2000 ANNUAL WATER QUALITY REPORT Water Quality Management Division Tucson Water is pleased to provide our customers with this third Annual Water Quality Report. The report will serve as a reference with important information on the quality of water we deliver, provide you with contacts and phone numbers you may need from time to time, and fulfill a federal regulatory requirement to give you annual information about the source and quality of your drinking water. CLE RD O RA SKYLINE DR RIV ER RO A IRONWOOD HILLS CRAYCROFT RD INA RD D SNYDER RD TANQUE VERDE RD GRANT RD SPEEDWAY BROADWAY 22ND STREET KI NN AJO HIG VALENCIA RD PIMA MINE RD COUNTRY CLUB RD Y WA NOGALES HIGH WHERE DOES OUR DRINKING WATER COME FROM? IRVINGTON HOUGHTON AY HW RD RD KOLB RD EY MISS ION RD • Where does our drinking water come from? • What contaminants have been detected in our drinking water? • Detailed information on detected contaminants. • Definitions of technical and regulatory terms used in the report. • Information on expected drinking water contaminants. • Were there any violations of drinking water regulations? • How is our drinking water treated? • Who can I contact for more information? If you are a non-English speaking resident, we recommend that you speak with someone who understands the report. Call our Public Information Office at 791-4331 for a copy of this report in Spanish. The format for this report follows the guidelines set by the United States Environmental Protection Agency (USEPA) as part of the Safe Drinking Water Act. The USEPA requires all public water providers to deliver this information to all customers on an annual basis in a single report that provides water quality data to the public in an understandable manner. SANDARIO RD THIS REPORT CONTAINS THE FOLLOWING INFORMATION: In 2000, Tucson Water served about 675,000 people in the Tucson area. The water supply came from approximately 190 groundwater wells located in and around the Tucson metropolitan area (see map). In urban Tucson, most of the wells (also known as Points of Entry or POE) serve the neighborhood in which they are located, with excess supply routed to reservoirs for use elsewhere in the system. Wells located outside the urban core often deliver water to a single “collector” main prior to delivery to customers. In these cases, the collector main is termed a “combined Point of Entry (POE)” to the drinking water system. The Tucson Water system has three combined POEs: the Southern Avra Valley well field, the Santa Cruz well field, and the South Side well field, which includes Tucson Airport Area Remediation Project (TARP). 1 WHAT CONTAMINANTS HAVE BEEN DETECTED IN OUR DRINKING WATER? Tucson Water regularly samples the drinking water that is delivered to you. Much of this testing is required by drinking water regulations. In addition to this required monitoring, we perform a great deal of discretionary monitoring in order to provide both Tucson Water staff and customers with additional information. The table on the next page lists all contaminants that were detected in both the required and discretionary drinking water monitoring. Three inorganic contaminants of special interest are arsenic, fluoride, and nitrate. Fluoride and arsenic are naturally occurring and tend to increase as water is drawn from greater depths. Nitrate on the other hand is typically found in higher concentrations near the surface of the groundwater table because it is frequently associated with fertilizer use, septic tanks and other human activities. Please see the Detected Contaminants Table and the specific explanations, which follow the table, for more information. It is important to remember that the detection of a contaminant in drinking water does not necessarily represent a threat to public health. Current technology allows water utilities to detect extremely low levels of contaminants in drinking water. A detected result means a concentration that is above the minimum value that can be measured by the laboratory. In most cases, the minimum detectable level of a contaminant is well below the USEPA regulatory limit for that contaminant. To compare the detected amount with the amount allowed by the USEPA, refer to the Maximum Contaminant Level (MCL) column in the table. (Because the vast majority of regulated contaminants were not detectable in drinking water delivered by Tucson Water, the non-detected results were not included in this table. For a complete list of all USEPA regulated contaminants contact the USEPA at 1-800-426-4791 or visit the USEPA website at www.epa.gov/safewater/ creg/html. INFORMATION ON EXPECTED DRINKING WATER CONTAMINANTS In 2000, groundwater was the source of all of the drinking water delivered by Tucson Water. All drinking water, including bottled water, may reasonably be expected to contain at least small amounts of some contaminants. Tucson’s groundwater contains dissolved minerals and organic compounds, which have been leached from the rock, sediments, and plant materials through which the water traveled. One would expect to find beneficial minerals such as calcium and magnesium, harmless minerals such as chloride, bicarbonate, and sulfate, and metals such as iron, copper, arsenic, and lead, which may be either beneficial or harmless at low concentrations, but harmful at high concentrations. In addition to these naturally occurring contaminants, our groundwater may contain contaminants resulting from human, industrial or domestic activities. For this reason, water utilities must currently monitor for approximately 90 regulated and 48 unregulated contaminants. The following language is required by the USEPA to appear in this report, some of which may not be applicable to deep groundwater wells, the source of the Tucson Water supply: Contaminants that may be present in a source water can include: • Microbial contaminants, such as viruses and bacteria, which may come from sewage, agricultural livestock, and wildlife. • Inorganic contaminants, such as salts and metals, which can be naturally-occurring or result from urban stormwater runoff, industrial or domestic wastewater discharges, oil and gas production, mining, or farming. • Pesticides and herbicides, which may come from a variety of sources such as agriculture, urban stormwater runoff, and residential uses. • Organic chemical contaminants, including synthetic and volatile organic chemicals, which are byproducts of industrial processes and petroleum production, and can also come from gas stations, urban stormwater runoff, and septic systems. • Radioactive contaminants, which can be naturally-occurring or be the result of oil and gas production and mining activities. In order to ensure that tap water is safe to drink, USEPA regulations limit the amount of certain contaminants in water provided by public water systems. Food and Drug Administration regulations establish limits for contaminants in bottled water that must provide the same protection for public health. Bottled water may come from either a surface water source or groundwater source, and may be treated minimally or extensively. For information on the quality of your bottled water, contact the water bottling company. A SPECIAL NOTE TO AT-RISK POPULATIONS While the Safe Drinking Water Act regulations are intended to protect consumers throughout their lifetime, some people may be more vulnerable to infections from drinking water than the general population. These “at-risk” populations include: immuno-compromised persons such as persons with cancer undergoing chemotherapy, people who have undergone organ transplants, people with HIV/AIDS or other immune system disorders, and in some cases, elderly people and infants. These people should seek advice about drinking water from their health care providers. USEPA/CDC guidelines on appropriate means to lessen the risk of infection by cryptosporidium and other microbial contaminants are available from the USEPA’s Safe Drinking Water hotline. 2 DETECTED CONTAMINANTS TABLE Inorganics Contaminant Arsenic, Total Fluoride Nitrate (as N) Maximum Result 10 ppb 2 ppm 8.3 ppm Range < 1.5 — 10 ppb < 0.1 — 2 ppm 0.34 — 8.3 ppm2 MCL 50 ppb 4 ppm 10 ppm MCLG None 4 ppm 10 ppm Major Sources Natural deposits Natural deposits Natural deposits; septic tanks; agriculture; sewage Radiochemical Contaminant Adjusted Gross Alpha Radon Activity Radium Activity, Combined Uranium Activity 2.5 pCi/L 1420 pCi/L 0.2 pCi/L 5.1 pCi/L < 0.5 — 2.5 pCi/L < 20 — 1420 pCi/L 0.2 — 0.2 pCi/L <0.5 — 5.1 pCi/L 15 pCi/L No MCL 5 pCi/L 30 pCi/L 0 pCi/L None 0 pCi/L None Natural deposits Natural deposits Natural deposits Natural deposits Volatile Organics Contaminant Chloromethane 0.7 ppb <0.5 — 0.7 ppb No MCL None Dibromomethane 0.9 ppb <0.5 — 0.9 ppb No MCL None Ethylbenzene 1.1 ppb <0.5 — 1.1 ppb 700 ppb 700 ppb Methyl-tert-butyl Ether Tetrachloroethene (PCE) Total Xylenes 0.6 ppb 0.8 ppb 0.0092 ppm <0.5 ppb — 0.6 ppb No MCL < 0.5 — 0.8 ppb 5 ppb < 0.0005 — 0.0092 ppm10 ppm None 0 ppb 10 ppm Rubber manufacturing; refrigerant; propellant in polystyrene foam production Fumigant for ground pest control; constituent of ethyl gasoline Solvent used in paint coatings; Component of aviation and automotive gasoline Fuel additive Dry cleaning agent; degreaser Solvent used in paint coatings, adhesives, and fuel < 0.1 — 0.19 ppb < 0.6 — 2.9 ppb < 0.04 — 0.12 ppb 70 ppb 6 ppb 1 ppb 70 ppb 0 ppb 0 ppb Herbicide used for weed control Rubber and chemical manufacturing Wood preservative < 0.5 < 0.5 < 0.5 < 0.5 < 0.5 n/a n/a n/a n/a 80 ppb n/a n/a n/a n/a 0 ppb By-product of chlorination By-product of chlorination By-product of chlorination By-product of chlorination By-product of chlorination MCLG Major Sources 0 1.3 ppm Corrosion of household plumbing systems Corrosion of household plumbing systems Synthetic Organics Contaminant— 1998 2,4-Dichlorophenoxy acetic acid 0.19 ppb Di(2-ethylhexyl)phthalate 2.9 ppb Pentachlorophenol 0.12 ppb Trihalomethanes Contaminant Chloroform Bromodichloromethane Bromoform Chlorodibromomethane Total Trihalomethanes (TTHMs) Annual Average for TTHMS 0.5 ppb 1.5 ppb 4.2 ppb 3 ppb 6.9 ppb 2.2 ppb — 0.5 ppb — 1.5 ppb — 4.2 ppb — 3 ppb — 6.9 ppb Contaminant No. of Samples Above 90th Percentile Value Action Level the Action Level Lead and Copper in Standing Water Samples — 1999 Lead one 3.4 ppb 15 ppb Copper none 0.23 ppm 1.3 ppm Contaminant Month of Highest Coliform Percentage Number of Positive Total # of Samples MCL Samples for the Month Collected for the Month Inorganics Total Coliform 2 May 1 246 11 positives June 1 246 11 positives A discretionary sample revealed 11 ppm nitrate, see additional information on detected contaminant. MCLG Major Sources 0 0 Naturally present in environment Naturally present in environment DEFINITIONS OF TECHNICAL AND REGULATORY TERMS Action level. The concentration of a contaminant which, if exceeded, triggers a treatment or other requirement which a water system must follow. Maximum Contaminant Level (MCL). The highest level of a contaminant that is allowed in drinking water. MCLs are set as close to the MCLGs as feasible using the best available treatment technology. If a contaminant is believed to cause health concerns in humans, then the MCL is set as close as practical to zero and at an acceptable level of risk. Generally, the maximum acceptable risk of cancer is 1 in 10,000 with 70 years of exposure. Maximum Contaminant Level Goal (MCLG). The level of a contaminant in drinking water below which there is no known or expected risk to health. MCLGs allow for a margin of safety. Parts Per Billion (ppb). Some constituents in water are measured in very small units. One ppb equals one microgram per liter. For example, one part per billion equals: 2 drops of water in a 15,000 gallon backyard swimming pool, one second of time in 31.7 years, or the first 16 inches of a trip to the moon. Parts Per Million (ppm). One ppm equals one milligram per liter. One part per million equals: 1/4 cup of water in a typical 15,000 gallon backyard swimming pool or one second of time in 11.6 days. Picocurie Per Liter (pCi/l). The quantity of radioactive material in one liter which produces 2.22 nuclear disintegrations per minute. Point of Entry (POE). All water sources are monitored at the point of entry to the distribution system before the first customer but after any required treatment. For most wells directly feeding the distribution system without treatment, the POE is the well, but in a few cases where the water from a number of wells is collected in a common pipeline before delivery, the POE represents a number of wells in a well field. Treatment Technique. A required process intended to reduce the level of a contaminant in drinking water. 3 DETECTED CONTAMINANTS: PERCENT OF POSITIVE SAMPLES FOR TOTAL COLIFORM EPA Maximum Contamination Level is 5% 1997 1998 1999 2000 INFORMATION ON DETECTED CONTAMINANTS Coliform bacteria are very commonly found in the environment and in the digestive tracts of animals. While rarely harmful, coliform bacteria in drinking water are an indicator that the water may also contain harmful microorganisms. unexpected increase in well SC-006a, which serves about 330 customers located south of Hughes Access Road and west of Nogales Highway. This well had a 50 percent increase in nitrate within 30 days. When the 11 ppm concentration test result was received, the well was immediately closed, customers were notified and bottled water provided until an alternate source of water could be routed to this area. This was the only case nitrate was above the 10 ppm standard. The next highest level for nitrate was 8.3 ppm. Tucson Water performs extra monitoring for wells high in nitrate for extra assurance that action can be taken when approaching the MCL. Nitrate in drinking water at levels above 10 ppm is a health risk for infants of less than six months of age. High nitrate levels in drinking water can cause blue baby syndrome. Arsenic is a naturally occurring substance commonly found in groundwater in the southwestern United States that is known to cause cancer at high concentrations. EPA is reviewing the drinking water standard for arsenic because of special concerns that it may not be stringent enough. To prepare for the lower standard Tucson Water is participating in studies to determine the best treatment process for removing arsenic from Tucson groundwater. Tucson Water completed four quarters of arsenic monitoring at all points of entry (POE) to determine the impact of this new standard. The highest arsenic concentration was 10 ppb. For more information and a color-coded map indicating the arsenic concentrations in our wells, please visit our website: www.ci.tucson.az.us/ water/. Lead and Copper are naturally occurring metals, which are generally found at very low levels in source waters. However these levels can increase when water contacts plumbing materials that contain lead or copper or brass. Infants and young children are more vulnerable to lead in drinking water than the general population. While Tucson Water is well within standards, concerned customers can take an extra precaution to protect children from lead leached from new brass faucets by running the water for a few seconds and using the water for something other than drinking. This is especially important if the water has been sitting in the pipes for a few hours or more. Fluoride is an important naturally occurring mineral that helps to form healthy teeth and bones. A concentration of 0.8 ppm is considered optimum for Tucson. At concentrations above 2 ppm, fluoride can cause mild discoloration of teeth, and exposure at above the MCL of 4 can cause both severe discoloration of teeth and over many years of exposure, bone disease. Nitrate is a form of nitrogen and an important plant nutrient. Nitrate values met standards except for an 4 Adjusted Gross Alpha is a measure of radioactivity due to naturally occurring minerals in groundwater. The MCL for gross alpha radioactivity is set at 15 picocuries per liter (pCi/l). This excludes the radioactivity contributed by either radon or uranium. INFORMATION ON DETECTED CONTAMINANTS (CONTINUED) refurbished water pressure tanks. These low concentration releases from pressure tank coatings rapidly decrease as the tank ages. One POE had ethylbenzene at 1.1 ppb (the MCL is 700ppb), and three POEs had total xylenes of which 0.0092 ppm was the maximum (the MCL is 10 ppm). Radon is a naturally occurring radioactive gas that may cause cancer, and may be found in drinking water and indoor air. While ingesting radon in drinking water has a small risk, inhaling radon is a primary health concern, particularly for smokers or ex-smokers. Radon diffusing up from the soil into homes and buildings is usually the main source of radon in indoor air. Only about 1-2 percent of radon in indoor air comes from drinking water. Methyl-tert-butyl Ether (MTBE) was detected in only a single well at the very low concentration of 0.6 ppb. MTBE is a popular gasoline additive used to reduce air pollution. EPA is currently reevaluating its use due to its threat to water supplies. While MTBE is not thought to be a significant health threat at low concentrations, it has a very low taste and odor threshold and is difficult to remove from drinking water supplies by treatment. Unlike most VOCs, MTBE is very soluble in water. This property allows it to move readily with percolating water and contaminate groundwater much more readily than the less soluble components of gasoline. MTBE does not appear to present a major threat to Tucson’s groundwater supplies. If you are concerned about radon in your home, you should test your house and install controls if you find a level of 4 pCi/l or higher in your indoor air. For more information, call USEPA’s Radon Hotline (800-SOSRADON) or visit the web site http://www.epa.gov/iaq/ radon/. The USEPA does not currently have a final regulation for radon in drinking water. Extra radon monitoring was performed on the Tucson Water wells in two quarters during 2000. Test results indicate that, when compared with other communities across the country, Tucson has fairly typical concentrations for radon in the water supply. For more information on radon, please visit our website: www.ci.tucson.az.us/ water/ Tetrachloroethylene (PCE) was detected in one well. The detected amount was 0.8 ppb. Synthetic Organic Contaminants (SOCs) are occasionally detected in a monitoring sample, but the presence of an SOC in the water produced by a potable supply well has never been confirmed. The few occasions when SOCs were detected can be attributed to contamination during sampling, shipping, or in the laboratory. Tucson Water was not required to sample for SOCs during 2000. The detected SOCs shown in the table are from 1998. Radium 226 and 228 are two radioisotopes of radium. The combined amount of both currently cannot exceed an MCL of 5 pCi/l. Uranium is a metallic element, which is highly toxic and radioactive. The USEPA has just set a new standard of 30 ppb or approximately 30 pCi/l for uranium, which water systems must meet by December 2003. Chloroform, Bromodichloromethane, Bromoform, and Chlorodibromomethane are unregulated Volatile Organic Contaminants that make up the contaminant group known as total trihalomethanes. These compounds are detected at very low concentrations in Tucson’s chlorinated groundwater. Volatile Organic Compounds (VOCs) include such compounds as trichloroethylene (TCE) and tetrachloroethylene (PCE). VOCs are volatile like alcohol or gasoline and are made up of relatively small molecules, which allows them to migrate readily through soils. Solvents such as TCE and PCE have been commonly used for cleaning machine parts, and for dry cleaning. These contaminants are often associated with industrial operations and landfills. Despite the vulnerability of groundwater to such contamination, Tucson Water’s potable supplies are virtually free of such contamination. Total Trihalomethanes (TTHMs) are formed when chlorine combines with naturally occurring organic material in water. Since the level of organic matter in our groundwater is extremely low, these compounds are found at very low concentrations. Compliance with the TTHM is based on the running average quarterly concentration at 16 distribution monitoring points, (2.2 ppb for the year 2000). The compounds, which make up the TTHMs, include: chloroform, Bromodichloromethane, bromoform, and chlorodibromomethane. The highest TTHM result in any system sample was 6.9 ppb and the highest concentration for any of the four compounds was 4.2 ppb for bromoform. The standard is 80 ppb. Chloromethane and Dibromomethane are industrial solvents and were both detected at 0.7 ppb and 0.9 ppb respectively. Ethylbenzene and Xylenes are residual solvents, typically associated with the coatings used to protect new or 5 MONITORING WAIVERS HOW IS OUR DRINKING WATER TREATED? The Arizona Department of Environmental Quality, the regulatory agency for all public water suppliers in Arizona, grants waivers for certain monitoring requirements during a year. Waivers are granted for specific contaminants if previous monitoring results, and the land uses within a half-mile radius of the well, allows ADEQ to conclude that the risk of contamination by a specific substance is very low. The groundwater delivered by Tucson Water meets all drinking water standards without treatment, with the exception of the water supplied from the Tucson Airport Area Remediation Project (TARP) wells. However, approximately 0.8 parts per million (ppm) of chlorine is added to the drinking water supply at well sites, and approximately 1 ppm is added to reservoirs and other facilities to provide assurance that water delivered to customers will remain free of microbiological LATE MONITORING AND REPORTING contamination. This also ensures that the water meets At the end of each year Tucson Water conducts an internal microbiological drinking water standards from the time audit of compliance monitoring records to verify that all it is pumped from the ground until it reaches the required monitoring has been completed and reported to customer’s tap. the State. The 2000 audit revealed that Tucson Water was late on one occasion in reporting results to the State: The MORE ABOUT TARP reports on 13 microbiological samples taken in March 2000 The TARP program was developed in order to clean and were due to ADEQ by April 10, 2000, but were sent on make beneficial use of water contaminated with the April 17, 2000. A public notification for this violation was industrial solvent trichloroethylene (TCE). Tucson Water published in The Arizona Daily Star and The Tucson Citizen operates TARP under an agreement with the USEPA and newspapers. As stated in the public notice, this was a other industrial and governmental agencies, which pay reporting error only and it does not represent any threat for operation of the TARP program. to public health. Nine wells extract the contaminated water and deliver it through a pipeline to a treatment plant that removes the TCE from the water. The TARP treatment plant uses an “air stripping” process which forces volatile contaminants such as TCE to evaporate from the water into air. The air is then passed through activated carbon filters, which removes the airborne TCE. The TARP plant treats approximately 7.3 million gallons of water per day. During 2000, this plant treated a total of approximately 2.7 billion gallons of water. WHAT ABOUT CAP WATER? City of Tucson has rights to approximately 139,000 acrefeet of Colorado River water per year delivered through the Central Arizona Project (CAP). However, no CAP water was delivered to drinking water customers in 2000. At the Clearwater Renewable Resource Facility located in Avra Valley, Tucson Water is recharging a portion of the City’s available CAP supply by delivering the river water to shallow basins and allowing the water to percolate (or recharge) naturally through the earth to reach and blend with the groundwater below. Tucson Water began delivery of this blend of recharged CAP water and groundwater in May 2001. In the early years of delivery, this new source will primarily be Avra Valley (AV) groundwater. Over time, it will contain an increasing percentage of recharged CAP water. During the year 2000, Tucson Water served a mixture of (AV) groundwater and recharged CAP water to selected volunteer neighborhoods in Tucson, which approximates what this blend will be like in 8 to 10 years. Information on the quality of this blend is not contained in this report, but is available on Tucson Water’s web site. This treated water has non-detected levels of TCE. The treated water has been tested on a weekly basis since the start of operations in 1994. The cleaned water flows into the Tucson Water system and is delivered to customers as part of the drinking water supply. This water accounts for approximately 8 % of water served on a daily basis by Tucson Water. 6 WHO DO I CONTACT FOR MORE INFORMATION? For more information on this Tucson Water report contact Tom Jefferson with the Water Quality Management Division. Call 791-5252 or e-mail your questions to tjeffer1@ci.tucson.az.us. The Water Quality Management Division also publishes an Annual Microbiological Water Quality report detailing the results of monthly distribution system monitoring. Call 791-5252 for more information. In 2000, Tucson Water also collected additional monthly water quality data. The results of this additional monitoring are available on the Tucson Water web page, www.ci.tucson.az.us/water/, and the water quality phone line. In early 2001 Tucson Water and a number of partners were awarded a $400,000 grant by the USEPA Environmental Monitoring for Public Access and Community Tracking (EMPACT) program. The funds will be used to support additional distribution of water quality information to the community. Tucson Water P.O.Box 27210 Tucson, AZ 85726-7210 TELEPHONE NUMBERS: Tucson Water Quality Automated phone line: 791-4227 Tucson Water Public Information Office: 791-4331 Tucson Water Quality Management Division: 791-5252 Tucson Water Customer Advocate: 791-5945 Tucson Water Customer Service/Billing: 791-3242 Tucson Water 24-hour Emergency: 791-4133 United States Environmental Protection Agency Safe Drinking Water Hotline: 1-800-426-4791 USEPA Website: www.epa.gov/safewater/ Si usted desea este documento escrito en español, por favor, llame al 791-4331. City of Tucson TTY#: 791-2639 The Report Cost: The approximate cost for printing and mailing each of these individual reports was 30 cents. 7 PIO 5/01