Pesticide Contamination Prevention Program Report A.R.S. §49-303.B The Arizona Pesticide Contamination Prevention Program was established by the Environmental Quality Act of 1987. The program’s major objective is to prevent or eliminate groundwater contamination by agricultural pesticide use and is composed of the following four major components: 1. 2. 3. 4. Product chemistry and environmental fate review - prior to registering an agricultural pesticide, applicants shall submit product chemistry and environmental fate data of the associated active ingredient to ADEQ for review and approval. The information is used to generate the Groundwater Protection List (GWPL). Groundwater Protection List - the GWPL is a list of agricultural pesticide active ingredients that have the potential to contaminate the groundwater. Monitoring - ADEQ is to monitor the presence of agricultural pesticide active ingredients on the GWPL in the groundwater and soil statewide. Compilation of data - ADEQ collects and reports sales and use information on soil applied agricultural pesticides containing active ingredients that fail the Specific Numeric Values (SNVs). This report is in fulfillment of a final requirement pursuant to A.R.S. §49-303.B that ADEQ shall report the following information to the legislature annually: 1. 2. 3. List of agricultural pesticide active ingredients for which there is a groundwater protection data gap A list of each agricultural pesticide containing an active ingredient that fail the SNVs presented in Table 1. The sales and use information on soil applied agricultural pesticides containing active ingredients that fail the SNVs presented in Table 1 in the state during the most recent year and where the pesticide was used. Groundwater Protection Data Gap Pursuant to A.R.S. §49-302, prior to registering an agricultural pesticide in the state, applicants shall submit the product chemistry and environmental fate data of the associated active ingredients to ADEQ for review and approval based on its validity, completeness and adequacy. An agricultural pesticide cannot be registered in the ADEQ's FY 03 Pesticide Report, Page 1 state without completing these processes, otherwise a groundwater protection data gap will exist for such pesticide. Since the implementation of the program in 1987, a total of 320 agricultural pesticide active ingredients have completed the above review and approval processes. Groundwater Protection List After ADEQ reviews and approves the product chemistry and environmental fate data of the agricultural pesticide active ingredient, it is compared with specific numeric values (SNVs), which are criteria adopted by rule. The SNVs, found at A.A.C. R18-6-103, are based on the Environmental Protection Agency’s (EPA) criteria for identifying pesticide active ingredients that, based on mobility and persistence factors, have the potential to leach to groundwater. The SNVs are presented in Table 1. Table 1: Specific Numeric Values Property SNVs Mobility Factors Water Solubility > 30 parts per million Soil Adsorption Coefficient < 5 milliliters per gram Persistence Factor Hydrolysis (half-life) > 25 weeks Aerobic Soil Metabolism (half-life) > 3 weeks Anaerobic Soil Metabolism (half-life) >3 weeks Field Dissipation (half-life) >3 weeks Agricultural pesticide active ingredients that fail at least one SNVs in both of the mobility factors AND persistence factors will be placed on the GWPL. The current GWPL, which is composed of 152 agricultural pesticide active ingredients, was adopted by rule in 1992 (A.A.C. R18-6-301) based on the SNVs in Table 1 and the agricultural pesticide registrations at the time. Each year a draft GWPL is established but does not become effective unless adopted by rule. The FY 2003 draft GWPL, which is presented in Table 2, contains 261 agricultural pesticide active ingredients and is based on the current agricultural pesticides registration requirements. ADEQ's FY 03 Pesticide Report, Page 2 Table 2: Draft Groundwater Protection List C_CAS C_Name 542-75-6 1,3-Dichloropropene 1928-43-4 2,4-D 2-Ethylhexyl Ester 94-75-7 2,4-D Acid 33333-3333 2,4-D Alkanol*Amine Salts of Ethanol and Isopropanol 137335-70-7 2,4-D Alkyl*Amine *(as in tall oil fatty acids) 1929-73-3 2,4-D Butoxyethyl Ester 94-80-4 2,4-D Butyl Ester 2212-54-6 2,4-D DDA (Dodecyclamine Salt) 5742-19-8 2,4-D Diethanolamine Salt 20940-37-8 2,4-D Diethylamine Salt 2008-39-1 2,4-D Dimethylamine Salt 533-23-3 2,4-D Ethylhexyl Ester 1713-15-1 2,4-D Isobutyl Ester 53404-37-8 2,4-D Isooctyl (2-ethyl-4-methylpentyl) 5742-17-6 2,4-D Isopropylamine Salt 25168-26-7 2,4-D Isooctyl Ester 94-11-1 2,4-D Isopropyl Ester of 2212-59-1 2,4-D N-Oleyl-1,3-Propylenediamine Salt 28685-18-9 2,4-D Tda (Tetradecyclamine) 2646-78-8 2,4-D Triethylamine Salt 32341-80-3 2,4-D Triisopropanolamine Salt 32357-46-3 2,4-DB, Butoxyethyl Ester 2758-42-1 2,4-DB, DMA Salt 16165-67-0 2,4-DP-P 30560-19-1 Acephate 135410-20-7 Acetamiprid 135158-54-2 Acibenzolar-S-Methyl 107-02-8 Acrolein 15972-60-8 Alachlor 116-06-3 Aldicarb 834-12-8 Ametryn 61-82-5 Amitrole 101-05-3 Anilazine 7778-39-4 Arsenic Acid 2302-17-2 Asulam, Sodium Salt 1912-24-9 Atrazine 86-50-0 Azinphos-Methyl 131860-33-8 Azoxystrobin 22781-23-3 Bendiocarb 1861-40-1 Benefin ADEQ's FY 03 Pesticide Report, Page 3 Table 2: Draft Groundwater Protection List C_CAS C_Name 17804-35-2 Benomyl 741-58-2 Bensulide 149877-41-8 Bifenazate 83322-02-5 Bifenthrin (Cis) 82657-04-3 Bifenthrin (Trans) 314-40-9 Bromacil 53404-19-6 Bromacil, Lithum Salt 78-48-8 Butifos (Def) 2008-41-5 Butylate 75-60-5 Cacodylic Acid (Dimethylarsinic Acid) 124-65-2 Cacodylic Acid, Sodium Salt 133-06-2 Captan 63-25-2 Carbaryl 1563-66-2 Carbofuran 5234-68-4 Carboxin 128639-02-1 Carfentrazone-Ethyl 76-06-2 Chloropicrin 1897-45-6 Chlorothalonil 2921-88-2 Chlorpyrifos 64902-72-3 Chlorsulfuron 99129-21-2 Clethodim 1702-17-6 Clopyralid 16828-95-8 Copper Ammonia Complex 33113-08-5 Copper Ammonium Carbonate 12069-69-1 Copper Carbonate 14215-52-2 Copper Ethanolamine Complex 13426-91-0 Copper Ethylenediamine 9007-39-0 Copper Salts of Fatty & Rosin Acids 1344-73-6 Copper Sulfate, Basic 1332-14-5 Copper Sulfate, Basic (2+) 82027-59-6 Copper Triethanolamine Complex 20427-59-2 Copper Hydroxide 7758-99-8 Copper Sulfate 420-04-2 Cyanamide 21725-46-2 Cyanazine 1134-23-2 Cycloate 68359-37-5 Cyfluthrin 52315-07-8 Cypermethrin 66215-27-8 Cyromazine 1861-32-1 DCPA (Dimethyl Tetrachloroterephtholate) ADEQ's FY 03 Pesticide Report, Page 4 Table 2: Draft Groundwater Protection List C_CAS C_Name 52918-63-5 Deltamethrin 13684-56-5 Desmedipham 333-41-5 Diazinon 1918-00-9 Dicamba 25059-78-3 Dicamba, DEA Salt 104040-79-1 Dicamba, DGA Salt 2300-66-5 Dicamba, DMA Salt 10007-85-9 Dicamba, Potassium Salt 1982-69-0 Dicamba, Sodium Salt 1194-65-6 Dichlobenil 99-30-9 Dicloran 51338-27-3 Diclofop-Methyl 115-32-2 Dicofol 2227-17-0 Dienochlor (Decachlorobis) 38727-55-8 Diethathyl Ethyl 43222-48-6 Difenzoquat Methyl Sulfate 35367-38-5 Diflubenzuron 109293-97-2 Diflufenzopyr 60-51-5 Dimethoate 110488-70-5 Dimethomorph 957-51-7 Diphenamid 298-04-4 Disulfoton 85-00-7 Diquat Dibromide 97886-45-8 Dithiopyr 330-54-1 Diuron 79277-27-3 DPX-M6316 144-21-8 DSMA (Disodium Methanearsonate) 115-29-7 Endosulfan 145-73-3 Endothall 2164-07-0 Endothall, Dipotassium Salt of 129-67-9 Endothall, Disodium Salt of 759-94-4 EPTC 66230-04-4 Esfenvalerate 55283-68-6 Ethalfluralin 16672-87-0 Ethephon 26225-79-6 Ethofumesate 563-12-2 Ethion 13194-48-4 Ethoprop 56-38-2 Ethyl Parathion 2593-15-9 Etridiazole ADEQ's FY 03 Pesticide Report, Page 5 Table 2: Draft Groundwater Protection List C_CAS C_Name 22224-92-6 Fenamiphos 60168-88-9 Fenarimol 39515-41-8 Fenpropathrin 51630-58-1 Fenvalerate 69806-50-4 Fluazifop-Butyl 79241-46-6 Fluazifop-P or R -Butyl 70124-77-5 Flucythrinate 142459-58-3 Flufenacet (Thiafluamide) 2164-17-2 Fluometuron 59756-60-4 Fluridone 66332-96-5 Flutolanil 102851-06-9 Fluvalinate 944-22-9 Fonofos 23422-53-9 Formetanate Hydrochloride 25954-13-6 Fosamine Ammonium 39148-24-8 Fosetyl-Al 77182-82-2 Glufosinate-Ammonium 1071-83-6 Glyphosate (Group) 114370-14-8 Glyphosate Ammonium Salt 38641-94-0 Glyphosate, Isopropylamine Salt 70901-12-1 Glyphosate, Potassium Salt 112226-61-6 Halofenozide 100784-20-1 Halosulfuran-Methyl 13356-08-6 Hexakis (Fenbutatin Oxide) 51235-04-2 Hexazinone 173584-44-6 Indoxacarb (Carboxylate) 35554-44-0 Imazalil 81405-85-8 Imazamethabenz-Methyl (Meta) 81405-85-8 Imazamethabenz-Methyl (Para) 104098-48-8 Imazapic 81335-37-7 Imazaquin 81335-77-5 Imazethapyr 101917-66-2 Imazethapyr, Ammonium Salt 138261-41-3 Imidacloprid 144171-61-9 Indoxacarb 36734-19-7 Iprodione 25311-71-1 Isofenphos 42509-80-8 Isazophos 82558-50-7 Isoxaben 143390-89-0 Kresoxim Methyl ADEQ's FY 03 Pesticide Report, Page 6 Table 2: Draft Groundwater Protection List C_CAS C_Name 91465-08-6 Lambdacyhalothrin 58-89-9 Lindane 330-55-2 Linuron 128-58-3 MAA (Methanearsonic Acid) 121-75-5 Malathion 28282-15-2 Maleic Hydrazide, Potassium Salt 12427-38-2 Maneb 94-74-6 MCPA 2039-46-5 MCPA, DMA Salt 29450-45-1 MCPA, 2 Ethylhexyl Ester 26544-20-7 MCPA, Isooctyl Ester 3653-48-3 MCPA, Sodium Salt 16484-77-8 Mecoprop (P) 70630-17-0 Mefenoxam 24307-26-4 Mepiquat Chloride 245735-90-4 Mepiquat Pentaborate 57837-19-1 Metalaxyl 108-62-3 Metaldehyde 137-41-7 Metam-K (Potassium) 137-42-8 Metam-Na (Sodium) 10265-92-6 Methamidophos 2032-65-7 Methiocarb 16752-77-5 Methomyl 161050-58-4 Methoxyfenozide 298-00-0 Methyl Parathion 51218-45-2 Metolachlor 87392-12-9 Metolachlor - S 21087-64-9 Metribuzin 74223-64-6 Metsulfuron Methyl 7786-34-7 Mevinphos 6923-22-4 Monocrotophos 2163-80-6 Monosodium Methanearsonate (MSMA) 88671-89-0 Myclobutanil 15299-99-7 Napropamide 111991-09-04 Nicosulfuron 27314-13-2 Norflurazon 19044-88-3 Oryzalin 19666-30-6 Oxadiazon 23135-22-0 Oxamyl 301-12-2 Oxydemeton-Methyl ADEQ's FY 03 Pesticide Report, Page 7 Table 2: Draft Groundwater Protection List C_CAS C_Name 42874-03-3 Oxyfluorfen 1910-42-5 Paraquat Dichloride 1114-71-2 Pebulate 82-68-8 PCNB (Quintozene) 40487-42-1 Pendimethalin 52645-53-1 Permethrin 13684-63-4 Phenmedipham 2310-17-0 Phosalone 732-11-6 Phosmet 13171-21-6 Phosphamidon 1918-02-1 Picloram 26952-20-5 Picloram, Isooctyl Ester of 2545-60-0 Picloram, Potassium Salt 6753-47-5 Picloram, Triisopropanolamine Salt 51-03-6 Piperonyl Butoxide 29091-21-2 Prodiamine 41198-08-7 Profenofos 1610-78-0 Prometon 7287-19-6 Prometryn 23950-58-5 Pronamide 25606-41-1 Propamocarb 2312-35-8 Propargite 60207-90-1 Propiconazole 94125-34-5 Prosulfuron 123312-89-0 Pymetrozine 1698-60-8 Pyrazon (Chlordiazon) 8003-34-7 Pyrethrin 95737-68-1 Pyriproxyfen 123343-16-8 Pyrithiobac Sodium 84087-01-4 Quinclorac 74051-80-2 Sethoxydim 122-34-9 Simazine 50723-80-3 Sodium Bentazon 7775-09-9 Sodium Chlorate 74222-97-2 Sulfometuron-Methyl 81591-81-3 Sulfosate 35400-43-2 Sulprofos 112410-23-8 Tebufenozide 34014-18-1 Tebuthiuron 5902-51-2 Terbacil 13071-79-9 Terbufos ADEQ's FY 03 Pesticide Report, Page 8 Table 2: Draft Groundwater Protection List C_CAS C_Name 886-50-0 Terbutryn 153719-23-4 Thiamethoxam 117718-60-2 Thiazopyr 51707-55-2 Thidiazuron 59669-26-0 Thiodicarb 23564-05-8 Thiophanate-Methyl 137-26-8 Thiram 87820-88-0 Tralkoxydim 2303-17-5 Triallate 43121-43-3 Triadimefon 52-68-6 Trichlorfon 55335-06-3 Triclopyr 64700-56-7 Triclopyr, Butoxyethyl Ester 57213-69-1 Triclopyr, Triethylamine Salt 141517-21-7 Trifloxystrobin 26644-46-2 Triforine 1582-09-8 Trifluralin 95266-40-3 Trinexapac-Ethyl 1929-77-7 Vernolate 50471-44-8 Vinclozolin The GWPL provides information on pesticide active ingredients and where they have been applied. ADEQ then focuses its groundwater and soil monitoring activities on these areas. If these pesticide active ingredients are detected in the groundwater or soil as a result of agricultural activities, ADEQ may, depending on the detected level, require registrants to modify their application use patterns or cancel the registration to prevent further contamination. Sales and Use Information on Agricultural Pesticides Containing Active Ingredients on the GWPL State rules require a pesticide dealer to file quarterly reports on the quantity and date of sales of agricultural use pesticides on the Groundwater Protection List that are soil applied (A.A.C R18-6-303). Since this information can be obtained from the pesticide application report (Form 1080) that pesticide users must submit to the Arizona Department of Agriculture prior to use, ADEQ allows the pesticide sellers and users to use Form 1080 to fulfill the reporting requirement of sales and use of the agricultural pesticides in Arizona. ADEQ's FY 03 Pesticide Report, Page 9 For the sale of agricultural pesticide to be used outside Arizona, sellers and users must submit the required information in ADEQ-designated form. If one has brought the pesticides from out of state and use them here, it would not be on the “Sale Report" but rather would be listed on the “Use Report”. On the other hand, if one buys pesticides here in Arizona but use the product in New Mexico, it would be the "SALE" report, but not the "USE" report. The sales and use information are presented in the following tables. • Sales information on agricultural pesticides containing active ingredients failing the SNVs that were intended for soil application outside Arizona between Jan. 1, 2002 and Dec. 31, 2002 (Table 3) • Sales information on agricultural pesticides containing active ingredients failing the SNVs that were intended for soil application within Arizona between Jan. 1, 2002 and Dec. 31, 2002 (Table 4) • Use information on agricultural pesticides containing active ingredients failing the SNVs that were intended for soil application within each county in Arizona between Jan. 1, 2002 and Dec. 31, 2002 (Table 5) A total of 106 soil-applied agricultural pesticides containing 61 different active ingredients that fail the SNVs were sold or used in Arizona between Jan. 1, 2002 and Dec. 31, 2002. ADEQ's FY 03 Pesticide Report, Page 10 Table 3: Pesticides Sold Outside Arizona During Jan. 1, 2001 to Dec. 31, 2001 No reported sales outside Arizona during Jan. 1, 2002 to Dec. 31, 2002. Table 4: Reported Sales in Arizona During Jan. 1, 2002 to Dec. 31, 2002 EPA 1 EPA 2 EPA 3 Brand Active Ingredient 62719 62719 42750 9779 56077 59639 264 100 19713 34704 34704 352 10163 73637 2935 279 279 58266 62719 59639 1812 3125 279 279 5481 10163 10163 2935 7969 1812 1812 264 32 321 19 263 26 89 330 497 11 69 746 564 200 3 366 2876 3241 5 220 3 366 351 3027 3126 490 100 104 408 137 257 257 634 56077 11220 ZA ZB Telone II Telone EC 2,4-D Amine 4 Herbicide 2,4-D Amine 4 Herbicide Butoxone 200 Orthene 75 WSP Temik Brand 15 G Aldicarb Herbicide Aatrex Drexel Atrazine 4 L Herbicide Atrazine 4 L Herbicide Balan DF Herbicide Benlate Prefar 4 E Selective Herbicide Sultan + 6.7 E Sevin 5 Bait Furadan 4 F Aim EC Herbicide Tri-Clor EC Fumigant Lorsban 4 F Select 2 EC Herbicide Cy-Pro 4 L Herbicide Baythroid 2 E Pyrethroid Insecticide Ammo 2.5 EC Insecticide Mustang Insecticie Dacthal W 75 Herbicide Gowan Diazinon 4 E Gowan Diazinon 14 G Diazinon 14 G Clarity Herbicide Direx 4 L Herbicide Karmex IWC 4 L Ginstar EC Cotton 1,3 Dichloropropene 1,3 Dichloropropene 2,4-D DMA Salt 2,4-D DMA Salt 2,4-DB DMA Salt Acephate Aldicarb Atrazine Atrazine Atrazine Benefin Benomyl Bensulide Butylate Carbaryl Carbofuran Carfentrazone - Ethyl Chloropicrin Chloropyrifos Clethodim Cyanazine Cyfluthrin Cypermethrin Cypermehtrin DCPA Diazinon Diazinon Diazinon Dicamba, DGA Salt Diuron Diuron Diuron + Thidiazuron ADEQ's FY 03 Pesticide Report, Page 11 Total Chemical 24,217 43,470 17 30 24 690 12,435 4,520 41 8 12,509 50 5,362 59 3,572 128 4 103,606 40 47 671 2 1 242 2,542 519 382 648 6 593 593 70 Units Gals Gals Gals Gals Gals Lbs Lbs Gals Gals Gals Lbs Lbs Gals Gals Lbs Gals Gals Lbs Gals Gals Gals Gals Gals Gals Lbs Gals Lbs Lbs Gals Gals Gals Gals 10182 10182 352 3125 199 220 515 283 1812 524 524 524 524 524 524 524 524 524 524 62719 62719 62719 62719 10182 241 241 3125 352 264 10182 5905 1812 1812 100 55146 5481 61842 352 62719 100 3125 3125 50534 439 445 445 445 445 475 475 475 475 475 512 322 322 322 323 449 310 386 422 597 482 434 250 251 251 801 73 463 6 342 442 816 325 314 6 ZE ZG ZF ZD ZE ZA ZB ZC ZD 18102 Eptam 20 G Selective Herbicide Eptam 7 E Selective Herbicide Du Pont Asana XL Insecticide Nemacur 3 E Systematic InsecticideNematicide Cotoran 4 C Herbicide Honcho Herbicide Rascal Herbicide Roundup Herbicide Roundup Original Herbicide Accord Site Prep Herbicide Roundup Orginal II CA Herbicie Roundup Pro Herbicide Roundup Ultra Herbicide Roundup W Roundup Ultramax Herbicide Accord SP Herbicide Glyphomax Plus Glypro Plus Glyphomax Touchdown Herbicide Pursuit Herbicide Pursuit WDG Herbicide Eco-Pak Admire 2 F Du Pont Avaunt Insecticide Rovral 4 F Fungicide Warrior/Karate Insecticide Fyfanon 8 E Manex Fungicide Flowable With Zinc Pentathlon Fungicide Flowable With Zinc Ridomil Gold EC Fungicide Ultra Flourish Agricultural Fungicide Vapam Soil Fumigant Sectagon HL Fumigant Solution Du Pont Lannate SP Insecticide Intrepid 2 F Dual Magnum Herbicide Sencor 75 Turf Herbicide Sencor 4 F Herbicide Bueno 6 EPTC EPTC Esfenvalerate Fenamiphos 4,590 28 2 30 Lbs Gals Gals Gals Fluometuron Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate, Isopropylamine Glyphosate - Trimesium Imazethapyr Imazethapyr Imidacloprid Indoxacarb Iprodione Lambdacyhalothrin Malathion Maneb Maneb Mefenoxam Metalaxyl Metam-Sodium Metam-Sodium Methomyl Methoxyfenozide Metolachlor Metribuzin Metribuzin MSMA 8 146 146 146 146 46 46 46 46 46 291 156 156 156 13 18 5 12 1,008 4 1,212 24 4 292 292 600 6 47,018 17,891 218 3 266 2,412 104 6 Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Lbs Gals Lbs Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Gals Lbs Gals ADEQ's FY 03 Pesticide Report, Page 12 100 55947 707 66222 100 241 68156 279 279 100 1812 34704 62719 707 352 7969 100 100 19713 707 707 100 1812 34704 1812 10163 62715 62719 62719 62719 62719 100 3125 7969 7069 1812 9779 72444 848 77 243 28 1074 337 6 3014 3051 620 274 692 397 159 576 58 603 603 60 238 238 939 328 792 355 120 131 131 131 250 250 919 559 85 85 367 255 0 62719 51036 55467 71058 71058 ZA ZC Zorial Rapid 80 Herbicide Sandoz-Zorial Rapid 80 Herbicide Goal 2 XI Herbicide Galigan 2 E Herbicide Gramoxone Maximum Prowl 3.3 EC Herbicide Pendimax 3.3 EC Herbicide Pounce 3.2 EC Insecticide Pounce 25 WP Insecticide Caparol 4 L Herbicide Cotton-Pro Herbicide Prometryn 4L Herbicide Kerb 50 W/WSP Herbicide Kerb 50 W/WSP Herbicide Stable Herbicide Poast Princep Caliber 90 Herbicide Princep DF Herbicide Drexel Simazine 4 L Herbicide Confirm 2 F Agricultural Insecticide Confirm T/O Insecticide Platinum Trilin 10 G Herbicide Trifluralin HF Trilin Herbicide Gowan Trifluralin 10 G Herbicide Treflan TR-10 Tenkoz Trifluralin 10 G Triap 10 G Treflan HFP Triap 4 HF Flint Fungicide Flint Fungicide Curalan DF/EG Fungicide Ronilan DF/EG Fungicide Unknown Unknown Unknown Norflurazon Norflurazon Oxyfluorfen Oxyfluorfen Paraquat Dichloride Pendimethalin Pendimethalin Permethrin Permethrin Prometryn Prometryn Prometryn Pronamide Pronamide Pyrithiobac-Sodium Sethoxydim Simazine Simazine Simazine Tebufenozide Tebufenozide Thiamethoxam Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Trifloxystrobin Trifloxystrobin Vinclozolin Vinclozolin Unknown Unknown Unknown ADEQ's FY 03 Pesticide Report, Page 13 1,505 730 136 30 43 4,719 216 13 22 1,220 2,701 184 1,731 36,354 11 9 210 105 250 2 2 1 11,815 351 669 27,150 133,368 3,000 4,000 30 1,100 23 10 1,520 1,520 25 207 100 Lbs Lbs Gals Gals Gals Gals Gals Gals Lbs Gals Gals Gals Lbs Lbs Lbs Gals Lbs Lbs Gals Gals Gals Gals Lbs Gals Gals Lbs Lbs Lbs Lbs Gals Gals Lbs Lbs Lbs Lbs Gals Gals Lbs Table 5: Reported Pesticide Application by County Jan. 1, 2002 to Dec. 31, 2002 EPA 1 EPA 2 EPA 3 Brand Active Ingredient 9779 264 100 34704 279 59639 524 524 524 524 62719 62719 62719 62719 707 62719 9779 42750 7969 100 62719 62719 10163 2935 10163 3125 100 5481 61842 241 1812 3125 1812 1812 62719 263 330 497 69 2876 3 445 ZE 445 ZG 445 445 ZE 322 ZD 322 322 323 159 250 255 19 137 497 250 71058 321 200 366 100 422 801 468 6 337 274 559 328 355 131 2,4-D Amine 4 Herbicide Temik Brand 15 G Aldicarb Herbicide Aatrex 4 L Herbicide Atrazine 4 L Herbicide Furdan 4 F Select 2 EC Herbicide Honcho Herbicide Rascal Herbicide Roundup Herbicide Roundup Original Herbicide Accord SP Herbicide Glyphomax Plus Glypro Plus Gluphomax Kerb 50 W/WSP Triap 4 HF Unknown 2,4-D Amine 4 Herbicide Clarity Herbicide Aatrex 4 L Herbicide Triap 4 HF Telone EC Prefar 4 E Selective Herbicide Sevin 5 Bait Gowan Diazinon 4 E Admire 2 F Ridomil Gold EC Fungicide Vapam HL Soil Fumigant Sectagon 4 L Fumigant Solution Prowl 3.3 EC Herbicide Cotton-Pro Herbicide Flint Fungicide Trilin 10 G Herbicide Trilin Herbicide Treflan TR 10 Total Units County Chemical 2,4-D DMA Salt Aldicarb 30 1,380 GalsCOC LbsCOC Atrazine Atrazine Carbofuran Clethodim Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Pronamide Trifluralin Unknown 2,4-D DMA Salt Dicamba, DGA Salt Atrazine Trifluralin 1,3 Dichloropropene Bensulate Carbaryl Diazinon Imidacloprid Mefenoxam Metam-Sodium Metam-Sodium Pendimethalin Prometryn Trifloxystrobin Trifluralin Trifluralin Trifluralin 3,296 8 128 8 146 146 146 146 156 156 156 13 960 25 207 17 6 320 20 31,289 916 3,572 11 231 285 8,202 15,141 241 211 10 1,750 34 2,020 GalsCOC GalsCOC GalsCOC GalsCOC GalsCOC GalsCOC GalsCOC GalsCOC GalsCOC GalsCOC GalsCOC GalsCOC LbsCOC GalsCOC GalsCOC GalsGIL GalsGIL GalsGRA GalsGRA GalsLAP GalsLAP LbsLAP GalsLAP GalsLAP GalsLAP GalsLAP GalsLAP GalsLAP GalsLAP LbsLAP LbsLAP GalsLAP LbsLAP ADEQ's FY 03 Pesticide Report, Page 14 62719 62719 62719 264 250 71058 32 321 330 100 10163 58266 62719 59639 1812 10163 10163 1812 1812 2935 3125 497 200 5 11220 220 3 366 100 104 257 ZA 257 ZB 408 283 524 524 524 524 524 524 10182 241 241 3125 10182 5905 100 5481 3125 3125 50534 100 55947 241 100 1812 475 ZD 475 ZE 475 ZA 475 ZB 475 ZC 512 449 310 386 422 434 250 801 468 314 325 6 10182 848 77 337 620 274 Triap 4 HF Telone II Telone EC Temik Brand 15 G Aldicarb Pesticide Aatrex 4 L Herbicide Prefar 4 E Selective Herbicide Tri-Clor EC Fumigant Lorsban 4 E Select 2 EC Herbicide Cy-Pro 4 L Herbicide Gowan Diazinon 4 E Gowan Diazinon 14 G Direx 4 L Herbicide Karmex IWC 4 L Herbicide Diazinon 14 G Nemacur 3 E Systemic InsecticideNematicide Accord SP Herbicide Roundup Original II CA Herbicide Roundup Pro Herbicide Roundup Ultra Herbicide Roundup W Herbicide Roundup Ultramax Herbicide Touchdown Herbicide Pursuit Herbicide Pursuit WDG Herbicide Eco-Pak Admire 2 F Warrior/Karate Insecticide Fyfanon 8 E Ridomil Gold EC Fungicide Vapam HL Soil Fumigant Sencor 4 F Herbicide Sencor 75% Turf Herbicide Bueno 6 Zorial rapid 80 Herbicide Sandoz-Zrial Rapid 80 Herbicide Prowl 3.3 EC Herbicide Caparol 4 L Herbicide Cotton-Pro Herbicide Trifluralin 1,3 Dichloropropene 1,3 Dichloropropene Aldicarb 80 23,846 11,641 4,050 GalsLAP GalsMAR GalsMAR LbsMAR Atrazine Bensulate Chloropicrin Chlorpyrifos Clethodim Cyanazine Diazinon Diazinon Diuron Diuron Diazinon Fenamiphos 66 40 69,751 40 31 244 18 382 391 391 648 30 GalsMAR GalsMAR LbsMAR GalsMAR GalsMAR GalsMAR GalsMAR LbsMAR GalsMAR GalsMAR LbsMAR GalsMAR Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Trimesium Imazethhapyr Imazethhapyr Imidacloprid Lambdacyhalothrin Malathion Mefenoxam Metam-Sodium Metribuzin Metribuzin MSMA Norflurazon Norflurazon Pendimethalin Prometryn Prometryn 15 15 15 15 15 280 18 5 2 116 24 4 125 13,907 104 2,288 6 945 560 2,347 60 943 GalsMAR GalsMAR GalsMAR GalsMAR GalsMAR GalsMAR GalsMAR GalsMAR LbsMAR GalsMAR GalsMAR GalsMAR GalsMAR GalsMAR LbsMAR LbsMAR GalsMAR LbsMAR LbsMAR GalsMAR GalsMAR GalsMAR ADEQ's FY 03 Pesticide Report, Page 15 352 7969 100 100 10163 1812 1812 62715 62719 62719 62719 100 1812 524 524 524 524 524 241 1812 241 68156 100 1812 62719 62719 62719 56077 264 576 58 603 603 120 328 355 131 131 250 250 939 367 475 475 475 475 475 337 274 337 6 620 274 250 250 32 26 330 100 19713 73677 279 58266 59639 1812 3125 1812 1812 497 11 3 3241 5 3 366 351 257 257 Staple Herbicide Poast Princip Caliber 90 Herbicide Princep DF Herbicide Gowan Trifluralin 10 G Herbicide Trilin 10 G Herbicide Trilin Herbicide Treflan TR 10 55467 Tenkoz Trifluralin 10 G Treflan HFP 71058 Triap 4 HF Platinum Unknown ZD Accord SP Herbicide ZE Roundup riginal II CA Herbicide ZA Roundup Pro Herbicide ZB Roundup Ultra Herbicide ZC Roundup W Herbicide Prowl 3.3 EC Herbicide Cotton-Pro Herbicide Prowl 3.3 EC Herbicide 62719 Pendimax 3.3 EC Herbicide Caparol 4 L Herbicide Cotton-Pro-Herbicide Treflan HFP 71058 Triap 4 HF Telone II Butoxone 200 Temik Brand 15 G Aldicarb Pesticide Aatrex 4 L Herbicide Drexel Atrazine 4 L Herbicide 56077 Sultan + 6.7 E Aim Herbicide 11220 Tri-Clor EC Fumigant Select 2 EC Herbicide Cy-Pro 4 L Herbicide Baythroid 2 E Pyrethroid Insecticide Direx 4 L Herbicide Karmex IWC 4 L Herbicide 51036 Pyrithiobac-Sodium Sethoxydim Simazine Simazine Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Thiamethoxam Unknown Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Pendimethalin Prometryn Pendimethalin Pendimethalin Prometryn Prometryn Trifluralin Trifluralin 1,3 Dichloropropene 2,4-DB DMA Salt Aldicarb 11 9 210 105 27,150 5,665 463 82,198 3,000 14 500 1 25 25 25 25 25 25 113 45 199 78 1,160 192 9 82 371 24 7,005 LbsMAR GalsMAR LbsMAR LbsMAR LbsMAR LbsMAR GalsMAR LbsMAR LbsMAR GalsMAR GalsMAR GalsMAR GalsMAR GalsMOH GalsMOH GalsMOH GalsMOH GalsMOH GalsMOH GalsMOH GalsPIM GalsPIM GalsPIM GalsPIM GalsPIM GalsPIM GalsPIN GalsPIN LbsPIN Atrazine Atrazine Butylate Carfentrazone - Ethyl Chloropicrin Clethodim Cyanazine Cyfluthrin Diuron Diuron 838 41 59 4 33,855 8 427 2 202 202 GalsPIN GalsPIN GalsPIN GalsPIN LbsPIN GalsPIN GalsPIN GalsPIN GalsPIN GalsPIN ADEQ's FY 03 Pesticide Report, Page 16 10182 10182 1812 241 100 100 68156 241 55947 1812 34704 1812 1812 34704 62719 62719 62719 59639 34704 352 10163 279 279 5481 10163 264 352 524 524 524 524 524 524 3125 352 264 1812 1812 199 Eptam 20 G Selective Herbicide 220 Eptam 7 E Selective Herbicide 439 Cotoran 4 L Herbicide 386 Pursuit WDG Herbicide Eco-Pak 816 Dual magnum Herbicide 848 Zorial rapid 80 Herbicide 6 62719 Pendimax 3.3 EC Herbicide 337 Prowl 3.3 EC Herbicide 77 Sandoz-Zorial Rapid 80 Herbicide 274 Cotton-Pro Herbicide 692 Prometryn 4 L Herbicide 328 Trilin 10 G Herbicide 355 Trilin Herbicide 792 Trifluralin HF 131 Treflan TR 10 131 71058 Triap 10 G 250 71058 Triap 4 HP 89 Orthene 75 WSP 746 Balan DF Herbicide 564 Benlate SP Fungicide 200 Prefar 4 E Selective Herbicide 3027 Ammo 2.5 EC Insecticide 3126 Mustang Insecticide 490 Dacthal W 75 Herbicide 100 Gowan Diazinon 5 E 634 Ginstar Cotton Defoliant 515 Du Pont Asana XL Insecticide 475 ZD Accord SP Herbicide 475 ZE Roundup Original II CA Herbicide 475 ZA Roundup Pro Herbicide 475 ZB Roundup Ultra Herbicide 475 ZC Roundup W Herbicide 512 Roundup Ultramax Herbicide 422 Admire 2 F 597 Du Pont Avaunt Insecticide 482 Rovral 4 F Fungicide 251 Manex Fungicide Flowable With Zinc 251 Pentathlon Fungicide Flowable With Zinc EPTC EPTC Fluometuron Imazathapyr Metolachlor Norflurazon Pendimethalin Pendimethalin Norflurazon Prometryn Prometryn Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Trifluralin Acephate Benefin Benomyl Bensulate Cypermethrin Cypermethrin DCPA Diazinon Diuron + Thidiazuron Esfenvalerate Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Glyphosate, Isopropylamine Salt Imidacloprid Indoxacarb Iprodione Maneb Maneb ADEQ's FY 03 Pesticide Report, Page 17 4,590 28 8 10 124 560 138 1,718 170 1,310 184 4,400 172 351 46,400 4,000 232 690 12,509 50 4,406 1 242 2,542 490 70 2 6 6 6 6 6 11 661 4 1,212 292 LbsPIN GalsPIN GalsPIN LbsPIN GalsPIN LbsPIN GalsPIN GalsPIN LbsPIN GalsPIN GalsPIN LbsPIN GalsPIN GalsPIN LbsPIN LbsPIN GalsPIN LbsYUM LbsYUM LbsYUM GalsYUM GalsYUM GalsYUM LbsYUM GalsYUM GalsYUM GalsYUM GalsYUM GalsYUM GalsYUM GalsYUM GalsYUM GalsYUM GalsYUM LbsYUM GalsYUM GalsYUM 292 GalsYUM 100 5481 61842 55146 352 62719 100 3125 707 66222 100 241 279 279 707 62719 19713 707 707 62719 62719 62719 100 7969 7969 72444 801 Ridomil Gold EC Fungicide 468 Vapam HL Soil Fumigant 6 Sectagon 4 L Fumigant Solution 73 Ultra Flourish Agricultural Fungicide 342 Du Pont Lannate SP Insecticide 442 Intrepid 2 F 816 Dual Magnum Herbicde 325 Sencor 75% Turf Herbicide 243 Goal 2 XI Herbicide 28 Galigan 2 E 1074 Gramoxone Max 337 Prowl 3.3 EC Herbicide 3014 Pounce 3.2 EC Insecticide 3051 Pounce 25 WP Insecticide 159 Kerb 50 W/WSP Herbicide 397 Kerb 50 W/WSP Herbicide 60 Drexel Simazine 4 L 238 Confirm 2 F Agricultural Insecticide 238 Confirm T/O Insecticide 131 Treflan TR 10 250 Treflan HFP 250 71058 Triap 4 HP 919 Flint Fungicide 85 ZA Curalan DF/EG Fungicide 85 ZC Ronilan DF/EG Fungicide 0 Unknown Mefenoxam Metam-Sodium Metam-Sodium Metalaxyl Methomyl Methoxyfenozide Metolachlor Metribuzin Oxyfluorfen Oxyfluorfen Paraquat Dichloride Pendimethalin Permethrin Permethrin Pronamide Pronamide Simazine Tebufenozide Tebufenozide Trifluralin Trifluralin Trifluralin Trifloxystrobin Vinclozolin Vinclozolin Unknown ADEQ's FY 03 Pesticide Report, Page 18 190 24,909 2,750 6 218 35 124 124 136 30 43 101 13 22 35,394 1,731 250 2 2 2,750 13 161 23 1,520 1,520 100 GalsYUM GalsYUM GalsYUM GalsYUM LbsYUM GalsYUM GalsYUM LbsYUM GalsYUM GalsYUM GalsYUM GalsYUM GalsYUM LbsYUM LbsYUM LbsYUM GalsYUM GalsYUM GalsYUM LbsYUM GalsYUM GalsYUM LbsYUM LbsYUM LbsYUM LbsYUM