.101 0.025 0.012 0.771 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 0.833 0.012 0.101 0.025 0.012 0.789 0.012 0.101 0.025 0.012 0.789 0.012 0.101 0.025 0.012 0.799 0.012 0.101 0.025 0.012 0.799 0.012 0.101 0.025 0.012 0.801 0.011 0.101 0.025 0.012 0.814 0.012 0.101 0.025 0.012 0.814 0.012 0.101 0.025 0.012 0.800 0.012 0.101 0.025 0.012 0.800 0.012 0.101 0.025 0.012 0.842 0.012 0.101 0.025 0.012 0.801 0.011 0.101 A5–21 HDGV 0.062 0.045 2.307 0.017 0.045 0.062 0.045 2.084 0.017 0.045 0.062 0.045 2.084 0.017 0.045 0.062 0.044 1.959 0.017 0.045 0.062 0.044 1.959 0.017 0.045 0.062 0.044 1.684 0.017 0.045 0.062 0.045 2.186 0.017 0.045 0.062 0.045 2.186 0.017 0.045 0.062 0.044 1.956 0.017 0.045 0.062 0.044 1.956 0.017 0.045 0.062 0.044 1.864 0.017 0.045 0.062 0.044 1.684 0.017 0.045 LDDV 0.112 0.092 0.820 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.852 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.676 0.001 0.007 0.112 0.092 0.852 0.001 0.007 LDDT 0.077 0.059 0.736 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.765 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.605 0.002 0.007 0.077 0.059 0.765 0.002 0.007 HDDV 0.172 0.135 7.524 0.006 0.027 0.172 0.135 5.494 0.006 0.027 0.172 0.135 5.494 0.006 0.027 0.172 0.135 5.450 0.006 0.027 0.172 0.135 5.450 0.006 0.027 0.172 0.135 6.851 0.006 0.027 0.172 0.135 6.440 0.006 0.027 0.172 0.135 6.440 0.006 0.027 0.172 0.135 5.452 0.006 0.027 0.172 0.135 5.452 0.006 0.027 0.172 0.135 5.748 0.006 0.027 0.172 0.135 6.851 0.006 0.027 MC 0.037 0.021 1.170 0.003 0.011 0.037 0.021 1.020 0.003 0.011 0.037 0.021 1.020 0.003 0.011 0.037 0.021 0.960 0.003 0.011 0.037 0.021 0.960 0.003 0.011 0.037 0.021 0.810 0.003 0.011 0.037 0.021 1.050 0.003 0.011 0.037 0.021 1.050 0.003 0.011 0.037 0.021 0.960 0.003 0.011 0.037 0.021 0.960 0.003 0.011 0.037 0.021 0.910 0.003 0.011 0.037 0.021 0.810 0.003 0.011 June 2010 September 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.582 0.007 0.102 0.025 0.011 0.558 0.007 0.102 0.025 0.011 0.558 0.007 0.102 0.025 0.011 0.575 0.007 0.102 0.025 0.011 0.575 0.007 0.102 0.025 0.012 0.600 0.007 0.102 0.025 0.011 0.571 0.007 0.102 0.025 0.011 0.571 0.007 0.102 0.025 0.011 0.576 0.007 0.102 0.025 0.011 0.576 0.007 0.102 0.025 0.011 0.617 0.007 0.102 0.025 0.012 0.600 0.007 0.102 LDGT12 0.025 0.012 0.874 0.009 0.101 0.025 0.012 0.824 0.009 0.101 0.025 0.012 0.824 0.009 0.101 0.025 0.012 0.833 0.009 0.101 0.025 0.012 0.833 0.009 0.101 0.025 0.012 0.828 0.009 0.101 0.025 0.012 0.852 0.009 0.101 0.025 0.012 0.852 0.009 0.101 0.025 0.012 0.834 0.009 0.101 0.025 0.012 0.834 0.009 0.101 0.025 0.012 0.877 0.009 0.101 0.025 0.012 0.828 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 0.895 0.012 0.101 0.025 0.012 0.850 0.012 0.101 0.025 0.012 0.850 0.012 0.101 0.025 0.012 0.860 0.012 0.101 0.025 0.012 0.860 0.012 0.101 0.025 0.012 0.859 0.011 0.101 0.025 0.012 0.876 0.012 0.101 0.025 0.012 0.876 0.012 0.101 0.025 0.012 0.860 0.012 0.101 0.025 0.012 0.860 0.012 0.101 0.025 0.012 0.903 0.012 0.101 0.025 0.012 0.859 0.011 0.101 A5–22 HDGV 0.062 0.045 2.304 0.017 0.045 0.062 0.045 2.082 0.017 0.045 0.062 0.045 2.082 0.017 0.045 0.062 0.044 1.957 0.017 0.045 0.062 0.044 1.957 0.017 0.045 0.062 0.044 1.682 0.017 0.045 0.062 0.045 2.183 0.017 0.045 0.062 0.045 2.183 0.017 0.045 0.062 0.044 1.953 0.017 0.045 0.062 0.044 1.953 0.017 0.045 0.062 0.044 1.862 0.017 0.045 0.062 0.044 1.682 0.017 0.045 LDDV 0.112 0.092 0.820 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.646 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.852 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.693 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.641 0.001 0.007 0.112 0.092 0.676 0.001 0.007 0.112 0.092 0.852 0.001 0.007 LDDT 0.077 0.059 0.736 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.578 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.765 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.621 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.573 0.002 0.007 0.077 0.059 0.605 0.002 0.007 0.077 0.059 0.765 0.002 0.007 HDDV 0.172 0.135 7.524 0.006 0.027 0.172 0.135 5.494 0.006 0.027 0.172 0.135 5.494 0.006 0.027 0.172 0.135 5.450 0.006 0.027 0.172 0.135 5.450 0.006 0.027 0.172 0.135 6.851 0.006 0.027 0.172 0.135 6.440 0.006 0.027 0.172 0.135 6.440 0.006 0.027 0.172 0.135 5.452 0.006 0.027 0.172 0.135 5.452 0.006 0.027 0.172 0.135 5.748 0.006 0.027 0.172 0.135 6.851 0.006 0.027 MC 0.037 0.021 1.340 0.003 0.011 0.037 0.021 1.150 0.003 0.011 0.037 0.021 1.150 0.003 0.011 0.037 0.021 1.100 0.003 0.011 0.037 0.021 1.100 0.003 0.011 0.037 0.021 0.920 0.003 0.011 0.037 0.021 1.190 0.003 0.011 0.037 0.021 1.190 0.003 0.011 0.037 0.021 1.090 0.003 0.011 0.037 0.021 1.090 0.003 0.011 0.037 0.021 1.030 0.003 0.011 0.037 0.021 0.920 0.003 0.011 June 2010 October 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.605 0.007 0.102 0.025 0.011 0.571 0.007 0.102 0.025 0.011 0.571 0.007 0.102 0.025 0.011 0.582 0.007 0.102 0.025 0.011 0.582 0.007 0.102 0.025 0.012 0.586 0.007 0.102 0.025 0.011 0.590 0.007 0.102 0.025 0.011 0.590 0.007 0.102 0.025 0.011 0.582 0.007 0.102 0.025 0.011 0.582 0.007 0.102 0.025 0.012 0.617 0.007 0.102 0.025 0.012 0.586 0.007 0.102 LDGT12 0.025 0.012 0.900 0.009 0.101 0.025 0.012 0.847 0.009 0.101 0.025 0.012 0.847 0.009 0.101 0.025 0.012 0.854 0.009 0.101 0.025 0.012 0.854 0.009 0.101 0.025 0.012 0.839 0.009 0.101 0.025 0.012 0.877 0.009 0.101 0.025 0.012 0.877 0.009 0.101 0.025 0.012 0.854 0.009 0.101 0.025 0.012 0.854 0.009 0.101 0.025 0.012 0.895 0.009 0.101 0.025 0.012 0.839 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 1.005 0.012 0.101 0.025 0.012 0.953 0.012 0.101 0.025 0.012 0.953 0.012 0.101 0.025 0.012 0.961 0.012 0.101 0.025 0.012 0.961 0.012 0.101 0.025 0.012 0.950 0.011 0.101 0.025 0.012 0.983 0.012 0.101 0.025 0.012 0.983 0.012 0.101 0.025 0.012 0.962 0.012 0.101 0.025 0.012 0.962 0.012 0.101 0.025 0.012 1.007 0.012 0.101 0.025 0.012 0.950 0.011 0.101 A5–23 HDGV 0.067 0.049 2.556 0.017 0.045 0.067 0.049 2.309 0.017 0.045 0.067 0.049 2.309 0.017 0.045 0.067 0.048 2.171 0.017 0.045 0.067 0.048 2.171 0.017 0.045 0.066 0.048 1.866 0.017 0.045 0.067 0.049 2.422 0.017 0.045 0.067 0.049 2.422 0.017 0.045 0.067 0.048 2.167 0.017 0.045 0.067 0.048 2.167 0.017 0.045 0.066 0.048 2.066 0.017 0.045 0.066 0.048 1.866 0.017 0.045 LDDV 0.116 0.096 0.850 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.883 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.701 0.001 0.007 0.116 0.096 0.883 0.001 0.007 LDDT 0.083 0.065 0.806 0.002 0.007 0.083 0.065 0.633 0.002 0.007 0.083 0.065 0.633 0.002 0.007 0.083 0.065 0.627 0.002 0.007 0.083 0.065 0.627 0.002 0.007 0.083 0.065 0.838 0.002 0.007 0.083 0.065 0.680 0.002 0.007 0.083 0.065 0.680 0.002 0.007 0.083 0.065 0.628 0.002 0.007 0.083 0.065 0.628 0.002 0.007 0.083 0.065 0.662 0.002 0.007 0.083 0.065 0.838 0.002 0.007 HDDV 0.191 0.152 8.196 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 7.391 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 6.233 0.006 0.027 0.191 0.152 7.391 0.006 0.027 MC 0.037 0.021 1.630 0.003 0.011 0.037 0.021 1.410 0.003 0.011 0.037 0.021 1.410 0.003 0.011 0.037 0.021 1.330 0.003 0.011 0.037 0.021 1.330 0.003 0.011 0.037 0.021 1.120 0.003 0.011 0.037 0.021 1.450 0.003 0.011 0.037 0.021 1.450 0.003 0.011 0.037 0.021 1.330 0.003 0.011 0.037 0.021 1.330 0.003 0.011 0.037 0.021 1.250 0.003 0.011 0.037 0.021 1.120 0.003 0.011 June 2010 November 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.590 0.007 0.102 0.025 0.011 0.548 0.007 0.102 0.025 0.011 0.548 0.007 0.102 0.025 0.011 0.552 0.007 0.102 0.025 0.011 0.552 0.007 0.102 0.025 0.012 0.534 0.007 0.102 0.025 0.011 0.572 0.007 0.102 0.025 0.011 0.572 0.007 0.102 0.025 0.011 0.552 0.007 0.102 0.025 0.011 0.552 0.007 0.102 0.025 0.012 0.579 0.007 0.102 0.025 0.012 0.534 0.007 0.102 LDGT12 0.025 0.012 0.898 0.009 0.101 0.025 0.012 0.840 0.009 0.101 0.025 0.012 0.840 0.009 0.101 0.025 0.012 0.844 0.009 0.101 0.025 0.012 0.844 0.009 0.101 0.025 0.012 0.819 0.009 0.101 0.025 0.012 0.872 0.009 0.101 0.025 0.012 0.872 0.009 0.101 0.025 0.012 0.845 0.009 0.101 0.025 0.012 0.845 0.009 0.101 0.025 0.012 0.882 0.009 0.101 0.025 0.012 0.819 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 1.002 0.012 0.101 0.025 0.012 0.945 0.012 0.101 0.025 0.012 0.945 0.012 0.101 0.025 0.012 0.950 0.012 0.101 0.025 0.012 0.950 0.012 0.101 0.025 0.012 0.928 0.011 0.101 0.025 0.012 0.978 0.012 0.101 0.025 0.012 0.978 0.012 0.101 0.025 0.012 0.951 0.012 0.101 0.025 0.012 0.951 0.012 0.101 0.025 0.012 0.993 0.012 0.101 0.025 0.012 0.928 0.011 0.101 A5–24 HDGV 0.067 0.049 2.542 0.017 0.045 0.067 0.049 2.297 0.017 0.045 0.067 0.049 2.297 0.017 0.045 0.067 0.048 2.159 0.017 0.045 0.067 0.048 2.159 0.017 0.045 0.066 0.048 1.855 0.017 0.045 0.067 0.049 2.409 0.017 0.045 0.067 0.049 2.409 0.017 0.045 0.067 0.048 2.155 0.017 0.045 0.067 0.048 2.155 0.017 0.045 0.066 0.048 2.055 0.017 0.045 0.066 0.048 1.855 0.017 0.045 LDDV 0.116 0.096 0.850 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.883 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.701 0.001 0.007 0.116 0.096 0.883 0.001 0.007 LDDT 0.083 0.065 0.806 0.002 0.007 0.083 0.065 0.633 0.002 0.007 0.083 0.065 0.633 0.002 0.007 0.083 0.065 0.627 0.002 0.007 0.083 0.065 0.627 0.002 0.007 0.083 0.065 0.838 0.002 0.007 0.083 0.065 0.680 0.002 0.007 0.083 0.065 0.680 0.002 0.007 0.083 0.065 0.628 0.002 0.007 0.083 0.065 0.628 0.002 0.007 0.083 0.065 0.662 0.002 0.007 0.083 0.065 0.838 0.002 0.007 HDDV 0.191 0.152 8.196 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 7.391 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 6.233 0.006 0.027 0.191 0.152 7.391 0.006 0.027 MC 0.037 0.021 1.770 0.003 0.011 0.037 0.021 1.530 0.003 0.011 0.037 0.021 1.530 0.003 0.011 0.037 0.021 1.450 0.003 0.011 0.037 0.021 1.450 0.003 0.011 0.037 0.021 1.210 0.003 0.011 0.037 0.021 1.570 0.003 0.011 0.037 0.021 1.570 0.003 0.011 0.037 0.021 1.450 0.003 0.011 0.037 0.021 1.450 0.003 0.011 0.037 0.021 1.360 0.003 0.011 0.037 0.021 1.210 0.003 0.011 June 2010 December 2008 (Weighted by 91.6% of I/M and 8.4% of Non-I/M) Facility Type Rural Principal Arterial – Interstate Rural Principal Arterial – Other Rural Minor Arterial Rural Major Collector Rural Minor Collector Rural Local Urban Principal Arterial – Interstate Urban Freeway & Expressway Urban Principal Arterial – Other Urban Minor Arterial Urban Collector Urban Local Pollutant PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 PM10 PM2.5 NOx SOx NH3 LDGV 0.025 0.011 0.623 0.007 0.102 0.025 0.011 0.575 0.007 0.102 0.025 0.011 0.575 0.007 0.102 0.025 0.011 0.576 0.007 0.102 0.025 0.011 0.576 0.007 0.102 0.025 0.012 0.550 0.007 0.102 0.025 0.011 0.602 0.007 0.102 0.025 0.011 0.602 0.007 0.102 0.025 0.011 0.577 0.007 0.102 0.025 0.011 0.577 0.007 0.102 0.025 0.012 0.603 0.007 0.102 0.025 0.012 0.550 0.007 0.102 LDGT12 0.025 0.012 0.959 0.009 0.101 0.025 0.012 0.897 0.009 0.101 0.025 0.012 0.897 0.009 0.101 0.025 0.012 0.899 0.009 0.101 0.025 0.012 0.899 0.009 0.101 0.025 0.012 0.869 0.009 0.101 0.025 0.012 0.931 0.009 0.101 0.025 0.012 0.931 0.009 0.101 0.025 0.012 0.900 0.009 0.101 0.025 0.012 0.900 0.009 0.101 0.025 0.012 0.938 0.009 0.101 0.025 0.012 0.869 0.009 0.101 2008 Maricopa Co. PM10 Emission Inventory LDGT34 0.025 0.012 1.070 0.012 0.101 0.025 0.012 1.008 0.012 0.101 0.025 0.012 1.008 0.012 0.101 0.025 0.012 1.012 0.012 0.101 0.025 0.012 1.012 0.012 0.101 0.025 0.012 0.984 0.011 0.101 0.025 0.012 1.043 0.012 0.101 0.025 0.012 1.043 0.012 0.101 0.025 0.012 1.013 0.012 0.101 0.025 0.012 1.013 0.012 0.101 0.025 0.012 1.055 0.012 0.101 0.025 0.012 0.984 0.011 0.101 A5–25 HDGV 0.067 0.049 2.592 0.017 0.045 0.067 0.049 2.342 0.017 0.045 0.067 0.049 2.342 0.017 0.045 0.067 0.048 2.202 0.017 0.045 0.067 0.048 2.202 0.017 0.045 0.066 0.048 1.892 0.017 0.045 0.067 0.049 2.457 0.017 0.045 0.067 0.049 2.457 0.017 0.045 0.067 0.048 2.198 0.017 0.045 0.067 0.048 2.198 0.017 0.045 0.066 0.048 2.095 0.017 0.045 0.066 0.048 1.892 0.017 0.045 LDDV 0.116 0.096 0.850 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.670 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.883 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.719 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.665 0.001 0.007 0.116 0.096 0.701 0.001 0.007 0.116 0.096 0.883 0.001 0.007 LDDT 0.083 0.065 0.806 0.003 0.007 0.083 0.065 0.633 0.003 0.007 0.083 0.065 0.633 0.003 0.007 0.083 0.065 0.627 0.003 0.007 0.083 0.065 0.627 0.003 0.007 0.083 0.065 0.838 0.003 0.007 0.083 0.065 0.680 0.003 0.007 0.083 0.065 0.680 0.003 0.007 0.083 0.065 0.628 0.003 0.007 0.083 0.065 0.628 0.003 0.007 0.083 0.065 0.662 0.003 0.007 0.083 0.065 0.838 0.003 0.007 HDDV 0.191 0.152 8.196 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.959 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 5.911 0.006 0.027 0.191 0.152 7.391 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 7.025 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 5.913 0.006 0.027 0.191 0.152 6.233 0.006 0.027 0.191 0.152 7.391 0.006 0.027 MC 0.037 0.021 1.890 0.003 0.011 0.037 0.021 1.630 0.003 0.011 0.037 0.021 1.630 0.003 0.011 0.037 0.021 1.550 0.003 0.011 0.037 0.021 1.550 0.003 0.011 0.037 0.021 1.300 0.003 0.011 0.037 0.021 1.680 0.003 0.011 0.037 0.021 1.680 0.003 0.011 0.037 0.021 1.550 0.003 0.011 0.037 0.021 1.550 0.003 0.011 0.037 0.021 1.450 0.003 0.011 0.037 0.021 1.300 0.003 0.011 June 2010