PESTICIDES A N N UA L REPORT 2004 (A.R.S. 49-303.C) Pesticide Contamination Prevention Program Report A.R.S. §49-303.C Arizona’s Pesticide Contamination Prevention Program was established by the Environmental Quality Act of 1987. The program’s major objective is to prevent or eliminate groundwater contamination by agricultural use pesticides and is composed of the following four major components: • Product chemistry and environmental fate review - Prior to registering an agricultural use pesticide, an applicant must submit product chemistry and environmental fate data for the associated active ingredient(s) to ADEQ for review and approval. Once the data requirements have been satisfied, ADEQ notifies the Department of Agriculture that the pesticide registration can be processed. • Creation of the Groundwater Protection List (GWPL) – ADEQ evaluates the product chemistry and environmental fate data to determine whether an agricultural use pesticide active ingredient has the potential to pollute groundwater. Those active ingredients found to have the potential to pollute are placed on the Groundwater Protection List and regulated in accordance with A.R.S. 49-305.A. • Soil and Groundwater Monitoring – ADEQ, in cooperation with the Department of Agriculture, monitors groundwater and soils in agricultural areas throughout the state for the presence of agricultural pesticide active ingredients on the GWPL. • Annual Reports – ADEQ compiles and reports sales and use information on soilapplied agricultural use pesticides containing active ingredients that fail the specific numeric values (SNVs) and therefore have the potential to pollute groundwater. The SNVs are criteria, based on the persistence and mobility characteristics of the active ingredient, that have been adopted in rule (A.A.C. R18-6-103). This report is in fulfillment of the fourth requirement, pursuant to A.R.S. §49-303.C, that ADEQ report to the Legislature by Dec. 1st of each year, the following information: • A list of agricultural use pesticide active ingredients for which there is a groundwater protection data gap. • A list of agricultural use pesticides containing an active ingredient that failed the specific numeric values presented in Table 1. • The sales and use information on these pesticides that were soil applied in the state during the most recent year, where they were applied and for what purpose or condition the pesticide was used. This report covers calendar year 2003. ADEQ Pesticides Annual Report 2004 - Page 1 Groundwater Protection Data Gap Pursuant to A.R.S. §49-302, prior to registering an agricultural pesticide in the state, applicants shall submit the product chemistry and environmental fate data of the associated active ingredients to ADEQ for review and approval. ADEQ’s review is based on the validity, completeness and adequacy of the submitted data. An agricultural use pesticide cannot be registered in the state without completing this process. If an agricultural use pesticide is registered without ADEQ’s review and approval, a groundwater protection data gap will exist. The Department of Agriculture will cancel the registration of any pesticides found to have a groundwater protection data gap. Since the implementation of the program in 1987, a total of 332 agricultural use pesticide active ingredients have completed the review and approval process and have been legally registered with the Arizona Department of Agriculture. Groundwater Protection List After the pesticide has completed the information submittal process and has been registered with the Department of Agriculture , the product chemistry and environmental fate data is compared to the specific numeric values (SNVs) in rule. The SNVs, found at A.A.C. R18-6-103 and in Table 1 below, are based on the Environmental Protection Agency’s (EPA) criteria for identifying those pesticides with the potential to leach to and pollute groundwater. There are two different factors for assessing the potential of a pesticide to pollute groundwater: mobility and persistence. Table 1: Specific Numeric Values Property SNVs Mobility Factor Water Solubility > 30 parts per million Soil Adsorption Coefficient < 5 milliliters per gram Persistence Factor Hydrolysis (half-life) > 25 weeks Aerobic Soil Metabolism (half-life) Anaerobic Soil Metabolism (half-life) Field Dissipation (half-life) > 3 weeks >3 weeks >3 weeks Agricultural use pesticide active ingredients that fail at least one SNV in both the mobility and persistence factors will be placed on the GWPL. The current GWPL is composed of 152 agricultural pesticide active ingredients and was adopted by rule in 1992 (A.A.C. R18-6-301) and was developed based on the SNVs in Table 1. Each year a new draft GWPL is established but does not become effective unless adopted by rule. The draft GWPL for 2003, which is presented in Table 2, contains 223 agricultural use pesticide active ingredients and includes the active ingredients from the 1992 GWPL plus all currently registered active ingredients that have failed at least one SNV in both mobility and persistence factors. ADEQ Pesticides Annual Report 2004 - Page 2 Table 2: Draft Groundwater Protection List for 2003 CAS Number Chemical Name 542-75-6 1,3-Dichloropropene 1928-43-4 2,4-D 2-Ethylhexyl Ester 94-75-7 2,4-D Acid 2,4-D Alkanol*Amine Salts of Ethanol and Isopropanol 137335-70-7 2,4-D Alkyl*Amine *(as in tall oil fatty acids) 1929-73-3 2,4-D Butoxyethyl Ester 94-80-4 2,4-D Butyl Ester 2212-54-6 2,4-D DDA (Dodecyclamine Salt) 5742-19-8 2,4-D Diethanolamine Salt 20940-37-8 2,4-D Diethylamine Salt 2008-39-1 2,4-D Dimethylamine Salt 533-23-3 2,4-D Ethylhexyl Ester 1713-15-1 2,4-D Isobutyl Ester 53404-37-8 2,4-D Isooctyl (2-ethyl-4-methylpentyl) 5742-17-6 2,4-D Isopropylamine Salt 25168-26-7 2,4-D Isooctyl Ester 94-11-1 2,4-D Isopropyl Ester of 2212-59-1 2,4-D N-Oleyl-1,3-Propylenediamine Salt 28685-18-9 2,4-D TDA (Tetradecyclamine) 2646-78-8 2,4-D Triethylamine Salt 32341-80-3 2,4-D Triisopropanolamine Salt 32357-46-3 2,4-DB, Butoxyethyl Ester 2758-42-1 2,4-DB, DMA Salt 16165-67-0 2,4-DP-P 30560-19-1 Acephate 135410-20-7 Acetamiprid 135158-54-2 Acibenzolar-S-Methyl 107-02-8 Acrolein 15972-60-8 Alachlor 116-06-3 Aldicarb 834-12-8 Ametryn 61-82-5 Amitrole 7778-39-4 Arsenic Acid 2302-17-2 Asulam, Sodium Salt 1912-24-9 Atrazine 86-50-0 Azinphos-Methyl 131860-33-8 Azoxystrobin 22781-23-3 Bendiocarb 17804-35-2 Benomyl 314-40-9 Bromacil 53404-19-6 Bromacil, Lithum Salt 2008-41-5 Butylate 75-60-5 Cacodylic Acid (Dimethylarsinic Acid) ADEQ Pesticides Annual Report 2004 - Page 3 124-65-2 133-06-2 63-25-2 1563-66-2 5234-68-4 128639-02-1 76-06-2 1897-45-6 64902-72-3 99129-21-2 1702-17-6 16828-95-8 33113-08-5 12069-69-1 14215-52-2 13426-91-0 9007-39-0 1344-73-6 1332-14-5 82027-59-6 20427-59-2 7758-99-8 420-04-2 21725-46-2 1134-23-2 66215-27-8 52918-63-5 13684-56-5 333-41-5 1918-00-9 25059-78-3 104040-79-1 2300-66-5 10007-85-9 1982-69-0 1194-65-6 99-30-9 38727-55-8 43222-48-6 109293-97-2 60-51-5 110488-70-5 957-51-7 85-00-7 330-54-1 79277-27-3 144-21-8 137512-74-4 Cacodylic Acid, Sodium Salt Captan Carbaryl Carbofuran Carboxin Carfentrazone-Ethyl Chloropicrin Chlorothalonil Chlorsulfuron Clethodim Clopyralid Copper Ammonia Complex Copper Ammonium Carbonate Copper Carbonate Copper Ethanolamine Complex Copper Ethylenediamine Copper Salts of Fatty & Rosin Acids Copper Sulfate, Basic Copper Sulfate, Basic (2+) Copper Triethanolamine Complex Copper Hydroxide Copper Sulfate Cyanamide Cyanazine Cycloate Cyromazine Deltamethrin Desmedipham Diazinon Dicamba Dicamba, DEA Salt Dicamba, DGA Salt Dicamba, DMA Salt Dicamba, Potassium Salt Dicamba, Sodium Salt Dichlobenil Dicloran Diethathyl Ethyl Difenzoquat Methyl Sulfate Diflufenzopyr Dimethoate Dimethomorph Diphenamid Diquat Dibromide Diuron DPX-M6316 DSMA (Disodium Methanearsonate) Emamectin Benzoate ADEQ Pesticides Annual Report 2004 - Page 4 115-29-7 145-73-3 2164-07-0 129-67-9 759-94-4 16672-87-0 26225-79-6 13194-48-4 56-38-2 2593-15-9 22224-92-6 60168-88-9 69806-50-4 79241-46-6 70124-77-5 142459-58-3 2164-17-2 59756-60-4 66332-96-5 102851-06-9 25954-13-6 39148-24-8 77182-82-2 1071-83-6 114370-14-8 38641-94-0 70901-12-1 112226-61-6 100784-20-1 51235-04-2 35554-44-0 114311-32-9 81405-85-8 81405-85-8 104098-48-8 81335-37-7 81335-77-5 101917-66-2 138261-41-3 42509-80-8 143390-89-0 58-89-9 330-55-2 128-58-3 121-75-5 28282-15-2 12427-38-2 94-74-6 Endosulfan Endothall Endothall, Dipotassium Salt of Endothall, Disodium Salt of EPTC Ethephon Ethofumesate Ethoprop Ethyl Parathion Etridiazole Fenamiphos Fenarimol Fluazifop-Butyl Fluazifop-P or R -Butyl Flucythrinate Flufenacet (Thiafluamide) Fluometuron Fluridone Flutolanil Fluvalinate Fosamine Ammonium Fosetyl-Al Glufosinate-Ammonium Glyphosate (Group) Glyphosate Ammonium Salt Glyphosate, Isopropylamine Salt Glyphosate, Potassium Salt Halofenozide Halosulfuron-Methyl Hexazinone Imazalil Imazamox Imazamethabenz-Methyl (Meta) Imazamethabenz-Methyl (Para) Imazapic Imazaquin Imazethapyr Imazethapyr, Ammonium Salt Imidacloprid Isazophos Kresoxim Methyl Lindane Linuron MAA (Methanearsonic Acid) Malathion Maleic Hydrazide, Potassium Salt Maneb MCPA ADEQ Pesticides Annual Report 2004 - Page 5 2039-46-5 29450-45-1 26544-20-7 3653-48-3 16484-77-8 70630-17-0 24307-26-4 245735-90-4 208465-21-8 57837-19-1 108-62-3 137-41-7 137-42-8 10265-92-6 2032-65-7 16752-77-5 161050-58-4 298-00-0 51218-45-2 87392-12-9 21087-64-9 74223-64-6 7786-34-7 6923-22-4 2163-80-6 88671-89-0 15299-99-7 111991-09-04 27314-13-2 19044-88-3 23135-22-0 301-12-2 4685-14-7 1910-42-5 1114-71-2 732-11-6 13171-21-6 1918-02-1 26952-20-5 2545-60-0 6753-47-5 51-03-6 41198-08-7 1610-78-0 7287-19-6 23950-58-5 25606-41-1 60207-90-1 MCPA, DMA Salt MCPA, 2 Ethylhexyl Ester MCPA, Isooctyl Ester MCPA, Sodium Salt Mecoprop-P (MCPP-P) Mefenoxam Mepiquat Chloride Mepiquat Pentaborate Mesosulfuron-Methyl Metalaxyl Metaldehyde Metam-K (Potassium) Metam-Na (Sodium) Methamidophos Methiocarb Methomyl Methoxyfenozide Methyl Parathion Metolachlor Metolachlor - S Metribuzin Metsulfuron Methyl Mevinphos Monocrotophos Monosodium Methanearsonate (MSMA) Myclobutanil Napropamide Nicosulfuron Norflurazon Oryzalin Oxamyl Oxydemeton-Methyl Paraquat Paraquat Dichloride Pebulate Phosmet Phosphamidon Picloram Picloram, Isooctyl Ester of Picloram, Potassium Salt Picloram, Triisopropanolamine Salt Piperonyl Butoxide Profenofos Prometon Prometryn Pronamide Propamocarb Propiconazole ADEQ Pesticides Annual Report 2004 - Page 6 94125-34-5 123312-89-0 129630-19-9 1698-60-8 123343-16-8 84087-01-4 74051-80-2 122-34-9 50723-80-3 7775-09-9 74222-97-2 81591-81-3 35400-43-2 112410-23-8 34014-18-1 5902-51-2 13071-79-9 886-50-0 111988-49-9 153719-23-4 117718-60-2 51707-55-2 59669-26-0 23564-05-8 137-26-8 87820-88-0 43121-43-3 52-68-6 55335-06-3 64700-56-7 57213-69-1 199119-58-9 26644-46-2 95266-40-3 1929-77-7 50471-44-8 Prosulfuron Pymetrozine Pyraflufen-Ethyl Pyrazon (Chlordiazon) Pyrithiobac Sodium Quinclorac Sethoxydim Simazine Sodium Bentazon Sodium Chlorate Sulfometuron-Methyl Sulfosate Sulprofos Tebufenozide Tebuthiuron Terbacil Terbufos Terbutryn Thiacloprid Thiamethoxam Thiazopyr Thidiazuron Thiodicarb Thiophanate-Methyl Thiram Tralkoxydim Triadimefon Trichlorfon Triclopyr Triclopyr, Butoxyethyl Ester Triclopyr, Triethylamine Salt Trifloxysulfuron-Sodium Triforine Trinexapac-Ethyl Vernolate Vinclozolin ADEQ Pesticides Annual Report 2004 - Page 7 The GWPL and the annual reports provide information on pesticide active ingredients and where and when they were applied. ADEQ can then focus its groundwater and soil monitoring activities in these areas. If these pesticide active ingredients are detected in the groundwater or soil as a result of agricultural activities, ADEQ may, depending on the level at which they were detected, require registrants to modify their application patterns and use or cancel the registration to prevent further contamination. Sales and Use Information on Agricultural Pesticides Containing Active Ingredients on the GWPL State rules require a pesticide dealer to file quarterly reports on the quantity and date of sales of agricultural use pesticides on the Groundwater Protection List that are soil applied (A.A.C R186-303). Since this information can be obtained from the pesticide application report (Form 1080) that pesticide users must submit to the Arizona Department of Agriculture prior to use, ADEQ has allowed the pesticide sellers and users to use Form 1080 to fulfill the reporting requirement of sales and use of the agricultural pesticides in Arizona. For the sale of agricultural pesticide to be used outside Arizona, sellers and users must submit the required information in ADEQ-designated form. If pesticides are brought in from out of state for use here, reporting would be on the “Use Report” rather than the “Sale Report". Conversely, if pesticides are purchased here in Arizona but used in New Mexico, this would be reported on the "SALE" report, not the "USE" report. A total of 62 soil-applied agricultural pesticides containing 44 different active ingredients that failed the SNVs were sold or used in Arizona between Jan. 1, 2003 and Dec. 31, 2003. The sales and use information are presented in the following tables. • Sales information on agricultural pesticides containing active ingredients on the draft GWPL (Table 2) that were intended for soil application outside Arizona between Jan. 1, 2003 and Dec. 31, 2003 (Table 3) • Sales information on agricultural pesticides containing active ingredients on the draft GWPL (Table 2) that were intended for soil application within Arizona between Jan. 1, 2003 and Dec. 31, 2003 (Table 4) • Use information on agricultural pesticides containing active ingredients on the draft GWPL (Table 2) that were intended for soil application within each county in Arizona between Jan. 1, 2003 and Dec. 31, 2003 (Table 5) Table 3: Pesticides Containing Active Ingredients on the Draft Groundwater Protection List Sold Outside Arizona During Jan. 1, 2003 to Dec. 31, 2003 No reported sales outside Arizona during Jan. 1, 2003 to Dec. 31, 2003. ADEQ Pesticides Annual Report 2004 - Page 8 Table 4: Reported Sales in Arizona During Jan. 1, 2003 to Dec. 31, 2003 EPA 1 62719 62719 1381 56077 59639 264 100 19713 2935 279 279 58266 59639 10163 10163 2935 51036 1812 17913 66222 10182 10182 1812 524 524 62719 71368 241 241 EPA 2 32 321 103 26 89 330 497 60 366 2876 3241 5 3 100 104 408 110 257 399 63 199 220 439 512 475 322 20 379 350 EPA 3 11220 Brand Name Telone II Telone EC 2,4-D Amine 4 Butoxone 200 Herbicide Orthene 75 WSP Temik 15 D (SLN AZ-820015) Aatrex 4 L Drexel Atrazine 4 L Herbicide Sevin 5 Bait Furadan 4 F (SLN AZ-910001) Aim EC Herbicide Tri-Clor EC Fumigant Select 2 EC Herbicde Gowan Diazinon 4 E Gowan Diazon 14 G Diazinon 14 G Dimethoate 4 E (SLN AZ-890011) Direx 4 L Herbicide Drexel Endosulfan 3 EC (SLN AZ-980004) Thionex 3 EC Eptam 20 G Selective Herbicide Eptam 7 E Selective Herbicide Cotoran 4 L Herbicide Roundup Ultramax Herbicide Roundup W Glyphomax Plus Nufarm Credit System Herbicide BASF Raptor Herbicide Pursuit-DG Herbicide Eco-Pak ™ Water Soluble Pack Active Ingredient 1,3-Dichloropropene 1,3-Dichloropropene 2,4-D DMA Salt 2,4-DB DMA Salt Acephate Aldicarb Atrazine Atrazine Carbaryl Carbofuran Carfentrazone-Ethyl Chloropicrin Clethodim Diazinon Diazinon Diazinon Dimethoate Diuron Endosulfan Endosulfan EPTC EPTC Fluometuron Glyphasate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Imazamox Imazathapyr ADEQ Pesticides Annual Report 2004 - Page 9 Total Chemical 13305.50 45314.26 100.00 9.25 332.00 810.00 352.50 113.88 3505.70 78.50 1.72 32064.00 6.50 358.31 2088.00 245.00 17.50 540.93 22.50 10.00 7750.00 520.49 70.50 155.63 94.55 218.69 60.00 5.00 11.70 Unit GAL GAL GAL GAL LBS LBS GAL GAL LBS GAL GAL LBS GAL GAL LBS LBS GAL GAL GAL GAL LBS GAL GAL GAL GAL GAL GAL GAL LBS EPA 1 241 3125 1812 228 100 51036 55146 5481 61842 352 62719 100 100 3125 50534 352 55947 100 100 1812 37404 1812 66222 62719 707 100 352 7969 19713 707 100 4581 4581 EPA 2 386 457 251 143 801 188 73 468 6 342 442 816 818 325 6 560 77 1074 620 274 692 274 15 397 159 912 576 58 60 238 939 377 408 EPA 3 10182 66222 51036 Brand Name Pusuit WDG Herbicide Eco-Pak Provado 1.6 Flowable Insecticide Manex Fungicide Flowable With Zinc Nufarm Rhomene MCPA Broadleaf Herbicide Ridomil Gold EC Fungicide Mepichlor 4.2% Liquid Ultra Flourish Agricultural Fungicide Vapam HL Soil Fumigant Sectagon 42 Funigant Solution For All Crops Dupont Lannate SP Insecticide Intrepid 2 F Dual Magnum Dual II Magnum Sencor 75 Turf Herbicide Bueno 6 Dupont ™ Accent ® Herbicide Sandoz-Zoral Rapid 80 Herbicide Gramoxone Max Caparol 4 L Cotton-Pro Herbicide Prometryn 4 L Herbicide Prometryn 4 L CA/AZ Prometryn 4 L Kerb 50 W (SLN AZ-020010) Kerb 50 W Selective Herbicide (SLN AX-790036) Fulfill Dupont ™ Staple ® Herbicide Poast Drexel Simazine 4 L Confirm 2 F Agricultural Insecticide (Sec 18 98-AZ-09) Platinum Topsin M WSB Topsin M WSB Active Ingredient Imazathapyr Imidacloprid Maneb MCPA Mefenoxam Mepiquat Chloride Metalaxyl Metam-Sodium Metam-Sodium Methomyl Methoxyfuroxide Metolachlor Metolachlor Metribuzin MSMA Nicosulfuron Norflurazon Paraquat Dichloride Prometryn Prometryn Prometryn Prometryn Prometryn Pronamide Pronamide Pymetrozine Pyrithiobac-Sodium Sethoxydim Simazine Tebufenozide Thiamethoxam Thiophanate-Methyl Thiophanate-Methyl ADEQ Pesticides Annual Report 2004 - Page 10 Total Chemical 5.40 0.80 138.55 57.50 62.92 29.00 136.71 57255.66 2750.00 366.00 39.47 109.45 20.00 971.00 13.50 3.75 530.00 68.71 280.50 2198.00 20.00 13.75 498.00 14974.55 7128.54 4.83 33.94 53.28 349.90 7.40 4.50 225.05 101.05 Unit LBS GAL GAL GAL GAL GAL GAL GAL GAL LBS GAL GAL GAL LBS GAL LBS LBS GAL GAL GAL GAL GAL GAL LBS LBS LBS LBS GAL GAL GAL GAL LBS LBS Table 5: Reported Pesticide Applications by County Jan. 1, 2003 to Dec. 31, 2003 County codes: EPA1 1381 100 19713 279 524 62719 352 100 100 62719 2935 279 10163 51036 100 5481 4581 4581 62719 62719 56077 19713 58266 59639 10163 EPA2 103 497 11 2876 475 322 560 497 818 321 366 2876 100 110 801 468 377 408 32 321 26 11 5 3 104 APA = Apache; COC = Coconino; COH = Cochise; GIL = Gila; GRA = Graham; GRE = Greenlee; LAP = La Paz; MAR = Maricopa; MOH = Mohave; NAV = Navajo; PIM = Pima; PIN = Pinal; SAN = Santa Cruz; YAV = Yavapai; YUM= Yuma EPA3 11220 Brand Name 2,4-D Amine 4 Aatrex 4L Drexel Atrazine 4L Herbicide Furadan 4 F (SLN AZ-910001) Roundup W Glyphomax Plus Dupont (TM) Accent (R) Herbicide Aatrex 4 L Dual II Magnum Telone EC Sevin 5 Bait Furadan 4 F (SLN AZ-910001) Gowan Diazinon 4 E Dimethoate 4E (SLN AZ-890011) Ridomil Gold EC Fungicide Vapam HL Soil Fumigant Topsin M WSB Topsin M WSB Telone II Telone EC Butoxone 200 Herbicide Drexel Atrazine 4 L Herbicide Tri-Clor EC Fumigant Select 2 EC Herbicide Gowan Diazinon 14 G Active Ingredient 2,4-D DMA Salt Atrazine Atrazine Carbofuran Glyphosate, Isopropylamine Glyphosate, Isopropylamine Nicosulfuron Atrazine Metolachlor 1,3-Dichloropropene Carbaryl Carbofuran Diazinon Dimethoate Mefenoxam Metam-Sodium Thiophanate-Methyl Thiophanate-Methyl 1,3-Dichloropropene 1,3-Dichloropropene 2,4-DB DMA Salt Atrazine Chloropicrin Clethodim Diazinon ADEQ Pesticides Annual Report 2004 - Page 11 Total Chemical 100.00 50.00 112.50 60.00 94.55 162.50 3.75 197.50 20.00 30543.46 3505.70 15.00 8.57 17.50 54.06 25691.26 170.05 101.05 11932.50 14770.80 9.25 1.38 25264.00 3.50 350.00 Unit GAL GAL GAL GAL GAL GAL LBS GAL GAL GAL LBS GAL GAL GAL GAL GAL LBS LBS GAL GAL GAL GAL LBS GAL LBS County COC COC COC COC COC COC COC GRA GRA LAP LAP LAP LAP LAP LAP LAP LAP LAP MAR MAR MAR MAR MAR MAR MAR EPA1 2935 1812 10182 10182 524 71368 241 5481 3125 50534 100 1812 1812 34704 66222 352 7969 100 4581 66222 1812 100 1812 62719 264 100 279 58266 1812 1812 241 EPA2 408 257 199 220 512 20 350 468 325 6 620 274 274 692 15 576 58 939 377 63 274 620 274 32 330 497 2876 5 257 439 379 EPA3 10182 66222 51036 11220 Brand Name Diazinon 14 G Derex 4 L Herbicide Eptam 20 G Selective Herbicide Eptam 7 E Select, Herbicide Roundup Ultramax Herbicide Nufarm Credit Systemic Herbicide Pursuit-DG Herbicide Eco-Pak ™ Water Soluble Packets Vapam HL Soil Fumigant Sencor 75 Turf Herbicide Bueno 6 Caparol 4 L Cotton-Pro Herbicide Prometryn 4 L CA/AZ Prometryne 4 L Herbicide Prometryn 4 L Dupont ™ Staple ® Herbicide Poast Platinum Topsin M WSB Thionex 3 EC Cotton-Pro Herbicide Caparol 4 L Cotton-Pro Herbicide Telone II Temik 15 G (SLN AZ-820015) Aatrex 4 L Furadan 4 F (SLN AZ-910001) Tri-clor E L Fumigant Direx 4 L Herbicide Cotoran 4 L Herbicide BASF Raptor Herbicide Active Ingredient Diazinon Diuron EPTC EPTC Glyphosate, Isopropylamine Glyphosate, Isopropylamine Imazathapyr Metam-Sodium Metribuzin MSMA Prometryn Prometryn Prometryn Prometryn Prometryn Pyrithiobac-Sodium Sethoxydim Thiamethoxam Thiophanate-Methyl Endosulfan Prometryn Prometryn Prometryn 1,3-Dichloropropene Aldicarb Atrazine Carbofuran Chloropicrin Diuron Fluometuron Imazamox ADEQ Pesticides Annual Report 2004 - Page 12 Total Chemical 245.00 418.05 7750.00 425.90 38.13 60.00 4.50 8600.00 951.00 13.50 49.50 755.00 13.75 20.00 107.50 33.94 53.28 4.50 55.00 10.00 47.25 231.00 400.50 1372.00 810.00 105.00 3.50 6800.00 122.88 70.50 5.00 Unit LBS GAL LBS GAL GAL GAL LBS GAL LBS GAL GAL GAL GAL GAL GAL LBS GAL GAL LBS GAL GAL GAL GAL GAL LBS GAL GAL LBS GAL GAL GAL County MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MAR MOH MOH PIM PIM PIN PIN PIN PIN PIN PIN PIN PIN EPA1 241 228 100 55947 1812 66222 59639 279 59639 10163 10163 10163 19713 10182 524 62719 241 3125 1812 100 51036 55146 5481 61842 352 62719 100 3125 100 1812 62719 EPA2 350 143 816 77 274 15 89 3241 3 100 100 104 399 220 512 322 386 457 251 801 188 73 468 6 342 442 816 325 1074 274 397 EPA3 71368 Brand Name Pursuit -DG Herbicide Eco-Pak ™ Water Soluble Packets Nufarm Rhomene MCPA Broadleaf Herbicide Dual Magnum Sandoz--Zorial Rapid 80 Herbicide Cotton-Pro Herbicide Prometryn 4 L Orthene 75 WSP Aim EC Herbicide Select 2 EC Herbicide Gowan Diazinon 4 E Gowan Diazinon 4 E Gowan Diazinon 14 G Drexel Endosulfan 3 EC (SLN AZ-980004) Eptam 7 E Select, Herbicide Roundup Ultramax Herbicide Glyphomax Plus Pursuit WDG Herbicide Eco-Pak Provado 1.6 Flowable Insecticide Manex Fungicide Flowable With Zinc Ridomil Gold EC Fungicide Mepichlor 4.2% Liquid Ultra Flourish Agricultural Fungicide Vapam HL Soil Fumigant Sectagon 42 Fumigant Solution For All Crops Dupont Lannate SP Insecticide Intrepid 2 F Dual Magnum Sencor 75 Turf Herbicide Gramoxone Max Cotton-Pro Herbicide Kerb 50-W (SLN AZ-020010) Active Ingredient Imazathapyr MCPA Metolachlor Norflurazon Prometryn Prometryn Acephate Carfentrazone-Ethyl Clethodim Diazinon Diazinon Diazinon Endosulfan EPTC Glyphosate, Isopropylamine Glyphosate, Isopropylamine Imazathapyr Imidacloprid Maneb Mefenoxam Mepiquat Chloride Metalaxyl Metam-Sodium Metam-Sodium Methomyl Methoxyfuroxide Metolachlor Metribuzin Paraquat Dichlordie Prometryn Pronamide ADEQ Pesticides Annual Report 2004 - Page 13 Total Chemical 7.20 57.50 15.00 530.00 900.25 390.50 332.00 1.72 3.00 347.75 1.99 1738.00 22.50 94.59 117.50 56.19 5.40 0.80 138.55 8.86 29.00 136.71 22964.40 2750.00 366.00 39.47 94.45 20.00 68.71 95.00 14974.55 Unit LBS GAL GAL LBS GAL GAL LBS GAL GAL GAL GA LBS GAL GAL GAL GAL LBS GAL GAL GAL GAL GAL GAL GAL LBS GAL GAL LBS GAL GAL LBS County PIN PIN PIN PIN PIN PIN YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM YUM EPA1 707 100 19713 707 EPA2 150 912 60 238 EPA3 Brand Name Kerb 50 W Selective Herbicide (SLN AZ-790036) Fulfill Drexel Simazine 4 L Confirm 2 F Agricultural Insecticide (SEC 1898-AZ-09,10) Active Ingredient Pronamide Pymetrozine Simazine Tebufenozide ADEQ Pesticides Annual Report 2004 - Page 14 Total Chemical 7128.54 4.83 349.90 7.40 Unit LBS LBS GAL GAL County YUM YUM YUM YUM