OFR-15-05 State of Arizona Air Monitoring Network Plan For the Year 2015 Arizona Department of Environmental Quality Air Quality Division Air Assessment Section July 1, 2015 Final State of Arizona Air Monitoring Network Plan for the Year 2015 Page 1 Table of Contents 1.0 INTRODUCTION ................................................................................................................................ 3 1.1 Executive Summary .........................................................................................................................................5 2.0 ADEQ PROGRAM AND NETWORK DESCRIPTIONS ................................................................... 6 2.1 NAAQS Compliance Network .........................................................................................................................6 2.2 State Implementation Plan (SIP) and Maintenance Area Network ..................................................................6 2.3 Source-Oriented Network ................................................................................................................................6 2.4 NCore Network ................................................................................................................................................7 2.5 Meteorological Network ..................................................................................................................................7 2.6 Photochemical Assessment Monitoring Stations (PAMS) ...............................................................................7 2.7 National Air Toxics Trend Sites (NATTS) ......................................................................................................8 2.8 Chemical Speciation Network (CSN) ..............................................................................................................8 2.9 Class 1 Area Network and IMPROVE Program ..............................................................................................8 2.10 AirNow Reporting..........................................................................................................................................8 2.11 Urban Haze Network......................................................................................................................................9 2.12 E-BAM Network of PM2.5 Special Purpose Monitors ...................................................................................9 2.13 Arizona / Mexico Border Network...............................................................................................................10 3.0 MONITORING NETWORK EVALUATION ................................................................................... 11 3.1 Site Closures ..................................................................................................................................................11 3.2 New Sites Planned..........................................................................................................................................11 3.3 Network Changes – Current and Planned ......................................................................................................11 4.0 ADEQ MONITORING NETWORKS ............................................................................................... 13 4.1 PM2.5 Monitoring Network Requirements .....................................................................................................13 4.2 PM10 Monitoring Network Requirements ......................................................................................................15 4.3 O3 Monitoring Network Requirements ..........................................................................................................17 4.4 Pb Monitoring Network Requirements ..........................................................................................................18 4.5 SO2 Monitoring Network Requirements ........................................................................................................18 4.6 NO2 Monitoring Network Requirements .......................................................................................................19 4.7 CO Monitoring Network Requirements .........................................................................................................20 4.8 PAMS Monitoring Network Requirements....................................................................................................20 4.9 NCore Monitoring Network Requirements ....................................................................................................22 4.10 SIP Monitoring Network Requirements .......................................................................................................23 4.11 Source Compliance Monitoring Network Requirements .............................................................................24 4.12 Class 1 Visibility Network ...........................................................................................................................25 4.13 Urban Haze Monitoring Network ................................................................................................................26 4.14 Meteorology Monitoring Network ...............................................................................................................27 5.0 QUALITY ASSURANCE .................................................................................................................. 28 5.1 EPA QA Reports and Network Performance .................................................................................................29 5.2 EPA Data Reports ..........................................................................................................................................29 Appendix A – Definitions and Abbreviations ............................................................................................ 1 Appendix B – Network Maps ..................................................................................................................... 1 Appendix C – Current Monitors by Program or Network .......................................................................... 1 Appendix D – Site Information Data Tables .............................................................................................. 1 Appendix E – Criteria Pollutant Minimum Monitoring Requirements ...................................................... 1 Appendix F – Letters to EPA ...................................................................................................................... 1 Appendix G – ADEQ’s Air Quality Monitoring Role in Arizona .............................................................. 1 State of Arizona Air Monitoring Network Plan for the Year 2015 Page 2 1.0 INTRODUCTION This document fulfills the obligation, under the Code of Federal Regulations (CFR), Title 40, § 58.10(a), requiring the Arizona Department of Environmental Quality (ADEQ) to complete and submit to the United States Environmental Protection Agency (EPA) an annual monitoring network plan for the year 2015. This plan informs EPA Region 9 of the monitoring activities ADEQ has implemented since July 2014, as well as activities ADEQ will undertake through December 2016. However, some changes may occur after the plan is published and approved due to unforeseen events at monitoring sites, funding changes, or changes in EPA monitoring requirements. Data from ADEQ's monitors are reported to EPA's Air Quality System (AQS) database and to AirNow. In 40 CFR Part 51, EPA requires states to create, submit, and adopt State Implementation Plans (SIPs) to address the various issues and responsibilities involved with creating and implementing air quality programs. 40 CFR Part 51 Subpart J specifies that 40 CFR Part 58 Subpart - C contain the requirements for establishing air quality surveillance systems to monitor ambient air quality. Air quality surveillance systems consist of networks of monitors located at carefully selected physical locations referred to as sites or stations. The networks, sites, and monitors include:             NAAQS Compliance network or the State and Local Air Monitoring Stations Network (SLAMS) – measures the criteria pollutants for demonstrating compliance to the standard State Implementation Plan (SIP) specific network – tracks compliance in areas that are currently in nonattainment or in areas where on-going demonstration of maintenance is required Source-Oriented network – requires several major point sources in the state to conduct ambient monitoring for criteria pollutants as outlined in their permit NCore Network – a nationwide multipollutant network that integrates several advanced measurement systems for particles, pollutant gases, and meteorology Photochemical Assessment Monitoring Stations Network (PAMS) – enhanced monitoring of O3 to obtain comprehensive and representative O3 data National Air Toxics Trends Station Network (NATTS) – to monitor and record the concentrations of EPA identified air toxics on a national scale Chemical Speciation Network (CSN) – for monitoring speciated PM2.5 to determine the chemical composition of these particles on a national scale The Interagency Monitoring of Protected Visual Environments (IMPROVE) – tracks visual impairment in specified national parks and wilderness areas Phoenix’ Urban Haze Network – to provide State and Local policy-makers and the public with information regarding the urban haze levels ADEQ’s Smoke Management Network – provide continuous, real-time particulate concentration data that is useful for making smoke management decisions related to prescribed burns and wildfire monitoring Arizona / Mexico Border Network – to review the air quality monitoring data and air monitoring networks in rural and urban areas along the border Meteorological Network – to support the analysis of ambient air quality data This Annual Monitoring Network Plan identifies the purpose(s) of each monitor and provides evidence that both the siting and the operation of each monitor meets the requirements in 40 CFR Part 58 Appendices A, C, D, and E as follows:  40 CFR 58 Appendix A – Quality Assurance Requirements for SLAMS, SPMs, and Prevention of Significant Deterioration (PSD) Air Monitoring State of Arizona Air Monitoring Network Plan for the Year 2015 Page 3  40 CFR 58 Appendix C – Ambient Air Quality Monitoring Methodology  40 CFR 58 Appendix D – Network Design Criteria for Ambient Air Quality Monitoring  40 CFR 58 Appendix E – Probe and Monitoring Path Siting Criteria for Ambient Air Quality Monitoring The results of the annual network review and planning are used to determine how well the networks are achieving their required air monitoring objectives, how well they meet data users’ needs, and how they should be modified to continue meeting their objectives and data needs. Modifications can include the termination of existing stations, relocation of stations, establishment of new stations, monitoring of additional parameters, and/or changes to the sampling schedule. The annual network review and planning are performed for the purpose of improving the monitoring networks and ensuring that they provide adequate, representative, and regulatory compliant air quality data. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 4 1.1 Executive Summary The purpose of this executive summary is to state the status of the ADEQ’s monitoring network, the compliance with regulatory requirements, and to outline any planned or past changes to the monitoring network. ADEQ’s main monitoring objective is to measure the criteria pollutants regulated under the Clean Air Act as National Ambient Air Quality Standards. ADEQ supports or operates many different state and national networks which help improve air quality in Arizona and nationwide. ADEQ continually strives to protect and enhance public health and the environment in Arizona through ambient air quality monitoring. ADEQ fulfills all the monitoring requirements as stated in 40 CFR Part 58, in any State or Local laws, and according to the EPA administrator with regards to data quality and assurance, siting and sampling criteria, annual data certification, and minimum monitoring requirements for all networks. Past and future changes to the ambient monitoring network as outlined in this Annual Network Plan are for the time period of July 2014 – December 2016. Any additional changes not outline here will be requested to EPA Region 9 for their approval. ADEQ may change the plans according to new rules or direction from ADEQ management or the EPA administrator and includes these changes in the subsequent Annual Network Plan. The past and planned changes for this timeline are as follows: Table 1.1-1 Past Changes to the Network Site Name Monitors Date of Change Alamo Lake NO2 1-July-2014 Table 1.1-2 Future Changes to the Network Planned Date Site Name Monitors of Change Description An Ecotech NO2 9841 was installed in July 2014 and designated as a special purpose monitor (SPM). Description A CO monitor will be deployed to the site as a SPM for background data purposes. Relocation of Doug1 IMPROVE monitor to the Nogales Post Office site, Nogales, AZ. A Pb monitor will be deployed at the Hillcrest site in Hayden, AZ. Alamo Lake CO 1-Jan-2016 Douglas Red Cross IMPROVE 1-July-2016 Hillcrest Miami Jones Ranch and Miami Townsite Miami Ridgeline Nogales Post Office Nogales Post Office Pb TBD SO2 1-July-2015 Removal of the requirement for FMMI to monitor at these locations. PM10 1-July-2015 Removal of the requirement for FMMI to monitor at this location. PM10 1-Jul-2015 Removal of the POC 1 PM10 manual method. PM2.5 1-Jul-2015 Removal of the POC 2 PM2.5 manual method. O3 1-Jan-2016 Closure of the Prescott College AQD site and establishment of new site in the City of Prescott. Prescott College State of Arizona Air Monitoring Network Plan for the Year 2015 Page 5 2.0 ADEQ PROGRAM AND NETWORK DESCRIPTIONS ADEQ operates ambient air quality equipment for a variety of Federal and State monitoring programs. Detailed descriptions of the equipment deployed for each monitoring program are presented in Appendix C of this Network Plan. The equipment is grouped by monitoring program or network to easily compare instrument specifics. Appendix D of this Network Plan lists information on each of ADEQ's current and recently closed monitoring sites, including those sites which ADEQ shares with other agencies or serves as the local site operator. General information about the monitoring programs in which ADEQ participates is described in the following sections. 2.1 NAAQS Compliance Network ADEQ’s compliance network consists of monitoring sites operated for the purpose of demonstrating compliance with the National Ambient Air Quality Standards (NAAQS) for the “criteria” pollutants: carbon monoxide (CO), nitrogen dioxide (NO2), sulfur dioxide (SO2), ozone (O3), particulate matter (PM10 and PM2.5), and lead (Pb). For each of these pollutants, EPA has established national air quality standards to protect public health. The criteria pollutants are measured using instruments designated by EPA as Federal Reference Methods (FRM) or Federal Equivalent Methods (FEM). 40 CFR Part 58 specifies the minimum requirements for determining NAAQS compliance including the following network and site criteria:  Number and types of monitors required per Metropolitan Statistical Area (MSA) by pollutant  Objectives and spatial scales  Sampling frequency  Collocation  Special NCore-related requirements  Meteorology  Probe location and other restrictions within a site  Periodic performance evaluations  Quality Assurance  Data reporting 2.2 State Implementation Plan (SIP) and Maintenance Area Network ADEQ maintains several air monitoring sites for the purpose of tracking compliance in areas that are currently in nonattainment for one or more of the NAAQS, and in areas where the NAAQS have been met but on-going demonstration of maintenance is required. Specific monitoring requirements for each of these areas are described in their respective SIPs and/or Maintenance Plans. 2.3 Source-Oriented Network Several major point sources in the state are required to conduct ambient monitoring for criteria pollutants, primarily PM10 and SO2, as part of their air quality permit. Some of the source-generated data from these sites have been State of Arizona Air Monitoring Network Plan for the Year 2015 Page 6 submitted to AQS. Discussions with American Smelting and Refining Company (ASARCO) are ongoing to have ADEQ collocate SO2 at sites in and around Hayden, AZ. 2.4 NCore Network EPA describes the nationwide NCore network, which is composed of approximately 70 urban and 20 rural sites, as a multipollutant network that integrates several advanced measurement systems for particles, pollutant gases, and meteorology. Some objectives of the NCore network include:  Tracking long-term trends of criteria and non-criteria pollutants;  Support for long-term health assessments which contribute to ongoing reviews of the NAAQS;  Support to scientific studies ranging across technological, health, and atmospheric process disciplines  Support to ecosystem assessments recognizing that national air quality networks benefit ecosystem assessments and, in turn, benefit from data specifically designed to address ecosystem analyses. As required by 40 CFR Part 58.13, ADEQ’s NCore site, JLG Supersite, was operational by January 1, 2011. In addition to the above missions and the NCore monitoring requirements set forth in the 40 CFR Part 58.13, ADEQ will use the JLG Supersite to test new technologies in various ADEQ monitoring networks. Examples include advanced communications and serial data collection, remote zero/span/precision (Z/S/P) checks and calibrations, high sensitivity instruments, and instruments that monitor additional pollutants that may be added to current CFR requirements. Additional NCore information is available from the EPA website: http://www.epa.gov/ttn/amtic/ncore/index.html 2.5 Meteorological Network ADEQ collects meteorological data at sites throughout the state to support the analysis of ambient air quality data and to provide support for exceptional event reporting. Meteorological measurements are also required for the NCore and PAMS networks. ADEQ continues to add meteorological instrumentation to most of ADEQ’s monitoring sites that were not previously equipped, and for which there are adequate facilities to support the meteorological tower and equipment. ADEQ currently meets the meteorological monitoring requirements for the NCore and PAMS networks. 2.6 Photochemical Assessment Monitoring Stations (PAMS) Section 182(c)(1) of the 1990 Clean Air Act (CAA) Amendments requires the Administrator to promulgate rules for enhanced monitoring of O3 that includes concurrent monitoring of O3, oxides of nitrogen (NOx), total reactive nitrogen (NOy), speciated volatile organic compounds (VOC), carbonyls, CO, and meteorology to obtain comprehensive and representative O3 data. Immediately following the promulgation of those rules, ADEQ began to implement a program to improve ambient monitoring activities related to the precursors of O3. The subsequent revisions to 40 CFR Part 58 (1993) required states to establish PAMS as part of their monitoring networks in O3 nonattainment areas classified as serious, severe, or extreme. The principal reasons for requiring the collection of additional ambient air pollutants and meteorological data are the widespread nonattainment of the O3 NAAQS and the need for a more comprehensive air quality database for O3 and its precursors. ADEQ operates three PAMS sites to represent the Phoenix metropolitan area: JLG Supersite (type 2), Queen Valley (type 3), and VEI (meteorological). State of Arizona Air Monitoring Network Plan for the Year 2015 Page 7 EPA has issued a proposal for a reengineering as the PAMS program. This was included in the 2015 O 3 NAAQS revision. The finalization of both the O3 NAAQS revision and PAMS reengineering is scheduled to be finalized October, 2015. 2.7 National Air Toxics Trend Sites (NATTS) The NATTS network was designed to monitor and record the concentrations of EPA identified air toxics on a national scale. Data from EPA’s national monitoring activities are used to estimate national average concentrations for these air toxics compounds and to detect trends. Using this information, EPA, states, and local agencies can estimate changes to the human exposure from air toxics. Detection of increased human toxicity risk can then be used to support changes in environmental policy. As part of the National Air Toxics Assessment (NATA) process, ambient air quality data are used to assess the national toxics inventory and long-term hazardous air pollutant (HAP) trends. ADEQ’s JLG Supersite is the designated NATTS site for the Phoenix MSA with an additional site at the South Phoenix site. 2.8 Chemical Speciation Network (CSN) The CSN was established to meet the regulatory requirements for monitoring speciated PM 2.5 to determine the chemical composition of these particles. The purpose of the CSN is to determine, over a period of several years, trends in concentration levels of selected ions, metals, carbon species, and organic compounds in the PM2.5 samples collected at select sites throughout the country. The program began in 1999 with 54 Speciation Trends Network (STN) sites across the nation located primarily in or near larger MSAs. The network has increased to around 200 sites nationwide. PM2.5 speciation monitoring at JLG Supersite includes two CSN PM2.5 speciation samplers. The collocated IMPROVE samplers provide precision and bias information for the IMPROVE network and the data are reasonably comparable to the CSN speciation data. In 2009, the URG 3000N sampler was added at JLG Supersite for collecting the carbon sample in lieu of the Met One SuperSASS, which had been used to collect all three types of filter samples e.g. Quartz, Teflon, and Nylon. The laboratory analysis method for carbon samples collected by the URG also changed. These changes to the CSN program’s monitoring and analytical design were geared toward more closely matching the carbon analytes from the CSN sampler to those collected via the IMPROVE network. 2.9 Class 1 Area Network and IMPROVE Program The rural visibility monitoring network tracks impairment in specified national parks and wilderness areas. These parks and wilderness areas are called federally mandatory Class 1 areas and were designated based on an evaluation required by Congress in the 1977 Federal CAA Amendments. The evaluation, performed by the United States Forest Service (USFS) and National Park Service (NPS), reviewed the areas of parks and national forests, which were designated as wilderness before 1977, were larger than 6,000 acres, and to which visual air was an important resource for the visitor experience. Of the 156 Class 1 areas designated across the nation, 12 are located in Arizona. Nine Class 1 areas are located in USFS land and three in NPS land. EPA initiated the nationally-operated IMPROVE monitoring network in 1987, whose purpose is to characterize broad regional trends and visibility conditions using monitoring data collected in or near Class 1 wilderness areas across the United States. Ten Class 1 IMPROVE sites were originally placed in and around these Class 1 areas. Additionally, ADEQ has added six other IMPROVE sites identified as Protocol sites. Refer to section 4.12 and the map in Appendix B for additional details regarding ADEQ’s Class 1 Visibility and IMPROVE networks. 2.10 AirNow Reporting State of Arizona Air Monitoring Network Plan for the Year 2015 Page 8 ADEQ reports near real-time data from its continuous air quality monitors to the AirNow system. The AirNow system is a set of near real-time public maps which report an Air Quality Index (AQI) for the five major air pollutants regulated by the CAA. These pollutants are: ground-level O3, PM, CO, SO2, and NO2. The purpose of the AQI is to help understand what local air quality means to your health. To make it easier to understand, the AQI is divided into six color coded categories: Good, Moderate, Unhealthy for Sensitive Groups, Unhealthy, Very Unhealthy and Hazardous. ADEQ will continue to expand efforts for data submission to AirNow to support the collection and nationwide dissemination of consistently provided air quality data in the AQI. The AQI format is used by local weather forecasters, medical facilities, schools and the general public to make health-related activity decisions based on the reported local AQI. 2.11 Urban Haze Network The purpose of the Urban Haze Network is to provide State and Local policy-makers and the public with information regarding the urban haze levels, track short-term and long-term trends, assess source contributions, and better evaluate the effectiveness of air pollution control strategies. ADEQ utilizes transmissometers, particulate monitors, and/or digital camera systems to evaluate urban visibility. More than a decade of urban visibility data has been collected for the Phoenix and Tucson area. Currently, only the Phoenix metropolitan area urban visibility is monitored using high resolution cameras. Additional details regarding ADEQ’s Urban Haze Network can be found in section 4.13. 2.12 E-BAM Network of PM2.5 Special Purpose Monitors E-BAM monitors are special purpose monitors (SPM) which provide continuous, real-time particulate concentration data that is useful for making informed smoke management decisions related to prescribed burns and wildfire monitoring. The current network of special purpose continuous particulate monitors (listed in Table 2.121) is composed of lightweight, portable E-BAM monitors typically in self-contained, environmentally sealed enclosures. They can be battery or solar powered for operation at sites without fixed electrical power. Data are sampled every second and concentrations are calculated and recorded every minute. E-BAM monitors have been used by many agencies, particularly in the western United States. They are not classified as FRMs or FEMs and may not be used to demonstrate NAAQS compliance. ADEQ uses these monitors primarily in populated areas that could be impacted by smoke from prescribed burns and wildfires. In 2011 ADEQ configured the E-BAM monitors to measure PM2.5 to be consistent with the National Forest Service monitors. Hourly PM2.5 data from the E-BAM monitors can be viewed at: http://www.phoenixvis.net/PPMmain.aspx. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 9 Table 2.12-1 Current Locations of E-BAM Monitors Site Name Flagstaff Middle School Payson Well Site Prescott College AQD Sedona Fire Station AQD Show Low Springerville Verde Ranger Station Address 755 N. Bonito, Flagstaff, AZ 86001 204 W. Aero Dr., Payson, AZ 85541 226 Grove Ave., Prescott, AZ 86301 310 Forest Road, Sedona, AZ, 86336 561 E. Deuce of Clubs, Show Low, AZ 85901 323 S. Mountain Ave., Springerville, AZ 85936 300 E. Highway 260, Camp Verde, AZ 86322 2.13 Arizona / Mexico Border Network ADEQ works with the EPA Border Program as part of the U.S. – Mexico Border Air Monitoring Working Group. This working group’s primary priority is reviewing the air quality monitoring data and air monitoring networks in rural and urban areas along the border and evaluating the adequacy of these networks. The secondary priority of this group is to identify operational and maintenance needs, plan for future capabilities, and develop recommendations to resolve any inadequacies. Through this effort, relationships between EPA, ADEQ, Secretariat of Environment and Natural Resources (SEMARNAT), and Commission for Ecology and Sustainable Development (CEDES) are expected to develop, such that data are shared across the border and capacity is built to meet the needs of the air monitoring program objectives. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 10 3.0 MONITORING NETWORK EVALUATION This section provides a summary of changes to ADEQ's monitoring networks completed since the 2014 Network Plan submission, as well as changes planned for July 2015 through December 2016. Any occurrence of unplanned changes due to emerging needs, budget constraints, or other circumstances will be documented in next year’s Air Monitoring Network Plan, and ADEQ will communicate with EPA Region 9 regarding any significant changes on a case-by-case basis. Below is a summary of the planned network changes. Details regarding these changes can be found in Section 4 of this Monitoring Network Plan. 3.1 Site Closures Prescott College AQD – ADEQ plans to close the Prescott College site by January 1, 2016. The current building on the Prescott College campus is not a viable location for long term monitoring. The building is being considered for demolition and it is in the best interest of ADEQ to relocate the monitor elsewhere. A comparison study with the new site will be conducted if possible. 3.2 New Sites Planned Hillcrest, Hayden, AZ – ADEQ plans to add a new Pb monitor in the Hayden area at the existing Hillcrest site. The Pb monitor will be added by January 1, 2016. Prescott, AZ – ADEQ is currently scoping locations for a new site in Prescott for the O3 monitor. The new O3 monitor is planned to be added by January 1, 2016. A comparison study with the Prescott College AQD will be conducted if possible. Previously planned sites in Lake Havasu City, AZ and Sierra Vista, AZ have been put on hold due to higher priority needs. 3.3 Network Changes – Current and Planned Alamo Lake, AZ – ADEQ plans to install a CO analyzer by January 2016 to be designated as a background/SPM to provide background data as a part of Arizona’s permitting process, SIP development, and modeling purposes in addition to the SO2 and NOx analyzers currently in place. ADEQ plans to remove the SO2 and NOx analyzers in March 2016 and June 2016 respectively before two full years of operation. Douglas Red Cross, AZ – ADEQ plans to relocate the Douglas Red Cross IMPROVE monitor in accordance with all necessary requirements, working with the IMPROVE steering committee to the Nogales, AZ site. The relocation to Nogales, AZ will serve a variety of purposes and will still be operated by ADEQ. Relocation to Nogales, AZ is desirable due its proximity to a larger and unknown area of interest (Nogales, Sonora) and its shorter distance from ADEQ’s operator in Tucson, AZ. The timeframe for this relocation is not yet in place. Miami, AZ – At Miami Jones Ranch and Miami Townsite, ADEQ plans to remove the requirement for source monitoring of SO2 by Freeport-McMoRan Copper and Gold Inc. (FMMI). Operation of these instruments henceforth is subject to the discretion of FMMI. This will not affect any of ADEQ’s monitors at these locations. Miami Ridgeline, AZ – ADEQ plans to remove the requirement for source monitoring of PM10 by FMMI. Operation of this PM10 instrument henceforth at Ridgeline is subject to the discretion of FMMI. The Miami Golf Course monitor operated by ADEQ will then be the PM10 monitor representing the Miami, AZ PM10 nonattainment area. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 11 Nogales Post Office, AZ – In addition to the previously discussed IMPROVE relocation to Nogales Post Office, AZ, ADEQ plans to remove two of the collocated instruments at the site in order to align with collocation requirements for the PM10 and PM2.5 networks. As the rest of ADEQ’s PM10 network is now continuous and there are no collocation requirements for a continuous PM10 network, the POC 1 PM10 instrument at Nogales Post Office is no longer needed and will be removed on July 1, 2015. ADEQ’s PM2.5 network consists exclusively of a single automated method. At Nogales, there are three PM2.5 instruments, one automated method and two manual methods. ADEQ plans to remove POC 2 PM2.5 instrument on July 1, 2015. Table 3.3-1 Instrument Changes Made from July 2014 thru June 2015 Site Name Monitors Date of Change Alamo Lake NO2 1-July-2014 Description An Ecotech NO2 9841 was installed in July 2014 and designated as a special purpose monitor (SPM). Table 3.4-2 Instrument Changes Planned for July 2015 to December 2015 Site Name Monitors Planned Date of Change Alamo Lake CO 1-Jan-2016 Douglas Red Cross IMPROVE 1-July-2016 Hillcrest Miami Jones Ranch and Miami Townsite Miami Ridgeline Nogales Post Office Nogales Post Office Pb TBD SO2 1-July-2015 Removal of the requirement for FMMI to monitor at these locations. PM10 1-July-2015 Removal of the requirement for FMMI to monitor at this location. PM10 1-Jul-2015 Removal of the POC 1 PM10 manual method. PM2.5 1-Jul-2015 Removal of the POC 2 PM2.5 manual method. O3 1-Jan-2016 Closure of the Prescott College AQD site and establishment of new site in the City of Prescott. Prescott College Description A CO monitor will be deployed to the site as a SPM for background data purposes. Relocation of Doug1 IMPROVE monitor to the Nogales Post Office site, Nogales, AZ A Pb monitor will be deployed at the Hillcrest site in Hayden, AZ. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 12 4.0 ADEQ MONITORING NETWORKS The minimum monitoring requirements for each pollutant are described in 40 CFR Part 58 Appendix D and are typically based on the population of urban areas. Current minimum monitoring requirements are only associated with MSAs, and there are no minimum monitoring requirements for Micropolitan Statistical Areas. Tables 4.0-1 and 4.0-2 outline metropolitan and micropolitan statistical areas in Arizona as identified by the U.S. Census Bureau. Table 4.0-1 Metropolitan Statistical Areas (2010 Census) Metropolitan Statistical Area Flagstaff Lake Havasu City – Kingman Phoenix – Mesa – Scottsdale Prescott Sierra Vista – Douglas Tucson Yuma Area included Coconino County Mohave County Maricopa & Pinal Counties Yavapai County Cochise Pima County Yuma County Population 134,421 200,186 4,192,887 211,033 131,346 980,263 195,751 Table 4.0-2 Micropolitan Statistical Areas (2010 Census) Micropolitan Statistical Area Nogales Payson Safford Show Low County Santa Cruz Gila Graham & Greenlee Counties Navajo Population 47,420 53,597 37,220 107,449 4.1 PM2.5 Monitoring Network Requirements The number of PM2.5 samplers required in urban areas is based on population (see Table 4.0-1) and design values for PM2.5 concentrations (see Table 4.1-1). Table 4.1-1 Minimum Number of PM2.5 Monitors Required (40 CFR 58 Appendix D) Population (MSA) Most recent 3-Yr design value ≥ 85% of any PM2.5 NAAQS * Most recent 3-Yr design value <85% any PM2.5 NAAQS * or no Design Value Available >1,000,000 3 2 500,000 – <1,000,000 2 1 50,000 – <500,000 1 0 3 3 3 *85% Annual NAAQS (12 μg/m ) = 10.2 μg/m ; 85% 24-Hour NAAQS (35 μg/m ) = 29.75 μg/m3 The required sample collection frequency is based on the type of sampler and the design value calculated from data collected at each FRM (filter-based) or FEM (continuous) sampler (see Table 4.1-2). 40 CFR §58.12 (d)(1) states the manual PM2.5 sample collection frequency requirement at required SLAMS stations as every third day at sites without a collocated continuously operating PM2.5 monitor. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 13 Table 4.1-2 PM2.5 Design Values and Sampling Frequencies at ADEQ Sites 2012-2014 2012-2014 24-Hour Design Annual Design Value (μg/m3) Value (μg/m3) 04-003-1005 Douglas Red Cross 13 7.0 04-012-8000 Alamo Lake1 8 2.0 04-013-9997 JLG Supersite 21 7.3 04-023-0004 Nogales Post Office 27 9.3 04-027-8011 Yuma Supersite2 19 7.4 1 Alamo Lake is designated as the Background site for the PM2.5 Network 2 Yuma Supersite is designated as the Transport site in the PM2.5 Network AQS Site ID Site Name Sample Frequency Continuous Continuous Continuous Continuous Continuous ADEQ currently operates EPA-approved FEM monitors at five PM2.5 monitoring sites. An EPA-approved FEM monitor was deployed to the Alamo Lake site and designated as the PM2.5 monitoring network’s Background site. Yuma Supersite is designated as the required PM2.5 Transport site. ADEQ operates both an EPA-approved FEM continuous monitor and a Partisol 2000 PM2.5 FRM at the JLG Supersite fulfilling an NCore collocation requirement. The EPA-approved FEM sampler is designated the primary PM2.5 monitor for NAAQS compliance purposes. Several non-FEM continuous PM2.5 monitors are also in operation throughout the state, most of which are associated with the Smoke Management E-BAM network. See Section 2.12 for additional details on the E-BAM network. 4.1.1 PM2.5 Collocation Requirements For the ADEQ PM2.5 network, one site is required to have collocated monitoring. The Nogales Post Office site has the highest PM2.5 design value in ADEQ’s PM2.5 network and is therefore a PM2.5 collocated site. ADEQ operates both an EPA-approved FEM continuous instrument and two Partisol 2000 PM2.5 FRM instruments at the Nogales Post Office site. The FEM BAM 1020 is designated as the primary PM2.5 monitor for this site, thus enabling ADEQ to exceed the required 1-in-3 day monitoring frequency. This combination of instruments also fulfills the collocation requirement of the PM2.5 network for ADEQ. The QA collocated Partisol PM2.5 FRM operates on a 1in-6 day monitoring frequency rather than the required 1-in-12 day monitoring frequency. Additionally, ADEQ operates one Partisol 2000 PM2.5 FRM instrument and one continuous PM2.5 FEM monitor at the JLG Supersite. This PM2.5 FEM is designated the primary instrument as required by NCore. The PM2.5 FEM monitor is also labeled as an NCore PMcoarse paired monitor. The PM2.5 FRM instrument is labeled as a QA collocated instrument for the site. Table 4.1-3 summarizes ADEQ’s PM2.5 collocation requirements. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 14 Table 4.1-3 PM2.5 FRM/FEM Collocation Details Method Code (Instrument Type) 143 (Partisol 2000i) 170 (Met One BAM 1020) # of Sites 2 5 # of Primary Monitors 0 5 # of Required Collocated Monitors 0 1 # of Active Collocated Monitors 0 2 4.1.2 Relocating Any Violating PM2.5 Monitors ADEQ does not have any violating PM2.5 monitors that are being considered for relocation. A process for relocating violating PM2.5 monitors is required and described in 40 CFR Part 58.10 (c). It requires the annual monitoring network plan to document how state and local agencies provide for the review of changes to a PM 2.5 monitoring network that impact the location of a violating PM2.5 monitor or the creation/change to a community monitoring zone. The analysis includes a description of the proposed use of spatial averaging for purposes of making comparisons to the annual PM2.5 NAAQS as set forth in Appendix N to Part 50. The affected agency must document the process for obtaining public comment and include any comments received through the public notification process within their submitted plan. ADEQ does not intend to establish community monitoring zones as described in the rule or utilize spatial averaging for comparison to the PM2.5 NAAQS. A public comment procedure is required prior to relocation of a violating monitor and ADEQ will utilize the following procedure: 1. Evaluation of the potential replacement site will include review and comparison of available pollutant data, meteorology, climatology, terrain, and siting characteristics. This information will be documented in a brief report. 2. Make notice of such a change in the annual monitoring network plan. 3. If the change must be accomplished prior to annual monitoring network plan submittal, ADEQ will make appropriate notice via the agency Web page and invite participation from the public prior to relocation of the affected site. 4. Relocation of the monitor. 4.2 PM10 Monitoring Network Requirements The number of PM10 samplers required in urban areas is based on the population of the area (see Table 4.2-1) and design values for PM10 24-hour concentrations (see Table 4.2-2). Maricopa, Pinal, and Pima Counties have delegated authority for their monitoring networks and AQS reporting. ADEQ's PM10 monitoring network includes the MSAs in all other Arizona counties, as well as the PM10 nonattainment areas in those counties. JLG Supersite PM10 concentrations for the NCore network are provided by the PM10 FEM BAM 1020. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 15 Table 4.2-1 Minimum Number of PM10 Monitors Required (40 CFR 58 Appendix D) MSA Population High Concentration Exceeds 24-Hour NAAQS by 20% or more (>180µg/m3) Medium Concentration Exceeds 80% of 24-Hour NAAQS (>120µg/m3) >1,000,000 500,000 – <1,000,000 250,000 – <500,000 100,000 – <250,000 6-10 4-8 3-4 1-2 4-8 2-4 1-2 0-1 Low Concentration Less than 80% of 24-Hour NAAQS (<120 µg/m3) or no Design Value Available 2-4 1-2 0-1 0 The monitoring rule in 40 CFR Part 58.12(e) states that for PM10 sites, “…the minimum monitoring schedule for the site in the area of expected maximum concentration shall be based on the relative level of that monitoring site concentration with respect to the 24-hour standard.” ADEQ has transitioned most PM10 monitors from filter-based methods to continuous methods. All the PM10 monitors in the ADEQ PM10 network are continuous methods. Table 4.2-2 lists the PM10 network site Design Values and Annual Means. Table 4.2-2 PM10 Design Values (Estimated Exceedances) and Annual Means for ADEQ Sites 2012 - 2014 Average Estimated Days PM10>150 μg/m3 Including Events 2012 – 2014 Average Estimated Days PM10>150 μg/m3 Excluding Events 2014 Annual Mean Concentration (μg/m3) 1.9* 1.9* 20.9* 1.7 0* 0.7 0* 0 1.3 0.7 0.3 1.7 0* 0.7 0* 0 0.7 0.7* 0.3 37.6 15.5* 37.5 22.6 11.7 29.9 20.6 27.1 2.7 2.7 39.0 04-023-0004 Nogales Post Office 0 04-023-0004 Nogales Post Office 1.7* 04-027-8011 Yuma Supersite 8 * Annual values not meeting completeness criteria 0 1.7* 8 33.2 39.9 44.71 AQS Site ID Site Name 04-003-1005 04-007-0008 04-007-1001 04-007-8000 04-012-8000 04-013-9997 04-015-1003 04-019-0001 Paul Spur Chemical Lime Plant Douglas Red Cross Payson Well Site Hayden Old Jail Miami Golf Course Alamo Lake JLG Supersite Bullhead City Ajo 04-019-0020 Rillito 04-003-0011 4.2.1 PM10 Collocation Requirements State of Arizona Air Monitoring Network Plan for the Year 2015 Page 16 There are no collocation requirements for EPA-approved PM10 FEM monitors. ADEQ has transitioned the PM10 network to continuous FEM monitors. ADEQ does operate an additional Partisol 2000 FRM at the Nogales Post Office site. While the FEM is designated as the primary PM10 monitor, the Partisol 2000 monitor is designated a QA collocated PM10 instrument. Table 4.2-3 summarizes ADEQ’s PM10 collocation requirements. Table 4.2-3 PM10 FRM/FEM Collocation Details # of Required # of Active Method Code # of Sites Collocated Collocated Monitors Monitors 126 (Partisol 2000) 0* 0* 0* 0* 079 (TEOM) 8 8 0 0 122 (BAM) 4 4 0 0 * The Partisol 2000 monitor at the Nogales Post office will be removed beginning July 2015 # of Primary Monitors 4.3 O3 Monitoring Network Requirements Table 4.3-1 Minimum Number of O3 Monitors Required (40 CFR Part 58 Appendix D) Population (MSA) Most recent 3 year 8-hour Design Value ≥ 85% of NAAQS (0.06375 ppm) Most recent 3 year 8-hour Design Value <85% NAAQS (0.06375 ppm) or no Design Value available >10 Million 4 – <10 Million 350,000 – <4 Million 50,000 – <350,000 4 3 2 1 2 1 1 0 The minimum monitoring requirements for O3 are shown above in Table 4.3-1. ADEQ operates a network of seven O3 monitors throughout Arizona (see Table 4.3-2). ADEQ is updating the O3 network with remote zero/span/precision checks utilizing the Teledyne T703 UV Photometric O3 Calibrator with Internal Zero Air Pump and External Zero Air Shut-Off Valve. This will allow air monitoring staff to more efficiently maintain the O3 network while minimizing travel time during the O3 season, and avoiding calibration during the peak hours of the day when O3 levels are highest. Additionally, Maricopa, Pima, and Pinal Counties operate O3 monitors. Table 4.3-2 ADEQ O3 Sites and Design Values AQS Site ID 04-005-1008 04-007-0010 04-012-8000 04-013-9997 04-021-8001 04-025-8033 04-027-8011 Site Flagstaff Middle School Tonto National Monument Alamo Lake JLG Supersite Queen Valley Prescott College AQD Yuma Supersite Current Operating Schedule 2012-2014 Design Value (ppm) January - December January - December January - December January - December January - December January - December January - December 0.071 0.074 0.072 0.077 0.073 0.071 0.077 State of Arizona Air Monitoring Network Plan for the Year 2015 Page 17 4.3.1 O3 Season In accordance with 40 CFR Part 58, Appendix D, Table D-3, ADEQ will started year round monitoring on March 1, 2015. 4.4 Pb Monitoring Network Requirements ADEQ has operated three source-oriented TSP Hi-Vol Pb monitors between the Globe Highway site (collocated) and the Miami Golf Course site since January 2011. 40 CFR Part 58 Appendix D states that at a minimum, there must be one source-oriented SLAMS site located to measure the maximum Pb concentration in ambient air resulting from each non-airport source which emits 0.50 or more tons per year and each airport source which emits 1.0 or more tons per year. Per the National Emissions Inventory (NEI) 2011, there are no non-airport sources in the 0.51.0 ton per year category. For the NCore-Pb requirement, ADEQ uses the same PM10 metals speciation sample that is used for the NATTS program. Eastern Research Group (ERG) currently analyzes these samples. On June 1, 2012 ERG received EPA approval for the ICP-MS analysis method for lead in PM10. No changes in the actual monitoring or analysis method has occurred for Pb-PM10 data collected at JLG Supersite; however, parameter code 85129 and method code 202 are associated with these data in AQS. 4.4.1 Pb Collocation Requirements ADEQ’s Pb network requires only one collocated site. The Globe Highway site located in Hayden, AZ has the highest design value in the Pb network and is therefore the collocated site. Although ADEQ monitors NCore-Pb at the JLG Supersite, collocated NCore-Pb sites are determined by the EPA and JLG Supersite is not a designated NCore-Pb collocated site. Table 4.4-1 summarizes ADEQ’s Pb collocation requirements. Table 4.4-1 Pb FRM/FEM Collocation Details # of Required Collocated Monitors 191 (Pb-TSP ICP/MS) 2 2 1 202 (Pb-PM10 ICP/MS) 1 1 0* * Pb-PM10 monitor is located at an NCore site and does not require collocation Method Code # of Sites # of Primary Monitors # of Active Collocated Monitors 1 0 Table 4.4-2 Pb Design Values at ADEQ Sites AQS Site ID Site Name 04-007-1002 Globe Highway 04-007-8000 Miami Golf Course 04-013-9997 JLG Supersite * Design Value not available 2012-2014 Design Value (µg/m3) 0.20 0.05 --* 4.5 SO2 Monitoring Network Requirements ADEQ operates a network of six SO2 monitors throughout Arizona. Authority to operate SO2 monitors has also been delegated to Maricopa and Pima Counties. Additionally, two sources, ASARCO and FMMI, operate SO2 State of Arizona Air Monitoring Network Plan for the Year 2015 Page 18 monitoring networks in Gila County for permit compliance and to support SIP rule requirements. ADEQ is currently negotiating with both sources to ensure that the monitors are operated under the required quality assurance requirements. In Miami, ADEQ runs the Miami Ridgeline site, the Miami Townsite, and the Miami Jones Ranch site. For Hayden, ADEQ currently operates an SO2 monitor at Hayden Old Jail. ADEQ initiated discussions with ASARCO regarding Globe Highway and Montgomery Ranch on the best means to meet the PQAO requirements. ADEQ also operates a trace-level SO2 monitor at its NCore site (JLG Supersite), as required by 40 CFR Part 58 Appendix D. An SO2 monitor was placed at Alamo Lake in February 2014 and is designated as the background SPM monitor. The SO2 monitoring requirements in 40 CFR Part 58 Appendix D are based on a Population Weighted Emissions Index (PWEI) calculated for each CBSA. CBSAs with PWEIs greater than 5,000 require at least one SO2 monitor, PWEIs greater than 100,000 require a minimum of two SO2 monitors, and PWEIs greater than 1,000,000 require three SO2 monitors. There are no PWEI greater than 5,000 in Arizona, but there are other SO2 monitors in Arizona, which are operated by Maricopa County and Pima County. Table 4.5-1 SO2 Design Values at ADEQ Sites AQS Site ID Site Name 04-007-0009 04-007-0011 04-007-0012 04-007-1001 04-012-8000 04-013-9997 Miami Ridgeline Miami Jones Ranch Miami Townsite Hayden Old Jail Alamo Lake JLG Supersite 2012-2014 1-Hour Design Value (ppb) 122 178 179 282 2 6 4.6 NO2 Monitoring Network Requirements ADEQ currently operates two NO2 monitors throughout the state of Arizona. These NO2 monitors are located at the JLG Supersite and Alamo Lake. JLG Supersite is operated to fulfill a PAMS requirement and Alamo Lake is designated as a SPM. The NO2 monitoring requirements set forth in 40 CFR Part 58 Appendix D are based on a combination of CBSA population and Annual Average Daily Traffic (AADT) counts. The first requirement to be considered is the CBSA population. CBSAs with populations greater than 500,000 are required to operate one near-roadway monitor, while CBSAs with populations greater than 2.5 million are required to operate two near-roadway monitors. Additionally, CBSAs with populations greater than 500,000 and containing roadway segments with 250,000 or greater AADT require two near-roadway monitors. As can be seen in Table 4.0-1, two CBSAs within Arizona (Phoenix and Tucson Metro areas) contain populations greater than 500,000, and therefore, require at least one NO2 near-roadway monitor. The Phoenix CBSA exceeds 2.5 million in population; therefore, two near-roadway monitors are needed in the Phoenix CBSA. Pima and Maricopa Counties will operate the required near-roadway monitors in Tucson and Phoenix, respectively. In addition to the near-roadway monitoring requirements set forth in 40 CFR Part 58 Appendix D, there is also a requirement for area-wide NO2 monitoring. CBSAs with populations of one million or more require one NO2 monitor to measure NO2 concentrations that represent neighborhood or larger spatial scales. The Phoenix metropolitan area is the only area within the state of Arizona that requires ambient monitoring of NO2. The current NO2 monitors operated by Maricopa and Pima Counties are meeting the current monitoring requirements set forth State of Arizona Air Monitoring Network Plan for the Year 2015 Page 19 in 40 CFR Part 58 Appendix D. ADEQ will continue to monitor NO2 at JLG Supersite as part of the NOx measurements required by the PAMS program. See Table 4.6-1 for design values. Table 4.6-1 NO2 Design Values at ADEQ Sites AQS Site ID Site Name 04-013-9997 04-012-8000 JLG Supersite Alamo Lake 2012-2014 1-Hour Design Value (ppb) 56 6 2014 Annual Mean (ppb) 16.21 0.75 4.7 CO Monitoring Network Requirements ADEQ operates only one CO monitor throughout Arizona, with plans to operate a second at Alamo Lake as a background SPM. The current CO monitor is located at the JLG Supersite and has sufficient sensitivity to monitor trace levels. This CO monitor fulfills NCore as well as PAMS monitoring requirements. Maricopa and Pima Counties operate the other required CO monitors within the State of Arizona. The Phoenix population exceeds the one million population requirement set forth in 40 CFR Part 58 Appendix D, therefore one CO monitor is required to be collocated with a near-road NO2 monitor. The required near-roadway monitor in Phoenix will be operated by Maricopa County. The most recent census data show the Tucson MSA is below one million and therefore nearroad CO monitoring is not required. The Trace-Level CO (COTL) analyzer that is currently operated by ADEQ exceeds the minimum monitoring requirements for the NCore and PAMS network design criteria set forth in 40 CFR Part 58 Appendix D. Due to the low range at which the JLG Supersite COTL analyzer operates, ADEQ urges some caution be exercised when utilizing these data for the purpose of NAAQS compliance. Under most circumstances, the data would be used to determine compliance with the CO NAAQS. However, due to the consistently low ambient concentrations, the trace-level analyzer’s operating range is set at 0-5 ppm, which is the range most frequently measured at JLG Supersite. This operating range is well below the CO NAAQS of 9 ppm, therefore, when/if under certain rare circumstances, the CO concentrations are > 5 ppm, determining compliance with the CO NAAQS may not be possible, because measurement uncertainty increases and becomes challenging to statistically quantify. Table 4.7-1 contains the most recent design values for CO at JLG Supersite. Table 4.7-1 CO Design Values at ADEQ Sites AQS Site ID Site Name 04-013-9997 JLG Supersite 2014 CO 1-Hour Max. Value (ppm) 3.065 2014 CO 8-Hour Max. Value (ppm) 2.2 4.8 PAMS Monitoring Network Requirements Network design and monitoring requirements for PAMS stations are provided in 40 CFR 58 Appendix D for areas classified as serious, severe, or extreme nonattainment for O3. Two sites are required for each area, providing all chemical measurements are made. Measurements include speciated VOCs, Carbonyls, NOx, trace-level reactive oxides of nitrogen (NOy), CO, O3, surface meteorology, and upper air meteorology. In 2008, EPA shortened the PAMS monitoring season to June through August. ADEQ's PAMS network consists of two ambient air monitoring sites in the Phoenix-Mesa-Scottsdale MSA and a meteorological site for the collection of upper air meteorological data and solar radiation data. JLG Supersite – Type 2 PAMS Site State of Arizona Air Monitoring Network Plan for the Year 2015 Page 20 The JLG Supersite was designated a PAMS site in 1999. Since the required manual method of eight three-hour canisters running daily is impractical due to increased expenses for staff, shipping, and analysis, ADEQ returned in 2008 to the 2006 monitoring schedule of a 24-hour canister sample every sixth day at the JLG Supersite during PAMS season for VOCs. This will be reviewed when the final results of the PAMS re-engineering program are available which is anticipated to include recommendations for changes to monitoring and new types of instruments. ADEQ also operates carbonyl, O3, CO, NOx, and surface meteorological monitoring equipment at JLG Supersite (see Table 4.8-1). Carbonyl monitoring at JLG Supersite is not currently required for PAMS, but because carbonyls are considered important for PAMS, there are no current plans to discontinue carbonyl monitoring at JLG Supersite. Table 4.8-1 JLG Supersite PAMS Instrumentation Parameter VOC * Carbonyl * Period of Operation Jan-Dec Jan-Dec Collection Method Canister Sampler Multi-port Carbonyl Sampler CO Jan – Dec Trace CO Frequency and Duration Every 6th day, 24 hrs. Every 6th day, 1-24 hr sample (DecJan). Every 6th day, 3 – 3 hr samples (0500-0800, 0800-1100, 11001400)(June-August) Hourly average O3 Jan – Dec O3 Analyzer Hourly average NOx Meteorology Jan – Dec Jan – Dec NOx Analyzer Hourly average Hourly average  Wind speed/direction  Temperature  Relative humidity * 24-hour VOC and Carbonyl measurements are also part of the NATTS program and collected year-round Queen Valley – Type 3 PAMS Site Queen Valley was designated a PAMS site in 2001. The site is located near the southeastern edge of the photochemical modeling grid domain and is considered to be downwind of the source of maximum precursor emissions in the Phoenix metropolitan area. Pollutants collected at the site include speciated PAMS VOCs, O3, total reactive NOy, and surface meteorology measurements. ADEQ’s 5-Year Network Assessment identified the Queen Valley site as not meeting PAMS monitoring requirements due to the lack of meteorological measurements. Meteorological instrumentation was added during the second quarter of 2011. Carbonyl samples are not required at Type 3 sites. Table 4.8-2 lists the instrumentation and monitoring schedule at the Queen Valley site. Table 4.8-2 Queen Valley PAMS Instrumentation Parameter VOC Period of Operation June – August Collection Method Multi-port sampler O3 NOy Meteorology Jan-Dec June – August Jan – Dec O3 Analyzer NOy Analyzer  Wind speed/direction  Temperature  Relative humidity Frequency and Duration Every 6th day, 24 hrs, and 3 – 3 hr samples (0500-0800, 1300-1600, 16001900) Hourly average Hourly average Hourly average Vehicle Emissions Laboratory – Upper Air Meteorology Site State of Arizona Air Monitoring Network Plan for the Year 2015 Page 21 This site is intended to be a meteorological ‘supersite’ and includes a pyranometer to measure total solar radiation, UV solar radiation, wind speed, wind direction, differential temperature (2 meters and 10 meters), and relative humidity. The National Weather Service (NWS) site at nearby Sky Harbor Airport collects barometric pressure and precipitation measurements. A Radio Acoustic Sounding System (RASS) and a Wind Profiler had also been collecting continuous upper air meteorological data for determination of mixing heights since 1998 until July 2012. The PAMS re-engineering workgroup noted the high maintenance cost and very limited use of the RASS and Wind Profiler data and unofficially recommended against its continued use – particularly if usable data is available from other sources. ADEQ considered the high operational cost and very limited data use when deciding to discontinue its operation. EPA is currently exploring the possibility of using mixing height data from some of the 1,000 ceilometers recently placed in use by NOAA. Table 4.8-3 Vehicle Emissions Laboratory PAMS Instrumentation Parameter Meteorology Period of Operation Jan – Dec      Method Pyranometer (total solar radiation) Ultra-violet (UV solar) Wind speed/direction Temperature Relative humidity Duration Hourly average 4.9 NCore Monitoring Network Requirements EPA has identified JLG Supersite as the required NCore site for the Phoenix metropolitan area. JLG Supersite has been a multipollutant monitoring site since its establishment in 1993. Currently, several monitoring programs are supported at this site, including: SLAMS, PAMS, NATTS, CSN, and meteorology. The required NCore parameters are listed in Table 4.9-1. The required NCore monitors were operational by January 1, 2011. The NCore-Pb requirement is being met by using the current Partisol 2000 PM10 sample filter for metals speciation. ADEQ recently received notice that the ERG analysis method for PM10 metals speciation was approved as a Federal Equivalent Method (FEM) for the analysis of Pb. While there will be no physical changes to the instrumentation or analysis method for Pb at the NCore site, the parameter code 85129 and method code 202 are now associated with Pb-PM10 data in AQS. Required Measurement PM2.5 FEM mass PM2.5 FRM mass PM10 FEM mass PMcoarse FEM mass PM2.5 speciation organic and elemental carbon, major ions, and trace metals Table 4.9-1 JLG Supersite NCore Instrumentation Frequency/Duration Status Hourly 24 hour average every 3rd day Hourly Hourly 24 hour average; every 3rd day Met One BAM 1020 FEM pair, designated primary Thermo Partisol 2000 is current instrument; PM2.5 samples collected since 1999 Met One BAM 1020 FEM pair Met One BAM 1020 FEM pair, difference method Met One SuperSASS with URG module is current instrument; STN/CSN samples collected since 1999 State of Arizona Air Monitoring Network Plan for the Year 2015 Page 22 Pb 24 hour average; every 6th day O3 CO (Trace Level) SO2 (Trace Level) NO/NO2/NOx NO/NOy Surface meteorology Hourly Hourly Hourly Hourly Hourly Hourly Currently Pb measurements are from the NATTS PM10 metals sampler. EPA recently approved ERG’s ICP-MS analysis method as an FEM. API Teledyne 400E Ecotech EC9830T Ecotech EC9850T Ecotech EC9841 Ecotech EC9843 RM Young anemometer, Vaisala temperature/relative humidity probe currently in operation 4.10 SIP Monitoring Network Requirements ADEQ, along with other delegated agencies, is responsible for the preparation and submittal of SIPs for nonattainment and maintenance areas in Arizona. ADEQ is responsible for conducting ambient air monitoring for areas not included within Maricopa, Pima, and Pinal Counties or tribal lands. Permitted sources are also responsible for monitoring air quality, if it is included in their air quality permit. Some monitoring sites are specifically named in the area’s SIP; other monitoring sites are not specifically named, but are representative of the air quality in that SIP area. Table 4.10-1 lists the ADEQ and source-operated monitors used to determine SIP compliance. Table 4.10-1 SIP Network Monitoring Requirements Area and County Pollutant Classification Phoenix, Maricopa Phoenix, Maricopa Phoenix-Apache Junction, Maricopa and Pinal Ajo, Pima Bullhead City, Mohave Douglas-Paul Spur, Cochise Hayden, Gila and Pinal Miami, Gila Nogales, Santa Cruz Payson, Gila Phoenix, Maricopa, and Pinal (Apache Junction portion) Phoenix (Salt River Area) Rillito, Pima Yuma, Yuma Nogales, Santa Cruz Ajo, Pima Douglas, Cochise Hayden, Gila and Pinal CO O3 1-hr O3 8-hr Maintenance/Attainment Maintenance/Attainment “Basic” Nonattainment PM10 PM10 PM10 PM10 PM10 PM10 PM10 PM10 Moderate Nonattainment Maintenance/Attainment Moderate Nonattainment Moderate Nonattainment Moderate Nonattainment Moderate Nonattainment Maintenance/Attainment Serious Nonattainment PM10 PM10 PM2.5 SO2 SO2 SO2 Moderate Nonattainment Moderate Nonattainment Nonattainment Maintenance/Attainment Maintenance/Attainment Nonattainment – Primary Miami, Gila SO2 Maintenance/Attainment ADEQ SIP Sites JLG Supersite JLG Supersite, Tonto National Monument Alamo Lake, JLG Supersite, Queen Valley, Tonto National Monument Ajo Bullhead City (Post Office) Douglas Red Cross, Paul Spur Chemical Lime Plant Hayden Old Jail Miami Golf Course & Miami Ridgeline Nogales Post Office Payson Well Site JLG Supersite Rillito Yuma Supersite Nogales Post Office No network or commitment No network or commitment ADEQ (SO2, MET): Hayden Old Jail ASARCO (5 SO2, 3 MET [no MET at Jail or Garfield]): Globe Hwy, Garfield Ave., Montgomery Ranch, Hayden Old Jail, Hayden Junction ADEQ: Miami Ridgeline, Miami Jones Ranch, Miami Townsite FMMI (SO2, MET) Miami Jones Ranch, Miami Townsite State of Arizona Air Monitoring Network Plan for the Year 2015 Page 23 Area and County Morenci, Greenlee San Manuel, Pima and Pinal Regional Haze, 12 Class 1 areas Pollutant SO2 SO2 Visibility Impairing pollutants (VOC, NOx, SO2, PM10, PM2.5, PM2.5 species) Classification Maintenance/Attainment Maintenance/Attainment Statewide – IMPROVE monitors ADEQ SIP Sites No network or commitment No network or commitment ADEQ Protocol sites: Douglas Red Cross, Organ Pipe National Monument, JLG Supersite, Queen Valley, Saguaro West National Monument, Meadview NPS / USFS sites: Chiricahua Entrance Station, Greer Water Treatment Plant, Grand Canyon - Indian Gardens, Grand Canyon - Hance Camp, Ike’s Backbone, Meadview, Petrified Forest National Park, Pleasant Valley Ranger Station, Saguaro National ParkEast, Sycamore Canyon, Tonto National Monument Note: Sites in italics are specifically required in SIP; others meet the general SIP requirement that representative monitoring be conducted (no specific monitoring sites are named in SIP). 4.11 Source Compliance Monitoring Network Requirements ADEQ requires select major and minor point sources in the state to conduct ambient monitoring for selected pollutants in and around their sources. Some requirements are for prevention of significant deterioration (PSD) monitoring prior to operation of the facility. Other monitoring requirements are for the duration of the permit or timeframe specified therein. ADEQ activities have been limited to regular performance audits of instruments at some of these sites and review of ambient monitoring data submitted according to the permit requirements. Sources are required to review and validate their data and submit quality assurance documents to ADEQ with the data. Table 4.11-1 lists the monitors operated by ADEQ permitted sources. Any data submitted to AQS needs to be approved by a PQAO that meets EPA’s QA requirements. Data from the ASARCO and FMMI monitors are being used for regulatory decision making and will need to be submitted to AQS. In spring 2012, ADEQ sent letters to ASARCO and FMMI discussing the PQAO requirements and suggesting that they meet with ADEQ to discuss options. FMMI representatives met with ADEQ, and in January 2013, ADEQ established monitors at the existing FMMI’s Miami Jones Ranch and Miami Townsite sites in the Miami, AZ area. As of May 8th, 2015 FMMI is no longer required to monitor SO2 at Miami Jones Ranch and Miami Townsite. Table 4.11-1 Source Compliance Monitoring Network Site Name City Globe Highway ASARCO – Hayden – Garfield Ave. ASARCO – Montgomery Ranch ASARCO – Hayden Junction Hayden Old Jail 1 Chemical Lime Plant Winkelman Hayden Hayden Hayden Junction Hayden Nelson Drake Cement Sycamore Canyon PCC – Clarkdale NW Clarkdale Pollutant(s) SO2 SO2 SO2 SO2 SO2 Meteorology PM10, PM2.5 mass and ammonium speciation, Meteorology PM10 mass and metals speciation, Meteorology AQS Submittal No No No No No No No No State of Arizona Air Monitoring Network Plan for the Year 2015 Page 24 Site Name City Pollutant(s) AQS Submittal PM10 mass and metals speciation, PCC – Clarkdale SE Clarkdale Meteorology No PM10, H2SO4, Carlota Mine – Sanctuary Globe Meteorology No 1 ADEQ also operates an SO2 monitor at this site. The ADEQ data are submitted to AQS while the facility data are not. 4.12 Class 1 Visibility Network As stated previously, visibility monitoring networks track impairment in specified national parks and wilderness areas called Class 1 areas based on designations made by the 1977 CAA Amendments. The evaluations, performed by the USFS and NPS, reviewed the wilderness areas of parks and national forests which were designated as wilderness before 1977, were more than 6,000 acres in size, and had visual air quality as an important resource for visitors. Of the 156 Class 1 areas designated across the nation, 12 are located in Arizona. For the Class 1 area designations, EPA initiated a nationally operated monitoring network in 1987 called the Interagency Monitoring of PROtected Visual Environments (IMPROVE) program. The purpose of this network is to characterize broad regional trends in visibility conditions using monitoring data collected in or near Class 1 areas across the United States. Originally, the national IMPROVE network was made up of approximately 30 sites at Class 1 areas. During 1999-2000 the number of sites increased to approximately 110. ADEQ, Pima County, and federal land managers at Arizona's Class 1 areas cooperatively operate the visibility monitoring network in Arizona. The current network is described in Table 4.12-1. In addition to the Class 1 IMPROVE monitors listed in Table 4.12-1, ADEQ also operates one IMPROVE monitor at the Douglas Red Cross site, and two collocated IMPROVE monitors at the JLG Supersite. The JLG Supersite serves as an urban IMPROVE monitor and has been used to provide comparative analysis with data from the CSN network. The Douglas Red Cross site may serve multiple objectives. In 2012, a review of the data from the Douglas Red Cross site was prepared by Air Resource Specialists and provided to ADEQ. These data will be used to evaluate if this site should be continued or if it could be better utilized at another location. See the IMPROVE map in Appendix B for a spatial representation of the IMPROVE monitoring network and Class 1 areas within the state of Arizona. Table 4.12-1 2015 Arizona Class 1 Visibility Monitoring Network Geographic Area Represented Background Chiricahua National Monument, Chiricahua Wilderness Area and Galiuro USFS Wilderness Grand Canyon National Park Mazatzal and Pine Mountain USFS Wilderness Mount Baldy Petrified Forest National Park Saguaro National Park Sierra Ancha USFS Wilderness Superstition USFS Wilderness Sycamore Canyon USFS Wilderness Monitoring Location Meadview, Organ Pipe National Monument Chiricahua Entrance Station Hance Camp Ike’s Backbone Greer Water Treatment Plant Petrified Forest East Unit and West Unit Pleasant Valley Ranger Station Tonto National Monument, Queen Valley Sycamore Canyon (Garland Prairie) State of Arizona Air Monitoring Network Plan for the Year 2015 Page 25 4.13 Urban Haze Monitoring Network ADEQ began studying the nature and causes of urban haze by conducting studies during the winter of 1989-90 in Phoenix and during the winter of 1992-93 in Tucson. These studies recommended long-term, year-round monitoring of visibility in both areas. In 1993, ADEQ began deploying visibility monitoring equipment in Phoenix and Tucson. Executive Order 2000-3 directed by the Governor’s Brown Cloud Summit was to establish options for a visibility standard or other method to track progress in improving visibility in the Phoenix area. The Summit concluded that a daily visibility index for the metropolitan area should have its characteristics defined through a public survey process. This process called for a representative cross-section of residents of Area A (as described in House Bill 2538, roughly the Phoenix metropolitan area), to determine what visual air qualities are desirable, what visual range is acceptable, and how often the combination of acceptable visual range and air quality is preferred. Through a series of meetings in 2002 and early 2003, ADEQ and the Visibility Index Oversight Committee designed the visibility survey, selected a contractor to conduct the survey, oversaw the completion of the field portion of the survey, and defined a recommended visibility index. The Visibility Index Oversight Committee Final Report was issued in early 2003 summarizing the visibility index. Equipment currently used to evaluate urban visibility includes transmissometers, nephelometers, and digital camera systems. The Phoenix urban haze network consists of a transmissometer for measuring light extinction along a fixed path length of four and a half kilometers, three nephelometers for measuring light scattering, and five digital camera systems to record visual characteristics of the urban area. The Tucson urban haze network was shut down in September 2010. In early 2011, a draft summary report was written which summarizes the nephelometer and transmissometer data that were collected since 1997. The report provides summaries and trends in urban visibility data, as well as meteorological data summaries in the form of wind roses. This report is meant to serve as a final data summary for the Tucson Urban Haze network. Information from this report may be utilized in the future if further modifications are needed to the Urban Haze Network. The current Phoenix urban haze sites (and their status) are described in Table 4.13-1. ADEQ continues to evaluate the Urban Haze program. The high-resolution images from these cameras can be viewed online at http://www.phoenixvis.net. Table 4.13-1 Phoenix Urban Haze Monitoring Network Site Name ADEQ Building Banner Mesa Medical Center Dysart Estrella Estrella Mountain Community College JLG Supersite North Mountain Summit Phoenix Transmissometer (Phoenix Baptist Hospital to Holiday Inn Hotel) Vehicle Emissions Laboratory Parameter(s) Measured High Resolution Digital Camera High Resolution Digital Camera Light Scattering (Bscat) Nephelometer Light Scattering (Bscat) Nephelometer High Resolution Digital Cameras IMPROVE 2 High Resolution Digital Cameras Transmissometer (Bext) Light Scattering (Bscat) Nephelometer State of Arizona Air Monitoring Network Plan for the Year 2015 Page 26 4.14 Meteorology Monitoring Network ADEQ operates meteorological equipment at selected sites throughout its network (see Table 4.14-1). Some sites were originally established because other meteorology networks (NWS, AZMet, etc.) were not located near ADEQ's ambient air quality sites. ADEQ has begun to expand the meteorology monitoring network and standardize the meteorological measurements so that all sites collect measurements of wind speed, wind direction, temperature, and relative humidity. Except for the items mentioned above, ADEQ does not have any specific plans to make changes to the meteorological network, but may add additional meteorological equipment at existing SLAMS sites as resources permit. At this time, ADEQ plans to only submit meteorological data that are required by 40 CFR Part 58.16 to EPA’s AQS database. If future resources allow additional meteorological data submittals to the AQS database, ADEQ may do so on a voluntary basis. A spatial representation of ADEQ’s meteorological monitoring network can be found in Appendix B. Table 4.14-1 Meteorology Monitoring Network Site Temp. Temp. Lapse Rate System Relative Humidity Wind Total Horizontal Solar Radiation Ultraviole t Solar Radiation Report to AQS Alamo Lake Ajo Douglas Red Cross Globe Highway Hayden Old Jail X X X X X X No No X X X No X X X X X X No No JLG Supersite X X X Yes X X X No X X X No X X X No X X X No Queen Valley X X X Yes Rillito Vehicle Emissions Laboratory Yuma Supersite X X X No X X X X Miami Golf Course Nogales Post Office Paul Spur Chemical Lime Plant Payson Well Site X X X X X Solar only No State of Arizona Air Monitoring Network Plan for the Year 2015 Page 27 Comments For NCore / PAMS support For PAMS support For PAMS support 5.0 QUALITY ASSURANCE ADEQ sustains a quality system as required by EPA to ensure high quality data are produced that meet the users’ needs. The EPA primarily specifies the quality assurance (QA) requirements for operating SLAMS, SPM, CSN, NCore, NATTS, PAMS, and prevention of significant deterioration (PSD) air monitors in 40 CFR Part 58 Appendix A, the Quality Assurance Handbook for Air Pollution Measurement Systems: Volume II: Ambient Air Quality Monitoring Program, technical assurance documents (TADs), and other supporting guidance documents. In response, ADEQ develops quality assurance plans for air monitoring networks, which provide detailed information regarding the specifics of each air monitoring network and how data will be managed. Components of ADEQ’s quality system include, but are not limited to:  ADEQ being established as the primary quality assurance organization (PQAO) for the criteria and noncriteria pollutant air monitoring data collected and reported to EPA’s air quality system (AQS).  An agency-level Quality Management Plan (QMP), which is an “umbrella” document that details, in broad terms, the strategies used to carry out QA/QC in environmental data collection activities.  Division-level quality assurance program plans (QAPPs) for each major, ongoing air monitoring network. Each QAPP describes:  o purpose for operating the monitoring station or network o data quality objectives (DQOs) and/or measurement quality objectives (MQOs) along with data quality indicators (DQIs) that specify the amount of tolerable error in the data using statistical metrics o variety of regularly occurring quality control (QC) checks along with pass/fail criteria o types of QA assessments and reports needed from the network o data validation processes and data reporting requirements Unit-level standard operating procedures (SOPs) that document procedures to assure that work products are reliable, reproducible, and consistent in quality. SOPs also serve to clearly communicate any process customizations in-use, providing a means of attesting that work products are credible, legally defensible, and meet or exceed our customers’ and/or stakeholders’ needs or requirements. ADEQ uses a multi-tiered approach to data validation to ensure consistent quality. It requires all data to move through different levels of QA by separate reviewers. Data have five different levels associated with each tier level.      Raw – Original unchanged data recorded by the sampler or produced by laboratory analysis. Level 1 – Data are reviewed programmatically using software written to flag data. The data are flagged valid or invalid based on instrumentation parameters. Level 2 – Data are reviewed manually on a daily to weekly basis by an initial data reviewer to flag any discrepancies found. This gives the data a preliminary verification decision and identifies outliers, anomalous data and instrumentation/laboratory problems. Level 3 – Data are reviewed manually on a monthly to quarterly basis by the final data reviewer by looking at the data spatially and temporally. QC measures are incorporated, environmental events are identified, and a final determination on the validity of data is made. Certified – Data are uploaded to AQS and are certified annually by ADEQ. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 28 5.1 EPA QA Reports and Network Performance Periodically, EPA publishes reports for some of the criteria pollutant networks, and potentially non-criteria pollutant networks, that rate and/or rank monitoring organizations’ performance over a three year period. The QA Team, as well as other personnel in DM&QA, review these reports to gauge how well our networks are performing with those across the nation. If needed, corrective actions are taken to ensure data of the highest quality possible are collected. ADEQ is monitoring the PM2.5 network to see how it performs nationally based on the results published in the most recent EPA report, the 3-Year Quality Assurance Report Calendar Years 2005, 2006, and 2007 The SLAMS PM2.5 Ambient Air Monitoring Program (February 2009). 5.2 EPA Data Reports The 2014 Data Certification Letter and adjoining AMP 600 and AMP 450N reports were submitted to Region 9 on April 17th, 2015. The data certification sections of AQS were also updated reflecting ADEQ’s recommendations for certifying the data. State of Arizona Air Monitoring Network Plan for the Year 2015 Page 29 Appendix A – Definitions and Abbreviations AAAD Air Assessment Ambient Database AAS Air Assessment Section AADT Annual Average Daily Traffic ADEQ Arizona Department of Environmental Quality AFL Air Filter Lab AMU Air Monitoring Unit ASARCO American Smelting and Refining Company, LLC ATEC Atmospheric Technologies, Inc. Auto GC/MS Automated Gas Chromatograph/Mass Spectrometer AQS Air Quality System (EPA database) BAM Beta Attenuation Monitor Bext Total Light Extinction Bscat Light Scattering CAA Clean Air Act CBSA Core Based Statistical Area CEDES Commission for Ecology and Sustainable Development CFR Code of Federal Regulations CO Carbon Monoxide CSN Chemical Speciation Network DCS Data Collection System DM&QA Data Management & Quality Assurance Unit DQO Data Quality Objective E-BAM Environment Proof - Beta Attenuation Monitor EDO Environmental Data Operation EPA Environmental Protection Agency ERG Eastern Research Group, Inc. FEM Federal Equivalent Method FMMI Freeport McMoRan Copper and Gold Inc. State of Arizona Air Monitoring Network Plan for the Year 2015 Appendix A Page 1 FRM Federal Reference Method HAP Hazardous Air Pollutant ICP-MS Inductively Coupled Plasma Mass Spectrometry IMPROVE Interagency Monitoring of PROtected Visual Environments MCAQD Maricopa County Air Quality Department MET Meteorological Measurements (wind, temperature, relative humidity) MQO Measurement Quality Objective MSA Metropolitan Statistical Area μg/m3 Micrograms per Cubic Meter NAAQS National Ambient Air Quality Standard NATTS National Air Toxics Trends Station NCore National Core multipollutant monitoring stations NIST National Institute of Standards and Technology NM National Monument NO2 Nitrogen Dioxide NOx Nitrogen oxides NOy Reactive Nitrogen Oxides NPAP National Performance Audit Program NPEP National Performance Evaluation Program NPS National Park Service NWS National Weather Service O3 Ozone OAQPS Office of Air Quality Planning and Standards PAHs Polycyclic Aromatic Hydrocarbons PAMS Photochemical Assessment Monitoring Station Pb Lead PCAQCD Pinal County Air Quality Control District PDEQ Pima County Department of Environmental Quality PE Performance Evaluation PEP Performance Evaluation Program State of Arizona Air Monitoring Network Plan for the Year 2015 Appendix A Page 2 PM Particulate Matter PM10 Particulate Matter ≤ 10 microns PMcoarse Coarse Particulate Matter between 2.5 to 10 micrometers aerodynamic diameter, may also be denoted as PM10-2.5 PM2.5 Particulate Matter ≤ 2.5 microns POC Parameter Occurrence Code ppb Parts Per Billion ppm Parts Per Million PQAO Primary Quality Assurance Organization PSD Prevention of Significant Deterioration PWEI Populated Weighted Emissions Index QA Quality Assurance QAPP Quality Assurance Program Plan QC Quality Control QMP Quality Management Plan RASS Radar Acoustic Sounding System SEMARNAT Secretariat of Environment and Natural Resources SIP State Implementation Plan SLAMS State and Local Air Monitoring Stations SO2 Sulfur Dioxide SOP Standard Operating Procedure SPM Special Purpose Monitor STN Speciation Trends Network TAD Technical Assistance Document TEOM Tapered Element Oscillating Microbalance TSA Technical System Audit USFS United States Forest Service VOC Volatile Organic Compound State of Arizona Air Monitoring Network Plan for the Year 2015 Appendix A Page 3 Appendix B – Network Maps There are ten maps in this section illustrating the location of ADEQ monitors:  CO Network  NO2 Network  O3 Network  SO2 Network  Pb Network  PM10 Network  PM2.5 Network  Meteorological Network  Urban Visibility Network  IMPROVE Network & Class I Wilderness areas State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 1 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 2 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 3 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 4 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 5 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 6 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 7 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 8 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 9 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 10 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix B Page 11 ` Appendix C – Current Monitors by Program or Network This appendix contains detailed information about monitors that are operated by ADEQ, or monitors that ADEQ has a strong association with (e.g. IMPROVE monitors). Only those monitors that are in operation at the time that this network plan was created are included in this appendix. Monitors that are proposed to be installed or those that were discontinued prior to the creation of this network plan are not included in this appendix. Since individual pollutants or networks have specific monitoring or siting criteria, this appendix was created so that siting criteria can be easily identified and evaluated throughout a program or network. See Appendix D for detailed information on specific monitoring sites. NON-REGULATORY NETWORKS Meteorology Temp/RH ..........................................................................................................................Appendix C Page 4 Wind .................................................................................................................................Appendix C Page 6 Special Purpose Monitors (SPM)............................................................................................Appendix C Page 8 NAAQS-RELATED NETWORKS State & Local Air Monitoring Stations (SLAMS) CO ....................................................................................................................................Appendix C Page 9 NO2 .................................................................................................................................Appendix C Page 10 O3 ................................................................................................................................... Appendix C Page 11 SO2..................................................................................................................................Appendix C Page 12 Pb ....................................................................................................................................Appendix C Page 13 PM10................................................................................................................................Appendix C Page 14 PM2.5 ...............................................................................................................................Appendix C Page 16 Chemical Speciation Network (CSN) ...................................................................................Appendix C Page 17 National Core Multi-Pollutant Monitoring Stations (NCore) ...............................................Appendix C Page 18 Photochemical Assessment Monitoring Stations (PAMS) ...................................................Appendix C Page 20 AIR TOXICS National Air Toxics Trends Sites (NATTS) .........................................................................Appendix C Page 23 Urban Air Toxics Monitoring Program (UATMP) ...............................................................Appendix C Page 24 VISIBILITY Urban Haze Camera............................................................................................................................Appendix C Page 25 Nephelometer .................................................................................................................Appendix C Page 26 Transmissometer ............................................................................................................Appendix C Page 27 Temp/RH ........................................................................................................................Appendix C Page 28 Interagency Monitoring of Protected Visual Environments (IMPROVE) ............................Appendix C Page 29 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix C Page 1 ` Definitions for Appendix C – Current Monitors by Program or Network Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Spatial scale (micro, neighborhood) Monitoring start date (MM/DD/YYYY) Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DDMM/DD) Probe height (meters) Distance from supporting structure (meters) Distance from obstructions on roof (meters) Distance from obstructions not on roof (meters) Official name for the site as written in ADEQ’s AirVision Database The pollutant(s) or parameter(s) being collected or measured at the site and the POC is the Primary Occurrence Code for the instrument, as it is in ADEQ’s AirVision Database The AQS code representing a specific pollutant being measured or monitored Purpose of monitoring for the parameter at the site (Public Information, NAAQS Comparison, or Research) A brief description of the intended purpose of the monitor’s measurements (Extreme Downwind, Highest Concentration, Max Ozone Concentration, Max Precursor Impact, Population Exposure, Source Oriented, Upwind Background, General / Background, Regional Transport, Welfare-Related Impacts, Quality Assurance, or Other) The associated monitoring network for the monitor (IMPROVE, Index Site, Industrial, NATTS, NCore, Non-EPA Federal, PAMS, Proposed NCore, QA Collocated, SLAMS, Special Purpose, Supplemental Speciation, Trends Speciation, Tribal Monitor, Unofficial PAMS) The specific make and model of the monitor or instrument used in the network The AQS code representing the particular method for collecting samples of the specified instrument Denotes if the instrument is a Federal Reference Method, Federal Equivalency Method, Approved Regional Method (for continuous PM2.5 only), or other according to the Federal Registry Name of agency collecting data Name of laboratory performing sample analysis Name of agency reporting the data Area represented by an air quality monitor (microscale: 0 – 100 m, middle scale: 0.1 – 0.5 km, neighborhood: 0.5 – 4 km, urban: 4 – 50 km, regional: ~50 – 500 km, or national/global) Date that the monitor was started at the site Frequency the instrument collects samples or measurements (e.g. hourly, daily, 1:3, 1:6, etc.) Theoretical frequency for particular matter instrument based on Ratio to Standard Figure in 40CFR Part 58.12 (e.g. hourly, daily, 1:3, 1:6) Period that the instrument collects samples or measurements throughout a given year (expressed as a range of months) Distance the probe is from the ground in meters (O3 and SO2 probes must be between 2 and 15 meters; others pollutants must be between 2 to 7 meters; meteorology typically 2 or 10 meters) For rooftop probe(s) only. The separation distance is in reference to walls, parapets, or penthouses located on roof Distance the instrument inlet is from the closest obstruction on the roof in meters (probes and inlets must be at least 1 meter from obstructions) Distance the instrument inlet is from the closest obstruction not on the roof in meters (probes and inlets must be at least 1 meter from obstructions) State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix C Page 2 ` Distance from trees (meters) Obstruction Height above Probe (meters) Tree Height above Probe (meters) Distance to furnace or incinerator flue (meters) Distance between collocated monitors (meters) Unrestricted airflow (degrees) Restricted airflow (degrees) Prevailing wind direction (degrees) Probe material for reactive gases Residence time for reactive gases (seconds) Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb Distance the instrument inlet is from the nearest tree in meters (must be a minimum of 10 meters from drip line) Height the obstruction is above the inlet (distance from the obstruction to the inlet must be at least 2x the height that the obstacle protrudes above the inlet). Trees can be considered obstructions depending on density of foliage, therefore the same obstruction requirements apply to trees Height the tree is above the inlet. Trees that are within 10 meters of inlet may not cause issue if the tree height is at or below the inlet height. Furthermore, as trees grow they may become obstructions, therefore it is important to capture the height of trees Distance the instrument inlet is from the nearest furnace or incinerator flue in meters (for Pb and SO2; designed to avoid undue influences from minor sources) Distance between the centers of collocated instruments in meters (must be between 1 and 4 meters) Angular measure (in degrees) of the area around an instrument that is free from obstructions (minimum of 180°) Direction the airflow is restricted in degrees as they are associated with the cardinal directions (i.e. 90º = E) (must not be in the direction of the prevailing winds) Direction the wind predominately comes from in degrees during the season of greatest pollutant concentration. Used to determine if restricted airflow is in the direction of the prevailing wind. Type of material probe is made of (SO2, NO2, O3 must have FEP Teflon or borosilicate glass; PAMS and VOCs must be borosilicate glass or stainless steel) Number of seconds it takes a sample of air to travel from the inlet to the instrument (reactive gases must be less than 20 seconds) Are there any planned changes to the monitoring in the next 18 months? (Y or N) Are the data being compared against the annual PM2.5 NAAQS standards? (Y or N) Frequency at which flow rate verifications occur for manual particulate matter and lead instruments (daily, weekly, bi-weekly, monthly) Frequency at which flow rate verifications occur for automated particulate matter instrument (daily, weekly, bi-weekly, monthly) Frequency at which zero/span/precision checks occur for gaseous instruments (daily, weekly, bi-weekly, monthly) Date the last Performance Evaluation audit was performed on the gaseous instrument. (SO2, NO2, O3, CO, etc.) (MM/DD/YYYY) Dates of the last two audits on the particulate matter and lead instruments flow rate (MM/DD/YYYY, MM/DD/YYYY) State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix C Page 3 Non-Regulatory - Meteorology - Temp/RH Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Spatial Scale (micro, neighborhood) Monitoring start date (MM/DD/YYYY) Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Ajo Alamo Lake Douglas Red Cross Globe Highway Hayden Old Jail JLG Supersite Miami Golf Course Temp/RH (1) 62101, 62201 -- Temp/RH (1) 62101, 62200 -- Temp/RH (1) 62101, 62201 -- Temp/RH (1) 62101, 62201 -- Temp/RH (1) 62101, 62201 -- Temp/RH (1) 62101, 62201 -- Population Exposure Population Exposure Population Exposure Source Oriented Population Exposure Source Oriented --Vaisala HMP 155 Probe 040 -ADEQ -ADEQ Neighborhood 02/11/2014 Continuous --Vaisala HMP 155 Probe 039 -ADEQ -ADEQ Neighborhood 07/09/2015 Continuous --Vaisala HMP 155 Probe 040 -ADEQ -ADEQ Neighborhood 08/16/2012 Continuous Temp/RH (1) 62101, 62201 -Highest Concentration, Source Oriented --Vaisala HMP 155 Probe 040 -ADEQ -ADEQ Neighborhood 04/15/2011 Continuous --Vaisala HMP 155 Probe 040 -ADEQ -ADEQ Neighborhood 02/02/2011 Continuous SLAMS NCore, PAMS Vaisala HMP 155 Probe 040 -ADEQ -ADEQ Neighborhood 07/01/1993 Continuous --Vaisala HMP 155 Probe 040 -ADEQ -ADEQ Neighborhood 06/08/2011 Continuous -- -- -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 Probe height (meters) 2.3 2.2 2 2 2.1 2 2 Distance from supporting structure (meters) 1.2 1 -- -- 0.5 1 -- Distance from obstructions on roof (meters) -- -- -- -- -- 2 -- Distance from obstructions not on roof (meters) -- -- -- -- -- 20 -- Distance from trees (meters) 14 -- 13 3.6 12 20 6 Obstruction Height above Probe (meters) -- -- -- -- -- 1 -- Tree Height above Probe (meters) -- -- -- -- -- 8 -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- -- 360 360 360 360 270 150 330 Restricted airflow (degrees) -- -- -- -- 250-340 140-350 310-350 Prevailing wind direction (degrees) -- -- -- -- -- -- -- Probe material for reactive gases -- -- -- -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers N N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters --- --- --- --- --- --- --- Last two semi-annual flow rate audits PM and Pb -- -- -- -- -- -- -- Sampling season (MM/DD-MM/DD) Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 4 Non-Regulatory - Meteorology - Temp/RH continued Nogales Post Office Paul Spur Chemical Lime Plant Payson Well Site Queen Valley Rillito Vehicle Emissions Laboratory Yuma Supersite Local Site Name Pollutant (POC) Temp/RH (1) Temp/RH (1) Temp/RH (1) Temp/RH (1) Temp/RH (1) Temp R/H (1) Temp/RH (1) Parameter code 62101, 62201 62101, 62201 62101, 62201 62101, 62201 62101, 62201 62101, 62201 62101, 62201 -Population Exposure --Vaisala HMP 155 Probe 040 -- -Population Exposure --Vaisala HMP 45C Probe 040 -- -- Downwind Source Oriented SLAMS PAMS Vaisala HMP 45C Probe 040 --Vaisala HMP 155 Probe 040 -Population Exposure --Vaisala HMP 155 Probe 040 -Population Exposure --Vaisala HMP 155 Probe 040 Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Source Oriented --Vaisala HMP 155 Probe 040 -- -- -- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ -- -- -- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Neighborhood Spatial Scale (micro, neighborhood) Neighborhood Middle Neighborhood Regional Middle Neighborhood Monitoring start date (MM/DD/YYYY) 08/11/2011 12/01/2011 05/30/1991 06/23/2003 03/30/2010 05/11/1999 03/17/2010 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous Continuous Continuous Continuous Continuous Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) -- -- -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 2 5.2 2 2 2.6 2.4 4.5 Distance from supporting structure (meters) -- -- -- 0.50 -- -- 1 Distance from obstructions on roof (meters) -- -- -- -- -- -- -- Distance from obstructions not on roof (meters) -- -- 5 -- -- -- 1 Distance from trees (meters) 5 9 1 1.2 19 10 -- Obstruction Height above Probe (meters) -- -- -- -- -- -- -- Tree Height above Probe (meters) -- -- -- -- -- -- -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- -- 360 360 250 180 290 360 270 Restricted airflow (degrees) -- -- -- 90-270 35-105 -- 0-90 Prevailing wind direction (degrees) -- -- -- -- -- -- -- Probe material for reactive gases -- -- -- -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers N N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters --- --- --- --- --- --- --- Last two semi-annual flow rate audits PM and Pb -- -- -- -- -- -- -- Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 5 Non-Regulatory - Meteorology - Wind Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Spatial Scale (micro, neighborhood) Monitoring start date (MM/DD/YYYY) Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) Distance from supporting structure (meters) Distance from obstructions on roof (meters) Distance from obstructions not on roof (meters) Distance from trees (meters) Obstruction Height above Probe (meters) Tree Height above Probe (meters) Distance to furnace or incinerator flue (meters) Distance between collocated monitors (meters) Unrestricted airflow (degrees) Restricted airflow (degrees) Prevailing wind direction (degrees) Probe material for reactive gases Residence time for reactive gases (seconds) Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb Ajo Alamo Lake Douglas Red Cross Globe Highway Hayden Old Jail JLG Supersite Miami Golf Course Wind (1) 61103, 61104 -- Wind (1) 61103, 61103 -- Wind (1) 61103, 61104 -- Wind (1) 61103, 61104 -- Wind (1) 61103, 61104 -- Wind (1) 61103, 61104 -- Population Exposure Population Exposure Population Exposure Source Oriented Population Exposure Source Oriented --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Neighborhood 07/01/1969 Continuous -01/01-12/31 10 ---14 ----360 ----N -- --RM Young 5305 Anemometer 019 -ADEQ -ADEQ Neighborhood 07/09/2015 Continuous -01/01-12/31 11 --------360 ----N -- --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Neighborhood 08/06/2012 Continuous -01/01-12/31 10 ---13 ----360 ----N -- Wind (1) 61103, 61104 -Highest Concentration, Source Oriented --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Neighborhood 04/15/2011 Continuous -01/01-12/31 10 --------360 ----N -- --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Neighborhood 02/02/2011 Continuous -01/01-12/31 10 --------360 ----N -- SLAMS NCore, PAMS RM Young 5305 Anemometer 020 -ADEQ -ADEQ Neighborhood 07/01/1993 Continuous -01/01-12/31 11.5 ---20 ----360 ----N -- --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Neighborhood 06/08/2011 Continuous -01/01-12/31 10.5 --------360 ----N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --- --- --- --- --- --- --- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 6 Non-Regulatory - Meteorology - Wind continued Nogales Post Office Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Paul Spur Chemical Lime Plant Vehicle Emissions Laboratory Yuma Supersite --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Middle 01/08/2004 Continuous -01/01-12/31 10.4 ---20 --- Wind (1) 61103, 61104 -Population Exposure --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Neighborhood 05/11/1999 Continuous -01/01-12/31 10 --30 50 --- Wind (1) 61103, 61104 -Population Exposure --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Neighborhood 03/17/2010 Continuous -01/01-12/32 10 6.3 ------ Payson Well Site Queen Valley Rillito Wind (1) 61103, 61104 -- Wind (1) 61103, 61104 -- Downwind Source Oriented --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Middle 12/01/2011 Continuous -01/01-12/31 10 ---35 --- Wind (1) 61103, 61104 -Population Exposure --RM Young 5103 Anemometer 020 -ADEQ -ADEQ Neighborhood 05/30/1991 Continuous -01/01-12/31 10 ---2 --- SLAMS PAMS RM Young 5103 Anemometer 020 -ADEQ -ADEQ Regional 06/23/2003 Continuous -01/01-12/31 9 6.5 ------ Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Spatial Scale (micro, neighborhood) Monitoring start date (MM/DD/YYYY) Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) Distance from supporting structure (meters) Distance from obstructions on roof (meters) Distance from obstructions not on roof (meters) Distance from trees (meters) Obstruction Height above Probe (meters) Tree Height above Probe (meters) Wind (1) 61103, 61104 -Population Exposure --RM Young 5305 Anemometer 020 -ADEQ -ADEQ Neighborhood 01/01/1980 Continuous -01/01-12/31 12 ------- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) Restricted airflow (degrees) Prevailing wind direction (degrees) Probe material for reactive gases Residence time for reactive gases (seconds) -360 ----N -- -360 ----N -- -270 ----N -- -360 ----N -- -360 ----N -- -360 ----N -- -360 ----N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- --- --- --- --- --- --- --- Site type(s) Monitor type Network Affiliation (s) Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb Wind (1) 61103, 61104 -Source Oriented State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 7 Non-Regulatory - SPM Local Site Name Pollutant (POC) Flagstaff Middle School PM2.5 (1) Parameter code -- -- -- -- Public Information Population Exposure Special Purpose -- Public Information Population Exposure Special Purpose -- Public Information Population Exposure Special Purpose -- Public Information Population Exposure Special Purpose -- Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Payson Well Site PM2.5 (1) Prescott College AQD PM2.5 (1) Sedona Fire Station AQD PM2.5 (1) Met One E-BAM Met One E-BAM Met One E-BAM Met One E-BAM Method code -- -- -- -- FRM/FEM/ARM/other -- -- -- -- ADEQ ADEQ ADEQ ADEQ Collecting Agency Analytical Lab (weight, toxics, other) -- -- -- -- ADEQ ADEQ ADEQ ADEQ Spatial Scale (micro, neighborhood) Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 09/09/1999 05/16/2012 07/13/2011 12/16/2011 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous Continuous Reporting Agency Calculated sampling frequency (1:3 / 1:1) -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 Probe height (meters) 6 2 6 3.6 Distance from supporting structure (meters) -- -- -- -- Distance from obstructions on roof (meters) 15 -- -- -- Distance from obstructions not on roof (meters) -- 6 -- 3 Distance from trees (meters) 15 4 -- -- Obstruction Height above Probe (meters) -- -- -- -- Tree Height above Probe (meters) -- -- -- -- Distance to furnace or incinerator flue (meters) -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- 270 90 360 300 Restricted airflow (degrees) -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- Probe material for reactive gases -- -- -- -- Sampling season (MM/DD-MM/DD) Residence time for reactive gases (seconds) -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N N N N -- -- -- -- Monthly Monthly Monthly Monthly -- -- -- -- Last Annual PE audit for gaseous parameters -- -- -- -- Last two semi-annual flow rate audits PM and Pb -- -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 8 NAAQS - SLAMS - CO Local Site Name JLG Supersite Pollutant (POC) CO (1) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model 42101 NAAQS Comparison Highest Concentration SLAMS NCore, PAMS Ecotech EC9830T Method code 588 FRM/FEM/ARM/other FEM Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Spatial Scale (micro, neighborhood) ADEQ -ADEQ Neighborhood Monitoring start date (MM/DD/YYYY) 07/01/1993 Current sampling frequency (1:3, continuous) Continuous Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) -01/01-12/31 Probe height (meters) 4.1 Distance from supporting structure (meters) 1.2 Distance from obstructions on roof (meters) -- Distance from obstructions not on roof (meters) 20 Distance from trees (meters) 20 Obstruction Height above Probe (meters) 6 Tree Height above Probe (meters) 6 Distance to furnace or incinerator flue (meters) -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) Restricted airflow (degrees) Prevailing wind direction (degrees) Probe material for reactive gases Residence time for reactive gases (seconds) -360 --Glass, Teflon 1.94 Changes within the next 18 months? (Y/N) N Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments -- Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb --Bi-Weekly 12/02/2014 -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 9 NAAQS - SLAMS - NO2 Local Site Name Alamo Lake JLG Supersite Pollutant (POC) NO2 (1) NO2 (1) Parameter code 42602 42602 NAAQS Comparison NAAQS Comparison Highest Concentration SLAMS Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Background SPM -- NCore Ecotech EC9841B Ecotech EC9841B Method code 074 074 FRM/FEM/ARM/other FRM FRM ADEQ ADEQ Collecting Agency -- -- ADEQ ADEQ Spatial Scale (micro, neighborhood) Regional Neighborhood Monitoring start date (MM/DD/YYYY) 07/01/2014 07/01/1993 Current sampling frequency (1:3, continuous) Continuous Continuous Analytical Lab (weight, toxics, other) Reporting Agency -- -- 01/01-12/31 01/01-12/31 Probe height (meters) 4.1 4.1 Distance from supporting structure (meters) 1.6 1.2 Distance from obstructions on roof (meters) -- -- Distance from obstructions not on roof (meters) -- 20 Distance from trees (meters) -- 20 Obstruction Height above Probe (meters) -- 6 Tree Height above Probe (meters) -- 6 Distance to furnace or incinerator flue (meters) -- -- Distance between collocated monitors (meters) -- -- 360 360 Restricted airflow (degrees) -- -- Prevailing wind direction (degrees) -- -- Teflon Glass, Teflon Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Unrestricted airflow (degrees) Probe material for reactive gases 3.6 1.94 Changes within the next 18 months? (Y/N) N N Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments -- -- -- -- -- -- Bi-Weekly Bi-Weekly 08/28/2014 11/13/2014 -- -- Residence time for reactive gases (seconds) Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 10 NAAQS - SLAMS - O3 O3 (1) Prescott College AQD O3 (1) SLAMS 44201 NAAQS Comparison Max O3 Concentration SLAMS 44201 NAAQS Comparison Max O3 Concentration SLAMS -- -- NCore, PAMS Alamo Lake Local Site Name Pollutant (POC) O3 (1) Parameter code 44201 NAAQS Comparison Basic monitoring objective Regional Transport Site type(s) Monitor type Network Affiliation (s) Flagstaff Middle School O3 (1) JLG Supersite O3 (1) Tonto National Monument O3 (1) 44201 NAAQS Comparison Max O3 Concentration SLAMS 44201 NAAQS Comparison 44201 NAAQS Comparison Downwind Downwind SLAMS SLAMS 44201 NAAQS Comparison Max O3 Concentration SLAMS -- PAMS -- -- Queen Valley Yuma Supersite O3 (1) Teledyne API 400E Teledyne API 400E Teledyne API 400E Teledyne API 400E Teledyne API 400E Teledyne API 400E Teledyne API 400E Instrument manufacturer and model Method code 087 087 087 087 087 087 087 FRM/FEM/ARM/other FEM FEM FEM FEM FEM FEM FEM ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ -- -- -- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Spatial Scale (micro, neighborhood) Regional Neighborhood Neighborhood Neighborhood Regional Regional Neighborhood Monitoring start date (MM/DD/YYYY) 05/20/2005 03/13/2008 07/01/1993 03/25/2008 01/01/1998 05/22/2002 05/06/2008 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous Continuous Continuous Continuous Continuous Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Calculated sampling frequency (1:3 / 1:1) -- -- -- -- -- -- -- 03/01-10/31 03/01-10/31 01/01-12/31 03/01-10/31 03/01-10/31 03/01-10/31 03/01-10/31 Probe height (meters) 4.1 10 4.1 6 4.5 5 4.3 Distance from supporting structure (meters) 1.6 2 1.2 1.5 2 2 1.6 Distance from obstructions on roof (meters) -- 0 -- -- -- -- -- Distance from obstructions not on roof (meters) -- -- 20 17 -- 65 Distance from trees (meters) -- 15 20 -- -- 6 -- Obstruction Height above Probe (meters) -- -- 6 0 -- -- 0 Sampling season (MM/DD-MM/DD) Tree Height above Probe (meters) -- 3 6 -- -- 0 -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- -- 360 360 360 360 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- -- Teflon Teflon Glass, Teflon Teflon Teflon Teflon Teflon 2.91 8.66 1.94 3.87 3.56 3.53 2.98 N N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Probe material for reactive gases Residence time for reactive gases (seconds) Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb Bi-Weekly Bi-Weekly Bi-Weekly Bi-Weekly Bi-Weekly Bi-Weekly Bi-Weekly 08/28/2014 05/29/2014 11/25/2014 06/04/2014 08/27/2014 08/12/2014 05/01/2014 -- -- -- -- -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 11 NAAQS - SLAMS - SO2 Local Site Name Pollutant (POC) Alamo Lake SO2 (1) Hayden Old Jail SO2 (1) JLG Supersite SO2 (1) Miami Jones Ranch SO2 (1) Miami Ridgeline SO2 (1) Miami Townsite SO2 (1) Parameter code 42401 NAAQS Comparison 42401 NAAQS Comparison 42401 NAAQS Comparison 42401 NAAQS Comparison 42401 NAAQS Comparison Background Source Oriented Source Oriented Source Oriented Source Oriented SPM SLAMS 42401 NAAQS Comparison Population Exposure SLAMS SLAMS SLAMS SLAMS -- -- NCore -- -- -- Ecotech EC9850T Ecotech EC9850T Ecotech EC9850T Ecotech EC9850T Thermo 43C Ecotech EC9850T Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code 592 592 592 592 060 592 FRM/FEM/ARM/other FEM FEM FEM FEM FEM FEM ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ -- -- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Spatial Scale (micro, neighborhood) Regional Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 01/14/2014 01/01/1975 03/03/2005 02/01/2013 10/05/1995 02/01/2013 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous Continuous Continuous Continuous Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Calculated sampling frequency (1:3 / 1:1) -- -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 Probe height (meters) 4.1 4.7 4.1 3.5 3.5 3.7 Distance from supporting structure (meters) 1.6 2.1 1.2 1 1.1 1 Distance from obstructions on roof (meters) -- -- -- -- -- -- Distance from obstructions not on roof (meters) -- -- 20 -- 10 26.4 Distance from trees (meters) -- 12 20 -- -- 14 Obstruction Height above Probe (meters) -- -- 6 -- 1.5 10.9 Sampling season (MM/DD-MM/DD) Tree Height above Probe (meters) -- 0 6 -- -- 7 Distance to furnace or incinerator flue (meters) -- 280 -- 3081 1411 2300 Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- 360 360 360 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- Teflon Teflon Glass, Teflon Teflon Teflon Teflon 3.72 4.75 1.94 4.08 4.88 3.96 N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Probe material for reactive gases Residence time for reactive gases (seconds) Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb Bi-Weekly Bi-Weekly Bi-Weekly Bi-Weekly Bi-Weekly Bi-Weekly 02/19/2014 02/04/2014 11/25/2014 07/22/2014 05/08/2014 11/19/2014 -- -- -- -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 12 NAAQS - SLAMS - Pb Local Site Name Pollutant (POC) Globe Highway Globe Highway JLG Supersite Pb (1) Pb (2) Pb-PM10 (1) Pb (1) Parameter code 14129 NAAQS Comparison Highest Concentration, Source Oriented 85129 NAAQS Comparison 14129 NAAQS Comparison Population Exposure Source Oriented Site type(s) 14129 NAAQS Comparison Highest Concentration, Source Oriented Monitor type SLAMS SLAMS SLAMS SLAMS -Tisch TE-8550-BL TSP 191 -Tisch TE-8550-BL TSP 191 NCore Thermo Partisol 2000 202 -Tisch TE-8550-BL TSP 191 Basic monitoring objective Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Miami Golf Course FEM FEM FEM FEM ADEQ ADEQ ADEQ ADEQ PCRWRD PCRWRD ERG PCRWRD ADEQ ADEQ ERG ADEQ Spatial Scale (micro, neighborhood) Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 10/01/2010 10/01/2010 01/01/2005 10/01/2010 1:6 1:6 1:6 1:6 -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 2 2 4.7 3 1.1 1.1 2 1.1 Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) Distance from supporting structure (meters) Distance from obstructions on roof (meters) -- -- -- -- Distance from obstructions not on roof (meters) 65 65 20 -- Distance from trees (meters) 3 3 20 7 Obstruction Height above Probe (meters) 23 23 6 -- Tree Height above Probe (meters) -1 -1 6 0 Distance to furnace or incinerator flue (meters) 1043 1043 -- 2635 Distance between collocated monitors (meters) Unrestricted airflow (degrees) 2.7 2.7 -- -- 360 360 360 360 Restricted airflow (degrees) -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- Probe material for reactive gases -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb -- -- -- -- Monthly Monthly Monthly Monthly -- -- -- -- -- -- -- -- -- -- -- -- 08/14/2014, 11/04/2014 08/14/2014, 11/04/2014 10/27/2014, 11/24/2014 07/24/2014, 11/04/2014 State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 13 NAAQS - SLAMS - PM10 Ajo Alamo Lake Bullhead City Douglas Red Cross Hayden Old Jail JLG Supersite Miami Golf Course Pollutant (POC) PM10 (3) PM10 (3) PM10 (3) PM10 (3) PM10 (3) PM10 (3) PM10 (3) Parameter code 81102 NAAQS Comparison Population Exposure SLAMS 81102 NAAQS Comparison 81102 NAAQS Comparison Population Exposure SLAMS 81102 NAAQS Comparison Population Exposure SLAMS 81102 NAAQS Comparison 81102 NAAQS Comparison Population Exposure SLAMS 81102 NAAQS Comparison -Thermo TEOM 1400AB 079 -Met One BAM 1020 -Thermo TEOM 1400AB 079 -Thermo TEOM 1400AB 079 Met One BAM 1020 122 -Thermo TEOM 1400AB 079 FEM FEM FEM FEM FEM FEM FEM ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Local Site Name Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Background SLAMS Source Oriented SLAMS NCore 122 Source Oriented SLAMS -Thermo TEOM 1400AB 079 -- -- -- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Neighborhood Spatial Scale (micro, neighborhood) Neighborhood Regional Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 02/11/1991 10/30/2013 11/05/1997 09/02/1998 01/06/1981 07/01/1993 7/26/2012 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous Continuous Continuous Continuous Continuous Calculated sampling frequency (1:3 / 1:1) 1:1 1:1 1:1 1:6 1:6 1:2 1:6 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 Probe height (meters) 2.9 4.4 5 3 4.6 4.9 4 Distance from supporting structure (meters) 1.8 1.9 2 2 2 2.5 2 Distance from obstructions on roof (meters) -- -- -- -- -- -- -- -- -- -- 10 -- 15 -- Distance from trees (meters) 12 -- 23 11 12 15 6 Obstruction Height above Probe (meters) -- -- -- 1 -- 5 -- Tree Height above Probe (meters) 0 -- 0 1 0 5 0 Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- -- 360 360 360 360 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- -- Probe material for reactive gases -- -- -- -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N N N Sampling season (MM/DD-MM/DD) Distance from obstructions not on roof (meters) Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb -- -- -- -- -- -- -- -- -- -- -- -- -- -- Monthly Monthly Monthly Monthly Monthly Monthly Monthly -- -- -- -- -- -- -- -04/30/2014, 10/28/2014 -02/19/2014, 08/28/2014 -06/04/2014, 12/11/2014 -01/29/2014, 07/30/2014 -02/04/2014, 08/14/2014 06/12/2014, 11/25/2014 -02/26/2014, 07/24/2014 State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 14 NAAQS - SLAMS - PM10 continued Nogales Post Office Nogales Post Office Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Paul Spur Chemical Lime Plant Payson Well Site Rillito Yuma Supersite PM10 (3) PM10 (1) PM10 (3) PM10 (3) PM10 (3) PM10 (3) 81102 NAAQS Comparison Population Exposure SLAMS 81102 NAAQS Comparison Population Exposure SLAMS 81102 NAAQS Comparison 81102 NAAQS Comparison Population Exposure SLAMS 81102 NAAQS Comparison SLAMS 81102 NAAQS Comparison Population Exposure SLAMS -- -Thermo TEOM 1400AB 079 Met One BAM 1020 -Thermo TEOM 1400AB 079 -Thermo TEOM 1400AB 079 Source Oriented SLAMS Method code 122 -Thermo Partisol 2000 126 FRM/FEM/ARM/other FEM FRM FEM FRM FEM FEM ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Met One BAM 1020 Instrument manufacturer and model Collecting Agency Analytical Lab (weight, toxics, other) -- Source Oriented 122 -- MCAQD AFL -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Spatial Scale (micro, neighborhood) Neighborhood Neighborhood Middle Neighborhood Middle Neighborhood Monitoring start date (MM/DD/YYYY) 01/01/1980 01/01/1980 01/06/1991 01/01/1991 01/03/1985 12/01/2009 Current sampling frequency (1:3, continuous) Continuous 1:6 Continuous Continous Continuous Continuous Reporting Agency Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) 1:1 1:1 1:2 1:6 1:6 1:6 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 8 7.3 3 4.75 4.3 4.5 Distance from supporting structure (meters) 2.7 2 2 2.1 2 1.8 Distance from obstructions on roof (meters) 11 15 -- -- -- -- -- -- 3 65 -- Distance from obstructions not on roof (meters) Distance from trees (meters) 10 10 35 17.4 20 Obstruction Height above Probe (meters) 2 2.7 -- -- 0 0 Tree Height above Probe (meters) 0 0 0 1 0 -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) 3 3 -- -- -- -- 360 360 360 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- Probe material for reactive gases -- -- -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N Y N N N N -- -- -- -- -- -- -- Monthly -- -- -- -- Monthly -- Monthly Monthly Monthly Monthly -- -- -- -- -- -- -- -01/29/2014, 07/30/2014 -05/22/2014, 12/03/2014 -04/24/2014, 10/28/2014 -05/01/2014, 10/29/2014 Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb -01/28/2014, 07/31/2014 1/28/2014, 08/13/14 State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 15 NAAQS - SLAMS - PM2.5 Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Alamo Lake Douglas Red Cross JLG Supersite JLG Supersite PM2.5 (3) PM2.5 (3) PM2.5 (3) PM2.5 (1) PM2.5 (3) PM2.5 (1) PM2.5 (2) 88101 88101 88101 88101 88101 88101 88101 88101 NAAQS Comparison NAAQS Comparison Population Exposure SLAMS NAAQS Comparison Population Exposure SLAMS NAAQS Comparison Highest Concentration SLAMS NAAQS Comparison Highest Concentration QA Collocated NAAQS Comparison Highest Concentration QA Collocated NAAQS Comparison SLAMS NAAQS Comparison Population Exposure SLAMS -- -- NCore NCore Thermo Partisol 2000 -- -Thermo Partisol 2000 -Thermo Partisol 2000 Background Met One BAM 1020 Met One BAM 1020 Met One BAM 1020 Nogales Post Office Nogales Post Office Nogales Post Office Met One BAM 1020 Yuma Supersite PM2.5 (3) Regional Transport SLAMS -Met One BAM 1020 Method code 170 170 170 143 170 143 143 170 FRM/FEM/ARM/other FEM FEM FEM FRM FEM FRM FRM FEM ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ -- -- -- MCAQD AFL -- MCAQD AFL MCAQD AFL -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Spatial Scale (micro, neighborhood) Regional Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 11/15/2013 11/02/2000 07/01/2003 07/01/2003 04/01/1999 04/01/1999 04/01/1999 01/01/2010 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous 1:3 Continuous 1:6 1:6 Continuous Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) 1:3 1:3 1:3 1:3 1:3 1:3 1:3 1:3 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 4.5 3 5 4.7 8.3 7.3 7.3 4.6 Distance from supporting structure (meters) 2 2.5 2.5 2 3 2 2 1.9 Distance from obstructions on roof (meters) -- -- -- -- 12 9 8 Distance from obstructions not on roof (meters) -- 10 15 20 Distance from trees (meters) -- 11 15 20 10 10 10 Obstruction Height above Probe (meters) -- 1 5 6 1.7 2.7 2.7 0 Tree Height above Probe (meters) -- 1 5 6 0 0 0 -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- 3 3, 2 2 -- 360 360 360 360 360 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- 180 180 180 -- Probe material for reactive gases -- -- -- -- -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N N Y N Y Y Y Y Y Y Y Y -- -- -- Monthly -- Monthly Monthly -- Monthly Monthly Monthly -- Monthly -- -- Monthly -- -- -- -- -- -- -- -- -02/19/2014, 08/28/2014 -01/29/2014, 07/30/2014 -06/12/2014, 11/25/2014 -10/27/2014, 11/24/2014 -01/28/2014, 07/31/2014 -01/28/2014, 08/13/2014 -08/13/2014, 09/09/2014 -05/01/2014, 10/29/2014 Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb -65 State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 16 -- NAAQS - CSN Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other JLG Supersite JLG Supersite PM2.5 Speciation (7) PM2.5 Speciation (7) Multiple Multiple Research Population Exposure SLAMS Research Population Exposure SLAMS CSN STN, NCore Met One SuperSASS Various CSN STN, NCore URG 3000N Various -- -- ADEQ ADEQ Analytical Lab (weight, toxics, other) RTI RTI Reporting Agency RTI RTI Spatial Scale (micro, neighborhood) Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 02/21/2000 02/21/2000 1:3 1:3 Collecting Agency Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) -- -- 01/01-12/31 01/01-12/31 4.7 4.9 Distance from supporting structure (meters) 2 2.2 Distance from obstructions on roof (meters) -- -- Distance from obstructions not on roof (meters) 20 15 Distance from trees (meters) 20 15 Obstruction Height above Probe (meters) 6 5 Tree Height above Probe (meters) 6 5 Distance to furnace or incinerator flue (meters) -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- 360 360 Restricted airflow (degrees) -- -- Prevailing wind direction (degrees) -- -- Probe material for reactive gases -- -- Residence time for reactive gases (seconds) -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N -- -- Monthly Monthly -- -- -- -- Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb -- -- 3/14/2014 3/14/2014 State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 17 NAAQS - NCore Local Site Name Pollutant (POC) JLG Supersite JLG Supersite NOy (1) JLG Supersite O3 (1) JLG Supersite SO2 (1) JLG Supersite CO (1) Parameter code Monitor type 42101 NAAQS Comparison Highest Concentration SLAMS 42600 NAAQS Comparison Population Exposure SLAMS 44201 NAAQS Comparison Max O3 Concentration SLAMS 42401 NAAQS Comparison Population Exposure SLAMS 85129 NAAQS Comparison Population Exposure SLAMS Network Affiliation (s) NCore, PAMS NCore NCore, PAMS NCore Met One BAM 1020 Basic monitoring objective Site type(s) Pb-PM10 (1) JLG Supersite PM10-2.5 (1) 86101 Research Population Exposure SLAMS Ecotech EC9830T Ecotech 9843 Teledyne API 400E Ecotech EC9850T Method code 588 591 087 592 NCore Thermo Partisol 2000 202 FRM/FEM/ARM/other FEM FEM FEM FEM FEM FEM ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ -- -- -- -- ERG -- ADEQ ADEQ ADEQ ADEQ ERG ADEQ Spatial Scale (micro, neighborhood) Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 07/01/1993 01/01/2011 07/01/1993 03/03/2005 01/01/2005 11/10/2010 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous Continuous 1:6 Continuous Instrument manufacturer and model Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Calculated sampling frequency (1:3 / 1:1) NCore 185 -- -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 Probe height (meters) 4.1 10 4.1 4.1 4.7 4.9 Distance from supporting structure (meters) 1.2 7 1.2 1.2 2 2.5 Distance from obstructions on roof (meters) -- -- -- -- -- -- Distance from obstructions not on roof (meters) 20 20 20 20 20 15 Distance from trees (meters) 20 20 20 20 20 15 Obstruction Height above Probe (meters) 6 0 6 6 6 5 Tree Height above Probe (meters) 6 0 6 6 6 5 Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- 360 360 360 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- Glass, Teflon Glass, Teflon Glass, Teflon Glass, Teflon -- -- 1.94 14.39 1.94 1.94 -- -- N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Monthly Bi-Weekly Bi-Weekly Bi-Weekly Bi-Weekly -- -- 12/02/2014 02/27/2014 11/25/2014 11/25/2014 -- -- -- -10/27/2014, 11/24/2014 -- -- Sampling season (MM/DD-MM/DD) Probe material for reactive gases Residence time for reactive gases (seconds) Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 18 -- NAAQS - NCore continued Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) JLG Supersite JLG Supersite PM2.5 (3) PM2.5 (1) 88101 NAAQS Comparison Population Exposure SLAMS 88101 NAAQS Comparison Population Exposure SLAMS NCore JLG Supersite JLG Supersite JLG Supersite PM2.5 Speciation (7) PM2.5 Speciation (7) JLG Supersite Temp/RH (1) Wind (1) Multiple Multiple 62101, 62201 61103, 61104 Research Research -- -- Population Exposure SLAMS Population Exposure SLAMS Population Exposure SLAMS Population Exposure SLAMS CSN STN, NCore Met One SuperSASS Various CSN STN, NCore -Vaisala HMP 155 Probe 040 -RM Young 5305 Anemometer 020 Method code 170 NCore Thermo Partisol 2000 143 FRM/FEM/ARM/other FEM FRM -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Met One BAM 1020 Instrument manufacturer and model Collecting Agency Analytical Lab (weight, toxics, other) URG 3000N Various -- ADEQ AFL RTI RTI -- -- ADEQ ADEQ RTI RTI ADEQ ADEQ Spatial Scale (micro, neighborhood) Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 07/01/2003 07/01/2003 02/21/2000 02/21/2000 07/01/1993 07/01/1993 Current sampling frequency (1:3, continuous) Continuous 1:3 1:3 1:3 Continuous Continuous Reporting Agency Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) 1:3 1:3 -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 11.5 5 4.7 4.7 4.9 2 Distance from supporting structure (meters) 2.5 2 2 2 1 7 Distance from obstructions on roof (meters) -- -- -- -- 2 -- Distance from obstructions not on roof (meters) 15 20 20 15 20 -- Distance from trees (meters) 15 20 20 15 20 20 Obstruction Height above Probe (meters) 5 6 6 5 1 -- Tree Height above Probe (meters) 5 6 6 5 8 -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- 360 360 360 360 150 360 Restricted airflow (degrees) -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- Probe material for reactive gases -- -- -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N N Y Y -- -- -- -- -- Monthly Monthly Monthly -- -- Monthly -- -- -- -- -- -- -- -- -- -- -- -06/12/2014, 11/25/2014 -10/27/2014, 11/24/2014 -- -- -- -- 3/14/2014 3/14/2014 -- -- Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 19 NAAQS - PAMS Local Site Name Pollutant (POC) JLG Supersite JLG Supersite JLG Supersite JLG Supersite JLG Supersite JLG Supersite CO (1) NO2 (1) O3 (1) Carbonyl (30,31) Carbonyl (32) VOC (6) Parameter code 42101 44201 NAAQS Comparison Max O3 Concentration SLAMS Multiple Multiple Multiple Research Research Research SLAMS 42602 NAAQS Comparison Highest Concentration SLAMS Max Precursor Impact SLAMS SLAMS Max Precursor Impact SLAMS NCore, PAMS NCore NCore, PAMS PAMS, NATTS PAMS, NATTS PAMS, NATTS NAAQS Comparison Basic monitoring objective Highest Concentration Site type(s) Monitor type Network Affiliation (s) Ecotech EC9830T ATEC 8000 ATEC 8000 ATEC 2200 Method code 588 074 087 202 202 126 FRM/FEM/ARM/other FEM FRM FEM -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ERG Instrument manufacturer and model Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Spatial Scale (micro, neighborhood) Ecotech EC9841B Teledyne API 400E QA Collocated -- -- -- ERG ERG ADEQ ADEQ ADEQ ERG ERG ERG Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 07/01/1993 07/01/1993 07/01/1993 05/15/1999 05/15/1999 05/15/1999 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous 1:6 NATTS not PAMS 1:6 -- -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 06/01-08/31 06/01-08/31 06/01-08/31 Probe height (meters) 4.1 4.1 4.1 4.7 4.7 4.7 Distance from supporting structure (meters) 1.2 1.2 1.2 2 2 2 Distance from obstructions on roof (meters) -- -- -- -- -- -- Distance from obstructions not on roof (meters) 20 20 20 20 20 20 Distance from trees (meters) 20 20 20 20 20 20 Obstruction Height above Probe (meters) 6 6 6 6 6 6 Tree Height above Probe (meters) 6 6 6 6 6 6 Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- 360 360 360 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- Glass, Teflon Glass, Teflon Glass, Teflon Stainless Steel Stainless Steel Stainless Steel 1.94 1.94 1.94 -- -- -- N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Bi-Weekly Bi-Weekly Bi-Weekly -- -- -- 12/02/2014 11/13/2014 11/25/2014 -- -- -- -- -- -- -- -- -- Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe material for reactive gases Residence time for reactive gases (seconds) Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments Last Annual PE audit for gaseous parameters Last two semi-annual flow rate audits PM and Pb State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 20 NAAQS - PAMS continued Local Site Name Pollutant (POC) JLG Supersite JLG Supersite JLG Supersite Queen Valley Queen Valley Queen Valley VOC (7) Temp/RH (1) Wind (1) O3 (1) NOy (1) VOC (6) Parameter code Multiple 62101, 62201 61103, 61104 44201 NAAQS Comparison 42600 Multiple Research Research Downwind Downwind Downwind SLAMS SLAMS SLAMS PAMS ATEC 8001 Research Basic monitoring objective -- -- Population Exposure SLAMS Population Exposure SLAMS NCore, PAMS RM Young 5305 Anemometer 020 Teledyne API 400E 126 NCore, PAMS Vaisala HMP 155 Probe 040 087 PAMS Thermo 42C TL Reactive 574 -- -- -- FEM FEM -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ QA Collocated Site type(s) Monitor type SLAMS Network Affiliation (s) PAMS, NATTS ATEC 2200 Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency PAMS 126 Analytical Lab (weight, toxics, other) ERG -- -- -- -- ERG Reporting Agency ERG ADEQ ADEQ ADEQ ADEQ ADEQ Spatial Scale (micro, neighborhood) Neighborhood Neighborhood Neighborhood Regional Regional Regional Monitoring start date (MM/DD/YYYY) 05/15/1999 07/01/1993 07/01/1993 01/01/1998 01/01/1998 05/20/2001 NATTS not PAMS Continuous Continuous Continuous Continuous 1:6 -- -- -- -- -- -- 06/01 - 08/31 01/01-12/31 01/01-12/31 03/01-10/31 06/01-08/31 06/01-08/31 4.5 Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) 4.7 2 11.5 4.5 5.1 Distance from supporting structure (meters) 2 1 -- 2 2.6 2 Distance from obstructions on roof (meters) -- 2 -- -- -- -- Distance from obstructions not on roof (meters) 20 20 -- 0 -- -- Distance from trees (meters) 20 20 20 -- -- -- Obstruction Height above Probe (meters) 6 1 -- -- -- -- Tree Height above Probe (meters) 6 8 -- -- -- -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- 360 150 360 360 360 360 Restricted airflow (degrees) -- 140-350 -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- Stainless Steel -- -- Teflon Glass, Teflon Stainless Steel Probe material for reactive gases Residence time for reactive gases (seconds) -- -- -- 3.56 13.8 -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Bi-Weekly Bi-Weekly -- Last Annual PE audit for gaseous parameters -- -- -- 08/27/2014 08/27/2014 -- Last two semi-annual flow rate audits PM and Pb -- -- -- -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 21 NAAQS - PAMS continued Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Queen Valley Queen Valley Vehicle Emissions Lab Vehicle Emissions Lab Ultraviolet Solar Radiation (1) 63302, 63304 Vehicle Emissions Laboratory Vehicle Emissions Laboratory Temp R/H (1) Wind (1) 62101, 61202 Vehicle Emissions Lab Horizontal Solar Raditation (1) 63301 Temp/RH (1) Wind (1) Delta Temp (1) 62101, 62201 61103, 61104 -- -- 62101, 62201 61103, 61104 Research Population Exposure Research Population Exposure Research Population Exposure -Population Exposure Downwind Downwind -Population Exposure PAMS Vaisala HMP 45C Probe 040 PAMS RM Young 5103 Anemometer 020 PAMS RM Young 7627 PAMS PAMS Li-Cor 200S2 Epply TUVR UV -Rotronics MP101A Probe 040 -RM Young 5305 Anemometer 020 810 011 011 -- -- -- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency -- -- -- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Neighborhood Spatial Scale (micro, neighborhood) Regional Regional Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 06/23/2003 06/23/2003 08/20/2004 06/18/1999 08/20/2004 05/11/1999 05/11/1999 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous Continuous Continuous Continuous Continuous Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) -- -- -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 Probe height (meters) 2.6 9 2.5 - 10 5 5 4.5 10 Distance from supporting structure (meters) 0.5 6.5 .5 -- -- -- -- Distance from obstructions on roof (meters) -- -- -- -- -- -- -- Distance from obstructions not on roof (meters) -- -- -- -- -- -- 30 Distance from trees (meters) 1.2 -- 10 10 10 10 50 Obstruction Height above Probe (meters) -- -- -- -- -- -- -- Tree Height above Probe (meters) -- -- -- -- -- -- -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- -- 180 360 360 360 360 360 360 -- Restricted airflow (degrees) 90-270 -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- -- Probe material for reactive gases -- -- -- -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters -- -- -- -- -- -- -- Last two semi-annual flow rate audits PM and Pb -- -- -- -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 22 Air Toxics -NATTS Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency JLG Supersite JLG Supersite JLG Supersite JLG Supersite JLG Supersite Carbonyl (6) Carbonyl (7) VOC (6) VOC (7) SVOC (6) Multiple Multiple Multiple Multiple Multiple JLG Supersite PM10 metals speciation (1) Multiple Research Population Exposure SLAMS Research Research QA Collocated QA Collocated SLAMS Research Population Exposure SLAMS SLAMS Research Population Exposure SLAMS Research Population Exposure SLAMS PAMS, NATTS PAMS, NATTS PAMS, NATTS PAMS, NATTS NATTS ATEC 8000 ATEC 8000 ATEC 2200 ATEC 2200 Tisch PUF+ 202 202 101 101 118 NATTS Thermo Partisol 2000 202 -- -- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ ADEQ Analytical Lab (weight, toxics, other) ERG ERG ERG ERG ERG ERG Reporting Agency ERG ERG ERG ERG ERG ERG Spatial Scale (micro, neighborhood) Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Neighborhood Monitoring start date (MM/DD/YYYY) 05/15/1999 05/15/1999 06/06/2001 06/06/2001 07/08/2007 01/01/2005 1:6 Every other month 1:6 Every other month 1:6 1:6 -- -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 4.7 Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) 4.7 4.7 4.7 4.7 4.1 Distance from supporting structure (meters) 2 2 2 2 1.2 2 Distance from obstructions on roof (meters) -- -- -- -- -- -- Distance from obstructions not on roof (meters) 20 20 20 20 20 20 Distance from trees (meters) 20 20 20 20 20 20 Obstruction Height above Probe (meters) 6 6 6 6 6 6 Tree Height above Probe (meters) 6 6 6 6 6 6 Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- 360 360 360 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- Stainless Steel Stainless Steel Stainless Steel Stainless Steel -- -- Probe material for reactive gases Residence time for reactive gases (seconds) -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N N -- -- -- -- -- -- -- -- -- -- -- Monthly -- -- -- -- -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters -- -- -- -- -- -- -- -- -- -- -10/27/2014, 11/24/2014 Last two semi-annual flow rate audits PM and Pb State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 23 Air Toxics - UATMP Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency South Phoenix VOC (6) Multiple Research Population Exposure SLAMS UATMP ATEC 8001 101 -ADEQ Analytical Lab (weight, toxics, other) ERG Reporting Agency ERG Spatial Scale (micro, neighborhood) Neighborhood Monitoring start date (MM/DD/YYYY) 8/5/2001 Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) 1:12 -01/01-12/31 Probe height (meters) 4.6 Distance from supporting structure (meters) 1.6 Distance from obstructions on roof (meters) -- Distance from obstructions not on roof (meters) 8.0 Distance from trees (meters) 4.8 Obstruction Height above Probe (meters) 8.0 Tree Height above Probe (meters) 8.0 Distance to furnace or incinerator flue (meters) -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) 335 Restricted airflow (degrees) Prevailing wind direction (degrees) Probe material for reactive gases -240-265 250-260 Stainless Steel Residence time for reactive gases (seconds) -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N Last Annual PE audit for gaseous parameters -- Last two semi-annual flow rate audits PM and Pb -- ----- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 24 Visibility - Urban Haze - Camera ADEQ Building Local Site Name Pollutant (POC) Visibility (1) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency Banner Mesa Medical Center Visibility (1) Estrella Mountain Community College Visibility (1) North Mountain Summit Visibility (1) North Mountain Summit Visibility (2) -- -- -- -- -- Public Information Population Exposure -- Public Information Population Exposure -- Public Information Population Exposure -- Public Information Population Exposure -- Public Information Population Exposure -- -----CANON EOS Rebel CANON EOS Rebel CANON EOS Rebel CANON EOS Rebel CANON EOS Rebel T2i T2i T2i T2i T2i ------- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ -- -- -- -- -- ADEQ ADEQ ADEQ ADEQ ADEQ Spatial Scale (micro, neighborhood) Urban Urban Urban Urban Urban Monitoring start date (MM/DD/YYYY) 07/01/2002 01/01/1993 01/01/1993 01/01/1993 01/01/1993 Current sampling frequency (1:3, continuous) Every 5 min. Every 5 min. Every 5 min. Every 5 min. Every 5 min. -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 Probe height (meters) -- -- -- -- -- Distance from supporting structure (meters) -- -- -- -- -- Distance from obstructions on roof (meters) -- -- -- -- -- Distance from obstructions not on roof (meters) -- -- -- -- -- Distance from trees (meters) -- -- -- -- -- Obstruction Height above Probe (meters) -- -- -- -- -- Tree Height above Probe (meters) -- -- -- -- -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- -- -- -- -- Restricted airflow (degrees) -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- Probe material for reactive gases -- -- -- -- -- Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Residence time for reactive gases (seconds) -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters -- -- -- -- -- Last two semi-annual flow rate audits PM and Pb -- -- -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 25 Visibility - Urban Haze - Nephelometer Vehicle Emissions Laboratory Bscat/PM2.5 (1) Local Site Name Pollutant (POC) Dysart Estrella Bscat/PM2.5 (1) Bscat/PM2.5 (1) Parameter code -- -- -- Public Information Population Exposure -- Public Information Population Exposure -- Public Information Population Exposure -- -Optec NGN 2 Nephelometer -- -Optec NGN 2 Nephelometer -- -Optec NGN 2 Nephelometer -- Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency -- -- -- ADEQ ADEQ ADEQ -- -- -- ADEQ ADEQ ADEQ Spatial Scale (micro, neighborhood) Urban Urban Urban Monitoring start date (MM/DD/YYYY) 01/01/2003 01/01/2003 06/25/2003 Current sampling frequency (1:3, continuous) Every 5 min. Every 5 min. Every 5 min. -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) 5 5 5 Distance from supporting structure (meters) -- -- -- Distance from obstructions on roof (meters) -- -- -- Distance from obstructions not on roof (meters) -- -- -- Distance from trees (meters) -- 5 10 Obstruction Height above Probe (meters) -- -- -- Tree Height above Probe (meters) -- -- -- Distance to furnace or incinerator flue (meters) -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- 360 360 360 Restricted airflow (degrees) -- -- -- Prevailing wind direction (degrees) -- -- -- Probe material for reactive gases -- -- -- Residence time for reactive gases (seconds) -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N -- -- -- -- -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters -- -- -- Last two semi-annual flow rate audits PM and Pb -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 26 Visibility - Urban Haze - Transmissometer Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Phoenix Transmissometer Receiver Phoenix Transmissometer Transmitter Bext (1) Bext (1) -- -- Public Information Population Exposure -- Public Information Population Exposure -- -- -- Optec LVP-2 Transmissometer Receiver Optec LVP-2 Transmissometer Transmitter Method code -- -- FRM/FEM/ARM/other -- -- ADEQ ADEQ Instrument manufacturer and model Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency -- -- ADEQ ADEQ Spatial Scale (micro, neighborhood) Urban Urban Monitoring start date (MM/DD/YYYY) 12/01/1992 12/01/1992 Current sampling frequency (1:3, continuous) Continuous Continuous Calculated sampling frequency (1:3 / 1:1) -- -- 01/01-12/31 01/01-12/31 Probe height (meters) 30 27 Distance from supporting structure (meters) -- -- Distance from obstructions on roof (meters) 5 -- Distance from obstructions not on roof (meters) -- -- Distance from trees (meters) -- -- Obstruction Height above Probe (meters) -- -- Tree Height above Probe (meters) -- -- Distance to furnace or incinerator flue (meters) -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- 240 360 Restricted airflow (degrees) -- -- Prevailing wind direction (degrees) -- -- Probe material for reactive gases -- -- Sampling season (MM/DD-MM/DD) Residence time for reactive gases (seconds) -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters -- -- Last two semi-annual flow rate audits PM and Pb -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 27 Visibility - Urban Haze - Temp/RH Dysart Estrella Phoenix Transmissometer Receiver Local Site Name Pollutant (POC) Temp R/H (1) Temp R/H (1) Temp R/H (1) Parameter code 62101, 62201 62101, 62201 62101, 62201 -Population Exposure -- -Population Exposure -- -Population Exposure -- -Vaisala HMP 155 Probe 040 -Vaisala HMP 155 Probe 040 -Vaisala HMP 155 Probe 040 Basic monitoring objective Site type(s) Monitor type Network Affiliation (s) Instrument manufacturer and model Method code FRM/FEM/ARM/other Collecting Agency Analytical Lab (weight, toxics, other) Reporting Agency -- -- -- ADEQ ADEQ ADEQ -- -- -- ADEQ ADEQ ADEQ Spatial Scale (micro, neighborhood) Urban Urban Urban Monitoring start date (MM/DD/YYYY) 07/16/2003 02/11/2003 01/01/1994 Current sampling frequency (1:3, continuous) Continuous Continuous Continuous -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 32 Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) 5 5 Distance from supporting structure (meters) -- -- -- Distance from obstructions on roof (meters) -- -- 10 Distance from obstructions not on roof (meters) -- -- -- Distance from trees (meters) -- 5 -- Obstruction Height above Probe (meters) -- -- -- Tree Height above Probe (meters) -- -- -- Distance to furnace or incinerator flue (meters) -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- 360 360 360 Restricted airflow (degrees) -- -- -- Prevailing wind direction (degrees) -- -- -- Probe material for reactive gases -- -- -- Residence time for reactive gases (seconds) -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N -- -- -- -- -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters -- -- -- Last two semi-annual flow rate audits PM and Pb -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 28 Visibility - IMPROVE Chiricahua Entrance Station Douglas Red Cross Grand Canyon National Park Hance Camp Greer Water Treatment Plant Ike's Backbone JLG Supersite JLG Supersite Meadview IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE Multiple Multiple Multiple Multiple Multiple Multiple Multiple Multiple Research Research Research Research Research Research Research Research Site type(s) Background Other Background Other Other Other Other Background Monitor type -- -- -- -- -- -- -- -- IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Network Affiliation (s) Instrument manufacturer and model Method code -- -- -- -- -- -- -- -- Various Various Various Various Various Various Various Various FRM/FEM/ARM/other Other Other Other Other Other Other Other Other Collecting Agency NPS ADEQ NPS NFS UC Davis ADEQ ADEQ NFS -- -- -- -- -- -- -- -- UC Davis UC Davis UC Davis UC Davis UC Davis UC Davis UC Davis UC Davis Analytical Lab (weight, toxics, other) Reporting Agency Spatial Scale (micro, neighborhood) Regional Regional Regional Regional Regional Neighborhood Neighborhood Regional Monitoring start date (MM/DD/YYYY) 03/02/1988 06/02/2004 09/24/1997 02/29/2000 04/02/2000 04/25/2001 04/25/2001 09/04/1991 1:3 1:3 1:3 1:3 1:3 1:3 1:3 1:3 -- -- -- -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) 4 3 -- 3.5 3.3 5.5 5.5 4.5 Distance from supporting structure (meters) -- -- -- 1 1.3 -- -- -- Distance from obstructions on roof (meters) -- -- -- -- -- -- -- -- Distance from obstructions not on roof (meters) 10 8 -- -- -- 15 15 -- Distance from trees (meters) 10 6 -- 44 -- 15 15 -- Obstruction Height above Probe (meters) -- -- -- -- -- 5 5 -- Tree Height above Probe (meters) Distance to furnace or incinerator flue (meters) ---- ---- ---- 7 --- ---- 5 -4 5 -4 ---- Distance between collocated monitors (meters) Unrestricted airflow (degrees) 360 360 -- 360 360 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- -- -- Probe material for reactive gases -- -- -- -- -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N N N N N N N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters -- -- -- -- -- -- -- -- Last two semi-annual flow rate audits PM and Pb -- -- -- -- -- -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 29 Visibility - IMPROVE - continued Organ Pipe National Monument Petrified Forest National Park Pleasant Valley Ranger Station Queen Valley IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE Multiple Multiple Multiple Multiple Multiple Multiple Multiple Multiple Research Research Research Research Research Research Research Research Site type(s) Other Background Other Other Background Other Background Background Monitor type -- -- -- -- -- -- -- -- IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE IMPROVE Local Site Name Pollutant (POC) Parameter code Basic monitoring objective Network Affiliation (s) Instrument manufacturer and model Saguaro National Saguaro National Sycamore Canyon Park East Park West Tonto National Monument IMPROVE -- -- -- -- -- -- -- -- Various Various Various Various Various Various Various Various FRM/FEM/ARM/other Other Other Other Other Other Other Other Other Collecting Agency NPS NPS NFS ADEQ NPS NPS ADEQ / UC Davis NPS -- -- -- -- -- -- -- -- UC Davis UC Davis UC Davis UC Davis UC Davis UC Davis UC Davis UC Davis Method code Analytical Lab (weight, toxics, other) Reporting Agency Spatial Scale (micro, neighborhood) Regional Regional Regional Regional Regional Regional Regional Regional Monitoring start date (MM/DD/YYYY) 01/15/2003 03/02/1988 02/10/2000 04/30/2001 06/04/1988 04/19/2001 09/11/1991 04/23/1988 1:3 1:3 1:3 1:3 1:3 1:3 1:3 1:3 -- -- -- -- -- -- -- -- 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 01/01-12/31 Current sampling frequency (1:3, continuous) Calculated sampling frequency (1:3 / 1:1) Sampling season (MM/DD-MM/DD) Probe height (meters) 3.4 4 3.5 5.2 -- 3.3 4 5 Distance from supporting structure (meters) 1.4 -- 1.2 2.7 -- 1 1.5 1.5 Distance from obstructions on roof (meters) -- -- -- -- -- -- -- -- Distance from obstructions not on roof (meters) -- -- -- -- -- -- -- -- Distance from trees (meters) 13 -- 10 -- -- 15 15 8 Obstruction Height above Probe (meters) -- -- -- -- -- -- -- -- Tree Height above Probe (meters) -- -- 0.6 -- -- 2 -- -- Distance to furnace or incinerator flue (meters) -- -- -- -- -- -- -- -- Distance between collocated monitors (meters) Unrestricted airflow (degrees) -- -- -- -- -- -- -- -- 360 360 360 360 -- 360 360 360 Restricted airflow (degrees) -- -- -- -- -- -- -- -- Prevailing wind direction (degrees) -- -- -- -- -- -- -- -- Probe material for reactive gases -- -- -- -- -- -- -- -- Residence time for reactive gases (seconds) -- -- -- -- -- -- -- -- Changes within the next 18 months? (Y/N) Comparison against the annual PM2.5? (Y/N) Frequency of flow rate verification manual PM and Pb samplers Frequency of flow rate verification automated PM analyzers Frequency of one-point QC check gaseous instruments N N N N N N N N N N N N N N N N -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- Last Annual PE audit for gaseous parameters -- -- -- -- -- -- -- -- Last two semi-annual flow rate audits PM and Pb -- -- -- -- -- -- -- -- State of Arizona Air Monitoring Network Plan for the Year 2015,Appendix C Page 30 ` Appendix D – Site Information Data Tables Note: Some measurements are rounded and/or estimations This appendix contains detailed information about sites that are fully or partially operated by ADEQ, as well as sites that ADEQ has a strong association with (e.g. IMPROVE sites). All current sites and those closed after July 1, 2015 are included in this appendix. Sites that were closed after July 1, 2015 contain a note indicating so in the site summary section. This appendix also contains general information about the air quality monitors at each site. See Appendix C for more detailed information on specific monitors and networks. AQS ID 04-019-0001 04-012-8000 04-015-1003 04-003-8001 04-003-1005 04-013-4010 04-013-8005 04-005-1008 04-007-1002 04-005-8102 04-001-8001 04-007-1001 04-025-8104 04-013-9997 04-015-9000 04-007-8000 04-007-0011 04-007-0009 04-007-0012 04-023-0004 04-019-0005 04-003-0011 04-007-0008 04-001-0012 04-007-8100 04-025-8033 04-021-8001 04-019-0020 04-019-0021 04-019-9000 04-013-4003 04-005-8103 ADEQ ID 21737 16316 34961 19489 16365 16679 16503 19550 16506 21736 16707 16593 16682 16323 16326 16421 16328 21298 16629 16631 16382 16632 16511 16480 16681 16391 16317 16473 16829 16330 16446 133011 16394 16499 16474 16475 142818 16377 16476 SITE NAME Appendix D PAGE # ADEQ Building Ajo Alamo Lake Banner Mesa Medical Center Bullhead City Chiricahua Entrance Station Douglas Red Cross Dysart Estrella Estrella Mountain Community College Flagstaff Middle School Globe Highway Grand Canyon National Park – Hance Camp Greer Water Treatment Plant Hayden Old Jail Ike’s Backbone JLG Supersite Meadview Miami Golf Course Miami Jones Ranch Miami Ridgeline Miami Townsite Nogales Post Office North Mountain Summit Organ Pipe National Monument Paul Spur Chemical Lime Plant Payson Well Site Petrified Forest National Park Phoenix Transmissometer Receiver Phoenix Transmissometer Transmitter Pleasant Valley Ranger Station Prescott College AQD Queen Valley Rillito Saguaro National Park East Saguaro National Park West Sedona Fire Station AQD South Phoenix Sycamore Canyon 5 6 7 9 10 11 12 14 15 16 17 18 19 20 21 22 23 26 27 28 29 30 31 33 34 35 36 37 38 39 40 41 42 44 45 46 47 48 49 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 1 ` 04-007-0010 04-013-9998 04-027-8011 16447 16363 11319 Tonto National Monument Vehicle Emissions Laboratory Yuma Supersite 50 51 53 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 2 ` Definitions for Appendix D – Site Information Data Tables Local Site Name Site Narrative Site Information AQS ID ADEQ ID Street Address County CBSA Surrounding Area Distance to Roadway Traffic Count of Nearest Major Roadway Groundcover Latitude Longitude Elevation Site Established Date Official name for the site as written in ADEQ’s AirVision Database Brief summary of the site location and surroundings Unique identifier from EPA’s Air Quality System database Unique identifier from the AZURITE / AAAD database for each monitoring site Physical Street Address or cross streets of the monitoring site Arizona county the monitor is located within Core Based Statistical Area that the site is located within. A CBSA is a U.S. geographic area defined by the Office of Management and Budget based around an urban center of at least 10,000 people and adjacent areas that are socioeconomically tied to the urban center by commuting. Description of area around monitoring site (residential, commercial, industrial, agricultural, desert, forest, mobile, blighted area, and military reservation) Distance and direction from the edge of the nearest roadway to the instrument in meters ADOT supplied traffic count for the nearest major roadway. Includes distance and direction of roadway if differs from the nearest roadway. Type of surface at the base of the instrument (e.g. sand, cement, rooftop, metal, asphalt, etc.) The North/South geographic location of a site in decimal degrees The East/West geographic location of a site in decimal degrees The vertical distance above sea level of the site in meters Date site was first used as a monitoring site Monitoring Information Pollutant The pollutant(s) or parameter(s) being collected or measured at the site Basic monitoring Purpose of monitoring for the parameter at the site (Public Information, objective NAAQS Comparison, or Research.) Site type(s) A brief description of the intended purpose of the monitor’s measurements (Extreme Downwind, Highest Concentration, Max Ozone Concentration, Max Precursor Impact, Population Exposure, Source Oriented, Upwind Background, General / Background, Regional Transport, Welfare-Related Impacts, Quality Assurance, or Other) Monitor type(s) The associated monitoring network for the monitor (IMPROVE, Index Site, Industrial, NATTS, NCore, Non-EPA Federal, PAMS, Proposed NCore, QA Collocated, SLAMS, Special Purpose, Supplemental Speciation, Trends Speciation, Tribal Monitor, Unofficial PAMS) Spatial scale Area represented by an air quality monitor (microscale: 0 – 100 m, middle scale: 0.1 – 0.5 km, neighborhood: 0.5 – 4 km, urban: 4 – 50 km, regional: ~50 – 500 km, or national/global) Monitor Start Date Date that a pollutant, parameter, or measurement was started at the site State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 3 ` Instrument manufacture and model Site Photos Aerial View Site View The specific make and model of the monitor or instrument used in the network Image of site and the surrounding area (using Google Earth) Most current photo of monitors at the site State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 4 ` ADEQ Building The high-resolution digital camera sits on the northeast corner of the building and points toward Camelback Mountain, which lies 13.4 km to the northeast. The pictures of the local view are updated every 5 minutes and can be viewed on the internet at http://phoenixvis.net/index.aspx. The area between the site and Camelback Mountain is primarily residential with some commercial areas. Site Information AQS ID None ADEQ ID Street Address 1110 W. Washington St. Phoenix, AZ 85007 County Maricopa Groundcover CBSA Phoenix-Mesa-Scottsdale Latitude Surrounding Area Residential/Commercial Longitude Distance to roadway 84 m – S – Washington St. Elevation Traffic count of Nearest Major 10,852 – Washington St. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 21737 Rooftop 33.4483 -112.0878 329 m 07/01/2002 Monitoring Information Visibility Public Information Population Exposure -CANON EOS Rebel T2i Urban 07/01/2002 Site Photos Aerial view of ADEQ Building Camera on rooftop of ADEQ Building – 4/2010 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 5 ` Ajo The site is located at the Pima County Maintenance Yard, with the wind system mounted to the north of the instruments. The closest structure to the site is an east-west oriented ADOT office/trailer to the south. To the east lie the stabilized tailings pile associated with the Ajo mining operation that closed in 1985. Site Information AQS ID 04-019-0001 ADEQ ID Street Address 1211 Well Rd. Ajo, AZ 85321 County Pima Groundcover CBSA Tucson Latitude Surrounding Area Residential/Commercial Longitude Distance to roadway 109 m – E – Ajo Well Rd. 1 Elevation Traffic count of Nearest Major 500 – Ajo Well Rd. 1 Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16316 Gravel 32.3820 -112.8575 515 m 07/01/1969 Monitoring Information PM10 Wind Temp/RH NAAQS --Comparison Population Population Population Exposure Exposure Exposure SLAMS --Thermo RM Young Vaisala HMP TEOM 5305 155 Probe 1400AB Anemometer Neighborhood Neighborhood Neighborhood 02/11/1991 07/01/1969 02/11/2014 Site Photos Ajo fenced area and meteorological tower 5/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 6 Aerial view of Ajo ` Alamo Lake The site was established to replace the Hillside site and is located in Alamo Lake State Park, which is approximately 49 km north of Wenden, AZ. The surrounding area consists of mostly desert, with a lake about 1 km to the northeast. A small water pump/storage tank (1,000 gallon) lies 7 meters to the east of the shelter. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Site Information 04-012-8000 Alamo Lake State Park La Paz None Desert 80 m – NE – Alamo Rd. Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 230 – Alamo Rd. ADEQ ID 34961 Groundcover Latitude Longitude Elevation Gravel 34.2439 -113.5586 403 m Site Established Date 05/20/2005 Monitoring Information O3 SO2 PM10 NAAQS NAAQS NAAQS Comparison Comparison Comparison Regional General / General / Transport Background Background SLAMS SPM SLAMS PM2.5 NAAQS Comparison General / Background SLAMS Teledyne API 400E Ecotech EC9850T Met One BAM 1020 Met One BAM 1020 Regional 05/20/2005 Regional 01/14/2014 Regional 10/30/2013 Regional 11/05/2013 Monitoring Information NO2 NAAQS Comparison General / Background SPM Ecotech EC9841 Regional 7/1/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 7 ` Site Photos Regional view of Alamo Lake Alamo Lake shelter with PM inlets – 7/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 8 ` Banner Mesa Medical Center The high-resolution digital camera points to the Superstition Mountains, which lie 32 km east of the site. The pictures of the local views are updated every 5 minutes and can be viewed on the internet at http://phoenixvis.net/index.aspx. The area between the site and the mountains is primarily residential with some commercial areas. Site Information AQS ID None ADEQ ID Street Address 525 W. Brown Rd. Mesa, AZ 85201 County Maricopa Groundcover CBSA Phoenix-Mesa-Scottsdale Latitude Surrounding Area Residential Longitude Distance to roadway 170 m – N – W Brown St. Elevation Traffic count of 32,760 – Country Club Dr. – Nearest Major Site Established Date 260m – E Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 19489 Rooftop 33.4335 -111.8428 454 m 01/01/1993 Monitoring Information Visibility Public Information Population Exposure -CANON EOS Rebel T2i Urban 01/01/1993 Site Photos Banner Mesa Medical Center Camera– 05/2013 Aerial view of Banner Mesa Medical Center State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 9 ` Bullhead City The site is located on the rooftop of the U.S. Post Office Building, northeast of SR 95 and 7th Street. The surrounding area is commercial and residential to the west and south. The Colorado River lies to the west less than 400 meters. To the northeast/east, about 575 meters, is the Bullhead City Airport. Site Information AQS ID 04-015-1003 ADEQ ID Street Address 990 Highway 95 Bullhead City, AZ 86429 County Mohave Groundcover CBSA Lake Havasu City-Kingman Latitude Surrounding Area Commercial/Residential Longitude Distance to roadway 40 m – W – SR 95 Elevation Traffic count of Nearest Major 25,500 – SR 95 Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16365 Rooftop 35.1538 -114.5668 167 m 11/01/1997 Monitoring Information PM10 NAAQS Comparison Population Exposure SLAMS Thermo TEOM 1400AB Neighborhood 11/05/1997 Site Photos Aerial view of Bullhead City Roof of Bullhead City Post Office– 06/2012 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 10 ` Chiricahua Entrance Station The site is operated by the NPS. The surrounding area is wilderness and desert. The Chiricahua National Monument lies 3.8 km to the northeast. Site Information AQS ID 04-003-8001 ADEQ ID Street Address 13063 E. Bonita Canyon Rd. Wilcox, AZ 85643 County Cochise Groundcover CBSA Sierra Vista-Douglas Latitude Surrounding Area Desert Longitude 99 m – E – Bonita Canyon Distance to roadway Elevation Rd. Traffic count of Nearest Major 216 – Bonita Canyon Rd. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16679 Dirt/Rocks 32.0094 -109.3891 1,570 m 01/01/1988 Monitoring Information IMPROVE Research Background IMPROVE -Regional 03/02/1988 Site Photos Regional view of Chiricahua Entrance Station Chiricahua Entrance Station shelter and IMPROVE – 07/2008 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 11 ` Douglas Red Cross The site is located at the Red Cross building on the south side of 15th Street. The surrounding area is a mix of residential and commercial land use. The site is about 1,685 meters from the Arizona/Mexico border. Due to an oversight when loading IMPROVE data to the AQS database, a second AQS ID was created (04-003-9000) for IMPROVE data. This is an IMPROVE protocol site. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Site Information 04-003-1005 1445 E. 15th St. Douglas, AZ 85607 Cochise Sierra Vista-Douglas Commercial/Residential 30 m – N – 14th St. Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 2,474 – 14th St. ADEQ ID 16503 Groundcover Latitude Longitude Elevation Dirt/Grass 31.3492 -109.5396 1,231 m Site Established Date 09/01/1998 Monitoring Information PM10 PM2.5 Temp/RH NAAQS NAAQS -Comparison Comparison Population Population Population Exposure Exposure Exposure SLAMS SLAMS -Thermo Met One BAM Vaisala HMP TEOM 1020 155 Probe 1400AB Neighborhood Neighborhood Neighborhood 09/02/1998 11/02/2000 08/16/2012 Wind -Population Exposure -RM Young 5305 Anemometer Neighborhood 08/06/2012 Monitoring Information IMPROVE Research Other IMPROVE -Regional 06/02/2004 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 12 ` Site Photos Douglas Red Cross fenced site – 04/2013 Aerial view of Douglas Red Cross State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 13 ` Dysart The site is located in the Maricopa County Facility Maintenance Yard at the southeast corner of Bell Road and Dysart Road and is shared with MCAQD. The surrounding area is commercial and residential. Site Information AQS ID 04-013-4010 ADEQ ID Street Address 16825 N. Dysart Rd. Surprise, AZ 85374 County Maricopa Groundcover CBSA Phoenix-Mesa-Scottsdale Latitude Surrounding Area Commercial/Residential Longitude Distance to roadway 14 m – W – Dysart Rd Elevation Traffic count of 51,673 – Bell Rd. – 150m – Nearest Major Site Established Date N Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 19550 Gravel 33.6370 -112.3393 357 m 01/01/2003 Monitoring Information Bscat/PM2.5 Temp/ RH Public -Information Population Population Exposure Exposure --Vaisala Optec NGN 2 HMP155 Nephelometer Probe Urban Urban 01/01/2003 07/16/2003 Site Photos Dysart ADEQ Nephelometer tower attached to county shelter – 03/2013 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 14 Aerial view of Dysart ` Estrella The site is located in the southeast corner of the Maricopa County Maintenance Yard at Estrella Park. The surrounding area consist of the Estrella Mountains to the east, south, and west; a golf course 256 meters to the west; and a mixture of open land, agricultural lands, residential, and commercial activity to the north. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Site Information 04-013-8005 ADEQ ID 15099 W. Casey Abbott Rd. Goodyear, AZ 85338 Maricopa Groundcover Phoenix-Mesa-Scottsdale Latitude Desert/Recreation Area Longitude 258 m – N – W. Vineyard Elevation Ave. Traffic count of Nearest Major Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 910 – W. Vineyard Ave. Site Established Date 16506 Grass/Gravel 33.3833 -112.3728 277 m 01/01/1995 Monitoring Information Bscat/PM2.5 Temp/ RH Public -Information Population Population Exposure Exposure --Vaisala Optec NGN 2 HMP155 Nephelometer Probe Urban Urban 01/01/2003 02/11/2003 Site Photos Aerial view of Estrella Estrella Nephelometer tower – 06/2012 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 15 ` Estrella Mountain Community College One high-resolution digital camera points to the Estrella Mountains, which lies 11 km to the southwest, and the other camera points to the White Tanks mountain range which is 20 km to the northeast. The pictures of the local views are updated every 5 minutes and can be viewed on the internet athttp://phoenixvis.net/index.aspx. The area between the site and the mountain ranges is a mixture of residential, commercial, and agricultural uses. Site Information AQS ID None ADEQ ID Street Address 3000 N. Dysart Rd. Avondale, AZ 85323 County Maricopa Groundcover CBSA Phoenix-Mesa-Scottsdale Latitude Surrounding Area Residential Longitude Distance to roadway 155 m – S – Thomas Rd. Elevation Traffic count of Nearest Major 9,798 – Thomas Rd. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 21736 Rooftop 33.4836 -112.3503 305 m 01/01/1993 Monitoring Information Visibility Public Information Population Exposure -CANON EOS Rebel T2i Urban 01/01/1993 Site Photos No photo Aerial view of Estrella Mountain Community College State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 16 ` Flagstaff Middle School The site is west of Bonito Road on the rooftop of a Flagstaff Middle School building. The surrounding area is generally residential, with Thorpe Park located about 800 meters to the west, and US Route 180 approximately 415 meters to the east. At the end of 2013 the O3, and the PM10, and PM2.5 Partisols, will be removed from this site. Only the PM2.5 E-BAM unit will remain at the site. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Site Information 04-005-1008 755 N. Bonito St. Flagstaff, AZ 86001 Coconino Flagstaff Residential 80 m – E – N. Bonito St. 3,200 – N. Bonito St. ADEQ ID 16707 Groundcover Latitude Longitude Elevation Rooftop 35.2061 -111.6528 2,120 m Site Established Date 10/29/1996 Monitoring Information O3 PM2.5 NAAQS Public Comparison Information Max O3 Population Concentration Exposure SLAMS Special Purpose Teledyne API 400E Met One E-BAM Neighborhood 03/13/2008 Neighborhood 09/09/1999 Site Photos O3 sample cane at Flagstaff – 11/2012 Aerial view of Flagstaff Middle School State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 17 ` Globe Highway This site is the location of the collocated TSP Pb monitors in Hayden, AZ. ASARCO mine also maintains a SO2 analyzer, Pb sampler, PM sampler, wind monitor, rain gage, and temp/RH at the site. The site is located on the southwest end of a small canyon and may be influenced by both broad and local meteorological conditions. The Site is located approximately 1 km to the east/southeast of the ASARCO smelting facility. Surrounding trees are below inlet height and have no vegetation. Site Information AQS ID 04-007-1002 ADEQ ID Street Address SR 77 Winkelman, AZ 85292 County Gila Groundcover CBSA Payson Latitude Surrounding Area Desert/Residential Longitude Distance to roadway 10 m – W – SR 77 Elevation Traffic count of Nearest Major 2,700 – SR 77 Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Monitoring Information Pb Pb Temp/RH NAAQS NAAQS -Comparison Comparison Highest Highest Highest Concentration, Concentration, Concentration, Source Source Source Oriented Oriented Oriented SLAMS QA Collocated -Tisch TE8550-BL TSP Tisch TE8550-BL TSP Vaisala HMP 155 Probe Neighborhood 10/01/2010 Neighborhood 10/01/2010 Neighborhood 04/15/2011 16593 Gravel 33.002 -110.765 602 m 01/01/1975 Wind -Highest Concentration, Source Oriented -RM Young 5305 Anemometer Neighborhood 04/15/2011 Site Photos Shelter, towers, and TSP monitors at Globe Highway – 07/2013 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 18 Aerial view of Globe Highway ` Grand Canyon National Park - Hance Camp The site is operated by the NPS. The site is 183 meters south of East Rim Drive and 1,931 meters south of Grandview Point turnoff. The site is in a clearing surrounded by forest. Site Information AQS ID 04-005-8102 ADEQ ID Street Address West of SR 64 - Grand Canyon, AZ 86023 County Coconino Groundcover CBSA Flagstaff Latitude Surrounding Area Desert Longitude Distance to roadway 200 m – E – SR 64 Elevation Traffic count of Nearest Major 6,579 – SR 64 Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16682 Dirt 35.9731 -111.9841 2,235 m 09/24/1997 Monitoring Information IMPROVE Research Background IMPROVE -Regional 09/24/1997 Site Photos Regional view of Grand Canyon NP - Hance Camp Grand Canyon NP - Hance Camp shelter – date unknown State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 19 ` Greer Water Treatment Plant The site is located in the Apache National Forest and is operated the USFS. The surrounding area is forest with the town of Greer approximately 4 km to the south/southwest. Site Information AQS ID 04-001-8001 ADEQ ID Street Address SR 260 & SR 373 Greer, AZ 85927 County Apache Groundcover CBSA None Latitude Surrounding Area Forest Longitude Distance to roadway 1,600 m – N – SR 373 Elevation Traffic count of Nearest Major 1,044 – SR 373 Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16323 Grass 34.0583 -109.4400 2,503 m 01/01/2000 Monitoring Information IMPROVE Research Other IMPROVE -Regional 02/29/2000 Site Photos Aerial view of Greer Water Treatment Plant Shelter at Greer Water Treatment Plant – 08/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 20 ` Hayden Old Jail The site is located in a shelter next to the old Hayden Jail building near the center of town. The instruments were previously located in the jail building and were moved to a shelter next to the jail due to safety and siting concerns. The surrounding area consists mainly of residential and commercial. The site is located approximately 1 km to the west of the ASARCO smelting facility. ASARCO mine also maintains a sulfur dioxide analyzer at the site. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Site Information 04-007-1001 ADEQ ID Canyon Dr. & Kennecott Ave. Hayden, AZ 85235 Gila Groundcover Payson Latitude Residential Longitude 10 m – E – Canyon Dr. Elevation 1,790 – Velasco Ave. – Site Established Date 242m – E Monitoring Information SO2 PM10 Temp/RH NAAQS NAAQS -Comparison Comparison Source Source Source Oriented Oriented Oriented SLAMS SLAMS -Thermo Ecotech Vaisala HMP TEOM EC9850T 155 Probe 1400AB Neighborhood Neighborhood Neighborhood 01/01/1975 01/06/1981 02/02/2011 16326 Shelter 33.0062 -110.7864 625 m 01/01/1969 Wind -Source Oriented -RM Young 5305 Anemometer Neighborhood 02/02/2011 Site Photos Aerial view of Hayden Old Jail Hayden Old Jail shelter, PM inlet and meteorological tower – 05/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 21 ` Ike’s Backbone The site is operated by the USFS. The surrounding area is Tonto National Forest, which includes Mazatzal and Pine Mountain Wilderness areas. The site is located on a small ridge with the Verde River and mountains nearby. Site Information AQS ID 04-025-8104 ADEQ ID 16421 Street Address Fossil Creek Rd. and Childs Rd. Strawberry, AZ 85544 County Coconino Groundcover Rocks/Plants CBSA Flagstaff Latitude 34.3406 Surrounding Area Forest Longitude -111.6825 Distance to roadway 1000m – N – Childs Rd Elevation 1,303 m Traffic count of 475 – Fossil Creek Rd. – Nearest Major Site Established Date 04/02/2000 6500m – NE Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Monitoring Information IMPROVE Research Other IMPROVE -Regional 04/02/2000 Site Photos Regional view of Ike’s Backbone IMPROVE at Ike’s Backbone – 2011 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 22 ` JLG Supersite The site was established to represent air quality in the central core of the Phoenix metropolitan area. The surrounding area is primarily residential neighborhoods, with I-17 approximately 1.6 km to the west. This is also an IMPROVE protocol site. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Site Information 04-013-9997 ADEQ ID th 4530 N. 17 Ave. Phoenix, AZ 85015 Maricopa Groundcover Phoenix-Mesa-Scottsdale Latitude Residential Longitude 10 m – E – 17th Ave. Elevation 17th Ave – Not counted 1,557 – Campbell Ave. – 158m – S Site Established Date th 17,639 – N 19 Ave. – 367m – W Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Monitoring Information CO NO2 / NOx NOy NAAQS NAAQS NAAQS Comparison. Comparison Comparison Research Highest Highest Concentration, Population Concentration Population Exposure Exposure SLAMS, SLAMS, NCore NCore, PAMS PAMS Ecotech Ecotech Ecotech 9843 EC9830T EC9841B Neighborhood Neighborhood Neighborhood 07/01/1993 07/01/1993 01/01/2011 16328 Gravel 33.5038 -112.0957 354 m 07/01/1993 O3 NAAQS Comparison Max O3 Concentration SLAMS, NCore, PAMS Teledyne API 400E Neighborhood 07/01/1993 Monitoring Information SO2 Carbonyl VOC SVOC NAAQS Research Research Research Comparison Population Population Population Exposure, Max Exposure, Max Population Exposure Precursor Precursor Exposure Impact Impact Monitor type(s) SLAMS, PAMS, PAMS, NATTS NCore NATTS NATTS Instrument Ecotech Tisch TEATEC 8000 ATEC 2200 manufacture and model EC9850T 1000BL Spatial scale Neighborhood Neighborhood Neighborhood Neighborhood Monitor Start Date 03/03/2005 05/15/1999 05/15/1999 07/08/2007 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 23 Pollutant Basic monitoring objective Site type(s) ` Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Monitoring Information Pb-PM10 / PM10 metals PM10 PM10-2.5 speciation NAAQS NAAQS Comparison, Research Comparison Research Population Population Population Exposure Exposure Exposure SLAMS, NCore, SLAMS NCore NATTS Thermo Met One BAM Met One BAM Partisol 2000 1020 1020 Neighborhood Neighborhood Neighborhood 01/01/2005 07/01/1993 11/10/2010 Monitoring Information PM2.5 PM2.5 PM2.5 Speciation Speciation NAAQS Research Research Comparison Population Population Population Exposure Exposure Exposure Supplemental Supplemental SLAMS, Speciation, Speciation, NCore NCore NCore Thermo Met One URG 3000N Partisol 2000 SuperSASS Neighborhood Neighborhood Neighborhood 07/01/2003 02/21/2000 02/21/2000 Monitoring Information Wind IMPROVE -Population Exposure -RM Young 5305 Anemometer Neighborhood 07/01/1993 PM2.5 NAAQS Comparison Population Exposure SLAMS, NCore Met One BAM 1020 Neighborhood 07/01/2003 Temp/RH -Population Exposure -Vaisala HMP 155 Probe Neighborhood 07/01/1993 IMPROVE Research Research Other Other IMPROVE IMPROVE -- -- Neighborhood 04/25/2001 Neighborhood 04/25/2001 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 24 ` Site Photos Aerial view of JLG Supersite Eastern side of JLG Supersite two shelters, roof top, and meteorological tower – 08/2012 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 25 ` Meadview The site is located within the Lake Mead National Recreation Area on the north end of Meadview, AZ, where the Grand Canyon meets Lake Mead. The surrounding area is primarily desert. To the southwest 64.4 km is US 93, which is the closest highway to the site and about 96.5 km to the southeast is downtown Kingman. This is an IMPROVE protocol site. Site Information AQS ID 04-015-9000 ADEQ ID Street Address Pierce Ferry Rd. Meadview, AZ 86444 County Mohave Groundcover CBSA Lake Havasu City-Kingman Latitude Surrounding Area Desert/Residential Longitude Distance to roadway 100 m – E – Pierce Ferry Rd Elevation Traffic count of Nearest Major 0 – Pierce Ferry Rd. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 21298 Gravel/Desert 36.0194 -114.0685 907 m 09/04/1991 Monitoring Information IMPROVE Research Background IMPROVE -Regional 09/04/1991 Site Photos Photo of Meadview shelter – 06/2015 Regional view of Meadview State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 26 ` Miami Golf Course This site is the location of the TSP-Pb monitor in Miami, AZ. Freeport McMoRan Copper and Gold Inc. also maintained two particulate matter monitors at the site but were removed as of January 2014. The site is located near the Cobre Valley Country Club with residential areas to the south and east and the Freeport McMoRan facility approximately 2 km to the west/southwest. Surrounding trees are below inlet height and have no vegetation. Site Information AQS ID 04-007-8000 ADEQ ID Street Address SR 188 and US 60 Miami, AZ 85539 County Gila Groundcover CBSA Payson Latitude Surrounding Area Residential Longitude Distance to roadway 220 – SE – SR 188 Elevation Traffic count of Nearest 3,300 – SR 188 Site Established Date Major Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Monitoring Information Pb PM10 Temp/RH NAAQS NAAQS -Comparison Comparison Source Source Source Oriented Oriented Oriented SLAMS SLAMS -Thermo Tisch TEVaisala HMP TEOM 8550-BL TSP 155 Probe 1400AB Neighborhood Neighborhood Neighborhood 10/01/2010 7/26/2012 06/08/2011 16629 Gravel 33.4190 -110.8296 1000 m 01/01/1997 Wind -Source Oriented -RM Young 5305 Anemometer Neighborhood 06/08/2011 Site Photos Aerial view of Miami Golf Course Fenced Miami Golf Course site – 05/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 27 ` Miami Jones Ranch This site is one of three SO2 sites in the Miami area. Freeport McMoRan Copper and Gold Inc. operate a SO2 instrument at this site as well. The site is located south of the town of Miami and is over 3 km south/southwest of the smelter. The site located in the desert hills overlooking the town and is off a gravel/dirt road. Site Information AQS ID 04-007-0011 ADEQ ID Street Address Cherry Flats Rd. Miami, AZ 85539 County Gila Groundcover CBSA Payson Latitude Surrounding Area Residential Longitude 15m – SE – Cherry Flats Distance to roadway Elevation Rd. Traffic count of Nearest n/a Site Established Date Major Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16631 Gravel 33.3853 -110.8673 1,242 m 01/01/1997 Monitoring Information SO2 NAAQS Comparison Source Oriented SLAMS Ecotech EC9850T Neighborhood 02/01/2013 Site Photos Fenced Miami Jones Ranch site – 05/2014 Aerial view of Miami Jones Ranch State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 28 ` Miami Ridgeline This is one of three SO2 site in the Miami area. The site is located inside on private property off of Linden Road and sits on the side of a north-south oriented ridge, which slopes in a northerly direction toward the town of Miami. The surrounding area is desert. Freeport McMoRan Copper and Gold Inc. also maintain a PM10 monitor at the site. The Freeport McMoRan smelter is 1.6 km to the north of the site. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Site Information 04-007-0009 ADEQ ID 4030 Linden St. Miami, AZ 85539 Gila Groundcover Payson Latitude Residential Longitude 40 m – N – Linden St. Elevation Linden St – Not Counted 510 – Loomis Ave. – Site Established Date 230m – W Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16382 Dirt 33.3992 -110.8589 1,085 m 01/01/1993 Monitoring Information SO2 NAAQS Comparison Source Oriented SLAMS Thermo 43C Neighborhood 10/05/1995 Site Photos Aerial view of Miami Ridgeline Fenced Miami Ridgeline site – 05/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 29 ` Miami Townsite This site is one of three SO2 sites in the Miami area. Freeport McMoRan Copper and Gold Inc. run a SO2 instrument at this site as well. This site is located on the western side of Miami, near the center of the town. There is a church to the west and a Police Station to the west with residential to the north and south. The road is located to the south of the site. The smelter is over 2 km to the northwest of the site. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Site Information 04-007-0012 ADEQ ID Sullivan ST & Davis Canyon Miami, AZ 85539 Gila Groundcover Payson Latitude Residential Longitude 16.5 m – SE – Sullivan Elevation St. 470 – Sullivan St. Site Established Date 16382 Gravel 33.3973 -110.8744 1,042 m 0/01/1997 Monitoring Information SO2 NAAQS Comparison Source Oriented SLAMS Ecotech EC9850T Neighborhood 02/01/2013 Site Photos Aerial view of Miami Townsite Fenced Miami Townsite – 05/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 30 ` Nogales Post Office The site is located on the rooftop of the U.S. Post Office building, which lies approximately 670 meters north from the Arizona/Mexico Border. The surrounding area is a mixture of commercial and residential land use. This site is used to meet the PM2.5 collocation requirement. Site Information AQS ID 04-023-0004 ADEQ ID Street Address 300 N. Morley Ave. Nogales, AZ 85621 County Santa Cruz Groundcover CBSA Nogales Latitude Surrounding Area Residential/Commercial Longitude Distance to roadway 37.6 m – NW – Morley Ave. Elevation Traffic count of Nearest Major 7,199 – Morley Ave. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Monitoring Information PM10 PM10 PM2.5 NAAQS NAAQS NAAQS Comparison Comparison Comparison Population Population Highest Exposure Exposure Concentration SLAMS QA Collocated SLAMS Met One BAM Thermo Met One BAM 1020 Partisol 2000 1020 Neighborhood Neighborhood Neighborhood 01/01/1980 01/01/1980 04/01/1999 16511 Rooftop 31.3372 -110.9367 1,176 m 01/01/1980 PM2.5 NAAQS Comparison Highest Concentration QA Collocated Thermo Partisol 2000 Neighborhood 04/01/1999 Monitoring Information Temp/RH Wind -- -- Population Exposure -- Population Exposure -RM Young 5305 Anemometer Neighborhood 01/01/1980 Vaisala HMP 155 Probe Neighborhood 08/11/2011 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 31 ` Site Photos Aerial view of Nogales Post Office Particulate and meteorological monitors on roof of Nogales Post Office – 04/2013 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 32 ` North Mountain Summit The site is located on a mountaintop in the North Mountain Recreation Area of Phoenix. The high-resolution digital camera faces South Mountain, which lies 27 km to the south. The pictures of the local views are updated every 5 minutes and can be viewed on the internet at http://phoenixvis.net/index.aspx. The surrounding area is desert recreation area to the north and west and residential with some commercial activity to the south and east. Site Information AQS ID None ADEQ ID 16480 th Street Address West side of 7 St. in North Mountain Recreation Area Phoenix, AZ County Maricopa Groundcover Dirt/Desert CBSA Phoenix-Mesa-Scottsdale Latitude 33.5855 Surrounding Area Residential/Desert Longitude -112.0722 Distance to roadway 850 m – E – 7th St. Elevation 625 m Traffic count of Nearest Major 28,210 – 7th St. Site Established Date 01/01/1993 Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Monitoring Information Visibility Visibility Public Public Information Information Population Population Exposure Exposure --CANON EOS CANON EOS Rebel T2i Rebel T2i Urban Urban 01/01/1993 01/01/1993 Site Photos Camera located on tower at North Mountain Summit – 04/2013 Aerial view of North Mountain Summit State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 33 ` Organ Pipe National Monument The site is owned by the NPS, who operates the monitor at the site. The site is located 1 km south/southwest of the national monument visitor center, which is about 35.4 km south of Why, AZ. The site is about seven meters from a water pump house and lies about 540 meters east of a small mountain range. The surrounding area is predominately desert. This is an IMPROVE protocol site. Site Information AQS ID 04-019-0005 ADEQ ID Street Address SR 85 & Puerto Blanco Rd. Ajo, AZ 85321 County Pima Groundcover CBSA Tucson Latitude Surrounding Area Desert Longitude Distance to roadway 400 m – E – SR 85 Elevation Traffic count of Nearest Major 1,525 – SR 85 Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16681 Gravel 31.9499 -112.8010 505 m 01/01/1971 Monitoring Information IMPROVE Research Other IMPROVE -Regional 01/15/2003 Site Photos Regional view of Organ Pipe NM Shelter at Organ Pipe NM – 04/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 34 ` Paul Spur Chemical Lime Plant The site is located approximately 1 km to the northeast of the Chemical Lime Plant, just south of SR 80 between Bisbee and Douglas, and 3.5 km north of the Arizona/Mexico border. In 2011 the meteorological instruments were re-located to this site when the Paul Spur Chemical Lime Plant South site was closed. Other than the nearby Chemical Lime Plant, the surrounding area is predominately desert. The Chemical Lime Plant is not operational at this time. Site Information AQS ID 04-003-0011 ADEQ ID Street Address SR 80 & Paul Spur Rd. Paul Spur, AZ 85603 County Cochise Groundcover CBSA Sierra Vista-Douglas Latitude Surrounding Area Desert Longitude Distance to roadway 107 m – S – Paul Spur Rd. Elevation Traffic count of Paul Spur Rd – Not Counted Nearest Major 4,920 – SR 80 – Site Established Date Roadway 230m – N Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16391 Dirt 31.3658 -109.7309 1,278 m 01/01/1985 Monitoring Information PM10 Temp/RH Wind NAAQS --Comparison Source Source Source Oriented Oriented Oriented SLAMS --Thermo RM Young Vaisala HMP TEOM 5305 155 Probe 1400AB Anemometer Middle Middle Middle 01/06/1991 12/01/2011 12/01/2011 Site Photos Aerial view of Paul Spur CLP Particulate monitors and meteorological tower at Paul Spur CLP – 03/2013 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 35 ` Payson Well Site The site is located in the southern area of Payson, in a field at a well water site. To the south of the site are two tanks. In general, the surrounding area is commercial with some residential land use and 200 meters to the south east is SR 87. Site was moved 90m NE on the same parcel to meet siting requirements. The Thermo Partisol 2000 will be replaced with a continuous Met One BAM 1020 starting July 1, 2014. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Site Information 04-007-0008 ADEQ ID 204 W. Aero Dr. Payson, AZ 85541 Gila Groundcover Payson Latitude Residential/Commercial Longitude 134 m – S – Aero Dr. Elevation 1,724 – Aero Dr. Site Established Date Monitoring Information PM10 PM2.5 NAAQS Public Comparison Information Population Population Exposure Exposure Special SLAMS Purpose 16317 Gravel 34.2297 -111.3295 1,501 m 01/01/1991 Temp/RH Wind -- -- Population Exposure Population Exposure -- -- Met One BAM 1020 Met One E-BAM Vaisala HMP 45C Probe Neighborhood 01/01/1991 Neighborhood 05/16/2012 Neighborhood 05/30/1991 RM Young 5103 Anemometer Neighborhood 05/30/1991 Site Photos Aerial view of Payson Well Site Payson Well Site continuous particulate monitor probe and shelter – 07/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 36 ` Petrified Forest National Park The site is operated by the NPS and is located 1.6 km north of park headquarters. The park sits along I-40 and the surrounding area is desert. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Site Information 04-001-0012 ADEQ ID 16473 I-40 & Petrified Forest Rd. Petrified Forest National Park, AZ Apache Groundcover Dirt None Latitude 35.0770 Desert Longitude -109.7690 1,050 m – SW – I-40 Elevation 1,766 m Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 15,246 – I-40 Site Established Date 03/02/1988 Monitoring Information IMPROVE Research Background IMPROVE -Regional 03/02/1988 Site Photos Regional view of Petrified Forest NP Photo of Petrified Forest NP taken from IMPROVE website – date unknown State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 37 ` Phoenix Transmissometer Receiver The site is located in downtown Phoenix on the rooftop of the Holiday Inn Hotel near 2nd Avenue and Osborn Road. The transmitter is located on top of the Phoenix Baptist Hospital 4.5 km to the northwest. The area between the two sites is a mix of residential and commercial. Site Information AQS ID None ADEQ ID nd Street Address 3600 N. 2 Ave. Phoenix, AZ 85013 County Maricopa Groundcover CBSA Phoenix-Mesa-Scottsdale Latitude Surrounding Area Commercial/Residential Longitude Distance to roadway 25 m – E – Central Ave. Elevation Traffic count of Nearest Major 1,5470 – Central Ave. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16829 Rooftop 33.4901 -112.0767 337 m 12/01/1992 Monitoring Information Bext Temp R/H Public -Information Population Population Exposure Exposure --Optec LVP-2 Vaisala Transmissometer HMP155 Receiver Probe Urban Urban 12/01/1992 01/01/1994 Site Photos Aerial view of Phoenix Transmissometer Receiver Phoenix Transmissometer Receiver on hotel rooftop – 12/2012 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 38 ` Phoenix Transmissometer Transmitter The transmitter is located on the rooftop of Phoenix Baptist Hospital at 19th Avenue and Bethany Home Road. The receiver is located at the Holiday Inn Hotel 4.5 km to the southeast. The area between the two sites is a mix of residential and commercial. A new LED bulb was installed in May 2014. Site Information AQS ID None ADEQ ID Street Address 2000 W. Bethany Home Rd. Phoenix, AZ 85015 County Maricopa Groundcover CBSA Phoenix-Mesa-Scottsdale Latitude Surrounding Area Commercial/Residential Longitude Distance to roadway 120 m – S – Beth. Home Rd. Elevation Traffic count of Nearest Major 40,950 – Bethany Home Rd. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16330 Rooftop 33.5253 -112.1019 340 m 12/01/1992 Monitoring Information Bext Public Information Population Exposure -Optec LVP-2 Transmissometer Urban 12/01/1992 Site Photos Aerial view of Phoenix Transmissometer Transmitter Phoenix Transmissometer Transmitter Pathway – 2005 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 39 ` Pleasant Valley Ranger Station The site is operated by USFS. The site is located on a hilltop south of Young, AZ, within the Sierra Ancha Wilderness and Tonto National Forest. The surrounding area is a transitional zone between desert and forest. The site lies 1,160 meters to the south of SR 288. Site Information AQS ID 04-007-8100 ADEQ ID Street Address SR 288 & Old Cherry Rd. Young, AZ 85541 County Gila Groundcover CBSA Payson Latitude Surrounding Area Desert/Forest Longitude Distance to roadway 250 m – N – SR 288 Elevation Traffic count of Nearest Major 143 – SR 288 Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16446 Dirt 34.0908 -110.9419 1,587 m 01/01/2000 Monitoring Information IMPROVE Research Other IMPROVE -Regional 02/10/2000 Site Photos Regional view of Pleasant Valley Ranger Station Shelter at Pleasant Valley Ranger Station – 03/2015 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 40 ` Prescott College AQD The site was relocated at Prescott College from the Mogollon Building to the Penstemon Building due to Mogollon Building’s renovation and to meet siting requirements in 2013. The surrounding area is residential and commercial, with a high traffic street approximately 45 meters to the east. Site Information AQS ID 04-025-8033 ADEQ ID Street Address 330 Grove Ave., Prescott, AZ 86301 County Yavapai Groundcover CBSA Prescott Latitude Surrounding Area Residential/Commercial Longitude Distance to roadway 45m – E – Grove Ave. Elevation Traffic count of Nearest Major 13,300 – Grove Ave. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 133011 Rooftop 34.5451 -112.4768 1,636 m 12/05/2006 Monitoring Information O3 PM2.5 NAAQS Public Comparison Information Max O3 Population Concentration Exposure Special SLAMS Purpose Met One Teledyne 400e E-BAM Neighborhood Neighborhood 03/25/2008 07/13/2011 Site Photos Aerial view of Prescott College AQD Prescott College AQD – 06/2015 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 41 ` Queen Valley The site is located in northern Pinal County on the far east/southeastern outskirts of the Phoenix metropolitan area. It is located 635 meters southeast of the small town of Queen Valley, AZ and the surrounding area is primarily desert. This is a downwind PAMS type 3 site. This is also an IMPORVE protocol site. Site Information AQS ID 04-021-8001 ADEQ ID Street Address 10 S. Queen Anne Dr. Queen Valley, AZ 85219 County Pinal Groundcover CBSA Phoenix-Mesa-Scottsdale Latitude Surrounding Area Desert Longitude Distance to roadway 87 m – E – Queen Anne Dr. Elevation Traffic count of Nearest Major 1,284 – Queen Anne Dr. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Monitoring Information O3 NOy NAAQS Research Comparison Downwind Downwind SLAMS, PAMS PAMS Teledyne API Thermo 42C 400E TL Reactive Regional Regional 01/01/1998 01/01/1998 16394 Gravel 33.2938 -111.2857 668 m 01/01/1998 VOC Temp/RH Research -- Downwind Downwind PAMS -- ATEC 8001 Regional 05/20/2001 Vaisala HMP 45C Probe Regional 06/23/2003 Monitoring Information Wind IMPROVE -- Research Downwind -RM Young 5103 Anemometer Regional 06/23/2003 Other IMPROVE -Regional 04/30/2001 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 42 ` Site Photos Regional view of Queen Valley Shelter and meteorological tower at Queen Valley site – 08/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 43 ` Rillito In February of 2007 the site was moved from the Water St. location 91 meters southwest to its current location at a city water pumping station. The surrounding area is primarily residential and industrial, with I-10 approximately 260 meters to the northeast. The site is located within the small town of Rillito, AZ and is approximately 500 meters to the north/northwest of the Cal Portland Rillito Cement Plant. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Site Information 04-019-0020 ADEQ ID 8840 W. Robinson St. Rillito, AZ 85653 Pima Groundcover Tucson Latitude Residential Longitude 10 m – S – Robinson St. Elevation 2,634 – I-10 Frontage Rd. Site Established Date – 240m – NE 16499 Dirt 32.4143 -111.1545 626 m 01/01/1985 Monitoring Information PM10 Temp/RH Wind NAAQS --Comparison Source Source Source Oriented Oriented Oriented SLAMS --Thermo RM Young Vaisala HMP TEOM 5103 45C Probe 1400AB Anemometer Middle Middle Middle 01/03/1985 03/30/2010 01/08/2004 Site Photos Aerial view of Rillito Rillito meteorological tower and particulate monitors on platform – 01/2015 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 44 ` Saguaro National Park East The site is located within the Saguaro National Park East, 805 meters south of park headquarters and is operated jointly by PDEQ and NPS. The area surrounding the site is scattered residential to the west and desert to the east. Site Information AQS ID 04-019-0021 ADEQ ID Street Address 3905 S. Old Spanish Trail Tucson, AZ 85730 County Pima Groundcover CBSA Tucson Latitude Surrounding Area Residential/Desert Longitude Distance to roadway 82 m – W – Old Spanish Tr. Elevation Traffic count of Nearest Major 6,198 – Old Spanish Trail Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16474 Dirt 32.1740 -110.7360 938 m 06/04/1988 Monitoring Information IMPROVE Research Background IMPROVE -Regional 06/04/1988 Site Photos Regional view of Saguaro NP East Photo of Saguaro NP East taken from IMPROVE website – date unknown State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 45 ` Saguaro National Park West The site is located within the Saguaro National Park West. The site is operated by the NPS. The area surrounding the site is residential to the northwest and south/southeast and desert to the northeast. The site lies approximately 17 km southwest of I-10. This is an IMPROVE protocol site. Site Information AQS ID 04-019-9000 ADEQ ID Street Address N. Sandario Rd. and W. Mile Wide Rd. Tucson, AZ County Pima Groundcover CBSA Tucson Latitude Surrounding Area Desert Longitude Distance to roadway 27 m – W – Mile Wide Rd. Elevation Traffic count of Nearest Major 1,889 – Mile Wide Rd. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16475 Gravel 32.2485 -111.2175 718 m 12/29/1996 Monitoring Information IMPROVE Research Other IMPROVE -Regional 04/19/2001 Site Photos Shelters at Saguaro NP West site – 07/2012 Regional view of Saguaro NP West State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 46 ` Sedona Fire Station AQD In 2011, the EBAM instrument in Sedona was moved from the Sedona Post Office site to the Sedona Fire Station site due to concerns about local emissions affecting the monitor. The Sedona Fire Station site is located approximately 300 meters to the northeast of the Sedona Post Office site. The surrounding area is composed of residential and commercial use. AQS ID Street Address County CBSA Surrounding Area Distance to roadway Traffic count of Nearest Major Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Site Information None 310 Forest Rd, Sedona, AZ 86336 Coconino Flagstaff Commercial/Residential 50m – N – Forest Rd 5,689 – SR 89A – 150m – E ADEQ ID 142818 Groundcover Latitude Longitude Elevation Rooftop 34.8683 -111.7633 1,326 m Site Established Date 12/16/2011 Monitoring Information PM2.5 Public Information Population Exposure Special Purpose Met One E-BAM Neighborhood 12/16/2011 Site Photos Aerial view of Sedona Fire Station E-BAM on roof at Sedona Fire Station – 3/2012 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 47 ` South Phoenix The site is owned by MCAQD. ADEQ operates the toxics sampler at the site. The site is situated in South Phoenix, at the edge of a high population area, bordering a mixture of residential and commercial properties. Two high population areas are located north and west of the site. Site Information AQS ID 04-013-4003 ADEQ ID Street Address 33 W. Tamarisk St. Phoenix, AZ 85041 County Maricopa Groundcover CBSA Phoenix-Mesa-Scottsdale Latitude Surrounding Area Residential/Commercial Longitude Distance to roadway 83 m – N – Tamarisk St. Elevation Traffic count of 19,110 – Central Ave. – Nearest Major Site Established Date 165m – E Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16377 Asphalt 33.4030 -112.0750 330 m 01/01/1997 Monitoring Information VOC Research Population Exposure UATMP ATEC 8001 Neighborhood 8/5/2001 Site Photos Shelter and meteorological tower at South Phoenix site – 04/2005 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 48 Aerial view of South Phoenix ` Sycamore Canyon The site is located near the corner of Garland Prairie Road and Thomas Loop Road. This site was moved from a location near the Camp Raymond BSA camp. It was relocated approximately one mile to the north west. Site Information AQS ID 04-005-8103 ADEQ ID Street Address Camp Kimball Rd. Flagstaff, AZ (Camp Raymond) County Coconino Groundcover CBSA Flagstaff Latitude Surrounding Area Forest Longitude 33 m – NW – Boy Scout Distance to roadway Elevation Camp Rd Traffic count of 15,048 – I-40 – Nearest Major Site Established Date 12km – N Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16476 Dirt/Grass 35.1406 -111.9692 2,046 m 09/11/1991 Monitoring Information IMPROVE Research Background IMPROVE -Regional 09/11/1991 Site Photos Regional view of Sycamore Canyon Shelter at Sycamore Canyon site – 11/2012 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 49 ` Tonto National Monument The site is jointly operated by ADEQ and USFS. The site is located within the Tonto National Forest at the base of Tonto National Monument, about 40 meters south of SR 188. The area surrounding the site is desert with Roosevelt Lake about 1 km to the north. Site Information AQS ID 04-007-0010 ADEQ ID Street Address South of SR 188 Roosevelt, AZ 85545 County Gila Groundcover CBSA Payson Latitude Surrounding Area Desert Longitude Distance to roadway 17 m – NE – SR 188 Elevation Traffic count of Nearest Major 800 – SR 188 Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date 16447 Dirt/Rock 33.6547 -111.1074 786 m 04/23/1988 Monitoring Information O3 IMPROVE NAAQS Research Comparison Downwind Background SLAMS IMPROVE Teledyne API -400E Regional Regional 05/22/2002 04/23/1988 Site Photos Regional view of Tonto NM Shelter at Tonto NM site – 08/2013 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 50 ` Vehicle Emissions Laboratory The site is located in the northwest corner of the Vehicle Emissions Laboratory property. The surrounding area is a both residential and commercial, with an open field directly to the northwest. The site is about 415 meters south of Red Mountain Freeway (Loop 202). Site Information AQS ID 04-013-9998 ADEQ ID th Street Address 600 N. 40 St. Phoenix, AZ 85008 County Maricopa Groundcover CBSA Phoenix-Mesa-Scottsdale Latitude Surrounding Area Residential/Commercial Longitude Distance to roadway 66 m – E – 40th St. Elevation Traffic count of Nearest Major 10,740 – 40th St. Site Established Date Roadway 16363 Gravel 33.4553 -111.9961 356 m 04/01/1987 Monitoring Information Pollutant Bscat/PM2.5 Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Public Information Population Exposure -Optec NGN 2 Nephelometer Urban 06/25/2003 Delta Temp Horizontal Solar Radiation Ultraviolet Solar Radiation Research Research Research Population Exposure PAMS RM Young 7627 Neighborhood 08/20/2004 Population Exposure PAMS Population Exposure PAMS Epply TUVR UV Neighborhood 08/20/2004 Li-Cor 200S2 Neighborhood 06/18/1999 Monitoring Information Temp R/H Wind -- -- Population Exposure -Rotronics MP101A Probe Neighborhood 05/11/1999 Population Exposure -Vaisala HMP155 Probe Neighborhood 05/11/1999 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 51 ` Site Photos Aerial view of Vehicle Emissions Laboratory Meteorological tower, and shelter at VEL – 12/2012 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 52 ` Yuma Supersite The site was reopened in 2008 and has been used to consolidate air quality monitors in the Yuma area to one site. The site is located on the southeast corner of the Rural Metro Administration Facility property. The surrounding area is commercial and industrial, with a dirt lot adjacent to the south and I-8 1 km to the northeast. In addition to NAAQS compliance, the site is also used to help understand transport of PM and Ozone. Site Information AQS ID 04-027-8011 ADEQ ID Street Address 2323 S. Arizona Ave. Yuma, AZ 85364 County Yuma Groundcover CBSA Yuma Latitude Surrounding Area Commercial/Industrial Longitude Distance to roadway 91 m – W – Arizona Ave. Elevation Traffic count of Nearest Major 12,302 – Arizona Ave. Site Established Date Roadway Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Pollutant Basic monitoring objective Site type(s) Monitor type(s) Instrument manufacture and model Spatial scale Monitor Start Date Monitoring Information O3 PM10 PM2.5 NAAQS NAAQS NAAQS Comparison Comparison Comparison Max O3 Population Regional Concentration Exposure Transport SLAMS SLAMS SLAMS Thermo Teledyne API Met One BAM TEOM 400E 1020 1400AB Neighborhood Neighborhood Neighborhood 05/06/2008 12/01/2009 01/01/2010 113219 Gravel 32.6903 -114.6144 60 m 02/01/2006 Temp/RH -Population Exposure -Vaisala HMP 155 Probe Neighborhood 03/17/2010 Monitoring Information Wind -Population Exposure -RM Young 5305 Anemometer Neighborhood 03/17/2010 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 53 ` Site Photos Aerial view of Yuma Supersite Shelter and Meteorological Tower at Yuma Supersite – 4/2014 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix D Page 54 Appendix E – Criteria Pollutant Minimum Monitoring Requirements This appendix contains tables that summarize the criteria pollutant minimum monitoring requirements for each MSA or CBSA that ADEQ is designated as the Primary Quality Assurance Organization (PQAO). Minimum monitoring requirements for the Phoenix-Mesa-Scottsdale and Tucson MSAs are not included within this appendix as ADEQ is not the PQAO for these MSAs. State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix E Page 1 O3 (Note: Refer to section 4.1 and Table D-2 of Appendix D to 40 CFR Part 58) Table 1. Minimum Monitoring Requirements for O3. 2011-2013 # of Required # of Active 8-hr Design Design Value Site Monitors Monitors Value (ppb) Flagstaff Coconino 134,421 69 Flagstaff Middle School 1 1 Prescott Yavapai 211,033 69 Prescott College AQD 1 1 Yuma Yuma 195,751 76 Yuma Supersite 1 1 Lake Havasu-Kingman Mohave 200,186 N/A N/A 0 0 Sierra Vista - Douglas Cochise 131,346 N/A N/A 0 0 Monitors required for SIP or Maintenance Plan: Alamo Lake, JLG Supersite, Queen Valley, and Tonto National Monument. _________________________________________________________________________ MSA County 2010 Census Population # of Additional Monitors Needed 0 0 0 0 0 PM2.5 (Note: Refer to sections 4.7.1, 4.7.2 and Table D-5 of Appendix D to 40 CFR Part 58) Table 2 Minimum Monitoring Requirements for PM2.5 SLAMS. (FRM/FEM/ARM, see 40CFR 58 App D Section 4.7.1 and Table D-5) 2011-2013 Annual Design Value (μg/m3) MSA County 2010 Census Population Flagstaff Coconino 134,421 5.3 Prescott Yavapai 211,033 4.2 Yuma Yuma 195,751 7.8 Annual Design Value Site Flagstaff Middle School Prescott Valley Yuma Supersite Lake HavasuMohave 200,186 N/A N/A Kingman Sierra Douglas Vista Cochise 131,346 6.7 Red Cross Douglas * Continuous monitors are not FRMs, FEMs, or ARMs Monitors required for SIP or Maintenance Plan: Nogales Post Office. 2011-2013 Daily Design Value (μg/m3) 12 10 16 N/A 12 # of Required Monitors # of Required Continuous Monitors # of Active Continuous Monitors # of Additional Monitors Needed 0 0 1* 0 0 0 1* 0 1 1 1 0 N/A 0 0 0 0 Douglas Red Cross 1 1 1 0 Daily Design Value Site Flagstaff Middle School Prescott Valley Yuma Supersite State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix E Page 2 PM10 (Note: Refer to section 4.6 and Table D-4 of Appendix D to 40 CFR Part 58) Table 3. Minimum Monitoring Requirements for PM10. MSA County 2010 Census Population 2011-2013 Max Concentration [μg/m3] Max Concentration Site # of Required Monitors # of Active Monitors # of Additional Monitors Needed Flagstaff Coconino 134,421 61 Flagstaff Middle School 0 1 0 Prescott Yavapai 211,033 90 Prescott Valley 0 1 0 Yuma Yuma 195,751 274 Yuma Supersite 1-2 1 0 Lake Havasu-Kingman Mohave 200,186 185 Bullhead City 1-2 1 0 Sierra Vista - Douglas Cochise 131,346 251 Douglas Red Cross 1-2 2 0 Monitors required for SIP or Maintenance Plan: Ajo, Bullhead City, Douglas Red Cross, Hayden Old Jail, JLG Supersite, Miami Golf Course, Miami Ridgeline, Nogales Post Office, Paul Spur Chemical Lime Plant, Payson Well Site, Rillito, and Yuma Supersite. _________________________________________________________________________ NO2 (Note: Refer to section 4.3 of Appendix D to 40 CFR Part 58) Table 4. Minimum Monitoring Requirements for NO2. CBSA 2010 Census 2010 Population Max AADT Counts # of Required Near-road Monitors # of Active Near-road Monitors # of Additional Near-road Monitors Needed # of Required Area-wide Monitors # of Active Area-wide Monitors # of Additional Area-wide Monitors Needed Flagstaff 134,421 40,500 0 0 0 0 0 0 Prescott 211,033 38,000 0 0 0 0 0 0 Yuma 195,751 37,000 0 0 0 0 0 0 Lake Havasu – Kingman 200,186 34,500 0 0 0 0 0 0 0 0 0 0 Sierra Vista - Douglas 131,346 32,000 0 0 Monitors required for SIP or Maintenance Plan: None Monitors required for PAMS: JLG Supersite EPA Regional Administrator-required monitors per 40 CFR 58, App. D 4.3.4: None _________________________________________________________________________ SO2 (Note: Refer to section 4.4 of Appendix D to 40 CFR Part 58) Table 5. Minimum Monitoring Requirements for SO2. CBSA County 2010 Census Population 2011 Total SO21 [tons/year] Population Weighted Emissions Index2 [million persons-tons per year] 1.34 # of Required Monitors # of Active Monitors 0 0 # of Additional Monitors Needed 0 Flagstaff Coconino 134,421 10 Prescott Yavapai 211,033 2000 422 0 0 0 Yuma Yuma 195,751 12.6 2.40 0 0 0 Lake Havasu – Kingman Mohave 200,186 14.44 2.89 0 0 0 0 0 0 Sierra Vista - Douglas Cochise 131,346 3922 515 Using NEI data 2 Calculated by multiplying CBSA population and total SO2 and dividing product by one million 1 Monitors required for SIP or Maintenance Plan: Hayden Old Jail and Miami Ridgeline. EPA Regional Administrator-required monitors per 40 CFR 58, App. D 4.4.3: None _________________________________________________________________________ State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix E Page 3 CO (Note: Refer to section 4.2 of Appendix D to 40 CFR Part 58) Table 6. Minimum Monitoring Requirements for CO. CBSA 2010 Census # of Required Population Near-Road Monitors # of Active Near-Road Monitors # of Additional Monitors Needed Flagstaff 134,421 0 0 0 Prescott 211,033 0 0 0 Yuma 195,751 0 0 0 Lake Havasu – Kingman 200,186 0 0 0 Sierra Vista - Douglas 131,346 0 0 0 Monitors required for SIP or Maintenance Plan: JLG Supersite EPA Regional Administrator-required monitors per 40 CFR 58, App.D 4.2.2: None _____________________________________________________________________________ Pb (Note: Refer to section 4.5 of Appendix D to 40 CFR Part 58) Table 7a. Minimum Monitoring Requirements for Pb at NCore. NCore Site CBSA 2010 Census Population JLG Supersite State-wide Requirement 4,192,887 # of Required Monitors 1 # of Active Monitors # of Additional Monitors Needed 1 0 Table 7b. Minimum Source-Oriented Pb Monitoring above 0.5 Tons Per Year (including airports)1 Source Name Address Pb Emissions Emission Max 3-Month Design Value (tons per Inventory Design Date year) Source & Value* (third month, Data Year [μg/m3 ] year) ADEQ ASARCO LLC -3.87 0.27 June, 2011 2011 Freeport McMoRan ADEQ -4.87 0.06 April, 2011 Copper and Gold 2011 Inc. Ernest A. Love -0.89 NEI 2011 --Field Falcon Field -- 0.77 NEI 2011 -- Chandler -0.58 NEI 2011 -Municipal Phoenix -0.50 NEI 2011 -Goodyear Phoenix Deer -1.16 NEI 2011 -Valley2 *consider data from the past 3 years. 1 Monitoring Required on all non-airport sources above 0.5 TPY and on Airports above 1.0 TPY 2 Phoenix Deer Valley is not on the list of Airports to be monitored for Pb Monitors required for SIP or Maintenance Plan: None EPA Regional Administrator-required monitors per 40 CFR 58, App. D 4.5(c): None # of Required Monitors # of Active Monitors # of Additiona l Monitors Needed 1 1 0 1 1 0 0 0 0 -- 0 0 0 -- 0 0 0 -- 0 0 0 -- 0 0 0 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix E Page 4 Appendix F – Letters to EPA This appendix may contain letters to EPA that have occurred during current Network Plan time period. The letters may include siting waivers, requests for system modifications, and other communications outside of the Annual Network Plan. State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix F Page 1 Page 2of 2 ADEQ does not have any siting waivers, system modifications outside the Annual Network Plan, or other letters to EPA for the 2015 Network Plan. State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix F Page 2 Page 1of 3 Appendix G – ADEQ’s Air Quality Monitoring Role in Arizona This appendix contains a document to outline the responsibilities delineated to each monitoring agency in Arizona. State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix G Page 1 Page 2of 3 State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix G Page 2 Page 3of 3 Table 1: Minimum Monitoring Requirements in Arizona State of Arizona Air Monitoring Network Plan for the Year 2015, Appendix G Page 3