Main System 10-112 2009 Annual Water Quality Report City of Tucson Water Quality Management & Operations Division This Annual Water Quality Report provides information on your drinking water. The United States Environmental Protection Agency (USEPA) requires that all drinking water suppliers provide a water quality report to their customers on an annual basis. This report also contains important information on the quality of your water and contact information you may wish to use. Where does my water come from? Tucson Water serves about 734,000 people in the Tucson area. The water supply comes from approximately 200 groundwater wells located in and around the Tucson metropolitan area (see map). Most of the wells (also known as Entry Points to the Distribution System or EPDS) serve the neighborhood in which they are located, with excess supply routed to reservoirs for use elsewhere in the system. Tucson Water’s system contains 28 water service areas that are located in and around the Tucson metropolitan area, 4,500 miles of pipes, and 145 booster stations that are dedicated to pumping drinking water. For accommodations; materials in accessible formats; foreign language interpreters; and/or materials in a language other than English, please contact Tucson Water at (520) 791-4331 or (520) 791-2639 for TDD. at least 5 business days in advance of this scheduled event. 1 Why are there contaminants in my drinking water? All drinking water, including bottled water, may reasonably be expected to contain at least small amounts of some contaminants. Tucson’s groundwater contains dissolved minerals and organic compounds, which have been leached from the rock, sediments, and plant materials through which the water travels. One would expect to find beneficial minerals such as calcium and magnesium, harmless minerals such as chloride, bicarbonate, and sulfate, and metals such as iron, copper, arsenic, and lead, which may be either beneficial or harmless at low concentrations, but harmful at high concentrations. In addition to these naturally occurring contaminants, our groundwater may contain contaminants resulting from industrial or domestic activities. For this reason, water utilities must currently monitor for approximately 90 regulated and 25 unregulated contaminants. The following language is required by the USEPA to appear in this report, some of which may not be applicable to deep groundwater wells, the primary source of the Tucson Water supply: Contaminants that may be present in source water can include: • Microbial contaminants, such as viruses and bacteria, which may come from sewage, septic systems, agricultural livestock, and wildlife. • Inorganic contaminants, such as salts and metals, which can be naturally-occurring or result from urban stormwater runoff, industrial or domestic wastewater discharges, oil and gas production, mining, or farming. • Pesticides and herbicides, which may come from a variety of sources such as agriculture, urban stormwater runoff, and residential uses. • Organic chemical contaminants, including synthetic and volatile organic chemicals, which are byproducts of industrial processes and petroleum production, and can also come from gas stations, urban stormwater runoff, and septic systems. • Radioactive contaminants, which can be naturally occurring or be the result of oil and gas production and mining activities. Were there any contaminants detected in my drinking water? Tucson Water regularly monitors the drinking water that is delivered to you to comply with drinking water regulations set by the USEPA. In addition to this required monitoring, Tucson Water performs a great deal of discretionary monitoring in order to provide both Tucson Water staff and customers with additional water quality information. We are pleased to report that the results from the monitoring conducted in 2009 met all standards for safe drinking water. In most cases, the minimum detection level of a contaminant is well below the USEPA regulatory limit for that contaminant. The table on page 2 lists the contaminants that were detected in the required drinking water monitoring. To compare the detected amount with the maximum amount allowed by the USEPA, refer to the Maximum Contaminant Level (MCL) column in the table. The vast majority of regulated contaminants were not detected in the drinking water delivered by Tucson Water and those non-detected results were not included in the table. For a complete list of all USEPA regulated contaminants, contact the USEPA at 1-800-426-4791 or visit the USEPA Webster at www.epa.gov/safewater/mcl.html#mcls In order to ensure that tap water is safe to drink, USEPA regulations limit the amount of certain contaminants in water provided by public water systems. Food and Drug Administration regulations establish limits for contaminants in bottled water that must provide the same protection for public health. Bottled water may come from either a surface water source or groundwater source, and may be treated minimally or extensively. For information on the quality of your bottled water, contact the water bottling company. 2 Detected Contaminants Table Contaminant sample year Maximum Result 09 09 09 09 1.4 ppb 2.1 ppb 3.5 ppb < 2 ppb <1 - 1.4 ppb <1 – 2.1 ppb <2 – 3.5 ppb Trihalomethanes (THM) Bromodichloromethane 09 Bromoform 09 Chloroform 09 Chlorodibromomethane 09 Total Trihalomethanes 09 Running Annual Average for TTHMS 09 2.3 ppb 5.8 ppb 1.5 ppb 5.6 ppb 14.5 ppb 6.6 ppb <0.5 – 2.3 ppb <0.5 – 5.8 ppb <0.5 – 1.5 ppb <0.5 – 5.6 ppb <0.5 – 14.5 ppb Disinfection By-Products Haloacetic acids (HAA) Dichloroacetic Acid Dibromoacetic Acid Total Haloacetic Acids (5) Running Annual Average for HAA5 Range MCL MCLG None None None 60 ppb None None None None None 80 ppb Inorganics Arsenic 07-09 9.1 ppb <2.0 – 9.1 ppb 10 ppb 0 ppb Barium 07-09 0.15 ppm <0.02 – 0.15 ppm 2 ppm 2 ppm Fluoride 09 1.0 ppm <0.1 – 1.0 ppm 4 ppm 4 ppm Nitrate (as N) 09 7.7 ppm <0.25 – 7.7ppm 10 ppm 10 ppm Sodium 07-09 101 ppm 16 – 101 ppm None None Major Sources of Contaminant By-product of chlorination By-product of chlorination By-product of chlorination By-product of chlorination By-product of chlorination By-product of chlorination By-product of chlorination By-product of chlorination Natural deposits Natural deposits; Industrial Uses Natural deposits Natural deposits; septic tanks; agriculture; sewage Natural deposits Volatile Organics Total Xylenes 09 0.0015 ppm 0.0015-0.0015 ppm 10 ppm 10 ppm Synthetic Organics Atrazine 07-09 1.3 ppb <0.05-1.3 ppb 3 ppb 3 ppb Di (2-ethylhexyl) phthalate 07-09 0.7 ppb <0.6-0.7 ppb 6 ppb 0 ppb Simazine 07-09 0.05 ppb <0.05-0.05 ppb 4 ppb 4 ppb Runoff from herbicides used on raw crops Discharge from rubber and chemical factories Herbicide runoff Radioactive Chemicals Alpha Emitters Uranium Natural Deposits Natural Deposits Contaminant Lead Copper Contaminant Chlorine 09 09 2.2 pCi/L 4.7 ppb year No. of Samples Above sampled the Action Level 08 one 08 none year sampled 09 Annual Average 0.86 ppm <1.0 – 2.2 pCi/L 15 pCi/L <1.4 – 4.7 ppb 30 ppb 90th Percentile Action Value Level 2.0 ppb 15 ppb 0.12 ppm 1.3 ppm Monthly Average Range 0.79 – 0.93 ppm Drinking Water Terms and Definitions: 0 pCi/L 0 ppb Solvent used in paint coatings, adhesive, fuel MCLG Major Sources 0 1.3 ppm Corrosion of household plumbing systems Corrosion of household plumbing systems MRDL MCLG Source 4 ppm 4 ppm Disinfection additive used to control microbes Action level. The concentration of a contaminant which, if exceeded, triggers a treatment or other requirement which a water system must follow. Entry Point to the Distribution System (EPDS). All water sources are monitored at the entry point to the distribution system before the first customer but after any required treatment. Maximum Contaminant Level (MCL). The highest level of a contaminant that is allowed in drinking water. MCLs are set as close to the MCLGs as feasible using the best available treatment technology. If a contaminant is believed to cause health concerns in humans, then the MCL is set as close as practical to zero and at an acceptable level of risk. Generally, the maximum acceptable risk of cancer is 1 in 10,000 with 70 years of exposure. Maximum Contaminant Level Goal (MCLG). The level of a contaminant in drinking water below which there is no known or expected risk to health. MCLGs allow for a margin of safety. Maximum Residual Disinfectant Level (MRDL). The highest level of a disinfectant allowed in drinking water. There is convincing evidence that addition of a disinfectant is necessary for control of microbial contaminants. Maximum Residual Disinfectant Level Goal (MRDLG). The level of a drinking water disinfectant below which there is no known or expected risk to health. MRDLGs do not reflect the benefits of the use of disinfectants to control microbial contaminants. Parts Per Billion (ppb). Some constituents in water are measured in very small units. One ppb equals one microgram per liter. For example, one part per billion equals: 2 drops of water in a 15,000 gallon backyard swimming pool, one second of time in 31.7 years, or the first 16 inches of a trip to the moon. Parts Per Million (ppm). One ppm equals one milligram per liter or 1000 times more than a ppb. One part per million equals: 1/4 cup of water in a typical 15,000 gallon backyard swimming pool or one second of time in 11.6 days. Picocurie Per Liter (pCi/l). The quantity of radioactive material in one liter which produces 2.22 nuclear disintegrations per minute. 3 Explanation of the Data Presented in the Detected Contaminants Table: Tucson Water routinely monitors for contaminants in your drinking water as specified in the national Primary Drinking Water Standards and States laws. Monitoring results for the period of January 1 to December 31, 2009, or from the most recent period, are included in the table. Certain contaminants are monitored less than once a year because the concentrations of these contaminants are not expected to vary significantly from year to year, or the system is not considered vulnerable to this type of contamination. If the risk is high, a waiver is denied. If the risk is low, a waiver will be granted and the effect is a reduction in monitoring frequency. This reduction in monitoring saves Public Water Systems money without affecting public safety. Therefore, some of the data, though representative, may be more than one year old. Detailed Information on Detected Contaminants Haloacetic Acids (HAA5) are a group of chemicals that are formed along with other disinfection byproducts when chlorine or other disinfectants used to control microbial contaminants in drinking water react with naturally occurring organic and inorganic matter in water. The regulated haloacetic acid compounds, known as HAA5, are monochloroacetic acid, dichloroacetic acid, trichloroacetic acid, monobromoacetic acid, and dibromoacetic acid. USEPA has established an MCL of 60 parts per billion for HAA5. The annual HAA5 average for 2009, calculated from 19 locations, was not detected at 2 ppb. Total Trihalomethanes (TTHMs) are formed when chlorine combines with naturally occurring organic material in water. Since the level of organic matter in our groundwater is extremely low, these compounds are found at very low concentrations. The compounds which make up the TTHMs include bromodichloromethane, bromoform, chlorodibromomethane, and chloroform. The highest result for TTHM during 2009 was 14.5 ppb and the highest concentration for any of the four compounds was 5.8 ppb for bromoform. Compliance with the TTHM standard is based on the running annual average concentration from 19 distribution monitoring points. The running annual average for TTHMs in 2009 was 6.6 ppb (the MCL is 80 ppb). Arsenic is a naturally occurring substance commonly found in groundwater in the southwestern United States. While your drinking water meets USEPA’s standard for arsenic, it does contain low levels of arsenic. USEPA’s standard balances the current understanding of arsenic’s possible health effects against the cost of removing arsenic from drinking water. USEPA continues to research the health effect of low levels of arsenic which is a mineral known to cause cancer in humans at high concentrations and is linked to other health effects such as skin damage and circulatory problems. The highest arsenic concentration detected during 2007 - 2009 was 9.1 ppb (the MCL is 10 ppb). Barium occurs naturally at very low concentrations in our groundwater. The highest barium value from 2007 was 0.15 ppm (the MCL is 2 ppm). 4 Fluoride is an important naturally occurring mineral that helps to form healthy teeth and bones. A concentration of 1 ppm is considered optimum. At concentrations above 2 ppm, fluoride can cause mild discoloration of teeth, and exposure at above the MCL of 4 ppm can cause both severe discoloration of teeth and over many years of exposure, bone disease. The highest level of fluoride detected during 2009 was 1.0 ppm (the MCL is 4 ppm). Nitrate is a form of nitrogen and an important plant nutrient. Tucson Water performs more frequent monitoring of wells high in nitrate for extra assurance that action can be taken when approaching the MCL. Nitrate in drinking water at levels above 10 ppm is a health risk for infants of less than six months of age. High nitrate levels in drinking water can cause blue baby syndrome. Nitrate levels may rise quickly for short periods of time because of rainfall or agricultural activity. If you are caring for an infant you should ask advice from your heath care provider. The highest level for nitrate during 2009 was 7.7 ppm (the MCL is 10 ppm). Sodium is the sixth most abundant element on Earth and is widely distributed in soils, plants, water, and food. A goal of 2300 mg/day dietary sodium has been proposed by several government and health agencies. Drinking water containing between 30 and 60 ppm would contribute only 2.5 % to 5% of the dietary goal if tap water consumption is 2 L/day. Currently, there is no MCL for sodium in drinking water. The recommended EPA guidance level for individuals on a very low sodium diet (500 mg/day) is 20 ppm in drinking water. The highest sodium value in Tucson water during 2007 - 2009 was 101 ppm. Drinking water does not play a significant role in sodium exposure for most individuals. Those who are under treatment for sodium-sensitive hypertension should consult with their health care provider regarding sodium levels in their drinking water supply and the advisability of using an alternative water source or point-of-use treatment to reduce the sodium. Total Xylenes are residual volatile organic solvents, typically associated with the coatings used to protect new or refurbished water pressure tanks. These low concentration releases from pressure tank coatings rapidly decrease as the tank ages. The highest concentration of total xylenes detected in 2009 was 0.0015 ppm (the MCL is 10 ppm). Detailed Information on Detected Contaminants (continued) Synthetic Organics are generally not mobile. Atrazine, a herbicide and possible carcinogen at high doses, was detected at concentration of 1.3 ppb in 2007 (the MCL is 3 ppb). Simazine, also a herbicide, was detected at concentration of 0.05 ppb in 2007 (the MCL is 4 ppb). Another SOC, di(2-ethylhexyl) phthalate or DEHP, is the most commonly used group of related chemicals called phthalates or phthalic acid esters. The greatest use of DEHP is as a plasticizer for polyvinylchloride (PVC) and other polymers including rubber, cellulose and styrene. Because of its very broad use in plastic and rubber products, DEHP is frequently a laboratory contaminant. It was detected at concentration of 0.7 ppb during 2007 (the MCL is 6 ppb). Alpha Emitters are measure of radioactivity due to naturally occurring minerals in groundwater. This excludes the radioactivity contributed by either radon or uranium. In 2009, six representative EPDS were sampled for alpha emitters. The highest level for alpha emitters during 2009 was 2.2 picocuries per liter or pCi/L (the MCL is 15 pCi/L). Uranium is a metallic element, which is highly toxic and radioactive. The highest level for uranium during 2009 was 4.7 ppb (the MCL is 30 ppb). Lead and Copper are naturally occurring metals, which are generally found at very low levels in source waters. If present, elevated levels of lead can cause serious health problems, especially for pregnant women and young children. Lead in drinking water is primarily from materials and components associated with service lines and home plumbing. Tucson Water is responsible for providing high quality drinking water, but can not control the variety of materials used in plumbing components. When your water has been sitting for several hours, you can minimize the potential for lead exposure by flushing your tap for 30 seconds to 2 minutes before using water for drinking or cooking. If you are concerned about lead in your water, you may wish to have your water tested. Information on lead in drinking water, testing methods, and steps you can take to minimize exposure is available from the Safe Drinking Water Hotline at http://www.epa.gov/safewater/lead. The required lead and copper monitoring was performed during 2008. The 90th percentile value was 2 ppb for lead (Action Level is 15 ppb) and 0.12 ppm for copper (Action Level is 1.3 ppm). One sample was above the action level for lead. A second confirmation sample was collected from this residence using the proper procedure. No lead was detected in the second sample. There were no samples above the action level for copper. Chlorine Residual Disinfection is maintained throughout the distribution system. Approximately 1 ppm of chlorine is added to the drinking water supply at well sites, reservoirs and other facilities to provide assurance that water delivered to customers will remain free of microbiological contamination. This also ensures that the water meets microbiological drinking water standards from the time it is pumped from the ground until it reaches the customer’s tap. Chlorine Residual Disinfectant is measured from 247 sample stations where the bacteriological samples are collected monthly. The annual chlorine residual disinfectant is calculated using the monthly chlorine averages for the past 12 months. The annual average for twelve months of 2009 was 0.86 ppm. The maximum was 0.93 ppm (The Maximum Residual Disinfectant Limit or MRDL is 4 ppm). Unregulated Contaminant Monitoring Regulation (UCMR) Data Availability Unregulated contaminants are those for which USEPA has not established drinking water standards. The purpose of monitoring for these contaminants is to help EPA decide whether the contaminants should have a standard or whether a future regulation is warranted. UCMR sampling was conducted by Tucson Water during the second quarter of 2009, results of which were non-detects. As a Tucson Water customer, you have the right to know that this data is available. If you are interested in examining the results, please contact the Water Quality Manaagement & Operations Division by calling 791-2544. 1,4-Dioxane was first detected in 2002. The laboratory’s minimum reporting limit for this chemical is 1 ppb, with the highest concentration in 2009 at 1.3 ppb. 1,4 dioxane is used primarily as a stabilizer in chlorinated solvents, particularly 1,1,1-trichloroethane (TCA). At this time, USEPA has not established a drinking water standard for this compound. Therefore, it is not listed on the Detected Contaminant Table in page 2. However, the EPA Office of Drinking Water has a Health Advisory Level of 3 ppb to assist federal, state and local officials and managers of public or community water systems in protecting public health. Health advisories serve as informal technical guidance and are not legally enforceable Federal standards and are subject to change as new information becomes available. The maximum value measured is well below EPA’s health advisory. 5 Were there any monitoring failures or violations? Do I need to take special precautions? At the end of each quarter, Tucson Water conducts an internal audit of compliance monitoring records to verify that all required monitoring has been completed and reported to the State. There were no monitoring failures or violations during 2009. While the Safe Drinking Water Act regulations are intended to protect consumers throughout their lifetime, some people may be more vulnerable to infections from drinking water than the general population. These “at-risk” populations include: immunocompromised persons such as persons with cancer undergoing chemotherapy, people who have undergone organ transplants, people with HIV/AIDS or other immune system disorders, and in some cases, elderly people and infants. These people should seek advice about drinking water from their health care providers. USEPA/CDC guidelines on appropriate means to lessen the risk of infection by cryptosporidium and other microbial contaminants are available from the USEPA’s What about CAP water? The City of Tucson has rights to approximately 144,000 acre-feet of Colorado River water per year, delivered through the Central Arizona Project (CAP). In 2009, the City of Tucson’s Colorado River allocation was not used directly, but a portion of this allocation was recharged into the aquifer. At the end of 2009, Tucson Water was using approximately 71% of its available allocation. At the Clearwater Renewable Resource Facility located in Avra Valley, Tucson Water is recharging a portion of the City’s available CAP supply by delivering the river water to shallow basins and allowing the water to percolate (or recharge) naturally through the earth to reach and blend with the groundwater below. Tucson Water began delivery of this blend of recharged Colorado River water and groundwater in 2001. At the end of 2009, the blend was about 40% native groundwater and 60% recharged Colorado River water. Over time, it will contain an increasing percentage of recharged Colorado River water. Information on the quality of this blend is contained in the detected contaminant table, and more information is available on Tucson Water’s web site. Source Water Assessment Program (SWAP) The Arizona Department of Environmental Quality (ADEQ) has completed a source water assessment for Tucson Water drinking water wells. This assessment reviewed the adjacent land uses that may pose a potential risk to the water sources. These risks include, but are not limited to gas stations, landfills, dry cleaning, agricultural fields, wastewater treatment plants, and mining activities. The assessment has classified approximately 1/3 of our wells as high risks. How is our drinking water treated? The groundwater delivered by Tucson Water meets all drinking water standards without treatment, with the exception of the water supplied from the Tucson Airport Area Remediation Project or TARP (See below). However, approximately 1 ppm of chlorine is added to the drinking water supply at well sites, reservoirs and other facilities to provide assurance that water delivered to customers will remain free of microbiological contamination. This also ensures that the water meets microbiological drinking water standards from the time it is pumped from the ground until it reaches the customer’s tap. Tucson Water ensures the safety of its drinking water by conducting regular monitoring of all sources. If any contamination approaches the drinking water MCL, the source is removed from service. Residents can help protect our water sources by practicing good septic system maintenance, limiting pesticide and fertilizer use, and by taking hazardous household chemicals to the Household Hazardous Waste Program (visit http://www.deq.pima.gov/ waste/householdhaz.html or call 791-4502). Source Water Assessments on file with the ADEQ are available for public review. You may obtain a copy by contacting the Arizona Source Water Coordinator at (602) 771-4661. Additionally, to elevate the pH in the Clearwater blend, approximately 1.8 ppm of sodium hydroxide, also known as “caustic soda”, is added to the blend prior to delivery to customers to achieve a target pH of 8.1. This ensures that the delivered water is not corrosive. Corrosive water can damage metallic plumbing and leach metals such as copper and lead from certain plumbing fixtures (see Lead and Copper information). Monitoring Waivers The Arizona Department of Environmental Quality, the regulatory agency for all public water suppliers in Arizona, grants waivers for certain monitoring requirements. Waivers are granted for specific contaminants if previous monitoring results, and/or the land uses within a half-mile radius of the well, allow ADEQ to conclude that the risk of contamination by a specific substance is very low. 6 Tucson Water PRSRT STD US POSTAGE P.O.Box 27210 Tucson, AZ 85726-7210 PAID TUCSON, AZ PERMIT NO. 426 More about TARP Whom do I contact for more information? The Tucson Airport Area Remediation Project (TARP) was developed in order to clean and make beneficial use of water contaminated with the industrial solvent trichloroethylene (TCE). Tucson Water operates TARP under an agreement with the USEPA and other industrial and governmental agencies. All costs associated with operating and maintaining the TARP facility are fully reimbursed to Tucson Water. For more information on this Tucson Water report, contact Mohsen Belyani with the Water Quality Management and Operations Division. Call 791-2544 or e-mail your questions to: mohsen.belyani@tucsonaz.gov. Tucson’s Mayor and Council set policy and direction for Tucson Water, including those policies that may impact water quality. Mayor and Council meetings are normally held each Tuesday and are open to the public. Mayor and Council meeting agendas and other opportunities for public comment are published at www.tucsonaz.gov/mcc. Customers of Tucson Water may leave a recorded message on the Mayor and Council Comment Line at (520) 791-4700. Tucson Water in collaboration with ten community partners and the USEPA has established the Environmental Monitoring for Public Access and Community Tracking Program (EMPACT) which is designed to provide the community with more information about your drinking water. For more information please call 791-2666 or visit our web site at www.tucsonaz.gov/water/ Nine wells extract the contaminated water and deliver it through a pipeline to a treatment plant that removes the TCE from the water. The TARP treatment plant uses an “air stripping” process which forces volatile contaminants such as TCE to evaporate from the water into air. The air is then passed through activated carbon filters, which removes the airborne TCE. The TARP plant is designed to treat approximately 8.4 million gallons of water per day (or 5,800 gallon per minute). During 2009, this plant treated a total of approximately 2.325 billion gallons of water. The treatment system removed 303 pounds of combined VOCs from the groundwater. Telephone Numbers: Tucson Water Public Information Office 791-4331 Tucson Water Quality Management & Operations Division 791-2544 Tucson Water Customer Service/Billing 791-3242 Tucson Water 24 hour Emergency 791-4133 United States Environmental Protection Agency Safe Drinking Water Hotline: 1-800-426-4791 USEPA Website: www.epa.gov/safewater/ Para nuestros clients de habla español: Éste informe contiene información muy importante sobre la calidad de su agua beber. Traduscalo o hable con alguien que lo entienda bien. Para obtener una copia de este reporte en Español, llame al (520) 791-4331. 7 Si usted desea este documento escrito en español, por favor, llame al 791-4331 City of Tucson TDD#: 791-2639