2002 Periodic Emissions Inventory for PM10 for the Maricopa County, Arizona, Nonattainment Area June 2004 Revised March 2006 This emissions inventory has been prepared by: Bob Downing Dena Konopka Matt Poppen Eric Raisanen Maricopa County Environmental Services Department 1001 N. Central Ave. Suite 250 Phoenix, AZ 85004 Ruey-in Chiou Steve Ochs Roger Roy Maricopa Association of Governments 302 N. 1st Ave. Suite 300 Phoenix, AZ 85003 with additional contributions and/or review by: Randy Sedlacek Peter Hyde Arizona Department of Environmental Quality 1101 W. Washington St. Phoenix, AZ 85007 Bob Farrell Pima County Air Quality Control District P.O. Box 987 Florence, AZ 85232 Alison K. Pollock Cuong Tran Christian Lindjhem Gerry Mansell Till Stoeckenius ENVIRON International Corp. 101 Rowland Way Novato, CA 94945 Table of Contents 1. Introduction .............................................................................................................................. 1 1.1 1.2 1.3 1.4 1.5 Overview............................................................................................................................ 1 Agencies responsible for the emissions inventory............................................................. 1 Temporal scope.................................................................................................................. 2 Geographic scope............................................................................................................... 2 Overview of local demographic and land-use data............................................................ 3 1.5.1 Demographic profile ............................................................................................... 3 1.5.2 Land-use data .......................................................................................................... 3 1.6 Emissions overview by source category............................................................................ 4 1.6.1 Point sources ........................................................................................................... 4 1.6.2 Area sources............................................................................................................ 5 1.6.3 Nonroad mobile sources ......................................................................................... 5 1.6.4 Onroad mobile sources ........................................................................................... 6 1.6.5 Biogenic sources ..................................................................................................... 7 1.6.6 Summary of emissions by source category............................................................. 7 1.7 References........................................................................................................................ 14 2. Point Sources .......................................................................................................................... 15 2.1 Introduction and scope..................................................................................................... 15 2.2 Identification of point sources ......................................................................................... 16 2.3 Procedures for estimating emissions from point sources ................................................ 20 2.3.1 Sources with air quality permits issued by Maricopa County Environmental Services Department (MCESD)............................................................................ 20 2.3.1.1 Calculation of PM2.5 emissions................................................................ 21 2.3.1.2 Application of rule effectiveness ............................................................. 21 2.3.1.3 Example 1: United Metro Materials Plant #11 ........................................ 22 2.3.1.4 Example 2: 23rd Ave. Wastewater Treatment Plant ............................... 22 2.3.2 Sources with air quality permits issued by Pinal County Air Quality Control District................................................................................................................... 23 2.4 Detailed overview of point source emissions .................................................................. 23 2.4.1 Point source emissions by geographic location .................................................... 23 2.4.2 Point source emissions by process type ................................................................ 27 2.5 Emission reduction credits............................................................................................... 35 2.6 Summary of point source emissions ................................................................................ 35 2.7 Quality assurance / quality control procedures................................................................ 36 2.7.1 Emission survey preparation and data collection.................................................. 36 2.7.2 Submission processing.......................................................................................... 37 2.7.3 Analysis of annual point source emissions data for this inventory....................... 37 2.8 References........................................................................................................................ 38 3. Area Sources ........................................................................................................................... 39 3.1 Scope and methodology................................................................................................... 39 3.2 Fuel combustion............................................................................................................... 40 3.2.1 Industrial natural gas............................................................................................. 41 2002 PM10 Periodic Emission Inventory (Rev. 3/06) i Maricopa County, AZ 3.2.2 Industrial fuel oil................................................................................................... 42 3.2.3 Commercial/institutional natural gas .................................................................... 44 3.2.4 Commercial/institutional fuel oil .......................................................................... 45 3.2.5 Residential natural gas .......................................................................................... 47 3.2.6 Residential wood combustion ............................................................................... 47 3.2.7 Residential fuel oil ................................................................................................ 49 3.2.8 Summary of all area-source fuel combustion ....................................................... 49 3.3 Industrial processes.......................................................................................................... 50 3.3.1 Chemical manufacturing....................................................................................... 50 3.3.2 Food and kindred products.................................................................................... 52 3.3.2.1 Commercial cooking................................................................................ 52 3.3.2.2 Grain handling/processing ....................................................................... 53 3.3.2.3 Ammonia cold storage............................................................................. 54 3.3.3 Secondary metal production ................................................................................. 54 3.3.4 Non-metallic mineral processes............................................................................ 55 3.3.5 Mining and quarrying ........................................................................................... 56 3.3.6 Wood product manufacturing ............................................................................... 57 3.3.7 Rubber/plastics manufacturing ............................................................................. 58 3.3.8 Fabricated metal products manufacturing............................................................. 60 3.3.9 Construction.......................................................................................................... 61 3.3.10 Electrical equipment manufacturing ..................................................................... 63 3.3.11 State-permitted portable sources........................................................................... 65 3.3.12 Paved/unpaved road travel on industrial sites....................................................... 66 3.3.13 Industrial processes not elsewhere classified (NEC) ............................................ 67 3.3.14 Summary of all area-source industrial processes.................................................. 68 3.4 Waste treatment and disposal .......................................................................................... 69 3.4.1 On-site incineration............................................................................................... 69 3.4.2 Open burning ........................................................................................................ 70 3.4.3 Landfills ................................................................................................................ 72 3.4.4 Publicly owned treatment works (POTWs) .......................................................... 73 3.4.5 Other industrial waste disposal ............................................................................. 73 3.4.6 Summary of all area-source waste disposal .......................................................... 74 3.5 Miscellaneous area sources.............................................................................................. 74 3.5.1 Other combustion.................................................................................................. 74 3.5.1.1 Wildfires and brush fires ......................................................................... 74 3.5.1.2 Structure fires........................................................................................... 76 3.5.1.3 Vehicle fires............................................................................................. 77 3.5.1.4 Engine testing .......................................................................................... 78 3.5.2 Agricultural crops ................................................................................................. 78 3.5.2.1 Tilling ...................................................................................................... 78 3.5.2.2 Harvesting................................................................................................ 83 3.5.2.3 Cotton ginning ......................................................................................... 85 3.5.2.4 Fertilizer application................................................................................ 85 3.5.3 Livestock............................................................................................................... 86 3.5.4 Health services: crematories ................................................................................. 87 3.5.5 Accidental releases................................................................................................ 88 3.5.6 Humans ................................................................................................................. 89 2002 PM10 Periodic Emission Inventory (Rev. 3/06) ii Maricopa County, AZ 3.5.7 Windblown dust .................................................................................................... 89 3.5.8 Summary of all miscellaneous area sources ......................................................... 90 3.6 Summary of all area sources............................................................................................ 91 3.7 Quality assurance / quality control procedures................................................................ 94 3.8 References........................................................................................................................ 95 4. Nonroad Mobile Sources........................................................................................................ 99 4.1 4.2 4.3 4.4 4.5 4.6 4.7 4.8 4.9 4.10 4.11 4.12 4.13 4.14 4.15 4.16 Introduction...................................................................................................................... 99 Agricultural equipment.................................................................................................. 101 Airport ground support equipment ................................................................................ 102 Commercial equipment.................................................................................................. 103 Construction and mining equipment.............................................................................. 104 Industrial equipment ...................................................................................................... 104 Lawn and garden equipment.......................................................................................... 105 Logging equipment........................................................................................................ 106 Pleasure craft ................................................................................................................. 106 Railway maintenance equipment ................................................................................... 107 Recreational equipment ................................................................................................. 108 Aircraft........................................................................................................................... 108 Locomotives .................................................................................................................. 112 Summary of all nonroad mobile source emissions ........................................................ 113 Quality assurance procedures ........................................................................................ 114 References...................................................................................................................... 114 5. Onroad Mobile Sources ....................................................................................................... 115 5.1 5.2 5.3 5.4 5.5 Introduction.................................................................................................................... 115 VMT estimation procedure............................................................................................ 116 Speed estimation procedure........................................................................................... 119 Monthly VMT factors.................................................................................................... 120 Emission factor estimation procedure ........................................................................... 121 5.5.1 Emission factor model ........................................................................................ 121 5.5.2 Development of MOBILE6.2 model inputs........................................................ 123 5.5.3 Model outputs ..................................................................................................... 128 5.5.4 Summary of emission factors.............................................................................. 128 5.5.5 Emission estimates.............................................................................................. 128 5.6 Summary of particulate emissions from onroad mobile sources................................... 169 5.7 Quality assurance process.............................................................................................. 179 5.7.1 VMT estimates.................................................................................................... 179 5.7.2 Emission factor estimates ................................................................................... 179 5.7.3 Quality review of 2002 draft particulate matter emissions inventory................. 180 5.8 References...................................................................................................................... 180 6. Biogenic Sources ................................................................................................................... 181 6.1 Introduction and scope................................................................................................... 181 6.2 Modeling domain adjustments....................................................................................... 181 6.3 Land-use categories ....................................................................................................... 182 2002 PM10 Periodic Emission Inventory (Rev. 3/06) iii Maricopa County, AZ 6.4 6.5 6.6 6.7 Derivation of emission factors....................................................................................... 183 Meteorological inputs .................................................................................................... 185 Summary of emissions from biogenic sources .............................................................. 186 References...................................................................................................................... 186 List of Tables Table 1.2–1. Table 1.5–1. Table 1.5–2. Table 1.6–1. Chapter authors and QA/QC contacts. ......................................................................1 Demographic profile of Maricopa County and the PM10 nonattainment area. .........3 Land-use categories used to apportion emissions. ....................................................4 Summary of annual and typical daily emissions from point sources in Maricopa County.......................................................................................................4 Table 1.6–2. Summary of annual and typical daily emissions from point sources in the PM10 NAA. .........................................................................................................................5 Table 1.6–3. Summary of annual and typical daily emissions from area sources in Maricopa County. ......................................................................................................................5 Table 1.6–4. Summary of annual and typical daily emissions from area sources in the PM10 NAA. .........................................................................................................................5 Table 1.6–5. Annual and typical daily emissions from nonroad mobile sources in Maricopa County. ......................................................................................................................6 Table 1.6–6. Annual and typical daily emissions from all nonroad mobile sources in the PM10 NAA.................................................................................................................6 Table 1.6–7. Annual and typical daily emissions from all onroad mobile sources in Maricopa County.......................................................................................................6 Table 1.6–8. Annual and typical daily emissions from all onroad mobile sources in the PM10 NAA. .........................................................................................................................7 Table 1.6–9. Annual and season-day NOx emissions from biogenic sources. ...............................7 Table 1.6–10. Summary of annual emissions by source category, 1994–2002 (tons/yr). .............14 Table 2.2–1. Number of stationary point sources by location and permitting authority..............16 Table 2.2–2. Name and location of all point sources. ..................................................................17 Table 2.4–1. Annual and typical daily point source emissions, by facility..................................23 Table 2.4–2. Annual and typical daily point source emissions, by process type. ........................27 Table 2.5–1. Emission reduction credits. .....................................................................................35 Table 2.6–1. Summary of annual and typical daily point source emissions, by source category. ..................................................................................................................35 Table 3.1–1. List of area-source categories..................................................................................39 Table 3.2–1. Maricopa County natural gas sales data by supply company and end-user category. ..................................................................................................................40 Table 3.2–2. Emission factors and annual emissions from area-source industrial natural gas combustion, by combustion type. ...........................................................................41 Table 3.2–3. Annual and typical daily emissions from area-source industrial natural gas combustion. .............................................................................................................42 Table 3.2–4. Emission factors and annual emissions from area-source industrial fuel oil combustion, by combustion type. ...........................................................................43 Table 3.2–5. Annual and typical daily emissions from area-source industrial fuel oil combustion. .............................................................................................................43 2002 PM10 Periodic Emission Inventory (Rev. 3/06) iv Maricopa County, AZ Table 3.2–6. Emission factors and annual emissions from area-source commercial/institutional natural gas combustion, by combustion type. .................44 Table 3.2–7. Annual and typical daily emissions from area-source commercial/institutional natural gas combustion............................................................................................45 Table 3.2–8. Emission factors and annual emissions from area-source commercial/institutional fuel oil combustion, by combustion type. .......................46 Table 3.2–9. Annual and typical daily emissions from area-source commercial/institutional fuel oil combustion..................................................................................................46 Table 3.2–10. Residential natural gas combustion emission factors (in lb/MMCF). ....................47 Table 3.2–11. Annual and typical daily emissions from residential natural gas combustion. .......47 Table 3.2–12. Annual wood usage, emission factors, and annual emissions from residential wood combustion. ...................................................................................................48 Table 3.2–13. Annual and typical daily emissions from residential wood combustion. ...............49 Table 3.2–14. Annual and typical daily emissions from residential fuel oil combustion. .............49 Table 3.2–15. Annual and typical daily emissions from all area-source fuel combustion for Maricopa County.....................................................................................................50 Table 3.2–16. Annual and typical daily emissions from all area-source fuel combustion for the PM10 NAA.........................................................................................................50 Table 3.3–1. NAICS codes and descriptions for chemical manufacturing. .................................50 Table 3.3–2. Annual and typical daily emissions from area-source chemical manufacturing.....52 Table 3.3–3. Maricopa County restaurants by type. ....................................................................52 Table 3.3–4. Annual emissions from commercial cooking equipment, by equipment type. .......52 Table 3.3–5. Typical daily emissions from commercial cooking equipment, by equipment type..........................................................................................................................53 Table 3.3–6. Annual and typical daily emissions from commercial cooking equipment. ...........53 Table 3.3–7. Annual and typical daily emissions from area-source grain handling and processing................................................................................................................53 Table 3.3–8. Annual and typical daily NH3 emissions from ammonia cold storage. ..................54 Table 3.3–9. Annual and typical daily emissions from secondary metal production. .................55 Table 3.3–10. Annual and typical daily emissions from area-source non-metallic mineral products. ..................................................................................................................56 Table 3.3–11. Annual and typical daily emissions from area-source mining and quarrying operations. ...............................................................................................................56 Table 3.3–12. NAICS codes and descriptions for wood product manufacturing. .........................57 Table 3.3–13. Annual and typical daily emissions from area-source wood products manufacturing. ........................................................................................................58 Table 3.3–14. NAICS codes and descriptions for rubber and plastic manufacturing facilities. ....59 Table 3.3–15. Annual and typical daily emissions from area-source rubber/plastic products manufacturing. ........................................................................................................60 Table 3.3–16. Annual and typical daily emissions from area-source fabricated metal product manufacturing. ........................................................................................................61 Table 3.3–17. 2002 Maricopa County earthmoving permits issued, by type. ...............................61 Table 3.3–18. Average project duration and emission factor, by permit type. ..............................62 Table 3.3–19. Annual emissions from construction (tons/yr)........................................................63 Table 3.3–20. Annual and typical daily emissions from construction. ..........................................63 Table 3.3–21. NAICS codes and descriptions for electric equipment manufacturing...................64 Table 3.3–22. Annual and typical daily emissions from area-source electric equipment manufacturing. ........................................................................................................65 2002 PM10 Periodic Emission Inventory (Rev. 3/06) v Maricopa County, AZ Table 3.3–23. Emissions from ADEQ-permitted portable sources, by permit type. .....................66 Table 3.3–24. Annual and typical daily emissions from paved and unpaved road travel at industrial facilities...................................................................................................67 Table 3.3–25. Annual and typical daily emissions from other industrial processes not elsewhere classified.................................................................................................68 Table 3.3–26. Annual and typical daily emissions from all area-source industrial processes in Maricopa County.....................................................................................................68 Table 3.3–27. Annual and typical daily emissions from all area-source industrial processes in the PM10 NAA.........................................................................................................69 Table 3.4–1. Annual and typical daily emissions from on-site incineration................................70 Table 3.4–2. 2002 Maricopa County burn permit activity data. ..................................................70 Table 3.4–3. Emission and fuel loading factors for open burning. ..............................................70 Table 3.4–4. Annual emissions from open burning in Maricopa County. ...................................71 Table 3.4–5. Surrogate land-use classes, ratios, and annual emissions from open burning in the PM10 NAA.........................................................................................................72 Table 3.4–6. Typical daily emissions from open burning............................................................72 Table 3.4–7. Annual and typical daily emissions from landfills..................................................73 Table 3.4–8. NH3 emissions from publicly-owned treatment works (POTWs)...........................73 Table 3.4–9. Annual and typical daily emissions from other industrial waste disposal. .............73 Table 3.4–10. Annual and typical daily emissions from all area-source waste disposal for Maricopa County.....................................................................................................74 Table 3.4–11. Annual and typical daily emissions from all area-source waste disposal for the PM10 NAA...............................................................................................................74 Table 3.5–1. Emission and fuel loading factors for wildfires and brush fires. ............................75 Table 3.5–2. Annual emissions from wildfires and brush fires (tons/yr).....................................75 Table 3.5–3. Typical daily emissions from wildfires and brush fires (lbs/day)...........................75 Table 3.5–4. Estimated material burned, emission and fuel loading factors for structure fires...76 Table 3.5–5. Annual and typical daily emissions from structure fires.........................................77 Table 3.5–6. Estimated material burned, fuel loading factors, and emission factors for vehicle fires. ............................................................................................................77 Table 3.5–7. Annual and typical daily emissions from vehicle fires. ..........................................78 Table 3.5–8. Annual and typical daily emissions from engine testing. .......................................78 Table 3.5–9. 2002 Maricopa County agricultural crop acreage, activity, and uncontrolled annual PM10 emissions............................................................................................79 Table 3.5–10. Annual controlled PM10 emissions from agricultural tillage in Maricopa County. ....................................................................................................................80 Table 3.5–11. Annual controlled PM10 and PM2.5 emissions from agricultural tillage. ................81 Table 3.5–12. Controlled typical daily emissions from tillage in Maricopa County. ....................82 Table 3.5–13. Controlled annual and typical daily emissions from tillage within the PM10 NAA. .......................................................................................................................82 Table 3.5–14. Maricopa County harvested acres and emission factors. ........................................83 Table 3.5–15. Annual emissions from harvesting (tons/yr). ..........................................................84 Table 3.5–16. Typical daily emissions from harvesting (lbs/day). ................................................84 Table 3.5–17. Annual and typical daily emissions from area-source cotton ginning. ...................85 Table 3.5–18. Annual and typical daily ammonia emissions from fertilizer application. .............86 Table 3.5–19. Maricopa County cattle inventory and emission factors.........................................87 Table 3.5–20. Annual and typical daily emissions from cattle feedlots and dairies. .....................87 Table 3.5–21. Annual and typical daily emissions from crematories. ...........................................88 2002 PM10 Periodic Emission Inventory (Rev. 3/06) vi Maricopa County, AZ Table 3.5–22. Annual and typical daily emissions from accidental releases.................................89 Table 3.5–23. Annual and typical daily NH3 emissions from human activity...............................89 Table 3.5–24. 1995 and 2001 emissions from windblown dust for the PM10 nonattainment area. .........................................................................................................................89 Table 3.5–25. Annual and daily emissions from windblown dust within the PM10 nonattainment area. .................................................................................................90 Table 3.5–26. Annual and daily emissions from windblown dust in Maricopa County................90 Table 3.5–27. Annual and typical daily emissions from all miscellaneous area sources for Maricopa County.....................................................................................................91 Table 3.5–28. Annual and typical daily emissions from all miscellaneous area sources for the PM10 NAA...............................................................................................................91 Table 3.6–1. Summary of annual and typical daily emissions from all area sources in Maricopa County.....................................................................................................92 Table 3.6–2. Summary of annual and typical daily emissions from all area sources in the PM10 NAA...............................................................................................................93 Table 4.1–1. Default weekday and weekend day activity allocation fractions. .........................101 Table 4.2–1. Annual emissions (in tons/yr) from agricultural equipment in Maricopa County. ..................................................................................................................101 Table 4.2–2. Annual emissions (in tons/yr) from agricultural equipment in the PM10 NAA. ...102 Table 4.2–3. Typical daily emissions (in lbs/day) from agricultural equipment in Maricopa County. ..................................................................................................................102 Table 4.2–4. Typical daily emissions (in lbs/day) from agricultural equipment in the PM10 nonattainment area. ...............................................................................................102 Table 4.3–1. Annual emissions (in tons/yr) from airport ground support equipment................103 Table 4.3–2. Typical daily emissions (in lbs/day) from airport ground support equipment......103 Table 4.4–1. Annual emissions (in tons/yr) from commercial equipment.................................103 Table 4.4–2. Typical daily emissions (in lbs/day) from commercial equipment.......................104 Table 4.5–1. Annual emissions (in tons/yr) from construction and mining equipment.............104 Table 4.5–2. Typical daily emissions (in lbs/day) from construction and mining equipment...104 Table 4.6–1. Annual emissions (in tons/yr) from industrial equipment.....................................105 Table 4.6–2. Typical daily emissions (in lbs/day) from industrial equipment...........................105 Table 4.7–1. Annual emissions (in tons/yr) from lawn and garden equipment. ........................105 Table 4.7–2. Typical daily emissions (in lbs/day) from lawn and garden equipment. ..............106 Table 4.8–1. Annual emissions (in tons/yr) from logging equipment. ......................................106 Table 4.8–2. Typical daily emissions (in lbs/day) from logging equipment..............................106 Table 4.9–1. Annual emissions (in tons/yr) from pleasure craft equipment. .............................107 Table 4.9–2. Typical daily emissions (in lbs/day) from pleasure craft equipment. ...................107 Table 4.10–1. Annual emissions (in tons/yr) from railway maintenance equipment. .................107 Table 4.10–2. Typical daily emissions (in lbs/day) from railway maintenance equipment.........108 Table 4.11–1. Annual emissions (in tons/yr) from recreational equipment.................................108 Table 4.11–2. Typical daily emissions (in lbs/day) from recreational equipment.......................108 Table 4.12–1. NEI default emission factors (lbs/LTO), and conversion factors, by aircraft type........................................................................................................................109 Table 4.12–2. 2002 airport activity data, emission calculation methods, and emission factors. .110 Table 4.12–3. Annual and typical daily emissions, by airport and aircraft type..........................111 Table 4.13–1. Emission factors for locomotives..........................................................................112 Table 4.13–2. Fuel use and annual emissions from locomotives in Maricopa County. ..............112 Table 4.13–3. Annual emissions (in tons/yr) from locomotives in the PM10 NAA.....................112 2002 PM10 Periodic Emission Inventory (Rev. 3/06) vii Maricopa County, AZ Table 4.13–4. Typical daily emissions (in lbs/day) from locomotives in Maricopa County.......113 Table 4.13–5. Typical daily emissions (in lbs/day) from locomotives in the PM10 nonattainment area. ...............................................................................................113 Table 4.14–1. Annual and typical daily emissions from nonroad mobile sources in Maricopa County. ..................................................................................................................113 Table 4.14–2. Annual and typical daily emissions from nonroad mobile sources in the PM10 NAA. .....................................................................................................................114 Table 5.2–1. 2002 HPMS VMT by area type and facility type for the PM10 nonattainment area (annual average daily traffic).........................................................................117 Table 5.2–2. 2002 HPMS VMT by area type and facility type for Maricopa County (annual average daily traffic). ............................................................................................117 Table 5.2–3. VMT by silt loading category (percent of VMT in each silt loading category). ..118 Table 5.3–1. Average daily speeds (mph) for the 2002 periodic emissions inventory. .............119 Table 5.4–1. Average daily VMT estimate factors by month....................................................120 Table 5.5–1. Paved road fugitive dust emissions. ......................................................................123 Table 5.5–2. Unpaved road fugitive dust emissions. .................................................................123 Table 5.5–3. Daily PM10 emissions in the PM10 nonattainment area by facility type, vehicle class and area type (excludes fugitive dust)..........................................................129 Table 5.5–4. Daily PM2.5 emissions in the PM10 nonattainment area by facility type, vehicle class and area type (excludes fugitive dust. ..........................................................133 Table 5.5–5. Daily NOx emissions in the PM10 nonattainment area by facility type, vehicle class and area type.................................................................................................137 Table 5.5–6. Sulfur dioxide (gaseous) emissions in the PM10 nonattainment area by facility type, vehicle class and area type. ..........................................................................141 Table 5.5–7. Daily ammonia emissions in the PM10 nonattainment area by facility type, vehicle class and area type. ...................................................................................145 Table 5.5–8. Daily PM10 Emissions in Maricopa County by facility type, vehicle class and area type (excludes fugitive dust). ........................................................................149 Table 5.5–9. Daily PM2.5 emissions in Maricopa County by facility type, vehicle class and area type (excludes fugitive dust). ........................................................................153 Table 5.5–10. Daily NOx emissions in Maricopa County by facility type, vehicle class and area type (annual average day)..............................................................................157 Table 5.5–11. Daily sulfur dioxide (gaseous) emissions in Maricopa County by facility type, vehicle class and area type. ...................................................................................161 Table 5.5–12. Daily ammonia emissions in Maricopa County by facility type, vehicle class and area type. ........................................................................................................165 Table 5.6–1. Annual and average daily emissions from all onroad mobile sources for Maricopa County...................................................................................................169 Table 5.6–2. Annual and average daily emissions from all onroad mobile sources for the PM10 nonattainment area.......................................................................................169 Table 5.6–3. Daily PM10 emissions (kg/day) in the PM10 NAA by facility type, area type and vehicle class (annual average, excluding fugitive dust particulate matter)....170 Table 5.6–4. Daily PM2.5 emissions (kg/day) in the PM10 NAA by facility type, area type and vehicle class (annual average, excluding fugitive dust particulate matter)....171 Table 5.6–5. Daily NOx emissions (kg/day) in the PM10 NAA by facility type, area type and vehicle class (annual average)...............................................................................172 Table 5.6–6. Daily SO2 emissions (kg/day) in the PM10 NAA by facility type, area type and vehicle class (annual average)...............................................................................173 2002 PM10 Periodic Emission Inventory (Rev. 3/06) viii Maricopa County, AZ Table 5.6–7. Daily ammonia emissions (kg/day) in the PM10 NAA by facility type, area type and vehicle class (annual average)........................................................................174 Table 5.6–8. Daily PM10 emissions (kg/day) in Maricopa County by facility type, area type and vehicle class (annual average, excluding fugitive dust particulate matter.)...175 Table 5.6–9. Daily PM2.5 emissions (kg/day) in Maricopa County by facility type, area type and vehicle class (annual average, excluding fugitive dust particulate matter)....176 Table 5.6–10. Daily NOx emissions(kg/day) in Maricopa County by facility type, area type and vehicle class (annual average)........................................................................177 Table 5.6–11. Daily SO2 emissions (kg/day) in Maricopa County by facility type, area type and vehicle class (annual average)........................................................................178 Table 5.6–12. Daily ammonia emissions (kg/day) in Maricopa County by facility type, area type and vehicle class (annual average). ...............................................................179 Table 6.3–1. MAG 2000 land-use categories.............................................................................183 Table 6.3–2. Land-use categories from BELD3 used in the emission inventory.......................183 Table 6.4–1. NOx standardized emission factors, by land-use category. ...................................184 Table 6.4–2. Maricopa County crop statistics for 2002. ............................................................184 Table 6.4–3. Distribution of harvested cropland and total cropland..........................................185 Table 6.5–1. Information for surface temperature monitoring sites. .........................................186 Table 6.6–1. Summary of biogenic source NOx emissions (annual and average day). .............186 2002 PM10 Periodic Emission Inventory (Rev. 3/06) ix Maricopa County, AZ List of Figures Figure 1.4–1. Map of Maricopa County and the CO, ozone, and PM10 nonattainment areas.........2 Figure 1.6–1. Annual PM10 emissions in the PM10 nonattainment area, by source category (tons/yr). ....................................................................................................................8 Figure 1.6–2. Annual PM2.5 emissions in the PM10 nonattainment area, by source category (tons/yr). ....................................................................................................................8 Figure 1.6–3. Annual NOx emissions in the PM10 nonattainment area, by source category (tons/yr). ....................................................................................................................9 Figure 1.6–4. Annual SOx emissions in the PM10 nonattainment area, by source category (tons/yr). ....................................................................................................................9 Figure 1.6–5. Annual NH3 emissions in the PM10 nonattainment area, by source category (tons/yr). ..................................................................................................................10 Figure 1.6–6. Typical daily PM10 emissions in the PM10 nonattainment area, by source category (lbs/day)....................................................................................................10 Figure 1.6–7. Typical daily PM2.5 emissions in the PM10 nonattainment area, by source category (lbs/day)....................................................................................................11 Figure 1.6–8. Typical daily NOx emissions in the PM10 nonattainment area, by source category (lbs/day)....................................................................................................11 Figure 1.6–9. Typical daily SOx emissions in the PM10 nonattainment area, by source category (lbs/day)....................................................................................................12 Figure 1.6–10. Typical daily NH3 emissions in the PM10 nonattainment area, by source category (lbs/day)....................................................................................................12 Figure 1.6–11. Annual emissions in the PM10 nonattainment area, by source category (TPY).....13 Figure 1.6–12. Typical daily emissions in the PM10 nonattainment area, by source category (lb/day). ...................................................................................................................13 Figure 2.7–1. Data flow for annual point source emission inventory reporting............................36 Figure 6.2–1. PM10 nonattainment area, Maricopa County, and biogenic modeling domains (northern & southern grid outlines). .....................................................................182 Appendices Appendix 2.1 Instructions for Reporting 2002 Annual Air Pollution Emissions Appendix 2.2 Sample Rule Effectiveness (RE) Survey Form Appendix 3.1 2002 Maricopa County Agricultural Pesticide Application Appendix 3.2 2002 Fire Department Survey Results Appendix 5.1 Appendix 5.2 Appendix 5.3 Appendix 5.4 Appendix 5.5 Appendix 5.6 Appendix 5.7 Traffic Information MOBILE6.2 Inputs, Outputs, and Spreadsheet Vehicle Registration Data Minimum and Maximum Temperature Calculations VMT Reasonableness Calculations FORTRAN Source Code for Emission Factor Weighting Program Monthly Gasoline Data 2002 PM10 Periodic Emission Inventory (Rev. 3/06) x Maricopa County, AZ